{"id":188744,"date":"2019-11-01T12:00:59","date_gmt":"2019-11-01T04:00:59","guid":{"rendered":"\/\/m.iemloyee.com\/?p=188744"},"modified":"2019-10-31T14:14:05","modified_gmt":"2019-10-31T06:14:05","slug":"%e5%b7%b2%e6%a0%a1%e7%a8%bf%e4%bb%b6-%e8%83%a1%e6%96%8c%e5%9b%a2%e9%98%9f-joule-%e6%8a%a5%e9%81%93%ef%bc%9a%e5%88%a9%e7%94%a8%e7%9c%9f%e7%a9%ba%e6%9e%81%e5%8c%96-vacuum-poling-%e4%bd%bf%e5%87%86","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=188744","title":{"rendered":"\u80e1\u658c\u56e2\u961f Joule \u62a5\u9053\uff1a\u5229\u7528\u771f\u7a7a\u6781\u5316 (Vacuum poling) \u4f7f\u51c6\u4e8c\u7ef4\u9499\u949b\u77ff\u5747\u5300\u6392\u5217\u4ece\u800c\u5f62\u6210\u9ad8\u6548\u3001\u9ad8\u586b\u5145\u56e0\u5b50\u592a\u9633\u80fd\u7535\u6c60"},"content":{"rendered":"

\u3010\u80cc\u666f\u4ecb\u7ecd\u3011<\/strong><\/p>\n

\u901a\u8fc7\u7814\u7a76\u53d1\u73b0\uff0c\u5728\u6709\u673a\u65e0\u673a\u5364\u5316\u7269\u4e09\u7ef4\u9499\u949b\u77ff\uff08AMX3<\/sub>\uff09\u4e2d\u5f15\u5165\u5177\u6709\u758f\u6c34\u7279\u6027\u7684\u957f\u94fe\u6709\u673a\u914d\u4f53A\u2019\uff0c\u4f1a\u5f62\u6210\u5206\u5b50\u5f0f\u4e3aA\u20192<\/sub>An-1<\/sub>Mn<\/sub>X3n+1<\/sub>\u7684\u51c6\u4e8c\u7ef4\u9499\u949b\u77ff\u7ed3\u6784\uff0c\u5176\u4e2dn\u8868\u793a\u89d2\u5171\u4eab\u7684[MX6<\/sub>]4-<\/sup>\u516b\u9762\u4f53\u7684\u5c42\u6570\uff0cA\u3001M\u548cX\u5206\u522b\u8868\u793a\u4e00\u4ef7\u9633\u79bb\u5b50\u3001\u4e8c\u4ef7\u91d1\u5c5e\u9633\u79bb\u5b50\u548c\u5364\u5316\u7269\u9634\u79bb\u5b50\u3002\u8fd9\u79cd\u51c6\u4e8c\u7ef4\u8bbe\u8ba1\u5927\u5e45\u5ea6\u5730\u63d0\u9ad8\u4e86\u9499\u949b\u77ff\u6750\u6599\u7684\u7a33\u5b9a\u6027\uff0c\u540c\u65f6\u4e5f\u6781\u5927\u5730\u4e30\u5bcc\u4e86\u5176\u5149\u7535\u6027\u80fd\u3002\u901a\u8fc7\u8c03\u8282A\/A\u2019\u5206\u5b50\u7684\u6bd4\u4f8b\u6765\u63a7\u5236\u5f62\u6001\u7ed3\u6784\uff0c\u4ece\u800c\u5728\u5149\u5b66\u6027\u80fd\u4e0a\u5177\u6709\u53ef\u8c03\u6027\uff0c\u8fd9\u662f\u51c6\u4e8c\u7ef4\u9499\u949b\u77ff\u7684\u7279\u6709\u6027\u8d28\u3002\u7136\u800c\uff0c\u968f\u7740\u957f\u94fe\u7edd\u7f18\u6709\u673a\u914d\u4f53\u7684\u5f15\u5165\uff0c\u8f7d\u6d41\u5b50\u4f20\u8f93\u6210\u4e3a\u53d1\u5c55\u5176\u5149\u7535\u6027\u80fd\u7684\u9650\u5236\u56e0\u7d20\u3002<\/p>\n

\u901a\u5e38\u60c5\u51b5\u4e0b\uff0c\u51c6\u4e8c\u7ef4\u9499\u949b\u77ff\u8584\u819c\u4e0a\u4e0b\u8868\u9762\u4e4b\u95f4\u7684\u4ece\u5c0fn\u503c\u5230\u5927n\u503c\u7eb3\u7c73\u7247\u5728\u7ad6\u76f4\u65b9\u5411\u4e0a\u7684\u6709\u5e8f\u6392\u5217\uff0c\u662f\u57fa\u4e8e\u4e0d\u540cn\u503c\u7eb3\u7c73\u7247\u7684\u4e0d\u540c\u751f\u957f\u901f\u7387\u5728\u70ed\u52a8\u529b\u63a7\u5236\u4e0b\u81ea\u7ec4\u88c5\u7684\u3002\u5728\u51c6\u4e8c\u7ef4\u9499\u949b\u77ff\u8584\u819c\u4e2d\uff0c\u8fd9\u79cd\u7ad6\u76f4\u65b9\u5411\u4e0a\u6709\u5e8f\u7684n\u503c\u5206\u5e03\u63d0\u4f9b\u4e86\u4e00\u79cd\u80fd\u91cf\u7ea7\u8054\u7ed3\u6784\uff0c\u53ef\u540c\u65f6\u8f6c\u79fb\u7535\u5b50\u548c\u7a7a\u7a74\uff0c\u4ece\u800c\u589e\u5f3a\u4e86\u8f7d\u6d41\u5b50\u7684\u4f20\u8f93\u3002\u56e0\u6b64\uff0c\u5782\u76f4\u6392\u5217\u7684\u51c6\u4e8c\u7ef4\u9499\u949b\u77ff\u8584\u819c\u662f\u4fc3\u8fdb\u5b9a\u5411\u7535\u8377\u8f6c\u79fb\u7684\u5e38\u7528\u65b9\u6cd5\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u7f8e\u56fd\u7530\u7eb3\u897f\u5927\u5b66\u7684\u80e1\u658c\u6559\u6388\uff08\u901a\u8baf\u4f5c\u8005\uff09<\/strong>\u56e2\u961f\u62a5\u9053\u4e86\u4e00\u79cd\u901a\u8fc7\u5f15\u5165\u771f\u7a7a\u6781\u5316(Vacuum poling)\u5904\u7406\u6765\u5f3a\u5316\u7ed3\u6676\u8fc7\u7a0b\u4e2d\u7684\u6210\u6838\uff0c\u4ece\u800c\u5747\u5300\u5730\u6392\u5217\u4e0d\u540cn\u503c\u7684\u7eb3\u7c73\u7247\uff08PEA2<\/sub>MAn-1<\/sub>Pbn<\/sub>I3n+1<\/sub>\uff09\u7684\u65b0\u7b56\u7565\u3002\u901a\u8fc7\u76d1\u6d4b\u5149\u5438\u6536\u3001\u5149\u81f4\u53d1\u5149\uff08PL\uff09\u3001\u80fd\u91cf\u8272\u6563X\u5c04\u7ebf\u5149\u8c31\uff08EDS\uff09\u4ee5\u53ca\u5f00\u53d1\u7684\u7cbe\u7ec6\u673a\u68b0\u5265\u79bb\u6cd5\u8bc1\u660e\u4e86\u8fd9\u79cd\u5747\u5300\u5206\u5e03\u3002\u5728\u5747\u5300\u5206\u5e03\u7684\u60c5\u51b5\u4e0b\uff0c\u77ac\u6001\u5438\u6536\u663e\u793a\u4e8610 ps\u5185\u7684\u6709\u6548\u8f7d\u6d41\u5b50\u8f6c\u79fb\u3002\u6b64\u5916\uff0c\u586b\u5145\u56e0\u5b50\uff08FF\uff09\u9ad8\u8fbe82.4%\uff0c\u80fd\u91cf\u8f6c\u6362\u6548\u7387\uff08PCE\uff09\u4e3a18.04%\uff08Voc<\/sub>=1.223 V\u3001Jsc<\/sub>=17.91 mA\/cm2<\/sup>\uff09\u3002\u5728\u4fdd\u5b588\u4e2a\u6708\u540e\uff0c\u5668\u4ef6\u4ecd\u7136\u53ef\u4ee5\u4fdd\u630196.1\uff05\u7684\u521d\u59cb\u6548\u7387\uff0c\u5e76\u572880\u00b0C\u4e0b180 h\u4fdd\u630197.7\uff05\u7684\u521d\u59cb\u6548\u7387\uff0c\u4ece\u800c\u8bc1\u660e\u5176\u6709\u4f18\u5f02\u7684\u7a33\u5b9a\u6027\u3002\u603b\u4e4b\uff0c\u8fd9\u79cd\u5747\u5300\u6392\u5217\u7684\u4e0d\u540cn\u503c\u7eb3\u7c73\u7247\u53ef\u4ee5\u589e\u5f3a\u5404\u5411\u540c\u6027\u7684\u8f7d\u6d41\u5b50\u7684\u8f6c\u79fb\u548c\u63d0\u53d6\uff0c\u4ece\u800c\u6709\u52a9\u4e8e\u5f00\u53d1\u51fa\u9ad8\u6548\u4e14\u7a33\u5b9a\u7684\u51c6\u4e8c\u7ef4\u9499\u949b\u77ff\u578b\u592a\u9633\u80fd\u7535\u6c60\u3002\u7814\u7a76\u6210\u679c\u4ee5\u9898\u4e3a\u201cUniform Permutation of Quasi-2D Perovskites by Vacuum Poling for Efficient, High-Fill-Factor Solar Cells\u201d<\/strong>\u53d1\u8868\u5728\u56fd\u9645\u8457\u540d\u671f\u520aJoule<\/strong>\u4e0a\u3002<\/p>\n

\"\"<\/p>\n

\u3010\u6587\u7ae0\u4eae\u70b9\u3011<\/strong><\/p>\n

1\u3001 \u901a\u8fc7\u771f\u7a7a\u6781\u5316 (Vacuum poling) \u5b9e\u73b0\u4e0d\u540cn\u503c\u7eb3\u7c73\u7247\u7684\u5747\u5300\u5206\u5e03\u3002<\/p>\n

2\u3001 \u57fa\u4e8e\u80f6\u5e26\u5265\u79bb\u7684\u5149\u5b66\u7814\u7a76\u8bc1\u5b9e\u4e86\u5176\u5747\u5300\u5206\u5e03\u3002<\/p>\n

3\u3001\u5747\u5300\u5206\u5e03\u53ef\u5b9e\u73b0\u9ad8\u6548\u7684\u5404\u5411\u540c\u6027\u7684\u8f7d\u6d41\u5b50\u6536\u96c6\u3002<\/p>\n

4\u3001\u5747\u5300\u5206\u5e03\u53ef\u83b7\u5f97\u9ad8\u6548\u7387\uff0818.04\uff05\uff09\u548c\u6700\u9ad8\u7684FF\uff0882.4\uff05\uff09\u3002<\/p>\n

\u3010\u56fe\u6587\u89e3\u8bfb\u3011<\/strong><\/p>\n

\u56fe\u4e00\u3001\u6709\u65e0\u771f\u7a7a\u6781\u5316(Vacuum poling)\u5904\u7406\u7684\u51c6\u4e8c\u7ef4\u9499\u949b\u77ff\u8584\u819c\u7684\u5236\u5907\u8fc7\u7a0b\u548c\u57fa\u4e8e\u5e26\u5265\u79bb\u7684\u5149\u81f4\u53d1\u5149\u793a\u610f\u56fe<\/strong>
\n \"\"\uff08A\uff09\u6709\u65e0\u771f\u7a7a\u6781\u5316(Vacuum poling)\u5904\u7406\u7684\u51c6\u4e8c\u7ef4\u9499\u949b\u77ff\u8584\u819c\u7684\u5236\u5907\u5de5\u827a\uff1b<\/p>\n

\uff08B-C\uff09\u673a\u68b0\u5265\u79bb\u6cd5\u6495\u53bb\u8584\u819c\u4e0a\u8868\u9762\u524d\u540e\u7684PL\u8c31\u53d8\u5316\uff1b<\/p>\n

\uff08D-E\uff09\u4e0d\u540cn\u503c\u7684\u7eb3\u7c73\u7247\u7684\u5747\u5300\u5206\u5e03\u548c\u5782\u76f4\u9636\u68af\u72b6\u5206\u5e03\u3002<\/p>\n

\u56fe\u4e8c\u3001\u6709\u65e0\u771f\u7a7a\u6781\u5316(Vacuum poling)\u5904\u7406\u5236\u5907\u7684\u51c6\u4e8c\u7ef4\u9499\u949b\u77ff\u8f7d\u6d41\u5b50\u8fc1\u79fb\u52a8\u529b\u5b66\u7279\u5f81<\/strong>
\n \"\"\uff08A-B\uff09\u6709\u65e0\u771f\u7a7a\u6781\u5316(Vacuum poling)\u5904\u7406\u7684\u51c6\u4e8c\u7ef4\u9499\u949b\u77ff\u8584\u819c\u4ece\u9876\u90e8\u548c\u5e95\u90e8\u6fc0\u53d1\u7684TA\u8c31\uff1b<\/p>\n

\uff08C\uff09\u91c7\u7528\u771f\u7a7a\u6781\u5316(Vacuum poling)\u5904\u7406\u7684<n>=5\u8584\u819c\uff0c\u5728\u5c0fn\u503c\u7eb3\u7c73\u7247\u4e0a\u663e\u793a\u7684\u6b63\u77ac\u6001\u5438\u6536\u4fe1\u53f7\uff0c\u5e76\u5728724 nm\u5904\u5feb\u901f\u589e\u52a0\u7684\u8d1f\u4fe1\u53f7\uff1b<\/p>\n

\uff08D\uff09\u672a\u7ecf\u771f\u7a7a\u6781\u5316(Vacuum poling)\u5904\u7406\u7684<n>=5\u8584\u819c\u5728\u5c0fn\u503c\u7eb3\u7c73\u7247\u4e0a\u663e\u793a\u6b63\u548c\u8d1f\u77ac\u6001\u5438\u6536\u4fe1\u53f7\uff0c\u800c\u5728750 nm\u5904\u7f13\u6162\u589e\u52a0\u7684\u8d1f\u4fe1\u53f7\u3002<\/p>\n

\u56fe\u4e09\u3001\u6709\u65e0\u771f\u7a7a\u6781\u5316(Vacuum poling)\u5904\u7406\u5236\u5907\u7684\u51c6\u4e8c\u7ef4\u9499\u949b\u77ff\u8584\u819c\u7684PL\u8868\u5f81\u548c\u52a8\u529b\u5b66<\/strong><\/p>\n

\"\"\uff08A-B\uff09\u6709\u65e0\u771f\u7a7a\u6781\u5316(Vacuum poling)\u5904\u7406\u5236\u5907\u7684\u51c6\u4e8c\u7ef4\u9499\u949b\u77ff\u8584\u819c\u7684PL\u5149\u8c31\uff1b<\/p>\n

\uff08C\uff09\u4e0e\u6709\u65e0\u771f\u7a7a\u6781\u5316(Vacuum poling)\u5904\u7406\u5236\u5907\u7684\u5c0fn\u503c\u7eb3\u7c73\u7247\u76f8\u5173\u7684\u53d1\u5c04\u5cf0\u2264710 nm\u7684PL\u6fc0\u53d1\u5f3a\u5ea6\u4f9d\u8d56\u6027\uff1b<\/p>\n

\uff08D\uff09\u5728\u6709\u65e0\u771f\u7a7a\u6781\u5316(Vacuum poling)\u5904\u7406\u7684\u60c5\u51b5\u4e0b\uff0c\u5236\u5907\u7684\u6700\u5927n\u503c\u7eb3\u7c73\u7247\u7684PL\u6fc0\u53d1\u5f3a\u5ea6\u4f9d\u8d56\u6027\uff1b<\/p>\n

\uff08E-F\uff09\u6709\u65e0\u771f\u7a7a\u6781\u5316(Vacuum poling)\u5904\u7406\u5236\u5907\u7684\u51c6\u4e8c\u7ef4\u9499\u949b\u77ff\u8584\u819c\u7684PL\u52a8\u529b\u5b66\u3002<\/p>\n

\u56fe\u56db\u3001\u6709\u65e0\u771f\u7a7a\u6781\u5316(Vacuum poling)\u5904\u7406\u5236\u5907\u7684\u51c6\u4e8c\u7ef4\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u7684\u7279\u6027\u548c\u793a\u610f\u56fe<\/strong>
\n \"\"\uff08A\uff09\u57281\u4e2a\u592a\u9633\u7167\u5c04\u4e0b\uff0c\u901a\u8fc7\u771f\u7a7a\u6781\u5316(Vacuum poling)\u5904\u7406\u5236\u5907\u7684\u51c6\u4e8c\u7ef4\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u7684I-V\u7279\u6027\uff1b<\/p>\n

\uff08B\uff09\u771f\u7a7a\u9884\u5904\u7406\u7684\u51c6\u4e8c\u7ef4\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u6548\u7387\u540c\u6587\u732e\u53d1\u8868\u7684\u57fa\u4e8ePEA+<\/sup>\u548cBA+<\/sup>\u7684\u592a\u9633\u80fd\u7535\u6c60\u7684\u6548\u7387\u5bf9\u6bd4\uff1b<\/p>\n

\uff08C\uff09\u901a\u8fc7\u771f\u7a7a\u6781\u5316(Vacuum poling)\u5904\u7406\u5236\u5907\u7684\u51c6\u4e8c\u7ef4\u9499\u949b\u77ff\u5668\u4ef6\u7684\u7a33\u5b9a\u6027\uff1b<\/p>\n

\uff08D\uff09\u5177\u6709\u4e09\u79cd\u4e0d\u540c\u8bbe\u8ba1\u7684\u51c6\u4e8c\u7ef4\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u7684\u5149\u4f0f\u6027\u80fd\u7edf\u8ba1\u6570\u636e\uff1b<\/p>\n

\uff08E-F\uff09\u6709\u65e0\u771f\u7a7a\u6781\u5316(Vacuum poling)\u5904\u7406\u7684\u9499\u949b\u77ff\u8584\u819c\u5185\u90e8\u4e0d\u540cn\u503c\u7eb3\u7c73\u7247\u7684\u5206\u5e03\u60c5\u51b5\u3002<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n

\u7efc\u4e0a\u6240\u8ff0\uff0c\u4f5c\u8005\u901a\u8fc7\u5f15\u5165\u771f\u7a7a\u6781\u5316 (Vacuum poling) \u5904\u7406\uff0c\u7814\u7a76\u4e86\u5728\u51c6\u4e8c\u7ef4\u9499\u949b\u77ff\u8584\u819c[(PEA)2<\/sub>(MA)n-1<\/sub>Pbn<\/sub>I3n+1<\/sub>]\u7684\u4e0a\u4e0b\u8868\u9762\u4e4b\u95f4\u5747\u5300\u5206\u5e03\u7684\u4e0d\u540cn\u503c\u7eb3\u7c73\u7247\u7684\u5747\u5300\u5206\u5e03\u6027\u3002\u5728\u6ca1\u6709\u771f\u7a7a\u6781\u5316 (Vacuum poling) \u5904\u7406\u4e0b\uff0c\u5728\u51c6\u4e8c\u7ef4\u9499\u949b\u77ff\u819c\u7684\u4e0a\u4e0b\u8868\u9762\u4e4b\u95f4\uff0c\u4e0d\u540cn\u503c\u7684\u7eb3\u7c73\u7247\u5c06\u5f62\u6210\u6309n\u503c\u4ece\u5c0f\u5230\u5927\u7684\u5782\u76f4\u987a\u5e8f\u5206\u5e03\u3002\u901a\u8fc7\u80f6\u5e26\u5265\u79bb\u65b9\u6cd5\u9a8c\u8bc1\u4e86\u4e0d\u540cn\u503c\u7eb3\u7c73\u7247\u5728\u4e0a\u4e0b\u8868\u9762\u4e4b\u95f4\u7684\u5747\u5300\u548c\u6709\u5e8f\u7684\u5206\u5e03\u6027\uff0c\u5e76\u5229\u7528EDS\u3001PL\u5149\u8c31\u548c\u5149\u5b66\u5438\u6536\u8fdb\u884c\u68c0\u6d4b\uff0c\u540c\u65f6\u5c06\u7eb3\u7c73\u7247\u7684\u5355\u5206\u5b50\u5c42\u4ece\u9876\u8868\u9762\u673a\u68b0\u5730\u5206\u79bb\u5230\u5e95\u8868\u9762\u3002TA\u7ed3\u679c\u8868\u660e\uff0c\u4e0d\u540cn\u503c\u7eb3\u7c73\u7247\u7684\u5747\u5300\u5206\u5e03\u5c06\u5bfc\u81f4\u7535\u8377\u572810 ps\u5185\u5feb\u901f\u5411\u6700\u5927n\u503c\u7eb3\u7c73\u677f\u8f6c\u79fb\u3002\u800cPL\u52a8\u529b\u5b66\u7814\u7a76\u8868\u660e\uff0c\u5229\u7528\u771f\u7a7a\u6781\u5316 (Vacuum poling) \u5236\u5907\u7684\u51c6\u4e8c\u7ef4\u9499\u949b\u77ff\u8584\u819c\u5177\u6709\u589e\u5f3a\u7684PL\u5f3a\u5ea6\u548c\u5ef6\u957f\u7684\u4f7f\u7528\u5bff\u547d\u3002\u6b64\u5916\uff0c\u5728\u4e0d\u540cn\u503c\u7eb3\u7c73\u7247\u7684\u5747\u5300\u5206\u5e03\u4e0b\uff0c\u51c6\u4e8c\u7ef4\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u663e\u793a\u51fa\u521b\u7eaa\u5f55\u7684FF\uff0882.4\uff05\uff09\uff0c\u6700\u5927PCE\u4e3a18.04\uff05\u3002\u5728\u4fdd\u5b588\u4e2a\u6708\u540e\uff0c\u5176\u521d\u59cb\u6548\u7387\u4ecd\u4fdd\u630196\uff05\u4ee5\u4e0a\uff0c\u572880\u2103\u8fd0\u884c180 h\uff0c\u4ecd\u4fdd\u6301\u5176\u539f\u59cb\u503c\u768497.7\uff05\uff0c\u5177\u6709\u4f18\u5f02\u7684\u7a33\u5b9a\u6027\u3002\u56e0\u6b64\uff0c\u901a\u8fc7\u771f\u7a7a\u6781\u5316 (Vacuum poling) \u5904\u7406\u5f62\u6210\u5747\u5300\u6392\u5217\u3001\u4e0d\u540cn\u503c\u7684\u7eb3\u7c73\u7247\u53ef\u4ee5\u589e\u5f3a\u8f7d\u6d41\u5b50\u7684\u63d0\u53d6\uff0c\u4ece\u800c\u4e3a\u5f00\u53d1\u51fa\u9ad8\u6027\u80fd\u7684\u51c6\u4e8c\u7ef4\u9499\u949b\u77ff\u5149\u7535\u5668\u4ef6\u63d0\u4f9b\u4e86\u4e00\u79cd\u65b0\u7b56\u7565\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1aUniform Permutation of Quasi-2D Perovskites by Vacuum Poling for Efficient, High-Fill-Factor Solar Cells<\/a><\/strong>\uff08Joule<\/em>, 2019<\/strong>, DOI: 0.1016\/j.joule.2019.09.020\uff09<\/p>\n

\u901a\u8baf\u4f5c\u8005\u7b80\u4ecb<\/strong><\/p>\n

\u80e1\u658c\u6559\u6388,\u7f8e\u56fd\u7530\u7eb3\u897f\u5927\u5b66\u7ec8\u8eab\u6559\u6388\u548c\u535a\u58eb\u5bfc\u5e08\uff0c\u540c\u65f6\u517c\u4efb\u7f8e\u56fd\u80fd\u6e90\u90e8\u6a61\u6811\u5cad\u56fd\u5bb6\u5b9e\u9a8c\u5ba4\u7684\u5ba2\u5ea7\u7814\u7a76\u5458\uff0c\u53f0\u6e7e\u6210\u529f\u5927\u5b66\u7684\u5ba2\u5ea7\u6559\u6388\uff0c\u7f8e\u56fd\u7269\u7406\u5b66\u4f1a\u3001\u6750\u6599\u7814\u7a76\u5b66\u4f1a\u3001\u7f8e\u56fd\u5316\u5b66\u5b66\u4f1a\u3001\u6709\u673a\u81ea\u65cb\u7535\u5b50\u5b66\u56fd\u9645\u54a8\u8be2\u59d4\u5458\u4f1a\u4f1a\u5458<\/strong>\u3002\u7814\u7a76\u9886\u57df\u5305\u62ec\uff1a\u6709\u673a\u81ea\u65cb\u5149\u7535\u5b50\u5b66\u3001\u5364\u5316\u7269\u9499\u949b\u77ff\u53ca\u6709\u673a\u592a\u9633\u80fd\u7535\u6c60\u548c\u9ad8\u5206\u5b50\u70ed\u7535\u8f6c\u6362\u3001\u6fc0\u53d1\u6001\u548c\u7535\u8377\u76f8\u5e72\u884c\u4e3a\u3002\u9488\u5bf9\u6709\u673a\u5149\u7535\u5b50\u5b66\u5728\u81ea\u53d1\u548c\u53d7\u6fc0\u533a\u57df\u5229\u7528\u81ea\u65cb-\u8f68\u9053\u8026\u5408\u8c03\u63a7\u5149\u4f0f\u3001\u53d1\u5149\u3001\u6fc0\u5149\u884c\u4e3a\u8fdb\u884c\u4e86\u5e7f\u6cdb\u6df1\u5165\u7684\u7814\u7a76\u3002\u8fd1\u5e74\u6765\u5728\u9ad8\u5f71\u54cd\u56e0\u5b50Nature Materials, Nature Communications, Advanced Materials, Advanced Energy Materials, Advanced Functional Materials, JACS, ACS Nano, Nano Energy, Small, Scientific Report \u7b49\u6742\u5fd7\u4e0a\u53d1\u8868\u4e86\u4e00\u7cfb\u5217\u5f88\u6709\u5f71\u54cd\u529b\u7684\u6587\u7ae0\u3002\u76ee\u524d\u5728\u6709\u673a\u5149\u7535\u5b50\u5b66\u3001\u6709\u673a\u81ea\u65cb\u5149\u7535\u5b50\u5b66\u3001\u9499\u949b\u77ff\u5149\u4f0f-\u53d1\u5149-\u6fc0\u5149\u7814\u7a76\u65b9\u9762\u5171\u53d1\u8868\u8bba\u6587160\u591a\u7bc7\uff0c\u4ed6\u5f15\u6b21\u6570\u8d85\u8fc75000\u3002<\/p>\n

\u76ee\u524d\uff0c\u80e1\u658c\u6559\u6388\u56e2\u961f\u4e3b\u8981\u81f4\u529b\u4e8e\u6750\u6599\u7269\u7406\u76f8\u5173\u7684\u57fa\u7840\u7814\u7a76\uff1a<\/strong><\/p>\n

(1) \u81ea\u65cb\u7535\u5b50\u5b66\u3002\u4e3b\u8981\u7814\u7a76\u6709\u673a\u534a\u5bfc\u4f53\u4e2d\u6fc0\u53d1\u6001\u81ea\u65cb\u76f8\u5173\u7684\u7269\u7406\u8fc7 \u7a0b\u4ee5\u53ca\u4e0d\u540c\u65f6\u95f4\u5c3a\u5ea6\u4e0b\u7684\u7535\u8377\u8f93\u8fd0\u7279\u6027\u3002<\/p>\n

(2) \u8f68\u9053\u7535\u5b50\u5b66\u3002\u4e3b\u8981\u7814\u7a76\u6709\u673a\u65e0\u673a\u6742\u5316\u9499\u949b\u77ff\u6750\u6599\u4e2d\u8f68\u9053-\u8f68\u9053\u76f8\u4e92\u4f5c\u7528\u3002<\/p>\n

(3) \u5149\u7269\u7406\u3002\u63a2\u7d22\u5149\u4f0f\u3001\u53d1\u5149\u4e8c\u6781\u7ba1\u4ee5\u53ca\u6fc0\u5149\u5668\u4ef6\u4e2d\u901a\u8fc7\u81ea\u65cb-\u8f68\u9053\u8026\u5408\u8c03\u63a7\u7684\u65b0\u7269\u7406\u673a\u5236\u3002<\/p>\n

\u56e2\u961f\u5728\u9499\u949b\u77ff\u9886\u57df\u7684\u8fd1\u671f\u5de5\u4f5c\u6c47\u603b\uff1a<\/strong><\/p>\n

1\uff1a\u9488\u5bf9\u9499\u949b\u77ff\u5149\u6d78\u6ce1\u548c\u6ede\u56de\u73b0\u8c61\uff0c\u56e2\u961f\u5229\u7528\u53d8\u9891\u963b\u6297\u8c31\u548c\u65f6\u95f4\u5206\u8fa8\u7684\u8367\u5149\u6d4b\u8bd5\u8bc1\u660e\u4f53\u6781\u5316\u548c\u754c\u9762\u6781\u5316\u5171\u540c\u4f5c\u7528\u4e8e\u9499\u949b\u77ff\u6750\u6599\u7684\u7535\u8377\u62c6\u5206\u3001\u8f93\u8fd0\u548c\u6536\u96c6\uff0c\u4ece\u800c\u4fc3\u8fdb\u5668\u4ef6\u77ed\u8def\u7535\u6d41\u3001\u5f00\u8def\u7535\u538b\u548c\u586b\u5145\u56e0\u5b50\u7684\u63d0\u5347\u3002
\n Zhao Chen, et al. & Bin Hu. Advanced Energy Materials<\/em> 5, 1500279 (2015<\/strong>). https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/aenm.201500279<\/p>\n

2\uff1a\u56e2\u961f\u7cfb\u7edf\u7814\u7a76\u4e86\u6742\u5316\u9499\u949b\u77ff\u4e2d\u6b63\u4e8c\u4ef7\u91d1\u5c5e\u539f\u5b50\u7684\u81ea\u65cb\u8f68\u9053\u8026\u5408\u5f3a\u5ea6\u5bf9\u9499\u949b\u592a\u9633\u80fd\u7535\u6c60\u5668\u4ef6\u6548\u7387\u7684\u5f71\u54cd\u3002\u9488\u5bf9\u94c5\u9521\u6df7\u5408\u9499\u949b\u77ff\u4f53\u7cfb\uff0c\u56e2\u961f\u901a\u8fc7\u504f\u632f\u5149\u6fc0\u53d1\u548c\u78c1\u6548\u5e94\u7b49\u7814\u7a76\u624b\u6bb5\u8bc1\u660e\u4e86\u81ea\u65cb\u8f68\u9053\u8026\u5408\u5f3a\u5ea6\u5f71\u54cd\u9499\u949b\u77ff\u5668\u4ef6\u7684\u5149\u4f0f\u6027\u80fd\u3002
\n Zhang Jia, et al. & Bin Hu. Nano Energy<\/em> 38, 297-303 (2017<\/strong>).
\n https:\/\/www.sciencedirect.com\/science\/article\/pii\/S221128551730349X<\/p>\n

3\uff1a\u5728\u9499\u949b\u77ff\uff08MAPbBr3<\/sub>\uff09LED\u5668\u4ef6\u5de5\u4f5c\u6761\u4ef6\u4e0b\uff0c\u56e2\u961f\u8bc1\u660e\u5149\u7535\u6d41\u548cPL\u7684\u5f62\u6210\u8fc7\u7a0b\u4e2d\u5b58\u5728\u5149\u81f4\u6781\u5316\u3002\u5728\u9ad8\u9891\u72b6\u6001\u4e0b\u7684\u5149\u81f4\u7535\u5b50\u6781\u5316\u53ef\u4ee5\u8f6c\u6362\u4e3a\u5728\u5076\u6781\u6781\u5316\u72b6\u6001\u4e0b\u7684\u5149\u81f4\u4ecb\u7535\u6781\u5316\uff0c\u4ece\u800c\u5f71\u54cd\u5668\u4ef6\u6027\u80fd\u3002
\n Ma Shengbo, et al. & Bin Hu. Nano Energy<\/em> 65, 104004 (2019<\/strong>).
\n https:\/\/www.sciencedirect.com\/science\/article\/pii\/S2211285519307116<\/p>\n

4: \u5229\u7528\u9499\u949b\u77ff\u5408\u6210\u8fc7\u7a0b\u4e2d\u4e0d\u540c\u524d\u9a71\u4f53\u7ed3\u6676\u901f\u7387\u7684\u4e0d\u540c\uff0c\u56e2\u961f\u5728\u7532\u80fa\u94c5\u6eb4\uff08MAPbBr3<\/sub>\uff09\u8584\u819c\u4e2d\u5b9e\u73b0\u4e86\u7528\u7eb3\u7c73\u7ea7\u5c0f\u6676\u7c92\u53bb\u949d\u5316\u5fae\u7c73\u7ea7\u5927\u6676\u7c92\uff0cLED\u5668\u4ef6\u5728\u6052\u538b\u5de5\u4f5c\u6761\u4ef6\u4e0b\u5b9e\u73b0\u4e86\u9499\u949b\u77ff\u7684\u81ea\u949d\u5316\u8fc7\u7a0b\u3002
\n Qin Jiajun, et al. & Bin Hu. iScience<\/em>, 19, 378-387 (2019<\/strong>).
\n https:\/\/www.sciencedirect.com\/science\/article\/pii\/S2589004219302718<\/p>\n

5\uff1a\u5728\u81ea\u949d\u5316\u9499\u949b\u77ff\uff08MAPbBr3<\/sub>\uff09\u8584\u819c\u4e2d\uff0c\u56e2\u961f\u5b9e\u73b0\u4e86\u65e0\u5fae\u8154\u8c03\u5236\u60c5\u51b5\u4e0b\u7684\u81ea\u53d1\u8f90\u5c04\u653e\u5927\u6548\u5e94\u3002\u901a\u8fc7\u77ac\u6001\u5438\u6536\u3001\u89d2\u5206\u8fa8\u8367\u5149\u5149\u8c31\u3001\u504f\u632f\u5149\u63a2\u6d4b\u7b49\u4e00\u7cfb\u5217\u7814\u7a76\u624b\u6bb5\uff0c\u63ed\u793a\u4e86\u9499\u949b\u77ff\u6750\u6599\u4e2d\u81ea\u53d1\u8f90\u5c04\u653e\u5927\u7684\u7269\u7406\u673a\u5236\u3002
\n Bai Yujie, et al. & Bin Hu. Advanced Optical Materials<\/em>, 7, 1900345 (2019<\/strong>).
\n https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/adom.201900345<\/p>\n

6: \u5728\u51c6\u4e8c\u7ef4\u9499\u949b\u77ff\uff08PEA2<\/sub>MAn-1<\/sub>Pbn<\/sub>Br3n+1<\/sub>\uff09\u8584\u819c\u4e2d\uff0c\u56e2\u961f\u901a\u8fc7\u78c1\u5149\u81f4\u53d1\u5149\u548c\u6781\u5316\u76f8\u5173\u7684\u5149\u81f4\u53d1\u5149\u8868\u660e\uff0c\u80fd\u5e26\u95f4\u9699\u6001\u672c\u8d28\u662f\u7a7a\u95f4\u6269\u5c55\u6001\uff0c\u7a7a\u95f4\u6269\u5c55\u6001\u4e2d\u8f68\u9053\u95f4\u7684\u76f8\u4e92\u4f5c\u7528\u4e3a\u591a\u5149\u5b50\u4e0a\u8f6c\u5316\u5149\u81f4\u53d1\u5149\u63d0\u4f9b\u4e86\u5fc5\u8981\u6761\u4ef6\u548c\u65b0\u9014\u5f84\u3002
\n Zhu Xixiang, et al. & Bin Hu. Advanced Materials<\/em>, DOI:10.1002\/adma.201901240 (2019<\/strong>).
\n https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/adma.201901240<\/p>\n

7: \u5728\u51c6\u4e8c\u7ef4\u9499\u949b\u77ff\u8584\u819c\u4e2d\uff0c\u56e2\u961f\u63d0\u51fa\u771f\u7a7a\u6781\u5316\uff08Vacuum poling\uff09\u7684\u65b9\u6cd5\u5b9e\u73b0\u4e86\u6700\u5927n\u503c\u7eb3\u7c73\u7247\u8d2f\u7a7f\u751f\u957f\u3001\u540c\u65f6\u4e0d\u540cn\u503c\u5747\u5300\u6df7\u5408\u7684\u7279\u6b8a\u5206\u5e03\u3002\u8fd9\u4e00\u5206\u5e03\u901a\u8fc7\u80f6\u5e26\u5206\u5c42\u6cd5\u7ed3\u5408\u5143\u7d20\u5206\u6790\u3001\u8367\u5149\u5149\u8c31\u7b49\u4e00\u7cfb\u5217\u624b\u6bb5\u5f97\u5230\u8bc1\u660e\u3002\u540c\u65f6\uff0c\u901a\u8fc7\u77ac\u6001\u5438\u6536\u3001\u77ac\u6001\u8367\u5149\u7b49\u4e00\u7cfb\u5217\u624b\u6bb5\u8868\u660e\u8fd9\u79cd\u5168\u65b0\u7684\u7eb3\u7c73\u7247\u5206\u5e03\u6709\u52a9\u4e8e\u51c6\u4e8c\u7ef4\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u7684\u5404\u5411\u540c\u6027\u7684\u7535\u8377\u8f93\u8fd0\u548c\u62bd\u53d6\uff0c\u6700\u7ec8\u5b9e\u73b0\u4e86\u8d85\u8fc782%\u7684\u586b\u5145\u56e0\u5b50\u548c18.04%\u7684\u5149\u7535\u8f6c\u5316\u6548\u7387\u3002
\n Zhang Jia, et al. & Bin Hu. Joule, https:\/\/doi.org\/10.1016\/j.joule<\/em>.2019.09.020 (2019<\/strong>).
\n https:\/\/www.sciencedirect.com\/science\/article\/abs\/pii\/S2542435119304805<\/p>\n

\u672c\u6587\u7531CQR\u7f16\u8bd1\u3002<\/p>\n

\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1\uff1atougao@cailiaoren.com.<\/p>\n

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