{"id":184151,"date":"2019-09-03T06:30:59","date_gmt":"2019-09-02T22:30:59","guid":{"rendered":"\/\/m.iemloyee.com\/?p=184151"},"modified":"2019-09-02T16:47:42","modified_gmt":"2019-09-02T08:47:42","slug":"%e5%bd%93mofs%e9%81%87%e8%a7%81mnps%ef%bc%8c%e6%80%8e%e8%83%bd%e4%b8%8d%e5%a2%9e%e5%bc%ba%e5%8d%8f%e5%90%8c%e5%82%ac%e5%8c%96%ef%bc%81","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=184151","title":{"rendered":"\u5f53MOFs\u9047\u89c1MNPs\uff0c\u600e\u80fd\u4e0d\u589e\u5f3a\u534f\u540c\u50ac\u5316\uff01"},"content":{"rendered":"<p>\u91d1\u5c5e\u6709\u673a\u9aa8\u67b6(MOFs)\u662f\u4e00\u79cd\u5177\u6709\u8f83\u9ad8\u7684\u6bd4\u8868\u9762\u79ef\u3001\u7ed3\u6784\u591a\u6837\u6027\u548c\u53ef\u5b9a\u5236\u6027\u7684\u65b0\u578b\u7ed3\u6676\u591a\u5b54\u6750\u6599\uff0c\u5f15\u8d77\u79d1\u7814\u5de5\u4f5c\u8005\u7684\u5e7f\u6cdb\u5173\u6ce8\uff0c\u5e76\u5728\u8bf8\u591a\u9886\u57df\u8868\u73b0\u51fa\u6f5c\u5728\u7684\u5e94\u7528\u524d\u666f\uff0c\u7279\u522b\u662f\u5728\u50ac\u5316\u65b9\u9762\u7684\u5e94\u7528\u5f97\u5230\u9ad8\u5ea6\u7684\u5173\u6ce8\u3002\u7136\u800c\uff0cMOF\u6846\u67b6\u7684\u50ac\u5316\u6d3b\u6027\u4f4d\u7c7b\u578b\u5c11\uff0c\u53ef\u50ac\u5316\u7684\u53cd\u5e94\u79cd\u7c7b\u6709\u9650\uff0c\u5229\u7528MOF\u6750\u6599\u7684\u6c38\u4e45\u5b54\u6d1e\u6765\u9650\u5236\u5ba2\u4f53\u7269\u79cd\uff0c\u7279\u522b\u662f\u91d1\u5c5e\u7eb3\u7c73\u9897\u7c92\uff08MNPs\uff09\uff0c\u4ee5\u63d0\u9ad8\u50ac\u5316\u6027\u80fd\u548c\u6269\u5927\u53cd\u5e94\u8303\u56f4\u3002\u8fd9\u662f\u4e00\u4e2a\u53d1\u5c55\u8fc5\u901f\u7684\u8de8\u5b66\u79d1\u7814\u7a76\u9886\u57df\u3002<\/p>\n<p>MNP\/MOF\u590d\u5408\u6750\u6599\u53d1\u5c55\u7684\u4e3b\u8981\u76ee\u6807\u662f\u62d3\u5bbd\u50ac\u5316\u53cd\u5e94\u7684\u8303\u56f4\u548c\u589e\u5f3a\u50ac\u5316\u4f5c\u7528\u3002\u6362\u53e5\u8bdd\u8bf4\uff0c\u9700\u8981\u4e86\u89e3MNP\/MOF\u590d\u5408\u6750\u6599\u5982\u4f55\u80fd\u591f\u63d0\u9ad8\u50ac\u5316\u6027\u80fd\u3002\u6709\u5fc5\u8981\u8ba4\u8bc6\u5230\u8fd9\u4e24\u4e2a\u7ec4\u4ef6\u7684\u4f5c\u7528\uff0c\u4ee5\u53ca\u5b83\u4eec\u5982\u4f55\u534f\u540c\u5de5\u4f5c\uff0c\u4ee5\u5b9e\u73b0\u589e\u5f3a\u6027\u80fd\uff0c\u4e0e\u9002\u5f53\u8bbe\u8ba1\u7684MNP\/MOF\u590d\u5408\u50ac\u5316\u5242\u3002<\/p>\n<p>\u63a5\u4e0b\u6765\u6211\u4eec\u4ece\u9ad8\u88ab\u5f15\u8bba\u6587\u4e2d\u4ecb\u7ecd\u51e0\u5927\u7c7b\u50ac\u5316\u4f5c\u7528\u7684\u534f\u540c\u7814\u7a76<\/p>\n<h3><strong><b>MOF\u7528\u4e8e\u7a33\u5b9aMNPs\uff0cMNPs\u4e3a\u6d3b\u6027\u4e2d\u5fc3<\/b><\/strong><\/h3>\n<p>\u7531\u4e8e\u5176\u6c38\u4e45\u5b54\u9699\u5ea6\u548c\u53ef\u8c03\u5b54\u5f84\uff0cMOFs\u662fMNPs\u7a33\u5b9a\u7684\u7406\u60f3\u5019\u9009\u6750\u6599\u3002MOFs\u53ef\u4ee5\u9650\u5236\u6216\u7a33\u5b9a\u5c0f\u7684MNPs\uff0c\u5177\u6709\u826f\u597d\u7684\u50ac\u5316\u6d3b\u6027\u548c\u53ef\u56de\u6536\u6027\u3002\u5728\u8fd9\u4e9b\u590d\u5408\u6750\u6599\u4e2d\uff0cMNPs\u662f\u6d3b\u6027\u4e2d\u5fc3\uff0cMOFs\u662fMNPs\u7684\u7a33\u5b9a\u5242\u2014\u2014\u8fd9\u4ee3\u8868\u4e86MNPs\u548cMOFs\u4e4b\u95f4\u6700\u7b80\u5355\u7684\u534f\u540c\u4f5c\u7528\uff0c\u5e76\u5728\u8be5\u9886\u57df\u7684\u4e00\u7cfb\u5217\u91cd\u8981\u51fa\u7248\u7269\u4e2d\u5f97\u5230\u4e86\u8bc1\u660e\u3002<\/p>\n<p>\u94af\u50ac\u5316\u82b3\u57fa\u5364\u5316\u7269\u7684C-C\u5076\u8054\u53cd\u5e94\uff0cSuzuki-Miyaura\u53cd\u5e94\u548c\u4e4c\u5c14\u66fc\u53cd\u5e94\u662f\u6709\u673a\u5408\u6210\u4e2d\u6784\u5efa\u53cc\u82b3\u57fa\u5355\u5143\u7684\u91cd\u8981\u9014\u5f84\u3002\u534e\u5357\u7406\u5de5\u5927\u5b66\u7684\u674e\u6620\u4f1f\uff0c\u6c5f\u7115\u5cf0\u6559\u6388\u7b49\u62a5\u9053\u4e86\u82b3\u57fa\u6c2f\u5316\u7269\u5728Pd\/MIL-101\u4e0a\u7684\u6c34\u4ecb\u5bfc\u5076\u8054\u53cd\u5e94\u3002MIL-101\u5177\u6709\u8f83\u5927\u7684\u8868\u9762\u79ef\u3001\u8f83\u5927\u7684\u5b54\u5f84\u548c\u8f83\u9ad8\u7684\u7a33\u5b9a\u6027\uff0c\u662f\u5236\u5907Pd 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loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-184154 aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2019\/08\/\u56fe\u72471-34.png\" alt=\"\" width=\"493\" height=\"489\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2019\/08\/\u56fe\u72471-34.png 493w, \/\/m.iemloyee.com\/wp-content\/uploads\/2019\/08\/\u56fe\u72471-34-150x150.png 150w, \/\/m.iemloyee.com\/wp-content\/uploads\/2019\/08\/\u56fe\u72471-34-300x298.png 300w\" sizes=\"(max-width: 493px) 100vw, 493px\" \/><\/p>\n<p>\u4e3a\u4e86\u5b9e\u73b0NH<sub>3<\/sub>BH<sub>3<\/sub>\u7684\u6c34\u89e3\u9ad8\u6548\u8131\u6c22\uff0c\u65e5\u672c\u56fd\u5bb6\u5148\u8fdb\u5de5\u4e1a\u79d1\u5b66\u6280\u672f\u7814\u7a76\u9662Xu Qiang\u6559\u6388\u8bfe\u9898\u7ec4\u62a5\u9053\u4e86\u5728MIL-101\u4e2d\u5236\u5907\u4e86\u5305\u8986\u826f\u597d\u7684Pt 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loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-184156 aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2019\/08\/\u56fe\u72473-30.png\" alt=\"\" width=\"688\" height=\"417\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2019\/08\/\u56fe\u72473-30.png 688w, \/\/m.iemloyee.com\/wp-content\/uploads\/2019\/08\/\u56fe\u72473-30-300x182.png 300w\" sizes=\"(max-width: 688px) 100vw, 688px\" \/><\/p>\n<p>\u7f8e\u56fd\u7231\u8377\u534e\u5dde\u7acb\u5927\u5b66\u7684Wenyu Huang\u6559\u6388\u7684\u56e2\u961f\u5728\u4ee5\u6c28\u57fa\u5b98\u80fd\u56e2\u5316\u7684MOF\uff1aUiO-66-NH<sub>2<\/sub>\u5185\u5d4c\u5165\u7684Pt\u00a0NCs\u4e3a\u57fa\u7840\uff0c\u7814\u5236\u4e86\u4e00\u79cd\u9009\u62e9\u6027\u5f3a\u3001\u6027\u80fd\u4f18\u826f\u7684\u50ac\u5316\u5242\uff0c\u7a7a\u8154\u5185\u5c01\u88c5\u4e86\u5355\u5206\u6563Pt 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NCs\uff0c\u65e0\u6cd5\u5b9e\u73b0\u9ad8\u8089\u6842\u9187\u9009\u62e9\u6027\u3002\u503c\u5f97\u6ce8\u610f\u7684\u662f\uff0c\u5404\u79cd\u975e\u5747\u76f8\u548c\u5747\u76f8\u8d35\u91d1\u5c5e\u57fa\u50ac\u5316\u5242\uff0c\u5305\u62ecAu\u3001Pd\u3001Pt\u3001Ru\u3001Rh\u3001Ir\u5bf9\u8be5\u53cd\u5e94\u5747\u6709\u6d3b\u6027\uff0c\u4f46\u5bf9\u8089\u6842\u9187\u7684\u9009\u62e9\u6027\u8f83\u4f4e\uff0c\u56e0\u4e3aC=C\u52a0\u6c22\u6bd4C=O\u52a0\u6c22\u70ed\u529b\u5b66\u4e0a\u66f4\u6709\u5229\u3002\u5f71\u54cd\u8089\u6842\u919b\u52a0\u6c22\u53cd\u5e94\u9009\u62e9\u6027\u7684\u56e0\u7d20\u6709\u8f7d\u4f53\u3001MNP\u5927\u5c0f\u3001\u6dfb\u52a0\u5242\u7b49\u3002\u5176\u4e2d\uff0cMOF\u5b54\u9699\u65bd\u52a0\u7684\u7a7a\u95f4\u4f4d\u963b\u6548\u5e94\u5360\u4e3b\u5bfc\u5730\u4f4d\u3002\u7531\u4e8ePt NCs\u5c01\u88c5\u5728UiO-66-NH<sub>2<\/sub>\u4e2d\uff0c\u5bf9Pt NCs\u7684\u63a5\u8fd1\u53d7\u5230\u4e86UiO-66-NH<sub>2<\/sub>\u4e2d\u8fde\u63a5\u56db\u9762\u4f53\u548c\u516b\u9762\u4f53\u7b3c\u76846\u4e2a\u4e09\u89d2\u5f62\u7a97\u53e3\u7684\u4e25\u683c\u9650\u5236\u3002\u540c\u65f6\uff0c\u7531\u4e8eUiO-66-NH<sub>2<\/sub>\u7684\u4f4d\u963b\u4f5c\u7528\uff0c\u4e0e\u5206\u5b50\u672b\u7aef\u7684C=O\u952e\u76f8\u6bd4\uff0c\u8089\u6842\u919b\u4e2d\u95f4\u7684C=C\u952e\u5f88\u96be\u63a5\u8fd1Pt\u8868\u9762\u3002\u6b64\u5916\uff0c\u8be5\u50ac\u5316\u5242\u53ef\u5faa\u73af\u4f7f\u752810\u6b21\uff0c\u5176\u6d3b\u6027\u548c\u9009\u62e9\u6027\u65e0\u4efb\u4f55\u635f\u5931\u3002<sup>[<\/sup><sup>6]<\/sup><\/p>\n<p><strong>\u56fe4\u00a0\u8089\u6842\u919b\u5728Pt@UiO-66-NH<sub>2<\/sub>\u4e0a\u9009\u62e9\u6027\u7684\u6c34\u89e3\u53cd\u5e94<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-184157 aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2019\/08\/\u56fe\u72474-29.png\" alt=\"\" width=\"467\" height=\"276\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2019\/08\/\u56fe\u72474-29.png 467w, \/\/m.iemloyee.com\/wp-content\/uploads\/2019\/08\/\u56fe\u72474-29-300x177.png 300w\" sizes=\"(max-width: 467px) 100vw, 467px\" \/><\/p>\n<h3><strong><b>MNPs\u4f5c\u4e3a\u6d3b\u6027\u4e2d\u5fc3\uff0cMOF\u7528\u4e8e\u7a33\u5b9aMNPs\uff0c\u4e14\u5e95\u7269\u5bcc\u96c6<\/b><\/strong><\/h3>\n<p>\u5728\u8bb8\u591a\u91cd\u8981\u7684\u53cd\u5e94\u4e2d\uff0c\u90fd\u6d89\u53ca\u5230\u6c14\u4f53\u5206\u5b50\u3002\u5df2\u6709\u62a5\u9053\u8868\u660e\uff0cMNPs\/MOFs\u53ef\u4ee5\u5bcc\u96c6\u6d3b\u6027\u4f4d\u70b9\u5468\u56f4\u7684\u6c14\u4f53\u5206\u5b50\uff0c\u4ece\u800c\u63d0\u9ad8\u50ac\u5316\u6548\u7387\u3002<\/p>\n<p>\u4e1c\u4eac\u5927\u5b66\u7684Hirokazu Kobayashi\uff0cHiroshi Kitagawa\u6559\u6388\u7b49\u4eba\u62a5\u5bfc\u4e86MOFs\u5bf9\u5176\u6c22\u5438\u9644\u6027\u80fd\u7684\u5f71\u54cd\uff0c\u4ed6\u4eec\u53d1\u73b0MOF\uff1a\u00a0HKUST-1(Cu (II))\u5305\u8986\u7684Pd\u7eb3\u7c73\u6676\u50a8\u6c22\u80fd\u529b\u548c\u901f\u5ea6\u663e\u8457\u63d0\u9ad8\u3002MOF\u5305\u8986\u7684Pd\u7eb3\u7c73\u6676\u7684\u5b58\u50a8\u5bb9\u91cf\u662f\u88f8\u6f0fPd\u7eb3\u7c73\u6676\u4f53\u7684\u4e24\u500d\u3002\u901a\u8fc7\u6c22\u538b\u529b-\u7ec4\u6210\u7b49\u6e29\u7ebf\u548c\u56fa\u6001\u6c18\u6838\u78c1\u70ed\u5bb9\u6d4b\u8bd5\uff0c\u8bc1\u5b9e\u4e86\u8be5\u65b9\u6cd5\u663e\u8457\u63d0\u9ad8\u4e86\u50a8\u6c22\u80fd\u529b\u3002\u6b64\u5916\uff0cPd@HKUST-1\u8868\u73b0\u51fa\u5b8c\u5168\u53ef\u9006\u7684\u5438\u6536\/\u89e3\u5438\u53cd\u5e94\u3002\u8fd9\u4e9b\u7ed3\u679c\u8868\u660e\uff0c\u5305\u8986\u5728Pd\u7eb3\u7c73\u7ba1\u4e0a\u7684HKUST-1\u53ef\u4ee5\u63d0\u9ad8Pd\u7eb3\u7c73\u7ba1\u7684\u6c22\u5bb9\u91cf\uff0c\u63d0\u9ad8\u6c22\u7684\u5438\u6536\/\u89e3\u5438\u901f\u5ea6\u3002\u6587\u4e2d\u7814\u7a76\u7ed3\u679c\u8868\u660e\uff0c\u901a\u8fc7\u5728Pd\u7eb3\u7c73\u6676\u8868\u9762\u5305\u8986HKUST-1\u7684\u5438\u6536\u7279\u6027\u53d1\u751f\u4e86\u663e\u8457\u7684\u53d8\u5316\uff0cPd\u7684\u50a8\u6c22\u80fd\u529b\u63d0\u9ad8\u4e8674%\u3002\u6b64\u5916\uff0cHKUST-1\u6d82\u5c42\u7684\u5b58\u5728\u4e5f\u4f1a\u589e\u5f3a\u50a8\u6c22\u52a8\u529b\u5b66\u3002\u8fd9\u4e9b\u53d1\u73b0\u8868\u660e\uff0cMOF\u6d82\u5c42\u7684\u5b58\u5728\u6781\u5927\u5730\u6539\u53d8\u4e86\u7eb3\u7c73\u6676\u4f53\u7684\u8868\u9762\/\u4f53\u79ef\u53cd\u5e94\u6d3b\u6027\uff0c\u4f7f\u5176\u66f4\u5bb9\u6613\u4e0e\u6c22\u53cd\u5e94\uff0c\u3002\u867d\u7136Pd\u76f8\u5bf9\u7a00\u5c11\u4e14\u6602\u8d35\uff0c\u4f46\u8fd9\u79cd\u589e\u5f3a\u65b9\u6cd5\u53ef\u4ee5\u7528\u4e8e\u5bfb\u627e\u6210\u672c\u8f83\u4f4e\u7684\u589e\u5f3a\u578b\u50a8\u6c22\u6750\u6599\u3002\u8fd9\u79cd\u589e\u5f3a\u7684\u53cd\u5e94\u6d3b\u6027\u53ef\u80fd\u4e5f\u9002\u7528\u4e8e\u8bb8\u591a\u5176\u4ed6\u7684\u91d1\u5c5e@ mof\u7cfb\u7edf\uff0c\u53ef\u80fd\u63d0\u4f9b\u4e86\u4e00\u79cd\u63d0\u9ad8\u7eb3\u7c73\u6676\u4f53\u53cd\u5e94\u6d3b\u6027\u7684\u901a\u7528\u65b9\u6cd5\u3002<sup>[<\/sup><sup>7]<\/sup><\/p>\n<p><strong>\u56fe5\u00a0Pd @HKUST-1\u50ac\u5316\u5242\u7684\u590d\u5408\u53ca\u8868\u5f81<\/strong><\/p>\n<p><strong><b><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-184158 aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2019\/08\/\u56fe\u72475-22.png\" alt=\"\" width=\"680\" height=\"654\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2019\/08\/\u56fe\u72475-22.png 680w, \/\/m.iemloyee.com\/wp-content\/uploads\/2019\/08\/\u56fe\u72475-22-300x289.png 300w\" sizes=\"(max-width: 680px) 100vw, 680px\" \/><\/b><\/strong><\/p>\n<p>MNP\/MOF\u5728C=C\u952e\u7684\u52a0\u6c22\u53cd\u5e94\u4e2d\u4e5f\u6709\u7814\u7a76,\u00a0\u5728\u8fd1\u671f\u7684\u7814\u7a76\u4e2d\uff0c\u4e2d\u56fd\u79d1\u5b66\u6280\u672f\u5927\u5b66\u7684\u6c5f\u6d77\u9f99\u6559\u6388\u5c06Pd 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NCs\u7684\u4fdd\u62a4\uff0c\u590d\u5408\u7269\u5c55\u73b0\u51fa\u4e86\u4f18\u5f02\u7684\u53ef\u5faa\u73af\u6027\u3002\u76f8\u5bf9\u4e8e\u666e\u901a\u7684\u52a0\u70ed\u9a71\u52a8\u6c22\u5316\u53cd\u5e94\uff0cPd NCs@ ZIF-8\u7684\u7b49\u79bb\u5b50\u9a71\u52a8\u7684\u5149\u70ed\u8f6c\u6362\u65b9\u5f0f\u5177\u6709\u66f4\u597d\u7684\u50ac\u5316\u6548\u7387\u3002\u5176\u4f18\u8d8a\u7684\u50ac\u5316\u6027\u80fd\u53ef\u4ee5\u5f52\u56e0\u4e8ePd NCs\u5bbd\u7684\u5438\u6536\u5e26\u548c\u8bb8\u591a\u89d2\u843d\u548c\u8fb9\u7f18\u4f4d\u7f6e\u7684Pd\u6d3b\u6027\u4f4d\u70b9\u3002\u8fd9\u4e2a\u7814\u7a76\u8fc7\u7a0b\u4e2d\uff0c\u9996\u6b21\u5c06\u91d1\u5c5e\u7eb3\u7c73\u6676\u7b49\u79bb\u5b50\u5171\u632f\u6548\u5e94\u548cMOFs\u7684\u4f18\u5f02\u6027\u80fd\u7ed3\u5408\u8d77\u6765\uff0c\u4f7f\u5149\u80fd\u8f6c\u5316\u4e3a\u70ed\u80fd\u9a71\u52a8\u50ac\u5316\u53cd\u5e94\u7684\u8fdb\u884c\u3002\u8fd9\u5c06\u53d1\u6325\u4e8c\u8005\u534f\u540c\u4f18\u52bf\uff0c\u5f00\u62d3\u4e86\u5229\u7528\u5149\u80fd\u800c\u4e0d\u662f\u70ed\u80fd\u7684\u9014\u5f84\u6765\u9a71\u52a8\u591a\u76f8\u50ac\u5316\u53cd\u5e94\u3002<sup>[<\/sup><sup>8]<\/sup><\/p>\n<p><strong>\u56fe6\u00a0\u81ea\u7ec4\u88c5Pd NCs@ ZIF-8\u7eb3\u7c73\u590d\u5408\u6750\u6599\u53ca\u5176\u7b49\u79bb\u5b50\u9a71\u52a8\u7684\u70ef\u70c3\u9009\u62e9\u6027\u52a0\u6c22\u50ac\u5316<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-184159 aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2019\/08\/\u56fe\u72476-18.png\" alt=\"\" width=\"680\" height=\"453\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2019\/08\/\u56fe\u72476-18.png 680w, \/\/m.iemloyee.com\/wp-content\/uploads\/2019\/08\/\u56fe\u72476-18-300x200.png 300w\" sizes=\"(max-width: 680px) 100vw, 680px\" \/><\/p>\n<h3><strong><b>MNPs\u4f5c\u4e3a\u6d3b\u6027\u4e2d\u5fc3\uff0cMOF\u8c03\u63a7MNPs\u7684\u8868\u9762\u7535\u5b50\u7ed3\u6784<\/b><\/strong><\/h3>\n<p>\u50ac\u5316\u6d3b\u6027\u4e2d\u5fc3\u7684\u6027\u8d28\u4e0e\u5176\u5468\u56f4\u7684\u5316\u5b66\u73af\u5883\u5bc6\u5207\u76f8\u5173\u3002\u7531\u4e8eMOF\u7ed3\u6784\u5177\u6709\u9ad8\u5ea6\u53ef\u8c03\u7684\u7279\u6027\uff0c\u60ac\u540a\u5728\u914d\u4f53\/\u91d1\u5c5e\u7c07\u4e0a\u7684\u5b9a\u5236\u5b98\u80fd\u56e2\u53ef\u4ee5\u5728\u539f\u5b50\u6c34\u5e73\u4e0a\u8c03\u8282\u7535\u5b50\u6027\u80fd\u3002\u5177\u6709\u4e0d\u540c\u5b98\u80fd\u56e2\u7684\u914d\u4f53\u4e0eMNPs\u7684\u76f8\u4e92\u4f5c\u7528\u4e0d\u540c\uff0c\u4ece\u800c\u5bfc\u81f4\u4e86\u50ac\u5316\u5242\u6d3b\u6027\u548c\u9009\u62e9\u6027\u7684\u53d8\u5316\u3002<\/p>\n<p>\u7231\u8377\u534e\u5dde\u7acb\u5927\u5b66Wenyu\u00a0Huang\u7684\u56e2\u961f\u8bc1\u660e\u4e86Pd NPs\u7684\u50ac\u5316\u6027\u80fd\u53ef\u4ee5\u901a\u8fc7\u6539\u53d8MOFs\u4e2d\u5b54\u58c1\u7684\u5316\u5b66\u73af\u5883\u6765\u63a7\u5236\u3002Pd NPs\u901a\u8fc7UiO -66\u578b\u7ed3\u6784\u5728\u539f\u5b50\u53ef\u8c03\u5316\u5b66\u73af\u5883\u4e2d\u7a33\u5b9a\uff0c\u5f97\u5230Pd\/MOFs(Pd@UiO-66-X, X = H, NH<sub>2<\/sub>, OMe)\u7528\u4e8e\u82ef\u7532\u919b\u4e0e\u4e59\u4e8c\u9187\u7684\u6709\u6c27\u53cd\u5e94\u3002\u503c\u5f97\u6ce8\u610f\u7684\u662f\uff0c\u82ef\u7532\u919b\u4e0e\u4e59\u4e8c\u9187\u7684\u53cd\u5e94\u6709\u4e24\u79cd\u53cd\u5e94\u9014\u5f84:(1)\u82ef\u7532\u919b\u4e0e\u4e59\u4e8c\u9187\u7f29\u5408\u5f97\u5230\u534a\u7f29\u919b;(2)\u8fdb\u4e00\u6b65\u7f29\u5408\u5f97\u5230\u7f29\u919b\u6216\u6c27\u5316\u5f97\u5230\u916f\u3002Pd@UiO-66-NH<sub>2<\/sub>\u5bf9\u82ef\u7532\u919b\u4e59\u70ef\u7f29\u919b\u7684\u9009\u62e9\u6027\u8fbe\u523094%\uff0c\u800cPd@UiO-66\u548cPd@UiO-66- OMe\u5bf92-\u7f9f\u57fa\u82ef\u7532\u9178\u916f\u7684\u9009\u62e9\u6027\u5747\u8fbe\u5230\u4e8690%\u548c97%\uff0c\u5728UiO-66-X\u4e2d\u7684\u6709\u673a\u94fe\u63a5\u4ece-NH<sub>2<\/sub>\u5230-H \/-OMe\u7684\u5b98\u80fd\u56e2\u7684\u53d8\u5316\u53ef\u4ee5\u4f7f\u4ea7\u7269\u7684\u9009\u62e9\u6027\u4ece\u7f29\u919b\u5b8c\u5168\u8f6c\u53d8\u4e3a\u916f\uff0c\u6f2b\u53cd\u5c04\u7ea2\u5916\u5085\u91cc\u53f6\u53d8\u6362\u5149\u8c31(DRIFTS)\u8868\u660e\uff0cPd\/UiO-66-NH<sub>2<\/sub>\u4e2d-NH<sub>2<\/sub>\u4e0ePd NPs\u7684\u76f8\u4e92\u4f5c\u7528\u5f71\u54cdPd NPs\u7684\u7535\u5b50\u5bc6\u5ea6\u548c\u53cd\u5e94\u7269\u5438\u9644\u3002\u5bc6\u5ea6\u6cdb\u51fd\u7406\u8bba(DFT)\u8ba1\u7b97\u8868\u660e\uff0c\u4e0d\u540c\u5b98\u80fd\u56e2\u5bf9Pd NPs\u6c27\u5316\u80fd\u529b\u7684\u5f71\u54cd\uff0c\u5316\u5b66\u52bf\u7684\u589e\u52a0\u4f1a\u635f\u5bb3Pd NPs\u548cUiO-66-NH<sub>2<\/sub>\u7684\u6c27\u5316\u6027\u80fd\uff0c\u5bfc\u81f4\u5316\u5b66\u52bf\u7684\u589e\u52a0\u6bd4UiO-66-OMe\u66f4\u5927\u3002\u56e0\u6b64,\u6c27\u5316\u6027\u80fd\u76f8\u5bf9\u8f83\u5f31\u7684Pd@UiO-66-NH<sub>2<\/sub>\u4f1a\u963b\u788d\u7535\u5b50\u4ece\u53cd\u5e94\u7269\u4e2d\u64a4\u51fa\uff0c\u4ece\u800c\u963b\u788d\u916f\u7c7b\u7684\u751f\u6210\uff0c\u5bfc\u81f4\u7f29\u919b\u9009\u62e9\u6027\u9ad8\u3002\u76f8\u6bd4\u4e4b\u4e0b\uff0c\u672c\u53d1\u660e\u7684\u6c27\u5316\u6027\u80fd\u9002\u4e2d\uff0c\u5408\u6210\u4ea7\u7269\u5bf9\u916f\u7c7b\u7684\u5f62\u6210\u5177\u6709\u8f83\u9ad8\u7684\u50ac\u5316\u6d3b\u6027\u3002<sup>[<\/sup><sup>9]<\/sup><\/p>\n<p><strong>\u56fe7\u7b49\u5242\u91cf\u7684UiO-66-X\u63a7\u5236Pd NPs\u50ac\u5316\u6027\u80fd<\/strong><\/p>\n<p><strong><b><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-184160 aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2019\/08\/\u56fe\u72477-16.png\" alt=\"\" width=\"482\" height=\"227\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2019\/08\/\u56fe\u72477-16.png 482w, \/\/m.iemloyee.com\/wp-content\/uploads\/2019\/08\/\u56fe\u72477-16-300x141.png 300w\" sizes=\"(max-width: 482px) 100vw, 482px\" \/><\/b><\/strong><\/p>\n<p>\u57fa\u4e8eMOFs\u7684\u534a\u5bfc\u4f53\u6027\u8d28\uff0c\u5149\u5f3a\u7684\u6539\u53d8\u4f1a\u5f71\u54cdMOF\u548cMNPs\u4e4b\u95f4\u7535\u5b50\u8f6c\u79fb\u7684\u65b9\u5411\uff0c\u4ece\u800c\u6539\u53d8MNPs\u7684\u7535\u5b50\u72b6\u6001\u548c\u50ac\u5316\u6d3b\u6027\u3002\u4e2d\u79d1\u5927\u6c5f\u6d77\u9f99\u6559\u6388\u7684\u56e2\u961f\u89c2\u5bdf\u5230MNPs\u548c\u535f\u5549\u578bMOFs \uff1aPCN-224(M)\u4e4b\u95f4\u6709\u8da3\u7684\u7535\u5b50\u8f6c\u79fb\uff0c\u5b83\u901a\u8fc7\u6539\u53d8\u5149\u7684\u7167\u5c04\u5f3a\u5ea6\u6765\u8c03\u8282\u94c2\u8868\u9762\u7684\u7535\u5b50\u72b6\u6001\uff0c\u4ece\u800c\u8c03\u8282\u9187\u6c27\u5316\u7684\u50ac\u5316\u6548\u7387\uff0cPt\u7eb3\u7c73\u6676\u548cPCN-224\u5747\u80fd\u5728\u5149\u7167\u4e0b\u8bf1\u53d1\u5149\u70ed\u6548\u5e94\uff0c\u6709\u6548\u4fc3\u8fdb\u5438\u70ed\u53cd\u5e94\u7684\u8fdb\u884c\u3002\u540c\u65f6\uff0cPt\u7eb3\u7c73\u6676\u548cPCN-224(M)\u90fd\u53ef\u4ee5\u6709\u6548\u5730\u6d3b\u5316\u5206\u5b50\u6c27\u4ea7\u751f\u5355\u7ebf\u6001\u6c27\uff08<sup>1<\/sup>O<sub>2<\/sub>\uff09\uff0c\u7814\u7a76\u663e\u793a\uff0c\u6539\u53d8MOF\u4e2d\u535f\u5549\u4e2d\u5fc3\u7684\u91d1\u5c5e\u53ef\u4ee5\u5f71\u54cd\u5355\u7ebf\u6001\u6c27\u7684\u4ea7\u751f\uff0cPt\/PCN-224(Zn)\u5177\u6709\u6700\u597d\u7684\u5355\u7ebf\u6001\u6c27\u7684\u4ea7\u751f\u80fd\u529b<strong><b>\u3002<\/b><\/strong>\u5728\u4e0d\u540c\u7684\u5149\u7167\u5f3a\u5ea6\u4e0b\uff0cPCN-224(Zn)\u548cPt\u7eb3\u7c73\u6676\u4e4b\u95f4\u7535\u5b50\u8f6c\u79fb\u65b9\u5411\u7531\u8096\u7279\u57fa\u7ed3\u00a0\uff08Schottky junction\uff09\u548cplasmonic\u6548\u5e94\u4e4b\u95f4\u7684\u7ade\u4e89\u6548\u5e94\u6765\u4e3b\u5bfc\u3002\u56e0\u6b64\uff0c\u53ef\u4ee5\u901a\u8fc7\u6539\u53d8\u5149\u5f3a\u5b9e\u73b0Pt\u7eb3\u7c73\u6676\u8868\u9762\u7684\u7535\u5b50\u6001\u7684\u64cd\u63a7\uff0c\u4ece\u800c\u6539\u53d8\u5355\u7ebf\u6001\u6c27\u7684\u4ea7\u751f\u548c\u76f8\u5e94\u7684\u50ac\u5316\u6027\u80fd\u3002\u8fdb\u4e00\u6b65\u7814\u7a76\u53d1\u73b0\uff0c\u901a\u8fc7\u5c06Pt\/PCN-224(Zn)\u5e94\u7528\u4e8e\u82ef\u7532\u9187\u53ca\u5176\u884d\u751f\u7269\u7684\u9009\u62e9\u6027\u50ac\u5316\u53cd\u5e94\u53d1\u73b0\uff0c\u901a\u8fc7\u6539\u53d8\u5149\u5f3a\u64cd\u63a7Pt\u8868\u9762\u7535\u5b50\u6001\u4f18\u5316\u5355\u7ebf\u6001\u6c27\u4ea7\u751f\uff0c\u5728\u975e\u5e38\u6e29\u548c\u7684\u6761\u4ef6\u4e0b\uff08\u5ba4\u6e29\u3001\u53ef\u89c1\u5149\u548c1 atm O<sub>2<\/sub>\uff09\uff0c\u6210\u529f\u5b9e\u73b0\u4e86\u82ef\u7532\u9187\u53ca\u5176\u884d\u751f\u7269\u5230\u76f8\u5e94\u919b\u7684\u9ad8\u6548\u3001\u9ad8\u9009\u62e9\u6027\u50ac\u5316\u8f6c\u5316\uff0c\u4e14\u53cd\u5e94\u7684\u5faa\u73af\u7a33\u5b9a\u6027\u4e5f\u975e\u5e38\u597d\u3002<sup>[<\/sup><sup>10]<\/sup><\/p>\n<p><strong>\u56fe8\u00a0\u5728Pt\/PCN-224(M)\u4e0a\u5355\u7ebf\u6001\u6c27\u7684\u4ea7\u751f\u548c\u76f8\u5e94\u50ac\u5316\u6027\u80fd<\/strong><\/p>\n<p><strong><b><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-184161 aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2019\/08\/\u56fe\u72478-12.png\" alt=\"\" width=\"680\" height=\"461\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2019\/08\/\u56fe\u72478-12.png 680w, \/\/m.iemloyee.com\/wp-content\/uploads\/2019\/08\/\u56fe\u72478-12-300x203.png 300w\" sizes=\"(max-width: 680px) 100vw, 680px\" \/><\/b><\/strong><\/p>\n<h3><strong><b>MNPs\u4f5c\u4e3a\u7535\u5b50\u53d7\u4f53\u548c\u6d3b\u6027\u4e2d\u5fc3\uff0cMOF\u4f5c\u4e3a\u5149\u654f\u5242<\/b><\/strong><\/h3>\n<p>\u968f\u7740\u7814\u7a76\u7684\u4e0d\u65ad\u6df1\u5165\uff0cMOFs\u7684\u529f\u80fd\u4e5f\u5f97\u5230\u4e86\u8fdb\u4e00\u6b65\u7684\u63a2\u7d22\u3002MNP\/MOF\u590d\u5408\u6750\u6599\u9664\u4e86\u5728\u4e0a\u8ff0\u5e38\u89c1\u7684\u6709\u673a\u53cd\u5e94\u4e2d\u53d7\u5230\u5e7f\u6cdb\u7684\u5173\u6ce8\u5916\uff0c\u5728\u5149\u50ac\u5316\u7814\u7a76\u9886\u57df\u4e5f\u5177\u6709\u91cd\u8981\u7684\u5730\u4f4d\u3002\u7531\u4e8e\u5177\u6709\u7279\u6b8a\u7684\u6709\u673a\u914d\u4f53\u94fe\u63a5\uff0cMOFs\u5bf9\u7d2b\u5916\u7ebf\u751a\u81f3\u662f\u5927\u8303\u56f4\u7684\u53ef\u89c1\u5149\u90fd\u6709\u53cd\u5e94\uff0c\u56e0\u6b64\u9002\u5408\u4f5c\u4e3a\u5149\u654f\u5242\u7531MOFs\u7a33\u5b9a\u7684MNPs\u901a\u5e38\u8868\u73b0\u4e3a\u4f18\u826f\u7684\u7535\u5b50\u53d7\u4f53\u548c\u6d3b\u6027\u4e2d\u5fc3\uff0c\u5b83\u4eec\u4ece\u88ab\u6fc0\u53d1\u7684MOFs\u4e2d\u63a5\u53d7\u7535\u5b50\uff0c\u800cMOFs\u548cMNPs\u529f\u80fd\u7684\u6574\u5408\u53ef\u4ee5\u6709\u6548\u5730\u4fc3\u8fdb\u5149\u50ac\u5316\u53cd\u5e94\u3002<\/p>\n<p>\u5317\u5361\u7f57\u6765\u7eb3\u5927\u5b66Wenbin\u00a0Lin\u6559\u6388\u548c\u540c\u4e8b\u57fa\u4e8e[Ir <sup>III<\/sup>\u00a0(ppy)<sub>2<\/sub>(bpy)]<sup>+<\/sup>\u884d\u751f\u7684\u4e8c\u7fa7\u9178\u76d0\u914d\u4f53\u548cZr<sub>6<\/sub>(\u03bc<sub>3<\/sub>-O)<sub>4<\/sub>(\u03bc<sub>3<\/sub>-OH)<sub>4<\/sub>(carboxylate)<sub>12<\/sub>\u00a0\u4e3aSBUs\u5236\u5907\u4e86\u4e00\u79cd\u5149\u6d3b\u6027UiO\u578bMOF\uff0c\u5176\u4e2dPt NPs\u7531K<sub>2<\/sub>PtCl<sub>4<\/sub>\u5149\u8fd8\u539f\u539f\u4f4d\u751f\u6210\u3002\u5408\u6210\u7684Pt@MOF\u590d\u5408\u6750\u6599\u5728\u53ef\u89c1\u5149(&gt;420 nm)\u6761\u4ef6\u4e0b\uff0c\u5bf9\u6c34\u7684\u5149\u50ac\u5316\u5236\u6c22\u6548\u679c\u826f\u597d\u3002\u7ea2\u5916\u8367\u5149\u7c89(Ir-TON)\u57286 h\u5185\u7684\u6c22\u6f14\u5316\u5468\u8f6c\u7387(TON)\u6700\u9ad8\uff081620\uff09\uff0c\u5177\u6709\u8f83\u9ad8\u7684\u5149\u5316\u5b66\u91cf\u5b50\u4ea7\u7387\u3002\u53cd\u5e94\u7ed3\u675f\u540e\uff0c\u8be5\u50ac\u5316\u5242\u53ef\u901a\u8fc7\u79bb\u5fc3\u4ece\u6eb6\u6db2\u4e2d\u56de\u6536\uff0c\u5728\u4e0d\u6dfb\u52a0K<sub>2<\/sub>PtCl<sub>4<\/sub>\u7684\u65b0\u6eb6\u6db2\u4e2d\u53ef\u4ee5\u5b9e\u73b0\u518d\u6b21\u6790\u6c22\u3002\u50ac\u5316\u5242\u81f3\u5c11\u53ef\u56de\u6536\u4e09\u6b21\uff0c\u63a7\u5236\u5b9e\u9a8c\u4e2d\u4e0d\u6dfb\u52a0MOF\u6216K<sub>2<\/sub>PtCl<sub>4<\/sub>\u5728\u76f8\u540c\u7684\u6761\u4ef6\u4e0b\u5bf9\u6eb6\u6db2\u8fdb\u884c\u64cd\u4f5c\uff0c\u4f46\u6ca1\u6709\u68c0\u6d4b\u5230\u4ece\u6c34\u4e2d\u6790\u51fa\u7684\u6c22\uff0c\u6e05\u695a\u5730\u663e\u793a\u4e86\u4e24\u79cd\u7269\u8d28\u7684\u534f\u540c\u4f5c\u7528\u3002\u901a\u8fc7\u5bf9\u6bd4\u5b9e\u9a8c\uff0c\u4f5c\u8005\u8ba4\u4e3a\u534f\u540c\u5149\u50ac\u5316\u6c22\u7684\u53d1\u751f\u662f\u901a\u8fc7\u5149\u6355\u83b7\u8fc7\u7a0bMOF\u4e2d\u7535\u5b50\u7684\u5149\u6ce8\u5165Pt NPs\u6765\u5b9e\u73b0\u7684\uff0c[Ir<sup>III<\/sup>(ppy)<sub>2<\/sub>\u00a0(bpy\u2022-)]\u7684\u5149\u8fd8\u539f\u53cd\u5e94\u4ea7\u751f\u7684\u81ea\u7531\u57fa\u53ef\u4ee5\u5c06\u7535\u5b50\u8f6c\u79fb\u5230Pt NPs\u6765\u51cf\u5c11\u751f\u4ea7\u6c22\u7684\u8d28\u5b50\u6570\u3002<sup>[<\/sup><sup>11]<\/sup><\/p>\n<p><strong>\u56fe9\u00a0UiO\u578bMOF@NPs\u534f\u540c\u5149\u50ac\u5316\u6c22\u6f14\u5316<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-184162 aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2019\/08\/\u56fe\u72479-12.png\" alt=\"\" width=\"680\" height=\"320\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2019\/08\/\u56fe\u72479-12.png 680w, \/\/m.iemloyee.com\/wp-content\/uploads\/2019\/08\/\u56fe\u72479-12-300x141.png 300w\" sizes=\"(max-width: 680px) 100vw, 680px\" \/><\/p>\n<p>\u5728\u8fd1\u671f\u7684\u4e00\u9879\u7814\u7a76\u4e2d\uff0c\u5f20\u7fa4\u6559\u6388\u7b49\u4eba\u7814\u7a76\u4e86\u5728MNPs\/MOFs\u4f53\u7cfb\u4e2d\u7535\u5b50\u7a7a\u7a74\u5206\u79bb\u548c\u8f7d\u6d41\u5b50\u5229\u7528\u5149\u50ac\u5316\u7684\u6548\u7387\uff0c\u7814\u7a76\u5458\u4eec\u5408\u6210\u4e86\u4e24\u79cd\u7c7b\u578b\u7684\u590d\u5408\u6750\u6599:\u5c06\u7ea63nm\u7684Pt NPs\u63ba\u5165\u5176\u4e2d\u6216\u8d1f\u8f7d\u5728MOF\uff1aUiO-66-NH<sub>2<\/sub>\uff0c\u5206\u522b\u63d0\u4f9bPt@UiO-66-NH<sub>2<\/sub>\u548cPt\/UiO-66-NH<sub>2<\/sub>\uff0c\u7528\u4e8e\u6c34\u88c2\u89e3\u5149\u50ac\u5316\u5236\u6c22\u3002\u4e0e\u539f\u59cb\u7684MOF\u76f8\u6bd4\uff0c\u8fdb\u884c\u4e86Pt\u4fee\u9970\u7684MOF\u590d\u5408\u6750\u6599\u7684\u4ea7\u6c22\u6d3b\u6027\u6709\u663e\u8457\u63d0\u9ad8\uff0c\u4f46\u5b58\u5728\u660e\u663e\u5dee\u5f02\u3002\u4e3a\u4e86\u786e\u5b9a\u7535\u8377\u5206\u79bb\u6548\u7387\uff0c\u8fdb\u884c\u4e86\u5149\u7535\u6d41\u6d4b\u91cf\uff0c\u7ed3\u679c\u8868\u660e\uff0c\u4e0e\u539f\u59cb\u7684UiO-66-NH<sub>2<\/sub>\u76f8\u6bd4\uff0c\u7ecf\u8fc7Pt\u4fee\u9970\u7684UiO-66-NH<sub>2<\/sub>\u590d\u5408\u6750\u6599\u7684\u5149\u7535\u6d41\u5747\u6709\u6240\u589e\u5f3a\uff0c\u8fd9\u8bf4\u660e\u5f62\u6210Pt-MOF\u8096\u7279\u57fa\u7ed3\u5bf9\u5206\u79bb\u5149\u751f\u7535\u5b50\u7a7a\u7a74\u5bf9\u662f\u6709\u7528\u7684\u3002Pt@UiO-66-NH<sub>2<\/sub>\u6bd4Pt\/UiO-66-NH<sub>2<\/sub>\u8868\u73b0\u51fa\u66f4\u5f3a\u7684\u5149\u7535\u6d41\u54cd\u5e94\uff0c\u8868\u660e\u524d\u8005\u5177\u6709\u66f4\u9ad8\u7684\u7535\u8377\u4eceMOF\u8f6c\u79fb\u5230Pt NPs\u7684\u6548\u7387\u3002\u7535\u5316\u5b66\u963b\u6297\u8c31(EIS)\u7ed3\u679c\u4e5f\u652f\u6301\u4e86\u8fd9\u4e00\u89c2\u70b9,Pt@UiO-66-NH<sub>2<\/sub>\u7684\u534a\u5f84\u8f83\u5c0f\uff0c\u8868\u660e\u7535\u8377\u8f6c\u79fb\u7535\u963b\u8f83\u4f4e\u3002\u6b64\u5916\uff0c\u8d85\u5feb\u77ac\u6001\u5438\u6536\u5149\u8c31\u63ed\u793a\u4e86\u5176\u6f5c\u5728\u7684\u7535\u5b50\u8f6c\u79fb\u673a\u5236\uff0c\u5e76\u8868\u660e\u5728Pt@MOF\u4e2d\u5b9e\u73b0\u4e86\u6bd4\u5728Pt\/MOF\u548c\u7eafMOF\u4e2d\u66f4\u6709\u6548\u7684\u7535\u8377\u5206\u79bb\u3002\u7ed3\u679c\u8868\u660e\uff0c\u4e0eMOF\u548cPt\/MOF\u76f8\u6bd4\uff0cPt@MOF\u80fd\u66f4\u6709\u6548\u5730\u6291\u5236\u7535\u5b50-\u7a7a\u7a74\u590d\u5408\u3002\u5176\u4e2d\uff0c\u5c01\u88c5\u826f\u597d\u7684Pt NPs(\u4eceMOF\u5230Pt\u7684\u7535\u5b50\u8f93\u8fd0\u8ddd\u79bb\u8f83\u77ed)\u53ef\u4ee5\u5feb\u901f\u63d0\u53d6MOF\u7684\u5149\u7535\u5b50\uff0c\u4ece\u800c\u4f7f\u5f97Pt@UiO-66-NH<sub>2<\/sub>\u7684\u50ac\u5316\u6d3b\u6027\u8fdc\u8fdc\u4f18\u4e8ePt\/UiO-66-NH<sub>2<\/sub>\u548cUiO-66-NH<sub>2<\/sub>\u3002<sup>[<\/sup><sup>12]<\/sup><\/p>\n<p><strong>\u56fe10 \u5408\u6210Pt@UiO-66-NH<sub>2<\/sub>\u548cPt\/UiO-66-NH<sub>2<\/sub>\u7684\u539f\u7406\u56fe<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-184163 aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2019\/08\/\u56fe\u724710-11.png\" alt=\"\" width=\"680\" height=\"489\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2019\/08\/\u56fe\u724710-11.png 680w, \/\/m.iemloyee.com\/wp-content\/uploads\/2019\/08\/\u56fe\u724710-11-300x216.png 300w\" sizes=\"(max-width: 680px) 100vw, 680px\" \/><\/p>\n<h3><strong><b>MNPs\u548cMOF\u5747\u4f5c\u4e3a\u6d3b\u6027\u4e2d\u5fc3<\/b><\/strong><strong><b>\u00a0<\/b><\/strong><\/h3>\n<p>\u5728\u4e0a\u8ff0MNPs\u4e0eMOFs\u7684\u529f\u80fd\u534f\u540c\u7814\u7a76\u4e2d\uff0c\u867d\u7136\u5408\u6210\u7684\u50ac\u5316\u6027\u80fd\u5f88\u597d\uff0c\u4f46\u50ac\u5316\u6d3b\u6027\u51e0\u4e4e\u90fd\u6765\u81ea\u4e8eMNPs\u548cMOFs\u3002MOF\u5f88\u5c11\u8868\u73b0\u51fa\u50ac\u5316\u884c\u4e3a\uff0c\u8fd9\u663e\u7136\u662f\u4e00\u4e2a\u9057\u61be\u3002\u5c06MOF\u50ac\u5316\u4e0eMNP\u50ac\u5316\u6709\u673a\u5730\u7ed3\u5408\u8d77\u6765\u8fdb\u884c\u5355\u9505\u591a\u6b65\u4e32\u8054\u53cd\u5e94\u662f\u975e\u5e38\u5fc5\u8981\u7684\uff0c\u5176\u4e2dMOFs\u548cMNPs\u4f5c\u4e3a\u6d3b\u6027\u4f4d\u70b9\u53d1\u6325\u5404\u81ea\u7684\u529f\u80fd\uff0c\u534f\u540c\u50ac\u5316\u7ea7\u8054\u53cd\u5e94\u3002<\/p>\n<p>\u56fd\u5bb6\u7eb3\u7c73\u79d1\u5b66\u6280\u672f\u4e2d\u5fc3\u5510\u667a\u52c7\u6559\u6388\u56e2\u961f\u5236\u9020\u4e86\u4e00\u4e2a\u6838-\u58f3\u7ed3\u6784\u7684Pd@IRMOF-3\u50ac\u5316\u5242\uff0c\u8be5\u50ac\u5316\u5242\u7531\u4e00\u4e2aPd NP (~35nm)\u6838\u548c\u4e00\u4e2a\u6c28\u57fa\u529f\u80fd\u5316\u7684IRMOF-3\u58f3\u5c42\u7ec4\u6210\uff0c\u7528\u4e8e\u7ea7\u8054\u53cd\u5e94\u3002\u5305\u62ec\u7531IRMOF-3\u58f3\u5c42\u7684\u78b1\u6027\u6c28\u57fa\u50ac\u5316\u76844-\u785d\u57fa\u82ef\u7532\u919b(A)\u548c\u4e19\u4e8c\u8148\u7f29\u5408\u62102-(4-\u785d\u57fa\u82c4\u57fa)\u4e19\u4e8c\u8148(B)\uff0c\u7136\u540e\u518d\u7531Pd NPs\u50ac\u5316\u7684\u785d\u57fa\u9009\u62e9\u6027\u52a0\u6c22\u751f\u6210\u6c28\u57fa\u4ea7\u7269(C)\uff0c\u3002\u7531\u4e8e\u591a\u79cd\u56e0\u7d20\u7684\u7efc\u5408\u4f5c\u7528\uff0c\u5305\u62ec\u9009\u62e9\u6027\u5438\u9644\u3001\u6052\u5b9a\u7684\u6269\u6563\u65b9\u5411\u548c\u5408\u9002\u7684\u5b54\u9699\u5927\u5c0f\uff0c\u6838-\u58f3\u5c42\u4e0e\u8d1f\u8f7d\u5728IRMOF-3\u4e0a\u7684Pd NPs\u50ac\u5316\u5242\u76f8\u6bd4\uff0cPd@IRMOF-3\u50ac\u5316\u5242\u5177\u6709\u66f4\u597d\u7684\u52a0\u6c22\u9009\u62e9\u6027\u548c\u7a33\u5b9a\u6027\u3002IRMOF-3\u8868\u9762\u7684\u6c28\u57fa\u57fa\u56e2\u4e0e\u5e95\u7269\u7684\u785d\u57fa\u8868\u73b0\u51fa\u4f18\u5148\u7684\u76f8\u4e92\u4f5c\u7528\u3002\u5f53\u91c7\u7528\u6838\u58f3Pd@IRMOF-3\u590d\u5408\u6750\u6599\u4f5c\u4e3a\u50ac\u5316\u5242\u65f6\uff0cA\u4f18\u5148\u8fdb\u5165-NO2\u57fa\u56e2\u5bf9\u4f4d\u7684\u50ac\u5316\uff0c\u8fdb\u5165\u540e\uff0c\u6838\u58f3\u7eb3\u7c73\u7ed3\u6784\u7684\u6709\u9650\u5b54\u5f84\u6210\u4e3a\u63a7\u5236C\u7684\u9009\u62e9\u6027\u7684\u53e6\u4e00\u4e2a\u91cd\u8981\u56e0\u7d20\u3002\u7531\u4e8eB\u7684\u4f53\u79ef\u8f83\u5927\uff0c\u4e14-NO2\u57fa\u56e2\u8f83\u5c0f\uff0c\u6240\u4ee5\u5728IRMOF-3\u901a\u9053\u5185\uff0cB\u5fc5\u987b\u5728-NO2\u57fa\u56e2\u540e\u9762\u4fdd\u6301\u4e00\u4e2a\u6052\u5b9a\u7684\u65b9\u5411\uff0c\u5bfc\u81f4\u9009\u62e9\u6027\u751f\u6210C\u800c\u4e0d\u662f\u5176\u4ed6\u53ef\u80fd\u7684\u52a0\u6c22\u4ea7\u7269\u3002<sup>[<\/sup><sup>13]<\/sup><\/p>\n<p><strong>\u56fe11\u00a0\u5728IRMOF-3\u58f3\u5c42\u7684\u50ac\u5316\u4e0b<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-184164 aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2019\/08\/\u56fe\u724711-9.png\" alt=\"\" width=\"680\" height=\"517\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2019\/08\/\u56fe\u724711-9.png 680w, \/\/m.iemloyee.com\/wp-content\/uploads\/2019\/08\/\u56fe\u724711-9-300x228.png 300w\" sizes=\"(max-width: 680px) 100vw, 680px\" \/><\/p>\n<p>\u9664\u4e86\u7b80\u5355\u5730\u7ec4\u5408\u4e3b\u4f53MOF\u548c\u5ba2\u4f53MNPs\u7684\u5355\u4e00\u529f\u80fd\u4e4b\u5916\uff0c\u4e2d\u79d1\u5927\u6c5f\u6d77\u9f99\u7b49\u4eba\u8ba4\u4e3a\u8fd8\u9700\u8981\u66f4\u8fdb\u4e00\u6b65\u5408\u6210\u5355\u91d1\u5c5e\u548c\u53cc\u91d1\u5c5eNPs@MOF\u50ac\u5316\u5242\uff0c\u5728MIL-101\u7b3c\u5185\u5177\u6709\u5fae\u5c0f\u7684\u91d1\u5c5eNPs\uff0c\u7528\u4e8e\u4e00\u9505\u591a\u6b65\u9009\u62e9\u6027\u53cd\u5e94\u3002\u5728MOF\u8def\u6613\u65af\u9178\u548cPd\u4f4d\u70b9\u7684\u57fa\u7840\u4e0a\uff0cPd@MOF\u534f\u540c\u50ac\u5316\u4e86\u4e32\u8054\u53cd\u5e94\u3002\u4ee4\u4eba\u611f\u5174\u8da3\u7684\u662f\uff0c\u53cc\u91d1\u5c5ePdAg@MOF\u590d\u5408\u6750\u6599\u6d89\u53ca\u4e09\u4e2a\u6d3b\u6027\u4f4d\u70b9(\u8def\u6613\u65af\u9178\u3001Pd\u548cAg)\uff0c\u80fd\u591f\u6210\u529f\u5730\u5b9e\u73b0\u4e00\u9505\u591a\u6b65\u7ea7\u8054\u53cd\u5e94\u5408\u6210\u4ef2\u82b3\u57fa\u80fa\u3002\u901a\u8fc7MOF\u4e0e\u91d1\u5c5eNP\u5ba2\u4f53\u7684\u5b8c\u7f8e\u914d\u5408\uff0c\u4ee5\u53ca\u53cc\u91d1\u5c5e\u94af\u4e0e\u94f6\u7684\u534f\u540c\u50ac\u5316\u4f5c\u7528\uff0c\u5176\u4e2dMOF\u63d0\u4f9b\u8def\u6613\u65af\u9178\u7684\u4f4d\u7f6e\uff0cPd\u63d0\u4f9b\u6c22\u5316\u6d3b\u6027\uff0c\u5e76\u4e14Ag\u5927\u5927\u63d0\u9ad8\u4e86\u5bf9\u6240\u9700\u4ea7\u54c1\u7684\u9009\u62e9\u6027\u3002\u6b64\u5916\uff0cMIL-101\u7684\u7406\u60f3\u7ea6\u675f\u6548\u5e94\u5bfc\u81f4\u4e86\u8d85\u7ec61.5 nm\u7684PdAg\u5408\u91d1NPs\uff0c\u53ef\u80fd\u662f\u8868\u9762\u6d3b\u6027\u5242\u4fdd\u62a4\u4e0b\u6700\u5c0f\u7684\u53cc\u91d1\u5c5eNPs\uff0c\u5373\u4f7f\u7ecf\u8fc7\u4e09\u6b21\u5faa\u73af\uff0cMNP\u7684\u5927\u5c0f\u4ecd\u7136\u4fdd\u6301\u4e0d\u53d8\uff0c\u7a81\u51fa\u4e86MOF\u7684\u7a33\u5b9a\u80fd\u529b\u3002\u8bc1\u660e\u4e86\u4e00\u4e2aMOF\u5bbf\u4e3b\u548c\u4e24\u4e2a\u91d1\u5c5eNP\u5ba2\u4f53\u5728\u50ac\u5316\u4e2d\u8d77\u5230\u201c\u4e09\u811a\u67b6\u7684\u4e09\u6761\u817f\u201d\u7684\u4f5c\u7528\uff0c\u534f\u540c\u4fc3\u8fdb\u4e86\u4e00\u9505\u591a\u6b65\u7ea7\u8054\u53cd\u5e94\uff0c\u8fd9\u662f\u7b2c\u4e00\u4e2a\u5173\u4e8eMOF\u4e3b\u3001\u5ba2\u4f53MNPs\u534f\u540c\u50ac\u5316\u53cc\u91d1\u5c5eNPs\u7684\u62a5\u9053\u3002<sup>[<\/sup><sup>14]<\/sup><\/p>\n<p><strong>\u56fe12\u00a0\u7ea7\u8054\u53cd\u5e94\u591a\u6b65\u5408\u6210\u4ef2\u82b3\u80fa\u53ca\u534f\u540c\u4e09\u79cd\u7ec4\u5206\u5b9e\u73b0\u4e86PdAg@MIL-101\u4e0a\u7684\u5355\u9505\u7ea7\u8054\u53cd\u5e94\u793a\u610f\u56fe<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-184165 aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2019\/08\/\u56fe\u724712-7.png\" alt=\"\" width=\"680\" height=\"592\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2019\/08\/\u56fe\u724712-7.png 680w, \/\/m.iemloyee.com\/wp-content\/uploads\/2019\/08\/\u56fe\u724712-7-300x261.png 300w\" sizes=\"(max-width: 680px) 100vw, 680px\" \/><\/p>\n<h3>\u53c2\u8003\u6587\u732e\uff1a<\/h3>\n<p>1 B. Yuan, Y. Pan, Y. Li, B. Yin and H. Jiang, Angew. Chem.,\u00a0Int. Ed., 2010, 49, 4054\u20134058.<\/p>\n<p>2\u00a0A. Aijaz, A. Karkamkar, Y. J. Choi, N. Tsumori, E. Ro \u00a8nnebro,\u00a0T. Autrey, H. Shioyama and Q. Xu, J. Am. Chem. Soc., 2012,\u00a0134, 13926\u201313929.<\/p>\n<p>3\u00a0Q.-L. Zhu, J. Li and Q. Xu, J. Am. Chem. Soc., 2013, 135,\u00a010210\u201310213.<\/p>\n<p>4\u00a0Y.-Z. Chen, Q. Xu, S.-H. Yu and H.-L. Jiang, Small, 2015, 11,\u00a071\u201376.<\/p>\n<p>5 C. J. Stephenson, J. T. Hupp and O. K. Farha, Inorg. Chem.,\u00a02016, 55, 1361\u20131363.<\/p>\n<p>6<u>\u00a0<\/u>Z. Guo, C. Xiao, R. V. Maligal-Ganesh, L. Zhou, T. W. Goh,X. Li, D. Tesfagaber, A. Thiel and W. Huang, ACS Catal.,\u00a02014, 4, 1340\u20131348.<\/p>\n<p>7\u00a0G. Li, H. Kobayashi, J. M. Taylor, R. Ikeda, Y. Kubota,\u00a0K. Kato, M. Takata, T. Yamamoto, S. Toh, S. Matsumura\u00a0and H. Kitagawa, Nat. Mater., 2014, 13, 802\u2013806.<\/p>\n<p>8\u00a0Q. Yang, Q. Xu, S.-H. Yu and H.-L. Jiang, Angew. Chem., Int.\u00a0Ed., 2016, 55, 3685\u20133689.<\/p>\n<p>9\u00a0X. Li, T. W. Goh, L. Li, C. Xiao, Z. Guo, X. C. Zeng and\u00a0W. Huang, ACS Catal., 2016, 6, 3461\u20133468.<\/p>\n<p>10 Y.-Z. Chen, Z. U. Wang, H. Wang, J. Lu, S.-H. Yu and\u00a0H.-L. Jiang, J. Am. Chem. Soc., 2017, 139, 2035\u20132044.<\/p>\n<p>11 C. Wang, K. E. deKrafft and W. Lin, J. Am. Chem. Soc., 2012,\u00a0134, 7211\u20137214.<\/p>\n<p>12 J.-D. Xiao, Q. Shang, Y. Xiong, Q. Zhang, Y. Luo, S.-H. Yu\u00a0and H.-L. Jiang, Angew. Chem., Int. Ed., 2016, 55,\u00a09389\u20139393.<\/p>\n<p>13 M. Zhao, K. Deng, L. He, Y. Liu, G. Li, H. Zhao and Z. Tang,\u00a0J. Am. Chem. Soc., 2014, 136, 1738\u20131741.<\/p>\n<p>14 Y.-Z. Chen, Y.-X. Zhou, H. Wang, J. Lu, T. Uchida,\u00a0Q. Xu, S.-H. Yu and H.-L. 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