{"id":181068,"date":"2019-07-22T06:30:53","date_gmt":"2019-07-21T22:30:53","guid":{"rendered":"\/\/m.iemloyee.com\/?p=181068"},"modified":"2019-07-21T23:21:17","modified_gmt":"2019-07-21T15:21:17","slug":"%e5%b7%b2%e6%a0%a1-angew-chem-int-ed-cu2-cu-%e6%b0%a7%e5%8c%96%e8%bf%98%e5%8e%9f%e7%94%b5%e8%8d%b7%e8%bd%bd%e4%bd%93%e7%94%b5%e6%9e%81%e6%9d%90%e6%96%99%e7%9a%84%e5%ba%94%e7%94%a8","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=181068","title":{"rendered":"Angew. Chem. Int. Ed. : Cu2+\/Cu+ \u6c27\u5316\u8fd8\u539f\u7535\u8377\u8f7d\u4f53\u7535\u6781\u6750\u6599\u7684\u5e94\u7528"},"content":{"rendered":"<p><strong>\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n<p>\n \u7535\u6c60\u7535\u6781\u7684\u7535\u5316\u5b66\u6027\u8d28\u662f\u7531\u5b83\u6240\u53c2\u4e0e\u7684\u7535\u5316\u5b66\u8fc7\u7a0b\u51b3\u5b9a\u7684\uff0c\u8fd9\u4e2a\u8fc7\u7a0b\u4e0d\u5b8c\u5168\u662f\u7531\u7535\u6781\u6750\u6599\u81ea\u8eab\u6240\u4e3b\u5bb0\u7684\uff0c\u8fd9\u4e2a\u7535\u5316\u5b66\u8fc7\u7a0b\u4e2d\u6709\u201c\u53cd\u5e94\u7269\u201d\u548c\u201c\u4ea7\u7269\u201d\u3002\u4ea7\u7269\u7684\u4e0d\u540c\u53ef\u4e25\u91cd\u6539\u53d8\u4e00\u4e2a\u7535\u6781\u7684\u6c27\u5316\u8fd8\u539f\u884c\u4e3a\u3002\u800c\u8fd9\u91cc\u4ea7\u7269\u7684\u5f62\u6210\u548c\u7535\u6c60\u91cc\u7684\u79bb\u5b50\u8f7d\u6d41\u5b50\u7684\u6027\u8d28\u5173\u7cfb\u5bc6\u5207\uff0c\u5c24\u5176\u662f\u5f53\u8f7d\u6d41\u5b50\u81ea\u5df1\u6709\u6c27\u5316\u8fd8\u539f\u6d3b\u6027\u7684\u65f6\u5019\u3002 \u6240\u4ee5\u79bb\u5b50\u8f7d\u6d41\u5b50\u7684\u9009\u62e9\u5bf9\u7535\u6c60\u7535\u6781\u6027\u80fd\u7684\u5f71\u54cd\u81f3\u5173\u91cd\u8981\u3002\u4e0a\u8ff0\u5177\u6709\u6c27\u5316\u8fd8\u539f\u6d3b\u6027\u7684\u79bb\u5b50\u8f7d\u6d41\u5b50(RIC)\u5bf9\u7535\u6781\u7684\u597d\u5904\u662f\u53cc\u91cd\u7684\uff1a(1)\u79bb\u5b50\u7684\u6c27\u5316\u8fd8\u539f\u53cd\u5e94\u53ef\u4ee5\u8d21\u732e\u989d\u5916\u7684\u5bb9\u91cf\uff1b(2)\u6c27\u5316\u8fd8\u539f\u6d3b\u6027\u79bb\u5b50(\u5982\u8fc7\u6e21\u91d1\u5c5e\u79bb\u5b50)\u53ef\u4fc3\u8fdb\u7535\u6781\u6750\u6599\u5185\u7684\u4e30\u5bcc\u7684\u952e\u5408\u5316\u5b66\u3002<\/p>\n<p><strong>\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n<p>\n \u8fd1\u65e5\uff0c<strong>\u7f8e\u56fd\u4fc4\u52d2\u5188\u5dde\u7acb\u5927\u5b66\u7eaa\u79c0\u78ca\u6559\u6388\u3001\u7f8e\u56fd\u963f\u8d21\u56fd\u5bb6\u5b9e\u9a8c\u5ba4\u9646\u4fca\u7814\u7a76\u5458(\u5171\u540c\u901a\u8baf\u4f5c\u8005)\u7b49<\/strong>\u5c06\u5143\u7d20\u786b\u7535\u6781\u4e0eCu<sup>2+<\/sup>\u4f5c\u4e3a\u8f7d\u6d41\u5b50\u8026\u5408\uff0c\u901a\u8fc7S\u2194CuS\u2194Cu<sub>2<\/sub>S\u7684\u8f6c\u6362\u5b9e\u73b0\u4e86\u56db\u7535\u5b50\u786b\u7535\u6781\u53cd\u5e94\u3002\u8be5\u6210\u679c\u7684\u7814\u7a76\u8bba\u6587\u5728<strong>Angew. Chem. Int. Ed.<\/strong>\u4e0a\u53d1\u8868\uff0c\u9898\u4e3a\u201c<strong>A Four-Electron Sulfur Electrode Hosting Cu<sup>2+<\/sup>\/Cu<sup>+<\/sup> Redox Charge Carrier<\/strong>\u201d\u3002Cu-S\u6c27\u5316\u8fd8\u539f\u79bb\u5b50\u7535\u6781\u53ef\u63d0\u4f9b\u7ea63044 mAh\u00b7g<sup>-1<\/sup>(\u57fa\u4e8e\u786b\u8d28\u91cf)\u6216609 mAh\u00b7g<sup>-1<\/sup>(\u57fa\u4e8eCu<sub>2<\/sub>S\u8d28\u91cf)\u7684\u9ad8\u6bd4\u5bb9\u91cf\uff0c\u57280.5 V(vs. SHE)\u663e\u793a\u51fa\u524d\u6240\u672a\u6709\u4e4b\u9ad8\u7684\u786b\/\u91d1\u5c5e\u786b\u5316\u7269\u7684\u8fd8\u539f\u7535\u52bf\u3002\u6b64\u5916\uff0cCu-S\u7535\u6781\u8fd8\u5177\u6709\u6781\u4f4e\u7684\u6781\u5316\u7a0b\u5ea6(0.05 V)\uff0c\u572812.5 A\u00b7g<sup>-1<\/sup>\u7684\u7535\u6d41\u5bc6\u5ea6\u4e0b\u5faa\u73af1200\u5468\u540e\u521d\u59cb\u5bb9\u91cf\u4fdd\u630172 %\u3002\u5728\u91c7\u7528Zn\u91d1\u5c5e\u8d1f\u6781\u4ee5\u53ca\u9634\u79bb\u5b50\u4ea4\u6362\u819c\u4f5c\u4e3a\u9694\u819c\u7684\u6df7\u5408\u7535\u6c60\u4e2d\u8fdb\u4e00\u6b65\u8bc1\u660e\u4e86\u4e0a\u8ff0Cu-S\u6b63\u6781\u7684\u663e\u8457\u6548\u679c\uff0c\u5176\u4ea7\u751f\u7684\u5e73\u5747\u7535\u6c60\u653e\u7535\u7535\u538b\u4e3a1.15 V\uff0c\u534a\u7535\u6c60\u6bd4\u80fd\u91cf\u8fbe\u5230547 Wh\u00b7kg<sup>-1<\/sup>(\u57fa\u4e8eCu<sub>2<\/sub>S\/\u78b3\u590d\u5408\u6b63\u6781\u8d28\u91cf)\uff0c\u5e76\u4e14\u5728110\u4e2a\u5faa\u73af\u5185\u7a33\u5b9a\u5faa\u73af\u3002<\/p>\n<p><strong>\u3010\u56fe\u6587\u7b80\u4ecb\u3011<\/strong><br \/>\n <strong> \u56fe1 Cu-S RIC\u7535\u6781\u7684\u7535\u5316\u5b66\u6027\u80fd\u548c\u8868\u5f81<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-181069\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2019\/07\/1-28.jpg\" alt=\"\" width=\"604\" height=\"235\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2019\/07\/1-28.jpg 604w, \/\/m.iemloyee.com\/wp-content\/uploads\/2019\/07\/1-28-300x117.jpg 300w\" sizes=\"(max-width: 604px) 100vw, 604px\" \/><\/p>\n<p>a) \u4e09\u7535\u6781\u7535\u6c60\u4e2dS\/AC\u7535\u6781(50 wt% \u786b)\u7684GCD\u66f2\u7ebf\uff0c\u7535\u6d41\u901f\u7387\u4e3a100 mA\u00b7g<sup>-1<\/sup>\uff1b<br \/>\n b) Cu-K\u8fb9\u5149\u8c31\u7684\u5f52\u4e00\u5316XANES\uff1b<br \/>\n c) 10 mA\u00b7g<sup>-1<\/sup>\u4e0b\u5177\u6709\u786b\u6676\u4f53\u7684S\/C\u7535\u6781\u7684GCD\u66f2\u7ebf\uff1b<br \/>\n d) \u4e0d\u540cSOC\u4e0b\u7684\u975e\u539f\u4f4dXRD\u56fe\u8c31\uff1b<br \/>\n e) S8\u3001CuS\u548cCu<sub>2<\/sub>S\u7684\u6676\u80de\u7684\u793a\u610f\u56fe\uff0c\u663e\u793aCu-S RIC\u7535\u6781\u7684\u8f6c\u6362\u9014\u5f84\uff1b<br \/>\n f) Cu\u91d1\u5c5e\u3001S\u3001CuS\u548cCu<sub>2<\/sub>S\u4e4b\u95f4\u7684\u5409\u5e03\u65af\u81ea\u7531\u80fd\u53d8\u5316\u548c\u53cd\u5e94\u7535\u52bf\u3002<\/p>\n<p><strong>\u56fe2 Cu-S RIC\u7535\u6781\u5728\u4e09\u7535\u6781\u7535\u6c60\u4e2d\u7684\u7535\u5316\u5b66\u6027\u80fd<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-181070\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2019\/07\/2-28.jpg\" alt=\"\" width=\"611\" height=\"295\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2019\/07\/2-28.jpg 611w, \/\/m.iemloyee.com\/wp-content\/uploads\/2019\/07\/2-28-300x145.jpg 300w\" sizes=\"(max-width: 611px) 100vw, 611px\" \/><\/p>\n<p>a) \u50a8\u5b58Li<sup>+<\/sup>\u3001Cu<sup>2+<\/sup>\/Cu<sup>+<\/sup>\u3001Mn<sup>2+<\/sup>\u548cPb<sup>2+<\/sup>\u65f6S\/AC\u7535\u6781\u7684GCD\u66f2\u7ebf\u6bd4\u8f83\uff1b<br \/>\n b) \u786b\u7535\u6781\u5728\u4e09\u7535\u6781\u7535\u6c60\u4e2d\u50a8\u5b58\u4e0d\u540c\u91d1\u5c5e\u9633\u79bb\u5b50\u7684\u6781\u5316\u7a0b\u5ea6\uff1b<br \/>\n c) Cu-S RIC\u7535\u6781\u7684\u500d\u7387\u6027\u80fd\uff1b<br \/>\n d) 0.5 A\u00b7g<sup>-1<\/sup> (~0.186 C)\u65f6\u7684\u5faa\u73af\u6027\u80fd\uff1b<br \/>\n e) 12.5 A\u00b7g<sup>-1<\/sup>(~4.66 C)\u65f6\u7684\u5faa\u73af\u6027\u80fd\uff1b<br \/>\n f) S\/KB\u590d\u5408\u7535\u6781\u5728100 mA\u00b7g<sup>-1<\/sup>\u4e0b\u7684GCD\u66f2\u7ebf\u3002<\/p>\n<p><strong>\u56fe3 Cu-S || Zn\u6df7\u5408\u7535\u6c60<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-181071\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2019\/07\/3-28.jpg\" alt=\"\" width=\"600\" height=\"406\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2019\/07\/3-28.jpg 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2019\/07\/3-28-300x203.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>a) \u6df7\u5408\u7535\u6c60\u7684\u5de5\u4f5c\u673a\u7406\u793a\u610f\u56fe\uff1b<br \/>\n b) S\/KB\u6b63\u6781\u3001ZMA\u548c\u76f8\u5e94\u7684\u6df7\u5408\u7535\u6c60\u7535\u538b\u7684GCD\u7535\u4f4d\u66f2\u7ebf\uff1b<br \/>\n c) 50 mA\u00b7g<sup>-1<\/sup>\u4e0b\u6df7\u5408\u7535\u6c60\u7684\u9009\u5b9aGCD\u66f2\u7ebf\uff1b<br \/>\n d) \u5faa\u73af\u6027\u80fd\uff0c\u6bd4\u5bb9\u91cf\u548c\u7535\u6d41\u500d\u7387\u57fa\u4e8eS\/KB\u590d\u5408\u6750\u6599\u7684\u8d28\u91cf\u3002<\/p>\n<p><strong>\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n<p>\n \u7efc\u4e0a\u6240\u8ff0\uff0c\u4f5c\u8005\u5c55\u793a\u4e86\u901a\u8fc7RIC\u7535\u6781\u589e\u52a0\u7535\u6781\u7684\u5bb9\u91cf\u548c\u5de5\u4f5c\u7535\u538b\u7684\u901a\u7528\u7b56\u7565\uff0c\u5176\u4e2d\u79bb\u5b50\u8f7d\u6d41\u5b50\u7528\u4f5c\u7535\u5b50\u7535\u8377\u7684\u9644\u52a0\u50a8\u5b58\u5668\u3002\u5728Cu-S RIC\u4f53\u7cfb\u4e2d\uff0c\u786b\u7535\u6781\u8fdb\u884c\u4e86\u56db\u7535\u5b50\u8f6c\u79fb\uff0c\u5177\u6709\u9ad8\u5bb9\u91cf\u3001\u9ad8\u5de5\u4f5c\u7535\u538b\u3001\u6700\u5c0f\u7684\u6781\u5316\u7a0b\u5ea6\u4ee5\u53ca\u8f83\u7a33\u5b9a\u7684\u5faa\u73af\u3002\u975e\u539f\u4f4dXRD\u548cXANES\u7814\u7a76\u63ed\u793a\u4e86\u901a\u8fc7S\u2194CuS\u2194Cu<sub>2<\/sub>S\u8f6c\u5316\u7684\u53cd\u5e94\u9014\u5f84\u3002\u8be5\u7814\u7a76\u5f3a\u8c03\u4e86\u79bb\u5b50\u7535\u8377\u8f7d\u4f53\u5728\u786e\u5b9a\u7535\u6c60\u7535\u6781\u7684\u70ed\u529b\u5b66\u548c\u52a8\u529b\u5b66\u6027\u8d28\u4e2d\u7684\u5173\u952e\u4f5c\u7528\u3002<\/p>\n<p><strong>\u6587\u732e\u94fe\u63a5\uff1aA Four-Electron Sulfur Electrode Hosting Cu<sup>2+<\/sup>\/Cu<sup>+<\/sup> Redox Charge Carrier <\/strong>(<strong>Angew. Chem. Int. Ed.<\/strong>, 2019, DOI: 10.1002\/anie. 201905875)<\/p>\n<p>\u672c\u6587\u7531abc940504\u3010\u8096\u6770\u3011\u7f16\u8bd1\u6574\u7406\uff0c\u53c2\u4e0e\u65b0\u80fd\u6e90\u8bdd\u9898\u8ba8\u8bba\u8bf7\u52a0\u5165\u201c\u6750\u6599\u4eba\u65b0\u80fd\u6e90\u6750\u6599\u4ea4\u6d41\u7fa4 422065953\u201d\u3002<\/p>\n<p><strong>\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1acailiaokefu\uff0c\u6211\u4eec\u4f1a\u9080\u8bf7\u5404\u4f4d\u8001\u5e08\u52a0\u5165\u4e13\u5bb6\u7fa4\u3002<\/strong><\/p>\n<p>\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1tougao@cailiaoren.com\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u3010\u5f15\u8a00\u3011 \u7535\u6c60\u7535\u6781\u7684\u7535\u5316\u5b66\u6027\u8d28\u662f\u7531\u5b83\u6240\u53c2\u4e0e\u7684\u7535\u5316\u5b66\u8fc7\u7a0b\u51b3\u5b9a\u7684\uff0c\u8fd9\u4e2a\u8fc7\u7a0b\u4e0d\u5b8c\u5168\u662f\u7531\u7535\u6781\u6750\u6599\u81ea\u8eab\u6240\u4e3b\u5bb0\u7684\uff0c\u8fd9\u4e2a\u7535\u5316\u5b66\u8fc7\u7a0b\u4e2d\u6709\u201c\u53cd\u5e94\u7269\u201d\u548c\u201c\u4ea7\u7269\u201d\u3002\u4ea7\u7269\u7684\u4e0d\u540c\u53ef\u4e25\u91cd\u6539&#8230;<\/p>\n","protected":false},"author":4931,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[4108,4106,4107],"class_list":["post-181068","post","type-post","status-publish","format-standard","hentry","category-jiedu","tag-4108","tag-4106","tag-4107"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/181068"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/4931"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=181068"}],"version-history":[{"count":2,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/181068\/revisions"}],"predecessor-version":[{"id":181123,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/181068\/revisions\/181123"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=181068"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=181068"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=181068"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}