{"id":181008,"date":"2019-07-21T06:30:03","date_gmt":"2019-07-20T22:30:03","guid":{"rendered":"\/\/m.iemloyee.com\/?p=181008"},"modified":"2019-07-20T16:01:24","modified_gmt":"2019-07-20T08:01:24","slug":"%e5%8c%97%e8%88%aa%e7%9b%b8%e8%89%b3%e6%95%99%e6%8e%88%e8%af%be%e9%a2%98%e7%bb%84%ef%bc%9a%e7%94%a8%e4%ba%8e%e7%87%83%e6%96%99%e7%94%b5%e6%b1%a0%e9%98%b4%e6%9e%81%e6%b0%a7%e8%bf%98%e5%8e%9f%e5%8f%8d","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=181008","title":{"rendered":"\u5317\u822a\u76f8\u8273\u6559\u6388\u8bfe\u9898\u7ec4\uff1a\u7528\u4e8e\u71c3\u6599\u7535\u6c60\u9634\u6781\u6c27\u8fd8\u539f\u53cd\u5e94\u7684\u5355\u539f\u5b50\u94dc\u50ac\u5316\u5242"},"content":{"rendered":"<p>\u5317\u4eac\u822a\u7a7a\u822a\u5929\u5927\u5b66\u76f8\u8273\u8bfe\u9898\u7ec4\u6210\u529f\u5236\u5907\u4e86\u7528\u4e8e\u71c3\u6599\u7535\u6c60\u9634\u6781\u6c27\u8fd8\u539f\u53cd\u5e94\u7684\u5355\u539f\u5b50\u94dc\u50ac\u5316\u5242\uff0c\u8be5\u7814\u7a76\u6210\u679c\u201cA copper single-atom catalyst towards e\ufb03cient and durable oxygen reduction for fuel cells\u201d\u53d1\u8868\u5728Journal of Materials Chemistry A\u4e0a\uff0c\u5e76\u4e8e\u5f53\u671f\u5c01\u9762\u505a\u7b80\u8981\u4ecb\u7ecd\u3002\u8bba\u6587\u7684\u7b2c\u4e00\u4f5c\u8005\u662f\u5317\u822a\u7a7a\u95f4\u4e0e\u73af\u5883\u5b66\u96622018\u7ea7\u535a\u58eb\u751f\u5d14\u4e3d\u5a77\uff0c\u901a\u8baf\u4f5c\u8005\u4e3a\u5317\u822a\u7a7a\u95f4\u4e0e\u73af\u5883\u5b66\u9662\u76f8\u8273\u6559\u6388\u3001\u5362\u5584\u5bcc\u7814\u7a76\u5458\u3001\u738b\u6d77\u5b81\u526f\u6559\u6388\u3002<\/p>\n<p>\u968f\u7740\u80fd\u6e90\u548c\u73af\u5883\u95ee\u9898\u65e5\u76ca\u7a81\u51fa\uff0c\u71c3\u6599\u7535\u6c60\u4f5c\u4e3a\u4e00\u79cd\u5c06\u5316\u5b66\u80fd\u8f6c\u6362\u4e3a\u7535\u80fd\u7684\u88c5\u7f6e\uff0c\u56e0\u5176\u9ad8\u6548\u3001\u6e05\u6d01\u800c\u5907\u53d7\u5173\u6ce8\u3002\u7136\u800c\uff0c\u9634\u6781\u6c27\u8fd8\u539f\u53cd\u5e94\uff08ORR\uff09\u52a8\u529b\u5b66\u76f8\u5bf9\u8f83\u6162\uff0c\u4e25\u91cd\u4f9d\u8d56\u8d35\u91d1\u5c5ePt\u50ac\u5316\u5242\uff0c\u6210\u4e3a\u5236\u7ea6\u71c3\u6599\u7535\u6c60\u5927\u89c4\u6a21\u5e94\u7528\u7684\u4e00\u4e2a\u91cd\u8981\u56e0\u7d20\u3002\u56e0\u6b64\uff0c\u53d1\u5c55ORR\u4f4e\u94c2\/\u975e\u94c2\u50ac\u5316\u5242\u5bf9\u63a8\u8fdb\u71c3\u6599\u7535\u6c60\u5927\u89c4\u6a21\u5e94\u7528\u5177\u6709\u91cd\u8981\u610f\u4e49\u3002\u8fc7\u6e21\u91d1\u5c5e\u5355\u539f\u5b50\u50ac\u5316\u5242\uff08SAC\uff09\u5728\u5355\u7535\u6781\u8868\u5f81\u4e2d\u5c55\u73b0\u51fa\u4e86\u4f18\u5f02\u7684ORR\u6027\u80fd\uff0c\u8fd1\u5e74\u6765\u5f15\u8d77\u4e86\u6781\u5927\u7684\u5173\u6ce8\u3002\u5728\u4ee5\u5f80\u7684\u7814\u7a76\u62a5\u9053\u4e2d\uff0c\u8fc7\u6e21\u91d1\u5c5e\u591a\u4e3aFe\u3001Co\u3001Ni\u7b49\u3002\u91d1\u5c5eCu\u662f\u4ece\u591a\u79cd\u751f\u547d\u5f62\u5f0f\u4e2dORR\u7684\u4e2d\u5fc3\u539f\u5b50\uff0c\u7136\u800c\uff0c\u4ec5\u6709\u5c11\u6570\u57fa\u4e8eCu SAC\u7684ORR\u50ac\u5316\u5242\u7684\u7814\u7a76\u62a5\u9053\u3002\u6b64\u5916\uff0c\u5f88\u5c11\u6709\u5173\u4e8eCu SAC\u5728\u71c3\u6599\u7535\u6c60\u4e2d\u7684\u5e94\u7528\u62a5\u9053\u3002<\/p>\n<p>\u76f8\u8273\u8bfe\u9898\u7ec4\u4ee5\u915e\u83c1\u94dc\u4e3a\u524d\u9a71\u4f53\uff0c\u91c7\u7528\u7b80\u5355\u70ed\u89e3\u6cd5\u5236\u5907\u4e86\u5355\u539f\u5b50\u94dc\u50ac\u5316\u5242\u3002\u8be5\u50ac\u5316\u5242\u5728\u78b1\u6027\u4ecb\u8d28\u4e2d\u8868\u73b0\u51fa\u826f\u597d\u7684ORR\u6027\u80fd\uff0c\u5176\u534a\u6ce2\u7535\u4f4d\u4e3a0.81 V (vs. RHE)\uff0c\u6bd4\u5546\u4e1a\u5316Pt\/C\u76f8\u5dee30 mV\u3002\u540c\u65f6\u663e\u793a\u51fa\u4f18\u5f02\u7684\u8010\u4e45\u6027\uff0c\u5728\u78b1\u6027\u4ecb\u8d28\u4e2d5000\u6b21\u5faa\u73af\u540e\uff0c\u534a\u6ce2\u7535\u4f4d\u4ec5\u67099 mV\u7684\u8d1f\u79fb\u3002\u57fa\u4e8e\u8be5\u50ac\u5316\u5242\u7684\u9634\u79bb\u5b50\u4ea4\u6362\u819c\u71c3\u6599\u7535\u6c60\u572870\u2103\u4e0b\u7684\u5cf0\u503c\u529f\u7387\u5bc6\u5ea6\u53ef\u8fbe196 mW cm<sup>-2<\/sup>\u3002\u5bc6\u5ea6\u6cdb\u51fd\u7406\u8bba\u8ba1\u7b97\u8868\u660e\u4eceHOO*\u5230O*\u7684\u8fc7\u7a0b\u662f\u5f71\u54cd\u5176ORR\u6027\u80fd\u7684\u5173\u952e\u6b65\u9aa4\u3002Cu SAC\u6709\u671b\u6210\u4e3a\u4e00\u79cd\u7528\u4e8e\u71c3\u6599\u7535\u6c60\u7684\u975e\u8d35\u91d1\u5c5eORR\u50ac\u5316\u5242\u3002<\/p>\n<p>\u5c01\u9762\uff1a<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-181009 aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2019\/07\/\u5c01\u9762.png\" alt=\"\" width=\"519\" height=\"680\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2019\/07\/\u5c01\u9762.png 519w, \/\/m.iemloyee.com\/wp-content\/uploads\/2019\/07\/\u5c01\u9762-229x300.png 229w\" sizes=\"(max-width: 519px) 100vw, 519px\" \/><\/p>\n<p>\u56fe1 Cu SAC\u7684\u900f\u5c04\u7535\u955c\u7167\u7247<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-181010 aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2019\/07\/\u56fe\u72471-23.png\" alt=\"\" width=\"680\" height=\"266\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2019\/07\/\u56fe\u72471-23.png 680w, \/\/m.iemloyee.com\/wp-content\/uploads\/2019\/07\/\u56fe\u72471-23-300x117.png 300w\" sizes=\"(max-width: 680px) 100vw, 680px\" \/><\/p>\n<p>\u56fe2\u00a0Cu SAC\u7684\u8c31\u5b66\u8868\u5f81<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-181011 aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2019\/07\/\u56fe\u72472-22.png\" alt=\"\" width=\"653\" height=\"680\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2019\/07\/\u56fe\u72472-22.png 653w, \/\/m.iemloyee.com\/wp-content\/uploads\/2019\/07\/\u56fe\u72472-22-288x300.png 288w\" sizes=\"(max-width: 653px) 100vw, 653px\" \/><\/p>\n<p>\u56fe3\u00a0Cu SAC\u7684ORR\u6027\u80fd\u8868\u5f81<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-181012 aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2019\/07\/\u56fe\u72473-23.png\" alt=\"\" width=\"680\" height=\"473\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2019\/07\/\u56fe\u72473-23.png 680w, \/\/m.iemloyee.com\/wp-content\/uploads\/2019\/07\/\u56fe\u72473-23-300x209.png 300w\" sizes=\"(max-width: 680px) 100vw, 680px\" \/><\/p>\n<p>\u56fe4\u00a0Cu SAC\u7684ORR\u6027\u80fd\u8868\u5f81<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-181013 aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2019\/07\/\u56fe\u72474-19.png\" alt=\"\" width=\"680\" height=\"280\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2019\/07\/\u56fe\u72474-19.png 680w, \/\/m.iemloyee.com\/wp-content\/uploads\/2019\/07\/\u56fe\u72474-19-300x124.png 300w\" sizes=\"(max-width: 680px) 100vw, 680px\" \/><\/p>\n<p>\u56fe5\u00a0Cu SAC\u7684ORR\u7a33\u5b9a\u6027<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-181014 aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2019\/07\/\u56fe\u72475-17.png\" alt=\"\" width=\"680\" height=\"274\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2019\/07\/\u56fe\u72475-17.png 680w, \/\/m.iemloyee.com\/wp-content\/uploads\/2019\/07\/\u56fe\u72475-17-300x121.png 300w\" sizes=\"(max-width: 680px) 100vw, 680px\" \/><\/p>\n<p>\u56fe6\u00a0Cu SAC\u7684ORR\u8010\u4e45\u6027<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-181015 aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2019\/07\/\u56fe\u72476-15.png\" alt=\"\" width=\"636\" height=\"444\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2019\/07\/\u56fe\u72476-15.png 636w, \/\/m.iemloyee.com\/wp-content\/uploads\/2019\/07\/\u56fe\u72476-15-300x209.png 300w\" sizes=\"(max-width: 636px) 100vw, 636px\" \/><\/p>\n<p>\u56fe7\u00a0\u57fa\u4e8eCu SAC\u7684\u9634\u79bb\u5b50\u4ea4\u6362\u819c\u71c3\u6599\u7535\u6c60\u6027\u80fd<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-181016 aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2019\/07\/\u56fe\u72477-14.png\" alt=\"\" width=\"587\" height=\"414\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2019\/07\/\u56fe\u72477-14.png 587w, \/\/m.iemloyee.com\/wp-content\/uploads\/2019\/07\/\u56fe\u72477-14-300x212.png 300w\" sizes=\"(max-width: 587px) 100vw, 587px\" \/><\/p>\n<p>\u56fe8\u00a0\u901a\u8fc7\u5bc6\u5ea6\u6cdb\u51fd\u8ba1\u7b97\u5f97\u5230\u7684Cu SAC\u7684ORR\u53cd\u5e94\u8def\u5f84<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-181017 aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2019\/07\/\u56fe\u72478-14.png\" alt=\"\" width=\"680\" height=\"450\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2019\/07\/\u56fe\u72478-14.png 680w, \/\/m.iemloyee.com\/wp-content\/uploads\/2019\/07\/\u56fe\u72478-14-300x199.png 300w\" sizes=\"(max-width: 680px) 100vw, 680px\" \/><\/p>\n<p>\u672c\u5de5\u4f5c\u83b7\u56fd\u5bb6\u91cd\u70b9\u7814\u53d1\u8ba1\u5212\u548c\u56fd\u5bb6\u81ea\u7136\u79d1\u5b66\u57fa\u91d1\u7b49\u9879\u76ee\u7684\u652f\u6301\u3002<\/p>\n<p><strong>\u8bba\u6587\u94fe\u63a5\u00a0<\/strong> https:\/\/pubs.rsc.org\/en\/content\/articlelanding\/2019\/TA\/C9TA03518D<\/p>\n<p>\u672c\u6587\u7531<strong>\u5317\u4eac\u822a\u7a7a\u822a\u5929\u5927\u5b66<b>\u76f8\u8273\u6559\u6388\u8bfe\u9898\u7ec4<\/b><\/strong>\u4f9b\u7a3f\u3002<\/p>\n<p>\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1: tougao@cailiaoren.com.<\/p>\n<p>\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1acailiaorenVIP.<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u5317\u4eac\u822a\u7a7a\u822a\u5929\u5927\u5b66\u76f8\u8273\u8bfe\u9898\u7ec4\u6210\u529f\u5236\u5907\u4e86\u7528\u4e8e\u71c3\u6599\u7535\u6c60\u9634\u6781\u6c27\u8fd8\u539f\u53cd\u5e94\u7684\u5355\u539f\u5b50\u94dc\u50ac\u5316\u5242\uff0c\u8be5\u7814\u7a76\u6210\u679c\u201cA copper single-atom catalyst towa&#8230;<\/p>\n","protected":false},"author":10213,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[],"class_list":["post-181008","post","type-post","status-publish","format-standard","hentry","category-jiedu"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/181008"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/10213"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=181008"}],"version-history":[{"count":2,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/181008\/revisions"}],"predecessor-version":[{"id":181020,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/181008\/revisions\/181020"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=181008"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=181008"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=181008"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}