{"id":177905,"date":"2019-06-16T06:30:16","date_gmt":"2019-06-15T22:30:16","guid":{"rendered":"\/\/m.iemloyee.com\/?p=177905"},"modified":"2019-06-15T10:23:37","modified_gmt":"2019-06-15T02:23:37","slug":"%e5%8d%97%e4%ba%ac%e5%a4%a7%e5%ad%a6%e7%8e%8b%e5%ad%a6%e6%96%8c%e8%af%be%e9%a2%98%e7%bb%84nano-energy%ef%bc%9a%e6%96%b0%e9%a2%96%e8%b6%85%e8%bd%bb%e4%b8%89%e7%bb%b4%e7%94%b5%e6%9e%81%e7%94%a8%e4%ba%8e","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=177905","title":{"rendered":"\u5357\u4eac\u5927\u5b66\u738b\u5b66\u658c\u8bfe\u9898\u7ec4Nano Energy\uff1a\u65b0\u9896\u8d85\u8f7b\u4e09\u7ef4\u7535\u6781\u7528\u4e8e\u9ad8\u6548\u7535\u50ac\u5316\u6c34\u5206\u89e3"},"content":{"rendered":"
\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n \u8fd1\u65e5\uff0c\u738b\u5b66\u658c\u6559\u6388\u8bfe\u9898\u7ec4<\/strong>\u5728\u7535\u50ac\u5316\u6c34\u5206\u89e3\u7814\u7a76\u9886\u57df\u53d6\u5f97\u65b0\u8fdb\u5c55\uff0c\u8bfe\u9898\u7ec4\u5c06NiFeP\u8d85\u8584\u7eb3\u7c73\u7247\u8d1f\u8f7d\u4e8e\u65b0\u578b\u57fa\u5e95\u4e09\u7ef4\u7b4b\u6491\u77f3\u58a8\u70ef\u4e0a\u5f97\u5230\u81ea\u652f\u6491\u4e09\u7ef4\u6c34\u5206\u89e3\u7535\u6781\uff0c\u76f8\u5173\u5de5\u4f5c\u4ee5\u300aMonolithic electrode integrated of ultrathin NiFeP on 3D strutted graphene for bifunctionally efficient overall water splitting\u300b\u4e3a\u9898\u53d1\u8868\u5728Nano Energy\u4e0a\u00a0(Nano Energy,\u00a02019, 58, 870)\u3002<\/p>\n \u80fd\u6e90\u662f\u4eba\u7c7b\u793e\u4f1a\u751f\u5b58\u548c\u53d1\u5c55\u7684\u91cd\u8981\u7269\u8d28\u57fa\u7840\uff0c\u662f\u4eba\u7c7b\u793e\u4f1a\u53d1\u5c55\u548c\u8fdb\u6b65\u7684\u91cd\u8981\u652f\u6491\u3002\u50a8\u91cf\u6709\u9650\u7684\u4f20\u7edf\u5316\u77f3\u80fd\u6e90\u5927\u89c4\u6a21\u4f7f\u7528\u5e26\u6765\u4e86\u73af\u5883\u6c61\u67d3\u548c\u6e29\u5ba4\u6548\u5e94\u7b49\u95ee\u9898\uff0c\u4e25\u91cd\u963b\u788d\u4e86\u4eba\u7c7b\u793e\u4f1a\u7684\u53ef\u6301\u7eed\u53d1\u5c55\u3002\u6c22\u6c14\u4f5c\u4e3a\u4e00\u79cd\u6e05\u6d01\u7684\u4e8c\u6b21\u80fd\u6e90\uff0c\u5177\u6709\u8f83\u9ad8\u7684\u8d28\u80fd\u6bd4\uff0c\u5e76\u4e14\u71c3\u70e7\u4ea7\u7269\u65e0\u6c61\u67d3\uff0c\u5df2\u88ab\u89c6\u4e3a\u4e00\u79cd\u7406\u60f3\u7684\u80fd\u6e90\u8f7d\u4f53\uff0c\u901a\u8fc7\u7535\u50ac\u5316\u6c34\u5206\u89e3\u5236\u6c22\u662f\u4e00\u9879\u975e\u5e38\u6709\u524d\u666f\u7684\u9014\u5f84\u3002\u7136\u800c\u7535\u50ac\u5316\u5206\u89e3\u6c34\u9762\u4e34OER\u548cHER\u7684\u53cd\u5e94\u52a8\u529b\u5b66\u7f13\u6162\u548c\u8fc7\u7535\u4f4d\u8f83\u9ad8\u7684\u95ee\u9898\uff0c\u800c\u4e14\u5927\u90e8\u5206\u50ac\u5316\u5242\u5747\u5728\u9178\u6027\u6216\u78b1\u6027\u6761\u4ef6\u4e0b\u5de5\u4f5c\uff0c\u589e\u52a0\u4e86\u80fd\u6e90\u6d88\u8017\u548c\u751f\u4ea7\u6210\u672c\u3002\u53bb\u5e74\uff0c\u8bfe\u9898\u7ec4\u9488\u5bf9\u6c34\u5206\u89e3\u50ac\u5316\u5242\u5de5\u4f5c\u6761\u4ef6\uff08\u9178\u6027\u6216\u78b1\u6027\uff09\u7684\u95ee\u9898\uff0c\u53d1\u5c55\u4e86CoO\/Co4<\/sub>N\u5f02\u8d28\u7ed3\u6784\u7535\u50ac\u5316\u5242\uff0c\u5728\u4e2d\u6027\u4f53\u7cfb\u4e2d\u5b9e\u73b0\u4e86\u7535\u50ac\u5316\u9ad8\u6548\u5168\u5206\u89e3\u6c34\uff0c\u76f8\u5173\u5de5\u4f5c\u4ee5\u300aCoO-modified Co4<\/sub>N as a heterostructured electrocatalyst for highly efficient overall water splitting in neutral media\u300b\u4e3a\u9898\u53d1\u8868\u5728Journal of Materials Chemistry A\u4e0a\uff08Journal of Materials Chemistry A, 2018,\u00a0<\/b><\/strong>6, 24767.\uff09\u3002<\/p>\n \u4e3a\u4e86\u8fdb\u4e00\u6b65\u964d\u4f4e\u7535\u50ac\u5316OER\u548cHER\u7684\u8fc7\u7535\u4f4d\u548c\u63d0\u5347\u53cd\u5e94\u52a8\u529b\u5b66\u6027\u80fd\uff0c\u738b\u5b66\u658c\u6559\u6388\u8bfe\u9898\u7ec4\u5728\u524d\u671f\u4e09\u7ef4\u7b4b\u79f0\u77f3\u58a8\u70ef\u7814\u7a76\u5de5\u4f5c(Nature Communications, 2013, 4, 2905; Nano Energy, 2015, 16, 81;\u00a0Bulletin of the Chemical Society of Japan, 2018,92 , 245)\u7684\u57fa\u7840\u4e0a\uff0c\u901a\u8fc7\u5b9e\u9a8c\u8bbe\u8ba1\u5408\u6210\u4e86\u8d85\u8f7b\u7684\u4e09\u7ef4\u81ea\u652f\u6491\u7535\u6781NiFeP\/SG\uff0c\u76f4\u63a5\u4f5c\u4e3a\u53cd\u5e94\u7535\u6781\u7528\u4e8e\u9ad8\u6548\u7535\u50ac\u5316\u6790\u6c27\u3001\u6790\u6c22\u53cd\u5e94\u548c\u5168\u5206\u89e3\u6c34\u3002<\/p>\n \u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n \u56fe1 3D NiFeP\/SG\u7535\u6781\u7684\u5236\u5907\u8fc7\u7a0b\u53ca\u7528\u4e8e\u7535\u50ac\u5316\u5168\u5206\u89e3\u6c34<\/p>\n \u56fe2 NiFeP\/SG\u7684\u5236\u5907\u8fc7\u7a0b<\/p>\n 3D SG\u7531\u4e8e\u5177\u6709\u8f83\u5927\u6bd4\u8868\u9762\u79ef\u3001\u591a\u5b54\u7ed3\u6784\u3001\u8f83\u9ad8\u7535\u5bfc\u7387\u548c\u4f18\u5f02\u7684\u7a33\u5b9a\u6027\uff0c\u8bfe\u9898\u7ec4\u7387\u5148\u5c06\u5176\u4f5c\u4e3a\u57fa\u5e95\uff0c\u901a\u8fc7\u5c06\u8d85\u8584\u7684NiFeP\u7eb3\u7c73\u7247\u76f4\u63a5\u751f\u957f\u5728SG\u8868\u9762\uff0c\u5f97\u52303D NiFeP\/SG\u81ea\u652f\u6491\u6c34\u5206\u89e3\u7535\u6781\u3002\u7814\u7a76\u53d1\u73b0\uff0c\u94c1\u5143\u7d20\u7684\u5f15\u5165\u6709\u6548\u8c03\u8282\u4e86Ni2<\/sub>P\u7684\u7535\u5b50\u7ed3\u6784\uff0c\u4f7f\u5176d<\/i><\/em>\u5e26\u4e2d\u5fc3\u4e0a\u6d6e\uff0c\u5bfc\u81f4\u5438\u9644\u4e2d\u95f4\u4f53\u7684\u5438\u9644\u80fd\u51cf\u5c11\uff0c\u964d\u4f4e\u4e86\u53cd\u5e94\u52bf\u5792\uff0c\u63d0\u9ad8\u4e86\u7535\u50ac\u5316\u6d3b\u6027\u3002\u800c\u4e14\u8d85\u8584\u7684NiFeP\u7eb3\u7c73\u7247\u7ed3\u6784\u3001SG\u7684\u591a\u5b54\u7ed3\u6784\u548cSG\u4e0aNiFeP\u7684\u76f4\u63a5\u751f\u957f\u8fdb\u4e00\u6b65\u63d0\u5347\u4e86NiFeP\/SG\u7684\u50ac\u5316\u6d3b\u6027\u3002\u5f53\u76f4\u63a5\u4f5c\u4e3a\u50ac\u5316\u7535\u6781\u65f6\uff0c\u572810 mA cm-2<\/sup>\u7535\u6d41\u5bc6\u5ea6\u4e0b\uff0cOER\u548cHER\u5206\u522b\u4ec5\u9700\u8fc7\u7535\u4f4d\u4e3a218\u548c115 mV\uff0c\u5168\u5206\u89e3\u6c34\u7684\u7535\u538b\u4ec5\u97001.54 V\u3002\u5229\u7528RRDE\u6280\u672f\u5206\u522b\u8bc1\u660e\u4e863D NiFeP\/SG\u7684OER\u548cHER\u8fc7\u7a0b\u5177\u6709\u8f83\u9ad8\u7684\u6cd5\u62c9\u7b2c\u6548\u7387\u3002\u540c\u65f6\u4e0eNiFeP\/NF\u548cNiFeP\/Ti\u76f8\u6bd4\uff0c3D\u00a0NiFeP\/SG\u5177\u6709\u8f83\u5c0f\u7684\u963b\u6297\u548c\u8f83\u5927\u7684\u8d28\u91cf\u6d3b\u6027\u3002<\/p>\n \u56fe3<\/p>\n \uff08a\uff09NiFeP\/SG\u7684OER\u7684\u6781\u5316\u66f2\u7ebf\uff0c\uff08b\uff09RRDE\u6280\u672f\u6d4b\u8bd5\u7684\u6837\u54c1NiFeP\/SG\u7684OER\u6cd5\u62c9\u7b2c\u6548\u7387\uff0c\uff08c\uff09NiFeP\/SG\u7684HER\u6781\u5316\u66f2\u7ebf\uff0c\uff08d-f\uff09RRDE\u6280\u672f\u5bf9\u6837\u54c1NiFeP\/SG\u8fdb\u884cHER\u6cd5\u62c9\u7b2c\u6548\u7387\u7684\u6d4b\u8bd5<\/p>\n \u5357\u4eac\u5927\u5b66\u73b0\u4ee3\u5de5\u7a0b\u4e0e\u5e94\u7528\u79d1\u5b66\u5b66\u96622016\u7ea7\u535a\u58eb\u751f\u674e\u745e\u5e86\u4e3a\u8bba\u6587\u7684\u7b2c\u4e00\u4f5c\u8005\uff0c\u738b\u5b66\u658c\u6559\u6388\u4e3a\u8bba\u6587\u901a\u8baf\u4f5c\u8005\uff0c\u5408\u4f5c\u5355\u4f4d\u6709\u9999\u6e2f\u57ce\u5e02\u5927\u5b66\u3001\u65e5\u672c\u56fd\u7acb\u6750\u6599\u7814\u7a76\u6240\uff0c\u76f8\u5173\u5de5\u4f5c\u5f97\u5230\u4e86\u5357\u4eac\u5927\u5b66\u80e1\u5f81\u6559\u6388\u3001\u4e0a\u6d77\u5927\u5b66\u674e\u6c38\u4e50\u6559\u6388\u7b49\u4eba\u7684\u652f\u6301\uff0c\u4ee5\u53ca\u5357\u4eac\u5927\u5b66\u9ad8\u529b\u6ce2\u6559\u6388\u3001\u5f90\u6d01\u7814\u7a76\u5458\u5728\u62c9\u66fc\u8868\u5f81\u65b9\u9762\u7684\u5927\u529b\u534f\u52a9\u3002\u7814\u7a76\u5f97\u5230\u4e86\u56fd\u5bb6\u81ea\u7136\u79d1\u5b66\u57fa\u91d1\u59d4\u9762\u4e0a\u53ca\u9752\u5e74\u9879\u76ee\u3001\u4e2d\u592e\u9ad8\u6821\u57fa\u672c\u79d1\u7814\u4e1a\u52a1\u8d39\u4e13\u9879\u57fa\u91d1\u3001\u6c5f\u82cf\u7701\u4f18\u52bf\u5b66\u79d1\u3001\u6c5f\u82cf\u7701\u81ea\u7136\u57fa\u91d1\u7b49\u9879\u76ee\u7684\u652f\u6301\u3002<\/p>\n \u6587\u732e\u94fe\u63a5\uff1ahttps:\/\/www.sciencedirect.com\/science\/article\/pii\/S2211285519301363<\/a><\/strong><\/p>\n \u76f8\u5173\u6587\u7ae0\uff1a<\/p>\n
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