{"id":187077,"date":"2019-10-08T10:37:33","date_gmt":"2019-10-08T02:37:33","guid":{"rendered":"\/\/m.iemloyee.com\/?p=187077"},"modified":"2019-10-08T10:37:33","modified_gmt":"2019-10-08T02:37:33","slug":"%e8%8b%8f%e5%a4%a7%e9%bb%84%e5%b0%8f%e9%9d%92%e5%9b%a2%e9%98%9fnano-lett-pd4sn-nws%e7%9a%84%e7%bc%ba%e9%99%b7%e5%b7%a5%e7%a8%8b%e4%bd%bf%e5%85%b6%e6%88%90%e4%b8%ba%e7%87%83%e6%96%99%e7%94%b5","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=187077","title":{"rendered":"\u82cf\u5927\u9ec4\u5c0f\u9752\u56e2\u961fNano Lett.: Pd4Sn NWs\u7684\u7f3a\u9677\u5de5\u7a0b\u4f7f\u5176\u6210\u4e3a\u71c3\u6599\u7535\u6c60\u53cd\u5e94\u7684\u9ad8\u6548\u7535\u50ac\u5316\u5242"},"content":{"rendered":"

\u3010\u80cc\u666f\u4ecb\u7ecd\u3011<\/strong><\/p>\n

\u5982\u4eca\uff0c\u9ad8\u6027\u80fd\u7eb3\u7c73\u50ac\u5316\u5242\u4e0d\u4ec5\u5bf9\u5316\u5b66\u8f6c\u5316\u3001\u4f20\u611f\u5668\u3001\u71c3\u6599\u7535\u6c60\u7b49\u9886\u57df\u5360\u636e\u4e3b\u5bfc\uff0c\u800c\u4e14\u5bf9\u53d1\u5c55\u7eff\u8272\u53ef\u518d\u751f\u80fd\u6e90\uff0c\u5b9e\u73b0\u80fd\u6e90\u57fa\u7840\u8bbe\u65bd\u9769\u547d\u548c\u51cf\u5c11\u5371\u9669\u6392\u653e\u5177\u6709\u91cd\u8981\u610f\u4e49\u3002\u5176\u4e2d\uff0c\u8d35\u91d1\u5c5e\u7eb3\u7c73\u50ac\u5316\u5242\u4ee5\u5176\u9ad8\u6548\u3001\u72ec\u7279\u7684\u50ac\u5316\u6027\u80fd\u800c\u53d1\u6325\u91cd\u8981\u4f5c\u7528\u3002\u4eba\u4eec\u666e\u904d\u8ba4\u4e3a\u8d35\u91d1\u5c5e\u7eb3\u7c73\u50ac\u5316\u5242\u7684\u50ac\u5316\u6027\u80fd\u4e0e\u5176\u7ed3\u6784\u5bc6\u5207\u76f8\u5173\uff0c\u56e0\u800c\u901a\u8fc7\u5404\u79cd\u7b56\u7565\u6765\u8c03\u63a7\u50ac\u5316\u5242\u7684\u5c3a\u5bf8\u3001\u5f62\u8c8c\u3001\u7ec4\u6210\u548c\u76f8\u7ec4\u6210\u7b49\u3002\u7136\u800c\uff0c\u8d35\u91d1\u5c5e\u7eb3\u7c73\u50ac\u5316\u5242\u7684\u6027\u80fd\u4e5f\u4f1a\u53d7\u5230\u7f3a\u9677\u7684\u4e25\u91cd\u5f71\u54cd\uff0c\u4f46\u76f8\u5173\u7684\u62a5\u9053\u51e0\u4e4e\u6ca1\u6709\u3002\u5176\u5b9e\uff0c\u7eb3\u7c73\u6676\u4f53\u7684\u5fae\u89c2\u7ed3\u6784\u4e2d\u53ef\u7834\u574f\u6676\u4f53\u7ed3\u6784\u5b8c\u6574\u6027\u7684\u4f4d\u7f6e\u7f3a\u9677\u5206\u4e3a\u70b9\u7f3a\u9677\u3001\u7ebf\u7f3a\u9677\u548c\u8868\u9762\u7f3a\u9677\uff0c\u5e76\u4e14\u7531\u4e8e\u5176\u7f3a\u9677\u8c03\u8282\u8868\u9762\u7535\u5b50\u7ed3\u6784\uff0c\u6545\u5177\u6709\u5f02\u5e38\u7684\u5316\u5b66\u53cd\u5e94\u6027\u4e14\u6709\u52a9\u4e8e\u63d0\u9ad8\u50ac\u5316\u6027\u80fd\u65b9\u3002\u4f46\u662f\u76ee\u524d\u4ecd\u672a\u5bf9\u8d35\u91d1\u5c5e\u7eb3\u7c73\u50ac\u5316\u5242\u7684\u7f3a\u9677\u5f71\u54cd\u8fdb\u884c\u5145\u5206\u7814\u7a76\u3002\u4e86\u89e3\u7f3a\u9677\u5bf9\u91d1\u5c5e\u50ac\u5316\u4f5c\u7528\u5b58\u5728\u7684\u95ee\u9898\u662f\u5728\u5236\u9020\u5177\u6709\u53ef\u63a7\u7f3a\u9677\u7684\u91d1\u5c5e\u7eb3\u7c73\u50ac\u5316\u5242\u65b9\u9762\u5b58\u5728\u6781\u5927\u7684\u56f0\u96be\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u82cf\u5dde\u5927\u5b66\u7684\u9ec4\u5c0f\u9752\u6559\u6388\uff08\u901a\u8baf\u4f5c\u8005\uff09<\/strong>\u56e2\u961f\u9996\u6b21\u62a5\u9053\u4e00\u7ef4\uff081D\uff09\u8d35\u91d1\u5c5e\u7eb3\u7c73\u7ed3\u6784\u4e2d\u7684\u7f3a\u9677\u5bf9\u5b9e\u73b0\u9488\u5bf9\u71c3\u6599\u7535\u6c60\u53cd\u5e94\u7684\u9ad8\u6d3b\u6027\u548c\u7a33\u5b9a\u7684\u7535\u50ac\u5316\u5242\u65b9\u9762\u662f\u4e00\u4e2a\u4e3b\u8981\u4e14\u5fc5\u4e0d\u53ef\u5c11\u7684\u56e0\u7d20\u3002\u5b9e\u9a8c\u7ed3\u679c\u8868\u660e\uff0cPd-Sn\u7eb3\u7c73\u7ebf\uff08NWs\uff09\u8868\u73b0\u51fa\u7f3a\u9677\u4f9d\u8d56\u6027\u6027\u80fd\uff0c\u5176\u4e2d\u5bcc\u542b\u7f3a\u9677\u7684Pd4Sn\u6ce2\u72b6NWs\u5bf9\u4e8e\u7532\u9187\u6c27\u5316\u53cd\u5e94\uff08MOR\uff09\u548c\u6c27\u8fd8\u539f\u53cd\u5e94\uff08ORR\uff09\u5747\u663e\u793a\u51fa\u9ad8\u50ac\u5316\u6d3b\u6027\u548c\u8010\u4e45\u6027\u3002\u540c\u65f6\uff0c\u5229\u7528\u5bc6\u5ea6\u6cdb\u51fd\u7406\u8bba\uff08DFT\uff09\u8ba1\u7b97\u8868\u660e\u5927\u91cf\u7684\u8868\u9762\u7a7a\u4f4d\/\u805a\u96c6\u7684\u7a7a\u9699\u662f\u5728Pd4<\/sub>Sn WNWs\u5185\u5f62\u6210\u8868\u9762\u6676\u754c\uff08GBs\uff09\u7684\u9a71\u52a8\u529b\u3002\u901a\u8fc7\u8fd9\u79cd\u7f3a\u9677\u5de5\u7a0b\uff0cPd4<\/sub>Sn WNWs\u4ea7\u751f\u4e86\u9ad8\u6548\u7684\u78b1\u6027ORR\u548cMOR\u3002\u603b\u4e4b\uff0c\u8be5\u5de5\u4f5c\u5f3a\u8c03\u4e86\u7f3a\u9677\u5de5\u7a0b\u5728\u63d0\u9ad8\u5b9e\u9645\u71c3\u6599\u7535\u6c60\u548c\u80fd\u6e90\u5e94\u7528\u4e2d\u7684\u7535\u50ac\u5316\u5242\u6027\u80fd\u65b9\u9762\u7684\u91cd\u8981\u6027\u3002\u7814\u7a76\u6210\u679c\u4ee5\u9898\u4e3a\u201cDefect Engineering of Palladium-Tin Nanowires Enables Efficient Electrocatalysts for Fuel Cell Reactions\u201d<\/strong>\u53d1\u5e03\u5728\u8457\u540d\u671f\u520aNano Lett.<\/strong>\u4e0a\u3002
\n \"\"
\n \u3010\u56fe\u6587\u89e3\u8bfb\u3011<\/strong><\/p>\n

\u56fe\u4e00\u3001Pd4<\/sub>Sn NWs\u7684\u7269\u7406\u8868\u5f81<\/strong>
\n \"\"
\n \uff08A-C\uff09Pd4<\/sub>Sn NWs\u7684TEM\u56fe\u50cf\u3001HAADF-STEM\u56fe\u50cf\u548c\u76f8\u5e94\u7684\u5143\u7d20\u6620\u5c04\u56fe\u50cf\uff0c\u5176\u4e2dPd\u4e3a\u7ea2\u8272\u3001Sn\u4e3a\u7eff\u8272\uff1b<\/p>\n

\uff08D\uff09\u7a7f\u8fc7\uff08C\uff09\u4e2d\u9ec4\u8272\u7bad\u5934\u7684\u7ebf\u626b\u63cf\u5206\u6790\uff1b<\/p>\n

\uff08E-G\uff09Pd4<\/sub>Sn NWs\u7684PXRD\u56fe\u3001SEM-EDS\u5149\u8c31\u548cHR-TEM\u56fe\u50cf\u3002<\/p>\n

\u56fe\u4e8c\u3001Pd4<\/sub>Sn WNWs\u7684\u5f62\u8c8c\u548c\u7ed3\u6784\u8868\u5f81<\/strong>
\n \"\"\uff08A-C\uff09Pd4<\/sub>Sn WNWs\u7684HAADF-STEM\u56fe\u50cf\u3001TEM\u56fe\u50cf\u548c\u76f8\u5e94\u7684\u5143\u7d20\u6620\u5c04\u56fe\u50cf\uff0c\u5176\u4e2dPd\u7ea2\u8272\u8868\u793a\u3001Sn\u7eff\u8272\u8868\u793a\uff1b<\/p>\n

\uff08D-E\uff09Pd4<\/sub>Sn WNWs\u7684PXRD\u56fe\u8c31\u548cSEM-EDS\u5149\u8c31\uff1b<\/p>\n

\uff08F-H\uff09Pd4<\/sub>Sn WNWs\u7684Cs\u6821\u6b63TEM\u56fe\u50cf\uff0c\u5176\u4e2d\uff08F-G\uff09\u4e2d\u7684\u865a\u7ebf\u7a81\u51fa\u663e\u793a\u4e86\u6a2a\u7a7fWNW\u7684\u53cc\u7f3a\u9677\u7684\u5b58\u5728\uff0c\uff08H\uff09\u4e2d\u7684\u865a\u7ebf\u7bad\u5934\u7a81\u51fa\u663e\u793a\u4e86\u660e\u663e\u7684\u7f3a\u9677\/\u6676\u7c92\u8fb9\u754c\uff1b<\/p>\n

\uff08I\uff09Pd4<\/sub>Sn WNWs\u7684\u7ed3\u6784\u793a\u610f\u56fe\u3002<\/p>\n

\u56fe\u4e09\u3001Pd4<\/sub>Sn WNWs\u7684RHE\u3001\u50ac\u5316\u6d3b\u6027\u548c\u5faa\u73af\u6027\u80fd<\/strong>
\n \"\"\uff08A\uff09\u4ee520 mV\/s\u7684\u626b\u63cf\u901f\u7387\u57280.1 M HClO4<\/sub>\u6eb6\u6db2\u4e2d\u5bf9\u4e0d\u540c\u50ac\u5316\u5242\u8fdb\u884cCO\u5265\u79bb\u6d4b\u91cf\uff1b<\/p>\n

\uff08B\uff09\u4e0d\u540c\u50ac\u5316\u5242\u57280.1 M KOH\u548c0.5 M\u7532\u9187\u6eb6\u6db2\u4e2d\u7684CV\u66f2\u7ebf\uff1b<\/p>\n

\uff08C\uff09MOR\u7684\u4e0d\u540c\u50ac\u5316\u5242\u7684\u8d28\u91cf\u548c\u6bd4\u6d3b\u7684\u76f4\u65b9\u56fe\uff1b<\/p>\n

\uff08D\uff09\u5728\u5faa\u73af\u671f\u95f4\uff0c\u4e0d\u540c\u50ac\u5316\u5242\u4e0a\u7684\u7535\u6c27\u5316\u7535\u6d41\u5bc6\u5ea6\u7684\u53d8\u5316\u3002<\/p>\n

\u56fe\u56db\u3001Pd4<\/sub>Sn WNWs\u7684ORR\u548cRHE\u6027\u80fd<\/strong>
\n \"\"\uff08A-D\uff09ORR\u6781\u5316\u66f2\u7ebf\u4ee5\u53ca\u57280.90 V\u548c0.929 V\u4e0b\u76f8\u5bf9\u4e8eRHE\u7684\u534a\u6ce2\u7535\u52bf\u548cORR\u8d28\u91cf\u6d3b\u6027\uff0c\u4e0d\u540c\u50ac\u5316\u5242\u7684\u6bd4\u6d3b\u5ea6\uff1b<\/p>\n

\uff08E-F\uff0910000\u6b21ADT\u5faa\u73af\u524d\u540e\u4e0d\u540c\u50ac\u5316\u5242\u7684ORR\u6781\u5316\u66f2\u7ebf\u548c\u8d28\u91cf\u6d3b\u5ea6\u76f4\u65b9\u56fe\u3002<\/p>\n

\u56fe\u4e94\u3001Pd4<\/sub>Sn WNWs\u4e0d\u540c\u7f3a\u9677\u65f6\u7684\u51e0\u4f55\u7ed3\u6784<\/strong>
\n \"\"\uff08A\uff09\u5177\u6709Sn\u7f3a\u9677\u66b4\u9732\u7684\u5438\u9644\u6784\u578b\u7684\u51e0\u4f55\u7ed3\u6784\uff1b<\/p>\n

\uff08B\uff09\u5177\u6709Pd\u7f3a\u9677\u66b4\u9732\u7684\u5438\u9644\u6784\u578b\u7684\u51e0\u4f55\u7ed3\u6784\uff1b<\/p>\n

\uff08C\uff09\u57fa\u4e8eSr\u7f3a\u9677\u8868\u9762\u6784\u578b\u7684ORR\u4e2d\u53cd\u5e94\u8def\u5f84\u7684\u80fd\u91cf\u5206\u5e03\uff1b<\/p>\n

\uff08D\uff09\u57fa\u4e8ePd\u7f3a\u9677\u8868\u9762\u6784\u578b\u7684ORR\u4e2d\u53cd\u5e94\u8def\u5f84\u7684\u80fd\u91cf\u5206\u5e03\u3002<\/p>\n

\u56fe\u516d\u3001Pd4<\/sub>Sn WNWs\u7684\u7f3a\u9677\u6027\u80fd\u6d4b\u8bd5<\/strong>
\n \"\"\uff08A\uff09EF\u9644\u8fd1\u539f\u59cbPd4<\/sub>Sn\u8868\u9762\u7684\u952e\u5408\uff08\u84dd\u8272\uff09\u548c\u53cd\u952e\u5408\uff08\u7eff\u8272\uff09\u8f68\u9053\u8f6e\u5ed3\u56fe\uff1b<\/p>\n

\uff08B\uff09\u4e0e\u521d\u59cb\u5438\u9644\u6709\u5173\u7684Sn\u7a7a\u9699\u8868\u9762\u7684HOMO\u771f\u5b9e\u7a7a\u95f4\u8f6e\u5ed3\u56fe\uff1b<\/p>\n

\uff08C\uff09\u5f62\u6210\u4e2d\u95f4\u6b65\u9aa4\uff08OOH-\uff09\u7684HOMO\uff1b<\/p>\n

\uff08D\uff09Pd\u548cSn\u7ad9\u70b9\u7684\u8868\u9762PDOS\uff1b<\/p>\n

\uff08E\uff09PDOS\u5728\u4eceORR\u53cd\u5e94\u8def\u5f84\u5f00\u59cb\u7684Sn\u7f3a\u9677\u66b4\u9732\u8868\u9762\u7684Sn-5p\u548cO-2p\u8f68\u9053\u4e4b\u95f4\u91cd\u53e0\uff1b<\/p>\n

\uff08F\uff09\u4eceORR\u53cd\u5e94\u8def\u5f84\u5728Sn\u7a7a\u9699\u8868\u9762\u7684Pd-4d\u548cO-2p\u8f68\u9053\u4e4b\u95f4\u7684\u91cd\u53e0\u3002<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n

\u7efc\u4e0a\u6240\u8ff0\uff0c\u4f5c\u8005\u6210\u529f\u5730\u5f00\u53d1\u4e86\u4e00\u79cd\u7b80\u4fbf\u7684\u6e7f\u5316\u5b66\u7b56\u7565\uff0c\u53ea\u9700\u6539\u53d8\u5408\u6210\u6eb6\u5242\uff0c\u5373\u53ef\u9009\u62e9\u6027\u7684\u5236\u5907\u5177\u6709\u53ef\u63a7\u7f3a\u9677\uff08Pd4<\/sub>Sn WNWs\u548cPd4<\/sub>Sn NWs\uff09\u76841D Pd-Sn NWs\u3002\u5e76\u4e14\u9009\u62e9\u6027\u7684\u5236\u5907\u4e86\u7f3a\u9677\u4e30\u5bcc\u7684Pd4<\/sub>Sn NWs\u548c\u4e94\u91cd\u5bf9\u5076\u7684Pd4<\/sub>Sn NWs\u3002\u7531\u4e8e\u5177\u6709\u9ad8\u5ea6\u4e30\u5bcc\u7684\u8868\u9762\u7f3a\u9677\uff0cPd4<\/sub>Sn WNWs\/C\u5177\u6709\u76f8\u4f3c\u76841D\u7eb3\u7c73\u7ed3\u6784\u548c\u76f8\u540c\u7684\u6210\u5206\uff0c\u5176MOR\u548cORR\u7684\u6d3b\u6027\u548c\u8010\u4e45\u6027\u5747\u88ab\u589e\u5f3a\u3002DFT\u8ba1\u7b97\u8868\u660e\uff0c\u8868\u9762\u7a7a\u9699\u7ed3\u6784\u5728\u8f85\u52a9ORR\u548cMOR\u65b9\u9762\u90fd\u975e\u5e38\u6709\u5229\u3002\u603b\u4e4b\uff0c\u8be5\u5de5\u4f5c\u4e3a\u8bbe\u8ba1\u9ad8\u6027\u80fd\u7535\u50ac\u5316\u5242\u63d0\u4f9b\u4e86\u65b0\u7b56\u7565\uff0c\u6709\u5de8\u5927\u6f5c\u529b\u5e94\u7528\u4e8e\u672a\u6765\u7684\u5b9e\u7528\u71c3\u6599\u7535\u6c60\u4e2d\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1aDefect Engineering of Palladium-Tin Nanowires Enables Efficient Electrocatalysts for Fuel Cell Reactions<\/a><\/strong>\uff08Nano Lett.<\/em>, 2019<\/strong>, DOI: 10.1021\/acs.nanolett.9b02137\uff09<\/p>\n

\u672c\u6587\u7531CQR\u7f16\u8bd1\u3002<\/p>\n

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