{"id":187710,"date":"2019-10-20T13:42:59","date_gmt":"2019-10-20T05:42:59","guid":{"rendered":"\/\/m.iemloyee.com\/?p=187710"},"modified":"2019-10-20T13:42:59","modified_gmt":"2019-10-20T05:42:59","slug":"%e5%90%8c%e6%b5%8e%e5%a4%a7%e5%ad%a6%e5%91%a8%e4%bf%8a%e5%92%8c%e9%99%88%e6%9d%b0adv-funct-mater-%e5%af%bc%e7%94%b5%e8%81%9a%e5%90%88%e7%89%a9%e5%9f%ba%e6%9d%90%e6%96%99%e7%9a%84%e7%83%ad%e4%bc%a0","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=187710","title":{"rendered":"\u540c\u6d4e\u5927\u5b66\u5468\u4fca\u548c\u9648\u6770Adv. Funct. Mater.:\u5bfc\u7535\u805a\u5408\u7269\u57fa\u6750\u6599\u7684\u70ed\u4f20\u8f93"},"content":{"rendered":"

\u3010\u5f15\u8a00<\/strong>\u3011<\/p>\n

\u5bfc\u7535\u805a\u5408\u7269\u53ca\u5176\u590d\u5408\u6750\u6599\u7531\u4e8e\u5176\u91cd\u91cf\u8f7b\uff0c\u6210\u672c\u4f4e\uff0c\u53ef\u518d\u5faa\u73af\uff0c\u4ee5\u53ca\u4f18\u5f02\u7684\u5bfc\u7535\u6027\u548c\u5316\u5b66\u7a33\u5b9a\u6027\u7b49\u7a81\u51fa\u7279\u6027\u800c\u5907\u53d7\u5173\u6ce8\u3002\u53ef\u7a7f\u6234\u667a\u80fd\u8bbe\u5907\u7684\u6700\u65b0\u8fdb\u5c55\u4e3a\u4eba\u7c7b\u751f\u6d3b\u5e26\u6765\u4e86\u6781\u5927\u7684\u4fbf\u5229\u3002\u89e6\u6478\u5c4f\u663e\u793a\u5668\uff0c\u5065\u5eb7\u76d1\u6d4b\u4f20\u611f\u5668\uff0c\u529f\u80fd\u6027\u670d\u88c5\u548c\u5176\u4ed6\u667a\u80fd\u7eba\u7ec7\u4ea7\u54c1\u7b49\u8bbe\u5907\u90fd\u4f9d\u8d56\u4e8e\u5bfc\u7535\u805a\u5408\u7269\u6750\u6599\u7684\u4f18\u5f02\u7535\u6c14\u548c\u673a\u68b0\u6027\u80fd\u3002\u6b64\u5916\uff0c\u5bfc\u7535\u805a\u5408\u7269\u7531\u4e8e\u5176\u826f\u597d\u7684\u7535\u5b66\u6027\u8d28\u548c\u751f\u7269\u76f8\u5bb9\u6027\u4e5f\u5df2\u7ecf\u7528\u4e8e\u751f\u7269\u533b\u5b66\u5e94\u7528\uff0c\u4f8b\u5982\u751f\u7269\u4f20\u611f\u5668\u548c\u7ec4\u7ec7\u5de5\u7a0b\u3002\u7136\u800c\uff0c\u5bfc\u7535\u805a\u5408\u7269\u4e0d\u80fd\u964d\u89e3\u6210\u4e3a\u5b83\u4eec\u5728\u7ec4\u7ec7\u5de5\u7a0b\u4e2d\u5e94\u7528\u7684\u6700\u4e25\u91cd\u7684\u9650\u5236\u4e4b\u4e00\u3002\u79d1\u7814\u5de5\u4f5c\u8005\u5df2\u7ecf\u81f4\u529b\u4e8e\u5f00\u53d1\u53ef\u751f\u7269\u964d\u89e3\u548c\u5bfc\u7535\u7684\u805a\u5408\u7269\u6750\u6599\u3002\u5df2\u7ecf\u5408\u6210\u5e76\u5229\u7528\u5177\u6709\u6539\u8fdb\u7684\u751f\u7269\u964d\u89e3\u6027\u7684\u5bfc\u7535\u805a\u5408\u7269\u5171\u6df7\u7269\uff0c\u4f8b\u5982\u805a\u5df1\u5185\u916f\uff08PCL\uff09\/\u805a\u5421\u54af\uff08PPY\uff09\uff0c\u7528\u4e8e\u5236\u9020\u8bf8\u5982\u7535\u8c10\u632f\u5668\u7535\u8def\u7684\u751f\u7269\u7535\u5b50\u5668\u4ef6\u3002\u56e0\u6b64\uff0c\u5bfc\u7535\u805a\u5408\u7269\u57fa\u6750\u6599\u5177\u6709\u5e7f\u6cdb\u7684\u5e94\u7528\uff0c\u8303\u56f4\u4ece\u67d4\u6027\u7535\u5b50\uff0c\u751f\u7269\u533b\u5b66\u5e94\u7528\uff0c\u667a\u80fd\u7eba\u7ec7\u54c1\u5230\u70ed\u7535\u6750\u6599\u3002\u7136\u800c\uff0c\u5927\u591a\u6570\u805a\u5408\u7269\u7684\u5bfc\u70ed\u6027\u975e\u5e38\u4f4e\uff0c\u8fd9\u53ef\u80fd\u5bfc\u81f4\u8bf8\u5982\u6563\u70ed\u5931\u8d25\u7684\u5668\u4ef6\u5e94\u7528\u7684\u4e25\u91cd\u95ee\u9898\uff0c\u5c24\u5176\u662f\u5bf9\u4e8e\u6709\u673a\u7535\u5b50\u5668\u4ef6\u3002\u4ee5\u5f80\u7684\u7814\u7a76\u8868\u660e\uff0c\u805a\u5408\u7269\u7684\u4f4e\u5bfc\u70ed\u7cfb\u6570\u4e3b\u8981\u6765\u81ea\u65e0\u5b9a\u5f62\u7ed3\u6784\u548c\u5f31\u94fe\u95f4\u76f8\u4e92\u4f5c\u7528\u3002\u56e0\u6b64\uff0c\u4e3a\u4e86\u5b9a\u5236\u5bfc\u7535\u805a\u5408\u7269\u4e2d\u7684\u70ed\u4f20\u5bfc\uff0c\u7406\u89e3\u5bfc\u7535\u805a\u5408\u7269\u4e2d\u7684\u70ed\u4f20\u8f93\u673a\u5236\u662f\u975e\u5e38\u91cd\u8981\u7684\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb<\/strong>\u3011<\/p>\n

\u5bf9\u67d4\u6027\u5bfc\u7535\u6750\u6599\u7684\u9700\u6c42\u63a8\u52a8\u4e86\u8bb8\u591a\u6700\u8fd1\u5bf9\u5bfc\u7535\u805a\u5408\u7269\u57fa\u6750\u6599\u7684\u7814\u7a76\u3002\u7136\u800c\uff0c\u5bfc\u7535\u805a\u5408\u7269\u7684\u5bfc\u70ed\u7387\u76f8\u5bf9\u8f83\u4f4e\uff0c\u8fd9\u53ef\u80fd\u5bfc\u81f4\u5668\u4ef6\u5e94\u7528\u4e2d\u4e25\u91cd\u7684\u6563\u70ed\u95ee\u9898\u3002\u672c\u7efc\u8ff0\u6982\u8ff0\u4e86\u5bfc\u7535\u805a\u5408\u7269\u53ca\u5176\u590d\u5408\u6750\u6599\u4e2d\u70ed\u4f20\u8f93\u7684\u57fa\u672c\u539f\u7406\uff0c\u4ee5\u53ca\u6700\u8fd1\u5728\u8c03\u8282\u5bfc\u70ed\u6027\u65b9\u9762\u7684\u8fdb\u5c55\u3002\u9996\u5148\u603b\u7ed3\u4e86\u57fa\u4e8e\u5bfc\u7535\u805a\u5408\u7269\u7684\u6750\u6599\u4e2d\u7684\u70ed\u4f20\u8f93\u673a\u5236\u548c\u7528\u4e8e\u6d4b\u91cf\u70ed\u5bfc\u7387\u7684\u6700\u65b0\u5b9e\u9a8c\u65b9\u6cd5\u3002\u7136\u540e\u8ba8\u8bba\u4e86\u8c03\u8282\u70ed\u5bfc\u7387\u7684\u6709\u6548\u65b9\u6cd5\u3002\u6700\u540e\uff0c\u7ed9\u51fa\u4e86\u5bfc\u70ed\u805a\u5408\u7269\u53ca\u5176\u590d\u5408\u6750\u6599\u7684\u70ed\u76f8\u5173\u5e94\u7528\u548c\u672a\u6765\u524d\u666f\u3002\u8be5\u6210\u679c\u4ee5\u9898\u4e3a\u201cThermal Transport in Conductive Polymer-Based Materials\u201d\u53d1\u8868\u5728Adv. Funct. Mater.\u4e0a\u3002<\/strong><\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n

Figure 1.<\/strong>\u6d4b\u91cf\u65b9\u6cd5<\/strong><\/p>\n

\"\"<\/p>\n

a\uff09\u70ed\u63a5\u89e6\u7535\u963bRc\u548c\u672c\u5f81\u70ed\u963bRint\u7684\u793a\u610f\u56fe<\/p>\n

b\uff09\u60ac\u6d6e\u7ea4\u7ef4\u7684\u957f\u5ea6\u4f9d\u8d56\u6027\u70ed\u963b<\/p>\n

c\uff09\u7528\u4e8e\u70ed\u5bfc\u7387\u6d4b\u91cf\u7684TDTR\u65b9\u6cd5\u7684\u793a\u610f\u56fe<\/p>\n

d\uff09\u5e45\u5ea6\u7684\u539f\u59cb\u6570\u636e\u4ee5\u53ca\u5728T = 280K\u65f6\u73bb\u7483\u57fa\u677f\u4e0a\u7684P3HT\u7684\u62df\u5408\u7ed3\u679c<\/p>\n

e\uff09\u8de8\u5e73\u9762\u70ed\u5bfc\u7387\u7684\u5dee\u52063\u03c9\u6d4b\u91cf<\/p>\n

f\uff09\u7528\u4e8e\u4f30\u8ba1PEDOT\uff1aTos\u8584\u819c\u7684\u8de8\u5e73\u9762\u548c\u5e73\u9762\u5185\u70ed\u5bfc\u7387\u4e4b\u95f4\u7684\u6bd4\u7387\u7684\u88c5\u7f6e\u793a\u610f\u56fe<\/p>\n

g\uff09\u8f83\u5bbd\u548c\u8f83\u7a84\u52a0\u70ed\u5668\u7684\u6e29\u5ea6\u964d\u4f4e\uff0c\u5bf9\u5e94\u4e8e\uff08f\uff09\u3002\u5b83\u4eec\u7684\u6bd4\u7387\u4ee5\u53ca\u52a0\u70ed\u5668\u7684\u5bbd\u5ea6\u548c\u539a\u5ea6\u4e4b\u95f4\u7684\u6bd4\u7387\u7528\u4e8e\u63d0\u53d6\u6a2a\u5411\u5e73\u9762\u548c\u5e73\u9762\u5185\u70ed\u5bfc\u7387\u4e4b\u95f4\u7684\u6bd4\u7387\uff08\u63d2\u56fe\uff09\u3002<\/p>\n

Figure 2.<\/strong>\u70ed\u5bfc\u7387\u7684\u6d4b\u5b9a<\/strong><\/p>\n

\"\"<\/p>\n

a\uff09\u672a\u63ba\u6742\uff0c\u63ba\u6742\u548c\u53d6\u5411(CH)x<\/sub>\u7684\u5bfc\u70ed\u7387<\/p>\n

b\uff09\u7ed3\u6676PANI\u675f\u7684\u4f4e\u6e29\u5bfc\u70ed\u7387<\/p>\n

Figure 3.<\/strong>\u63ba\u6742\u7684\u5f71\u54cd<\/strong><\/p>\n

\"\"<\/p>\n

a\uff09\u7528\u4e8e\u70ed\u6d4b\u91cf\u7684\u60ac\u6302\u88c5\u7f6e\u7684\u626b\u63cf\u7535\u5b50\u663e\u5fae\u955c\uff08SEM\uff09\u56fe\u50cf<\/p>\n

b\uff09\u9762\u5185\u03ba\u4e0e300 K\u65f6\u7684\u9762\u5185\u03c3<\/p>\n

c\uff09PANI\u7684\u5bfc\u7535\u6027\u548c\u5bfc\u70ed\u6027\u4e4b\u95f4\u7684\u76f8\u5173\u6027<\/p>\n

Figure 4.<\/strong>\u6750\u6599\u8868\u5f81<\/strong><\/p>\n

\"\"<\/p>\n

a\uff09\u5177\u6709\u5c0f\u76f4\u5f84\u7684\u7eb3\u7c73\u7ea4\u7ef4\u4e2d\u7684\u51c6\u4e00\u7ef4\u70ed\u4f20\u8f93\u7684\u793a\u610f\u56fe\uff0c\u5176\u4e2d\u6240\u6709\u5206\u5b50\u94fe\u6cbf\u7740\u7ea4\u7ef4\u8f74\u6392\u5217<\/p>\n

b\uff09\u5177\u6709\u5927\u76f4\u5f84\u7684\u7eb3\u7c73\u7ea4\u7ef4\u4e2d\u7684\u51c6\u5404\u5411\u540c\u6027\u70ed\u6269\u6563\u7684\u793a\u610f\u56fe<\/p>\n

c\uff09\u5728\u73bb\u7483\u57fa\u677f\u4e0a\u7684P3HT\u7684WAXS\u56fe\u6848<\/p>\n

d\uff09\u5728\u73bb\u7483\u57fa\u677f\u4e0a\u7684\u7eaf\u65e0\u5b9a\u5f62P3HT\u7684WAXS\u56fe\u6848<\/p>\n

e\uff09P3HT\/FeCl3<\/sub>\u8584\u819c\u3002 \u57fa\u8d28\u4e0a\u7684\u6c27\u5316\u5242\uff08FeCl3<\/sub>\uff09\u7528\u4f5c\u805a\u5408\u7269\u94fe\u589e\u957f\u7684\u4e3b\u4f53\u6a21\u677f<\/p>\n

f\uff09\u901a\u8fc7\u7532\u9187\u6f02\u6d17\u9664\u53bb\u6c27\u5316\u5242\u7684P3HT\u8584\u819c<\/p>\n

Figure 5.<\/strong>\u5404\u79cd\u529b\u548c\u952e\u7684\u793a\u610f\u56fe<\/strong><\/p>\n

\"\"<\/p>\n

a\uff09\u9759\u7535\u529b<\/p>\n

b\uff09\u8303\u5fb7\u74e6\u5c14\u65af\u529b<\/p>\n

c\uff09\u6c22\u952e\u548c\u5171\u4ef7\u952e<\/p>\n

d\uff09\u79bb\u5b50\u952e<\/p>\n

Figure 6.<\/strong>\u57fa\u4e8e\u78b3\u6750\u6599\u7684\u5bfc\u70ed\u7387<\/strong><\/p>\n

\"\"<\/p>\n

a\uff09SWNT\/PANI\u590d\u5408\u8584\u819c\u7684\u5ba4\u6e29\u5bfc\u70ed\u7387<\/p>\n

b\uff09\u5f53CNT\u4e4b\u95f4\u7684\u70ed\u63a5\u89e6\u7535\u5bfc\u57280.1\u81f310 pW\/K-1\u4e4b\u95f4\u53d8\u5316\u65f6\uff0cCNT\/PANI\u590d\u5408\u6750\u6599\u7684\u7406\u8bba\u5bfc\u70ed\u7387<\/p>\n

Figure 7.<\/strong>\u7eb3\u7c73\u7ebf\u7684\u8868\u5f81<\/strong><\/p>\n

\"\"<\/p>\n

a-c\uff09\u4f7f\u7528\u5177\u6709\u4e0d\u540c\u76f4\u5f84\u7684P3HT\u7eb3\u7c73\u7ebf\u76843\u03c9-SThM\u7684SEM\u7167\u7247\uff0c\u539f\u5b50\u529b\u663e\u5fae\u955c\uff08AFM\uff09\u5f62\u8c8c\u548cSThM\u70ed\u56fe\u50cf<\/p>\n

d\uff09WAHTS\u6d4b\u91cfP3HT\u7eb3\u7c73\u7ebf\u7684\u96c6\u5408\uff0c\u5176\u4e2d\u6ce2\u77e2\u91cfQ\u5782\u76f4\u4e8e\u7eb3\u7c73\u7ebf<\/p>\n

Figure 8.<\/strong>\u78c1\u573a\u53ef\u4ee5\u5f15\u8d77<\/strong>mCNT<\/strong>\u6cbf\u78c1\u573a\u65b9\u5411\u7684\u6392\u5217<\/strong><\/p>\n

\"\"<\/p>\n

a-b\uff09\u5236\u5907\u5782\u76f4\u6392\u5217\u7684PVDF-mCNT\u590d\u5408\u6750\u6599\u548c\u6c34\u5e73\u6392\u5217\u7684PVDF-mCNT\u590d\u5408\u6750\u6599\u4e2dmCNT\u7684\u6392\u5217\u7684\u793a\u610f\u56fe<\/p>\n

c\uff09\u5177\u6709\u6c27\u5316\u94c1\u9897\u7c92\u7684mCNT\u7684\u900f\u5c04\u7535\u5b50\u663e\u5fae\u955c\uff08TEM\uff09<\/p>\n

Figure 9.<\/strong>\u4e0d\u540c\u9000\u706b\u6e29\u5ea6\u4e0b<\/strong>P(VDF-TrFE)<\/strong>\u8584\u819c\u7684\u5bfc\u70ed\u7cfb\u6570\u4e0e\u6e29\u5ea6\u7684\u5173\u7cfb<\/strong><\/p>\n

\"\"<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n

\u4f5c\u8005\u5728\u8fd9\u7bc7\u7efc\u8ff0\u4e2d\uff0c\u8ba8\u8bba\u4e86\u5bfc\u7535\u805a\u5408\u7269\u53ca\u5176\u590d\u5408\u6750\u6599\u7684\u70ed\u6027\u80fd\u548c\u6f5c\u5728\u5e94\u7528\u3002\u603b\u7ed3\u4e86\u8868\u5f81\u5bfc\u7535\u805a\u5408\u7269\u5bfc\u70ed\u6027\u7684\u7406\u8bba\u6a21\u578b\u548c\u5b9e\u9a8c\u6280\u672f\u3002\u5b64\u5b50\uff0c\u6781\u5316\u5b50\u548c\u53cc\u6781\u5316\u5b50\u7684\u51c6\u7c92\u5b50\u662f\u63ba\u6742\u805a\u5408\u7269\u4e2d\u7684\u4e3b\u8981\u70ed\u8f7d\u4f53\u3002\u6781\u9ad8\u7684\u63ba\u6742\u6c34\u5e73\u4e0d\u4f1a\u5bfc\u81f4\u5927\u7684\u5bfc\u70ed\u6027\uff0c\u5c3d\u7ba1\u5bfc\u7535\u7387\u53ef\u80fd\u63a5\u8fd1\u91d1\u5c5e\u7684\u503c\u3002\u6b64\u5916\uff0c\u5df2\u7ecf\u5229\u7528\u5404\u79cd\u5b9e\u9a8c\u65b9\u6cd5\u6765\u589e\u5f3a\u5bfc\u7535\u805a\u5408\u7269\u7684\u5bfc\u70ed\u6027\uff0c\u5305\u62ec\u94fe\u53d6\u5411\uff0c\u65e0\u673a\u586b\u6599\uff0c\u94fe\u95f4\u548c\u94fe\u5185\u5076\u8054\u548c\u7535\u5b50\u63ba\u6742\u3002\u540e\u4e00\u79cd\u65b9\u6cd5\u8868\u660eWiedemann-Franz\u5b9a\u5f8b\u5728\u5bfc\u7535\u805a\u5408\u7269\u4e2d\u7684\u6709\u6548\u6027\u503c\u5f97\u6000\u7591\uff0c\u8fd9\u53d6\u51b3\u4e8e\u63ba\u6742\u6c34\u5e73\u3002\u5df2\u7ecf\u6210\u529f\u5730\u4f7f\u7528\u5404\u79cd\u5b9e\u9a8c\u6d4b\u91cf\u6280\u672f\u6765\u6d4b\u91cf\u805a\u5408\u7269\u7684\u5bfc\u70ed\u7387\uff0c\u5c3d\u7ba1\u5b58\u5728\u4e00\u4e9b\u74f6\u9888\uff0c\u5c24\u5176\u662f\u5bf9\u4e8e\u8584\u819c\u7684\u9762\u5185\u70ed\u5bfc\u7387\u6d4b\u91cf\u3002\u3002<\/p>\n

Thermal Transport in Conductive Polymer-Based Materials<\/a><\/p>\n

(Adv. Funct. Mater., 2019, DOI: 10.1002\/adfm.201904704)<\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u5b66\u672f\u7ec4tt\u4f9b\u7a3f\uff0c\u6750\u6599\u725b\u6574\u7406\u7f16\u8f91\u3002\u00a0<\/p>\n

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