{"id":181096,"date":"2019-07-25T11:20:36","date_gmt":"2019-07-25T03:20:36","guid":{"rendered":"\/\/m.iemloyee.com\/?p=181096"},"modified":"2019-07-24T21:20:53","modified_gmt":"2019-07-24T13:20:53","slug":"%e5%8c%97%e7%90%86%e5%b7%a5%e9%99%88%e4%ba%ba%e6%9d%b0%e6%95%99%e6%8e%88%e8%af%be%e9%a2%98%e7%bb%84-adv-sci-%e5%b1%82%e5%b1%82%e7%bb%84%e8%a3%85%e7%9a%84%e5%82%ac%e5%8c%96%e7%94%b5%e6%9e%81","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=181096","title":{"rendered":"\u5317\u7406\u5de5\u9648\u4eba\u6770\u6559\u6388\u8bfe\u9898\u7ec4 Adv. Sci.: \u5c42\u5c42\u7ec4\u88c5\u7684\u50ac\u5316\u7535\u6781\u7528\u4e8e\u63d0\u5347\u9502\u786b\u7535\u6c60\u7684\u500d\u7387\u6027\u80fd"},"content":{"rendered":"

\u3010\u80cc\u666f\u4ecb\u7ecd\u3011<\/strong><\/p>\n

\u9502\u786b\uff08Li-S\uff09\u7535\u6c60\u4f5c\u4e3a\u9ad8\u6027\u80fd\u4e8c\u6b21\u7535\u6c60\u65b0\u4f53\u7cfb\u7684\u4ee3\u8868\uff0c\u7531\u4e8e\u5176\u5177\u6709\u8d28\u91cf\u80fd\u91cf\u5bc6\u5ea6\u9ad8\u3001\u5355\u8d28\u786b\u6765\u6e90\u5e7f\u6cdb\u548c\u73af\u5883\u53cb\u597d\u7b49\u4f18\u70b9\u800c\u53d7\u5230\u5e7f\u6cdb\u7684\u5173\u6ce8\u3002\u4f46\u662f\uff0c\u7531\u4e8e\u786b\u56fa\u6709\u7684\u4e00\u4e9b\u7279\u6027\uff0c\u9502-\u786b\u7535\u6c60\u7684\u4ea7\u4e1a\u5316\u5e94\u7528\u8fd8\u6ca1\u6709\u5b9e\u73b0\uff1a\uff081\uff09\u786b\u53ca\u5176\u653e\u7535\u4ea7\u7269\uff08Li2<\/sub>S\/Li2<\/sub>S2<\/sub>\uff09\u5177\u6709\u8f83\u4f4e\u7684\u7535\u5b50\u7535\u5bfc\u7387\uff1b\uff082\uff09\u53cd\u5e94\u4e2d\u95f4\u4ea7\u7269\u591a\u786b\u5316\u7269\uff08Li2<\/sub>Sn<\/sub>\uff0c4\u2264n\u22648\uff09\u5728\u6709\u673a\u7535\u89e3\u6db2\u4e2d\u7684\u6eb6\u89e3\u548c\u7a7f\u68ad\u4f1a\u5bfc\u81f4\u7535\u6c60\u5bb9\u91cf\u7684\u5feb\u901f\u8870\u51cf\uff1b\uff083\uff09\u4e0d\u540c\u6d3b\u6027\u6750\u6599\u95f4\u76f8\u8f6c\u5316\u9020\u6210\u7684\u7f13\u6162\u7684\u6c27\u5316\u8fd8\u539f\u53cd\u5e94\u52a8\u529b\u5b66\u5bfc\u81f4\u9502\u786b\u7535\u6c60\u7684\u500d\u7387\u6027\u80fd\u8f83\u4f4e\u3002<\/p>\n

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\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u5317\u4eac\u7406\u5de5\u5927\u5b66\u7684\u9648\u4eba\u6770\u6559\u6388\uff08\u901a\u8baf\u4f5c\u8005\uff09\u8bfe\u9898\u7ec4<\/strong>\u8bbe\u8ba1\u4e86\u4e00\u79cd\u5c42\u5c42\u7ec4\u88c5\u7684\u8d85\u7ec6CoS2<\/sub>\u7eb3\u7c73\u9897\u7c92\u9576\u5d4c\u7684\u78b3\u7eb3\u7c73\u7247\u4f5c\u4e3a\u786b\u7684\u8f7d\u4f53\u6750\u6599\u3002\u6bcf\u4e00\u5c42\u7684\u78b3\u7eb3\u7c73\u7247\u5305\u542b\u4e24\u5c42BMZIFs\u884d\u751f\u7684\u591a\u5b54\u78b3\u81f4\u5bc6\u5730\u951a\u5b9a\u5728\u8fd8\u539f\u6c27\u5316\u77f3\u58a8\u70ef\uff08rGO\uff09\u7684\u4e24\u4fa7\uff0c\u5176\u4e2d\u591a\u5b54\u78b3\u4e2d\u9576\u5d4c\u6709BMZIFs\u884d\u751f\u7684\u8d85\u7ec6CoS2<\/sub>\u7eb3\u7c73\u9897\u7c92\u3002\u5177\u6709\u8f83\u5927\u6bd4\u8868\u9762\u79ef\u548c\u5206\u7ea7\u591a\u5b54\u7ed3\u6784\u7684\u78b3\u7eb3\u7c73\u7247\u53ef\u4ee5\u6709\u6548\u5730\u56fa\u5b9a\u591a\u786b\u5316\u7269\uff0c\u4ee5rGO\u4e3a\u57fa\u5e95\u7684\u76f8\u4e92\u8d2f\u7a7f\u7684\u591a\u5c42\u78b3\u7247\u5177\u6709\u826f\u597d\u7684\u5bfc\u7535\u6027\u548c\u754c\u9762\u8fde\u901a\u6027\uff0c\u53ef\u4ee5\u4fc3\u8fdb\u7535\u5b50\u548c\u79bb\u5b50\u7684\u5feb\u901f\u4f20\u8f93\u3002BMZIFs\u884d\u751f\u7684\u8d85\u7ec6CoS2<\/sub>\u7eb3\u7c73\u9897\u7c92\u4e0d\u4ec5\u53ef\u4ee5\u5316\u5b66\u5438\u9644\u591a\u786b\u5316\u7269\uff0c\u8fd8\u53ef\u4ee5\u4e3a\u50ac\u5316\u591a\u786b\u5316\u7269\u7684\u6c27\u5316\u8fd8\u539f\u53cd\u5e94\u63d0\u4f9b\u5145\u8db3\u7684\u6d3b\u6027\u4f4d\u70b9\uff0c\u4f7f\u5f97\u591a\u786b\u5316\u7269\u4e0d\u6613\u5728\u6709\u673a\u7535\u89e3\u6db2\u4e2d\u6eb6\u89e3\u6269\u6563\uff0c\u4ece\u800c\u63d0\u5347\u7535\u6c60\u7684\u500d\u7387\u6027\u80fd\u548c\u5faa\u73af\u7a33\u5b9a\u6027\u3002\u57fa\u4e8e\u8be5\u8d85\u7ec6CoS2<\/sub>\u7eb3\u7c73\u9897\u7c92\u9576\u5d4c\u7684\u78b3\u7eb3\u7c73\u7247\u7684\u786b\u6b63\u6781\u57281C\u548c5 C\u500d\u7387\u4e0b\u7684\u653e\u7535\u5bb9\u91cf\u5206\u522b\u4e3a1180.7\u548c700 mAh g-1<\/sup>\uff0c\u57285 C\u500d\u7387\u4e0b\u5faa\u73af1000\u5468\u540e\u7684\u5bb9\u91cf\u8870\u51cf\u7387\u4ec5\u4e3a0.033%\/\u5468\u3002\u5373\u4f7f\u5f53\u786b\u8f7d\u91cf\u4e3a3.0 mg cm-2<\/sup>\u65f6\uff0c\u8be5\u590d\u5408\u6b63\u6781\u5728300\u5468\u5faa\u73af\u540e\u4ecd\u8868\u73b0\u51fa\u8f83\u9ad8\u7684\u653e\u7535\u5bb9\u91cf\u548c\u5faa\u73af\u7a33\u5b9a\u6027\u3002\u7814\u7a76\u6210\u679c\u4ee5\u9898\u4e3a\u201cBoosting High-Rate Li-S Batteries by an MOF-Derived Catalytic Electrode with a Layer-by-Layer Structure\u201d<\/strong>\u53d1\u5e03\u5728\u8457\u540d\u671f\u520aAdv. Sci.<\/strong>\u4e0a\u3002<\/p>\n

\u3010\u56fe\u6587\u89e3\u8bfb\u3011<\/strong><\/p>\n

\u56fe\u4e00\u3001CoS2<\/sub>-LBLCN\u7684\u5408\u6210\u793a\u610f\u56fe<\/strong><\/p>\n

\"\"<\/p>\n

\u56fe\u4e8c\u3001BMZIFs\/GO\u548cCoS2<\/sub>-LBLCN\u7684\u5fae\u89c2\u7ed3\u6784\u8868\u5f81<\/strong>
\n \"\"\uff08a-c\uff09BMZIFs\/GO\u7684SEM\u548cTEM\u56fe\uff1b<\/p>\n

\uff08d-f\uff09CoS2<\/sub>-LBLCN\u7684SEM\u548cTEM\u56fe\uff1b<\/p>\n

\uff08g\uff09CoS2<\/sub>-LBLCN\u7684STEM\u53ca\u5176\u5bf9\u5e94\u7684EDX\u5143\u7d20\u5206\u5e03\u56fe\uff1b<\/p>\n

\uff08h\uff09CoS2<\/sub>-LBLCN\u548cS@CoS2<\/sub>-LBLCN\u7684XRD\u56fe\u8c31\u3002<\/p>\n

\u56fe\u4e09\u3001S@CoS2<\/sub>-LBLCN\u548cS@LBLCN\u7684\u500d\u7387\u548c\u5faa\u73af\u6027\u80fd<\/strong>
\n \"\"\uff08a\uff09S@CoS2<\/sub>-LBLCN\u548cS@LBLCN\u6b63\u6781\u7684\u500d\u7387\u6027\u80fd\uff1b<\/p>\n

\uff08b-c\uff09S@CoS2<\/sub>-LBLCN\u548cS@LBLCN\u6b63\u6781\u5728\u4e0d\u540c\u500d\u7387\u4e0b\u7684\u5145\u653e\u7535\u66f2\u7ebf\uff1b<\/p>\n

\uff08d\uff09S@CoS2<\/sub>-LBLCN\u6b63\u6781\u57281.0\u548c5.0 C\u500d\u7387\u4e0b\u7684\u5faa\u73af\u6027\u80fd\u3002<\/p>\n

\u56fe\u56db\u3001\u9ad8\u786b\u8f7d\u91cfS@CoS2<\/sub>-LBLCN\u6b63\u6781\u7684\u500d\u7387\u548c\u5faa\u73af\u6027\u80fd<\/strong>
\n \"\"\uff08a\uff09\u786b\u8f7d\u91cf\u4e3a3.0 mg cm-2<\/sup>\u7684S@CoS2<\/sub>-LBLCN\u6b63\u6781\u7684\u500d\u7387\u6027\u80fd\uff1b<\/p>\n

\uff08b\uff09S@CoS2<\/sub>-LBLCN\u6b63\u6781\u57280.5 C\u500d\u7387\u4e0b\u7684\u5145\u653e\u7535\u66f2\u7ebf\uff1b<\/p>\n

\uff08C\uff09S@CoS2<\/sub>-LBLCN\u6b63\u6781\u57280.5\u548c1.0 C\u500d\u7387\u4e0b\u7684\u5faa\u73af\u6027\u80fd\u3002<\/p>\n

\u56fe\u4e94\u3001CoS2<\/sub>-LBLCN\u5bf9\u591a\u786b\u5316\u7269\uff08Li2<\/sub>S6<\/sub>\uff09\u7684\u9759\u6001\u5438\u9644\u5b9e\u9a8c<\/strong>
\n \"\"\uff08a\uff09\u591a\u786b\u5316\u7269\uff08Li2<\/sub>S6<\/sub>\uff09\u7684\u5438\u9644\u5b9e\u9a8c\uff1b<\/p>\n

\uff08b\uff09\u52a0\u5165Super P\u3001rGO\u3001LBLCN\u548cCoS2<\/sub>-LBLCN\u540eLi2<\/sub>S6<\/sub>\u6eb6\u6db2\u7684\u7d2b\u5916\u53ef\u89c1\u5438\u6536\u5149\u8c31\uff1b<\/p>\n

\uff08c-d\uff09\u5438\u9644Li2<\/sub>S6<\/sub>\u524d\u540e\uff0cCoS2<\/sub>-LBLCN\u7684Co 2P3\/2<\/sub> XPS\u56fe\u8c31\u3002<\/p>\n

\u56fe\u516d\u3001CoS2<\/sub>\u7eb3\u7c73\u9897\u7c92\u5bf9\u591a\u786b\u5316\u7269\u7684\u6c27\u5316\u8fd8\u539f\u53cd\u5e94\u52a8\u529b\u5b66\u7684\u5f71\u54cd<\/strong>
\n \"\"\uff08a\uff09\u542b\u6709\u548c\u4e0d\u542bLi2<\/sub>S6<\/sub>\u7684\u5bf9\u79f0\u7535\u6c60\u7684CV\u66f2\u7ebf\uff1b<\/p>\n

\uff08b\uff09Li2<\/sub>S6<\/sub>\u5bf9\u79f0\u7535\u6c60\u7684EIS\u56fe\u8c31\uff1b<\/p>\n

\uff08c\uff09S@CoS2<\/sub>-LBLCN\u6b63\u6781\u5728\u4e0d\u540c\u626b\u901f\u4e0b\u7684CV\u66f2\u7ebf\uff1b<\/p>\n

\uff08d-f\uff09S@CoS2<\/sub>-LBLCN\u548cS@LBLCN\u6b63\u6781\u6c27\u5316\u8fd8\u539f\u8fc7\u7a0b\u7684CV\u5cf0\u7535\u6d41\u4e0e\u626b\u901f\u5e73\u65b9\u6839\u7684\u5173\u7cfb\u56fe\uff1b<\/p>\n

\uff08g\uff09CoS2<\/sub>\u7eb3\u7c73\u9897\u7c92\u5bf9\u591a\u786b\u5316\u7269\u6355\u83b7\u548c\u8f6c\u5316\u4f5c\u7528\u7684\u793a\u610f\u56fe\u3002<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n

\u7efc\u4e0a\u6240\u8ff0\uff0c\u57fa\u4e8e\u5c42\u5c42\u7ec4\u88c5\u7684\u8bbe\u8ba1\u7406\u5ff5\uff0c\u4f5c\u8005\u7814\u5236\u51fa\u4e86\u4e00\u79cd\u53ef\u6709\u6548\u50ac\u5316\u591a\u786b\u5316\u7269\u8f6c\u5316\u7684S@CoS2<\/sub>-LBLCN\u590d\u5408\u6b63\u6781\u3002LBLCN\u5177\u6709\u76f8\u4e92\u8d2f\u7a7f\u7684\u5bfc\u7535\u9aa8\u67b6\u548c\u5206\u7ea7\u7684\u591a\u5b54\u7ed3\u6784\uff0c\u53ef\u4ee5\u4fc3\u8fdb\u79bb\u5b50\u548c\u7535\u5b50\u7684\u5feb\u901f\u4f20\u8f93\uff0c\u5e76\u4e3a\u786b\u7684\u50a8\u5b58\u548c\u5faa\u73af\u8fc7\u7a0b\u4e2d\u786b\u7684\u4f53\u79ef\u81a8\u80c0\u63d0\u4f9b\u4e86\u8db3\u591f\u7684\u7a7a\u95f4\u3002\u6b64\u5916\uff0cBMZIFs\u884d\u751f\u7684\u8d85\u7ec6CoS2<\/sub>\u7eb3\u7c73\u9897\u7c92\u5177\u6709\u8f83\u5f3a\u7684\u4eb2\u786b\u6027\u548c\u8f83\u9ad8\u7684\u50ac\u5316\u6d3b\u6027\uff0c\u53ef\u4ee5\u6709\u6548\u4fc3\u8fdb\u591a\u786b\u5316\u7269\u7684\u6c27\u5316\u8fd8\u539f\u53cd\u5e94\u52a8\u529b\u5b66\u3002\u57fa\u4e8eS@CoS2<\/sub>-LBLCN\u6b63\u6781\u7684\u9502\u786b\u7535\u6c60\u57285C\u500d\u7387\u4e0b\u5faa\u73af1000\u5468\u540e\u5bf9\u5e94\u7684\u5bb9\u91cf\u8870\u51cf\u7387\u4ec5\u4e3a0.033%\/\u5468\uff0c\u57281C\u548c5C\u500d\u7387\u4e0b\u7684\u653e\u7535\u5bb9\u91cf\u5206\u522b\u4e3a1180.7\u548c700 mAh g-1<\/sup>\u3002\u603b\u4e4b\uff0c\u8be5\u5c42\u5c42\u7ec4\u88c5\u7684\u8bbe\u8ba1\u7406\u5ff5\u4e3a\u9ad8\u500d\u7387\u9502-\u786b\u7535\u6c60\u63d0\u4f9b\u4e86\u4e00\u79cd\u65b0\u7684\u7b56\u7565\uff0c\u8be5\u7b56\u7565\u4e5f\u53ef\u5e94\u7528\u4e8e\u5176\u4ed6\u7535\u5316\u5b66\u9886\u57df\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1aBoosting High-Rate Li-S Batteries by an MOF-Derived Catalytic Electrode with a Layer-by-Layer Structure<\/strong>\uff08Adv. Sci., 2019<\/strong>, DOI:10.1002\/advs.201802362\uff09<\/p>\n

\u901a\u8baf\u4f5c\u8005\u7b80\u4ecb<\/strong><\/p>\n

\"\"<\/p>\n

\u9648\u4eba\u6770\uff0c\u5317\u4eac\u7406\u5de5\u5927\u5b66\u6559\u6388\u3001\u535a\u5bfc\uff1b\u4e2d\u56fd\u6750\u6599\u7814\u7a76\u5b66\u4f1a\u7406\u4e8b\uff08\u80fd\u6e90\u8f6c\u6362\u4e0e\u5b58\u50a8\u6750\u6599\u5206\u4f1a\u79d8\u4e66\u957f\uff09\u3001\u4e2d\u56fd\u56fa\u6001\u79bb\u5b50\u5b66\u4f1a\u7406\u4e8b\u3001\u56fd\u9645\u7535\u5316\u5b66\u80fd\u6e90\u79d1\u5b66\u5b66\u4f1a\uff08IAOEES\uff09\u59d4\u5458\u4f1a\u59d4\u5458\u3001\u5317\u4eac\u7535\u52a8\u8f66\u8f86\u534f\u540c\u521b\u65b0\u4e2d\u5fc3\u7814\u7a76\u5458<\/strong>\u3002\u4e3b\u8981\u7814\u7a76\u9886\u57df\uff1a\u591a\u7535\u5b50\u9ad8\u6bd4\u80fd\u4e8c\u6b21\u7535\u6c60\u65b0\u4f53\u7cfb\u53ca\u5173\u952e\u6750\u6599\u3001\u65b0\u578b\u79bb\u5b50\u6db2\u4f53\u53ca\u529f\u80fd\u7535\u89e3\u8d28\u6750\u6599\u3001\u7279\u79cd\u529f\u80fd\u7535\u6e90\u5168\u56fa\u6001\u4e8c\u6b21\u7535\u6c60\u5668\u4ef6\u53ca\u8584\u819c\u6750\u6599\u3002\u4f5c\u4e3a\u8d1f\u8d23\u4eba\uff0c\u627f\u62c5\u4e86\u56fd\u5bb6\u81ea\u7136\u79d1\u5b66\u57fa\u91d1\u59d4\u9879\u76ee\u3001\u79d1\u6280\u90e8\u91cd\u70b9\u7814\u53d1\u8ba1\u5212\u9879\u76ee\u3001\u79d1\u6280\u90e8863\u8ba1\u5212\u9879\u76ee\u3001\u79d1\u6280\u90e8\u56fd\u9645\u79d1\u6280\u5408\u4f5c\u9879\u76ee\u3001\u4e2d\u592e\u5728\u4eac\u9ad8\u6821\u91cd\u5927\u6210\u679c\u8f6c\u5316\u9879\u76ee\u3001\u5317\u4eac\u5e02\u91cd\u5927\u79d1\u6280\u9879\u76ee\u7b49\u8bfe\u9898\u3002\u5728Chem. Soc. Rev.\u3001Adv. Mater.\u3001Nature Commun.\u7b49\u671f\u520a\u53d1\u8868SCI\u6536\u5f55\u8bba\u6587220\u4f59\u7bc7\uff08IF>10\u768458\u7bc7\uff09\uff1b\u7533\u8bf7\u53d1\u660e\u4e13\u522968\u9879\uff0c\u83b7\u6388\u674328\u9879\uff1b\uff1b\u83b7\u6279\u8f6f\u4ef6\u8457\u4f5c\u67435\u9879\uff0c\u51fa\u7248\u5b66\u672f\u4e13\u84572\u90e8\u3002\u4f5c\u4e3a\u4e3b\u8981\u5b8c\u6210\u4eba\uff0c\u83b7\u5f97\u56fd\u5bb6\u6280\u672f\u53d1\u660e\u4e8c\u7b49\u59561\u9879\u3001\u90e8\u7ea7\u79d1\u5b66\u6280\u672f\u4e00\u7b49\u59563\u9879\u30022009\u5e74\u5165\u9009\u6559\u80b2\u90e8\u201c\u65b0\u4e16\u7eaa\u4f18\u79c0\u4eba\u624d\u652f\u6301\u8ba1\u5212\u201d\uff0c2010\u5e74\u5165\u9009\u5317\u4eac\u5e02\u4f18\u79c0\u4eba\u624d\u57f9\u517b\u8d44\u52a9\u8ba1\u5212\u3001\u5317\u4eac\u5e02\u79d1\u6280\u65b0\u661f\u8ba1\u5212\uff0c2018\u5e74\u5165\u9009\u5317\u4eac\u9ad8\u7b49\u5b66\u6821\u5353\u8d8a\u9752\u5e74\u79d1\u5b66\u5bb6\u8ba1\u5212\u3002<\/p>\n

\u9ad8\u6027\u80fd\u4e8c\u6b21\u7535\u6c60\u65b0\u4f53\u7cfb\u7684\u521b\u65b0\u7814\u7a76\u4e00\u76f4\u662f\u5f53\u524d\u65b0\u80fd\u6e90\u7814\u7a76\u9886\u57df\u7684\u70ed\u70b9\uff0c\u9648\u4eba\u6770\u6559\u6388\u56f4\u7ed5\u591a\u7535\u5b50\u9ad8\u6bd4\u80fd\u9502-\u786b\u4e8c\u6b21\u7535\u6c60\u53ca\u5173\u952e\u6750\u6599\u5f00\u5c55\u4e86\u4ece\u539f\u7406\u521b\u65b0\u3001\u6750\u6599\u7a81\u7834\u5230\u5668\u4ef6\u6784\u7b51\u7684\u7cfb\u7edf\u7814\u7a76\u3002<\/p>\n

1. \u9488\u5bf9\u9502-\u786b\u7535\u6c60\u7684\u6d3b\u6027\u7269\u8d28\u5229\u7528\u7387\u4f4e\u3001\u5faa\u73af\u5bff\u547d\u5dee\u3001\u5b58\u5728\u5b89\u5168\u7a33\u5b9a\u77ed\u677f\u7b49\u6280\u672f\u96be\u70b9\uff0c\u7814\u5236\u4e86\u9ad8\u8f7d\u786b\u9ad8\u5bfc\u7535\u591a\u7ef4\u7a33\u5b9a\u590d\u5408\u7535\u6781\uff08\u4e09\u7ef4\u591a\u5b54\u5c42\u72b6\u7ed3\u6784\u7684\u77f3\u58a8\u70ef-\u591a\u58c1\u78b3\u7eb3\u7c73\u7ba1\/\u786b\u590d\u5408\u6750\u6599\uff08Nano Lett., 2013<\/strong>, 13:4642; Nano Energy, 2015<\/strong>, 12: 742\uff09\u3001\u77f3\u58a8\u70ef-\u91d1\u5c5e\u6709\u673a\u6846\u67b6\u6750\u6599\/\u786b\u590d\u5408\u6750\u6599\uff08AIP\/APL Mater., 2014<\/strong>, 2: 124109\uff09\u548c\u787c\u63ba\u6742\u5fae\u5b54\u7eb3\u7c73\u78b3\/\u786b\u590d\u5408\u6750\u6599\uff08Nano Res., 2017<\/strong>, 10: 426\uff09\uff1b\u91c7\u7528\u539f\u4f4d\u5316\u5b66\u6c27\u5316\u6cd5\u5148\u540e\u5408\u6210\u4e86\u9897\u7c92\u5747\u5300\u3001\u5206\u6563\u826f\u597d\u7684\u805a\u591a\u5df4\u80fa\uff08Adv. Energy Mater., 2017<\/strong>, 7: 1601591\uff09\u4e3a\u4ee3\u8868\u7684\u7cfb\u5217\u805a\u5408\u7269\uff08\u805a\u567b\u5429\uff08J. Phys. Chem. C, 2011<\/strong>, 115: 6057\uff09\/\u805a\u82ef\u80fa\uff08J. Phys. Chem. C, 2011<\/strong>, 115: 24411\uff09\/\u805a\u5421\u54af\uff08ChemSusChem, 2013<\/strong>, 6: 1438\uff09\uff09\u5305\u8986\u4fee\u9970\u786b\u57fa\u590d\u5408\u7535\u6781\u6750\u6599\uff09\uff0c\u63d0\u9ad8\u4e86\u6bd4\u5bb9\u91cf\u548c\u500d\u7387\u6027\u80fd\u3002<\/p>\n

2. \u8bbe\u8ba1\u4e86\u8f7b\u8d28\u529f\u80fd\u4fee\u9970\u9694\u819c\/\u5939\u5c42\uff08\u805a\u591a\u5df4\u80fa\u6539\u6027\u7684\u53cc\u5c42\u5305\u8986\u9009\u62e9\u6027\u901a\u8fc7\u9694\u819c\uff08Nano Lett., 2015<\/strong>, 15: 7431\uff09\u3001\u787c\u63ba\u6742\u77f3\u58a8\u70ef\u6d82\u8986\u9694\u819c\uff08J. Mater. Chem. A, 2016<\/strong>, 4: 17033\uff09\u3001\u80a0\u9053\u7ed2\u6bdb\u4eff\u751f\u7ed3\u6784ZnO\u7eb3\u7c73\u5438\u9644\u9635\u5217\uff08ZnO\/Ni\uff09\u529f\u80fd\u5939\u5c42\uff08Adv. Funct. Mater., 2016<\/strong>, 26: 8418\uff09\u3001\u201c\u679c\u4ec1\u7cd6\u201d\u7ed3\u6784\u7684TiO2<\/sub>-\u78b3\u7ea4\u7ef4\uff08TiO2<\/sub>-C\uff09\u5939\u5c42\uff08Small, 2017<\/strong>, 13: 1700357\uff09\u3002<\/p>\n

3. \u53d1\u660e\u4e86\u9ad8\u5b89\u5168\u529f\u80fd\u590d\u5408\u7535\u89e3\u8d28\u6750\u6599\u5e76\u6784\u7b51\u4e863D\u7eb3\u7c73\u9635\u5217\u4fee\u9970\u6539\u6027\u9502\u8d1f\u6781\uff0c\u663e\u8457\u6539\u5584\u4e86\u5b89\u5168\u6027\u548c\u7a33\u5b9a\u6027\uff08\u4ee5LiODFB\uff08ACS Appl. Mater. Inter., 2014<\/strong>, 6: 15542; J. Power Sources, 2015<\/strong>, 296: 10\uff09\u3001LiTFSI\uff08Electrochimica Acta, 2015<\/strong>, 184: 356\uff09\u7b49\u4e3a\u590d\u914d\u9502\u76d0\u3001\u542b\u6709\u919a\u57fa\u5b98\u80fd\u56e2\u7684\u79bb\u5b50\u6db2\u4f53N-\u7532\u57fa-N-\u7532\u6c27\u57fa\u4e59\u57fa\u5421\u54af\u70f7\u53cc(\u4e09\u6c1f\u78fa\u9170\u4e9a\u80fa)\u4e3a\u4e3b\u6eb6\u5242\u3001\u4e09(\u4e59\u4e8c\u9187)\u4e8c\u7532\u919a\u4e3a\u5171\u6eb6\u5242\u7684\u6db2\u6001\u7535\u89e3\u8d28\u6750\u6599\uff1b\u81ea\u9002\u5e94\u7eb3\u7c73\u4ea4\u8054\u57fa\u590d\u5408\u56fa\u6001\u7535\u89e3\u8d28\uff0c\u9009\u7528SiO2<\/sub>\uff08Adv. Mater. 2011<\/strong>, 23, 5081\uff09\u3001TiO2<\/sub>\uff08Chem. Mater. 2016<\/strong>, 28: 848; Adv. Sci. 2016<\/strong>, 3: 1500306; Nano Energy, 2018<\/strong>, 47: 35\uff09\u3001ZrO2<\/sub>\uff08J. Mater. Chem. A, 2017<\/strong>, 5: 24677\uff09\u6216MOF\uff08J. Mater. Chem. A, 2019<\/strong>, 10.1039\/C8TA12539B\uff09\u6750\u6599\u91c7\u7528\u7eb3\u7c73\u4ea4\u8054\u5668\u901a\u8fc7\u539f\u4f4d\u6eb6\u80f6\u51dd\u80f6\u53cd\u5e94\u5c06\u79bb\u5b50\u6db2\u4f53\u57fa\u7535\u89e3\u6db2\uff08\u54aa\u5511\u3001\u54cc\u5576\u3001\u5421\u54af\u70f7\u7b49\uff09\u901a\u8fc7\u914d\u4f4d\u548c\u4ef7\u952e\u4f5c\u7528\u56fa\u5b9a\u5728\u4ea4\u8054\u5668\u7684\u7eb3\u7c73\u5b54\u9053\u5185\u5f62\u6210\u590d\u5408\u56fa\u6001\u7535\u89e3\u8d28\uff0c\u63d0\u9ad8\u4e0e\u7535\u6781\u6750\u6599\u7684\u7535\u5316\u5b66\u517c\u5bb9\u6027\uff0c\u6291\u5236\u9502\u679d\u6676\u7684\u5f62\u6210\uff1b\u6838\u58f3\u7ed3\u6784\u7eb3\u7c73\u9635\u5217\u8584\u819c\u4fee\u9970\u5c42\uff08Nature Commun., 2016<\/strong>, 7: 11774\uff09\u3001\u5361\u535a\u7279\u70ad\u9ed1XC-72\u7eb3\u7c73\u6a21\u5757\u91d1\u5c5e\u9502\u8d1f\u6781\u4fee\u9970\u5c42\uff08Energy Storage Mater., 2017<\/strong>, 9: 126\uff09\u3001\u7279\u5b9a\u5c3a\u5ea6\u591a\u5b54\u7ed3\u6784\u590d\u5408\u7535\u89e3\u8d28\u4fee\u9970\u5c42\uff08Energy Environ. Sci., 2017<\/strong>, 10: 1660; Adv. Energy Mater., 2018<\/strong>, 1702675\uff09\u63d0\u5347\u4e86\u9502\u91d1\u5c5e\u7684\u7a33\u5b9a\u6027\u80fd\uff09\u3002<\/p>\n

4. \u9488\u5bf9\u6750\u6599\u4f18\u5316\u8bbe\u8ba1\u96be\u3001\u5de5\u7a0b\u5b9e\u73b0\u5b58\u5728\u74f6\u9888\u7684\u6280\u672f\u96be\u70b9\uff0c\u6784\u5efa\u591a\u76ee\u6807\u4f18\u5316\u7684\u7406\u8bba\u8ba1\u7b97\u6a21\u578b\uff0c\u63d0\u51fa\u9502\u786b\u7535\u6c60\u6838\u5fc3\u6750\u6599\u7814\u7a76\u601d\u8def\uff08\u9502\u786b\u7535\u6c60\u6b63\u6781\u6750\u6599\uff08Chem. Commun., 2015<\/strong>, 51: 18\uff09\u3001\u591a\u7535\u5b50\u4f53\u7cfb\uff08Adv. Sci., 2016<\/strong>, 3: 1600051\uff09\u3001\u56fa\u6001\u7535\u89e3\u8d28\u6750\u6599\uff08Mater. Horiz., 2016<\/strong>, 3: 487\uff09\u3001\u9502\u786b\u7535\u6c60\u7535\u89e3\u8d28\u6750\u6599\uff08Adv. Funct. Mater., 2018<\/strong>, 1800919\uff09\u3001\u9502\u786b\u7535\u6c60\u8d1f\u6781\u6750\u6599\uff08Adv. Mater., 2018<\/strong>, DOI: 10.1002\/adma.201806532\uff09\uff09\u548c\u7535\u6c60\u5de5\u7a0b\u5316\u53d1\u5c55\u65b9\u5411\uff08J. Phys. Chem. Lett., 2018<\/strong>, 9: 1398\uff09\uff0c\u5f00\u53d1\u51fa\u9502\u786b\u7535\u6c60\u6750\u6599\u57fa\u56e0\u7ec4\u6570\u636e\u5e73\u53f0\uff082019SR0174149\u30012019SR0174157\u7b49\uff09\uff0c\u6784\u5efa\u4e86\u9ad8\u786b\u542b\u91cf\u548c\u9ad8\u786b\u8f7d\u91cf\u6b63\u6781\uff08ACS Nano, 2017<\/strong>, 11: 4694\u3001Adv. Mater., 2017<\/strong>, 29: 1700598\uff09\uff0c\u7814\u5236\u51fa1.5Ah\u30012Ah\u30015Ah\u300110Ah\u300120Ah\u548c30Ah\u7b49\u7ea7\u522b\u7684\u9502\u786b\u7535\u6c60\u6837\u54c1\uff08\u5bb9\u91cf18.6Ah\uff0c\u80fd\u91cf\u5bc6\u5ea6460Wh\/kg\uff0c100%DOD\u5faa\u73af10\u5468\uff0c\u4fdd\u6301\u7387>90%\uff1b\u5bb9\u91cf30Ah\uff0c\u80fd\u91cf\u5bc6\u5ea6545Wh\/kg\uff0c100%DOD\u5faa\u73af8\u5468\uff0c\u4fdd\u6301\u7387>85%\uff09\u548c\u957f\u5faa\u73af\u5bff\u547d\u578b\u7535\u6c60\uff08\u5bb9\u91cf3.6Ah\uff0c\u80fd\u91cf\u5bc6\u5ea6352Wh\/kg\uff0c100%DOD\u5faa\u73af100\u5468\uff0c\u4fdd\u6301\u7387>70%\uff09\uff09\uff0c\u5e76\u5df2\u5728\u65e0\u4eba\u673a\u3001\u673a\u5668\u4eba\u7b49\u65b9\u9762\u5f00\u5c55\u4e86\u5e94\u7528\u8bc4\u6d4b\u3002<\/strong><\/p>\n

\u672c\u6587\u7531CQR\u7f16\u8bd1\u3002<\/p>\n

\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1\uff1atougao@cailiaoren.com.<\/p>\n

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