{"id":186074,"date":"2019-10-02T06:30:00","date_gmt":"2019-10-01T22:30:00","guid":{"rendered":"\/\/m.iemloyee.com\/?p=186074"},"modified":"2019-10-01T20:31:55","modified_gmt":"2019-10-01T12:31:55","slug":"%e3%80%9010-2%e5%8f%b7%e6%8e%a8%e9%80%81-%e9%a6%96%e6%8e%a8%e3%80%91%e8%bf%91%e4%b8%89%e5%b9%b4%e4%b8%8a%e8%bf%87%e9%a1%b6%e5%88%8a%e5%b0%81%e9%9d%a2%e7%9a%84%e9%94%82%e7%94%b5%e6%b1%a0%e7%a0%94","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=186074","title":{"rendered":"\u8fd1\u4e09\u5e74\u4e0a\u8fc7\u9876\u520a\u5c01\u9762\u7684\u9502\u7535\u6c60\u7814\u7a76\u6709\u54ea\u4e9b"},"content":{"rendered":"

\u4f34\u968f\u7740\u7ecf\u6d4e\u5168\u7403\u5316\u7684\u8fdb\u7a0b\u548c\u80fd\u6e90\u9700\u6c42\u7684\u4e0d\u65ad\u9ad8\u6da8\uff0c\u5bfb\u627e\u65b0\u7684\u50a8\u80fd\u88c5\u7f6e\u5df2\u7ecf\u6210\u4e3a\u65b0\u80fd\u6e90\u76f8\u5173\u9886\u57df\u7684\u5173\u6ce8\u70ed\u70b9\u3002\u9502\u79bb\u5b50\u7535\u6c60\uff08LIB\uff09\u662f\u76ee\u524d\u7efc\u5408\u6027\u80fd\u6700\u597d\u7684\u7535\u6c60\u4f53\u7cfb\uff0c\u5177\u6709\u9ad8\u6bd4\u80fd\u91cf\u3001\u9ad8\u5faa\u73af\u5bff\u547d\u3001\u4f53\u79ef\u5c0f\u3001\u8d28\u91cf\u8f7b\u3001\u65e0\u8bb0\u5fc6\u6548\u5e94\u3001\u65e0\u6c61\u67d3\u7b49\u7279\u70b9\uff0c\u5e76\u8fc5\u901f\u53d1\u5c55\u6210\u4e3a\u65b0\u4e00\u4ee3\u50a8\u80fd\u7535\u6e90\uff0c\u7528\u4e8e\u4fe1\u606f\u6280\u672f\u3001\u7535\u52a8\u8f66\u548c\u6df7\u5408\u52a8\u529b\u8f66\u3001\u822a\u7a7a\u822a\u5929\u7b49\u9886\u57df\u7684\u52a8\u529b\u652f\u6301\u3002\u9502\u7535\u6c60\u662f\u7531\u6b63\u6781\u3001\u8d1f\u6781\u3001\u7535\u89e3\u6db2\u3001\u9694\u819c\u56db\u5927\u5173\u952e\u5143\u4ef6\u7ec4\u6210\u3002\u8fd1\u51e0\u5e74\u5bf9\u9502\u7535\u6c60\u7684\u7814\u7a76\u4e5f\u662f\u5f88\u706b\u70ed\uff0c2015\u5e74\u7684\u9502\u7a7a\u7535\u6c60\u8fd8\u520a\u767b\u5728\u4e86Science\u4e0a\u3002\u4e0b\u9762\u5c31\u548c\u5927\u5bb6\u4e00\u8d77\u6765\u770b\u770b\u6700\u8fd1\u4e09\u5e74\u90fd\u6709\u54ea\u4e9b\u9502\u7535\u6c60\u7814\u7a76\u8363\u767b\u9876\u520a\u5c01\u9762\uff0c\u4e5f\u5e0c\u671b\u4e3a\u5927\u5bb6\u4ee5\u540e\u7684\u7814\u7a76\u65b9\u5411\u63d0\u4f9b\u4e00\u4e2a\u601d\u8def\u3002<\/p>\n

\u4e00\u3001\u6b63\u6781\u6750\u6599<\/b><\/strong><\/h3>\n

1.<\/b><\/strong>\u00a0Accounts of Chemical Research\uff08\u300a\u5316\u5b66\u7814\u7a76\u8ff0\u8bc4\u300b\uff09\u5c01\u9762\uff1a\u5c42\u72b6\u8fc7\u6e21\u91d1\u5c5e\u6c27\u5316\u7269\u4e2dNi\/Li\u7684\u53cd\u4f4d\u73b0\u8c61\u7684\u8d77\u6e90\u3001\u63a7\u5236\u65b9\u6cd5\u53ca\u5176\u5bf9\u7535\u5316\u5b66\u7684\u5f71\u54cd<\/b><\/strong>[<\/b><\/sup><\/strong>1<\/b><\/sup><\/strong>]<\/b><\/sup><\/strong><\/h4>\n

\u5c42\u72b6\u9502\u8fc7\u5ea6\u91d1\u5c5e\u6c27\u5316\u7269\uff0c\u7279\u522b\u662fLi\uff08NixMnyCoz\uff09O2<\/sub>\uff08NMC\uff0cx + y + z = 1\uff09\uff0c\u80fd\u91cf\u5bc6\u5ea6\u9ad8\u3001\u5bff\u547d\u957f\u3001\u6210\u672c\u4f4e\u3001\u5b89\u5168\u6027\u9ad8\uff0c\u56e0\u6b64\u662f\u6700\u6709\u5e0c\u671b\u6210\u4e3a\u6b63\u6781\u6750\u6599\u7684\u5019\u9009\u6750\u6599\u3002\u4e3a\u8fdb\u4e00\u6b65\u63d0\u9ad8\u9502\u5b58\u50a8\u5bb9\u91cf\uff0c\u4eba\u4eec\u5f00\u59cb\u5f00\u53d1\u5bcc\u954d\u7684\u5c42\u72b6\u9502\u8fc7\u6e21\u91d1\u5c5e\u6c27\u5316\u7269\u3002\u7136\u800c\u5f53\u954d\u542b\u91cf\u589e\u52a0\u5230\u4e00\u5b9a\u503c\u540eNi\/Li\u53cd\u4f4d\u5bfc\u81f4\u7ed3\u6784\u7d0a\u4e71\u4f1a\u5bf9Li\u7684\u6269\u6563\u6027\u3001\u5faa\u73af\u7a33\u5b9a\u6027\u3001\u7b2c\u4e00\u5faa\u73af\u6548\u7387\u548c\u6574\u4f53\u7535\u6781\u6027\u80fd\u4ea7\u751f\u4e0d\u5229\u5f71\u54cd\u3002\u5317\u4eac\u5927\u5b66\u6df1\u5733\u7814\u7a76\u751f\u9662\u65b0\u6750\u6599\u5b66\u9662\u6f58\u950b\u6559\u6388\u7684\u8bfe\u9898\u7ec4\u5c31\u5982\u4f55\u63a7\u5236Ni\/Li\u53cd\u4f4d\u6765\u63d0\u9ad8\u9502\u7535\u6c60\u6b63\u6781\u6750\u6599\u6027\u80fd\u505a\u4e86\u5927\u91cf\u7684\u673a\u7406\u7814\u7a76\u3002\u8fd1\u671f\u6f58\u5cf0\u6559\u6388\u53d7\u9080\u4e3a\u5316\u5b66\u9886\u57df\u8457\u540d\u7efc\u8ff0\u671f\u520a\u300a\u5316\u5b66\u7814\u7a76\u8ff0\u8bc4\u300b\u5c31\u5c42\u72b6\u8fc7\u6e21\u91d1\u5c5e\u6c27\u5316\u7269\u4e2dNi\/Li\u7684\u53cd\u4f4d\u73b0\u8c61\u7684\u8d77\u6e90\u3001\u63a7\u5236\u65b9\u6cd5\u53ca\u5176\u5bf9\u7535\u5316\u5b66\u7684\u5f71\u54cd\u64b0\u5199\u4e86\u7efc\u8ff0\u8bba\u6587\uff0c\u5e76\u5165\u9009\u4e3a\u5f53\u671f\u5c01\u9762\u6587\u7ae0\u3002<\/p>\n

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\u4e8c\u3001\u8d1f\u6781\u6750\u6599<\/b><\/strong><\/h3>\n

1<\/b><\/strong>.<\/b><\/strong>\u00a0J. Am. Chem. Soc.<\/b><\/strong>\u5c01\u9762\uff1a\u7fa7\u57fa\u5316\u805a\u567b\u5429\u4fee\u9970\u7684\u5355\u58c1\u78b3\u7eb3\u7c73\u7ba1\u4e0e\u9502\u79bb\u5b50\u7535\u6c60\u8d1f\u6781\u6750\u6599\u7684\u4fa8\u8054\u7ed3\u6784<\/b><\/strong>[<\/b><\/sup><\/strong>2<\/b><\/sup><\/strong>]<\/b><\/sup><\/strong><\/h4>\n

\u5177\u6709\u6781\u6027\u5b98\u80fd\u56e2\u7684\u5171\u8f6d\u805a\u5408\u7269\u80fd\u591f\u6709\u6548\u5730\u5c06\u5355\u58c1\u78b3\u7eb3\u7c73\u7ba1\uff08SWNT\uff09\u4fee\u9970\u5230\u9ad8\u5bb9\u91cf\u8d1f\u6781\u6750\u6599\u7684\u8868\u9762\uff0c\u5e76\u4e14\u80fd\u591f\u5f62\u6210\u7535\u6781\u7f51\u7edc\u3002\u5177\u4f53\u5730\uff0c\u805a[3-\uff084-\u4e01\u9178\u94be\uff09\u567b\u5429]\uff08PPBT\uff09\u53ef\u4ee5\u5728SWNT\u7f51\u7edc\u548c\u4e0d\u540c\u8d1f\u6781\u6750\u6599\u4e4b\u95f4\u642d\u5efa\u6865\u6881\uff0c\u5305\u62ec\u5355\u5206\u6563\u7684Fe3<\/sub>O4<\/sub>\u7403\u548cSi\u7eb3\u7c73\u9897\u7c92\u3002 PPBT\u7684\u03c0-\u5171\u8f6d\u9aa8\u67b6\u548c\u7fa7\u9178\u916f\uff08COO-\uff09\u53d6\u4ee3\u7684\u70f7\u57fa\u4fa7\u94fe\u5206\u522b\u5438\u5f15SWNT\u03c0-\u7535\u5b50\u8868\u9762\u5e76\u4e0e\u6d3b\u6027\u6750\u6599\u8868\u9762\u7f9f\u57fa\uff08-OH\uff09\u7269\u8d28\u53d1\u751f\u5316\u5b66\u76f8\u4e92\u4f5c\u7528\u4ee5\u5f62\u6210\u7fa7\u9178\u916f\u952e\u3002\u8fd9\u79cd\u7ed3\u6784\u80fd\u591f\u6709\u6548\u5730\u6355\u83b7\u7531\u4e8e\u5728\u5145\u653e\u7535\u91cd\u590d\u5faa\u73af\u8fc7\u7a0b\u4e2d\u53d1\u751f\u7684\u6d3b\u6027\u6750\u6599\u4f53\u79ef\u53d8\u5316\u800c\u5f62\u6210\u7684\u88c2\u7f1d\/\u7c89\u788e\u7684\u9897\u7c92\uff0c\u4ece\u800c\u53ef\u4ee5\u6291\u5236\u7535\u6781\u539a\u5ea6\u7684\u53d8\u5316\uff0c\u5f62\u6210\u7a33\u5b9a\u7684SEI\u5c42\uff0c\u964d\u4f4e\u7535\u6781\u7535\u963b\uff0c\u5927\u5927\u6539\u5584\u9502\u79bb\u5b50\u7535\u6c60\u7684\u7535\u5316\u5b66\u6027\u80fd\u3002<\/p>\n

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2<\/b><\/strong>.<\/b><\/strong>\u00a0Angew. Chem. Int. Ed.<\/b><\/strong>\u5c01\u9762\uff1a\u77f3\u58a8\u70ef\u4e2d\u5f15\u5165\u63ba\u6c2e\u4f4d\u70b9\u5236\u5907\u4eb2\u9502\u5bfc\u7535\u9aa8\u67b6<\/b><\/strong>[<\/b><\/sup><\/strong>3<\/b><\/sup><\/strong>]<\/b><\/sup><\/strong><\/h4>\n

\u9502\u91d1\u5c5e\u662f\u4e0b\u4e00\u4ee3\u53ef\u5145\u7535\u7535\u6c60\u7684\u5173\u952e\u8d1f\u6781\u6750\u6599\u4e4b\u4e00\uff0c\u7136\u800c\u9502\u679d\u6676\u963b\u788d\u9502\u91d1\u5c5e\u8d1f\u6781\u7684\u5b9e\u9645\u5e94\u7528\u3002\u6e05\u534e\u5927\u5b66\u7684\u5f20\u5f3a\u6559\u6388\u91c7\u7528\u6c2e\u63ba\u6742\u7684\u77f3\u58a8\u70ef\u4f5c\u4e3aLi\u7535\u9540\u57fa\u4f53\uff0c\u4ee5\u8c03\u8282Li\u91d1\u5c5e\u6210\u6838\u5e76\u6291\u5236\u679d\u6676\u7684\u751f\u957f\u3002\u542bN\u7684\u5b98\u80fd\u56e2\uff0c\u4f8b\u5982N-\u63ba\u6742\u77f3\u58a8\u70ef\u4e2d\u7684\u5421\u5576\u548c\u5421\u54af\u6c2e\uff0c\u662f\u4eb2\u9502\u6027\u7684\uff0c\u5176\u5f15\u5bfc\u91d1\u5c5eLi\u6210\u6838\uff0c\u5747\u5300\u5730\u5206\u5e03\u5728\u8d1f\u6781\u8868\u9762\u4e0a\u3002\u7814\u7a76\u8bc1\u660e\uff0cN\u63ba\u6742\u7684\u77f3\u58a8\u70ef\u7528\u4e8eLi\u91d1\u5c5e\u8d1f\u6781\u4e2d\uff0c\u5728\u91cd\u590d\u7684\u5145\u653e\u7535\u8fc7\u7a0b\u4e2d\u65e0\u9502\u679d\u6676\u751f\u957f\uff0c\u5e76\u4e14\u5728\u63a5\u8fd1200\u4e2a\u5faa\u73af\u540e\u8868\u73b0\u51fa98\uff05\u7684\u9ad8\u5e93\u4ed1\u6548\u7387\u3002<\/p>\n

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3<\/b><\/strong>. <\/b><\/strong>Small<\/b><\/strong>\u5c01\u9762\uff1a\u9ad8\u6027\u80fd\u94a0\/\u9502\u79bb\u5b50\u7535\u6c60\u7528\u6838\u58f3\u7ed3\u6784<\/b><\/strong>Co<\/b><\/strong>9<\/b><\/sub><\/strong>S<\/b><\/strong>8<\/b><\/sub><\/strong>\/MoS<\/b><\/strong>2<\/b><\/sub><\/strong>\u8d1f\u6781\u6750\u6599<\/b><\/strong>[<\/b><\/sup><\/strong>4<\/b><\/sup><\/strong>]<\/b><\/sup><\/strong><\/h4>\n

\u6587\u7ae0\u4e2d\uff0cQingyu\u00a0Yan\u548cGu\u00a0Hongwei\u7b49\u4eba\u901a\u8fc7\u7b80\u4fbf\u7684\u9014\u5f84\u5408\u6210\u4e86\u5c3a\u5bf8\u5747\u5300\u7684Co9<\/sub>S8<\/sub>\/MoS2<\/sub>\u6838\u58f3\u7ed3\u6784\uff0c\u5e73\u5747\u76f4\u5f84\u7ea6500nm\u3002\u4e24\u76f8\u4e4b\u95f4\u7684\u534f\u540c\u4f5c\u7528\u63d0\u9ad8\u4e86\u7535\u5b50\u8f93\u9001\u901f\u5ea6\u548cLi+<\/sup>\/Na+<\/sup>\u4f20\u8f93\u52a8\u529b\u5b66\u3002\u5c06Co9<\/sub>S8<\/sub>\/MoS2<\/sub>\u590d\u5408\u6750\u6599\u505a\u6210\u7535\u6c60\u8d1f\u6781\u6750\u6599\uff0c\u9502\/\u94a0\u79bb\u5b50\u7535\u6c60\u5177\u6709\u9ad8\u6bd4\u5bb9\u91cf\u548c\u826f\u597d\u7684\u500d\u7387\u6027\u80fd\u53ca\u5faa\u73af\u7a33\u5b9a\u6027\u3002<\/p>\n

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4<\/b><\/strong>.<\/b><\/strong>\u00a0Adv. Mater.<\/b><\/strong>\u5c01\u9762\uff1a\u9ad8\u6027\u80fd\u9502\u79bb\u5b50\u7535\u6c60\u7528\u53cc\u529f\u80fd\u5316\u53cc\u78b3\u58f3\u5305\u8986\u7845\u7eb3\u7c73\u9897\u7c92<\/b><\/strong>[<\/b><\/sup><\/strong>5<\/b><\/sup><\/strong>]<\/b><\/sup><\/strong><\/h4>\n

\u4e3a\u4e86\u89e3\u51b3\u7845\u4f5c\u9502\u79bb\u5b50\u7535\u6c60\u8d1f\u6781\u6750\u6599\u65f6\u5728\u5145\u653e\u7535\u8fc7\u7a0b\u4e2d\u4ea7\u751f\u7684\u5de8\u5927\u7684\u4f53\u79ef\u53d8\u5316\u548c\u4e0d\u7a33\u5b9a\u7684SEI\u754c\u9762\u800c\u5f15\u8d77\u7684\u4e25\u91cd\u7684\u7535\u6781\u7c89\u788e\uff0c\u4e2d\u56fd\u79d1\u5b66\u6280\u672f\u5927\u5b66\u7684Prof. Yan Yu\u7b49\u4eba\u63d0\u51fa\u4e00\u79cd\u201c\u53cc\u58f3\u201d\u6982\u5ff5\uff0c\u5236\u5907\u4e86\u53cc\u78b3\u58f3\u5305\u8986\u7684\u7845\u7eb3\u7c73\u9897\u7c92\uff08DCS-Si\uff09\uff0c\u8d77\u5230\u5c01\u88c5\u7845\u7684\u4f53\u79ef\u53d8\u5316\u548c\u7a33\u5b9aSEI\u5c42\u7684\u53cc\u91cd\u4f5c\u7528\u3002\u5185\u90e8\u7684\u78b3\u58f3\u53ef\u4ee5\u63d0\u4f9b\u7a7a\u9699\u4ece\u800c\u5141\u8bb8\u5185\u90e8\u7684Si\u7eb3\u7c73\u9897\u7c92\u7684\u4f53\u79ef\u53d8\u5316\uff0c\u800c\u9759\u6001\u5916\u58f3\u53ef\u4ee5\u4fc3\u8fdb\u5f62\u6210\u7a33\u5b9a\u7684SEI\u5c42\u3002\u6700\u91cd\u8981\u7684\u662f\uff0c\u5982\u6b64\u8bbe\u8ba1\u65e2\u4fdd\u7559\u4e86\u58f3\u95f4\u7a7a\u95f4\u7f13\u51b2\u4f53\u79ef\u53d8\u5316\u53c8\u80fd\u591f\u51cf\u8f7b\u6765\u81ea\u78b3\u58f3\u7684\u673a\u68b0\u5e94\u529b\u3002DCS-Si\u5236\u5907\u7684\u9502\u7535\u6c60\u57280.2C\u7684\u7535\u6d41\u5bc6\u5ea6\u4e0b\u8868\u73b0\u51fa1802mAh\/g\u7684\u6bd4\u5bb9\u91cf\uff0c\u5177\u6709\u4f18\u5f02\u7684\u500d\u7387\u6027\u80fd\u548c\u5faa\u73af\u6027\u80fd\u3002<\/p>\n

\"\"<\/p>\n

5<\/b><\/strong>.<\/b><\/strong>\u00a0Adv. Energy Mater.<\/b><\/strong>\u5c01\u9762\uff1a\u9ad8\u6027\u80fd\u9502\u79bb\u5b50\u7535\u6c60\u7528\u7845\u7eb3\u7c73\u5c42\u5d4c\u5165\u77f3\u58a8\u7684\u6df7\u5408\u8d1f\u6781<\/b><\/strong>[<\/b><\/sup><\/strong>6<\/b><\/sup><\/strong>]<\/b><\/sup><\/strong><\/h4>\n

\u00a0\u7845\u56e0\u5176\u9ad8\u5bb9\u91cf\u6210\u4e3a\u6700\u5177\u6709\u5e0c\u671b\u7684\u9502\u79bb\u5b50\u7535\u6c60\u8d1f\u6781\uff0c\u7136\u800c\u5176\u6613\u8106\u6027\u3001\u9ad8\u4f53\u79ef\u81a8\u80c0\u3001\u4f4e\u5bfc\u7535\u7387\u3001\u8f83\u96be\u7684\u7535\u6781\u538b\u5ef6\u5de5\u827a\u4ee5\u53ca\u5bf9\u8fc7\u91cf\u7c98\u5408\u5242\u548c\u5bfc\u7535\u5242\u7684\u9700\u6c42\u963b\u788d\u4e86\u7845\u8d1f\u6781\u7684\u5b9e\u9645\u5e94\u7528\u3002\u56e0\u6b64\u4eba\u4eec\u5c06Si\u548c\u77f3\u58a8\u8fdb\u884c\u6df7\u5408\u4f5c\u4e3a\u9502\u7535\u6c60\u8d1f\u6781\u4f7f\u7528\u3002\u97e9\u56fd\u7684Prof. Minseong Ko\u548cJaephil Cho\u7b49\u4eba\u5c06Si\u7eb3\u7c73\u5c42\u5d4c\u5165\u77f3\u58a8\/\u78b3\u6750\u6599\u4e2d\uff0c\u5e76\u4e0e\u5546\u7528\u7535\u6781\u8fdb\u884c\u5bf9\u6bd4\u3002\u77f3\u58a8\/\u78b3\u4e0e\u4f20\u7edf\u77f3\u58a8\u4e4b\u95f4\u5177\u6709\u826f\u597d\u7684\u76f8\u5bb9\u6027\u548c\u7ed3\u6784\u7279\u5f81\uff0c\u53ef\u6709\u6548\u63d0\u9ad8\u9502\u79bb\u5b50\u7535\u6c60\u7845\u57fa\u8d1f\u6781\u6750\u6599\u6027\u80fd\u3002<\/p>\n

\"\"<\/p>\n

\u4e09\u3001\u7535\u89e3\u6db2<\/b><\/strong><\/h3>\n

1<\/b><\/strong>.<\/b><\/strong>\u00a0Batteries <\/b><\/strong>&<\/b><\/strong>\u00a0Supercaps<\/b><\/strong>\u5c01\u9762\uff1a\u9502\u7535\u6c60\u7535\u89e3\u6db2\u4e2d\u7684\u6eb6\u5242\u5316\u4f5c\u7528<\/b><\/strong>[<\/b><\/sup><\/strong>7<\/b><\/sup><\/strong>]<\/b><\/sup><\/strong><\/h4>\n

\u7535\u89e3\u6db2\u6eb6\u5242\u5316\u662f\u5f71\u54cd\u9502\u79bb\u5b50\u5728\u7535\u89e3\u8d28\u4e2d\u7684\u6269\u6563\uff0c\u6b63\u8d1f\u6781\u4e0e\u7535\u89e3\u6db2SEI\u7684\u5f62\u6210\u4ee5\u53caLi\u79bb\u5b50\u5728\u7535\u6781\u8868\u9762\u5d4c\u5165\u548c\u8131\u5d4c\u7684\u91cd\u8981\u56e0\u7d20\u3002\u6e05\u534e\u5927\u5b66\u7684\u5f20\u5f3a\u6559\u6388\u56e2\u961f\u4e0b\u7684\u9648\u7fd4\u535a\u58eb\u901a\u8fc7\u5bc6\u5ea6\u6cdb\u51fd\u7406\u8bba\u8ba1\u7b97\u7814\u7a76\u4e86\u79bb\u5b50-\u6eb6\u5242\uff0c\u79bb\u5b50-\u79bb\u5b50\u548c\u6eb6\u5242-\u6eb6\u5242\u4e4b\u95f4\u7684\u76f8\u4e92\u4f5c\u7528\u3002\u6eb6\u5242\u5316\u6548\u5e94\u53ef\u4ee5\u663e\u8457\u964d\u4f4e\u4e0a\u8ff0\u4e09\u79cd\u76f8\u4e92\u4f5c\u7528\u3002\u901a\u8fc7\u5c06\u785d\u9178\u9502\u6eb6\u89e3\u5728\u4e0d\u540c\u6eb6\u5242\u4e2d\uff0c\u8fdb\u4e00\u6b65\u63a2\u7d22\u4e86Li\u76d0\u5728\u7535\u89e3\u8d28\u4e2d\u7684\u6eb6\u89e3\u884c\u4e3a\u5e76\u8fdb\u884c\u4e86\u5b9e\u9a8c\u9a8c\u8bc1\u3002\u8fd9\u9879\u5de5\u4f5c\u63d0\u4f9b\u4e86\u5bf9\u7535\u89e3\u6db2\u5fae\u89c2\u6eb6\u5242\u5316\u4f5c\u7528\u7684\u7406\u8bba\u8ba1\u7b97\uff0c\u5e76\u7a81\u51fa\u4e86\u7535\u89e3\u6db2\u6eb6\u5242\u5316\u5728\u8c03\u8282\u7535\u6c60\u6027\u80fd\u4e2d\u7684\u91cd\u8981\u4f5c\u7528\uff0c\u4e3a\u9ad8\u6027\u80fd\u7535\u6c60\u7684\u65b0\u578b\u7535\u89e3\u6db2\u8bbe\u8ba1\u63d0\u4f9b\u4e86\u601d\u8def\u3002<\/p>\n

\"\"<\/p>\n

2.<\/b><\/strong>\u00a0Angew. Chem. Int. Ed.<\/b><\/strong>\u5c01\u9762\uff1a\u4e00\u79cd\u9ad8\u6027\u80fd\u590d\u5408\u805a\u5408\u7269\u9502\u79bb\u5b50\u7535\u6c60\u7535\u89e3\u6db2\u7528\u4e09\u7ef4\u7eb3\u7c73\u7ed3\u6784\u6c34\u51dd\u80f6\u9aa8\u67b6<\/b><\/strong>[<\/b><\/sup><\/strong>8<\/b><\/sup><\/strong>]<\/b><\/sup><\/strong><\/h4>\n

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\"\"<\/p>\n

3.<\/b><\/strong>\u00a0Nature Energy<\/b><\/strong>\u5c01\u9762\uff1a\u7528\u4e8e\u5b89\u5168\u7535\u6c60\u7684\u963b\u71c3\u6709\u673a\u7535\u89e3\u6db2<\/b><\/strong>[<\/b><\/sup><\/strong>9<\/b><\/sup><\/strong>]<\/b><\/sup><\/strong><\/h4>\n

\u4e25\u91cd\u7684\u5b89\u5168\u95ee\u9898\u963b\u788d\u4e86\u9502\u7535\u6c60\u7684\u5927\u89c4\u6a21\u4f7f\u7528\u3002\u5e38\u89c4\u7684\u7535\u89e3\u6db2\u662f\u9ad8\u5ea6\u6613\u71c3\u548c\u6613\u6325\u53d1\u7684\uff0c\u6613\u5f15\u8d77\u707e\u96be\u6027\u7684\u706b\u707e\u6216\u7206\u70b8\uff0c\u6240\u4ee5\u4eba\u4eec\u60f3\u5230\u5c06\u963b\u71c3\u5242\u5f15\u5165\u7535\u89e3\u6db2\u4e2d\uff0c\u7136\u800c\u963b\u71c3\u5242\u7684\u52a0\u5165\u4e0d\u9002\u5f53\u5730\u949d\u5316\u78b3\u8d1f\u6781\u800c\u5bfc\u81f4\u7535\u6c60\u6027\u80fd\u53d7\u635f\u3002\u65e5\u672c\u4e1c\u4eac\u5927\u5b66\u7684Atsuo\u00a0Yamada\u7b49\u4eba\u8bbe\u8ba1\u4e86\u4e00\u79cd\u6d53\u7f29\u76d0\u7535\u89e3\u6db2\uff0c\u901a\u8fc7\u5728\u8d1f\u6781\u4e0a\u81ea\u53d1\u5f62\u6210\u575a\u56fa\u7684\u65e0\u673a\u949d\u5316\u819c\u6765\u89e3\u51b3\u8fd9\u4e00\u96be\u9898\u3002\u5b9e\u9a8c\u8bc1\u660e\u4f7f\u7528\u76d0\u548c\u5e38\u7528\u7684\u963b\u71c3\u5242\uff08\u78f7\u9178\u4e09\u7532\u916f\uff09\u7684\u6d53\u7f29\u7535\u89e3\u76d0\uff0c\u4e0d\u6dfb\u52a0\u5176\u5b83\u6dfb\u52a0\u5242\u6216\u8f6f\u7c98\u5408\u5242\uff0c\u5c31\u53ef\u4ee5\u4f7f\u8d1f\u6781\u7a33\u5b9a\u5145\u653e\u7535\u5faa\u73af\u6b21\u6570\u8d85\u8fc71000\u6b21\uff08\u8d85\u8fc7\u4e00\u5e74\uff09\uff0c\u5faa\u73af\u6027\u80fd\u4e0e\u4f20\u7edf\u7684\u6613\u71c3\u78b3\u9178\u76d0\u7535\u89e3\u6db2\u65d7\u9f13\u76f8\u5f53\u751a\u81f3\u6bd4\u4f20\u7edf\u7684\u7535\u89e3\u6db2\u66f4\u597d\u3002\u6d53\u7f29\u7535\u89e3\u6db2\u7684\u949d\u5316\u7279\u6027\u52a0\u4e0a\u5176\u706d\u706b\u7279\u6027\u6709\u52a9\u4e8e\u5f00\u53d1\u5b89\u5168\u548c\u6301\u4e45\u7684\u9502\u7535\u6c60\uff0c\u4ece\u800c\u5f00\u53d1\u51fa\u66f4\u9ad8\u80fd\u91cf\u5bc6\u5ea6\u7684\u7535\u6c60\u7684\u3002<\/p>\n

\"\"<\/p>\n

\u56db\u3001S<\/b><\/strong>EI\u819c<\/b><\/strong><\/h3>\n

1<\/b><\/strong>.<\/b><\/strong>\u00a0Chem. Commun.<\/b><\/strong>\u5c01\u9762\uff1a\u56fa\u6001\u9502\u7535\u6c60\u4e2d\u9897\u7c92\u5927\u5c0f\u5bf9\u79bb\u5b50\u4f20\u8f93\u6027\u80fd\u7684\u5f71\u54cd<\/b><\/strong>[<\/b><\/sup><\/strong>10<\/b><\/sup><\/strong>]<\/b><\/sup><\/strong><\/h4>\n

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\"\"<\/p>\n

2<\/b><\/strong>.<\/b><\/strong>\u00a0Angew. Chem. Int. Ed.<\/b><\/strong>\u5c01\u9762\uff1a\u6784\u5efa\u6709\u673a\/\u65e0\u673a\u6742\u5316S<\/b><\/strong>EI\u819c<\/b><\/strong>\uff0c\u5b9e\u73b0\u53ef\u5145\u7535\u91d1\u5c5e\u7535\u6c60\u7684\u5feb\u901f\u754c\u9762\u4f20\u8f93<\/b><\/strong>[<\/b><\/sup><\/strong>11<\/b><\/sup><\/strong>]<\/b><\/sup><\/strong><\/h4>\n

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3.<\/b><\/strong>\u00a0<\/b><\/strong>Angew. Chem. Int. Ed.<\/b><\/strong>\u5c01\u9762\uff1a\u7528\u4e8e\u957f\u5bff\u547d\u9502\u91d1\u5c5e\u8d1f\u6781\u7684\u67d4\u6027S<\/b><\/strong>EI\u819c<\/b><\/strong>[<\/b><\/sup><\/strong>12<\/b><\/sup><\/strong>]<\/b><\/sup><\/strong><\/h4>\n

\u91d1\u5c5e\u9502\u56e0\u5176\u9ad8\u80fd\u91cf\u5bc6\u5ea6\u800c\u88ab\u4f5c\u4e3a\u8d1f\u6781\u6750\u6599\uff0c\u4f46\u9502\u8d1f\u6781\u5728\u5145\u653e\u7535\u7684\u5faa\u73af\u8fc7\u7a0b\u4e2d\u4e0d\u7a33\u5b9a\u7684SEI\u819c\u5c31\u4f1a\u88ab\u7834\u574f\uff0c\u5bfc\u81f4\u526f\u53cd\u5e94\u7684\u53d1\u751f\u548cLi\u679d\u6676\u7684\u751f\u957f\u3002\u90ed\u7389\u56fd\u56e2\u961f\u8bbe\u8ba1\u4e86\u4e00\u79cd\u9ad8\u5f39\u6027\u7684\u667a\u80fd\u9502\u805a\u4e19\u70ef\u9178\uff08LiPAA\uff09SEI\u819c\uff0c\u901a\u8fc7\u81ea\u9002\u5e94\u754c\u9762\u6765\u8c03\u63a7\u9502\u7684\u5d4c\u5165\u548c\u8131\u5d4c\u8fc7\u7a0b\uff0c\u5e76\u7528\u539f\u4f4dAFM\u8bc1\u660e\u4e86\u8fd9\u4e2a\u8fc7\u7a0b\u3002LiPAA\u805a\u5408\u7269\u5177\u6709\u9ad8\u7c98\u5408\u6027\u80fd\u548c\u4f18\u5f02\u7684\u7a33\u5b9a\u6027\uff0c\u4f7f\u5f97\u667a\u80fdSEI\u819c\u53ef\u663e\u8457\u51cf\u5c11\u526f\u53cd\u5e94\u5e76\u5927\u5927\u63d0\u9ad8\u7535\u6c60\u5b89\u5168\u6027\u3002\u5728\u9502\u5bf9\u79f0\u7535\u6c60\u4e2d\u53ef\u5b9e\u73b0700\u5c0f\u65f6\u7684\u7a33\u5b9a\u5faa\u73af\u3002\u81ea\u9002\u5e94SEI\u7684\u521b\u65b0\u8bbe\u8ba1\u53ef\u4ee5\u62d3\u5c55\u91d1\u5c5eLi\u8d1f\u6781\u5728\u7535\u6c60\u4e2d\u7684\u5e94\u7528\u3002<\/p>\n

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\u4e94\u3001\u53c2\u8003\u6587\u732e<\/b><\/strong><\/h3>\n
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  2. Y. H. Kwon, K. Minnici, J. J. Park et al. SWNT Anchored with Carboxylated Polythiophene \u201cLinks\u201d on High-Capacity Li-Ion Battery Anode Materials. J. Am. Chem. Soc.<\/i><\/em>, 2018<\/b><\/strong>, 140, 5666-5669.<\/li>\n
  3. R. Zhang, X. Chen, X. Chen, et al. Lithiophilic Sites in Doped Graphene Guide Uniform Lithium Nucleation for Dendrite-Free Lithium Metal Anodes.Angew. Chem. Int. Ed.<\/i><\/em>\uff0c2017<\/b><\/strong>, 56, 5633.<\/li>\n
  4. H. B. Geng, J. Yang, Z. F. Dai, et al. Na\/Li-Ion Batteries: Co9<\/sub>S8<\/sub>\/MoS2<\/sub>Yolk\u2013Shell Spheres for Advanced Li\/Na Storage. Small, 2017<\/b><\/strong>, 26, 3349-3358.<\/li>\n
  5. S. Q. Chen,\u00a0L. F. Shen,\u00a0Peter A. van Akenet al.\u00a0Dual\u2010Functionalized Double Carbon Shells Coated Silicon Nanoparticles for High Performance Lithium\u2010Ion Batteries.\u00a0Adv. Mater.<\/i><\/em>\uff0c2017<\/b><\/strong>\uff0c29, 1605650.<\/li>\n
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  12. N. W. Li, Y. Shi, Y. X. Yin et al. A Flexible Solid Electrolyte Interphase Layer for Long-Life Lithium Metal Anodes. Angew. Chem. Int. Ed.<\/i><\/em>\uff0c2018<\/b><\/strong>, 57, 1505-1509.<\/li>\n<\/ol>\n

    \u672c\u6587\u7531April<\/strong>\u4f9b\u7a3f\u3002<\/p>\n

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