{"id":186047,"date":"2019-09-23T09:34:58","date_gmt":"2019-09-23T01:34:58","guid":{"rendered":"\/\/m.iemloyee.com\/?p=186047"},"modified":"2019-10-18T18:25:13","modified_gmt":"2019-10-18T10:25:13","slug":"%e5%bd%ad%e6%85%a7%e8%83%9cangew-%ef%bc%9a%e4%ba%b2%e9%92%a0%e6%80%a7%e7%95%8c%e9%9d%a2%e8%b0%83%e6%8e%a7%e9%ab%98%e5%ae%b9%e9%87%8f%e3%80%81%e8%b6%85%e9%ab%98%e7%a8%b3%e5%ae%9a%e6%80%a7%e9%87%91","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=186047","title":{"rendered":"\u5f6d\u6167\u80dcAngew.\uff1a\u4eb2\u94a0\u6027\u754c\u9762\u8c03\u63a7\u9ad8\u5bb9\u91cf\u3001\u8d85\u9ad8\u7a33\u5b9a\u6027\u91d1\u5c5e\u94a0\u7535\u6c60"},"content":{"rendered":"

\u5f6d\u6167\u80dc<\/strong>Angew.<\/strong>\uff1a\u4eb2\u94a0\u6027\u754c\u9762\u8c03\u63a7\u9ad8\u5bb9\u91cf\u3001\u8d85\u9ad8\u7a33\u5b9a\u6027\u91d1\u5c5e\u94a0<\/strong><\/a>\u7535\u6c60<\/p>\n

\u3010\u7814\u7a76\u80cc\u666f\u3011<\/strong><\/p>\n

\u91d1\u5c5e\u94a0\uff08Na\uff09\u56e0\u5176\u7406\u8bba\u5bb9\u91cf\u9ad8\uff081166 mAh g-1<\/sup>\uff09\u800c\u88ab\u8ba4\u4e3a\u662f\u53ef\u5145\u5f0f\u9ad8\u80fd\u7535\u6c60\u6700\u5177\u5438\u5f15\u529b\u7684\u8d1f\u6781\u6750\u6599\u4e4b\u4e00\u3002\u8f83\u4f4e\u7684\u6c27\u5316\u8fd8\u539f\u7535\u4f4d\uff082.714 V vs\u6807\u51c6\u6c22\u7535\u6781\uff09\u548c\u6bd4\u91d1\u5c5e\u9502\uff08Li\uff09\u66f4\u9ad8\u7684\u4e30\u5ea6\u3002\u7136\u800c\uff0c\u7531\u4e8e\u4e0d\u5747\u5300\u6c89\u79ef\u800c\u5f62\u6210\u7684\u94a0\u679d\u6676\u4f1a\u964d\u4f4e\u5faa\u73af\u7a33\u5b9a\u6027\u5dee\u7684\u6d3b\u6027\u94a0\u7684\u5229\u7528\u7387\uff0c\u66f4\u91cd\u8981\u7684\u662f\uff0c\u5bfc\u81f4\u5185\u90e8\u77ed\u8def\u5bf9\u70ed\u5931\u63a7\u548c\u706b\u707e\u5371\u9669\u7684\u5a01\u80c1\u3002\u56e0\u6b64\uff0c\u94a0\u679d\u6676\u53ca\u5176\u76f8\u5173\u95ee\u9898\u4e25\u91cd\u963b\u788d\u4e86\u94a0\u91d1\u5c5e\u7535\u6c60\u5982\u94a0\u7a7a\u6c14\u7535\u6c60\u548c\u5ba4\u6e29\u94a0\u786b\u7535\u6c60\u7684\u5b9e\u9645\u5e94\u7528\u3002<\/p>\n

\u4e3a\u89e3\u51b3\u8fd9\u4e9b\u95ee\u9898\uff0c\u8fd1\u5e74\u6765\uff0c\u901a\u8fc7\u91c7\u7528\u5404\u79cd\u7b56\u7565\uff0c\u5305\u62ec\u4eba\u5de5\u56fa\u4f53\u7535\u89e3\u8d28\u754c\u9762\uff08SEI\uff09\u3001\u7535\u89e3\u8d28\u6dfb\u52a0\u5242\u3001\u56fa\u6001\u7535\u89e3\u8d28\u3001\u548c\u7eb3\u7c73\u7ed3\u6784Na\u9633\u6781\u7b49\uff0c\u53d6\u5f97\u4e86\u91cd\u5927\u8fdb\u5c55\u3002\u8fd9\u4e9b\u7b56\u7565\u4e3b\u8981\u96c6\u4e2d\u5728\u5df2\u5f62\u6210\u7684\u94a0\u9540\u5c42\u5f62\u6001\uff0c\u5373\u94a0\u679d\u6676\uff0c\u800c\u8f83\u5c11\u6d89\u53ca\u521d\u59cb\u7684\u94a0\u6c89\u79ef\u884c\u4e3a\uff0c\u5305\u62ec\u6210\u6838\u3002\u7136\u800c\uff0c\u6700\u7ec8\u7684\u94a0\u5f62\u6001\u663e\u8457\u5730\u53d6\u51b3\u4e8e\u521d\u59cb\u6210\u6838\u884c\u4e3a\uff0c\u7279\u522b\u662f\u53d6\u51b3\u4e8e\u9700\u8981\u9ad8\u9762\u79ef\u5bb9\u91cf\u7684\u5b9e\u9645\u5e94\u7528\uff08\u4f8b\u5982\uff0c10 mAh cm-2<\/sup>\uff09\u901a\u8fc7\u5728\u7535\u6d41\u6536\u96c6\u5668\u4e2d\u5f15\u5165\u6742\u539f\u5b50\uff08\u5982N\u548cS\uff09\u6765\u6539\u5584Na\/Li\u6210\u6838\u8fc7\u7a0b\uff0c\u540c\u65f6\u5c48\u670d\u9633\u6781\u663e\u793a\u51fa\u6709\u9650\u7684\u5bb9\u91cf\u3002\u56e0\u6b64\uff0cNa\u9633\u6781\u5728\u9ad8\u5faa\u73af\u4e0b\u901a\u5e38\u8868\u73b0\u51fa\u975e\u5e38\u5dee\u7684\u7a33\u5b9a\u6027\u533a\u57df\u5bb9\u91cf\u3002\u867d\u7136\u6709\u4e00\u4e9b\u5173\u4e8e\u94a0\u9633\u6781\u5faa\u73af\u5bff\u547d>1000 h\u7684\u62a5\u9053\uff0c\u4f46\u8fd9\u4e9b\u9ad8\u7a33\u5b9a\u6027\u4ec5\u5728\u94a0\u9762\u79ef\u5bb9\u91cf\u975e\u5e38\u4f4e\uff08<2mAh cm-2<\/sup>\uff09\u65f6\u5b9e\u73b0\u3002\u636e\u6211\u4eec\u6240\u77e5\uff0c\u9884\u671f\u9762\u79ef\u5bb9\u91cf\u226510mAh cm-2<\/sup>\u7684Na\u9633\u6781\u7684\u7a33\u5b9a\u5faa\u73af\uff08>1000 h\uff09\u4ece\u672a\u62a5\u9053\u8fc7\u3002\u56e0\u6b64\uff0c\u5982\u4f55\u6709\u6548\u5730\u5229\u7528\u9ad8\u5bb9\u91cf\u7684Na\u6765\u5236\u5907\u7a33\u5b9a\u7684\u9633\u6781\u5177\u6709\u91cd\u8981\u7684\u610f\u4e49\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u00a0 <\/strong>\u8fd1\u65e5\uff0c\u590d\u65e6\u5927\u5b66\u5f6d\u6167\u80dc\u6559\u6388\uff08\u901a\u8baf\u4f5c\u8005\uff09\u548c\u738b\u5175\u6770\u526f\u7814\u7a76\u5458<\/strong>\u5728\u94a0\u91d1\u5c5e\u7535\u6c60\u9886\u57df\u53d6\u5f97\u91cd\u5927\u8fdb\u5c55\uff0c\u5176\u6210\u679c\u53d1\u8868\u5728\u9876\u7ea7\u671f\u520aAngew. Chem. Int. Edit. <\/strong>\u6587\u7ae0\u9898\u76ee\u4e3a\u201cSodiophilic interphase mediated, dendrite-free anode with ultrahigh specific capacity for sodium-metal batteries\u201d\u3002\u8be5\u6587\u7ae0\u62a5\u9053\u4e86\u4e00\u79cd\u57fa\u4e8e\u6c27\u5b98\u80fd\u5316\u78b3\u7eb3\u7c73\u7ba1\u7f51\u7edc\u7684\u4eb2\u94a0\u754c\u9762\uff0c\u8be5\u754c\u9762\u540c\u65f6\u4fc3\u8fdb\u4e86\u94a0\u7684\u5747\u5300\u6210\u6838\u548c\u65e0\u679d\u6676\u7684\u6a2a\u5411\u751f\u957f\u884c\u4e3a\u3002\u8fd9\u4e00\u55dc\u94a0\u754c\u9762\u76f8\u4f7f\u4ea7\u751f\u7684\u94a0\u9633\u6781\u5177\u67091078 mAh g-1<\/sup>\u7684\u8d85\u9ad8\u5bb9\u91cf\uff0810 mAh cm-2<\/sup>\u7684\u9762\u79ef\u5bb9\u91cf\uff09\uff0c\u63a5\u8fd1\u7eaf\u94a01166 mAh g-1<\/sup>\u7684\u7406\u8bba\u5bb9\u91cf\uff0c\u4ee5\u53ca\u957f\u8fbe3000\u4e2a\u5faa\u73af\u7684\u957f\u5faa\u73af\u5bff\u547d\u3002<\/p>\n

\u3010\u56fe\u6587\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u56fe<\/strong>1 <\/strong>\u4f20\u7edf\u94dc\u57fa\u5e95\u4e0a\u94a0\u6c89\u79ef\u8fc7\u7a0b\u53ca\u78b3\u7eb3\u7c73\u7ba1\u7f51\u7edc\u7684\u55dc\u94a0\u6027\u793a\u610f\u56fe<\/strong><\/p>\n

\"\"<\/p>\n

a. \u5728\u4f20\u7edf\u7684\u57fa\u5e95\uff08\u5982\u94dc\u7b94\uff09\u4e0a\uff0c\u94a0\u79bb\u5b50\u96c6\u4e2d\u5728\u968f\u673a\u5206\u5e03\u7684\u7a81\u8d77\u6216\u7f3a\u9677\u4e0a\uff0c\u7136\u540e\u751f\u957f\u6210\u4e00\u7ef4\u679d\u6676\u3002<\/p>\n

b. \u5728Of<\/sub>-CNT(\u78b3\u7eb3\u7c73\u7ba1)\u7f51\u7edc\u4e2d\uff0c\u94a0\u901a\u91cf\u5747\u5300\u5730\u5f15\u5bfc\u6210\u6838\u5e76\u56f4\u7ed5\u55dc\u78b1\u5b98\u80fd\u56e2\u751f\u957f\u3002Na\u4e0d\u4ec5\u53ef\u4ee5\u5728cnt\u9aa8\u67b6\u4e0a\u751f\u957f\uff0c\u8fd8\u53ef\u4ee5\u5728\u7f51\u7edc\u4e2d\u5f62\u6210\u7a7a\u6d1e\uff0c\u5f62\u6210\u65e0\u679d\u6676\u5f62\u6001\u3002<\/p>\n

\u56fe<\/strong>2 <\/strong>\u4e0d\u540c\u94a0\u5316\u72b6\u6001\u4e0b\u78b3\u7eb3\u7c73\u7ba1\u9633\u6781<\/strong>Na@Of<\/sub>-CNT<\/strong>\u7684\u9876\u90e8\u548c\u6a2a\u622a\u9762\u626b\u63cf\u7535\u955c\u8868\u5f81<\/strong><\/p>\n

\"\"<\/p>\n

a-c. \u9540Na\u524dCNT\u7f51\u7edc\u7684\u539f\u59cb\u72b6\u6001\u3002<\/p>\n

d-f. \u9762\u79ef\u94a0\u5bb9\u91cf\u4e3a5mAh cm-2<\/sup>\u7684Na@Of<\/sub>-CNT\u7535\u6781\u3002<\/p>\n

g-i. \u9762\u79ef\u5bb9\u91cf\u4e3a10mah cm-2\u7684Na@Of<\/sub>-CNT\u7535\u6781\u3002<\/p>\n

j-l. \u7ecf\u8fc7200\u6b21\u94a0\u9540\/\u5265\u79bb\u5faa\u73af\uff0c\u5b8c\u5168\u5265\u79bbNa\u540e\u7684Of<\/sub>-CNT\u7f51\u7edc\u3002<\/p>\n

\u56fe<\/strong>3 Na@Of<\/sub>-CNT<\/strong>\u7535\u6781\u7684\u7535\u5316\u5b66\u8868\u5f81<\/strong><\/p>\n

\"\"<\/p>\n

a-b. 1mA cm-2<\/sup>, 1mAh cm-2<\/sup>\u65f6\uff0cNa@Of<\/sub>-CNT, Na@p-CNT\u548cNa@Cu\u7535\u538b\u66f2\u7ebf\u548c\u5bf9\u5e94\u7684CE\u66f2\u7ebf\u3002<\/p>\n

c-d. 5mA cm-2<\/sup>, 5mAh cm-2<\/sup>\u65f6\uff0cNa@Of<\/sub>-CNT, Na@p-CNT\u548cNa@Cu\u7535\u538b\u66f2\u7ebf\u548c\u5bf9\u5e94\u7684CE\u66f2\u7ebf\u3002<\/p>\n

e. 1mA cm-2<\/sup>, 1mAh cm-2<\/sup>\u65f6\uff0cNa@Of<\/sub>-CNT, Na@p-CNT\u548cNa@Cu\u6052\u7535\u6d41\u5faa\u73af\u66f2\u7ebf.<\/p>\n

f. Na@Of<\/sub>-CNT, Na@p-CNT\u548cNa@Cu\u5faa\u73af\u524d\u540e\u7684\u963b\u6297\u66f2\u7ebf\u3002<\/p>\n

g. \u4e0d\u540c\u7535\u6d41\u5bc6\u5ea6\u4e0b\uff0cNa@Of<\/sub>-CNT\u7684\u901f\u7387\u6027\u80fd<\/p>\n

\u56fe<\/strong>4 Of<\/sub>-CNT<\/strong>\u7684<\/strong>\u55dc\u94a0\u6027<\/strong><\/p>\n

\"\"<\/p>\n

a. \u7528\u4e8edft\u8ba1\u7b97\u7684\u539f\u5b50\u6a21\u578b\u3002<\/p>\n

b.Of<\/sub>-CNT\u4e2d\u4e0d\u540c\u5b98\u80fd\u56e2\u7684\u7ed3\u5408\u80fd\u3002<\/p>\n

c-d. Of<\/sub>-CNT\u548cp-CNT\u5728Na\u5438\u9644\u70b9\u7684\u5f62\u53d8\u7535\u8377\u5bc6\u5ea6\u3002<\/p>\n

e-f. \u7528dft\u8ba1\u7b97Of<\/sub>-CNT\u548c\u94dc\u7b94\u8868\u9762\u7684Na\u751f\u957f\u884c\u4e3a\u3002<\/p>\n

\u56fe<\/strong>5 <\/strong>\u94a0<\/strong>–<\/strong>\u7a7a\u6c14\u7535\u6c60\u8868\u5f81<\/strong><\/p>\n

\"\"<\/p>\n

a-b. Na@Of<\/sub>-CNT\u548cNa\u677f\u88f8\u9633\u6781\u94a0-\u7a7a\u6c14\u7535\u6c60\u57281000 mA g-1<\/sup>\u548c500 mAh g-1<\/sup>\u4e0b\u7684\u653e\u7535\/\u5145\u7535\u66f2\u7ebf<\/p>\n

c. a\u548cb\u4e2d\u94a0-\u7a7a\u6c14\u5168\u7535\u6c60\u7684\u76f8\u5e94\u5faa\u73af\u6027\u80fd\u3002<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n

\u00a0 \u8be5\u7814\u7a76\u4ee5\u6c27\u5b98\u80fd\u5316\u78b3\u7eb3\u7c73\u7ba1\u7f51\u7edc\u4e3a\u57fa\u7840\u5408\u6210\u4e86\u9ad8\u5bb9\u91cf\u3001\u957f\u5bff\u547d\u94a0\u91d1\u5c5e\u7535\u6c60\u7684\u4eb2\u94a0\u754c\u9762\u76f8\uff0c\u5c55\u793a\u4e86\u4e00\u79cd\u7b80\u4fbf\u3001\u901a\u7528\u7684\u5236\u5907\u7b56\u7565\u3002\u575a\u56fa\u7684\u55dc\u94a0\u754c\u9762\u4fc3\u8fdb\u4e86\u521d\u59cb\u7535\u9540\u9636\u6bb5\u94a0\u7684\u5747\u5300\u5f62\u6838\uff0c\u5e76\u5f15\u5bfc\u968f\u540e\u7684\u6a2a\u5411\u94a0\u9540\u5c42\u5f62\u6210\u65e0\u679d\u6676\u5f62\u6001\u3002\u6240\u5236\u5907\u7684Na@Of<\/sub>-CNT\u7535\u6781\u5177\u6709\u8d85\u9ad8\u7684\u6bd4\u5bb9\u91cf\uff0c\u63a5\u8fd1\u7eafNa\u548c\u8d85\u957f\u5bff\u547d\u7684\u7406\u8bba\u5bb9\u91cf\u3002\u57fa\u4e8e\u78b3\u7eb3\u7c73\u7ba1\u9633\u6781\u7a33\u5b9a\u7684Na@Of<\/sub>-CNT\uff0c\u76f8\u5e94\u7684Na\u7a7a\u6c14\u7535\u6c60\u7684\u5faa\u73af\u6027\u80fd\u6bd4\u4f20\u7edf\u7684Na\u9633\u6781\u63d0\u9ad8\u4e865\u500d\u3002\u5728\u4e0d\u4e45\u7684\u5c06\u6765\uff0c\u8fd9\u79cd\u9ad8\u94a0\u76f8\u95f4\u7684\u8bbe\u8ba1\u5c06\u4e3a\u9ad8\u5bb9\u91cf\u94a0\u9633\u6781\u7684\u5b9e\u9645\u5e94\u7528\u5f00\u8f9f\u4e00\u6761\u65b0\u7684\u9014\u5f84\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/strong>Sodiophilic interphase mediated, dendrite-free anode with ultrahigh specific capacity for sodium-metal batteries. <\/a>2019, Angew. Chem. Int. Edit., DOI: 10.1002\/anie.201910202.<\/p>\n

\u00a0<\/strong><\/p>\n","protected":false},"excerpt":{"rendered":"

\u5f6d\u6167\u80dcAngew.\uff1a\u4eb2\u94a0\u6027\u754c\u9762\u8c03\u63a7\u9ad8\u5bb9\u91cf\u3001\u8d85\u9ad8\u7a33\u5b9a\u6027\u91d1\u5c5e\u94a0\u7535\u6c60 \u3010\u7814\u7a76\u80cc\u666f\u3011 \u91d1\u5c5e\u94a0\uff08Na\uff09\u56e0\u5176\u7406\u8bba\u5bb9\u91cf\u9ad8\uff081166 mAh g-1\uff09\u800c\u88ab\u8ba4\u4e3a\u662f\u53ef\u5145\u5f0f\u9ad8\u80fd\u7535\u6c60\u6700…<\/p>\n","protected":false},"author":2114,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[],"class_list":["post-186047","post","type-post","status-publish","format-standard","hentry","category-jiedu"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/186047"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/2114"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=186047"}],"version-history":[{"count":2,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/186047\/revisions"}],"predecessor-version":[{"id":186235,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/186047\/revisions\/186235"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=186047"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=186047"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=186047"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}