{"id":178921,"date":"2019-06-29T06:30:26","date_gmt":"2019-06-28T22:30:26","guid":{"rendered":"\/\/m.iemloyee.com\/?p=178921"},"modified":"2019-06-29T09:51:24","modified_gmt":"2019-06-29T01:51:24","slug":"%e3%80%90%e5%b7%b2%e6%a0%a1%e3%80%91%e5%a4%a7%e8%bf%9e%e5%8c%96%e7%89%a9%e6%89%80%e7%8e%8b%e5%b3%b0nature-energy%ef%bc%9a%e5%8f%af%e8%a7%81%e5%85%89%e9%a9%b1%e5%8a%a8%e7%9a%84%e6%9c%a8%e8%b4%a8","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=178921","title":{"rendered":"\u5927\u8fde\u5316\u7269\u6240\u738b\u5cf0Nature Energy\uff1a\u53ef\u89c1\u5149\u9a71\u52a8\u7684\u6728\u8d28\u7ea4\u7ef4\u7d20\u57fa\u7532\u57fa\u544b\u5583\u540c\u65f6\u4ea7\u6c22\u548c\u67f4\u6cb9\u524d\u4f53"},"content":{"rendered":"

\u3010\u524d\u8a00\u3011<\/strong><\/p>\n

\u5149\u50ac\u5316\u751f\u7269\u8d28\u5236\u6c22\u662f\u6709\u6f5c\u529b\u7684\u66ff\u4ee3\u6c34\u4ea7\u6c22\u7684\u65b9\u5f0f\uff0c\u8fd9\u662f\u56e0\u4e3a\u751f\u7269\u8d28\u6c27\u5316\u8fd9\u4e00\u534a\u53cd\u5e94\u66f4\u5bb9\u6613\u53d1\u751f\u4e14\u8be5\u8fc7\u7a0b\u6709\u671b\u540c\u65f6\u5236\u5907\u592a\u9633\u71c3\u6599\u548c\u9ad8\u9644\u52a0\u503c\u5316\u5b66\u54c1\u3002\u672c\u6587\u62a5\u9053\u4e86\u5229\u7528Ru-ZnIn2<\/sub>S4<\/sub>\u50ac\u5316\u5242\u53ef\u89c1\u5149\u50ac\u5316\u65e0\u6c27\u8131\u6c22C\u2212C\u5076\u8054\u6765\u540c\u65f6\u5236\u5907\u6c22\u6c14\u548c\u67f4\u6cb9\u524d\u4f53\u3002\u5229\u7528\u8be5\u5316\u5b66\u539f\u7406\uff0c\u4ece\u6728\u8d28\u7ea4\u7ef4\u7d20\u57fa\u7532\u57fa\u544b\u5583\u5316\u5408\u7269\u53ef\u4ee5\u5f97\u5230\u6700\u9ad81.04 g gcatalyst<\/sub>-1<\/sup> h-1<\/sup>\u7684\u67f4\u6cb9\u524d\u4f53\u5e76\u4ea7\u751f6.0 mmol gcatalyst<\/sub>-1<\/sup> h-1<\/sup>\u7684H2<\/sub>. \u5176\u4e2d\u67f4\u6cb9\u524d\u4f53\u7684\u9009\u62e9\u6027\u5927\u4e8e96%\uff0c\u5e76\u6709~41%\u7684\u652f\u94fe\u70f7\u70c3\u524d\u4f53\u3002\u968f\u540e\u7684\u52a0\u6c22\u8131\u6c27\u53cd\u5e94\u5f97\u5230\u4e86\u540c\u65f6\u542b\u6709\u76f4\u94fe\u548c\u652f\u94fe\u7684\u67f4\u6cb9\u524d\u4f53\u3002\u6211\u4eec\u8ba4\u4e3a\u53d6\u4ee3ZnIn2<\/sub>S4<\/sub>\u6676\u683cIn3+<\/sup>\u7684\u63ba\u6742Ru\u63d0\u9ad8\u4e86\u7535\u8377\u5206\u79bb\u6548\u7387\u8fdb\u800c\u4fc3\u8fdb\u4e86C\u2212H\u952e\u6d3b\u5316\u800c\u540c\u65f6\u4ea7\u751f\u4e86H2<\/sub>\u548c\u67f4\u6cb9\u524d\u4f53\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u6700\u8fd1\uff0c\u5927\u8fde\u5316\u7269\u6240\u738b\u5cf0\u7814\u7a76\u5458<\/strong>\u9886\u5bfc\u7684\u79d1\u7814\u56e2\u961f\u5728\u56fd\u9645\u9876\u7ea7\u671f\u520aNature Energy<\/strong> \u4e0a\u53d1\u8868\u4e86\u9898\u4e3aVisible-light-driven coproduction of diesel precursors and hydrogen from lignocellulose-derived methylfurans<\/strong>\u7684\u6587\u7ae0\u3002\u5728\u8fd9\u9879\u5de5\u4f5c\u4e2d\uff0c\u7814\u7a76\u56e2\u961f\u5b9e\u73b0\u4e86Ru-ZnIn2<\/sub>S4<\/sub>\u5149\u50ac\u5316\u52422,5-DMF\u548c2- MF\u540c\u65f6\u751f\u4ea7H2<\/sub>\u548c\u67f4\u6cb9\u524d\u4f53(DFPs)\u3002\u7ed3\u679c\u8868\u660e\uff0c2,5-DMF\u548c2-MF(\u5355\u72ec\u53cd\u5e94\u6216\u6df7\u5408\u53cd\u5e94)\u7ecf\u5386\u8131\u6c22\u5076\u8054\u5f97\u5230\u7684\u6db2\u4f53\u6df7\u5408\u7269\uff08DFPs\uff09\u6240\u542b\u78b3\u6570\u8303\u56f4\u4e3a\u67f4\u6cb9\u8303\u7574\u3002\u52a0\u6c22\u8131\u6c27\u8be5\u6db2\u4f53\u6df7\u5408\u7269\uff0c\u5f97\u5230\u4e86\u540c\u65f6\u542b\u6709\u76f4\u94fe\u548c\u652f\u94fe\u70f7\u70c3\u7684\u590d\u6742\u6df7\u5408\u7269\u3002\u6211\u4eec\u8ba4\u4e3aRu\u63ba\u6742\u53ef\u4ee5ZnIn2<\/sub>S4<\/sub>\u50ac\u5316\u5242\u7684\u7535\u8377\u5206\u79bb\u6548\u7387\uff0c\u4ece\u800c\u52a0\u901fC-H\u952e\u6d3b\u5316\u800c\u4fc3\u8fdb\u5149\u50ac\u5316\u8131\u6c22\u5076\u8054\u548c\u4ea7\u6c22\u53cd\u5e94\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n

\u56fe1.\u6728\u8d28\u7ea4\u7ef4\u7d20\u5e9f\u7269\u751f\u4ea7\u67f4\u6cb9\u71c3\u6599\u7684\u6982\u5ff5\u6d41\u7a0b\u56fe<\/strong><\/p>\n

\"\"<\/p>\n

\u8be5\u56fe\u5c55\u793a\u4e86\u6784\u60f3\u7684\u7b2c\u4e8c\u4ee3\u751f\u7269\u8d28\u751f\u4ea7\u67f4\u6cb9\u7684\u8fc7\u7a0b\u3002\u7532\u57fa\u544b\u5583\u539f\u6599\u53ef\u4ee5\u901a\u8fc7\u5316\u5b66\u5904\u7406\u6728\u8d28\u7ea4\u7ef4\u7d20\u5e9f\u5f03\u7269\u5f97\u5230\uff0c\u5be1\u805a\u540e\u5f62\u6210C10<\/sub>-C20<\/sub>\u8303\u56f4\u5185\u7684\u542b\u6c27\u5316\u5408\u7269\u3002\u8fd9\u4e9bDFPs\u901a\u8fc7\u84b8\u998f\u5f88\u5bb9\u6613\u5730\u4ece\u672a\u53cd\u5e94\u7684\u7532\u57fa\u544b\u5583\u4e2d\u5206\u79bb\u51fa\u6765\uff0c\u6700\u7ec8\u7531HDO\u8f6c\u5316\u4e3a\u78b3\u6c22\u5316\u5408\u7269\u3002\u8fd9\u4e00\u8fc7\u7a0b\u7684\u5173\u952e\u6b65\u9aa4\u662f\u7532\u57fa\u544b\u5583\u7684\u53ef\u63a7\u5be1\u805a\uff0c\u5229\u7528\u672c\u6587\u63d0\u51fa\u7684Ru-ZnIn2<\/sub>S4<\/sub>\u50ac\u5316\u5242\u53ef\u4ee5\u5f88\u5bb9\u6613\u5730\u5728\u53ef\u89c1\u5149\u7167\u5c04\u4e0b\u9ad8\u9009\u62e9\u6027\u7684\u4ea7\u751f\u4e8c\u805a\u4f53\u3001\u4e09\u805a\u4f53\u548c\u56db\u805a\u4f53\uff0c\u5e76\u540c\u65f6\u5f97\u5230H2<\/sub>\uff0c\u800cH2<\/sub>\u53ef\u4ee5\u90e8\u5206\u6ee1\u8db3HDO\u6b65\u9aa4\u7684\u9700\u6c42\u3002<\/p>\n

\u56fe2.Ru- Znln2<\/sub>S4<\/sub>\u5149\u50ac\u5316\u5242\u7684\u8868\u5f81<\/strong><\/p>\n

\"\"<\/p>\n

a, Ru-ZnIn2<\/sub>S4<\/sub>\u548c\u672a\u63ba\u6742ZnIn2<\/sub>S4<\/sub>\u7684XRD\u8c31\u56fe\uff0c\u4e0e\u516d\u65b9P63<\/sub>mc<\/em>\u7a7a\u95f4\u7fa4(JCPDS no. 72 – 0773)\u5bf9\u5e94\u3002\u865a\u7ebf\u5f3a\u8c03\u4e86\u7531Ru\u63ba\u6742\u5f15\u8d77\u7684\u56fe\u6848\u7684\u53d8\u5316\u3002<\/p>\n

b, \u4ee3\u8868\u6027\u7684Ru-ZnIn2<\/sub>S4<\/sub>\u9ad8\u5206\u8fa8TEM\u56fe\u50cf\uff0c\u7bad\u5934\u8868\u793a\u7684\u662f(102)\u5e73\u9762\u95f4\u8ddd\u79bb\u3002\u63d2\u56fe\u4e3a\u76f8\u5e94\u7684FFT\u3002<\/p>\n

c, \u5806\u53e0\u7684Ru-ZnIn2<\/sub>S4<\/sub>\u3001Ru\u91d1\u5c5e\u548cRuS2<\/sub>\u7684Ru K\u8fb9XANES\u8c31\u56fe\u3002\u00b5X\u8868\u793aX\u5c04\u7ebf\u7684\u5438\u6536\u3002<\/p>\n

d, \u63d0\u53d6\u7684Ru-ZnIn2<\/sub>S4<\/sub>\u3001Ru\u91d1\u5c5e\u548cRuS2<\/sub>\u7684k<\/em>3<\/sup>\u03c7<\/em>(k<\/em>) EXAFS\u4fe1\u53f7\u3002<\/p>\n

e, Ru-ZnIn2<\/sub>S4<\/sub>\u7684FTk3<\/sup><\/em>–\u03c7(k)<\/em>\u7684Ru K\u8fb9EXAFS\u4fe1\u53f7\u3002<\/p>\n

f\u3001Ru-ZnIn2<\/sub>S4<\/sub>\u7ed3\u6784\u793a\u610f\u56fe\u53caRu- S\u914d\u4f4d\u7684\u62df\u5408\u7ed3\u679c\u3002<\/p>\n

\u56fe3.\u5728\u53ef\u89c1\u5149\u9a71\u52a8\u4e0b\uff0c2,5-DMF\/2-MF\u7ecf\u5149\u50ac\u5316\u8131\u6c22\u5076\u8054\u53cd\u5e94\u8f6c\u5316\u4e3a\u67f4\u6cb9<\/strong><\/p>\n

\"\"<\/p>\n

 <\/p>\n

a, 2,5-DMF \/2-MF\u8f6c\u5316\u4e3a\u67f4\u6cb9\u7684\u8fc7\u7a0b\u4e2d\u6240\u6d89\u53ca\u7684\u4ee3\u8868\u6027\u5316\u5b66\u53cd\u5e94<\/p>\n

b-d, 2,5-DMF\u4f5c\u4e3a\u5e95\u7269\u5149\u50ac\u5316\u8131\u6c22\u8026\u5408\u7684\u7ed3\u679c: (b)\u6807\u51c6\u6761\u4ef6\u5b9e\u9a8c\uff0c(c)\u50ac\u5316\u5242\u5bff\u547d\u8bc4\u4f30\uff0c(d)\u542b\u6c27DFPs\u548c\u652f\u94feDFPs\u7684\u9009\u62e9\u6027\u3002<\/p>\n

e, \u6807\u51c6\u5b9e\u9a8c\u6761\u4ef6\u4e0b2-MF\u5149\u50ac\u5316\u8131\u6c22\u5076\u8054\u53cd\u5e94\u7ed3\u679c\u3002<\/p>\n

f, \u6807\u51c6\u5b9e\u9a8c\u6761\u4ef6\u4e0b\uff0c\u5149\u50ac\u53162,5-DMF\u548c2-MF(\u4f53\u79ef\u6bd4\u4e3a1:3)\u7684\u6df7\u5408\u7269\u8131\u6c22\u5076\u8054\u53cd\u5e94\u7ed3\u679c\u3002g, \u4ece\u653e\u5927\u7684\u5149\u50ac\u5316\u8131\u6c22\u5076\u8054\u53cd\u5e94\u5236\u5907\u7684DFPs\u52a0\u6c22\u8131\u6c27\u540e\u5f97\u5230\u7684\u4ea7\u7269\u7684\u6536\u7387\u3002\u603b\u6db2\u4f53\u4ea7\u7269\u7b49\u4e8e\u4ea7\u751f\u7684\u4e8c\u805a\u4f53\u3001\u4e09\u805a\u4f53\u548c\u56db\u805a\u4f53\u4e4b\u548c\u3002<\/p>\n

\u56fe4.\u5149\u50ac\u5316\u65e0\u53d7\u4f53\u544b\u5583\u7532\u57fa\uff08\u82c4\u57fa\uff09C-H\u952e\u6d3b\u5316\u53caC-C\u952e\u5076\u8054\u53cd\u5e94\u673a\u7406\u7814\u7a76<\/strong><\/p>\n

\"\"<\/p>\n

a, TEMPO (0.2 mmol)\u5b58\u5728\u4e0b\uff0c\u7532\u82ef\u5149\u50ac\u5316\u8131\u6c22\u5076\u8054\u53cd\u5e94\u6df7\u5408\u7269\u7684\u5178\u578b\u6c14\u76f8\u8272\u8c31\u56fe\u3002<\/p>\n

b, \u5bf9\u4e8c\u7532\u82ef\u4e0e\u5bf9\u7532\u57fa\u8334\u9999\u919a\u7684\u4ea4\u53c9\u5076\u8054\u53cd\u5e94\u7ed3\u679c\u3002<\/p>\n

c, \u63d0\u51fa\u76842,5- DMF\u5149\u50ac\u5316\u8131\u6c22\u5076\u8054\u53cd\u5e94\u673a\u7406<\/p>\n

\u56fe5. Ru-ZnIn2<\/sub>S4<\/sub>\u5149\u50ac\u5316\u5242\u7684\u539f\u4f4d\u548c\u5149\u7269\u7406\u6027\u8d28<\/strong><\/p>\n

\"\"<\/p>\n

a\u3001b Ru-ZnIn2<\/sub>S4<\/sub> \u7684\u539f\u4f4dXANES\u5149\u8c31\u3002\u62df\u5408\u7684Ru-ZnIn2<\/sub>S4<\/sub>\u7684Ru K\u8fb9k3<\/sup><\/em>-weighted \u03c7(k) XANES\u5149\u8c31(a)\u548cRu K\u8fb9EXAFS\u4fe1\u53f7(b)<\/p>\n

c, ZnIn2<\/sub>S4<\/sub>\u548cRu-ZnIn2<\/sub>S4<\/sub>\u7684CPD\u3002<\/p>\n

d\uff0c ZnIn2<\/sub>S4<\/sub>\u548cRu-ZnIn2<\/sub>S4<\/sub>\u5728774.3 nm\u5904\u7684\u77ac\u6001\u5438\u6536\u52a8\u529b\u5b66\u3002\u539f\u4f4dXANES\/EXAFS\u548cCPD\u5b9e\u9a8c\u4e2d\uff0c\u6fc0\u53d1\u6ce2\u957f\u4e3a450 nm; \u77ac\u6001\u5438\u6536\u52a8\u529b\u5b66\u5b9e\u9a8c\u4e2d\uff0c\u6fc0\u53d1\u6ce2\u957f\u4e3a400 nm\u3002\u77ac\u6001\u5438\u6536\u52a8\u529b\u5b66\u4e2d\u7684\u8bef\u5dee\u4e3a\u5bff\u547d\u5747\u503c\u7684\u6807\u51c6\u5dee\uff0c\u62ec\u53f7\u5185\u7684\u503c\u4e3a\u76f8\u5e94\u5bff\u547d\u7684\u6bd4\u4f8b\u3002<\/p>\n

\u3010\u7ed3\u8bba\u3011<\/strong><\/p>\n

\u672c\u6587\u62a5\u9053\u4e86Ru\u63ba\u6742ZnIn2<\/sub>S4<\/sub>\u5149\u50ac\u5316\u6728\u8d28\u7ea4\u7ef4\u7d20\u57fa2,5-DMF\u548c2-MF\u8131\u6c22C-C\u5076\u8054\u8f6c\u5316\u5230H2<\/sub>\u548c\u67f4\u6cb9\u524d\u9a71\u4f53\u7684\u8fc7\u7a0b\uff0c\u5e76\u5f97\u5230\u4e86\u6700\u9ad815.2%\u7684\u91cf\u5b50\u4ea7\u7387\u3002\u5149\u751f\u7a7a\u7a74\u9996\u5148\u6c27\u5316\u4e862,5-DMF\/2-MF\u7684\u544b\u5583\u7532\u57faC-H\u952e\uff0c\u968f\u540e\u7684C-C\u952e\u5076\u8054\u5f97\u5230\u4e86\u76f8\u5e94\u7684\u67f4\u6cb9\u524d\u9a71\u4f53\u3002\u540c\u65f6\uff0c\u4f34\u968f\u7a7a\u7a74\u751f\u6210\u7684\u5149\u751f\u7535\u5b50\u5c06\u8d28\u5b50\u8fd8\u539f\u6210H2<\/sub>\u3002\u67f4\u6cb9\u524d\u9a71\u4f53\u52a0\u6c22\u8131\u6c27\u540e\uff0c\u5f97\u5230\u4e86~C10<\/sub>-C18<\/sub>\u70f7\u70c3\u3002\u8be5\u70f7\u70c3\u5305\u542b\u76f4\u94fe\u548c\u652f\u94fe\u7ec4\u5206\uff0c\u4f7f\u5f97\u76f8\u5e94\u7684\u67f4\u6cb9\u548c\u6c7d\u6cb9\u6765\u6e90\u67f4\u6cb9\u4e2d\u7684\u70f7\u70c3\u7ec4\u5206\u76f8\u8fd1\u3002\u66f4\u91cd\u8981\u7684\u662f\uff0c\u6765\u6e90\u4e8e\u620a\u805a\u7cd6\u548c\u5df1\u805a\u7cd6\u7684\u539f\u6599\u90fd\u53ef\u4ee5\u88abRu-ZnIn2<\/sub>S4<\/sub>\u5149\u50ac\u5316\u8f6c\u5316\u6210H2<\/sub>\u548c\u67f4\u6cb9\u524d\u9a71\u4f53\u3002ZnIn2<\/sub>S4<\/sub>\u6676\u683c\u4e2d\u7684Ru\u79bb\u5b50\u53ef\u4ee5\u63d0\u9ad8\u5149\u7684\u5438\u6536\u548c\u8f7d\u6d41\u5b50\u5206\u79bb\u6548\u7387\uff0c\u8fdb\u800c\u4fc3\u8fdbC-H\u952e\u7684\u6d3b\u5316\u800c\u540c\u65f6\u5f97\u5230H2<\/sub>\u548c\u67f4\u6cb9\u524d\u9a71\u4f53\u3002\u4ee5\u540e\u7684\u5de5\u4f5c\u5c06\u4f1a\u6ce8\u91cd\u5f00\u53d1\u66f4\u9ad8\u6548\u7684\u50ac\u5316\u5242\u53bb\u8fdb\u4e00\u6b65\u63d0\u9ad8\u8131\u6c22\u5076\u8054\u53cd\u5e94\u7684\u91cf\u5b50\u4ea7\u7387\u4ee5\u5f97\u5230\u548c\u70ed\u50ac\u5316\u548c\u5316\u5b66\u5408\u6210\u53ef\u6bd4\u8f83\u7684\u7ed3\u679c\u3002<\/p>\n

\u3010\u56e2\u961f\u4ecb\u7ecd\u3011<\/strong><\/p>\n

\u738b\u5cf0<\/strong>\uff0c\u4e2d\u56fd\u79d1\u5b66\u9662\u5927\u8fde\u5316\u5b66\u7269\u7406\u7814\u7a76\u6240\u7814\u7a76\u5458\uff0c\u8bfe\u9898\u7ec4\u957f\u3001\u751f\u7269\u80fd\u6e90\u7814\u7a76\u90e8\u90e8\u957f\u3001\u6240\u957f\u52a9\u7406\u3002\u7acb\u8db3\u50ac\u5316\u53cd\u5e94\u7814\u7a76\uff0c\u4ee5\u4f4e\u78b3\u70ef\u70c3\u548c\u9187\u7c7b\u5c0f\u5206\u5b50\u3001\u751f\u7269\u8d28\u548c\u70c3\u7c7b\u5316\u5408\u7269\u7b49\u4e3a\u539f\u6599\uff0c\u5236\u5907\u9ad8\u503c\u542b\u6c27\/\u6c2e\u5316\u5b66\u54c1\uff0c\u7740\u91cd\u7814\u7a76\u9178\u78b1\u50ac\u5316\u548c\u6c27\u5316\u8fd8\u539f\u50ac\u5316\u53cd\u5e94\u3002\u8fd1\u4e94\u5e74\uff0c\u4ee5\u901a\u8baf\u4f5c\u8005\u8eab\u4efd\u5728Nature Energy (1)\u3001Nature Commun. (1)\u3001JACS (3)\u3001Angew. Chem. Int. Ed. (4)\u3001ACS Catal. (13)\u7b49\u6742\u5fd7\u4e0a\u53d1\u8868\u8bba\u658746\u7bc7\u3002\u83b7\u4e2d\u56fd\u53d1\u660e\u4e13\u5229\u6388\u674347\u4ef6\u3002\u56fd\u5bb6\u81ea\u7136\u79d1\u5b66\u57fa\u91d1\u4f18\u79c0\u9752\u5e74\u79d1\u5b66\u57fa\u91d1\u83b7\u5f97\u8005\uff082015\uff09\u3001\u6559\u80b2\u90e8\u957f\u6c5f\u5b66\u8005\u5956\u52b1\u8ba1\u5212\u9752\u5e74\u5b66\u8005\uff082017\uff09\u3001\u82f1\u56fd\u7687\u5bb6\u5b66\u4f1a\u725b\u987f\u9ad8\u7ea7\u5b66\u8005\uff082019\uff09\u7b49\u3002\u8bfe\u9898\u7ec4\u4e3b\u9875\uff1ahttp:\/\/www.fwang.dicp.ac.cn\/<\/a>\u3002<\/p>\n

\u8be5\u9886\u57df\u8fd15\u5e74\u76f8\u5173\u5de5\u4f5c\uff08\u751f\u7269\u8d28\u8f6c\u5316\uff09\uff1a<\/p>\n

1. Nengchao Luo, Tiziano Montini, Jian Zhang, Paolo Fornasiero, Emiliano Fonda, Tingting Hou, Wei Nie, Jianmin Lu, Junxue Liu, Marc Heggen, Long Lin, Changtong Ma, Min Wang, Fengtao Fan, Shengye Jin, Feng Wang*. Visible-light-driven coproduction of diesel precursors and hydrogen from lignocellulose-derived methylfurans. Nat. Energy, 2019, doi:10.1038\/s41560-019-0403-5.<\/p>\n

2. Yehong Wang, Mi Peng, Jian Zhang, Zhixin Zhang, Jinghua An, Shuyan Du, Hongyu An, Fengtao Fan, Xi Liu, Peng Zhai, Ding Ma*, Feng Wang*. Selective production of phase-separable product from a mixture of biomass-derived aqueous oxygenates. Nat. Commun., 2018, 9, 5183.<\/p>\n

3. Yancheng Hu\u2021, Zhitong Zhao\u2021, Yanting Liu, Guangyi Li, Aiqin Wang, Yu Cong, Tao Zhang, Feng Wang*, Ning Li*. Synthesis of 1,4-cyclohexanedimethanol, 1,4-cyclohexanedicarboxylic acid and 1,2-cyclohexanedicarboxylates from formaldehyde, crotonaldehyde and acrylate. Angew. Chem. Int. Ed., 2018, 57(23), 6901-6905.<\/p>\n

4. Hongji Li, Elena Subbotina, Anon Bunrit, Feng Wang*, Joseph S. M. Samec*. Functionalized spirolactones by photoinduced dearomatization of biaryl compounds. Chem. Sci., 2019, 10, 3681-3686.<\/p>\n

5. Min Wang, Meijiang Liu, Hongji Li, Zhitong Zhao, Xiaochen Zhang, Feng Wang*. Dealkylation of lignin to phenol via oxidation\u2013hydrogenation strategy. ACS Catal., 2018, 8(8), 6837-6843.<\/p>\n

6. Huifang Liu, Hongji Li, Jianmin Lu, Shu Zeng, Min Wang, Nengchao Luo, Shutao Xu, Feng Wang*. Photocatalytic cleavage of C\u2013C bond in lignin models under visible light on mesoporous graphitic carbon nitride through \u03c0-\u03c0 stacking interaction. ACS Catal., 2018, 8(6), 4761-4771.<\/p>\n

7. Min Wang, Jiping Ma, Huifang Liu, Nengchao Luo, Zhitong Zhao, Feng Wang*. Sustainable productions of organic acids and their derivatives from biomass via selective oxidative cleavage of C-C bond. ACS Catal., 2018, 8(3), 2129-2165.<\/p>\n

8. Min Wang, Xiaochen Zhang, Hongji Li, Jianmin Lu, Meijiang Liu, Feng Wang*. Carbon modification of nickel catalyst for depolymerization of oxidized lignin to aromatics. ACS Catal., 2018, 8(2), 1614-1620.<\/p>\n

9. Nengchao Luo, Min Wang, Hongji Li, Jian Zhang, Tingting Hou, Haijun Chen, Xiaochen Zhang, Jianmin Lu, Feng Wang*. Visible-light-driven self-hydrogen transfer hydrogenolysis of lignin models and extracts into phenolic products. ACS Catal., 2017, 7(7), 4571-4580.<\/p>\n

10. Hongji Li, Min Wang, Huifang Liu, Nengchao Luo, Jianmin Lu, Chaofeng Zhang, Feng Wang*. NH2OH-mediated lignin conversion to isoxazole and nitrile. ACS Sustainable Chem. Eng., 2018, 6(3), 3748-3753.<\/p>\n

11. Tingting Hou, Nengchao Luo, Hongji Li, Marc Heggen, Jianmin Lu, Yehong Wang, Feng Wang*. Yin and Yang dual characters of CuOx clusters for C\u2013C bond oxidation driven by visible light. ACS Catal., 2017, 7(6), 3850\u20133859.<\/p>\n

12. Chaofeng Zhang, Hongji Li, Jianmin Lu, Xiaochen Zhang, Katherine E MacArthur, Marc Heggen, Feng Wang*. Promoting lignin depolymerization and restraining the condensation via an oxidation-hydrogenation strategy. ACS Catal., 2017, 7(5), 3419\u20133429.<\/p>\n

13. Nengchao Luo, Min Wang, Hongji Li, Jian Zhang, Huifang Liu, Feng Wang*. Photocatalytic oxidation-hydrogenolysis of lignin \u03b2-O-4 models via a dual light wavelength switching strategy. ACS Catal., 2016, 6(11), 7716\u20137721.<\/p>\n

14. Min Wang, Jianmin Lu, Xiaochen Zhang, Lihua Li, Hongji Li, Nengchao Luo, Feng Wang*. Two-step, catalytic C\u2013C bond oxidative cleavage process converts lignin models and extracts to aromatic acids. ACS Catal., 2016, 6(9), 6086\u20136090.<\/p>\n

15. Jianmin Lu, Min Wang, Xiaochen Zhang, Andreas Heyden, Feng Wang*. \u03b2-O-4 bond cleavage mechanism for lignin model compounds over Pd catalysts identified by combination of first-principles calculations and experiments. ACS Catal., 2016, 6(8), 5589\u20135598.<\/p>\n

16. Min Wang, Lihua Li, Jianmin Lu, Hongji Li, Xiaochen Zhang, Huifang Liu, Nengchao Luo, Feng Wang*. Acid promoted C\u2013C bond oxidative cleavage of \u03b2-O-4 and \u03b2-1 lignin models to esters over a copper catalyst. Green Chem., 2017, 19(3), 702-706.<\/p>\n

17. Chaofeng Zhang, Jianmin Lu, Xiaochen Zhang, Katherine E MacArthur, Marc Heggen, Hongji Li, Feng Wang*. Cleavage of lignin \u03b2-O-4 ether bond via dehydroxylation-hydrogenation strategy over a NiMo sulfide catalyst. Green Chem., 2016,18(24), 6545-6555.<\/p>\n

18. Chaofeng Zhang, Feng Wang*. Sell a dummy: Adjacent functional group modification strategy for the catalytic cleavage of lignin \u03b2-O-4 linkage. Chin. J. Catal., 2017. 38(7), 1102-1107.<\/p>\n

\u6587\u732e\u94fe\u63a5:\u00a0<\/strong>Visible-light-driven coproduction of diesel precursors and hydrogen from lignocellulose-derived methylfurans<\/a><\/p>\n

\u672c\u6587\u7531luna\u7f16\u8bd1\u4f9b\u7a3f\u3002<\/p>\n

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