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6\u3001\u7eb3\u7c73M<\/b><\/strong>OF<\/b><\/strong>\u5b9e\u73b0\u836f\u7269\u4f20\u8f93<\/b><\/strong><\/p>\n

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\u56fe8\u00a0\u836f\u7269\u91ca\u653e\u7eb3\u7c73MOF\u8bbe\u8ba1\u8fc7\u7a0b<\/p>\n

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7\u3001M<\/b><\/strong>OF<\/b><\/strong>\u57fa<\/b><\/strong>\u950c\u7a7a\u6c14\u7535\u6c60<\/b><\/strong>\u5927\u663e\u8eab\u624b<\/b><\/strong><\/p>\n

\u8d85\u957f\u5faa\u73af\u5bff\u547d\u7684\u5148\u8fdb\u950c\u7a7a\u6c14\u7535\u6c60(ZABs)\u5229\u7528\u53cc\u529f\u80fd\u7535\u5316\u5b66\u53cd\u5e94\u7684\u80fd\u91cf\uff0c\u5bf9\u6df7\u5408\u52a8\u529b\/\u7535\u52a8\u6c7d\u8f66\u548c\u53ef\u7a7f\u6234\u7535\u5b50\u4ea7\u54c1\u7684\u5546\u4e1a\u5316\u5177\u6709\u91cd\u8981\u7684\u6311\u6218\u3002\u5728\u6b64\uff0c\u97e9\u56fd\u6c49\u9633\u5927\u5b66Jung-Ho Lee\u6559\u6388\u5f00\u653e\u4e86\u4e00\u79cd\u575a\u56fa\u7684\u6c34\u6027\u548c\u67d4\u6027ZABs\uff0c\u91c7\u7528\u65b0\u578b\u7684\u4e09\u7ef4\u53cc\u94fe\u5df1\u4e8c\u82ef\u91d1\u5c5e\u6709\u673a\u9aa8\u67b6(Mn\/Fe-HIB-MOF)\u7684\u53cc\u529f\u80fd\u6c27\u7535\u50ac\u5316\u5242\u548c\u8d85\u79bb\u5b50\u529f\u80fd\u5316\u751f\u7269\u7ea4\u7ef4\u7d20\u7535\u89e3\u8d28(64 mS cm–<\/sup>1<\/sup>)\u3002[<\/sup>7]<\/sup><\/p>\n

\u56fe9 \u4e09\u7ef4M-HIB-MOFs\u7684\u5408\u6210\u7b56\u7565<\/p>\n

\"\"\u00a0<\/p>\n

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\u7528\u5bc6\u5ea6\u6cdb\u51fd\u7406\u8bba\u8bc1\u5b9e\u4e86\u5b83\u4eec\u826f\u597d\u7684\u6c27\u53cd\u5e94\u548c\u8868\u9762\u7535\u5b50\u7ed3\u6784\u3002\u9634\u6781\u663e\u793a\u4e86\u8fc4\u4eca\u4e3a\u6b62\u53ef\u5145\u7535ZABs\u7684\u6700\u9ad8\u5bff\u547d\uff0c\u53731000 h (0.75 voltage gap@10 mA cm–<\/sup>2<\/sup>) \u8d85\u8fc76000\u4e2a\u5faa\u73af\uff0c600 h(\u6548\u7387\u7ea665.24%@25 mA cm–<\/sup>2<\/sup>)\u8d85\u8fc73600\u4e2a\u5faa\u73af\uff0c\u5bf9\u6db2\u4f53\u548c\u5168\u56fa\u6001\u67d4\u6027ZABs\u5177\u6709\u6781\u597d\u7684\u9002\u5e94\u6027\u3002\u8fd9\u4e9b\u6709\u5e0c\u671b\u7684\u7ed3\u679c\u8bf4\u660e\u4e86\u8fd9\u4e9b\u65b0\u578b\u7684\u5df1\u4e8c\u7532\u82efMOFs\u548c\u8d85\u79bb\u5b50\u751f\u7269\u7ea4\u7ef4\u7d20\u819c\u5728\u53ef\u5145\u7535ZABs\u7684\u5546\u4e1a\u5316\u5e94\u7528\u65b9\u9762\u7684\u5de8\u5927\u6f5c\u529b\u3002\u4e3a\u4e0b\u4e00\u4ee3\u5148\u8fdb\u7684\u7eff\u8272\u80fd\u6e90\u5b58\u50a8\u6280\u672f\u94fa\u5e73\u4e86\u9053\u8def<\/p>\n

8\u3001\u6c1f\u5316M<\/b><\/strong>OF<\/b><\/strong>\u51c0\u5316\u5929\u7136\u6c14<\/b><\/strong><\/p>\n

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\u56fe10 \u6c1f\u5316MOFs\u4e0eH2<\/sub>S\/CO2<\/sub>\u9009\u62e9\u6027\u7684\u5173\u7cfb<\/p>\n

\"\"<\/p>\n

\u8fd9\u79cd\u65b9\u6cd5\u4e3a\u7b80\u5316\u590d\u6742\u7684\u9178\u6027\u6c14\u4f53\u53bb\u9664\u65b9\u6848\u63d0\u4f9b\u4e86\u524d\u666f\u3002\u53e6\u5916\u53ef\u4ee5\u901a\u8fc7\u5fae\u8c03\u5176\u56fa\u6709\u6027\u8d28\u6765\u6ee1\u8db3\u7ed9\u5b9a\u7684\u5e94\u7528\u9700\u6c42\uff0c\u4ece\u542b\u7532\u70f7\u4e30\u5bcc\u7684\u5929\u7136\u6c14\u4e2d\u8131\u9664\u786b\u5316\u6c22\u548c\u4e8c\u6c27\u5316\u78b3\u7684\u5de5\u827a\u3002\u5e76\u5bf9\u5176\u8fdb\u884c\u63a2\u7d22\u548c\u6d4b\u8bd5\uff0c\u4ee5\u7528\u4e8eNG\u7684\u5fae\u578b\u5316\u53d8\u538b\u5438\u9644(PSA)\u548c\u53d8\u6e29\u5438\u9644(PTSA)\u7cfb\u7edf\u3002\u4ee5\u8fd9\u79cd\u65b9\u5f0f\u5347\u7ea7\u5929\u7136\u6c14\u53ef\u4ee5\u5e2e\u52a9\u6c99\u7279\u963f\u62c9\u4f2f\u66f4\u5145\u5206\uff0c\u66f4\u6e05\u6d01\u5730\u5229\u7528\u5176\u4e30\u5bcc\u7684\u5929\u7136\u6c14\u4f9b\u5e94\uff0c\u8fd9\u4e9b\u5929\u7136\u6c14\u4f9b\u5e94\u4e2d\u542b\u6709\u5927\u91cf\u7684\u8fd9\u4e24\u79cd\u6742\u8d28\u3002\u8be5\u6280\u672f\u8fd8\u53ef\u4ee5\u4fc3\u8fdb\u5168\u7403\u5929\u7136\u6c14\u548c\u5176\u4ed6\u542b\u6709\u786b\u5316\u6c22\u548c\u4e8c\u6c27\u5316\u78b3\u7684\u5de5\u4e1a\u6c14\u4f53\u7684\u4f7f\u7528\uff0c\u4ee5\u83b7\u5f97\u6f5c\u5728\u7684\u5de8\u5927\u73af\u5883\u548c\u7ecf\u6d4e\u6548\u76ca\u3002<\/p>\n

\u7efc\u4e0a\u6240\u8ff0\uff0c\u5728\u4e0d\u4e45\u7684\u5c06\u6765\uff0c\u57fa\u4e8eMOF \u7684\u5de5\u4e1a\u4ea7\u54c1\u3001\u7edd\u7f18\u6750\u6599\u3001\u9694\u97f3\u8033\u673a\u548c\u5148\u8fdb\u7684\u4f20\u611f\u5668\u90fd\u6709\u53ef\u80fd\u95ee\u4e16\u3002\u672a\u6765\uff0c\u6211\u4eec\u53ef\u4ee5\u5229\u7528MOFs\u4ece\u5927\u6c14\u4e2d\u5438\u6536\u78b3\uff0c\u6216\u8005\u4e3a\u65b0\u4e00\u4ee3\u71c3\u6599\u7bb1\u63d0\u4f9b\u52a8\u529b\u3002\u8fd9\u9700\u8981\u5f53\u4ee3\u79d1\u5b66\u5bb6\u4eec\u4e00\u8d77\u52aa\u529b\uff0c\u5171\u7b51\u7f8e\u597d\u5bb6\u56ed\u3002<\/p>\n

\u53c2\u8003\u6587\u732e\uff1a<\/b><\/strong><\/p>\n

1<\/b><\/strong>\u00a0A pressure-amplifying framework material with negative gas adsorption transitions. Nature, 2016,(532),\u00a0348.<\/p>\n

2<\/b><\/strong>\u00a0Reticular Chemistry in Action: A Hydrolytically Stable MOF Capturing Twice Its Weight in Adsorbed Water. Chem, 2018, 4(1), 94-105.<\/p>\n

3<\/b><\/strong>\u00a0Metal-organic frameworks with photocatalytic bactericidal activity for integrated air cleaning\u00a0,Nature Communications :https:doi.org\/10.1038\/s41467-019-10218-9.<\/p>\n

4\u00a0<\/strong>3D Energetic Metal\u2013Organic Frameworks: Synthesis and Properties of High Energy Materials, Angew. Chem. Int. Ed. 2013, 52, 14031.14035.<\/p>\n

5<\/strong>\u00a0Merging Photoredox and Organometallic Catalysts in a Metal\u2013Organic Framework Significantly Boosts Photocatalytic Activities,\u00a0Angew. Chem. Int. Ed. 2018, 57, 14090-14094.<\/p>\n

6<\/b><\/strong>\u00a0Stimuli-responsive metal\u2013organic frameworks gated by pillar[5]arene supramolecular switches,\u00a0Chem. Sci., 2015, 6, 1640-1644.<\/p>\n

7<\/b><\/strong>\u00a0Unveiling dual-linkage 3D hexaiminobenzene metal\u2013organic frameworks towards long-lasting advanced reversible Zn\u2013air batteries,\u00a0Energy Environ. Sci., <\/i><\/em>2019, 12, 727-738.<\/p>\n

8<\/b><\/strong>\u00a0Natural gas upgrading using a fluorinated MOF with tuned H2<\/sub>S and CO2<\/sub>\u00a0adsorption selectivity,\u00a0Nature Energy 2018(3),1059-1066.<\/p>\n

\u5f80\u671f\u56de\u987e\uff1a<\/strong><\/p>\n

\u6750\u6599\u4eba\u62a5\u544a | \u5404\u56fd\u5728MOFs\u9886\u57df\u7684\u7814\u7a76\u72b6\u51b5\u5206\u6790<\/a><\/p>\n

\u6253\u901aMOFs\u4efb\u7763\u4e8c\u8109 \u2014\u2014 \u77e5\u540d\u671f\u520a\u8fd1\u671f\u901f\u89c8<\/a><\/p>\n

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MOF\u4e13\u680f & PPT \u2014\u2014 \u56fd\u9645\u77e5\u540dMOF\u5927\u725b\u96c6\u9526<\/a><\/p>\n

\u672c\u6587\u7cfbJunas\u4f9b\u7a3f\u3002<\/p>\n

\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1: tougao@cailiaoren.com.<\/p>\n

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