{"id":181486,"date":"2019-07-28T06:30:29","date_gmt":"2019-07-27T22:30:29","guid":{"rendered":"\/\/m.iemloyee.com\/?p=181486"},"modified":"2019-07-27T17:26:21","modified_gmt":"2019-07-27T09:26:21","slug":"%e3%80%90%e5%b7%b2%e6%a0%a1%e7%a8%bf%e3%80%91%e6%b8%85%e5%8d%8e%e5%a4%a7%e5%ad%a6adv-funct-mater-%e7%bb%93%e6%9e%84%e6%9c%89%e5%ba%8f%e7%9a%84%e4%bd%8ept%e9%87%91%e5%b1%9e%e9%97%b4%e7%94%b5","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=181486","title":{"rendered":"\u6e05\u534e\u5927\u5b66Adv. Funct. Mater.:\u7ed3\u6784\u6709\u5e8f\u7684\u4f4ePt\u91d1\u5c5e\u95f4\u7535\u50ac\u5316\u5242\u83b7\u5f97\u6301\u4e45\u3001\u9ad8\u6548\u6c27\u8fd8\u539f\u53cd\u5e94\u6d3b\u6027"},"content":{"rendered":"
\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n \u6c27\u8fd8\u539f\u53cd\u5e94\uff08ORR\uff09\u7684\u7f13\u6162\u52a8\u529b\u5b66\u662f\u9650\u5236\u8d28\u5b50\u4ea4\u6362\u819c\u71c3\u6599\u7535\u6c60\uff08PEMFC\uff09\u5546\u4e1a\u5e94\u7528\u7684\u4e3b\u8981\u74f6\u9888\u3002Pt\u4e0e3d\u8fc7\u6e21\u91d1\u5c5eM\uff08M=Fe\u3001Co\u3001Ni\u548cCu\u7b49\uff09\u7684\u5408\u91d1\u5316\u662f\u52a0\u901fORR\u548c\u51cf\u5c11\u8d35\u91d1\u5c5ePt\u4f7f\u7528\u7684\u4e00\u4e2a\u6709\u6548\u9014\u5f84\u3002\u5176\u4e2dPt-Co\u548cPt-Ni\u88ab\u8bc1\u660e\u662f\u4e24\u79cd\u6700\u6d3b\u6cfc\u7684Pt\u53cc\u91d1\u5c5e\u5408\u91d1\u3002\u5728\u4e0ePEMFCs\u76f8\u5173\u7684ORR\u7535\u50ac\u5316\u8fc7\u7a0b\u4e2d\uff0c\u8868\u9762\u4e0a\u7684\u975e\u8d35\u91d1\u5c5e\u4f1a\u6eb6\u89e3\u8fdb\u800c\u5f62\u6210\u6838-\u58f3\u7ed3\u6784\u3002\u76f8\u6bd4\u4e8e\u4f20\u7edf\u7684\u5bccPt\u5408\u91d1(Pt3<\/sub>M, PtM\u7b49)\uff0c\u5177\u6709\u5178\u578b\u5316\u5b66\u8ba1\u91cfPtM3<\/sub>\u7684\u4f4ePt\u5408\u91d1\u7eb3\u7c73\u9897\u7c92\u5c55\u73b0\u51fa\u589e\u5f3a\u7684\u5e94\u53d8\u6548\u5e94\u548c\u66f4\u4f18\u5f02\u7684ORR\u6d3b\u6027\u3002\u7136\u800c\uff0c\u5728\u957f\u671fORR\u7535\u50ac\u5316\u8fc7\u7a0b\u4e2d\uff0c\u975e\u8d35\u91d1\u5c5e\u4f1a\u8fde\u7eed\u4ece\u8868\u9762\u6eb6\u89e3\uff0c\u5bfc\u81f4\u5e94\u53d8\u6548\u5e94\u51cf\u5f31\u800c\u4e14\u6d3b\u6027\u663e\u8457\u964d\u4f4e\u3002\u6709\u5e8fPt\u57fa\u91d1\u5c5e\u95f4\u5316\u5408\u7269\u5177\u6709\u66f4\u9ad8\u7684\u6d3b\u6027\u548c\u8010\u4e45\u6027\u3001 \u66f4\u7262\u56fa\u7684Pt-M\u952e\uff0c\u56e0\u800c\u80fd\u591f\u5e26\u6765\u66f4\u9ad8\u7684\u975e\u8d35\u91d1\u5c5e\u6297\u6eb6\u89e3\u80fd\u529b\uff0c\u5f15\u8d77\u4e86\u8d8a\u6765\u8d8a\u591a\u7684\u7814\u7a76\u5174\u8da3\u3002\u4f46\u662f\u622a\u6b62\u76ee\u524d\uff0c\u5927\u591a\u6570\u6709\u5e8fPt\u91d1\u5c5e\u95f4\u5316\u5408\u7269\u7684\u7814\u7a76\u90fd\u96c6\u4e2d\u5728\u5bccPt\u7684\u6210\u5206\u4e0a\uff0c\u975e\u8d35\u91d1\u5c5e\u542b\u91cf\u8f83\u4f4e\u9650\u5236\u4e86\u5176\u50ac\u5316\u6d3b\u6027\u7684\u8fdb\u4e00\u6b65\u589e\u5f3a\u3002\u56e0\u6b64\uff0c\u5f00\u53d1\u5177\u6709\u9ad8\u6d3b\u6027\u548c\u7a33\u5b9a\u6027\u7684\u4f4ePt\u6709\u5e8f\u91d1\u5c5e\u95f4ORR\u7535\u50ac\u5316\u5242\u5177\u6709\u91cd\u8981\u610f\u4e49\u3002<\/p>\n \u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n \u8fd1\u65e5\uff0c\u6e05\u534e\u5927\u5b66\u5e72\u6797\u526f\u6559\u6388\uff08\u901a\u8baf\u4f5c\u8005\uff09\u8bfe\u9898\u7ec4<\/strong>\u5229\u7528\u4f4ePt\u6709\u5e8f\u91d1\u5c5e\u95f4\u5316\u5408\u7269\u4f5c\u4e3aORR\u7684\u6301\u4e45\u6d3b\u6027\u7535\u50ac\u5316\u5242\uff0c\u901a\u8fc7\u6bd4\u8f83\u5236\u5907\u4e86\u4e09\u79cd\u652f\u6491\u5728\u9ad8\u8868\u9762\u79ef\u78b3\u8f7d\u4f53\u4e0a\u7684\u5355\u5206\u6563\u4f4ePt\u5408\u91d1\u7eb3\u7c73\u7c92\u5b50\uff0c\u7136\u540e\u91cd\u70b9\u7814\u7a76\u4e86\u70ed\u9000\u706b\u524d\u540e\u548c\u957f\u671fORR\u7535\u50ac\u5316\u524d\u540e\u539f\u5b50\u5c3a\u5ea6\u4e0a\u7684\u6709\u65e0\u5e8f\/\u6709\u5e8f\u7ed3\u6784\u548c\u7ec4\u6210\u7cbe\u7ec6\u7ed3\u6784\u3002\u7814\u7a76\u8868\u660e\uff0c\u6709\u5e8fPtCo3<\/sub>\u91d1\u5c5e\u95f4\u7535\u50ac\u5316\u5242\u53ef\u4ee5\u7a33\u5b9a\u5730\u5f62\u6210\u800c\u6ca1\u6709\u660e\u663e\u7684\u9897\u7c92\u70e7\u7ed3\uff1b PtFe3<\/sub>\u50ac\u5316\u5242\u867d\u7136\u80fd\u5b9e\u73b0\u6709\u5e8f\u5316\uff0c\u4f46\u5728\u70ed\u5904\u7406\u8fc7\u7a0b\u4e2d\u6613\u53d1\u751f\u9897\u7c92\u70e7\u7ed3\uff1b\u800cPtNi3\u4e0d\u4ec5\u9897\u7c92\u70e7\u7ed3\u6700\u4e25\u91cd\uff0c\u5e76\u4e14\u96be\u4ee5\u5b9e\u73b0\u6709\u5e8f\u5316\u8f6c\u53d8\u3002\u6240\u5236\u5907\u7684\u6709\u5e8fPtCo3<\/sub>\u91d1\u5c5e\u95f4\u7535\u50ac\u5316\u5242\u6bd4\u5176\u4ed6\u4f4ePt\u7535\u50ac\u5316\u5242\u4ee5\u53ca\u4f20\u7edf\u7684\u6709\u5e8f\u5bccPt\u91d1\u5c5e\u95f4\u5316\u5408\u7269\u5c55\u73b0\u51fa\u66f4\u9ad8\u7684\u6d3b\u6027\u548c\u7a33\u5b9a\u6027\u3002\u8be5\u6210\u679c\u4ee5\u9898\u4e3a” Structurally Ordered Low<\/strong>\u2010<\/strong>Pt Intermetallic Electrocatalysts toward Durably High Oxygen Reduction Reaction Activity<\/strong>“\u53d1\u8868\u5728\u56fd\u9645\u8457\u540d\u671f\u520aAdv. Funct. Mater.<\/strong>\u4e0a\u3002<\/p>\n \u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n \u56fe1 \u78b3\u8f7dPtM3<\/sub>\u50ac\u5316\u5242\u7684\u5408\u6210\u793a\u610f\u56fe\u53ca\u8868\u5f81<\/strong><\/p>\n (a) \u7ed3\u6784\u65e0\u5e8f\u548c\u6709\u5e8f\u4f4ePt\u91d1\u5c5e\u95f4\u50ac\u5316\u5242\u7684\u5408\u6210\u793a\u610f\u56fe\uff1b<\/p>\n (b) \u78b3\u8f7dPtM3<\/sub>\u50ac\u5316\u5242\u5728Ar\/H2<\/sub>\u4e2d400\u6216600\u00baC\u6761\u4ef6\u4e0b\u9000\u706b4\u5c0f\u65f6\u540e\u7684XRD\u56fe\u8c31\uff1b<\/p>\n (c) PtFe3<\/sub>-H600\u7684HAADF-STEM\u56fe\u50cf\uff1b<\/p>\n (d) PtCo3<\/sub>-H600\u7684HAADF-STEM\u56fe\u50cf\uff1b<\/p>\n (e) PtNi3<\/sub>-H600\u7684HAADF-STEM\u56fe\u50cf\uff1b<\/p>\n (f) PtFe3<\/sub>-H600 NPs\u7684\u9ad8\u5206\u8fa8\u7387STEM\u56fe\u50cf\uff1b<\/p>\n (g) PtFe3<\/sub>-H600 NPs\u7684EELS\u5143\u7d20mapping\u56fe\uff1b<\/p>\n (h) PtCo3<\/sub>-H600 NPs\u7684\u9ad8\u5206\u8fa8\u7387STEM\u56fe\u50cf\uff1b<\/p>\n (i) PtCo3<\/sub>-H600 NPs\u7684EELS\u5143\u7d20mapping\u56fe\u3002<\/p>\n \u56fe2 \u4e0d\u540c\u4f4ePt\u50ac\u5316\u5242\u7684ORR\u6d3b\u6027\u548c\u7a33\u5b9a\u6027\u8bc4\u4f30<\/strong><\/p>\n (a) \u7535\u5316\u5b66\u6d3b\u5316\u524d\u540e\u521d\u59cb\u72b6\u6001\u548c\u6d3b\u5316\u72b6\u6001\u7684PtCo3<\/sub>-H600\u548cPtFe3<\/sub>-H600\u50ac\u5316\u5242\u7684CV\u66f2\u7ebf\uff1b<\/p>\n (b) \u6d3b\u5316\u548c\u8001\u5316\u7684PtNi3<\/sub>\u50ac\u5316\u5242\u7684ORR\u6781\u5316\u66f2\u7ebf\uff1b<\/p>\n (c) \u6d3b\u5316\u548c\u8001\u5316\u7684PtCo3<\/sub>\u50ac\u5316\u5242\u7684ORR\u6781\u5316\u66f2\u7ebf\uff1b<\/p>\n (d) \u6d3b\u5316\u548c\u8001\u5316\u7684PtFe3<\/sub>\u50ac\u5316\u5242\u7684ORR\u6781\u5316\u66f2\u7ebf;<\/p>\n (e) \u6d3b\u5316\u548c\u8001\u5316\u7684PtM3<\/sub>-H400\/H600\u50ac\u5316\u5242\u7684\u8d28\u91cf\u6bd4\u6d3b\u6027\u7684\u6bd4\u8f83\uff1b<\/p>\n (f) \u6d3b\u5316\u548c\u8001\u5316\u7684PtM3<\/sub>-H400\/H600\u50ac\u5316\u5242\u7684\u9762\u79ef\u6bd4\u6d3b\u6027\u7684\u6bd4\u8f83\u3002<\/p>\n \u56fe3 ORR\u524d\u540e\u4f4ePt\u5408\u91d1\u50ac\u5316\u5242\u7684\u7ec4\u6210\u53d8\u5316<\/strong><\/p>\n (a) \u4e0d\u540c\u9636\u6bb5\uff08\u521d\u59cb\u3001\u6d3b\u5316\u548c\u8001\u5316\uff09\u7684\u4e0d\u540cPtM3<\/sub>-H400\/H600\u50ac\u5316\u5242\u7684EDX\u7ec4\u6210\u5206\u6790\uff1b<\/p>\n (b) \u6d3b\u5316\u7684\u6709\u5e8fPtCo3<\/sub>-H600\u50ac\u5316\u5242\u7684\u9ad8\u5206\u8fa8\u7387STEM\u56fe\u50cf\u548cEELS mapping\u56fe\uff1b<\/p>\n (c) \u8001\u5316\u7684PtFe3<\/sub>-H600\u3001PtCo3<\/sub>-H600\u548cPtNi3<\/sub>-H600\u50ac\u5316\u5242\u7684\u9ad8\u5206\u8fa8\u7387STEM\u56fe\u50cf\u548cEELS mapping\u56fe\u3002<\/p>\n \u56fe4 \u4e0d\u540c\u50ac\u5316\u7684CO\u5265\u79bb\u4f0f\u5b89\u56fe<\/strong><\/p>\n (a) PtNi3<\/sub>-H400\u7684CO\u5265\u79bb\u4f0f\u5b89\u56fe\uff1b<\/p>\n (b) PtNi3<\/sub>-H600\u7684CO\u5265\u79bb\u4f0f\u5b89\u56fe\uff1b<\/p>\n (c) PtCo3<\/sub>-H400\u7684CO\u5265\u79bb\u4f0f\u5b89\u56fe\uff1b<\/p>\n (d) PtCo3<\/sub>-H600\u7684CO\u5265\u79bb\u4f0f\u5b89\u56fe\uff1b<\/p>\n (e) PtFe3<\/sub>-H400\u7684CO\u5265\u79bb\u4f0f\u5b89\u56fe\uff1b<\/p>\n (f) PtFe3<\/sub>-H600\u7684CO\u5265\u79bb\u4f0f\u5b89\u56fe\u3002<\/p>\n \u56fe5 \u4f4ePt\u4e0e\u4f20\u7edf\u7684\u5bccPt\u6709\u5e8f\u91d1\u5c5e\u95f4\u5316\u5408\u7269\u7684\u6bd4\u8f83<\/strong><\/p>\n (a) \u5728600\u00baC\u4e0b\u9000\u706b\u7684PtCo\u548cPtCo3<\/sub>\u50ac\u5316\u5242\u7684XRD\u56fe\u6848\uff1b<\/p>\n (b) PtCo\u548cPtCo3<\/sub>\u50ac\u5316\u5242\u5728N2<\/sub>\u9971\u548c0.1 M HClO4<\/sub>\u6eb6\u6db2\u4e2d\u7684CV\u66f2\u7ebf\uff1b<\/p>\n (c) PtCo3<\/sub>-H400\u3001PtCo3<\/sub>-H600\u3001PtCo-H400 \u3001PtCo-H600\u548cPtC\u7684ORR\u6781\u5316\u66f2\u7ebf\uff1b<\/p>\n (d) 0.9 V\u65f6\u7684\u52a8\u529b\u5b66\u8d28\u91cf\u6bd4\u6d3b\u6027\u7684\u6bd4\u8f83\u3002<\/p>\n \u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n \u672c\u6587\u4e2d\uff0c\u4f5c\u8005\u53d1\u73b0\u4e09\u79cd\u5178\u578b\u7684\u78b3\u8f7d\u4f4ePt\u5408\u91d1\u7eb3\u7c73\u7c92\u5b50\u50ac\u5316\u5242\u5728\u70ed\u5904\u7406\u6761\u4ef6\u4e0b\u8868\u73b0\u51fa\u4e0d\u540c\u7684\u6709\u5e8f\u5316\u8f6c\u53d8\u548c\u6297\u70e7\u7ed3\u884c\u4e3a\u3002\u5176\u4e2d\uff0cPtCo3<\/sub>\u50ac\u5316\u5242\u4e0d\u4ec5\u80fd\u5b9e\u73b0\u7ed3\u6784\u6709\u5e8f\u5316\uff08\u5f62\u6210\u91d1\u5c5e\u95f4\u5316\u5408\u7269\uff09\uff0c\u4e14\u5728\u70ed\u5904\u7406\u8fc7\u7a0b\u4e2d\u5177\u6709\u6700\u4f73\u7684\u6297\u70e7\u7ed3\u80fd\u529b\uff0c\u4ece\u800c\u4e0e\u4e4b\u524d\u62a5\u9053\u7684\u5bccPt\u6709\u5e8f\u91d1\u5c5e\u95f4\u5316\u5408\u7269\u4ee5\u53ca\u4f4ePt\u65e0\u5e8f\u5408\u91d1\u50ac\u5316\u5242\u76f8\u6bd4\u83b7\u5f97\u66f4\u9ad8\u7684ORR\u6d3b\u6027\u53ca\u66f4\u9ad8\u7684\u8010\u4e45\u6027\u3002\u7814\u7a76\u53d1\u73b0\uff0c\u4f18\u5f02\u7684ORR\u6d3b\u6027\u548c\u7a33\u5b9a\u6027\u5f52\u56e0\u4e8e\u539a\u5ea6\u4f4e\u4e8e0.6 nm\u8584Pt\u58f3\u5c42\u7684\u6301\u4e45\u548c\u5747\u4e00\u4ee5\u53ca\u548c\u5faa\u73af10k\u6b21\u540e\u6709\u5e8f\u91d1\u5c5e\u95f4\u5316\u5408\u7269\u6838\u4e2d\u7684\u9ad8Co\u542b\u91cf\u3002\u8be5\u7814\u7a76\u8868\u660ePtCo3<\/sub>\u4f4e\u94c2\u6709\u5e8f\u91d1\u5c5e\u95f4\u7535\u50ac\u5316\u5242\u7684\u5408\u7406\u8bbe\u8ba1\u4e3a\u6301\u4e45\u4e14\u9ad8\u6d3b\u6027ORR\u7535\u50ac\u5316\u5242\u63d0\u4f9b\u4e86\u65b0\u65b9\u6cd5\u3002<\/p>\n<\/p>\n
<\/p>\n
<\/p>\n
<\/p>\n
<\/p>\n