{"id":187848,"date":"2019-10-19T06:30:47","date_gmt":"2019-10-18T22:30:47","guid":{"rendered":"\/\/m.iemloyee.com\/?p=187848"},"modified":"2019-10-18T18:02:12","modified_gmt":"2019-10-18T10:02:12","slug":"%e3%80%90%e6%8a%95%e7%a8%bf%e3%80%91angew-chem-int-edit%ef%bc%9a%e7%a2%b3%e5%b1%82%e8%ae%be%e8%ae%a1%e4%b8%8e%e8%a1%a8%e9%9d%a2%e6%b4%bb%e6%80%a7%e7%b3%bb%e5%b8%a6%e5%9f%ba%e5%9b%a2%e5%8a%a9","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=187848","title":{"rendered":"ANGEW CHEM INT EDIT\uff1a\u78b3\u5c42\u8bbe\u8ba1\u4e0e\u8868\u9762\u6d3b\u6027\u7cfb\u5e26\u57fa\u56e2\u52a9\u529bSi\u8d1f\u6781\u5b9e\u73b0\u5168\u7535\u6c60\u7a33\u5b9a\u5faa\u73af"},"content":{"rendered":"<h3><span style=\"color: #000000;\"><strong><b>\u7814\u7a76\u80cc\u666f<\/b><\/strong><\/span><\/h3>\n<p><span style=\"color: #000000;\">\u9ad8\u50a8\u80fd\u5bc6\u5ea6\u7535\u6c60\u6280\u672f\u662f\u65b0\u80fd\u6e90\u9886\u57df\u7684\u7814\u7a76\u70ed\u70b9\uff0c\u4ece\u78b3\u57fa\u8d1f\u6781\u5230\u7845\u78b3\u590d\u5408\u8d1f\u6781\u662f\u9502\u79bb\u5b50\u7535\u6c60\u9ad8\u6bd4\u80fd\u5316\u53d1\u5c55\u7684\u5fc5\u7531\u4e4b\u8def\u3002\u5e38\u89c4\u7684\u5316\u5b66\u78b3\u5305\u8986\u6216\u8005\u7269\u7406\u6df7\u5408\u65b9\u6cd5\u6784\u5efa\u7684\u7845\u78b3\u590d\u5408\u7ed3\u6784\u96be\u4ee5\u5728\u5faa\u73af\u8fc7\u7a0b\u4e2d\u4fdd\u6301\u7a33\u5b9a\u3002\u4f53\u79ef\u53d8\u5316\u5f15\u8d77\u7684SEI\u819c\u53cd\u590d\u751f\u957f\u7684\u95ee\u9898\u672a\u5f97\u6839\u672c\u89e3\u51b3\uff0c\u5f15\u8d77\u6df1\u5ea6\u5faa\u73af\u8fc7\u7a0b\u4e2d\u7535\u89e3\u6db2\u53ca\u6d3b\u6027\u9502\u7684\u4e0d\u65ad\u6d88\u8017\uff0c\u9020\u6210\u6781\u5316\u4e0a\u5347\u4e0e\u5bb9\u91cf\u8870\u51cf\u3002\u76ee\u524d\u5df2\u77e5\uff0c\u9664\u7845\u9897\u7c92\u672c\u8eab\u4ee5\u5916\uff0c\u4f5c\u4e3a\u7845\u5305\u8986\/\u8d1f\u8f7d\u5c42\u7684\u78b3\u6750\u6599\u7684\u8868\u9762\u7f3a\u9677\uff08\u5982\u542b\u6c27\u57fa\u56e2\u3001\u5f02\u8d28\u539f\u5b50\u3001\u7eb3\u7c73\u5b54\u7b49\uff09\u5c06\u50ac\u5316\u7535\u89e3\u6db2\u5206\u89e3\uff0c\u4fc3\u8fdbSEI\u819c\u8fc7\u5ea6\u5f62\u6210\uff0c\u800c\u5728\u9ad8\u6bd4\u8868\u9762\u7eb3\u7c73\u4f53\u7cfb\u4e2d\uff0c\u8fd9\u4e00\u673a\u5236\u8fd8\u53ef\u80fd\u4f1a\u88ab\u8fdb\u4e00\u6b65\u653e\u5927\uff0c\u5e26\u6765\u66f4\u5927\u7684\u8d1f\u9762\u5f71\u54cd\u3002\u600e\u6837\u5316\u5b66\u7ed3\u6784\u7684\u78b3\u5305\u8986\u5c42\u624d\u662f\u5bf9\u7845\u8d1f\u6781\u6700\u6709\u5229\u7684\uff1f\u5982\u4f55\u6784\u5efa\u5177\u6709\u8f83\u9ad8\u4f53\u79ef\u81a8\u80c0\u8010\u53d7\u529b\u7684<\/span>\u7535\u6781<span style=\"color: #000000;\">\u590d\u5408\u7ed3\u6784\uff0c\u4e14\u5b9e\u73b0\u6750\u6599\u8868\u9762\u949d\u5316\u5c42\u7684\u7a33\u5b9a\uff1f<\/span><\/p>\n<h3><span style=\"color: #000000;\"><strong><b>\u6210\u679c\u7b80\u4ecb<\/b><\/strong><\/span><\/h3>\n<p><span style=\"color: #000000;\">\u56db\u5ddd\u5927\u5b66\u65b0\u80fd\u6e90\u4e0e\u4f4e\u78b3\u6280\u672f\u7814\u7a76\u9662 Wei Liu \u526f\u6559\u6388\u4e0e\u7f8e\u56fd\u5fb7\u5dde\u5927\u5b66 David Mitlin\u6559\u6388\u901a\u8fc7\u539f\u4f4d\u63d2\u5c42-\u81a8\u80c0\u5265\u79bb\u6cd5\u4e00\u6b65\u5236\u5907\u4e86\u7845-\u9ad8\u54c1\u8d28\u77f3\u58a8\u70ef\u590d\u5408\u6750\u6599\uff08Si-pG\uff09\uff0c\u6709\u522b\u4e8e\u5e38\u89c4\u7684\u6c27\u8fd8\u77f3\u58a8\u70efr-GO\u6750\u6599\uff0c\u8be5\u65b9\u6cd5\u5236\u5907\u7684\u77f3\u58a8\u70ef\u7f3a\u9677\u53ca\u542b\u6c27\u91cf\u663e\u8457\u8f83\u4f4e\u3002\u8fdb\u4e00\u6b65\uff0c\u901a\u8fc7\u5728\u6750\u6599\u8868\u9762\u5f15\u5165\u73af\u6c27\u57fa\u56e2\uff0c\u53ef\u4e0eCMC\u7c98\u63a5\u5242\u5f62\u6210\u5316\u5b66\u6865\u8fde\uff0c\u63d0\u9ad8\u6781\u7247\u7684\u5e94\u53d8\u8010\u53d7\u80fd\u529b\u53ca\u7535\u6781\u754c\u9762\u7684\u7a33\u5b9a\u6027\u3002\u5728\u9ad8\u77f3\u58a8\u5316\u3001\u4f4e\u7f3a\u9677\u78b3\u7f13\u51b2\u5c42\u548c\u754c\u9762\u5316\u5b66\u6865\u8fde\u7684\u534f\u6548\u4f5c\u7528\u4e0b\uff0c\u5b9e\u73b0\u4e86\u9ad8\u8d1f\u8f7d\u91cf\u94b4\u9178\u9502\u5168\u7535\u6c60\u73af\u5883\u4e0b\u7684\u7845\u8d1f\u6781\u7a33\u5b9a\u5faa\u73af\u3002\u7814\u7a76\u6210\u679c\u9898\u4e3a\u201cSynergy of Epoxy Chemical Tethers and Defect-Free Graphene in Enabling Stable Lithium Cycling of Silicon Nanoparticles\u201d\u53d1\u8868\u4e8e\u56fd\u9645\u77e5\u540d\u671f\u520a\u300a\u5fb7\u56fd\u5e94\u7528\u5316\u5b66\u300b(Angewandte\u00a0Chemie International Edition)<\/span><\/p>\n<h3><span style=\"color: #000000;\"><strong><b>\u56fe\u6587\u5bfc\u8bfb<\/b><\/strong><\/span><\/h3>\n<p><span style=\"color: #000000;\"><strong><b>\u56fe<\/b><\/strong><strong><b>1.<\/b><\/strong><\/span><\/p>\n<p><span style=\"color: #000000;\"><img loading=\"lazy\" decoding=\"async\" class=\"wp-image-187858 size-full aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2019\/10\/\u56fe\u72476-10.png\" alt=\"\" width=\"680\" height=\"1046\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2019\/10\/\u56fe\u72476-10.png 680w, \/\/m.iemloyee.com\/wp-content\/uploads\/2019\/10\/\u56fe\u72476-10-195x300.png 195w, \/\/m.iemloyee.com\/wp-content\/uploads\/2019\/10\/\u56fe\u72476-10-666x1024.png 666w\" sizes=\"(max-width: 680px) 100vw, 680px\" \/><\/span><\/p>\n<p><span style=\"color: #000000;\">(a)\u00a0\u5728\u77f3\u58a8\u81a8\u80c0\u8fc7\u7a0b\u4e2d\u8bf1\u5bfc\u7845\u7eb3\u7c73\u7c92\u5b50\u539f\u4f4d\u63d2\u5165\u5f62\u6210Si-pG\u590d\u5408\u6750\u6599,\u00a0(b)\u00a0Si-pG\u8868\u9762\u53d1\u751f\u7845\u70f7\u5076\u8054\u53cd\u5e94\u5f62\u6210\u8868\u9762\u5bcc\u542b\u73af\u6c27\u7cfb\u5e26\u57fa\u56e2\uff08epoxy tethers\uff09\u7684 \u201cE-Si-pG\u201d (c)\u00a0E-Si-pG \u4e0e\u7c98\u63a5\u5242CMC\u5728\u7535\u6781\u5e72\u71e5\u8fc7\u7a0b\u4e2d\u952e\u5408\u00a0(\u201cbuckled-up\u201d)\u00a0<\/span><\/p>\n<p><span style=\"color: #000000;\"><strong><b>\u56fe<\/b><\/strong><strong><b>2<\/b><\/strong><strong><b>.<\/b><\/strong><\/span><\/p>\n<p><span style=\"color: #000000;\"><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-187850 aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2019\/10\/2-15.png\" alt=\"\" width=\"680\" height=\"609\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2019\/10\/2-15.png 680w, \/\/m.iemloyee.com\/wp-content\/uploads\/2019\/10\/2-15-300x269.png 300w\" sizes=\"(max-width: 680px) 100vw, 680px\" \/><\/span><\/p>\n<p><span style=\"color: #000000;\">\u00a0(a-b) XRD\u4e0eRaman\u8868\u660e\uff1apG\u8f83\u5e38\u89c4\u6c27\u8fd8\u77f3\u58a8\u70efr-GO\u7f3a\u9677\u542b\u91cf\u663e\u8457\u8f83\u4f4e\u53ca\u78b3\u6709\u5e8f\u5ea6\u660e\u663e\u8f83\u9ad8\uff1b\u00a0(c-f) TEM \u53caEDXS\u8868\u660ep-G\u4e0a\u81f4\u5bc6\u5747\u5300\u7684\u7845\u7eb3\u7c73\u9897\u7c92\u5206\u5e03\uff1b(g-i) HRTEM \u8868\u660e\u7eb3\u7c73\u7845\u8868\u9762\u4e0a\u5f62\u6210\u4e86\u4e00\u5c42~2nm\u539a\u5ea6\u7684\u65e0\u5b9a\u578b\u6c27\u5316\u5c42<\/span><\/p>\n<p><span style=\"color: #000000;\"><strong>\u56fe3.<\/strong><\/span><\/p>\n<p><span style=\"color: #000000;\"><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-187851 aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2019\/10\/3-16.png\" alt=\"\" width=\"680\" height=\"271\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2019\/10\/3-16.png 680w, \/\/m.iemloyee.com\/wp-content\/uploads\/2019\/10\/3-16-300x120.png 300w\" sizes=\"(max-width: 680px) 100vw, 680px\" \/><\/span><\/p>\n<p><span style=\"color: #000000;\">XPS\uff08a-d\uff09\u53caFTIR\uff08e\uff09\u4e2d\u663e\u793a\u73af\u6c27\u57fa\u53ca\u919a\u6865\u7684\u5149\u8c31\u4fe1\u606f\uff0c\u9a8c\u8bc1\u4eceSi-pG\u5230E-Si-pG\u7684\u8868\u9762\u7845\u70f7\u5076\u8054\u53cd\u5e94\u3002<\/span><\/p>\n<p><span style=\"color: #000000;\"><strong><b>\u56fe4<\/b><\/strong><b><\/b><\/span><\/p>\n<p><span style=\"color: #000000;\"><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-187852 aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2019\/10\/4-12.png\" alt=\"\" width=\"680\" height=\"566\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2019\/10\/4-12.png 680w, \/\/m.iemloyee.com\/wp-content\/uploads\/2019\/10\/4-12-300x250.png 300w\" sizes=\"(max-width: 680px) 100vw, 680px\" \/><\/span><\/p>\n<p><span style=\"color: #000000;\">\u00a0(a-c)\u4e09\u79cd\u6750\u6599\u7684\u521d\u59cb\u5145\u653e\u7535\u66f2\u7ebf\uff0c\u00a0(d)\u524d\u671f\u5faa\u73af\u8fc7\u7a0b\u4e2d\u7684\u4e0d\u53ef\u9006\u5bb9\u91cf\u635f\u5931\u884c\u4e3a\uff0c\u00a0(e) \u957f\u5faa\u73af\u5bb9\u91cf\u4fdd\u6301\u884c\u4e3a\u5bf9\u6bd4\uff0c(f) \u5faa\u73af\u540e\u6781\u7247\u963b\u6297\u884c\u4e3a\u5bf9\u6bd4\uff0c\u00a0(g) E-Si-pG\u6750\u6599\u5faa\u73af\u8fc7\u7a0b\u4e2d\u7684\u7ed3\u6784\u4fdd\u6301\u673a\u5236<\/span><\/p>\n<p><span style=\"color: #000000;\"><strong>\u56fe5.<\/strong><\/span><\/p>\n<p><span style=\"color: #000000;\"><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-187853 aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2019\/10\/5-9.png\" alt=\"\" width=\"680\" height=\"718\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2019\/10\/5-9.png 680w, \/\/m.iemloyee.com\/wp-content\/uploads\/2019\/10\/5-9-284x300.png 284w\" sizes=\"(max-width: 680px) 100vw, 680px\" \/><\/span><\/p>\n<p><span style=\"color: #000000;\">(a) \u91c7\u7528\u8fd1\u5546\u4e1a\u52a0\u8f7d\u91cf\u94b4\u9178\u9502\u6b63\u6781\u7684E-Si-pG\u5168\u7535\u6c60\u8bbe\u8ba1, (b)\u5168\u7535\u6c60\u4e2d\u6b63\u8d1f\u6781\u6750\u6599\u7684\u5404\u81ea\u7535\u538b\u66f2\u7ebf\uff0c(c) \u5168\u7535\u6c60\u4e0d\u540c\u5145\u653e\u7535\u500d\u7387\u7684\u7535\u538b\u66f2\u7ebf\uff0c(d) \u5168\u7535\u6c60\u500d\u7387\u884c\u4e3a\uff0c(e) \u5168\u7535\u6c60\u7a33\u5b9a\u5faa\u73af\u8d85\u8fc7150\u5708<\/span><\/p>\n<h3><span style=\"color: #000000;\"><strong><b>\u5c0f\u7ed3<\/b><\/strong><\/span><\/h3>\n<p><span style=\"color: #000000;\">\u5236\u5907\u548c\u8868\u5f81\u4e86\u4e00\u79cd\u65b0\u578b\u7684\u7845\u78b3\u8d1f\u6781\u6750\u6599\uff0c\u5176\u5305\u8986\u7845\u7684\u77f3\u58a8\u70ef\uff08p-G\uff09\u5177\u5907\u8f83\u4f4e\u7684\u7f3a\u9677\u542b\u91cf\u3002\u4e0e\u9ad8\u7f3a\u9677\u7684rGO\u6750\u6599\u76f8\u6bd4\uff0cp-G\u4e0d\u6613\u5f15\u8d77\u7535\u89e3\u6db2\u5206\u89e3\u548cSEI\u819c\u8fc7\u5ea6\u5f62\u6210\u3002\u540c\u65f6\u5728\u590d\u5408\u6750\u6599\u8868\u9762\u5f15\u5165\u7845\u70f7\u5076\u8054\u53cd\u5e94\uff0c\u83b7\u5f97\u7684E-Si-pG\u6750\u6599\u53ef\u901a\u8fc7\u4e0e\u7c98\u63a5\u5242\u5316\u5b66\u6865\u8fde\u800c\u5f3a\u5316\u6750\u6599\u5e94\u53d8\u8010\u53d7\u529b\uff0c\u8868\u9762\u6865\u8fde\u5c42\u540c\u65f6\u53ef\u6291\u5236\u7535\u89e3\u6db2\u7684\u526f\u53cd\u5e94\u3002\u5e94\u7528E-Si-pG\u6750\u6599\u8d1f\u6781\uff0c\u4ee5\u5546\u4e1a\u7ea7\u8d1f\u8f7d\u94b4\u9178\u9502\u6b63\u6781\uff0c\u53ef\u6784\u5efa\u6700\u9ad8\u80fd\u91cf\u5bc6\u5ea6\u8d85\u8fc7500Wh\/kg\u7684\u5168\u7535\u6c60\uff0c\u4e14\u57281C\u6761\u4ef6\u4e0b\u7a33\u5b9a\u5faa\u73af\u3002\u6b64\u7814\u7a76\u63d0\u4f9b\u4e86\u4e00\u79cd\u7845\u78b3\u8d1f\u6781\u6750\u6599\u5236\u5907\u7684\u65b0\u601d\u8def\uff1a\u9ad8\u77f3\u58a8\u5316\u3001\u4f4e\u7f3a\u9677\u7684\u5305\u8986\/\u62c5\u8f7d\u78b3\u5c42\u53caCMC\u7c98\u63a5\u5242\u4e0e\u6750\u6599\u4e4b\u95f4\u7684\u5316\u5b66\u6865\u8fde\u5c42\u53ef\u534f\u540c\u63d0\u9ad8\u7845\u78b3\u8d1f\u6781\u6750\u6599\u7684\u5faa\u73af\u5bff\u547d\u3002\u00a0<\/span><\/p>\n<p><span style=\"color: #000000;\">\u539f\u6587\u94fe\u63a5\uff1a\u00a0https:\/\/onlinelibrary.wiley.com\/doi\/abs\/10.1002\/ange.201906612<\/span><\/p>\n<p><span style=\"color: #000000;\">\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1: tougao@cailiaoren.com.<\/span><\/p>\n<p><span style=\"color: #000000;\">\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1acailiaorenVIP.<\/span><\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u7814\u7a76\u80cc\u666f 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