{"id":184870,"date":"2019-09-03T06:30:15","date_gmt":"2019-09-02T22:30:15","guid":{"rendered":"\/\/m.iemloyee.com\/?p=184870"},"modified":"2019-09-02T10:38:46","modified_gmt":"2019-09-02T02:38:46","slug":"%e6%88%90%e9%83%bd%e7%90%86%e5%b7%a5%e5%a4%a7%e5%ad%a6jmca%e7%bb%bc%e8%bf%b0%ef%bc%9a%e9%92%88%e5%af%b9%e6%96%b0%e5%85%b4li%e2%88%92co2%e7%94%b5%e6%b1%a0%e7%9a%84%e5%82%ac%e5%8c%96%e6%9d%90%e6%96%99","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=184870","title":{"rendered":"\u6210\u90fd\u7406\u5de5\u5927\u5b66JMCA\u7efc\u8ff0\uff1a\u9488\u5bf9\u65b0\u5174Li\u2212CO2\u7535\u6c60\u7684\u50ac\u5316\u6750\u6599\u548c\u6b63\u6781\u7ed3\u6784\u8bbe\u8ba1\u7b56\u7565"},"content":{"rendered":"

\"\"<\/p>\n

\u7b2c\u4e00\u4f5c\u8005\uff1a\u80e1\u5b89\u4fca<\/p>\n

\u901a\u8baf\u4f5c\u8005\uff1a\u9f99\u5251\u5e73, \u8212\u671d\u8457<\/p>\n

\u901a\u8baf\u5355\u4f4d\uff1a\u6210\u90fd\u7406\u5de5\u5927\u5b66<\/p>\n

DOI\uff1a10.1039\/C9TA06506G<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/p>\n

https:\/\/pubs.rsc.org\/en\/Content\/ArticleLanding\/2019\/TA\/C9TA06506G<\/u><\/a><\/p>\n

\u5168\u6587\u901f\u89c8<\/b><\/strong><\/h3>\n

\u5c06\u50a8\u80fd\u6280\u672f\u4e0e\u6e05\u6d01\u4e8c\u6c27\u5316\u78b3\uff08CO2<\/sub>\uff09\u518d\u5faa\u73af\u76f8\u7ed3\u5408\u53ef\u4ee5\u7f13\u89e3CO2<\/sub>\u6392\u653e\u5f15\u8d77\u7684\u5168\u7403\u53d8\u6696\uff0c\u5e76\u6ee1\u8db3\u65e5\u76ca\u589e\u957f\u7684\u7535\u80fd\u4f9b\u5e94\u9700\u6c42\u3002\u6700\u8fd1\uff0c\u9502\u2212<\/b><\/strong>\u4e8c\u6c27\u5316\u78b3\uff08Li\u2212<\/b><\/strong>CO2<\/sub>\uff09\u7535\u5316\u5b66\u7cfb\u7edf\u88ab\u8ba4\u4e3a\u662f\u4e00\u79cd\u80fd\u91cf\u5b58\u50a8\u548cCO2<\/sub>\u6355\u83b7\u7684\u65b0\u7b56\u7565\u3002\u7136\u800c\uff0c\u5bf9\u8fd9\u79cd\u7cfb\u7edf\u7684\u7814\u7a76\u4ecd\u5904\u4e8e\u521d\u6b65\u9636\u6bb5\uff0c\u5176\u53d1\u5c55\u8fc7\u7a0b\u4ecd\u7136\u9762\u4e34\u5de8\u5927\u7684\u6311\u6218\uff0c\u5982\u4f4e\u80fd\u91cf\u6548\u7387\u548c\u56e0\u9ad8\u5145\u7535\u8fc7\u7535\u4f4d\u5f15\u8d77\u7684\u7535\u89e3\u8d28\u5206\u89e3\uff0c\u8fd9\u4e3b\u8981\u5f52\u56e0\u4e8eLi\u2212<\/b><\/strong>CO2<\/sub>\u7535\u6c60\u4e2dCO2<\/sub>\u6d3b\u5316\u53cd\u5e94\u7684\u52a8\u529b\u5b66\u7f13\u6162\u3002\u56e0\u6b64\uff0c\u5408\u7406\u8bbe\u8ba1\u548c\u5236\u5907\u5177\u6709\u4f18\u5f02\u50ac\u5316\u6d3b\u6027\u548c\u9ad8\u7a33\u5b9a\u6027\u7684\u50ac\u5316\u5242\u662f\u5f00\u53d1\u5b9e\u7528Li\u2212<\/b><\/strong>CO2<\/sub>\u7535\u6c60\u7684\u5173\u952e\u3002\u672c\u7efc\u8ff0\u4e2d\uff0c\u9996\u5148\u5bf9Li\u2212<\/b><\/strong>CO2<\/sub>\u7535\u6c60\u7684\u7ed3\u6784\u548c\u57fa\u672c\u7535\u5316\u5b66\u539f\u7406\u8fdb\u884c\u4e86\u8be6\u7ec6\u4ecb\u7ecd\uff0c\u4e4b\u540e\u5bf9Li\u2212<\/b><\/strong>CO2<\/sub>\u7535\u6c60\u6240\u7528\u7684\u9ad8\u6d3b\u6027\u50ac\u5316\u6750\u6599\u548c\u6b63\u6781\u7ed3\u6784\u8bbe\u8ba1\u7b56\u7565\u8fdb\u884c\u4e86\u5168\u9762\u7684\u8bc4\u8ff0\u3002\u8be5\u7efc\u8ff0\u5c06\u6fc0\u53d1\u7814\u7a76\u8005\u5bf9\u8fd9\u4e00\u65b0\u5174\u80fd\u6e90\u5b58\u50a8\u7cfb\u7edf\u7684\u7814\u7a76\u5174\u8da3\u548c\u5173\u6ce8\uff0c\u4ece\u800c\u63a8\u52a8\u8fd9\u4e00\u4f53\u7cfb\u9762\u5411\u5b9e\u7528\u5316\u7684\u53d1\u5c55\u8fdb\u7a0b\u3002<\/p>\n

\u524d\u8a00<\/b><\/strong><\/h3>\n

\u8fd1\u5e74\u6765\uff0c\u4eba\u7c7b\u793e\u4f1a\u5728\u5b9e\u73b0\u53ef\u6301\u7eed\u53d1\u5c55\u65b9\u9762\u9762\u4e34\u7740\u5de8\u5927\u7684\u6311\u6218\uff0c\u5316\u77f3\u71c3\u6599\u7684\u65e5\u76ca\u6d88\u8017\u9020\u6210\u4e86\u73af\u5883\u6c61\u67d3\u548c\u80fd\u6e90\u77ed\u7f3a\u3002\u56e0\u6b64\uff0c\u5f00\u53d1\u80fd\u591f\u5145\u5206\u5229\u7528\u53ef\u518d\u751f\u80fd\u6e90\u7684\u5148\u8fdb\u80fd\u91cf\u50a8\u5b58\u4e0e\u8f6c\u6362\u7cfb\u7edf\u53d8\u5f97\u5c24\u4e3a\u91cd\u8981\u3002\u76ee\u524d\uff0c\u7eff\u8272\u7684\u9ad8\u80fd\u91cf\u5bc6\u5ea6\u4e8c\u6b21\u7535\u6c60\u88ab\u8ba4\u4e3a\u662f\u9ad8\u6548\u7684\u50a8\u80fd\u7cfb\u7edf\u3002\u81ea1991\u5e74\u5546\u4e1a\u5316\u4ee5\u6765\uff0c\u9502\u79bb\u5b50\u7535\u6c60\u51ed\u501f\u5176\u9ad8\u7684\u80fd\u91cf\u5bc6\u5ea6\u548c\u957f\u7684\u5faa\u73af\u5bff\u547d\u4e00\u76f4\u5728\u4fbf\u643a\u5f0f\u7535\u5b50\u5e02\u573a\u5360\u636e\u4e3b\u5bfc\u5730\u4f4d\u3002\u7136\u800c\uff0c\u53d7\u9650\u4e8e\u63d2\u5c42\u53cd\u5e94\u673a\u7406\uff0c\u76ee\u524d\u6700\u5148\u8fdb\u7684\u9502\u79bb\u5b50\u7535\u6c60\u4e0d\u8db3\u4ee5\u6ee1\u8db3\u4e0d\u65ad\u589e\u957f\u7684\u80fd\u91cf\u50a8\u5b58\u9700\u6c42\u3002<\/p>\n

\u9502\u2212<\/b><\/strong>\u7a7a\u6c14\u7535\u6c60\u7684\u7406\u8bba\u80fd\u91cf\u5bc6\u5ea6\u9ad8\u8fbe3500 Wh kg\u2212<\/b><\/sup><\/strong>1<\/sup>\uff0c\u88ab\u8ba4\u4e3a\u662f\u6700\u6709\u5e0c\u671b\u66ff\u4ee3\u9502\u79bb\u5b50\u7535\u6c60\u7684\u4e0b\u4e00\u4ee3\u50a8\u80fd\u5668\u4ef6\u4e4b\u4e00\u3002\u901a\u5e38\uff0c\u5b9e\u9645\u7684\u9502\u2212<\/b><\/strong>\u7a7a\u6c14\u7535\u6c60\u5e94\u8be5\u5728\u542b\u6709N2<\/sub>\u3001O2<\/sub>\u53caCO2<\/sub>\u548c\u6c34\u5206\u7b49\u7684\u7a7a\u6c14\u6c14\u6c1b\u4e2d\u8fd0\u884c\u3002\u7136\u800c\uff0c\u7531\u4e8eH2<\/sub>O\u4e0e\u4e3b\u8981\u653e\u7535\u4ea7\u7269\u8fc7\u6c27\u5316\u9502\uff08Li2<\/sub>O2<\/sub>\uff09\u53ef\u4ee5\u901a\u8fc7\u5316\u5b66\u53cd\u5e94\u5f62\u6210LiOH\uff0c\u56e0\u6b64\u6f6e\u6e7f\u7684\u73af\u5883\u7a7a\u6c14\u4f1a\u4f7f\u7535\u6c60\u6027\u80fd\u52a3\u5316\u3002\u6b64\u5916\uff0c\u7531\u4e8eCO2<\/sub>\u5728\u6709\u673a\u7535\u89e3\u8d28\u4e2d\u5177\u6709\u8f83\u9ad8\u7684\u6eb6\u89e3\u5ea6\uff08\u5176\u6eb6\u89e3\u5ea6\u6bd4O2<\/sub>\u9ad850\u500d\uff09\uff0c\u6eb6\u5242\u5316\u7684CO2<\/sub>\u5bf9\u7535\u5316\u5b66\u53cd\u5e94\u6709\u660e\u663e\u7684\u5f71\u54cd\u3002\u4e00\u65e6CO2<\/sub>\u6269\u6563\u5230\u9502-\u7a7a\u6c14\u7535\u6c60\u6b63\u6781\uff0cCO2<\/sub>\u5219\u5f88\u5bb9\u6613\u5f62\u6210\u78b3\u9178\u9502\uff08Li2<\/sub>CO3<\/sub>\uff09\u3002\u6839\u636e\u5176\u6807\u51c6\u5409\u5e03\u65af\u81ea\u7531\u80fd\u53ef\u77e5\uff0cLi2<\/sub>CO3<\/sub>\u7684\u7a33\u5b9a\u6027\u9ad8\u4e8eLi2<\/sub>O2<\/sub>\u3002\u56e0\u6b64\uff0c\u5728CO2<\/sub>\u5b58\u5728\u65f6\uff0c\u603b\u662f\u5b58\u5728\u70ed\u529b\u5b66\u9a71\u52a8\u529b\u5c06Li2<\/sub>O2<\/sub>\u8f6c\u5316\u4e3aLi2<\/sub>CO3<\/sub>\u3002\u503c\u5f97\u6ce8\u610f\u7684\u662f\uff0c\u8003\u8651\u5230CO2<\/sub>\u7684\u53cd\u5e94\u6027\uff0c\u7814\u7a76\u8005\u5df2\u7ecf\u6210\u529f\u5f00\u53d1\u51fa\u5229\u7528O2<\/sub>\/CO2<\/sub>\u6df7\u5408\u6c14\u4f53\u6216\u7eafCO2<\/sub>\u6c14\u4f53\u4f5c\u4e3a\u53cd\u5e94\u6c14\u4f53\u7684Li\u2212<\/b><\/strong>CO2<\/sub>\u7535\u6c60\u3002<\/p>\n

Li\u2212<\/b><\/strong>CO2<\/sub>\u7535\u6c60\u57fa\u4e8eCO2<\/sub>\u7684\u6c27\u5316\u8fd8\u539f\u53cd\u5e94\uff1a4Li + 3CO2<\/sub>\u00a0\u2194 2Li2<\/sub>CO3<\/sub>\u00a0+ C\uff0c\u7406\u8bba\u4e0a\u53ef\u4ee5\u5b9e\u73b01876 Wh kg\u2212<\/b><\/sup><\/strong>1<\/sup>\u7684\u80fd\u91cf\u5bc6\u5ea6\u3002\u5c3d\u7ba1\u5982\u6b64\uff0c\u5728Li\u2212<\/b><\/strong>CO2<\/sub>\u7535\u6c60\u5b9e\u73b0\u5b9e\u7528\u5316\u4e4b\u524d\uff0c\u8bb8\u591a\u5173\u952e\u95ee\u9898\u5fc5\u987b\u89e3\u51b3\u3002\u65e9\u671f\u7684\u7814\u7a76\u53d1\u73b0\uff0c\u79ef\u7d2f\u7684Li2<\/sub>CO3<\/sub>\u4f1a\u5bfc\u81f4\u6b63\u6781\u8868\u9762\u949d\u5316\uff0c\u4ece\u800c\u964d\u4f4e\u7535\u6c60\u5faa\u73af\u5bff\u547d\u3002\u6b64\u5916\uff0cLi2<\/sub>CO3<\/sub>\u662f\u4e00\u79cd\u5bbd\u5e26\u9699\u7edd\u7f18\u4f53\uff0c\u901a\u5e38\u9700\u8981\u9ad8\u7684\u7535\u4f4d\uff08> 4.3\u00a0V vs. Li\/Li+<\/sup>\uff09\u624d\u8db3\u4ee5\u5206\u89e3Li2<\/sub>CO3<\/sub>\u3002\u5982\u6b64\u9ad8\u7684\u7535\u4f4d\u4e0b\uff0c\u7535\u89e3\u8d28\u4f1a\u53d1\u751f\u4e00\u7cfb\u5217\u7684\u6c27\u5316\u5206\u89e3\u53cd\u5e94\u3002\u8fd9\u4e9b\u95ee\u9898\u4ece\u6839\u672c\u4e0a\u6765\u6e90\u81ea\u6b63\u6781\u8868\u9762\u7f13\u6162\u7684CO2<\/sub>\u8fd8\u539f\u53cd\u5e94\uff08CO2<\/sub>RR\uff09\u548cCO2<\/sub>\u6790\u51fa\u53cd\u5e94\uff08CO2<\/sub>ER\uff09\u52a8\u529b\u5b66\u8fc7\u7a0b\u3002\u56e0\u6b64\uff0c\u63a2\u7d22\u5177\u6709\u826f\u597d\u50ac\u5316\u6d3b\u6027\u548c\u72ec\u7279\u7ed3\u6784\u7684\u9ad8\u6548\u6b63\u6781\u50ac\u5316\u5242\u4ee5\u964d\u4f4e\u5145\u653e\u7535\u8fc7\u7535\u4f4d\uff0c\u4ece\u800c\u4fc3\u8fdb\u4ea7\u7269\u7684\u53ef\u9006\u5f62\u6210\u548c\u5206\u89e3\uff0c\u8fd9\u5bf9\u4e8e\u8bbe\u8ba1\u9ad8\u6027\u80fd\u7684Li\u2212<\/b><\/strong>CO2<\/sub>\u7535\u6c60\u81f3\u5173\u91cd\u8981\u3002<\/p>\n

\u6210\u679c\u7b80\u4ecb<\/b><\/strong><\/h3>\n

\u5bf9Li\u2212<\/b><\/strong>CO2<\/sub>\u7535\u6c60\u6b63\u6781\u53cd\u5e94\u673a\u7406\u3001\u50ac\u5316\u5242\u53ca\u5176\u76f8\u4e92\u5173\u7cfb\u7684\u6df1\u5165\u5206\u6790\u65e0\u7591\u4f1a\u63a8\u52a8\u8fd9\u79cd\u50a8\u80fd\u5668\u4ef6\u7684\u5feb\u901f\u53d1\u5c55\u3002\u8fd1\u65e5\uff0c\u6210\u90fd\u7406\u5de5\u5927\u5b66\u9f99\u5251\u5e73\u6559\u6388\u548c\u8212\u671d\u8457\u526f\u6559\u6388\uff08\u5171\u540c\u901a\u8baf\uff09\u56e2\u961f<\/b><\/strong>\u4ee5\u201cDesign strategies toward catalytic materials and cathode structure for emerging Li\u2212<\/b><\/strong>CO2<\/sub>\u00a0batteries\u201d\u4e3a\u9898\u5728J. Mater. Chem<\/i><\/em>.<\/i><\/em>\u00a0A<\/i><\/em>\u4e0a\u53d1\u8868\u7efc\u8ff0\u6587\u7ae0\uff0c\u5168\u9762\u7cfb\u7edf\u5730\u4ecb\u7ecd\u4e86Li\u2212<\/b><\/strong>CO2<\/sub>\u7535\u6c60\u7684\u5145\u653e\u7535\u53cd\u5e94\u673a\u7406\u3001\u50ac\u5316\u6750\u6599\u548c\u6b63\u6781\u7ed3\u6784\u7684\u8bbe\u8ba1\u7b56\u7565\u53ca\u5176\u7814\u7a76\u8fdb\u5c55\uff0c\u5e76\u5bf9\u8fd9\u4e00\u50a8\u80fd\u5668\u4ef6\u7684\u672a\u6765\u524d\u666f\u63d0\u51fa\u4e86\u5c55\u671b\u3002<\/p>\n

\u56fe\u6587<\/b><\/strong>\u5bfc\u8bfb<\/b><\/strong><\/h3>\n

1. Li<\/b><\/strong>\u2212<\/b><\/strong>CO<\/b><\/strong>2<\/b><\/sub><\/strong>\u7535\u6c60\u7ed3\u6784\u53ca\u5145\u653e\u7535\u53cd\u5e94\u673a\u7406<\/b><\/strong><\/h4>\n

\u56fe1. Li\u2212<\/b><\/strong>CO2<\/sub>\u7535\u6c60\u7ed3\u6784\u793a\u610f\u56fe<\/p>\n

\"\"<\/p>\n

\u5178\u578b\u7684Li\u2212<\/b><\/strong>CO2<\/sub>\u7535\u6c60\u662f\u7531\u91d1\u5c5eLi\u9633\u6781\u3001\u6709\u673a\u7535\u89e3\u8d28\u548c\u6c14\u4f53\u6269\u6563\u7535\u6781\u6784\u6210\uff0c\u6b63\u6781\u7684\u6d3b\u6027\u53cd\u5e94\u7269\u8d28\u662fO2<\/sub>\/CO2<\/sub>\u6df7\u5408\u6c14\u4f53\u6216\u7eafCO2<\/sub>\u6c14\u4f53\u3002\u5728\u4e0d\u540c\u7684\u53cd\u5e94\u6c14\u4f53\u4e2dLi\u2212<\/b><\/strong>CO2<\/sub>\u7535\u6c60\u7684\u53cd\u5e94\u673a\u7406\u5b58\u5728\u5dee\u5f02\u3002\u6b64\u5916\uff0c\u4e0d\u540c\u6eb6\u5242\u5bf9\u5176\u53cd\u5e94\u4e5f\u5b58\u5728\u5f88\u5927\u7684\u5f71\u54cd\u3002\u5728\u7eafCO2<\/sub>\u4e2d\u6b63\u6781\u53cd\u5e94\u57fa\u4e8e4Li + 3CO2<\/sub>\u00a0\u2194 2Li2<\/sub>CO3<\/sub>\u00a0+ C (Eo<\/sup>\u00a0= 2.80 V vs Li\/Li+<\/sup>)\u3002\u800c\u5bf9\u4e8eCO2<\/sub>ER\uff0c\u76ee\u524d\u7684\u7814\u7a76\u7ed3\u679c\u8868\u660eCO2<\/sub>\u6790\u51fa\u53ef\u80fd\u6765\u6e90\u4e8eLi2<\/sub>CO3<\/sub>\u7684\u81ea\u5206\u89e3\u6216Li2<\/sub>CO3<\/sub>\u4e0e\u78b3\u7269\u8d28\u95f4\u7684\u53ef\u9006\u53cd\u5e94\u3002\u5b9e\u9645\u4e0a\uff0c\u76ee\u524d\u5bf9Li\u2212<\/b><\/strong>CO2<\/sub>\u7535\u6c60\u7535\u5316\u5b66\u8fc7\u7a0b\u7684\u8ba4\u8bc6\u5c1a\u5904\u4e8e\u521d\u671f\u9636\u6bb5\u3002<\/p>\n

2. Li<\/b><\/strong>\u2212<\/b><\/strong>CO<\/b><\/strong>2<\/b><\/sub><\/strong>\u7535\u6c60\u50ac\u5316\u6750\u6599\u548c\u6b63\u6781\u7ed3\u6784\u8bbe\u8ba1\u6807\u51c6\u548c\u7b56\u7565<\/b><\/strong><\/h4>\n

\u56fe2.\u00a0Li\u2212CO2<\/sub>\u7535\u6c60\u9ad8\u6027\u80fd\u50ac\u5316\u6750\u6599\u7684\u8bbe\u8ba1\u8981\u6c42<\/p>\n

\"\"<\/p>\n

\u56fe3.\u00a0Li\u2212CO2<\/sub>\u7535\u6c60\u50ac\u5316\u6750\u6599\u8bbe\u8ba1\u7b56\u7565<\/p>\n

\"\"<\/p>\n

\u672c\u90e8\u5206\u9996\u5148\u4ecb\u7ecd\u4e86Li\u2212CO2<\/sub>\u7535\u6c60\u6b63\u6781\u50ac\u5316\u5242\u7684\u8bbe\u8ba1\u8981\u6c42\uff0c\u5305\u62ec\uff1a\u9ad8\u50ac\u5316\u6d3b\u6027\u3001\u591a\u5b54\u5206\u5c42\u7ed3\u6784\u3001\u9ad8\u5bfc\u7535\u7387\u4ee5\u53ca\u4f18\u5f02\u7684\u7a33\u5b9a\u6027\u7b49\u3002\u5728\u6b64\u57fa\u7840\u4e0a\uff0c\u4ece\u6750\u6599\u5206\u7c7b\u548c\u7535\u6781\u7ed3\u6784\u8bbe\u8ba1\u7684\u89d2\u5ea6\u5168\u9762\u7cfb\u7edf\u7684\u7efc\u8ff0\u4e86\u6b63\u6781\u50ac\u5316\u5242\u7684\u6700\u65b0\u7814\u7a76\u8fdb\u5c55\uff0c\u5e76\u8ba8\u8bba\u4e86\u50ac\u5316\u5242\u7684\u5316\u5b66\u7ec4\u6210\u548c\u7ed3\u6784\u5bf9CO2<\/sub>RR\u548cCO2<\/sub>ER\u6d3b\u6027\u4ee5\u53caLi\u2212CO2<\/sub>\u7535\u6c60\u7684\u603b\u4f53\u6027\u80fd\u7684\u5f71\u54cd\u3002\u6700\u540e\uff0c\u63d0\u51fa\u8bbe\u8ba1\u9ad8\u6027\u80fd\u50ac\u5316\u5242\u7684\u6311\u6218\u548c\u672a\u6765\u7814\u7a76\u65b9\u5411\u3002<\/p>\n

\u5c0f\u7ed3<\/b><\/strong><\/h3>\n

Li\u2212<\/b><\/strong>CO2<\/sub>\u7535\u6c60\u63d0\u4f9b\u4e86\u4e00\u79cd\u6709\u6548\u6355\u83b7\u548c\u5229\u7528CO2<\/sub>\u7684\u65b0\u65b9\u6cd5\u3002\u63a2\u7d22\u5177\u6709\u72ec\u7279\u7ed3\u6784\u548c\u9ad8\u50ac\u5316\u6d3b\u6027\u7684\u9ad8\u6548\u50ac\u5316\u5242\u4ee5\u4fc3\u8fdb\u5176\u6b63\u6781\u53cd\u5e94\u52a8\u529b\u5b66\u662f\u672a\u6765\u7684\u9996\u8981\u4efb\u52a1\u3002\u5f00\u53d1\u548c\u8bbe\u8ba1Li\u2212<\/b><\/strong>CO2<\/sub>\u7535\u6c60\u9ad8\u6548\u6b63\u6781\u6750\u6599\u7684\u51e0\u4e2a\u5173\u952e\u56e0\u7d20\u503c\u5f97\u5173\u6ce8\uff1a<\/p>\n

\uff081\uff09\u7535\u5b50\u7ed3\u6784\u548c\u5185\u5728\u6d3b\u6027\u8c03\u8282<\/i><\/em>\u3002\u8c03\u8282\u50ac\u5316\u5242\u7684\u5185\u5728\u6d3b\u6027\u901a\u5e38\u662f\u901a\u8fc7\u6539\u53d8\u8868\u9762\u5143\u7d20\u7684\u5316\u5b66\u73af\u5883\u53ca\u6d3b\u6027\u4f4d\u70b9\u7684\u7535\u5b50\u7ed3\u6784\u6765\u5b9e\u73b0\u3002\u4e3a\u6b64\uff0c\u9700\u8981\u6784\u5efa\u5177\u6709\u6709\u5229\u7535\u5b50\u7ed3\u6784\u7684\u65b0\u578b\u7535\u50ac\u5316\u5242\u3002\u8c03\u8282\u7b56\u7565\uff0c\u5982\u6742\u539f\u5b50\u63ba\u6742\u3001\u7f3a\u9677\u63a7\u5236\u548c\u5e94\u53d8\u63a7\u5236\u7b49\uff0c\u662f\u5f00\u53d1Li\u2212<\/b><\/strong>CO2<\/sub>\u7535\u6c60\u7535\u50ac\u5316\u5242\u7684\u6709\u6548\u65b9\u6cd5\u3002<\/p>\n

\uff082\uff09\u6b63\u6781\u7ed3\u6784\u8bbe\u8ba1<\/i><\/em>\u3002\u6d3b\u6027\u4f4d\u70b9\u7684\u6570\u91cf\u9ad8\u5ea6\u4f9d\u8d56\u4e8e\u6b63\u6781\u7ed3\u6784\uff0c\u56e0\u6b64\u5b54\u5f84\u548c\u6bd4\u8868\u9762\u79ef\u662f\u5f71\u54cd\u5176\u50ac\u5316\u6027\u80fd\u7684\u5173\u952e\u56e0\u7d20\u3002\u5177\u6709\u9ad8\u6bd4\u8868\u9762\u79ef\u7684\u5206\u5c42\u591a\u7ea7\u5b54\u7ed3\u6784\u7684\u6b63\u6781\u6709\u5229\u4e8e\u63d0\u9ad8\u6d3b\u6027\u4f4d\u70b9\u7684\u5229\u7528\u6548\u7387\u3002\u7136\u800c\uff0c\u53d7\u7535\u8377\u8f6c\u79fb\u548c\u4f20\u8d28\u7684\u9650\u5236\uff0c\u8868\u89c2\u6d3b\u6027\u4e0d\u80fd\u901a\u8fc7\u7ed3\u6784\u8bbe\u8ba1\u65e0\u9650\u589e\u5f3a\u3002\u56e0\u6b64\uff0c\u4e3a\u4e86\u63d0\u9ad8\u7535\u6781\u6750\u6599\u7684\u50ac\u5316\u6027\u80fd\uff0c\u7ed3\u6784\u8bbe\u8ba1\u5e94\u7ed3\u5408\u5185\u5728\u6d3b\u6027\u548c\u7535\u5b50\u7ed3\u6784\u8c03\u8282\u3002<\/p>\n

\uff083\uff09\u5c3a\u5bf8\u63a7\u5236<\/i><\/em>\u3002\u50ac\u5316\u5242\u9897\u7c92\u7684\u5c3a\u5bf8\u63a7\u5236\u5bf9\u4e8e\u63d0\u9ad8Li\u2212<\/b><\/strong>CO2<\/sub>\u7535\u6c60\u7684\u6027\u80fd\u81f3\u5173\u91cd\u8981\u3002\u603b\u7684\u6765\u8bf4\uff0c\u968f\u7740\u6d3b\u6027\u7c92\u5b50\u7c92\u5f84\u7684\u51cf\u5c0f\uff0c\u5176\u6bd4\u6d3b\u6027\u901a\u5e38\u4f1a\u589e\u52a0\u3002\u6b64\u5916\uff0c\u50ac\u5316\u5242\u754c\u9762\u5904\u7684\u7535\u5b50\u8f6c\u79fb\u5f88\u5927\u7a0b\u5ea6\u4e0a\u53d7\u5236\u4e8e\u8f7d\u4f53\u4e0a\u7684\u7eb3\u7c73\u6750\u6599\u5c3a\u5bf8\u7684\u5f71\u54cd\u3002\u5f53\u9ad8\u5206\u6563\u7684\u7eb3\u7c73\u6750\u6599\u8d1f\u8f7d\u5728\u8f7d\u4f53\u4e0a\u65f6\uff0c\u5176\u754c\u9762\u7535\u5b50\u76f8\u4e92\u4f5c\u7528\u53d8\u5f3a\u3002\u56e0\u6b64\uff0c\u4e3a\u4e86\u52a0\u901f\u7535\u5b50\u8f6c\u79fb\u548c\u6539\u5584\u50ac\u5316\u6d3b\u6027\uff0c\u9700\u8981\u964d\u4f4e\u50ac\u5316\u5242\u5c3a\u5bf8\u3002\u4f7f\u7528\u9002\u5f53\u7684\u8f7d\u4f53\u6750\u6599\u63d0\u9ad8\u50ac\u5316\u5242\u7684\u5206\u6563\u5ea6\u5bf9\u4fc3\u8fdb\u50ac\u5316\u6d3b\u6027\u7684\u5145\u5206\u53d1\u6325\u8d77\u7740\u91cd\u8981\u4f5c\u7528\u3002<\/p>\n

\uff084\uff09\u7535\u5b50\u4f20\u5bfc<\/i><\/em>\u3002\u4e3a\u4e86\u964d\u4f4e\u6b27\u59c6\u7535\u963b\uff0c\u50ac\u5316\u5242\u5e94\u5177\u6709\u9ad8\u7684\u5bfc\u7535\u6027\uff0c\u4ece\u800c\u6539\u5584\u7535\u6c60\u7684\u500d\u7387\u6027\u80fd\u3002\u6b64\u5916\uff0c\u5c06\u5bfc\u7535\u57fa\u5e95\uff08\u5982\u77f3\u58a8\u70ef\u3001\u78b3\u7eb3\u7c73\u7ba1\u7b49\uff09\u7ed3\u5408\u5230\u590d\u5408\u6750\u6599\u4e2d\u4ee5\u4fc3\u8fdb\u57fa\u5e95\u548c\u6d3b\u6027\u4f4d\u70b9\u4e4b\u95f4\u7684\u5f3a\u76f8\u4e92\u4f5c\u7528\uff0c\u80fd\u591f\u52a0\u901f\u7535\u5b50\u8f6c\u79fb\u3002\u6700\u540e\uff0c\u5236\u5907\u5177\u6709\u81ea\u652f\u6491\u7ed3\u6784\u7684\u50ac\u5316\u5242\u4ece\u800c\u6539\u5584\u50ac\u5316\u5242\u548c\u57fa\u5e95\u4e4b\u95f4\u7684\u76f8\u4e92\u4f5c\u7528\u4e5f\u662f\u53ef\u884c\u7684\u9014\u5f84\u3002<\/p>\n

\uff085\uff09\u6b63\u6781\u7a33\u5b9a\u6027<\/i><\/em>\u3002\u4e0d\u6eb6\u6027\u548c\u7edd\u7f18\u7684\u653e\u7535\u4ea7\u7269Li2<\/sub>CO3<\/sub>\u7684\u4e0d\u89c4\u5219\u6c89\u79ef\u5c06\u5bfc\u81f4\u6b63\u6781\u7684\u4f53\u79ef\u81a8\u80c0\uff0c\u8fd9\u5c06\u5bfc\u81f4Li\u2212<\/b><\/strong>CO2<\/sub>\u7535\u6c60\u6b63\u6781\u7ed3\u6784\u7684\u4e25\u91cd\u7834\u574f\u3002\u901a\u8fc7\u6709\u6548\u7684\u7ed3\u6784\u6539\u6027\u6765\u63d0\u4f9b\u8db3\u591f\u7684\u7a7a\u95f4\uff0c\u80fd\u591f\u6709\u6548\u5730\u51cf\u8f7b\u7531Li2<\/sub>CO3<\/sub>\u6c89\u79ef\u5f15\u8d77\u7684\u7535\u6781\u4f53\u79ef\u81a8\u80c0\u3002\u6b64\u5916\uff0cLi2<\/sub>CO3<\/sub>\u7684\u81ea\u5206\u89e3\u5f15\u53d1\u7684\u4e00\u7cfb\u5217\u526f\u53cd\u5e94\u4f1a\u8fdb\u4e00\u6b65\u5f71\u54cd\u50ac\u5316\u5242\u7684\u5316\u5b66\u7a33\u5b9a\u6027\u3002\u56e0\u6b64\uff0c\u7535\u89e3\u8d28-\u6b63\u6781\u7684\u534f\u540c\u8bbe\u8ba1\u975e\u5e38\u91cd\u8981\u3002<\/p>\n

\uff086\uff09\u53cd\u5e94\u673a\u7406\u7684\u7406\u89e3<\/i><\/em>\u3002Li\u2212<\/b><\/strong>CO2<\/sub>\u7535\u6c60\u6b63\u6781\u53cd\u5e94\u662f\u4e00\u4e2a\u6d89\u53ca\u591a\u6b65\u53cd\u5e94\u7684\u590d\u6742\u8fc7\u7a0b\uff0c\u5f53\u524d\u5bf9\u50ac\u5316\u5242\u7684\u5185\u5728\u7ed3\u6784\u4e0eLi\u2212<\/b><\/strong>CO2<\/sub>\u7535\u6c60\u7684\u6b63\u6781\u53cd\u5e94\u673a\u7406\u4e4b\u95f4\u7684\u5173\u7cfb\u7406\u89e3\u8fd8\u4e0d\u591f\u6df1\u5165\u3002\u5728\u4eca\u540e\u7684\u7814\u7a76\u4e2d\uff0c\u5e94\u5f00\u53d1\u5148\u8fdb\u7684\u65b9\u6cd5\uff08\u5982\u539f\u4f4d\u5206\u6790\u3001\u540c\u4f4d\u7d20\u6821\u51c6\u548c\u7406\u8bba\u8ba1\u7b97\u7b49\uff09\uff0c\u5bf9\u4e0d\u7a33\u5b9a\/\u4e9a\u7a33\u6001\u4e2d\u95f4\u4f53\u8fdb\u884c\u5b9e\u65f6\u68c0\u6d4b\uff0c\u4ee5\u6b64\u786e\u8ba4Li\u2212<\/b><\/strong>CO2<\/sub>\u7535\u6c60\u6b63\u6781\u53cd\u5e94\u7684\u5b9e\u9645\u53cd\u5e94\u8def\u5f84\u3002<\/p>\n

\u4f5c\u8005\u7b80\u4ecb<\/b><\/strong><\/h3>\n

\u80e1\u5b89\u4fca\uff08\u4e00\u4f5c\uff09\uff1a<\/b><\/strong>\u7855\u58eb\uff0c2019\u5e747\u6708\u6bd5\u4e1a\u4e8e\u6210\u90fd\u7406\u5de5\u5927\u5b66\u6750\u6599\u4e0e\u5316\u5b66\u5316\u5de5\u5b66\u9662\u5e76\u83b7\u7855\u58eb\u5b66\u4f4d\uff0c\u5e08\u4ece\u9f99\u5251\u5e73\u6559\u6388\u548c\u8212\u671d\u8457\u526f\u6559\u6388\u3002\u540c\u5e749\u6708\u8fdb\u5165\u7535\u5b50\u79d1\u6280\u5927\u5b66\u7535\u5b50\u79d1\u5b66\u4e0e\u5de5\u7a0b\u5b66\u9662\u653b\u8bfb\u535a\u58eb\u5b66\u4f4d\u3002\u653b\u8bfb\u7855\u58eb\u671f\u95f4\u4e3b\u8981\u4ece\u4e8b\u7535\u6781\u6750\u6599\u7684\u5236\u5907\u53ca\u8868\u754c\u9762\u6027\u8d28\u8c03\u63a7\u3001\u50ac\u5316\u4f5c\u7528\u8fc7\u7a0b\u53ca\u6784\u6548\u5173\u7cfb\u7814\u7a76\u3002\u7855\u58eb\u671f\u95f4\u4ee5\u7b2c\u4e00\u4f5c\u8005\u5728J. Mater. Chem. A\u3001ACS Appl. Mater. Interfaces\u3001Chem. Eng. J.\u3001ACS Sustainable Chem. Eng.\u3001Electrochim. Acta\u7b49\u671f\u520a\u53d1\u8868SCI\u8bba\u65877\u7bc7\uff0cEI\u8bba\u65871\u7bc7\u3002<\/p>\n

\u8212\u671d\u8457\uff08\u901a\u8baf\uff09<\/b><\/strong>\uff1a\u526f\u6559\u6388\uff0c2013\u5e74\u6bd5\u4e1a\u4e8e\u4e2d\u56fd\u79d1\u5b66\u9662\u5927\u8fde\u5316\u5b66\u7269\u7406\u7814\u7a76\u6240\u5e76\u83b7\u7406\u5b66\u535a\u58eb\u5b66\u4f4d\u30022014\u5e744\u6708-2016\u5e744\u6708\u4e2d\u56fd\u79d1\u5b66\u9662\u91d1\u5c5e\u7814\u7a76\u6240\u6c88\u9633\u6750\u6599\u79d1\u5b66\u56fd\u5bb6\u5b9e\u9a8c\u5ba4\uff08\u73b0\u6c88\u9633\u6750\u6599\u79d1\u5b66\u56fd\u5bb6\u7814\u7a76\u4e2d\u5fc3\uff09\u535a\u58eb\u540e\u30022018\u5e741\u6708-2019\u5e742\u6708\u6fb3\u5927\u5229\u4e9a\u4f0d\u4f26\u8d21\u5927\u5b66\u8d85\u5bfc\u4e0e\u7535\u5b50\u6750\u6599\u7814\u7a76\u6240\u8bbf\u95ee\u5b66\u8005\u3002\u4f5c\u4e3a\u9879\u76ee\u8d1f\u8d23\u4eba\u627f\u62c5\u56fd\u5bb6\u81ea\u7136\u79d1\u5b66\u57fa\u91d1\u9879\u76ee\u3001\u56db\u5ddd\u7701\u79d1\u6280\u5385\u91cd\u70b9\u7814\u53d1\u9879\u76ee\u3001\u5e94\u7528\u57fa\u7840\u7814\u7a76\u91cd\u70b9\u9879\u76ee\u3001\u56db\u5ddd\u7701\u6559\u80b2\u5385\u81ea\u7136\u79d1\u5b66\u9879\u76ee\u53ca\u5176\u4ed6\u6a2a\u5411\u59d4\u6258\u9879\u76ee\u3002\u76ee\u524d\u4e3b\u8981\u4ece\u4e8b\u9ad8\u6bd4\u80fd\u91cf\u4e8c\u6b21\u7535\u6c60\u5173\u952e\u6750\u6599\u7684\u57fa\u7840\u7814\u7a76\u53ca\u5173\u952e\u6280\u672f\u5f00\u53d1\u3002\u4ee5\u7b2c\u4e00\u4f5c\u8005\u6216\u901a\u8baf\u4f5c\u8005\u5728Adv. Mater., Nano Energy, Small, ChemSusChem\u7b49\u56fd\u9645\u77e5\u540d\u671f\u520a\u4e0a\u53d1\u8868SCI\u8bba\u658730\u4f59\u7bc7\uff08IF\u5927\u4e8e10\u8bba\u65876\u7bc7\uff09\u3002<\/p>\n

\u9f99\u5251\u5e73\uff08\u901a\u8baf\uff09\uff1a<\/b><\/strong>\u6559\u6388\uff0c\u4e3b\u8981\u4ece\u4e8b\u65b0\u578b\u91d1\u5c5e\u6750\u6599\u3001\u590d\u5408\u6750\u6599\u3001\u65b0\u578b\u80fd\u6e90\u6750\u6599\u7684\u57fa\u7840\u7814\u7a76\u4e0e\u5e94\u7528\u5f00\u53d1\u5de5\u4f5c\u3002\u4f5c\u4e3a\u8d1f\u8d23\u4eba\u4e3b\u6301\u5728\u7814\u56db\u5ddd\u7701\u53d1\u5c55\u4e0e\u6539\u9769\u59d4\u5458\u4f1a\u6500\u897f\u6218\u7565\u8d44\u6e90\u521b\u65b0\u5f00\u53d1\u91cd\u5927\u79d1\u6280\u653b\u5173\u9879\u76ee1\u9879\uff0c\u56db\u5ddd\u7701\u79d1\u6280\u5385\u79d1\u6280\u652f\u6491\u9879\u76ee3\u9879\u3001\u56db\u5ddd\u7701\u79d1\u6280\u6210\u679c\u8f6c\u5316\u793a\u8303\u9879\u76ee1\u9879\uff0c\u56db\u5ddd\u7701\u79d1\u6280\u5385\u5e73\u53f0\u5efa\u8bbe\u9879\u76ee1\u9879\uff0c\u56db\u5ddd\u7701\u79d1\u6280\u5385\u5e94\u7528\u57fa\u7840\u7814\u7a76\u9879\u76ee1\u9879\uff0c\u56db\u5ddd\u7701\u6559\u80b2\u5385\u81ea\u7136\u79d1\u5b66\u57fa\u91d1\u9752\u5e74\u9879\u76ee1\u9879\uff0c\u56db\u5ddd\u7701\u6559\u80b2\u5385\u81ea\u7136\u79d1\u5b66\u91cd\u70b9\u9879\u76ee1\u9879\uff1b\u4e3b\u6301\u4f01\u4e1a\u59d4\u6258\u6a2a\u5411\u9879\u76ee10\u4f59\u9879\u3002\u53d1\u8868\u5b66\u672f\u8bba\u6587107\u7bc7\uff0c\u5176\u4e2dSCI\u6536\u5f5543\u7bc7\u3002\u7533\u8bf7\u56fd\u5bb6\u53d1\u660e\u4e13\u522919\u9879\uff0c\u5df2\u6388\u6743\u56fd\u5bb6\u53d1\u660e\u4e13\u52299\u9879\u3002\u51fa\u7248\u6559\u67501\u90e8\u3002<\/p>\n

\u672c\u6587\u7531\u6210\u90fd\u7406\u5de5\u5927\u5b66\u9f99\u5251\u5e73\u6559\u6388\u56e2\u961f<\/b><\/strong>\u4f9b\u7a3f\u3002<\/p>\n

\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1: tougao@cailiaoren.com.<\/p>\n

\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1acailiaorenVIP.<\/p>\n","protected":false},"excerpt":{"rendered":"

\u7b2c\u4e00\u4f5c\u8005\uff1a\u80e1\u5b89\u4fca \u901a\u8baf\u4f5c\u8005\uff1a\u9f99\u5251\u5e73, \u8212\u671d\u8457 \u901a\u8baf\u5355\u4f4d\uff1a\u6210\u90fd\u7406\u5de5\u5927\u5b66 DOI\uff1a10.1039\/C9TA06506G \u6587\u732e\u94fe\u63a5\uff1a https:\/\/pubs.rsc…<\/p>\n","protected":false},"author":10213,"featured_media":184871,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[],"class_list":["post-184870","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-jiedu"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/184870"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/10213"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=184870"}],"version-history":[{"count":1,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/184870\/revisions"}],"predecessor-version":[{"id":184883,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/184870\/revisions\/184883"}],"wp:featuredmedia":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/media\/184871"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=184870"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=184870"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=184870"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}