{"id":188631,"date":"2019-10-30T10:02:07","date_gmt":"2019-10-30T02:02:07","guid":{"rendered":"\/\/m.iemloyee.com\/?p=188631"},"modified":"2019-10-30T10:02:07","modified_gmt":"2019-10-30T02:02:07","slug":"adv-mater-%e7%bb%bc%e8%bf%b0-%e7%94%a8%e4%ba%8e%e9%94%8c%e5%9f%ba%e6%b6%b2%e6%b5%81%e7%94%b5%e6%b1%a0%e7%9a%84%e5%85%88%e8%bf%9b%e6%9d%90%e6%96%99%e5%8f%91%e5%b1%95%e4%b8%8e%e6%8c%91%e6%88%98","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=188631","title":{"rendered":"Adv. Mater.\u7efc\u8ff0: \u7528\u4e8e\u950c\u57fa\u6db2\u6d41\u7535\u6c60\u7684\u5148\u8fdb\u6750\u6599:\u53d1\u5c55\u4e0e\u6311\u6218"},"content":{"rendered":"

\u3010\u80cc\u666f\u4ecb\u7ecd\u3011<\/strong><\/p>\n

\u7531\u4e8e\u80fd\u6e90\u77ed\u7f3a\u548c\u73af\u5883\u8d1f\u8377\u52a0\u91cd\u7684\u5371\u673a\uff0c\u592a\u9633\u80fd\u548c\u98ce\u80fd\u7b49\u53ef\u518d\u751f\u80fd\u6e90\u53d8\u5f97\u8d8a\u6765\u8d8a\u91cd\u8981\u3002\u7136\u800c\uff0c\u8fd9\u4e9b\u53ef\u518d\u751f\u80fd\u6e90\u672c\u8d28\u4e0a\u662f\u95f4\u6b47\u6027\u7684\uff0c\u4e25\u91cd\u963b\u788d\u5176\u5e7f\u6cdb\u5e94\u7528\u3002\u80fd\u6e90\u5b58\u50a8\u5668\u4ef6\u7279\u522b\u662f\u5e94\u7528\u6781\u5176\u5e7f\u6cdb\u7684\u7535\u5316\u5b66\u50a8\u80fd\u6280\u672f\uff0c\u9700\u8981\u6709\u6548\u7684\u89e3\u51b3\u8fd9\u4e9b\u95ee\u9898\uff1a\u63d0\u9ad8\u4fbf\u643a\u7535\u5b50\u8bbe\u5907\u7535\u7f51\u7684\u7a33\u5b9a\u6027\u548c\u6548\u7387\uff0c\u4ee5\u53ca\u5728\u7535\u7f51\u8fde\u63a5\u9650\u5236\u7684\u533a\u57df\u6216\u5728\u8fdb\u884c\u79bb\u7f51\u5e94\u7528\u65f6\u63d0\u4f9b\u5907\u7528\u7535\u6e90\u7b49\u7b49\u3002\u800c\u5728\u4f17\u591a\u7684\u7535\u5316\u5b66\u50a8\u80fd\u6280\u672f\u4e2d\uff0c\u6db2\u6d41\u7535\u6c60\uff08FBS\uff09\u4ee5\u5176\u9ad8\u5b89\u5168\u6027\u3001\u9ad8\u6548\u7387\u548c\u9ad8\u7075\u6d3b\u6027\u7b49\u5b8c\u7f8e\u7ed3\u5408\u7684\u4f18\u52bf\uff0c\u5728\u50a8\u80fd\u65b9\u9762\u5177\u6709\u7684\u5de8\u5927\u7684\u5e94\u7528\u524d\u666f\u3002\u6db2\u6d41\u7535\u6c60\u901a\u8fc7\u901a\u5e38\u901a\u8fc7\u50a8\u5b58\u5728\u7535\u89e3\u8d28\u4e2d\u7684\u79bb\u5b50\u5bfc\u7535\u819c\u5206\u79bb\u7684\u9633\u6781\u6c27\u5316\u548c\u9634\u6781\u5faa\u73af\u7684\u8fd8\u539f\u53cd\u5e94\uff0c\u4ee5\u5b9e\u73b0\u5316\u5b66\u80fd\u8f6c\u5316\u4e3a\u7535\u80fd\u3002\u6839\u636e\u9633\u6781\u6db2\u548c\u9634\u6781\u6db2\u4e2d\u6c27\u5316\u8fd8\u539f\u70b9\u5bf9\u8fde\u63a5\u7684\u5f62\u5f0f\uff0c\u6db2\u6d41\u7535\u6c60\u53ef\u5206\u4e3a\u6db2-\u6db2\u6d41\u7535\u6c60\u548c\u6df7\u5408\u6db2\u6d41\u7535\u6c60\u3002\u950c\u57fa\u6db2\u6d41\u7535\u6c60\uff08ZFBS\uff09\u4f5c\u4e3a\u6df7\u5408\u6db2\u6d41\u7535\u6c60\u4e2d\u7684\u5178\u578b\u4ee3\u8868\uff0c\u5177\u6709\u80fd\u91cf\u5bc6\u5ea6\u9ad8\u3001\u6210\u672c\u4f4e\u7b49\u4f18\u70b9\uff0c\u975e\u5e38\u9002\u5408\u4e8e\u56fa\u5b9a\u578b\u50a8\u80fd\u7cfb\u7edf\u7684\u5e94\u7528\u3002\u7136\u800c\uff0c\u5b83\u4eec\u7684\u5e7f\u6cdb\u5e94\u7528\u4ecd\u7136\u9762\u4e34\u7740\u6311\u6218\uff0c\u8fd9\u4e9b\u6311\u6218\u4e3b\u8981\u6765\u81ea\u4e8e\u5148\u8fdb\u6750\u6599\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u6700\u8fd1\uff0cAdv. Mater.<\/strong>\u5728\u7ebf\u520a\u767b\u4e86\u4e2d\u56fd\u79d1\u5b66\u9662\u5927\u8fde\u5316\u5b66\u7269\u7406\u7814\u7a76\u6240\u674e\u5148\u950b\u7814\u7a76\u5458\u7b49<\/strong>\u603b\u7ed3\u7684\u7528\u4e8e\u950c\u57fa\u6db2\u6d41\u7535\u6c60\u7684\u5148\u8fdb\u6750\u6599\u6240\u9762\u4e34\u53d1\u5c55\u4e0e\u6311\u6218\u7684\u7efc\u8ff0\u3002\u9898\u76ee\u662f\u201cAdvanced Materials for Zinc-Based Flow Battery: Development and Challenge\u201d<\/strong>\u3002\u5728\u8fd9\u7bc7\u7efc\u8ff0\u4e2d\uff0c\u4f5c\u8005\u9996\u5148\u91cd\u70b9\u7efc\u8ff0\u4e86\u8fd9\u4e9b\u5148\u8fdb\u6750\u6599\u7684\u57fa\u672c\u8bbe\u8ba1\u53ca\u5176\u5316\u5b66\u6027\u8d28\u4e0e\u7535\u6c60\u6027\u80fd\u7684\u5173\u7cfb\u3002\u5176\u6b21\uff0c\u4f5c\u8005\u53c8\u8be6\u7ec6\u8ba8\u8bba\u4e86\u4e0d\u540cZFB\u6280\u672f\u4e2d\u4f7f\u7528\u4e0d\u540c\u6750\u6599\u7684\u539f\u7406\u3001\u6750\u6599\u7684\u529f\u80fd\u548c\u7ed3\u6784\uff0c\u4ee5\u53ca\u8fdb\u4e00\u6b65\u7684\u6750\u6599\u6539\u8fdb\u3002\u6700\u540e\uff0c\u4f5c\u8005\u8fd8\u603b\u7ed3\u4e86ZFBs\u7684\u524d\u666f\u53ca\u6240\u9762\u4e34\u5f97\u6311\u6218\u3002\u4f5c\u8005\u8ba4\u4e3a\uff0c\u8be5\u7efc\u8ff0\u5bf9ZFBs\u65b0\u6750\u6599\u548c\u65b0\u5316\u5b66\u8bd5\u5242\u7684\u8bbe\u8ba1\u548c\u5f00\u53d1\u63d0\u4f9b\u4e86\u6709\u4ef7\u503c\u7684\u6307\u5bfc\u3002<\/p>\n

\u3010\u56fe\u6587\u89e3\u8bfb\u3011<\/strong><\/p>\n

1<\/strong>\u3001\u5f15\u8a00<\/strong><\/p>\n

\u56fe\u4e00\u3001<\/strong>ZFB<\/strong>\u6280\u672f\u7684\u53d1\u5c55\u5386\u53f2<\/strong><\/p>\n

\"\"<\/p>\n

\u56fe\u4e8c\u3001\u5355\u4e00\u950c\u6eb4\u6db2\u6d41\u7535\u6c60\u7684\u6f14\u793a<\/strong><\/p>\n

\"\"<\/p>\n

\uff08a\uff09\u7b2c\u4e00\u4ee35 kW\/5 kWh\u5355\u4f53\u950c\u6eb4\u6db2\u6d41\u7535\u6c60\uff1b<\/p>\n

\uff08b\uff09\u7b2c\u4e8c\u4ee35 kW\/5 kWh\u5355\u4f53\u950c\u6eb4\u6db2\u6d41\u7535\u6c60\u3002<\/p>\n

2<\/strong>\u3001\u950c\u57fa\u6d41\u52a8\u7535\u6c60\u7684\u79cd\u7c7b<\/strong><\/p>\n

\u56fe\u4e09\u3001\u4e0d\u540c<\/strong>pH<\/strong>\u503c\u7684<\/strong>ZFBs<\/strong><\/p>\n

\"\"<\/p>\n

3<\/strong>\u3001<\/strong>ZFBs<\/strong>\u7684\u5171\u540c\u6311\u6218<\/strong><\/p>\n

3.1<\/strong>\u3001<\/strong>\u950c\u679d\u6676\u4e0e\u84c4\u79ef<\/strong><\/p>\n

3.2<\/strong>\u3001<\/strong>\u6709\u9650\u9762\u79ef\u5bb9\u91cf<\/strong><\/p>\n

\u56fe\u56db\u3001<\/strong>\u6e29\u5ea6\u5bf9<\/strong>FF<\/strong>\u7eb3\u7c73\u7ba1\u5149\u5b66\u6027\u80fd\u7684\u5f71\u54cd<\/strong><\/p>\n

\"\"<\/p>\n

\uff08a\uff09\u591a\u5b54\u819c\uff1b<\/p>\n

\uff08b\uff09\u81f4\u5bc6\u819c\uff1b<\/p>\n

\uff08c\uff09ZFB\u8d1f\u534a\u7535\u6c60\u6709\u9650\u9762\u79ef\u5bb9\u91cf\u793a\u610f\u56fe\u3002<\/p>\n

3.3<\/strong>\u3001<\/strong>\u64cd\u4f5c\u7535\u6d41\u5bc6\u5ea6<\/strong><\/p>\n

4<\/strong>\u3001\u7528\u4e8e\u950c\u57fa\u6db2\u6d41\u7535\u6c60\u7684\u5148\u8fdb\u6750\u6599<\/strong><\/p>\n

\u56fe\u4e94\u3001\u7528\u4e8e<\/strong>ZFBs<\/strong>\u7684\u5148\u8fdb\u819c\u3001\u7535\u6781\u548c\u7535\u89e3\u8d28\u6750\u6599<\/strong><\/p>\n

\"\"<\/p>\n

4.1<\/strong>\u3001<\/strong>\u819c<\/strong><\/p>\n

4.1.1<\/strong>\u3001\u7528\u4e8e<\/strong>\u4e2d\u6027\u6216\u9178\u6027<\/strong>ZFBs<\/strong>\u7684\u819c<\/strong><\/p>\n

\u56fe\u516d\u3001\u9002\u7528\u4e8e\u4e2d\u6027\u548c\u9178\u6027<\/strong>ZFB<\/strong>\u4f53\u7cfb\u7684\u819c<\/strong><\/p>\n

\"\"<\/p>\n

\u56fe\u4e03\u3001\u950c<\/strong>–<\/strong>\u6eb4\u548c\uff08\u5355\uff09\u950c<\/strong>–<\/strong>\u7898\u6db2\u6d41\u7535\u6c60\u7684\u819c<\/strong><\/p>\n

\"\"<\/p>\n

\uff08a\uff09\u7528Nafion\u586b\u5145\u591a\u5b54\u819c\uff08Nafion\/PP\uff09\u7684\u950c-\u6eb4\u6db2\u6d41\u7535\u6c60\u793a\u610f\u56fe\uff1b<\/p>\n

\uff08b\u3001d\uff09\u591a\u5b54\u805a\u4e19\u70ef\u819c\u7684\u8868\u9762\u548c\u6a2a\u622a\u9762\u56fe\uff1b<\/p>\n

\uff08c\u3001e\uff09Nafion\/PP\u819c\u7684\u8868\u9762\u548c\u6a2a\u622a\u9762\u56fe\uff1b<\/p>\n

\uff08f\uff09\u88c5\u6709SF600\u548cNFion\/PP\u819c\u7684\u950c-\u6eb4\u6db2\u6d41\u7535\u6c60\u7684\u5145\u653e\u7535\u66f2\u7ebf\uff1b<\/p>\n

\uff08g\uff09\u4f7f\u7528\u591a\u5b54\u805a\u70ef\u70c3\u819c\u7684\u950c-\u7898\u6db2\u6d41\u7535\u6c60\u8fc7\u5145\u548c\u81ea\u6108\u8fc7\u7a0b\u793a\u610f\u56fe\uff1b<\/p>\n

\uff08h\uff09\u7535\u6d41\u5bc6\u5ea6\u4e3a80 mA cm-2<\/sup>\u65f6\uff0c\u4e0d\u540c\u653e\u5927\u500d\u6570\u7684\u950c\u6c89\u79ef\u5f62\u6001\uff1b<\/p>\n

\uff08i\uff09\u4f7f\u75286 M\u7535\u89e3\u6db2\u7684\u950c-\u7898\u6db2\u6d41\u7535\u6c60\u7684\u5faa\u73af\u6027\u80fd\uff1b<\/p>\n

\uff08j\uff09\u5355\u950c-\u7898\u6db2\u6d41\u7535\u6c60\u7684\u539f\u7406\u56fe\uff1b<\/p>\n

\uff08k\u3001l\uff09\u6c1f\u5316\u94a0\u6d82\u5c42\u591a\u5b54\u805a\u70ef\u70c3\u819c\u7684\u8868\u9762\u548c\u6a2a\u622a\u9762\u5f62\u8c8c\u56fe\uff1b<\/p>\n

\uff08m\uff09\u572840 mA cm-2<\/sup>\u548c6 M\u7535\u89e3\u8d28\u4e0b\u8fd0\u884c\u7684\u5355\u4e2a\u950c-\u7898\u6db2\u6d41\u7535\u6c60\u7684\u5145\u7535-\u653e\u7535\u66f2\u7ebf\uff1b<\/p>\n

\uff08n\uff09\u572880 mA cm-2<\/sup>\u4e0b\u4f7f\u75286 M\u7535\u89e3\u6db2\u7684\u5355\u4e2a\u950c-\u7898\u6db2\u6d41\u7535\u6c60\u7684\u5faa\u73af\u6027\u80fd\u3002<\/p>\n

\u56fe\u516b\u3001\u7528\u4e8e\u950c<\/strong>–<\/strong>\u94c1\u6db2\u6d41\u7535\u6c60\u7684\u819c<\/strong><\/p>\n

\"\"<\/p>\n

\uff08a\uff09\u591a\u5b54\u805a\u82ef\u5e76\u54aa\u5511\uff08PBI\uff09\u819c\u793a\u610f\u56fe\uff1b<\/p>\n

\uff08b\u3001d\uff09PBI\u591a\u5b54\u819c\u7684\u622a\u9762\u5f62\u6001\u548c\u653e\u5927\u622a\u9762\u5f62\u6001\uff1b<\/p>\n

\uff08c\u3001e\uff09PBI\u591a\u5b54\u819c\u7684\u8868\u9762\u5f62\u6001\u548c\u653e\u5927\u8868\u9762\u5f62\u6001\uff1b<\/p>\n

\uff08f\uff09\u5177\u6709\u591a\u5b54PBI\u819c\u7684\u950c-\u94c1\u6db2\u6d41\u7535\u6c60\u572840 mA cm\u22122<\/sup>\u4e0b\u7684\u5faa\u73af\u6027\u80fd\uff1b<\/p>\n

\uff08g\uff09Nafion 115\u819c\u7684\u6837\u54c1\u6a21\u578b\uff1b<\/p>\n

\uff08h\uff09\u5faa\u73af\u8bd5\u9a8c\u540eNafion 115\u819c\u7684\u6837\u54c1\u6a21\u578b\uff1b<\/p>\n

\uff08i\uff09\u4f7f\u7528Nafion 115\u819c\u7684\u950c-\u94c1\u6d41\u7535\u6c60\u572840 mA cm\u22122<\/sup>\u4e0b\u7684\u5faa\u73af\u6027\u80fd\uff1b<\/p>\n

\uff08j\uff09\u950c-\u94c1\u6d41\u7535\u6c60\u4e2dSPEEK-K\u819c\u7684\u793a\u610f\u56fe\uff1b<\/p>\n

\uff08k\uff09\u572840 mA cm\u22122<\/sup>\u4e0b\uff0c\u4f7f\u7528SPEEK-K\u819c\u7684\u950c-\u94c1\u6db2\u6d41\u7535\u6c60\u7684\u5faa\u73af\u6027\u80fd\u3002<\/p>\n

4.1.2<\/strong>\u3001<\/strong>\u78b1\u6027\u950c\u57fa\u6db2\u6d41\u7535\u6c60\u8584\u819c<\/strong><\/p>\n

\u56fe\u4e5d\u3001\u78b1\u6027\u950c<\/strong>–<\/strong>\u94c1\u6db2\u6d41\u7535\u6c60\u7528\u819c<\/strong><\/p>\n

\"\"<\/p>\n

\uff08a\uff09\u5728\u7535\u6d41\u5bc6\u5ea6\u4e3a80 mA cm\u22122<\/sup>\u65f6\uff0c\u4f7f\u7528\u4e0d\u540c\u7535\u89e3\u6db2\u7684Nafion 212\u819c\u78b1\u6027\u950c-\u94c1\u6db2\u6d41\u7535\u6c60\u7684\u7535\u6c60\u6027\u80fd\uff1b<\/p>\n

\uff08b\uff09NaOH\u548cKOH\u6eb6\u6db2\u4e2dNafion 212\u7684\u79bb\u5b50\u56e2\u7c07\u5927\u5c0f\u6a21\u578b\uff1b<\/p>\n

\uff08c\uff09Nafion 212\u4e2dSO3\u2212<\/sup>\u4e0e\u7535\u89e3\u6db2\u4e2d\u9633\u79bb\u5b50\uff08K+<\/sup>\u6216Na+<\/sup>\uff09\u76f8\u4e92\u4f5c\u7528\u7684DFT\u8ba1\u7b97\uff1b<\/p>\n

\uff08d\uff09\u81ea\u5236\u7684\u4e3a\u5177\u6709\u8d85\u9ad8\u673a\u68b0\u7a33\u5b9a\u6027\u7684\u78b1\u6027\u950c-\u94c1\u6d41\u7535\u6c60PBI\u819c\u7684\u793a\u610f\u56fe\uff1b<\/p>\n

\uff08e\uff09OH\u2212<\/sup>\u901a\u8fc7PBI\u819c\u7684\u4f20\u8f93\u673a\u5236\uff1b<\/p>\n

\uff08f\uff09\u4f7f\u7528PBI\u819c\u7684\u78b1\u6027\u950c-\u94c1\u6d41\u7535\u6c60\u7684\u5faa\u73af\u6027\u80fd\uff1b<\/p>\n

\uff08g\u3001h\uff09\u5e26\u8d1f\u7535\u8377\u7eb3\u7c73\u591a\u5b54\u819c\uff08P20\uff09\u7684\u6a2a\u622a\u9762\u548c\u6a2a\u622a\u9762\u653e\u5927\u5f62\u8c8c\u56fe\uff1b<\/p>\n

\uff08i\uff09\u7535\u6c60\u7b2c53\u6b21\u5145\u7535\u7ed3\u675f\u65f6\uff0c\u950c\u91d1\u5c5e\uff08\u6811\u679d\u72b6\u6676\uff09\u7684\u626b\u63cf\u7535\u955c\u56fe\uff1b<\/p>\n

\uff08j\uff09\u7535\u6c60\u7b2c183\u6b21\u5145\u7535\u7ed3\u675f\u65f6\u5e26\u6709P20\u819c\u7684\u950c\u91d1\u5c5e\u7684\u626b\u63cf\u7535\u955c\u56fe\uff1b<\/p>\n

\uff08k\uff09\u5e26\u8d1f\u7535\u8377\uff08P20\uff09\u548c\u4e0d\u5e26\u7535\u8377\uff08P0\uff09\u7eb3\u7c73\u591a\u5b54\u819c\u7684\u78b1\u6027\u950c-\u94c1\u6db2\u6d41\u7535\u6c60\u7684\u653e\u7535\u5bb9\u91cf\u3002<\/p>\n

4.2<\/strong>\u3001<\/strong>\u7535\u6781<\/strong><\/p>\n

4.2.1<\/strong>\u3001<\/strong>\u4e2d\u6027\u6216\u9178\u6027<\/strong>ZFBs<\/strong>\u7535\u6781<\/strong><\/p>\n

\u56fe\u5341\u3001\u950c<\/strong>–<\/strong>\u6eb4\u6db2\u6d41\u7535\u6c60\u7535\u6781<\/strong><\/p>\n

\"\"<\/p>\n

\uff08a\uff09\u4f7f\u7528\u78b3\u819c\uff08CCM\uff09\u7684\u950c-\u6eb4\u6db2\u6d41\u7535\u6c60\u793a\u610f\u56fe\uff1b<\/p>\n

\uff08b\uff09\u78b3\u819c\u7684\u6a2a\u622a\u9762\u5f62\u8c8c\u56fe\uff1b<\/p>\n

\uff08c\uff0925 \u2103\u4e0b\u626b\u63cf\u901f\u5ea6\u4e3a20 mV s-1<\/sup>\u7684\u6d3b\u6027\u70ad\u548c\u78b3\u6be1\u7684\u5faa\u73af\u4f0f\u5b89\u6cd5\uff1b<\/p>\n

\uff08d\uff09\u5728\u5f00\u8def\u7535\u538b\u4e0b\u4f7f\u7528CCM\u548c\u78b3\u6be1\u7684\u950c-\u6eb4\u6db2\u6d41\u7535\u6c60\u7684\u963b\u6297\u8c31\uff1b<\/p>\n

\uff08e\uff09\u4f7f\u7528\u78b3\u7eb3\u7c73\u7ba1\u56fa\u5b9a\u78b3\u6be1\uff08CF\uff09\u4f5c\u4e3a\u6eb4\u7535\u6781\u7684\u950c-\u6eb4\u6db2\u6d41\u7535\u6c60\uff1b<\/p>\n

\uff08f\uff09\u5355\u58c1\u78b3\u7eb3\u7c73\u7ba1\uff08SWCNT\uff09\u548c\u591a\u58c1\u78b3\u7eb3\u7c73\u7ba1\uff08MWCNT\uff09\u4fee\u9970\u7535\u6781\u548c\u73bb\u78b3\u7535\u6781\uff08GCE\uff09\u572820 mV s\u22121<\/sup>\u5728\u542b1 M HClO4<\/sub>\u76840.05 M ZnBr2<\/sub>\u4e2d\u7684\u5faa\u73af\u4f0f\u5b89\u56fe\uff1b<\/p>\n

\uff08g\uff09\u4e0d\u540c\u7535\u6781\u7684\u950c-\u6eb4\u6db2\u6d41\u7535\u6c60\u7684\u6548\u7387\uff1b<\/p>\n

\uff08h~j\uff09\u78b3\u6be1\u3001SWCNT\u6539\u6027CF\u548cMWCNT\u6539\u6027CF\u7684SEM\u56fe\u50cf\u3002<\/p>\n

\u56fe\u5341\u4e00\u3001<\/strong>\u950c<\/strong>–<\/strong>\u6eb4\u6db2\u6d41\u7535\u6c60\u7528\u78b3\u57fa\u7535\u50ac\u5316\u5242<\/strong><\/p>\n

\"\"<\/p>\n

\uff08a\uff09\u53cc\u5cf0\u6709\u5e8f\u4e2d\u7ed3\u6784\u78b3\uff08BOMCs\uff09\u7684\u5408\u6210\u65b9\u6cd5\uff1b<\/p>\n

\uff08b\u3001c\uff09BOMC-2\u7684SEM\u3001TEM\u56fe\uff1b<\/p>\n

\uff08d\uff09\u950c-\u6eb4\u6db2\u6d41\u7535\u6c60\u7b3c\u72b6\u591a\u5b54\u70ad\u7684\u5236\u5907\u53ca\u539f\u7406\u793a\u610f\u56fe\uff1b<\/p>\n

\uff08e\u3001f\uff09CPC\u7684\u626b\u63cf\u7535\u955c\u548c\u900f\u5c04\u7535\u955c\u56fe\uff1b<\/p>\n

\uff08g\uff09\u7535\u6d41\u5bc6\u5ea6\u4e3a80 mA cm\u22122<\/sup>\u65f6\uff0cCPC\u4f5c\u4e3a\u6eb4\u5076\u7535\u50ac\u5316\u5242\u7684\u950c-\u6eb4\u6db2\u6d41\u7535\u6c60\u7684\u6027\u80fd\uff1b<\/p>\n

\uff08h\uff09\u591a\u5b54\u7eb3\u7c73\u7247\u78b3\u5236\u5907\u793a\u610f\u56fe\uff1b<\/p>\n

\uff08i\u3001j\uff09\u7eb3\u7c73\u6cb8\u77f3\u578b\u91d1\u5c5e\u6709\u673a\u9aa8\u67b6\uff08NSZIF\uff09\u7684TEM\u548cHRTEM\uff1b<\/p>\n

\uff08k\uff09\u591a\u5b54\u7eb3\u7c73\u78b3\uff08PNSC\uff09\u5bf9\u6eb4\u6c27\u5316\u8fd8\u539f\u53cd\u5e94\u7684\u50ac\u5316\u673a\u7406\u3002<\/p>\n

\u56fe\u5341\u4e8c\u3001\u9178\u6027\u950c<\/strong>–<\/strong>\u94c8\u6db2\u6d41\u7535\u6c60\u7535\u6781<\/strong><\/p>\n

\"\"<\/p>\n

\uff08a\u3001b\uff09\u5c42\u72b6\u591a\u5b54\u70ad\uff08HPC\uff09\u7684SEM\u56fe\u548cTEM\u56fe\uff1b<\/p>\n

\uff08c\uff09\u9ad8\u6027\u80fd\u70ad\u548c\u78b3\u6be1\u7535\u6781\u4e0aCe3+<\/sup>\/Ce4+<\/sup>\u5076\u7684\u5faa\u73af\u4f0f\u5b89\u56fe\uff1b<\/p>\n

\uff08d\uff09\u4e0d\u540c\u6b63\u6781\u950c-\u94c8\u6db2\u6d41\u7535\u6c60\u7684\u5145\u653e\u7535\u66f2\u7ebf\uff1b<\/p>\n

\uff08e\u3001f\uff09\u572850 mA cm\u22122<\/sup>\u4e0b\uff0c\u5728e\uff09HDPE-1\uff08\u9ad8\u5bc6\u5ea6\u805a\u4e59\u70ef\uff09\u548cPVE\uff08\u73af\u6c27\u6811\u8102\u548c\u4e59\u70ef\u57fa\u916f\uff09\u590d\u5408\u7535\u6781\u4e0a\u6c89\u79ef2\u5206\u949f\u7684\u950c\u5f62\u6001\uff1b<\/p>\n

\uff08g\u3001h\uff09\u572850 mA cm\u22122<\/sup>\u4e0b\uff0c\u5728HDPE-1\u548cPVE\u590d\u5408\u7535\u6781\u4e0a\u6c89\u79ef5\u5206\u949f\u7684\u950c\u5f62\u6001\uff1b<\/p>\n

\uff08i~l\uff09BMM3\uff08Pt\/Ir50\/50\uff09\u7535\u6781\uff0c SL2\uff083 g Pt m-2<\/sup>\uff09\u7535\u6781\u8868\u9762\u7684\u9876\u89c6SEM\u56fe\u3002<\/p>\n

4.2.2<\/strong>\u3001\u78b1\u6027\u950c\u57fa\u6db2\u6d41\u7535\u6c60\u7535\u6781<\/strong><\/p>\n

\u56fe\u5341\u4e09\u3001<\/strong>\u78b1\u6027\u950c<\/strong>–<\/strong>\u954d\u6216\u6c14\u6d41\u7535\u6c60\u7684\u7535\u6781<\/strong><\/p>\n

\"\"<\/p>\n

\uff08a\uff09\u572820 mA cm\u22122<\/sup>\u4e0b\uff0c\u5728\u6b63\u6781\u9644\u8fd1\u76843D\u591a\u5b54\u954d\u6ce1\u6cab\uff08NFs\uff09\u4e0a\u6c89\u79ef40\u5206\u949f\u7684\u950c\u7684\u5f62\u6001\uff1b<\/p>\n

\uff08b\uff09\u572820 mA cm\u22122<\/sup>\u4e0b\uff0c\u5728NF\u7684\u5bf9\u9762\u76843D\u591a\u5b54\u954d\u6ce1\u6cab\uff08NFs\uff09\u4e0a\u6c89\u79ef40\u5206\u949f\u7684\u950c\u7684\u5f62\u6001\uff1b<\/p>\n

\uff08c\uff09\u7528\u4e8e\u78b1\u6027\u950c\u6c14\u6d41\u7535\u6c60\u7684NiSx-FeOy\/SCFP\u7535\u6781\u7684\u5236\u9020\u6d41\u7a0b\uff1b<\/p>\n

\uff08d\uff09\u76f8\u5e94\u6750\u6599\u7684\u5f62\u8c8c\u56fe\uff1b<\/p>\n

\uff08e\uff09\u5355\u6d41\u5f0fZn\u2013Ni(OH)2<\/sub>\/O2<\/sub>\u6df7\u5408\u7535\u6c60\u7684\u793a\u610f\u56fe\uff1b<\/p>\n

\uff08f\u3001g\uff09\u5355Zn\u2013Ni(OH)2<\/sub>\/O2<\/sub>\u6df7\u5408\u6db2\u6d41\u7535\u6c60\u4e2dNi(OH)2<\/sub>\u548cAg4<\/sub>Bi2<\/sub>O5<\/sub>\u7684\u5f62\u8c8c\u3002<\/p>\n

4.3<\/strong>\u3001\u7535\u89e3\u6db2<\/strong><\/p>\n

4.3.1<\/strong>\u3001\u7528\u4e8e\u4e2d\u6027\u6216\u9178\u6027\u950c\u57fa\u6db2\u6d41\u7535\u6c60\u7684\u7535\u89e3\u8d28<\/strong><\/p>\n

\u56fe\u5341\u56db\u3001\u7528\u4e8e\u4e2d\u6027\u6216\u9178\u6027\u950c\u57fa\u6db2\u6d41\u7535\u6c60\u7684\u7535\u89e3\u8d28<\/strong><\/p>\n

\"\"<\/p>\n

\uff08a\uff09\u6eb4\u5076\u7edc\u5408\u5242\uff1b<\/p>\n

\uff08b\uff09\u6eb4\u4f5c\u4e3a\u7a33\u5b9a\u7898\u7684\u590d\u5408\u5242\u7684\u6982\u5ff5\u8bf4\u660e\uff1b<\/p>\n

\uff08c\uff09\u4e2d\u6027\u950c\u94c1\u6d41\u7535\u6c60\u9633\u6781\u6db2\u7684DFT\u4f18\u5316\u5206\u5b50\u7ed3\u6784\uff1b<\/p>\n

\uff08d\uff09\u4e09\u7898\u7edc\u5408\u950c\u79bb\u5b50\u7684DFT\u4f18\u5316\u5206\u5b50\u7ed3\u6784\uff1b<\/p>\n

\uff08e\uff09\u5145\u7535\u8fc7\u7a0b\u4e2d\u5f62\u6210\u7684EtOH\u7edc\u5408\u950c\u79bb\u5b50\u7684DFT\u4f18\u5316\u5206\u5b50\u7ed3\u6784\uff1b<\/p>\n

\uff08f\uff09TEMPO\u884d\u751f\u7269\u7684\u5408\u6210\u3002<\/p>\n

4.3.2<\/strong>\u3001\u78b1\u6027\u950c\u57fa\u6db2\u6d41\u7535\u6c60\u7684\u7535\u89e3\u6db2<\/strong><\/p>\n

\u56fe\u5341\u4e94\u3001\u6dfb\u52a0\u5242\u5bf9\u78b1\u6027\u950c\u57fa\u6d41\u52a8\u7535\u6c60\u950c\u5f62\u6001\u7684\u5f71\u54cd<\/strong><\/p>\n

\"\"<\/p>\n

\uff08a~c\uff090 M\u30015\u00d710-5<\/sup> M\u548c10-3<\/sup> M\u6d53\u5ea6\u94c5\u79bb\u5b50\u5b58\u5728\u4e0b\u9540\u950c\u5c42\u7684\u5f62\u8c8c\u56fe\uff1b<\/p>\n

\uff08d~f\uff090.4 M\u30010.6 M\u548c1.0 M\u6d53\u5ea6\u94a8\u9178\u76d0\u79bb\u5b50\u5b58\u5728\u4e0b\u9540\u950c\u5c42\u7684\u5f62\u8c8c\u56fe\uff1b<\/p>\n

\uff08g~i\uff09\u78b1\u6027\u7a7a\u767d\u6eb6\u6db2\u300110-4<\/sup> M Pb2+<\/sup>\u548c10-4 <\/sup>M Pb2+<\/sup>+5\u00d710-5<\/sup> M\u56db\u4e01\u57fa\u6eb4\u5316\u94f5\uff08TBAB\uff09\u6761\u4ef6\u4e0b\u9540\u950c\u5c42\u7684\u5f62\u8c8c\u56fe\u3002<\/p>\n

5<\/strong>\u3001\u7ed3\u8bba\u548c\u5c55\u671b<\/strong><\/p>\n

5.1<\/strong>\u3001\u8bbe\u8ba1\u548c\u5236\u9020\u9ad8\u6027\u80fd\u819c\u6750\u6599<\/strong><\/p>\n

5.2<\/strong>\u3001\u9ad8\u6027\u80fd\u7535\u6781\u6750\u6599\u4e0e\u589e\u5f3a\u533a\u57df\u80fd\u529b<\/strong><\/p>\n

5.3<\/strong>\u3001\u9ad8\u7a33\u5b9a\u6027\u7684\u9ad8\u6d53\u5ea6\u7535\u89e3\u8d28<\/strong><\/p>\n

\u5728\u8fd9\u7bc7\u7efc\u8ff0\u4e2d\uff0c\u4f5c\u8005\u4e3b\u8981\u4ece\u7535\u6781\u6750\u6599\u3001\u819c\u6750\u6599\u548c\u7535\u89e3\u8d28\u7b49\u5148\u8fdb\u6750\u6599\u65b9\u9762\u7efc\u8ff0\u4e86ZFB\u7684\u6700\u65b0\u8fdb\u5c55\u548c\u9762\u4e34\u7684\u6311\u6218\u3002\u6b64\u5916\uff0c\u8fd8\u5c06\u5bf9\u5404\u79cdZFBs\u7684\u5148\u8fdb\u6750\u6599\u8fdb\u884c\u7efc\u8ff0\u3002\u540c\u65f6\uff0c\u4f5c\u8005\u8fd8\u7279\u522b\u8be6\u7ec6\u8ba8\u8bba\u8fd9\u4e9b\u6750\u6599\u5bf9\u7535\u6c60\u6027\u80fd\u7684\u5f71\u54cd\u3002\u4f5c\u8005\u8ba4\u4e3a\uff0c\u5c3d\u7ba1\u76ee\u524d\u4eba\u4eec\u901a\u8fc7\u5bf9\u5148\u8fdb\u6750\u6599\u7684\u5e7f\u6cdb\u7814\u7a76\uff0cZFB\u5df2\u7ecf\u53d6\u5f97\u4e86\u663e\u8457\u7684\u6027\u80fd\uff0c\u4f46\u8981\u5b9e\u73b0\u8fd9\u4e9b\u5668\u4ef6\u7684\u5546\u4e1a\u5316\u548c\u4ea7\u4e1a\u5316\uff0c\u5176\u529f\u7387\u5bc6\u5ea6\u3001\u5faa\u73af\u5bff\u547d\u751a\u81f3\u80fd\u91cf\u5bc6\u5ea6\u90fd\u9700\u8981\u8fdb\u4e00\u6b65\u63d0\u9ad8\u3002\u540c\u65f6\u8981\u5b9e\u73b0ZFB\u7684\u4ea7\u4e1a\u5316\uff0c\u4ecd\u7136\u8feb\u5207\u9700\u8981\u4f4e\u6210\u672c\u7684\u5148\u8fdb\u6750\u6599\u3002\u56e0\u6b64\uff0c\u4f5c\u8005\u6700\u540e\u53c8\u603b\u7ed3\u4e86\u5173\u4e8e\u6539\u8fdb\u5148\u8fdb\u6750\u6599\u4ee5\u514b\u670dZFB\u6280\u672f\u7684\u5c40\u9650\u6027\u7684\u7b56\u7565\uff0c\u4ee5\u53ca\u65b0\u7684\u7535\u6c60\u5316\u5b66\u7269\u8d28\u7684\u53d1\u73b0\u3002\u4f5c\u8005\u76f8\u4fe1\uff0c\u968f\u7740\u5148\u8fdb\u6750\u6599\u7684\u4e0d\u65ad\u53d1\u5c55\uff0cZFB\u6280\u672f\u5728\u56fa\u5b9a\u578b\u50a8\u80fd\u9886\u57df\u6709\u7740\u5de8\u5927\u7684\u5e94\u7528\u6f5c\u529b\u3002<\/p>\n

 <\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a Advanced Materials for Zinc\u2010Based Flow Battery: Development and Challenge <\/a>\uff08Adv. Mater. 2019, 1902025\uff09<\/p>\n

\u672c\u6587\u7531\u6211\u4ea6\u662f\u884c\u4eba\u7f16\u8bd1\u6574\u7406\u3002<\/p>\n

\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1\uff1atougao@cailiaoren.com.<\/a><\/p>\n

\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1acailiaokefu.<\/p>\n","protected":false},"excerpt":{"rendered":"

\u3010\u80cc\u666f\u4ecb\u7ecd\u3011 \u7531\u4e8e\u80fd\u6e90\u77ed\u7f3a\u548c\u73af\u5883\u8d1f\u8377\u52a0\u91cd\u7684\u5371\u673a\uff0c\u592a\u9633\u80fd\u548c\u98ce\u80fd\u7b49\u53ef\u518d\u751f\u80fd\u6e90\u53d8\u5f97\u8d8a\u6765\u8d8a\u91cd\u8981\u3002\u7136\u800c\uff0c\u8fd9\u4e9b\u53ef\u518d\u751f\u80fd\u6e90\u672c\u8d28\u4e0a\u662f\u95f4\u6b47\u6027\u7684\uff0c\u4e25\u91cd\u963b\u788d\u5176\u5e7f\u6cdb\u5e94\u7528\u3002\u80fd\u6e90\u5b58\u50a8\u5668\u4ef6\u7279…<\/p>\n","protected":false},"author":11455,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[533],"tags":[4226],"class_list":["post-188631","post","type-post","status-publish","format-standard","hentry","category-zongshu","tag-4226"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/188631"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/11455"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=188631"}],"version-history":[{"count":4,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/188631\/revisions"}],"predecessor-version":[{"id":188870,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/188631\/revisions\/188870"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=188631"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=188631"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=188631"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}