{"id":181919,"date":"2019-08-02T06:30:30","date_gmt":"2019-08-01T22:30:30","guid":{"rendered":"\/\/m.iemloyee.com\/?p=181919"},"modified":"2019-08-01T11:43:36","modified_gmt":"2019-08-01T03:43:36","slug":"%e3%80%90%e5%b7%b2%e6%a0%a1%e7%a8%bf%e3%80%91%e6%96%b0%e5%8a%a0%e5%9d%a1%e5%9b%bd%e7%ab%8b%e5%a4%a7%e5%ad%a6advancd-energy-materials%e5%85%b7%e6%9c%89%e8%b6%85%e9%ab%98%e7%a6%bb%e5%ad%90%e5%a1%9e","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=181919","title":{"rendered":"\u65b0\u52a0\u5761\u56fd\u7acb\u5927\u5b66Advancd Energy Materials:\u5177\u6709\u8d85\u9ad8\u79bb\u5b50\u585e\u8d1d\u514b\u7cfb\u6570\u548c\u70ed\u7535\u6027\u80fd\u7684\u67d4\u6027\u51c6\u56fa\u6001\u79bb\u5b50\u6db2\u4f53\u51dd\u80f6"},"content":{"rendered":"
\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n \u5730\u7403\u4e0a\u7684\u70ed\u80fd\u5f88\u4e30\u5bcc\uff0c\u7136\u800c\u5f88\u5927\u4e00\u90e8\u5206\u70ed\u80fd\u90fd\u4ee5\u5e9f\u70ed\u7684\u5f62\u5f0f\u6563\u53d1\u5230\u73af\u5883\u4e2d\uff0c\u663e\u7136\u6536\u96c6\u5e76\u5229\u7528\u5e9f\u70ed\u5bf9\u4e8e\u5b9e\u73b0\u53ef\u6301\u7eed\u53d1\u5c55\u5177\u6709\u91cd\u8981\u610f\u4e49\u3002\u76ee\u524d\u5df2\u6709\u5305\u62ec\u6709\u673a\u6717\u80af\u5faa\u73af\u3001\u70ed\u7535\u5316\u5b66\u7535\u6c60\u4ee5\u53ca\u70ed\u7535\u53d1\u7535\u673a\u7b49\u6280\u672f\u53ef\u5c06\u70ed\u91cf\u8f6c\u5316\u4e3a\u7535\u80fd\uff0c\u4f46\u662f\u53ea\u6709\u70ed\u7535\u53d1\u7535\u673a\u6280\u672f\u624d\u80fd\u6709\u6548\u5229\u7528\u4f4e\u7b49\u7ea7\u7684\u70ed\u91cf\u3002\u70ed\u7535\u53d1\u7535\u673a\u7684\u70ed\u7535\u8f6c\u6362\u6548\u7387\u53d6\u51b3\u4e8e\u70ed\u7535\u6750\u6599\u7684\u4f18\u503c\u7cfb\u6570\uff08ZT\uff09\u3002\u7535\u5b50\u5bfc\u4f53\u7c7b\u70ed\u7535\u6750\u6599\u5f80\u5f80\u5177\u6709\u9ad8\u5bfc\u7535\u6027\uff0c\u4f46\u4ed6\u4eec\u7684\u585e\u8d1d\u514b\u7cfb\u6570\u901a\u5e38\u8fdc\u5c0f\u4e8e1 mV K-1<\/sup>\u3002\u6b64\u5916\uff0c\u57fa\u4e8e\u7535\u5b50\u5bfc\u4f53\u7684\u70ed\u7535\u7cfb\u7edf\u8f83\u4e3a\u590d\u6742\uff0c\u663e\u8457\u63d0\u9ad8\u4e86\u5236\u9020\u548c\u7ef4\u62a4\u6210\u672c\uff0c\u4f7f\u5f97\u5229\u7528\u7535\u5b50\u5bfc\u4f53\u6765\u6536\u96c6\u70ed\u91cf\u662f\u4e00\u4e2a\u5de8\u5927\u7684\u6311\u6218\u3002\u4e0e\u7535\u5b50\u5bfc\u4f53\u76f8\u6bd4\uff0c\u4ee5\u5f80\u79bb\u5b50\u5bfc\u4f53\u7531\u4e8e\u70ed\u7535\u8f6c\u6362\u8f83\u5dee\u800c\u53d7\u5230\u5173\u6ce8\u8f83\u5c11\u3002\u867d\u7136\u79bb\u5b50\u5bfc\u4f53\u7684\u585e\u8d1d\u514b\u7cfb\u6570\u53ef\u4ee5\u6bd4\u7535\u5b50\u5bfc\u4f53\u9ad8\u51e0\u4e2a\u6570\u91cf\u7ea7\uff0c\u4f46\u79bb\u5b50\u5bfc\u4f53\u7684ZT\u503c\u901a\u5e38\u5c0f\u4e8e0.1\uff0c\u4e3b\u8981\u662f\u7531\u4e8e\u5176\u8f83\u4f4e\u7684\u79bb\u5b50\u7535\u5bfc\u7387\u3002\u56e0\u6b64\uff0c\u63a2\u7d22\u5177\u6709\u9ad8\u585e\u8d1d\u514b\u7cfb\u6570\u548c\u9ad8ZT\u503c\u7684\u6750\u6599\u5bf9\u4e8e\u5b9e\u73b0\u9ad8\u6548\u3001\u4f4e\u6210\u672c\u7684\u70ed\u7535\u8f6c\u6362\u662f\u6781\u5176\u91cd\u8981\u7684\u3002<\/p>\n \u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n \u8fd1\u65e5\uff0c\u65b0\u52a0\u5761\u56fd\u7acb\u5927\u5b66\u6b27\u9633\u5efa\u52c7\u6559\u6388\uff08\u901a\u8baf\u4f5c\u8005\uff09\u8bfe\u9898\u7ec4<\/strong>\u62a5\u9053\u4e86\u7531\u805a\uff08\u504f\u4e8c\u6c1f\u4e59\u70ef\u5171\u516d\u6c1f\u4e19\u70ef\uff09\uff08PVDF-HFP\uff09\u5236\u5f97\u7684\u73af\u5883\u53cb\u597d\u3001\u67d4\u6027\u51c6\u56fa\u6001\u79bb\u5b50\u6db2\u4f53\u51dd\u80f6\uff0c\u4e14\u8be5\u79bb\u5b50\u6db2\u4f53\u51dd\u80f6\u5177\u6709\u8d85\u9ad8\u79bb\u5b50\u585e\u8d1d\u514b\u7cfb\u6570\uff0826.1 mV K-1<\/sup>\uff09\u3001\u9ad8\u79bb\u5b50\u7535\u5bfc\u7387\uff086.7 mS cm-1<\/sup>\uff09\u548c\u4f4e\u70ed\u5bfc\u7387\uff080.176 W m-1<\/sup> K-1<\/sup>\uff09\u3002\u8fd9\u662f\u8fc4\u4eca\u4e3a\u6b62\u5728\u7535\u5b50\u548c\u79bb\u5b50\u70ed\u7535\u6750\u6599\u4e2d\u89c2\u5bdf\u5230\u7684\u6700\u9ad8\u7684\u585e\u8d1d\u514b\u7cfb\u6570\u3002 \u7814\u7a76\u8868\u660e\uff0c\u8d85\u9ad8\u585e\u8d1d\u514b\u7cfb\u6570\u4e0ePVDF-HFP\u548c\u79bb\u5b50\u6db2\u4f53\u4e4b\u95f4\u7684\u79bb\u5b50-\u5076\u6781\u76f8\u4e92\u4f5c\u7528\u6709\u5173\u3002\u6b64\u5916\uff0c\u8be5\u79bb\u5b50\u51dd\u80f6\u5728\u79bb\u5b50\u578b\u70ed\u7535\u7535\u5bb9\u5668\u4e2d\u7684\u5e94\u7528\u4e5f\u88ab\u8bc1\u660e\u53ef\u4ee5\u5c06\u95f4\u6b47\u6027\u70ed\u91cf\u8f6c\u6362\u4e3a\u7535\u80fd\u3002\u8be5\u6210\u679c\u4ee5\u9898\u4e3a” Flexible Quasi-Solid State Ionogels with Remarkable Seebeck Coefficient and High Thermoelectric Properties <\/strong>“\u53d1\u8868\u5728\u56fd\u9645\u8457\u540d\u671f\u520aAdvanced Energy Materials<\/strong>\u4e0a\u3002<\/p>\n \u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n \u56fe1 \u79bb\u5b50\u6db2\u4f53\u7684\u5316\u5b66\u7ed3\u6784\u53ca\u79bb\u5b50\u6db2\u4f53\u51dd\u80f6\u7684\u70ed\u7535\u8868\u5f81<\/strong><\/p>\n (a) \u79bb\u5b50\u6db2\u4f53\u7684\u5316\u5b66\u7ed3\u6784\uff08EMIM:DCA\u3001EMIM:TFSI\u3001BMIM:BF4<\/sub>\u548c\u805a\u5408\u7269PVDF-HFP\uff09\uff1b<\/p>\n (b) EMIM:DCA\/PVDF-HFP\u79bb\u5b50\u6db2\u4f53\u51dd\u80f6\uff08EMIM:DCA\u8d1f\u8f7d\u91cf\u4e3a50 wt%\uff09\u8584\u819c\u7167\u7247\uff1b<\/p>\n (c) EMIM:DCA\u3001EMIM:TFSI\u548cBMIM\uff1aBF4<\/sub>\u8d1f\u8f7d\u91cf\u4e3a50 wt%\u7684\u79bb\u5b50\u6db2\u4f53\u51dd\u80f6\u7684\u963b\u6297\u56fe\uff1b<\/p>\n (d) EMIM:DCA\u3001EMIM:TFSI\u548cBMIM\uff1aBF4<\/sub>\u8d1f\u8f7d\u91cf\u4e3a50 wt%\u7684\u79bb\u5b50\u6db2\u4f53\u51dd\u80f6\u7684\u79bb\u5b50\u7535\u5bfc\u7387\u548c\u79bb\u5b50\u585e\u8d1d\u514b\u7cfb\u6570\u3002<\/p>\n \u56fe2 \u79bb\u5b50\u6db2\u4f53\u51dd\u80f6\u6027\u8d28\u4e0e\u79bb\u5b50\u6db2\u4f53\u542b\u91cf\u7684\u5173\u7cfb<\/strong><\/p>\n (a) \u79bb\u5b50\u7535\u5bfc\u7387\u548c\u79bb\u5b50\u585e\u8d1d\u514b\u7cfb\u6570\u4e0e\u79bb\u5b50\u6db2\u4f53\u51dd\u80f6\u4e2dEMIM:DCA\u8d1f\u8f7d\u91cf\u7684\u5173\u7cfb\u56fe\uff1b<\/p>\n (b) \u70ed\u5bfc\u7387\u4e0e\u79bb\u5b50\u6db2\u4f53\u51dd\u80f6\u4e2dEMIM:DCA\u8d1f\u8f7d\u91cf\u7684\u5173\u7cfb\u56fe\uff1b<\/p>\n (c) \u70ed\u7535\u4f18\u503c\u4e0e\u79bb\u5b50\u6db2\u4f53\u51dd\u80f6\u4e2dEMIM:DCA\u8d1f\u8f7d\u91cf\u7684\u5173\u7cfb\u56fe\u3002<\/p>\n \u56fe<\/strong>3 <\/strong>\u4e0d\u540c\u79bb\u5b50\u6db2\u4f53\u51dd\u80f6\u7684<\/strong>FTIR<\/strong>\u5149\u8c31\u53ca\u5176\u79bb\u5b50\u585e\u8d1d\u514b\u7cfb\u6570<\/strong><\/p>\n (a) PVDF-HFP\u548c\u542b\u6709\u4e0d\u540c\u79bb\u5b50\u6db2\u4f53\u7684\u51dd\u80f6\u7684FTIR\u900f\u5c04\u5149\u8c31\uff1b<\/p>\n (b) PVDF-HFP\u3001 EMIM:DCA\u548c\u4e0d\u540c\u8d1f\u8f7d\u91cf\u7684PVDF-HFP\/EMIM:DCA\u79bb\u5b50\u51dd\u80f6\u7684FTIR\u900f\u5c04\u5149\u8c31\uff1b<\/p>\n (c) \u5728\u5404\u79cd\u805a\u5408\u7269\u4e2d\u8d1f\u8f7d\u5177\u670980wt% EMIM: DCA\u5f97\u5230\u79bb\u5b50\u51dd\u80f6\u7684\u7684\u79bb\u5b50\u585e\u8d1d\u514b\u7cfb\u6570\u3002<\/p>\n \u56fe4 \u79bb\u5b50\u578b\u70ed\u7535\u7535\u5bb9\u5668\u5de5\u4f5c\u539f\u7406\u53ca\u6027\u80fd\u6d4b\u8bd5<\/strong><\/p>\n (b) \u5229\u752850 wt%\u548c80wt%IL\u8d1f\u8f7d\u91cf\u7684EMIM:DCA\/PVDF-HFP\u79bb\u5b50\u51dd\u80f6\u548c\u94f6\u7535\u6781\u8fde\u63a5\u79bb\u5b50\u70ed\u7535\u5bb9\u5668\u548c\u5916\u90e8\u8d1f\u8377\u7684\u7535\u538b\u66f2\u7ebf\uff1b<\/p>\n (c) \u4f7f\u7528\u94f6\u6216\u5355\u58c1\u78b3\u7eb3\u7c73\u7ba1\u7535\u6781\u8fde\u63a5\u79bb\u5b50\u70ed\u7535\u7535\u5bb9\u5668\u548c\u5916\u90e8\u8d1f\u8377\u5728\u6b63\u538b\u5de5\u4f5c\u65f6\u7684\u7535\u538b\u66f2\u7ebf\uff1b<\/p>\n (d) \u4f7f\u7528\u94f6\u6216\u5355\u58c1\u78b3\u7eb3\u7c73\u7ba1\u7535\u6781\u8fde\u63a5\u79bb\u5b50\u70ed\u7535\u7535\u5bb9\u5668\u548c\u5916\u90e8\u8d1f\u8377\u5728\u8d1f\u538b\u5de5\u4f5c\u65f6\u7684\u7535\u538b\u66f2\u7ebf\uff1b<\/p>\n (e) \u5047\u8bbe\u9ad8\u6e29\u5904\u4e3a375 K\u3001\u4f4e\u6e29\u5904\u4e3a275 K\uff0c\u4f20\u7edf\u70ed\u7535\u53d1\u7535\u673a\u548c\u79bb\u5b50\u70ed\u7535\u7535\u5bb9\u5668\u76f8\u5bf9\u4e8e\u4f18\u503c\u7cfb\u6570\u7684\u70ed\u7535\u8f6c\u6362\u6548\u7387\u3002<\/p>\n \u3010\u5c0f<\/strong>\u7ed3\u3011<\/strong><\/p>\n \u672c\u6587\u4e2d\uff0c\u4f5c\u8005\u62a5\u9053\u4e86\u7531EMIM:DCA\u548cPVDF-HFP\u5236\u5f97\u7684\u51c6\u56fa\u6001\u79bb\u5b50\u6db2\u4f53\u51dd\u80f6\uff0c\u5176\u53ef\u4ee5\u8868\u73b0\u51fa\u8d85\u9ad8\u7684\u585e\u8d1d\u514b\u7cfb\u6570\uff08\u53ef\u9ad8\u8fbe26.1 mV K-1<\/sup>\uff09\uff0c\u9ad8\u79bb\u5b50\u585e\u8d1d\u514b\u7cfb\u6570\u5f52\u56e0\u4e8e\u79bb\u5b50-\u79bb\u5b50\u76f8\u4e92\u4f5c\u7528\u4ee5\u53ca\u79bb\u5b50\u548cPVDF-HFP\u4e4b\u95f4\u7684\u76f8\u4e92\u4f5c\u7528\u3002\u6b64\u5916\uff0c\u8be5\u79bb\u5b50\u51dd\u80f6\u53ef\u5177\u67096.7 mS cm-1<\/sup>\u7684\u9ad8\u79bb\u5b50\u7535\u5bfc\u7387\u548c0.176 W m-1<\/sup>K-1<\/sup>\u7684\u4f4e\u5bfc\u70ed\u7387\u3002\u56e0\u6b64\uff0c\u5176\u70ed\u7535\u4f18\u503c\u53ef\u4ee5\u9ad8\u8fbe0.75\u3002\u7814\u7a76\u8fd8\u8868\u660e\uff0c\u79bb\u5b50\u6db2\u4f53\u51dd\u80f6\u53ef\u7528\u4e8e\u79bb\u5b50\u70ed\u7535\u7535\u5bb9\u5668\u4e2d\u8fdb\u884c\u70ed\u7535\u8f6c\u6362\u3002<\/p>\n<\/p>\n
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(a) \u79bb\u5b50\u578b\u70ed\u7535\u7535\u5bb9\u5668\u5de5\u4f5c\u539f\u7406\u7684\u793a\u610f\u56fe\uff1b<\/p>\n