{"id":182373,"date":"2019-08-03T06:33:52","date_gmt":"2019-08-02T22:33:52","guid":{"rendered":"\/\/m.iemloyee.com\/?p=182373"},"modified":"2019-08-02T22:52:27","modified_gmt":"2019-08-02T14:52:27","slug":"%e5%b1%b1%e4%b8%9c%e5%b8%88%e5%a4%a7%e8%91%a3%e8%82%b2%e6%96%8c%e6%95%99%e6%8e%88%e8%af%be%e9%a2%98%e7%bb%84nat-commun-%ef%bc%9a-%e8%b4%9f%e8%bd%bd%e9%87%91%e5%b1%9enps%e7%9a%84%e6%89%8b%e6%80%a7cof","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=182373","title":{"rendered":"\u5c71\u4e1c\u5e08\u5927\u8463\u80b2\u658c\u6559\u6388\u8bfe\u9898\u7ec4Nat.Commun.\uff1a \u8d1f\u8f7d\u91d1\u5c5eNPs\u7684\u624b\u6027COF\u901a\u8fc7\u5149\u70ed\u8f6c\u6362\u5f15\u53d1\u70ed\u9a71\u52a8\u4e0d\u5bf9\u79f0\u50ac\u5316"},"content":{"rendered":"

\u5f15\u8a00<\/b><\/strong><\/h3>\n

\u5149\u70ed\u8f6c\u6362\u6750\u6599\uff08PTCMs\uff09\u5c06\u5149\u80fd\u8f6c\u6362\u6210\u70ed\u80fd\uff0c\u5728\u5149\u70ed\u6cbb\u7597\uff08PTT\uff09\u3001\u5149\u70ed\/\u5149\u58f0\uff08PT\/PA\uff09\u6210\u50cf\u3001\u5149\u70ed\u7535\u5b50\u5668\u4ef6\u7b49\u9886\u57df\u5177\u6709\u5e7f\u6cdb\u7684\u5e94\u7528\u524d\u666f\uff0c\u7136\u800c\u57fa\u4e8ePTCM\u7684\u5149\u70ed\u624b\u6027\u50ac\u5316\u7814\u7a76\u751a\u5c11\u3002\u4f17\u6240\u5468\u77e5\uff0c\u5b9e\u73b0\u9ad8\u4ea7\u7387\u548c\u4f18\u5f02\u7684\u7acb\u4f53\u9009\u62e9\u6027\u5bf9\u624b\u6027\u5408\u6210\u5177\u6709\u91cd\u8981\u610f\u4e49\uff0c\u4e3a\u4e86\u83b7\u5f97\u9ad8\u5bf9\u6620\u9009\u62e9\u6027\uff0c\u76ee\u524d\u62a5\u9053\u7684\u70ed\u9a71\u52a8\u4e0d\u5bf9\u79f0\u50ac\u5316\u53cd\u5e94\u901a\u5e38\u5728\u4f4e\u6e29\u4e0b\u8fdb\u884c\uff0c\u4f46\u4ea7\u7387\u5f80\u5f80\u5f88\u4f4e\u3002\u56e0\u6b64\uff0c\u5b9e\u73b0\u9ad8\u7acb\u4f53\u9009\u62e9\u6027\u548c\u4ea7\u7387\u662f\u5de8\u5927\u7684\u6311\u6218\u3002\u4e3a\u4e86\u6ee1\u8db3\u70ed\u9a71\u52a8\u4e0d\u5bf9\u79f0\u50ac\u5316\u7684\u591a\u65b9\u9762\u8981\u6c42\uff0c\u8feb\u5207\u9700\u8981\u5f00\u53d1\u65b0\u7684\u7b56\u7565\u6765\u5236\u5907\u591a\u529f\u80fd\u590d\u5408\u50ac\u5316\u5242\u3002<\/p>\n

\u6210\u679c\u7b80\u4ecb<\/b><\/strong><\/h3>\n

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\u56fe\u6587<\/b><\/strong>\u5bfc\u8bfb<\/b><\/strong><\/h3>\n

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\"\"<\/p>\n

(a) CCOF-CuTPP\u3001Au@CCOF-CuTPP\u548cPd@CCOF-CuTPP\u7684\u5408\u6210\u8fc7\u7a0b\u53caCCOF-CuTPP\u7684\u7a7a\u95f4\u586b\u5145\u6a21\u578b<\/p>\n

(b) CCOF-CuTPP\u3001Au@CCOF-CuTPP\u548cPd@CCOF-CuTPP\u7684\u5b9e\u9a8c\u548c\u6a21\u62dfPXRD\u56fe\uff0c\u63d2\u5165\u56fe\u4e3aCCOF-CuTPP\u7684TEM\u56fe\u50cf<\/p>\n

(c) (d) Au@CCOF-CuTPP\u548cPd@CCOF-CuTPP\u7684TEM\u56fe\u50cf<\/p>\n

(e).(f) CCOF-CuTPP\u3001Au@CCOF-CuTPP\u548cPd@CCOF-CuTPP\u7684N2<\/sub>\u5438\u9644\uff0d\u89e3\u5438\u7b49\u6e29\u7ebf\u53ca\u5b54\u5f84\u5206\u5e03<\/p>\n

\u88681. Au@CCOF-CuTPP\u50ac\u5316\u4e32\u8054\u4e0d\u5bf9\u79f0Henry\u53cd\u5e94\u7684\u4f18\u5316\u5b9e\u9a8c<\/p>\n

\"\"<\/p>\n

\u88682. Au@CCOF-CuTPP\u50ac\u5316\u4e32\u8054\u4e0d\u5bf9\u79f0Henry\u53cd\u5e94\u7684\u5e95\u7269\u6269\u5c55<\/p>\n

\"\"<\/p>\n

\u88683. Pd@CCOF-CuTPP\u50ac\u5316\u4e32\u8054\u4e0d\u5bf9\u79f0A3<\/sup>-\u5076\u8054\u53cd\u5e94\u7684\u4f18\u5316\u5b9e\u9a8c<\/p>\n

\"\"<\/p>\n

\u88684. Pd@CCOF-CuTPP\u50ac\u5316\u4e32\u8054\u4e0d\u5bf9\u79f0A3<\/sup>-\u5076\u8054\u53cd\u5e94\u7684\u5e95\u7269\u8303\u56f4<\/p>\n

\"\"<\/p>\n

\u56fe2. CCOF-CuTPP\u3001Au@CCOF-CuTPP\u548cPd@CCOF-CuTPP\u7684\u5149\u70ed\u6027\u80fd<\/p>\n

\"\"<\/p>\n

(a) (b) CCOF-CuTP\u5206\u522b\u5728\u7532\u82ef\/\u4e59\u9187\u548c1, 4-\u4e8c\u6c27\u516d\u73af\u4e2d\u7684\u5149\u70ed\u4f5c\u7528<\/p>\n

(c) Au@CCOF-CuTPP\u5728\u7532\u82ef\/\u4e59\u9187\u4e2d\u7684\u5149\u70ed\u6548\u5e94<\/p>\n

(d) Pd@CCOF-CuTPP\u57281, 4-\u4e8c\u6c27\u516d\u73af\u4e2d\u7684\u5149\u70ed\u6548\u5e94<\/p>\n

\u56fe3. \u572860-100\u2103\u8303\u56f4\u5185\uff0cAu@CCOF-CuTPP\u548cPd@CCOF-CuTPP\u5206\u522b\u70ed\u50ac\u5316\u4e32\u8054\u4e0d\u5bf9\u79f0Henry\u53cd\u5e94\u548cA3<\/sup>-\u5076\u8054\u53cd\u5e94<\/p>\n

\"\"<\/p>\n

\u5c0f\u7ed3<\/b><\/strong><\/h3>\n

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\u8bfe\u9898\u7ec4\u4ecb\u7ecd<\/b><\/strong><\/h3>\n

\u8463\u80b2\u658c\uff0c\u5c71\u4e1c\u5e08\u8303\u5927\u5b66\u5316\u5b66\u9662\u6559\u6388\uff0c\u6559\u80b2\u90e8\u957f\u6c5f\u5b66\u8005\u7279\u8058\u6559\u6388\uff0c\u6559\u80b2\u90e8\u201c\u957f\u6c5f\u5b66\u8005\u548c\u521b\u65b0\u56e2\u961f\u53d1\u5c55\u8ba1\u5212\u201d\u521b\u65b0\u56e2\u961f\u5e26\u5934\u4eba\uff0c\u5165\u9009\u56fd\u5bb6\u767e\u5343\u4e07\u4eba\u624d\u5de5\u7a0b\uff0c\u662f\u56fd\u5bb6\u7ea7\u201c\u6709\u7a81\u51fa\u8d21\u732e\u4e2d\u9752\u5e74\u4e13\u5bb6\u201d\uff0c\u6cf0\u5c71\u5b66\u8005\u7279\u8058\u6559\u6388\uff0cESI\u5168\u7403\u5316\u5b66\u9886\u57df\u524d1%\u79d1\u5b66\u5bb6\u3002\u4e3b\u8981\u4ece\u4e8b\u8d85\u5206\u5b50\u7ec4\u88c5\u5316\u5b66\u548c\u91d1\u5c5e\u6709\u673a\u5316\u5b66\u7b49\u65b9\u9762\u7684\u7814\u7a76\u5de5\u4f5c\u3002\u5728Nat. Commun., iScience, J. Am. Chem. Soc., Angew. Chem., Chem. Mater., Chem. Commun., Inorg. Chem., Organometallics\u7b49\u56fd\u9645\u6709\u91cd\u8981\u5f71\u54cd\u7684\u5b66\u672f\u520a\u7269\u4e0a\u53d1\u8868\u7814\u7a76\u8bba\u6587190\u4f59\u7bc7\uff0c\u5f15\u75285800\u4f59\u6b21\uff0cH\u6307\u657044\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1ahttps:\/\/www.nature.com\/articles\/s41467-019-11355-x<\/p>\n

\u672c\u6587\u7531\u5c71\u4e1c\u5e08\u5927\u8463\u80b2\u658c\u6559\u6388\u8bfe\u9898\u7ec4<\/strong>\u4f9b\u7a3f\u3002<\/p>\n

\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1: tougao@cailiaoren.com.<\/p>\n

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