{"id":186144,"date":"2019-10-03T06:30:38","date_gmt":"2019-10-02T22:30:38","guid":{"rendered":"\/\/m.iemloyee.com\/?p=186144"},"modified":"2019-10-01T22:21:33","modified_gmt":"2019-10-01T14:21:33","slug":"%e3%80%90%e5%b7%b2%e6%a0%a1%e7%a8%bf%e3%80%91%e5%8d%97%e5%b8%88%e5%a4%a7%e5%88%98%e7%8a%87acs-nano%ef%bc%9a-%e7%94%a8%e4%ba%8e%e9%ab%98%e6%95%88%e7%94%b5%e5%82%ac%e5%8c%96%e7%9a%84%e4%b8%89%e5%85%83pd","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=186144","title":{"rendered":"\u5357\u5e08\u5927\u5218\u7287ACS Nano\uff1a \u7528\u4e8e\u9ad8\u6548\u7535\u50ac\u5316\u7684\u4e09\u5143PdBP\u5408\u91d1\u4ecb\u5b54\u7eb3\u7c73\u7403"},"content":{"rendered":"
\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n 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\u4ecb\u5b54\u6750\u6599\u76f8\u6bd4\u96f6\u7ef4\u7eb3\u7c73\u9897\u7c92\u5177\u6709\u66f4\u5927\u7684\u6bd4\u8868\u9762\u79ef\u548c\u8fdb\u800c\u66b4\u9732\u66f4\u591a\u7684\u6d3b\u6027\u4f4d\u70b9\uff0c\u56e0\u6b64\u901a\u5e38\u5177\u6709\u66f4\u5f3a\u7684\u50ac\u5316\u6d3b\u6027\u3002\u5177\u6709\u7a7a\u95f4\u6811\u679d\u72b6\u7eb3\u7c73\u7ed3\u6784\u7684\u4e9a100 nm\u4ecb\u5b54\u7eb3\u7c73\u7403\u53ef\u4ee5\u8fdb\u4e00\u6b65\u52a0\u901f\u7269\u8d28\/\u7535\u5b50\u8f6c\u79fb\u5e76\u63d0\u9ad8\u50ac\u5316\u6027\u80fd\u3002\u5728\u4ecb\u5b54\u6750\u6599\u7684\u5404\u79cd\u5408\u6210\u8def\u7ebf\u4e2d\uff0c\u8f6f\u6a21\u677f\u6cd5\u5177\u6709\u5f88\u597d\u7684\u5e94\u7528\u524d\u666f\uff0c\u53ef\u4ee5\u5229\u7528\u4e24\u4eb2\u5206\u5b50\u6a21\u677f\u5242\u7684\u81ea\u7ec4\u88c5\u6765\u5236\u5907\u7eb3\u7c73\u6811\u679d\u72b6\u4ecb\u5b54\u7eb3\u7c73\u7403(MS)\u3002<\/p>\n \u76ee\u524d\uff0c\u7531\u4e8e\u7eb3\u7c73\u6676\u6210\u6838\u548c\u7ed3\u6676\u8fc7\u7a0b\u4e2d\uff0c\u5bf9\u7c7b\u91d1\u5c5e\u548c\u975e\u91d1\u5c5e\u6e90\u7684\u534f\u540c\u8fd8\u539f\u52a8\u529b\u5b66\u7684\u8c03\u63a7\u4ecd\u662f\u96be\u70b9\uff0c\u76f8\u5173\u62a5\u9053\u8fd8\u5f88\u5c11\u3002\u73b0\u6709\u7684\u7eb3\u7c73\u5408\u6210\u65b9\u6cd5\u53ea\u80fd\u751f\u6210\u5305\u542b\u4e00\u79cd\u7c7b\u91d1\u5c5e\u6216\u975e\u91d1\u5c5e\u5143\u7d20\u7684Pd\u57fa\u5408\u91d1\uff0c\u9650\u5236\u4e86\u80fd\u63d0\u9ad8Pd\u57fa\u7eb3\u7c73\u50ac\u5316\u5242\u7684\u5143\u7d20\u7ed3\u5408\u79cd\u7c7b\uff1b\u5177\u6709\u591a\u5b54\u7684\u4e09\u7ef4\u679d\u72b6\u7eb3\u7c73\u7ed3\u6784\u7684\u591a\u5143\u8d35\u91d1\u5c5e-\u7c7b\u91d1\u5c5e-\u975e\u91d1\u5c5e\u7eb3\u7c73\u6750\u6599\u4ecd\u672a\u6709\u62a5\u9053\u3002<\/p>\n \u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n \u8fd1\u65e5\uff0c\u5357\u4eac\u5e08\u8303\u5927\u5b66\u5218\u7287\u6559\u6388\uff08\u901a\u8baf\u4f5c\u8005\uff09<\/strong>\u5728ACS Nano<\/strong>\u4e0a\u53d1\u8868\u4e86\u9898\u4e3a\u201cTernary Palladium-Boron-Phosphorus Alloy Mesoporous Nanospheres for Highly Efficient Electrocatalysis<\/strong>\u201d\u7684\u6587\u7ae0\u3002\u8bba\u6587\u7b2c\u4e00\u4f5c\u8005\u4e3a\u5357\u5e08\u5927\u5316\u5b66\u4e0e\u6750\u6599\u79d1\u5b66\u5b66\u9662\u7855\u58eb\u7814\u7a76\u751f\u5415\u6d69\u3002\u672c\u6587\u62a5\u9053\u4e86\u4e00\u79cd\u7b80\u5355\u7684\u8f6f\u6a21\u677f\u5408\u6210\u7b56\u7565\uff0c\u5b9e\u73b0Pd\u5143\u7d20\u4e0e\u7c7b\u91d1\u5c5e\u5143\u7d20B\u3001\u975e\u91d1\u5c5e\u5143\u7d20P\u7684\u5171\u5408\u91d1\u5316\uff0c\u5236\u5907\u4e86\u4e09\u7ef4\u679d\u72b6\u9aa8\u67b6\u7684\u4e09\u5143PdBP\u4ecb\u5b54\u7eb3\u7c73\u7403\u3002\u8be5\u65b9\u6cd5\u4e3a\u4e00\u6b65\u6c34\u76f8\u5408\u6210\uff0c\u4ee5\u4e8c\u7532\u57fa\u53cc\u5341\u516b\u70f7\u57fa\u6c2f\u5316\u94f5\u4e3a\u6a21\u677f\uff0c\u4e8c\u7532\u80fa\u57fa\u7532\u787c\u70f7\u548c\u6b21\u78f7\u9178\u94a0\u4f5c\u4e3aB\u6e90\u548cP\u6e90\u4ee5\u53ca\u5171\u8fd8\u539f\u5242\u3002\u53ef\u4ee5\u5b9e\u73b0\u5bf9\u7c7b\u91d1\u5c5e\u548c\u975e\u91d1\u5c5e\u542b\u91cf\u4ee5\u53ca\u4ecb\u5b54\u7eb3\u7c73\u7403\u76f4\u5f84\u7684\u6709\u6548\u8c03\u8282\u3002\u8be5\u5408\u6210\u7b56\u7565\u53ef\u6269\u5c55\u5230\u5176\u4ed6\u591a\u7ec4\u5143PdMBP\u5408\u91d1\u4ecb\u5b54\u7eb3\u7c73\u7403\u4e2d\uff0c\u6765\u4ea7\u751f\u4e0d\u540c\u79cd\u7c7b\u7684\u679d\u72b6\u4ecb\u5b54\u6846\u67b6\u3002\u7531\u4e8e\u787c\u548c\u78f7\u53ef\u4ee5\u4fc3\u8fdbPd\u8868\u9762\u542b\u6c27\u4e2d\u95f4\u7269\u8d28\u7684\u5206\u89e3\uff0c\u4e09\u5143PdBP\u5408\u91d1\u53ef\u7528\u4e8e\u52a0\u901f\u7535\u5316\u5b66\u6c27\u8fd8\u539f\uff08ORR\uff09\u548c\u9187\u6c27\u5316\u53cd\u5e94\uff08AOR\uff09\u7684\u52a8\u529b\u5b66\u3002\u4e09\u5143PdBP\u4ecb\u5b54\u7eb3\u7c73\u7403\u7684\u679d\u72b6\u4ecb\u5b54\u5f62\u8c8c\u4e5f\u52a0\u901f\u4e86\u7535\u5b50\/\u7269\u8d28\u8f6c\u79fb\uff0c\u5e76\u66b4\u9732\u51fa\u5927\u91cf\u7684\u6d3b\u6027\u4f4d\u70b9\uff0c\u8fdb\u4e00\u6b65\u52a0\u901fORR\u548cAOR\u7684\u8fdb\u884c\u3002<\/p>\n \u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n \u56fe1\uff1a\u4e09\u5143PdBP\u5408\u91d1\u4ecb\u5b54\u7eb3\u7c73\u7403\u7684\u7ec4\u5206\u548c\u7ed3\u6784\u8868\u5f81\u3002<\/p>\n (b)HAADF-STEM\u56fe\u50cf\uff1b<\/p>\n (c,d) \u9ad8\u500d\u7387\u7684TEM\u56fe\u50cf\uff1b<\/p>\n (e) \u7ed3\u6784\u793a\u610f\u56fe\uff1b<\/p>\n (f) \u9ad8\u5206\u8fa8HAADF-STEM\u56fe\u50cf\uff1b<\/p>\n (g) STEM EDS\u5143\u7d20\u5206\u5e03\uff1b<\/p>\n (h) \u76f8\u5e94\u7684\u7ebf\u626b\u63cf\u7ed3\u679c\u3002<\/p>\n \u56fe2\uff1a\u4e09\u5143PdBP\u5408\u91d1\u4ecb\u5b54\u7eb3\u7c73\u7403\u7684XRD\u8868\u5f81\u3002<\/p>\n (b)\u91d1\u5c5ePd\u4ecb\u5b54\u7eb3\u7c73\u7403\u3001\u4e8c\u5143PdB\u4ecb\u5b54\u7eb3\u7c73\u7403\u548c\u4e09\u5143PdBP\u5408\u91d1\u4ecb\u5b54\u7eb3\u7c73\u7403\u7684\u5e7f\u89d2XRD\u56fe\u8c31\u3002<\/p>\n \u56fe3\uff1a\u4e09\u5143PdBP\u5408\u91d1\u4ecb\u5b54\u7eb3\u7c73\u7403\u7684\u8868\u9762\u7535\u5b50\u6001\u3002<\/p>\n (a,b,c)\u4f9d\u6b21\u4e3a\u4e09\u5143PdBP\u5408\u91d1\u4ecb\u5b54\u7eb3\u7c73\u7403\u7684Pd 3d\uff0cB 1s, P 2p\u8f68\u9053\u7684\u9ad8\u5206\u8fa8XPS\u8c31\u7ebf\uff1b<\/p>\n (d)\u4e09\u5143PdBP\u5408\u91d1\u4ecb\u5b54\u7eb3\u7c73\u7403\u548c\u5355\u5143Pd\u4ecb\u5b54\u7eb3\u7c73\u7403\u7684\u4e00\u6c27\u5316\u78b3\u6eb6\u51fa\u4f0f\u5b89\u56fe\u50cf\u3002<\/p>\n \u56fe4\uff1a\u4e09\u5143PdBP\u5408\u91d1\u4ecb\u5b54\u7eb3\u7c73\u7403\u7684\u5f62\u6210\u673a\u7406\u548c\u679d\u72b6\u7ed3\u6784\u8c03\u63a7\u3002<\/p>\n (b,c,d) \u5206\u522b\u7528DDDAC\uff0cDODAC-2\u548cC22<\/sub>TAC\u4f5c\u4e3a\u8868\u9762\u6d3b\u6027\u5242\uff0c\u5f97\u5230\u7684PdBP\u7eb3\u7c73\u7ed3\u6784\u7684\u5178\u578bTEM\u56fe\u50cf\uff1b<\/p>\n (e,f,g) \u5408\u6210\u65f6\u5206\u522b\u52a0\u51650.05mL,0.1mL\u548c0.4mL\u6c28\u6c34\uff0c\u5f97\u5230\u4e0d\u540c\u76f4\u5f84\u7684\u4e09\u5143PdBP\u4ecb\u5b54\u7eb3\u7c73\u7403\u7684\u5178\u578bTEM\u56fe\u50cf\u3002<\/p>\n \u56fe5\uff1a\u6210\u5206\u548c\u5c3a\u5bf8\u63a7\u5236\u3002<\/p>\n (b)\u5408\u6210\u4e09\u5143PdBP\u4ecb\u5b54\u7eb3\u7c73\u7403\u671f\u95f4P\u542b\u91cf\/\u76f4\u5f84\u548cNaH2<\/sub>PO2<\/sub>\u52a0\u5165\u91cf\u4e4b\u95f4\u7684\u5173\u7cfb\u3002<\/p>\n \u56fe6\uff1a\u591a\u5143PdMBP\u5408\u91d1\u4ecb\u5b54\u7eb3\u7c73\u7403\u7684\u901a\u7528\u5236\u5907\u65b9\u6cd5\u3002<\/p>\n (a,c,e) \u4f9d\u6b21\u4e3aPdCuBP, PdAgBP\u548cPdPtBP\u4ecb\u5b54\u7eb3\u7c73\u7403\u7684TEM\u56fe\u50cf\uff1b<\/p>\n (b,d,f) \u4f9d\u6b21\u4e3aPdCuBP, PdAgBP\u548cPdPtBP\u4ecb\u5b54\u7eb3\u7c73\u7403\u7684STEM\u5143\u7d20\u5206\u5e03\u56fe\u3002<\/p>\n \u56fe7\uff1a\u4e09\u5143PdBP\u5408\u91d1\u4ecb\u5b54\u7eb3\u7c73\u7403\u7684\u7535\u50ac\u5316ORR\u6027\u80fd\u3002<\/p>\n (b)ORR\u6781\u5316\u66f2\u7ebf\uff1b<\/p>\n (c)9V\u65f6\u603b\u8d28\u91cf\u6d3b\u5ea6\u548c\u6bd4\u6d3b\u5ea6\u603b\u7ed3\uff1b<\/p>\n (d)Tafel\u659c\u7387\u56fe\u50cf\uff1b<\/p>\n (e)ORR\u6781\u5316\u66f2\u7ebf\uff0c\u5185\u63d2\u56fe\u4e3aPdBP\u4ecb\u5b54\u7eb3\u7c73\u7403\u5728\u9971\u548cO2<\/sub>\u76841M KOH\u4e2d\u8fde\u7eed50000\u6b21\u5faa\u73af\u626b\u63cf\u540e\u7684TEM\u56fe\u50cf\uff1b<\/p>\n (f)PdBP\u4ecb\u5b54\u7eb3\u7c73\u7403\u548c\u7eb3\u7c73\u9897\u7c92\u7684\u8d28\u91cf\u6d3b\u5ea6\u5bf9\u6bd4\u3002<\/p>\n \u56fe8\uff1a\u4e09\u5143PdBP\u5408\u91d1\u4ecb\u5b54\u7eb3\u7c73\u7403\u7684\u7535\u50ac\u5316AOR\u53cd\u5e94\u6027\u80fd\u8868\u73b0\u3002<\/p>\n (b)EOR\u7684\u8d28\u91cf\u6d3b\u6027\u603b\u7ed3\uff1b<\/p>\n (c)\u4e09\u5143PdBP\u4ecb\u5b54\u7eb3\u7c73\u7403\u3001PdB\u4ecb\u5b54\u7eb3\u7c73\u7403\u3001Pd\u4ecb\u5b54\u7eb3\u7c73\u7403\u3001\u5546\u7528Pt\u548cPd\u7eb3\u7c73\u9897\u7c92\u57280M KOH\u548c1.0M \u4e59\u9187\u4e2d\u7684\u8ba1\u65f6\u7535\u6d41\u66f2\u7ebf\uff1b<\/p>\n (d)\u4e09\u5143PdBP\u5408\u91d1\u4ecb\u5b54\u7eb3\u7c73\u7403\u548c\u5546\u7528Pd\u7eb3\u7c73\u9897\u7c92\u7684FOR\uff0cMOR\u548cGOR\u8d28\u91cf\u6d3b\u6027\u603b\u7ed3\u3002<\/p>\n \u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n 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(a)\u4e09\u5143PdBP\u5408\u91d1\u4ecb\u5b54\u7eb3\u7c73\u7403\u7684\u5c0f\u89d2XRD\u56fe\u6837\uff1b<\/p>\n
<\/p>\n
(a)\u8868\u9762\u6d3b\u6027\u5242\u5bfc\u5411\u7684\u81ea\u4e0b\u800c\u4e0a\u5f0f\u5408\u6210\u4e09\u5143PdBP\u5408\u91d1\u4ecb\u5b54\u7eb3\u7c73\u7403\u7684\u793a\u610f\u56fe\uff1b<\/p>\n
(a)\u901a\u8fc7\u6c28\u6c34\u52a0\u5165\u91cf\u548cDODAC\u6d53\u5ea6\u6765\u63a7\u5236\u4e09\u5143PdBP\u4ecb\u5b54\u7eb3\u7c73\u7403\u7684\u5c3a\u5bf8\uff1b<\/p>\n
<\/p>\n
(a)\u7eb3\u7c73\u50ac\u5316\u5242\u7684\u5faa\u73af\u4f0f\u5b89\u66f2\u7ebf\uff1b<\/p>\n
(a)\u4f0f\u5b89\u7279\u6027\u66f2\u7ebf\uff1b<\/p>\n