{"id":187777,"date":"2019-10-20T06:58:36","date_gmt":"2019-10-19T22:58:36","guid":{"rendered":"\/\/m.iemloyee.com\/?p=187777"},"modified":"2019-10-21T15:53:57","modified_gmt":"2019-10-21T07:53:57","slug":"%e8%93%a6%e7%84%b6%e5%9b%9e%e9%a6%96%ef%bc%8cmof%e5%8d%b4%e5%9c%a8%e7%81%af%e7%81%ab%e9%98%91%e7%8f%8a%e5%a4%84%ef%bd%9c%e8%bf%91%e6%9c%9f%e7%a0%94%e7%a9%b6%e9%80%9f%e8%a7%88","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=187777","title":{"rendered":"\u84e6\u7136\u56de\u9996\uff0cMOF\u5374\u5728\u706f\u706b\u9611\u73ca\u5904\uff5c\u8fd1\u671f\u7814\u7a76\u901f\u89c8"},"content":{"rendered":"

MOFs\u662f\u8fd1\u5341\u5e74\u6765\u53d1\u5c55\u8fc5\u901f\u7684\u4e00\u79cd\u914d\u4f4d\u805a\u5408\u7269\uff0c\u5177\u6709\u4e09\u7ef4\u7684\u5b54\u7ed3\u6784\uff0c\u81ea\u7ec4\u88c5\u5f62\u6210\u5177\u6709\u5468\u671f\u6027\u7f51\u72b6\u9aa8\u67b6\u7684\u7ed3\u6784\uff0c\u6784\u6210\u7a7a\u95f43D\u5ef6\u4f38\uff0c\u7cfb\u6cb8\u77f3\u548c\u78b3\u7eb3\u7c73\u7ba1\u4e4b\u5916\u7684\u53c8\u4e00\u7c7b\u91cd\u8981\u7684\u65b0\u578b\u591a\u5b54\u6750\u6599\uff0c\u5728\u50ac\u5316\u3001\u50a8\u80fd\u548c\u5206\u79bb\u7b49\u7b49\u4e2d\u90fd\u6709\u5e7f\u6cdb\u5e94\u7528\u3002\u81ea20\u4e16\u7eaa90\u5e74\u4ee3\uff0c\u7b2c\u4e00\u4ee3MOFs\u6750\u6599\u88ab\u5408\u6210\u51fa\u6765\uff0cMOFs\u5df2\u6210\u4e3a\u65e0\u673a\u5316\u5b66\u3001\u6709\u673a\u5316\u5b66\u7b49\u591a\u4e2a\u5316\u5b66\u5206\u652f\u7684\u91cd\u8981\u7814\u7a76\u65b9\u5411\u3002\u7b14\u8005\u5b9a\u671f\u68b3\u7406\u8fd1\u671f\u6750\u6599\u7c7b\u7cfb\u5217\u520a\u4e2dMOFs\u7684\u76f8\u5173\u6587\u7ae0\uff0c\u4e00\u8d77\u4e86\u89e3\u4e0b\u76f8\u5173\u7814\u7a76\uff01<\/span><\/p>\n

1 MOF\u5206\u79bb\u9ad8\u7eaf\u5ea6\u4e59\u70ef\u65b0\u8fdb\u5c55<\/b><\/strong>\uff5c<\/b><\/strong>Science<\/b><\/strong><\/span><\/h3>\n

\u4e59\u70ef(C2<\/sub>H4<\/sub>)\u662f\u5316\u5b66\u5de5\u4e1a\u4e2d\u4f53\u79ef\u5360\u6bd4\u6700\u5927\u7684\u4ea7\u54c1\uff0c\u5176\u51c0\u5316\u76ee\u524d\u6d89\u53ca\u80fd\u6e90\u5bc6\u96c6\u578b\u8fc7\u7a0b\uff0c\u5982\u5316\u5b66\u5438\u9644(\u4e8c\u6c27\u5316\u78b3\u53bb\u9664)\u3001\u50ac\u5316\u52a0\u6c22(C2<\/sub>H2<\/sub>\u8f6c\u5316)\u548c\u4f4e\u6e29\u84b8\u998f(C2<\/sub>H6<\/sub>\u5206\u79bb)\u3002\u867d\u7136\u5148\u8fdb\u7684\u7269\u7406\u6216\u819c\u5206\u79bb\u53ef\u4ee5\u964d\u4f4e\u80fd\u91cf\u7684\u8f93\u5165\uff0c\u4f46\u4e00\u6b65\u53bb\u9664\u591a\u79cd\u6742\u8d28\uff0c\u7279\u522b\u662f\u5fae\u91cf\u6742\u8d28\uff0c\u662f\u4e0d\u53ef\u884c\u7684\u3002\u897f\u5317\u5de5\u4e1a\u5927\u5b66\u9648\u51ef\u6770\u6559\u6388\uff0c\u8054\u5408\u7231\u5c14\u5170\u5229\u83ab\u745e\u514b\u5927\u5b66Mike Zaworotko\u6559\u6388\u3001\u5229\u83ab\u745e\u514b\u5927\u5b66David G. Madden\u535a\u58eb\u548c\u7f8e\u56fd\u5357\u4f5b\u7f57\u91cc\u8fbe\u5927\u5b66Brian Space\u6559\u6388\u79d1\u7814\u56e2\u961f\u9996\u6b21\u5b9e\u73b0\u4e86\u5728\u56db\u7ec4\u4efd\u4f53\u7cfb\u4e0b\u4e59\u70ef\u7684\u4e00\u6b65\u9ad8\u6548\u5206\u79bb\u5236\u5907\u3002\u4ecb\u7ecd\u4e86\u4ece\u4e09\u5143(C2<\/sub>H2<\/sub>\/C2<\/sub>H6<\/sub>\/C2<\/sub>H4<\/sub>)\u6216\u56db\u5143(C2<\/sub>H2<\/sub>\/C2<\/sub>H6<\/sub>\/C2<\/sub>H4<\/sub>)\u6df7\u5408\u6c14\u4f53\u4e2d\u4e00\u6b65\u5408\u6210\u805a\u5408\u7ea7C2<\/sub>H4<\/sub>\u7684\u534f\u540c\u5438\u9644\u5206\u79bb\u65b9\u6cd5\u3002\u5408\u6210\u4e86\u6613\u4e8e\u518d\u751f\u7684\u8d85\u9009\u62e9\u6027\u5fae\u5b54MOFs\uff0c\u4e09\u79cd\u9ad8\u6027\u80fd\u8d85\u5fae\u5b54MOFs\u4e4b\u95f4\u5b58\u5728\u534f\u540c\u4f5c\u7528\uff0c\u5b9e\u73b0\u4e86\u9ad8\u7eaf\u5ea6\u4e59\u70ef\u5728\u56db\u7ec4\u4efd\u6df7\u5408\u4f53\u7cfb\u4e0b\u7684\u4e00\u6b65\u5206\u79bb\u5236\u5907\u3002\u7814\u7a76\u53d1\u73b0\uff0c\u901a\u8fc7\u6709\u6548\u5730\u4e32\u8054\u4e09\u79cdMOF\u6750\u6599\u5728\u5355\u4e00\u5438\u9644\u67f1\u5185\uff0c\u80fd\u591f\u5206\u522b\u5c06\u4e59\u7094\uff0c\u4e59\u70f7\u548c\u4e8c\u6c27\u5316\u78b3\u4f9d\u6b21\u9ad8\u6548\u5730\u53bb\u9664\uff0c\u4ece\u800c\u5728\u5438\u9644\u67f1\u5c3e\u7aef\u5b9e\u73b0\u9ad8\u7eaf\u5ea6\u4e59\u70ef\uff08>99.9%\uff09\u7684\u4e00\u6b65\u5206\u79bb\u6536\u96c6\u3002\u540c\u65f6\uff0c\u5229\u7528\u5206\u5b50\u6a21\u62df\u624b\u6bb5\u5bf9\u4f53\u7cfb\u5185\u56db\u79cd\u6c14\u4f53\u5206\u5b50\u4e0e\u4e09\u79cdMOF\u6750\u6599\u7684\u5fae\u89c2\u4f5c\u7528\u673a\u7406\u8fdb\u884c\u4e86\u9610\u91ca\uff0c\u4ece\u800c\u8be6\u7ec6\u5730\u5256\u6790\u4e86\u4e09\u79cd\u5438\u9644\u6750\u6599\u5bf9\u4e0d\u540c\u6c14\u4f53\u9009\u62e9\u6027\u5438\u9644\u7684\u672c\u56e0\u3002\u76f8\u5173\u7814\u7a76\u4ee5\u201cSynergistic sorbent separation for one-step ethylene purification from a four-component mixture\u201d\u4e3a\u9898\u76ee\u53d1\u8868\u5728Science\u4e0a\u3002<\/span><\/p>\n

\u6587\u732e\u94fe\u63a5\uff1aScience 366, 241\u2013246 (2019).<\/span><\/p>\n

\u56fe1 \u534f\u540c\u5438\u9644\u5242\u5206\u79bb\u6280\u672f\u4e0e\u73b0\u6709\u7684\u63d0\u7eaf\u65b9\u6cd5\u5bf9\u6bd4<\/span><\/p>\n

\"\"<\/span><\/p>\n

2 MOF\u7528\u4e8e\u9ad8\u7535\u5316\u5b66\u4e8c\u6c27\u5316\u78b3\u8fd8\u539f\uff5cJACS<\/b><\/strong><\/span><\/h3>\n

CO2<\/sub>\u7684\u56fa\u5b9a\u548c\u5229\u7528\u4e0d\u4ec5\u6709\u5229\u4e8e\u7f13\u89e3\u6e29\u5ba4\u6548\u5e94\uff0c\u540c\u65f6\u8fd8\u53ef\u4ee5\u5c06\u5176\u8f6c\u5316\u6210\u71c3\u6599\u548c\u5316\u5b66\u54c1\uff0c\u5bf9\u5168\u7403\u53ef\u6301\u7eed\u53d1\u5c55\u5177\u6709\u91cd\u8981\u6218\u7565\u610f\u4e49\u3002\u7535\u50ac\u5316\u8fd8\u539fCO2<\/sub>\u53cd\u5e94\u53ef\u4ee5\u5728\u6e29\u548c\u7684\u6761\u4ef6\u4e0b\uff0c\u76f4\u63a5\u5229\u7528\u5f97\u5230\u7684\u7535\u5b50\u5e76\u7ed3\u5408\u6c34\u4e2d\u7684\u8d28\u5b50\u6765\u8fd8\u539fCO2<\/sub>\uff0c\u4ece\u800c\u5b9e\u73b0\u9ad8\u6548\u7684\u78b3\u5faa\u73af\u3002\u6765\u81ea\u52a0\u5dde\u5927\u5b66\u4f2f\u514b\u5229\u5206\u6821Peidong Yang, Omar M. Yaghi\u6559\u6388\u7b49\u4eba\u5408\u6210\u4e86\u4e00\u79cd\u65b0\u7684\u9634\u79bb\u5b50\u4e09\u7ef4\u91d1\u5c5e\u6846\u67b6MOF-1992\uff0cMOF-1992\u663e\u793a\u51fa\u7a7a\u95f4\u53ef\u8fbe\u7684Co\u6d3b\u6027\u4f4d\u70b9\u548c\u7535\u8377\u8f6c\u79fb\u7279\u6027\u3002\u57fa\u4e8eMOF-1992\u548c\u70ad\u9ed1(CB)\u7684\u9634\u6781\u663e\u793a\u51fa\u9ad8\u7684\u7535\u6d3b\u6027\u4f4d\u70b9\u8986\u76d6\u7387(270nmol cm\u22122<\/sup>)\u548c\u9ad8\u7535\u6d41\u5bc6\u5ea6(- 16.5 mA cm\u22122<\/sup>;\u8fc7\u7535\u4f4d\uff0c- 0.52 V)\uff0c\u7528\u4e8eCO2<\/sub>\u5230CO\u5728\u6c34\u4e2d\u7684\u8fd8\u539f\u53cd\u5e94(\u6cd5\u62c9\u7b2c\u6548\u7387\uff0c80%)\uff0c\u57286h\u7684\u5b9e\u9a8c\u4e2d\uff0cMOF-1992\/CB\u9634\u6781\u8fbe\u5230\u4e865800\u7684\u7ffb\u8f6c\u6b21\u6570\uff0c\u7ffb\u8f6c\u9891\u7387\u4e3a\u6bcf\u4e2a\u6d3b\u6027\u4f4d\u70b9\u4e3a0.20 s -1<\/sup>\u3002MOF-1992\u6240\u8fbe\u5230\u7684\u9ad8\u7535\u6d41\u5bc6\u5ea6\u6700\u7ec8\u662f\u7531\u4e8e\u8be5\u7ed3\u6784\u76843D\u5bfc\u7535\u6027\uff0c\u8fd9\u4f7f\u5f97\u7535\u6781\u4e0a\u7684\u6d3b\u6027\u4f4d\u70b9\u5177\u6709\u9ad8\u7684\u7535\u6d3b\u6027\u8986\u76d6\u3002\u603b\u7684\u6765\u8bf4\uff0cMOF-1992\u6f14\u793a\u4e86\u5206\u5b50\u50ac\u5316\u5242\u5728\u91d1\u5c5e\u4e0e\u914d\u4f53\u9aa8\u67b6\u4e2d\u7684\u7f51\u72b6\u7ed3\u6784\u662f\u5982\u4f55\u4e3aCO2\u8fd8\u539f\u53cd\u5e94\u751f\u6210\u9ad8\u6027\u80fd\u7684\u9634\u6781\u7684\u3002\u76f8\u5173\u7814\u7a76\u4ee5\u201cThree-Dimensional Phthalocyanine Metal-Catecholates for High Electrochemical Carbon Dioxide Reduction\u201d\u4e3a\u9898\u76ee\uff0c\u53d1\u8868\u5728JACS\u4e0a\u3002<\/span><\/p>\n

\u6587\u732e\u94fe\u63a5:\u00a0<\/b><\/strong>DOI: 10.1021\/jacs.9b09298.<\/span><\/p>\n

\u56fe2 MOF-1992\u7ed3\u6784\u793a\u610f\u56fe<\/span><\/p>\n

\"\"<\/span><\/p>\n

3\u00a0MOF-\u805a\u5408\u7269\u6df7\u5408\u57fa\u8d28\u819c\u7528\u4e8e\u624b\u6027\u5206\u5b50\u7684\u9ad8\u6548\u5206\u79bb\uff5cAngew.<\/b><\/strong><\/span><\/h3>\n

\u8fd1\u5e74\u6765\uff0c\u6709\u5173\u540c\u624b\u6027\u91d1\u5c5e-\u6709\u673a\u9aa8\u67b6(MOF)\u819c\u7528\u4e8e\u624b\u6027\u5206\u79bb\u7684\u62a5\u9053\u8d8a\u6765\u8d8a\u591a\u3002\u7136\u800c\uff0c\u7531\u4e8e\u65e0\u7f3a\u9677\u7684\u624b\u6027MOF\u5c42\u5728\u591a\u5b54\u886c\u5e95\u4e0a\u96be\u4ee5\u7ed3\u6676\uff0c\u76ee\u524d\u53ea\u6709\u5c11\u6570\u9ad8\u54c1\u8d28\u7684\u540c\u8d28\u591a\u6676\u5236\u5907\u4e86MOF\u819c\u3002 \u53e6\u5916\uff0c\u6df7\u5408\u57fa\u8d28\u819c(MMMs)\u7ed3\u5408\u4e86MOFs\u548c\u805a\u5408\u7269\u7684\u6f5c\u5728\u4f18\u52bf\uff0c\u5df2\u88ab\u5e7f\u6cdb\u7528\u4e8e\u6c14\u4f53\u5206\u79bb\u548c\u6c34\u51c0\u5316\u3002\u8fd1\u65e5\uff0c\u6765\u81ea\u6fb3\u5927\u5229\u4e9a\u83ab\u7eb3\u4ec0\u5927\u5b66\u738b\u7115\u5ead\u6559\u6388\u8bfe\u9898\u7ec4\uff0c\u62a5\u9053\u4e86\u4e00\u79cd\u65b0\u578b\u540c\u624b\u6027MOF\u805a\u5408\u7269\u6df7\u5408\u57fa\u8d28\u819c\u7528\u4e8e\u9ad8\u6548\u624b\u6027\u5206\u79bb\u7684\u3002\u901a\u8fc7\u6c28\u57fa\u9178\u7684\u540e\u5408\u6210\u4fee\u9970\uff0c\u6210\u529f\u5730\u5c06\u975e\u624b\u6027\u7684MIL-53-NH2<\/sub>\u7eb3\u7c73\u6676\u4f53\u4e0e\u540c\u624b\u6027\u76f8\u7ed3\u5408\uff0c\u7136\u540e\u5c06MIL-53-NH-L-His\u548cMIL-53-NH-L-Glu\u7eb3\u7c73\u6676\u4f53\u5d4c\u5165\u805a\u919a\u781c(PES)\u57fa\u8d28\u4e2d\uff0c\u5f62\u6210\u624b\u6027MMMs\u3002\u5176\u4e2dMIL-53-NH-L-His\u819c\u5bf9\u5916\u6d88\u65cb\u76841-\u82ef\u4e59\u9187\u5177\u6709\u826f\u597d\u7684\u5bf9\u6620\u9009\u62e9\u6027\uff0c\u5176\u5bf9\u6620\u4f53\u8fc7\u5269\u503c\u6700\u9ad8\u53ef\u8fbe100%\u3002\u53e6\u5916\u5bf9MIL-53-NH- L-Glu\u57faMMMs\u624b\u6027\u5206\u79bb\u6027\u80fd\u7684\u7814\u7a76\uff0c\u4e5f\u8bc1\u660e\u4e86\u8be5\u65b9\u6cd5\u5236\u5907\u5bf9\u6620\u9009\u62e9\u6027MMMs\u7684\u901a\u7528\u6027\u3002\u4ee5\u672c\u5de5\u4f5c\u4e3a\u4f8b\uff0c\u8bba\u8bc1\u4e86\u6784\u5efa\u591a\u79cd\u591a\u6837\u7684\u3001\u57fa\u4e8e\u540c\u624b\u6027MMMs\u7528\u4e8e\u624b\u6027\u5206\u79bb\u7684\u53ef\u884c\u6027\u3002\u76f8\u5173\u7814\u7a76\u4ee5\u201cHomochiral Metal\u2010Organic Frameworks\u2010Polymer Mixed Matrix Membranes for Efficient Separation of Chiral Molecules\u201d\u4e3a\u9898\u76ee\uff0c\u53d1\u8868\u5728Angew.\u4e0a\u3002<\/span><\/p>\n

\u6587\u732e\u94fe\u63a5\uff1aAngew. Chem. Int. Ed. 2019, 58, 2-10.<\/span><\/p>\n

\u56fe3 \u6c28\u57fa\u9178\u529f\u80fd\u5316MOF\u7eb3\u7c73\u6676\u7684\u5236\u5907\u4e0e\u8868\u5f81<\/span><\/p>\n

\"\"<\/span><\/p>\n

4 \u5f00\u653e\u94dc\u4f4d\u70b9\u7684MOF\u4e2dSO<\/b><\/strong>2<\/b><\/sub><\/strong>\u7684\u53ef\u9006\u914d\u4f4d\u548c\u5206\u79bb\uff5cNature Materials<\/b><\/strong><\/span><\/h3>\n

\u70df\u6c14\u548c\u6d77\u6d0b\u8fd0\u8f93\u6392\u653e\u7684\u4e8c\u6c27\u5316\u786b\u5bf9\u73af\u5883\u548c\u4eba\u4f53\u5065\u5eb7\u6709\u4e0d\u5229\u5f71\u54cd\uff0c\u4f46\u5982\u679c\u80fd\u591f\u6709\u6548\u5730\u56de\u6536\u3001\u50a8\u5b58\u548c\u8fd0\u8f93\uff0c\u4e8c\u6c27\u5316\u786b\u4e5f\u662f\u91cd\u8981\u7684\u5de5\u4e1a\u539f\u6599\u3002\u66fc\u5f7b\u65af\u7279\u5927\u5b66Martin Schr\u00f6der\uff0cSihai Yang\u7b49\u62a5\u544a\u7684\u7279\u6b8a\u5438\u9644\u548c\u5206\u79bb\u4e8c\u6c27\u5316\u786b\u5728\u591a\u5b54\u6750\u6599,[Cu2<\/sub>(L)] (H4<\/sub>L = 4\u2032, 4\u2034- (pyridine-3,5-diyl) bis([1,1\u2032-biphenyl]-3,5-dicarboxylic acid)): MFM-170\u3002MFM -170\u5728298k\u548c1.0 bar\u6761\u4ef6\u4e0b\u5b8c\u5168\u53ef\u9006\u5730\u5438\u653617.5 mmol g\u22121<\/sup>\u7684SO2<\/sub>\uff0c\u5e76\u4e14\u5df2\u7ecf\u786e\u5b9a\u4e86MFM-170\u4e2d\u88ab\u6355\u83b7\u5206\u5b50\u7684SO2<\/sub>\u7ed3\u5408\u57df\u3002\u62a5\u9053\u6307\u51faSO2<\/sub>\u4e0eCu(ii)\u4f4d\u70b9\u7684\u53ef\u9006\u914d\u4f4d\uff0c\u6709\u52a9\u4e8eMFM-170\u5728\u89e3\u5438\u540e\u5bf9SO2<\/sub>\u7684\u5438\u9644\u70ed\u529b\u5b66\u548c\u9009\u62e9\u6027\uff0c\u4ee5\u53ca\u65b9\u4fbf\u7684\u518d\u751f\u3002MFM-170\u5bf9\u6c34\u3001\u9178\u3001\u78b1\u7a33\u5b9a\uff0c\u5728\u6a21\u62df\u70df\u6c14\u6df7\u5408\u7269\u4e2d\u52a8\u6001\u5206\u79bbSO2<\/sub>\u65b9\u9762\u5177\u6709\u826f\u597d\u7684\u5e94\u7528\u524d\u666f\u3002\u76f8\u5173\u7814\u7a76\u4ee5\u201cReversible coordinative binding and separation of sulfur dioxide in a robust metal\u2013organic framework with open copper sites\u201d\u4e3a\u9898\u76ee\uff0c\u53d1\u8868\u5728Nature Materials\u4e0a\u3002<\/span><\/p>\n

\u6587\u732e\u94fe\u63a5\uff1ahttps:\/\/www.nature.com\/articles\/s41563-019-0495-0.<\/span><\/p>\n

\u56fe4 \u5355\u6676\u884d\u5c04\u6355\u6349\u5230 SO2<\/sub>\u5206\u5b50\u4f4d\u4e8eMFM-170\u7684\u5b54\u9699\u5185<\/span><\/p>\n

\"\"<\/span><\/p>\n

5 \u5177\u6709\u4ecb\u5b54\u548c\u5fae\u5b54\u7ed3\u6784\u7684\u6c34\u51dd\u80f6\u57faMOF\uff5cSmall<\/b><\/strong><\/span><\/h3>\n

\u91d1\u5c5e\u6709\u673a\u9aa8\u67b6(MOFs)\u4e2d\u9176\u7684\u5305\u5c01\u5e38\u5e38\u88ab\u5927\u591a\u6570\u62a5\u9053\u7684MOFs\u4e2d\u5178\u578b\u7684\u5c0f\u5b54\u7684\u5c0f\u5c3a\u5bf8\u6240\u963b\u788d\uff0c\u4ece\u800c\u963b\u788d\u4e86\u5927\u5c3a\u5bf8\u9176\u7684\u901a\u8fc7\u3002\u5317\u4eac\u5316\u5de5\u5927\u5b66\u8c2d\u5929\u4f1f\u9662\u58eb\u548c\u5415\u6c38\u7434\u6559\u6388\u7b49\u4eba\u4ecb\u7ecd\u4e86\u4ee5\u6c34\u51dd\u80f6\u4e3a\u6a21\u677f\uff0c\u91c7\u7528\u6a21\u677f\u4e73\u5316\u6cd5\u5236\u5907\u5206\u7ea7\u5fae\u5b54\u548c\u4ecb\u5b54\u950c\u57faMOFs\u7684\u65b9\u6cd5\u3002\u950c\u57fa\u6c34\u51dd\u80f6\u5177\u6709\u4e09\u7ef4\u4e92\u8054\u7f51\u7edc\uff0c\u9996\u5148\u901a\u8fc7\u4e09\u805a\u6c30\u80fa\u548c\u6c34\u6768\u9178\u4e4b\u95f4\u7684\u6c22\u952e\u5f62\u6210\uff0c\u5176\u4e2d\u950c\u79bb\u5b50\u5206\u5e03\u826f\u597d\u3002\u8fdb\u4e00\u6b65\u4e0e\u6709\u673a\u8fde\u63a5\u5242\u914d\u5408\uff0c\u7136\u540e\u53bb\u9664\u6c34\u51dd\u80f6\u6a21\u677f\u4ea7\u751f\u5206\u5c42\u542b\u6709\u5fae\u5b54\u548c\u4e2d\u5b54\u7684\u950c\u57faMOFs\u3002\u5229\u7528\u8fd9\u4e9b\u65b0\u7684MOFs\u5305\u5c01\u8461\u8404\u7cd6\u6c27\u5316\u9176\u548c\u8fa3\u6839\u8fc7\u6c27\u5316\u7269\u9176\u6765\u9a8c\u8bc1\u8fd9\u4e00\u6982\u5ff5\u3002\u56fa\u5b9a\u5316\u9176\u7684\u64cd\u4f5c\u7a33\u5b9a\u6027\u548c\u9176\u6d3b\u6027\u663e\u8457\u63d0\u9ad8\uff0c\u9176\u50ac\u5316\u6548\u7387kcat<\/sub>\u00a0\/km<\/sub>\u503c\u4e3a85.68 mM s-1<\/sup>\u3002\u8be5\u503c\u6bd4\u6eb6\u6db2\u4e2d\u6e38\u79bb\u9176\u7684\u503c\u9ad87.7\u500d\uff0c\u6bd4\u5438\u9644\u5728\u4f20\u7edf\u5fae\u5b54MOFs\u4e0a\u7684\u9176\u7684\u503c\u9ad82.7\u500d\u3002\u7ed3\u679c\u8868\u660e\uff0c\u4ecb\u5b54\u5076\u8054\u7269\u7684\u50ac\u5316\u6d3b\u6027\u6bd4\u5fae\u5b54\u5076\u8054\u7269\u9ad8\u5f97\u591a\uff0c\u8fd9\u662f\u56e0\u4e3a\u4ecb\u5b54\u5076\u8054\u7269\u5177\u6709\u66f4\u5927\u7684\u5b54\u6d1e\uff0c\u53ef\u4ee5\u66f4\u5bb9\u6613\u5730\u5230\u8fbe\u6d3b\u6027\u4f4d\u70b9\uff0c\u5e76\u4e0e\u5fae\u5b54\u5076\u8054\u7269\u7684\u50ac\u5316\u6d3b\u6027\u8fdb\u884c\u4e86\u6bd4\u8f83\u3002\u76f8\u5173\u7814\u7a76\u4ee5\u201cHierarchical Micro- and Mesoporous Zn-Based Metal\u2013Organic Frameworks Templated by Hydrogels: Their Use for Enzyme Immobilization and Catalysis of Knoevenagel Reaction\u201d\u4e3a\u9898\u76ee\uff0c\u53d1\u8868\u5728Small\u4e0a\u3002<\/span><\/p>\n

\u6587\u732e\u94fe\u63a5\uff1aSmall 2019, 1902927. DOI: 10.1002\/smll.201902927.<\/span><\/p>\n

\u56fe5 \u6a21\u677f\u4e73\u5316\u6cd5\u5236\u5907\u5fae\u5b54\u548c\u4e2d\u5b54\u9aa8\u67b6\u793a\u610f\u56fe<\/span><\/p>\n

\"\"<\/span><\/p>\n

6 \u8d85\u9ad8MOF\u62c5\u8f7d\u91cf\u819c\u5438\u9644\u5668\u7528\u4e8e\u9ad8\u6548\u5206\u79bb\uff5cNature Communications<\/b><\/strong><\/span><\/h3>\n

\u5177\u6709\u9ad8\u5b54\u9699\u7387\u548c\u53ef\u8bbe\u8ba1\u529f\u80fd\u7684\u91d1\u5c5e\u6709\u673a\u9aa8\u67b6(MOFs)\u5177\u6709\u9ad8\u6e17\u900f\u7387\u548c\u9ad8\u9009\u62e9\u6027\u7684\u4f18\u70b9\u3002\u7136\u800c\uff0c\u5236\u9020\u5177\u6709\u826f\u597d\u67d4\u6027\u548c\u8d85\u9ad8MOF\u8d1f\u8f7d\u7684\u6df7\u5408\u57fa\u8d28\u819c(MMMs)\u7684\u53ef\u6269\u5c55\u5236\u9020\u65b9\u6cd5\u662f\u8feb\u5207\u9700\u8981\u7684\uff0c\u4f46\u5728\u5f88\u5927\u7a0b\u5ea6\u4e0a\u8fd8\u6ca1\u6709\u5f97\u5230\u6ee1\u8db3\u3002\u5728\u6b64\uff0c\u5317\u4eac\u7406\u5de5\u5927\u5b66\u7684\u738b\u535a\u3001\u51af\u9704\u7814\u7a76\u56e2\u961f\u62a5\u9053\u4e86\u4e00\u79cd\u70ed\u8bf1\u5bfc\u76f8\u5206\u79bb-\u70ed\u538b(TIPS-HoP)\u7b56\u7565\uff0c\u4ee5\u751f\u4ea710\u79cd\u4e0d\u540c\u7684\u8f8a\u5bf9\u8f8a\u9ad8\u62c5\u8f7d\u91cf\u3001\u67d4\u6027MOF\u819c(\u8d1f\u8f7d\u91cd\u91cf\u53ef\u8fbe86% wt%)\u3002MOF\u5206\u6563\u5230\u7194\u878d\u6001\u7684\u8d85\u9ad8\u5206\u5b50\u91cf\u7684\u805a\u4e59\u70ef\u9897\u7c92\u4e2d\uff0c\u4ea4\u7ec7\u5728\u4e00\u8d77\uff0c\u63d0\u9ad8\u4e86\u5176\u673a\u68b0\u5f3a\u5ea6\u3002\u7814\u7a76\u8868\u660e\u6c34\u901a\u91cf\u4e3a125.7 L m-2<\/sup>\u00a0h-1<\/sup>\u00a0bar-1<\/sup>\u7684\u6709\u673a\u67d3\u6599\u5728\u6a2a\u6d41\u8fc7\u6ee4\u6a21\u5f0f\u4e0b\u7684\u6b8b\u7559\u4e3a99%\uff0cNH2<\/sub>-UiO-66 PE MMMs \u4e2dMOF\u9897\u7c92\u95f4\u7684\u5fae\u7c73\u7ea7\u901a\u9053\u8f6c\u5316\u4e3a\u5feb\u901f\u6c34\u6e17\u900f\uff0c\u800c\u591a\u5b54MOFs\u901a\u8fc7\u5feb\u901f\u5438\u9644\u6392\u65a5\u6eb6\u8d28\u3002\u8fd9\u4e00\u7b56\u7565\u4e3a\u5f00\u53d1\u7528\u4e8e\u5173\u952e\u5206\u79bb\u8fc7\u7a0b\u7684\u9ad8\u6027\u80fd\u819c\u5438\u9644\u5668\u94fa\u5e73\u4e86\u9053\u8def\u3002\u4f5c\u4e3a\u6982\u5ff5\u7684\u8bc1\u660e\uff0c\u819c\u5438\u9644\u5242\u5206\u79bb\u5916\u6d88\u65cb\u4f53\u548c\u86cb\u767d\u8d28\u7684\u80fd\u529b\u5df2\u7ecf\u5f97\u5230\u8bc1\u660e\u3002\u76f8\u5173\u7814\u7a76\u4ee5\u201cMembrane adsorbers with ultrahigh metal-organic framework loading for high flux separations\u201d\u4e3a\u9898\u76ee\uff0c\u53d1\u8868\u5728Nature Communications\u4e0a\u3002<\/span><\/p>\n

\u6587\u732e\u94fe\u63a5\uff1ahttps:\/\/doi.org\/10.1038\/s41467-019-12114-8.<\/span><\/p>\n

\u56fe6 TIPS-HoP\u7f16\u5199\u7684MOF PE MMM\u793a\u610f\u56fe<\/span><\/p>\n

\"\"<\/span><\/p>\n

7 \u81ea\u6298\u53e0\u7ed3\u6784\u53ef\u53d8\u7684MOF\u57fa\u805a\u5408\u7269\u8584\u819c\uff5cAM<\/b><\/strong><\/span><\/h3>\n

\u5c06\u53ef\u81a8\u80c0\u7684\u91d1\u5c5e\u6709\u673a\u9aa8\u67b6(MOFs)\u96c6\u6210\u5230\u805a\u5408\u7269\u590d\u5408\u819c\u4e2d\uff0c\u662f\u4e00\u79cd\u76f4\u63a5\u7684\u5f00\u53d1\u8f6f\u6750\u6599\u6676\u4f53\u5f39\u6027\u7684\u7b56\u7565\u3002\u7136\u800c\uff0c\u5b9e\u73b0\u5b83\u4eec\u7684\u5b9e\u9645\u5e94\u7528\u7684\u5173\u952e\u6b65\u9aa4\u4f9d\u8d56\u4e8e\u5b9e\u73b0\u7279\u6b8a\u529f\u80fd\u548c\u53ef\u7f16\u7a0b\u9a71\u52a8\u7684\u80fd\u529b\uff0c\u8fd9\u4f7f\u5f97\u6839\u636e\u9700\u8981\u8bbe\u8ba1\u81ea\u6210\u5f62\u5bf9\u8c61\u6210\u4e3a\u53ef\u80fd\u3002\u897f\u73ed\u7259\u52a0\u6cf0\u7f57\u5c3c\u4e9a\u7eb3\u7c73\u79d1\u5b66\u548c\u7eb3\u7c73\u6280\u672f\u7814\u7a76\u6240Daniel Maspoch\u6559\u6388\u6f14\u793a\u4e86\u4e00\u79cd\u5316\u5b66\u8680\u523b\u65b9\u6cd5\uff0c\u7528\u4e8e\u5236\u4f5c\u5177\u6709\u53ef\u8c03\u81ea\u6298\u53e0\u54cd\u5e94\u3001\u53ef\u9884\u6d4b\u4e14\u53ef\u7531\u6c34\u5438\u9644\/\u89e3\u5438\u89e6\u53d1\u7684\u4e8c\u7ef4\u5230\u4e09\u7ef4\u5f62\u72b6\u8f6c\u6362\u7684\u56fe\u5f62\u5316\u590d\u5408\u819c\u3002\u8fd9\u4e9b\u8584\u819c\u662f\u901a\u8fc7\u9009\u62e9\u6027\u53bb\u9664\u53ef\u81a8\u80c0\u7684MOF\u6676\u4f53\u6765\u63a7\u5236\u5176\u5728\u805a\u5408\u8584\u819c\u4e2d\u7684\u7a7a\u95f4\u5206\u5e03\u3002\u5f53\u66b4\u9732\u5728\u6f6e\u6e7f\u73af\u5883\u4e2d\uff0c\u5404\u79cd\u53ef\u7f16\u7a0b\u7684\u4e09\u7ef4\u7ed3\u6784\uff0c\u5305\u62ec\u4e00\u4e2a\u673a\u68b0\u5939\u6301\u5668\u3001\u4e00\u4e2a\u5347\u964d\u673a\u548c\u4e00\u4e2a\u5355\u5411\u884c\u8d70\u88c5\u7f6e\uff0c\u5c31\u4f1a\u4ea7\u751f\u3002\u503c\u5f97\u6ce8\u610f\u7684\u662f\uff0c\u8fd9\u4e9b2D\u52303D\u7684\u5f62\u72b6\u8f6c\u6362\u53ef\u4ee5\u901a\u8fc7\u5149\u8bf1\u5bfc\u89e3\u5438\u6765\u9006\u8f6c\u3002\u62a5\u544a\u7684\u7b56\u7565\u63d0\u4f9b\u4e86\u4e00\u4e2a\u5e73\u53f0\uff0c\u7528\u4e8e\u5236\u9020\u5177\u6709\u5fae\u64cd\u4f5c\u3001\u81ea\u52a8\u5316\u548c\u673a\u5668\u4eba\u529f\u80fd\u7684\u57fa\u4e8eMOF\u7684\u67d4\u6027\u81ea\u4e3b\u8f6f\u673a\u68b0\u8bbe\u5907\u3002\u76f8\u5173\u7814\u7a76\u4ee5\u201cProgrammable Self-Assembling 3D Architectures Generated by Patterning of Swellable MOF-Based Composite Films\u201d\u4e3a\u9898\u76ee\uff0c\u53d1\u8868\u5728AM\u4e0a\u3002<\/span><\/p>\n

\u6587\u732e\u94fe\u63a5\uff1aAdv. Mater. 2019, 1808235.<\/span><\/p>\n

\u56fe7 MIL-88A\u5728\u5438\u9644\/\u89e3\u5438\u540e\u7684\u7ed3\u6784\u8f6c\u53d8\u53caMIL-88A@PVDF \u8584\u819c\u76f8\u5173\u56fe\u5f62\u7684\u793a\u610f\u56fe<\/span><\/p>\n

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8 \u9ad8\u6548\u6c34\u57fa\u8d85\u4f4e\u6e29\u9a71\u52a8\u51b7\u5374\u7cfb\u7edf\u7684MOF\uff5c Nature Communications<\/b><\/strong><\/span><\/h3>\n

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\u6587\u732e\u94fe\u63a5\uff1ahttps:\/\/doi.org\/10.1038\/s41467-019-10960-0.<\/span><\/p>\n

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\u6253\u901aMOFs\u4efb\u7763\u4e8c\u8109 \u2014\u2014 \u77e5\u540d\u671f\u520a\u8fd1\u671f\u901f\u89c8<\/a><\/p>\n

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MOF\u4e13\u680f & PPT \u2014\u2014 \u56fd\u9645\u77e5\u540dMOF\u5927\u725b\u96c6\u9526<\/a><\/p>\n

MOF\u4e13\u680f & PPT\u2014\u2014\u56fd\u5185MOF\u5927\u725b\u96c6\u9526<\/a><\/p>\n

\u88abNature\u3001Science\u6367\u7ea2\u7684\u660e\u661f:\u2002MOF\u53d1\u5c55\u7684\u91cc\u7a0b\u7891\u3001\u547d\u540d\u89c4\u5219\u4ee5\u53ca\u4ee3\u8868\u6027MOF\u603b\u7ed3<\/a><\/p>\n

\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1: tougao@cailiaoren.com.<\/span><\/p>\n

\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1acailiaorenVIP.<\/span><\/p>\n","protected":false},"excerpt":{"rendered":"

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