{"id":17675,"date":"2016-06-04T14:00:22","date_gmt":"2016-06-04T06:00:22","guid":{"rendered":"\/\/m.iemloyee.com\/?p=17675"},"modified":"2016-06-04T13:13:40","modified_gmt":"2016-06-04T05:13:40","slug":"nature%e5%ad%90%e5%88%8a%ef%bc%9a%e9%ab%98%e6%95%88%e5%82%ac%e5%8c%96%e5%89%82%e7%9a%84%e5%8f%91%e7%8e%b0%e4%bd%bfli-o2%e7%94%b5%e6%b1%a0%e5%be%aa%e7%8e%af%e5%af%bf%e5%91%bd%e5%92%8c%e6%95%88","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=17675","title":{"rendered":"Nature\u5b50\u520a\uff1a\u9ad8\u6548\u50ac\u5316\u5242\u7684\u53d1\u73b0\u4f7fLi\u2013O2\u7535\u6c60\u5faa\u73af\u5bff\u547d\u548c\u6548\u7387\u4e0a\u6709\u4e86\u91cd\u5927\u8fdb\u6b65\uff01"},"content":{"rendered":"

\u5bf9\u4e8eLi-O2<\/sub>\u7535\u6c60\u800c\u8a00\uff0c\u5f00\u53d1\u65b0\u578b\u9ad8\u6548\u50ac\u5316\u5242\u662f\u63d0\u9ad8\u5faa\u73af\u5bff\u547d\u548c\u5f80\u8fd4\u6548\u7387\u7684\u91cd\u8981\u73af\u8282\u3002\u548c\u5e38\u89c4\u56fa\u4f53\u50ac\u5316\u5242\u76f8\u6bd4\uff0c\u53ef\u6eb6\u6027\u50ac\u5316\u5242\u6216\u8005\u6c27\u5316\u8fd8\u539f\u4ecb\u8d28\uff08redox mediators , RM\uff09\u5177\u6709\u8bb8\u591a\u4f18\u52bf\uff0c\u4e3b\u8981\u8868\u73b0\u5728\u6709\u5229\u4e8e\u52a0\u5feb\u9ad8\u7edd\u7f18\u6027\u653e\u7535\u4ea7\u7269\u7684\u6c27\u5316\uff0c\u5e76\u6709\u53ef\u80fd\u5b9e\u73b0\u8f83\u9ad8\u7684\u53ef\u9006\u5bb9\u91cf\uff0c\u8868\u73b0\u51fa\u66f4\u9ad8\u7684\u6548\u7387\u3002\u57fa\u4e8e\u8fd9\u4e2a\u539f\u56e0\uff0c\u9996\u5c14\u56fd\u7acb\u5927\u5b66\u7684Kyeongjae Cho\u53caKisuk Kang\u8bfe\u9898\u7ec4\u62a5\u9053\u4e86\u4e00\u79cd\u8bbe\u8ba1\u7b56\u7565\uff0c\u901a\u8fc7\u9009\u62e9\u4e00\u7cfb\u5217\u6709\u673a\u6c27\u5316\u8fd8\u539f\u4ecb\u8d28\u4f5c\u4e3a\u6a21\u578b\u4f53\u7cfb\uff0c\u6765\u786e\u8ba4Li-O2<\/sub>\u7535\u6c60\u50ac\u5316\u6d3b\u6027\u548c\u7a33\u5b9a\u6027\u7684\u51b3\u5b9a\u56e0\u7d20\uff0c\u4ece\u800c\u5b9e\u73b0\u66f4\u9ad8\u6548\u7684\u91cd\u590d\u5145\u7535\uff01<\/p>\n

\u7814\u7a76\u7ed3\u679c\u8868\u660e\uff0c\u5728\u6bd4\u8f83\u7535\u89e3\u8d28\u4e2dLi2<\/sub>O2<\/sub>\u7684\u5f62\u6210\u80fd\u548c\u88ab\u5360\u636e\u7684\u6700\u9ad8\u5206\u5b50\u8f68\u9053\u80fd\uff08HOMO\uff09\u65f6\uff0c\u5206\u5b50\u6570\u636e\u5e93\u7684\u53c2\u6570\u6240\u5f97\u5230\u7684\u7535\u79bb\u80fd\u7ea7\u5f71\u54cd\u91cd\u5927\uff0c\u5206\u522b\u8d77\u5230\u4e86\u964d\u4f4e\u8fc7\u7535\u4f4d\u548c\u63d0\u9ad8\u7a33\u5b9a\u6027\u7684\u4f5c\u7528\u3002\u6839\u636e\u7814\u7a76\u7ed3\u679c\uff0cHee-Dae Lim\u7b49\u4eba\u63d0\u51fa\u4e86\u4e00\u79cd\u666e\u904d\u53ef\u884c\u7684\u50ac\u5316\u5242\u8bbe\u8ba1\u539f\u5219\uff0c\u5e76\u636e\u6b64\u9009\u62e9\u4e86\u4e00\u79cd\u5408\u9002\u7684\u6c27\u5316\u8fd8\u539f\u4e2d\u95f4\u4f53\uff0c\u4e8c\u7532\u57fa\u5429\u55ea\uff0c\u5b9e\u73b0\u4e86\u8f83\u4f4e\u7684\u8fc7\u7535\u4f4d\u548c\u8f83\u9ad8\u7684\u7a33\u5b9a\u6027\u3002<\/p>\n

\u968f\u7740\u624b\u63d0\u5f0f\u80fd\u6e90\u9700\u6c42\u7684\u5feb\u901f\u53d1\u5c55\uff0c\u9ad8\u80fd\u91cf\u5bc6\u5ea6\u7684\u7535\u6c60\u8d8a\u6765\u8d8a\u53d7\u5230\u5173\u6ce8\u3002\u5728\u4f17\u591a\u9502\u7535\u6c60\u5019\u9009\u8005\u5f53\u4e2dLi\u2013O2<\/sub>\u7535\u6c60\u7531\u4e8e\u5176\u6781\u9ad8\u7684\u7406\u8bba\u80fd\u91cf\u5bc6\u5ea6\uff08\u7ea63500Wh kg\u22121\uff09\u3001\u65e0\u9700\u8fc7\u6e21\u91d1\u5c5e\u4ee5\u53ca\u5728\u7535\u5316\u5b66\u53cd\u5e94\u4e2d\u6c27\u6e90\u5145\u8db3\u7b49\u539f\u56e0\u6210\u4e3a\u4e86\u672a\u6765\u9502\u7535\u6c60\u53d1\u5c55\u7684\u65b9\u5411\u3002\u7136\u800c\uff0c\u73b0\u5982\u4eca\u7684Li\u2013O2<\/sub>\u7535\u6c60\u4ecd\u65e7\u9762\u4e34\u7740\u8bb8\u591a\u9650\u5236\uff0c\u8bf8\u5982\u77ed\u5faa\u73af\u5bff\u547d\u3001\u9ad8\u7684\u8fc7\u7535\u52bf\uff08\u4f4e\u80fd\u91cf\u6548\u7387\uff09\u3002\u7eb5\u7136\u5728\u67d0\u79cd\u89d2\u5ea6\u800c\u8a00\u5faa\u73af\u5bff\u547d\u548c\u9ad8\u7684\u8fc7\u7535\u52bf\u76f8\u4e92\u8054\u7cfb\uff0c\u8fc7\u7535\u52bf\u7684\u8d77\u56e0\u4e3b\u8981\u662f\u7531\u4e8e\u4e00\u4e9bLi2<\/sub>O2<\/sub>\u7684\u6eb6\u89e3\u56e0\u7d20\uff0c\u6bd4\u5982\u4f4e\u7535\u5bfc\u7387\u3001\u5f62\u6210\/\u5206\u89e3\u4e0d\u5e0c\u671b\u4ea7\u7269\uff08\u5982\uff1aLi2<\/sub>CO3<\/sub>\uff09\uff0c\u5728Li\u2013O2<\/sub>\u7535\u6c60\u4e2dLi2<\/sub>O2<\/sub> \u5728\u7535\u6781\u8868\u9762\u6c89\u79ef\u4e0d\u5747\u5300\u4f7f\u6b63\u6781\u7684\u900f\u6c14\u5b54\u5835\u585e\u5f71\u54cd\u6c27\u548c\u79bb\u5b50\u7684\u4f20\u8f93\u4ece\u800c\u5bfc\u81f4\u9ad8\u7684\u8fc7\u7535\u52bf\u3002\u60f3\u8981\u5145\u5206\u5229\u7528Li\u2013O2<\/sub>\u7535\u6c60\u9ad8\u80fd\u91cf\u5bc6\u5ea6\u7684\u7279\u70b9\u5c31\u5fc5\u987b\u89e3\u51b3\u4e0a\u8ff0\u95ee\u9898\u3002<\/p>\n

\u9ad8\u6548\u5206\u89e3Li2<\/sub>O2<\/sub>\u50ac\u5316\u5242\u7684\u53d1\u73b0\u4e3aLi\u2013O2<\/sub>\u7535\u6c60\u7cfb\u7edf\u7684\u53d1\u5c55\u505a\u51fa\u4e86\u5de8\u5927\u8d21\u732e\u3002\u5728\u65e9\u671f\u7684Li\u2013O2<\/sub><\/strong>\u7535\u6c60\u50ac\u5316\u5242\u7814\u7a76\u4e2d\uff0c\u50ac\u5316\u5242\u88ab\u5e7f\u6cdb\u5e94\u7528\u5728\u71c3\u6599\u7535\u6c60\u7684\u6790\u6c27\u53cd\u5e94\u6216\u8005\u6c34\u88c2\u89e3\u88c5\u7f6e\u3002\u5728\u8fd9\u4e2a\u8fc7\u7a0b\u4e2d\u50ac\u5316\u5242\u4e5f\u4fc3\u8fdb\u4e86\u7535\u89e3\u8d28\u7684\u5206\u89e3\uff0c\u800c\u4e14\u5b58\u5728\u4e8e\u56fa\u56fa\u8fde\u63a5\u5904\u7684\u9650\u5236\u6d3b\u6027\u4f4d\u70b9\u964d\u4f4e\u4e86\u50ac\u5316\u5242\u6d3b\u6027\u3002\u4e3a\u4e86\u907f\u514d\u8fd9\u4e2a\u95ee\u9898\u79d1\u7814\u4eba\u5458\u63d0\u51fa\u4e86\u53ef\u6eb6\u6027\u50ac\u5316\u5242\u548c\u6c27\u5316\u8fd8\u539f\u4ecb\u8d28\u3002\u53ef\u6269\u6563\u7684\u6c27\u5316\u8fd8\u539f\u4ecb\u8d28\u80fd\u8f7b\u6613\u7684\u5728\u7535\u89e3\u6db2\u4e2d\u8fd0\u52a8\u4e0e\u56fa\u6001\u4ea7\u7269\u76f8\u63a5\u5904\uff0c\u4ece\u800c\u6700\u5927\u9650\u5ea6\u7684\u63d0\u5347\u50ac\u5316\u6548\u679c\u3002\u8fd9\u4e2a\u65b9\u6cd5\u4e3a\u4ece\u7535\u6781\u5206\u79bb\u51fa\u6765\u7684\u653e\u7535\u7269\u8d28\u5145\u7535\u540c\u6837\u9002\u7528\uff0c\u5927\u5e45\u5ea6\u7684\u63d0\u5347\u4e86Li\u2013O2<\/sub><\/strong>\u7535\u6c60\u7684\u5faa\u73af\u5bff\u547d\u548c\u7535\u6c60\u6548\u7387\u3002\u7814\u7a76\u4eba\u5458\u5df2\u7ecf\u62a5\u9053\u4e86\u5982tetrathiafulvalene(TTF)\u3001tetramethylpiperidinyloxyl (TEMPO)\u7b49\u591a\u79cd\u53ef\u6eb6\u6027\u50ac\u5316\u5242\uff0c\u5728\u964d\u4f4e\u8fc7\u7535\u52bf\u4e0a\u6548\u679c\u663e\u8457\u3002<\/p>\n

\u7531\u4e8e\u53ef\u6eb6\u6027\u50ac\u5316\u5242\uff08RM\uff09\u7684\u6c27\u5316\u8fd8\u539f\u7535\u4f4d\u51b3\u5b9a\u7535\u6c60\u7684\u5145\u7535\u7535\u538b\uff0c\u53ef\u4ee5\u9009\u62e9\u5408\u9002\u7684\u50ac\u5316\u5242\u6765\u4fee\u6539\u8fc7\u7535\u52bf\u503c\u3002\u56e0\u6b64\uff0cRM\u7684\u5408\u7406\u8bbe\u8ba1\u5bf9\u4e8e\u964d\u4f4e\u8fc7\u7535\u52bf\uff0c\u63d0\u5347\u5faa\u73af\u7a33\u5b9a\u6027\u5341\u5206\u6709\u76ca\u3002\u672c\u8bfe\u9898\u63d0\u51fa\u4e00\u79cd\u57fa\u4e8e\u79bb\u5b50\u80fd\u7406\u8bba\u53d1\u73b0\u5408\u9002\u50ac\u5316\u5242\u7684\u7efc\u5408\u8bbe\u8ba1\u7406\u5ff5\u3002\u4ed6\u4eec\u53d1\u73b0\uff0c\u53ea\u6709\u4e00\u79cd\u7279\u5b9a\u8303\u56f4\u79bb\u5b50\u80fd\u7684\u6709\u673a\u6750\u6599\u53ef\u4ee5\u7528\u4f5c\u53ef\u6eb6\u6027\u50ac\u5316\u5242\u3002 \u5bc6\u5ea6\u6cdb\u51fd\u7406\u8bba\u8ba1\u7b97\u548c\u5b9e\u9a8c\u7ed3\u679c\u5747\u8868\u660e\uff0c\u7406\u8bba\u8fc7\u7535\u52bf\u53ca\u7a33\u5b9a\u6027\u53d6\u51b3\u4e8e Li2<\/sub>O2<\/sub>\u7684\u5206\u89e3\u80fd\u548c\u7535\u89e3\u6db2\u7684\u6c27\u5316\u7535\u4f4d\uff0c\u56e0\u6b64\u5e94\u9009\u62e9\u521d\u59cb\u6001\u548c\u6c27\u5316\u6001\u5747\u5177\u6709\u5408\u9002\u7684\u6700\u9ad8\u5360\u6709\u5206\u5b50\u8f68\u9053\u80fd\u7ea7\u7684\u50ac\u5316\u5242\u3002\u57fa\u4e8e\u5df2\u63d0\u51fa\u7684\u7406\u8bba\uff0c\u4f5c\u8005\u53d1\u73b0\uff0cDMPZ\uff085,10-dimethylphenazine\uff09\u5177\u6709\u663e\u8457\u7684\u4f4e\u8fc7\u7535\u52bf\u548c\u8f83\u9ad8\u7684\u7a33\u5b9a\u6027\u3002\u8fd9\u4e00\u91cd\u8981\u53d1\u73b0\u5bf9\u53ef\u6eb6\u6027\u50ac\u5316\u5242\u7684\u53d1\u5c55\u5177\u6709\u91cd\u5927\u4fc3\u8fdb\u610f\u4e49\uff0c\u540c\u65f6\u4e5f\u63a8\u8fdbLi\u2013O2<\/sub><\/strong>\u7535\u6c60\u7684\u4e0d\u65ad\u8fdb\u6b65\u3002<\/p>\n

\u4ee5\u4e0b\u662f\u56fe\u6587\u8be6\u89e3\uff1a<\/strong><\/p>\n

\u6839\u636e\u79bb\u5b50\u80fd\u7b5b\u9009\u6c27\u5316\u8fd8\u539f\u4ecb\u8d28<\/strong><\/p>\n

\"fig1\"<\/p>\n

\u56fe1. Li-O2<\/sub>\u7535\u6c60\u4e2d\u6c27\u5316\u8fd8\u539f\u4ecb\u8d28\u7684\u4f5c\u7528\u3002 a\u4e3a\u56fe\u89e3RM\u5728Li-O2<\/sub>\u7535\u6c60\u4e2d\u7684\u53cd\u5e94\u673a\u5236\u3002\u9996\u5148\u5728\u5145\u7535\u8fc7\u7a0b\u4e2dRM\uff08\u84dd\u5706\uff09\u5728\u7535\u6781\u8868\u9762\u9644\u8fd1\u88ab\u6c27\u5316\uff08step 1\uff09\uff0c\u63a5\u7740RM+<\/sup><\/strong>\uff08\u7ea2\u5706\uff09\u5c06Li2<\/sub>O2<\/sub>\u6c27\u5316\u62102Li+<\/sup><\/strong>\uff08\u7eff\u5706\uff09\u548cO2<\/sub>\uff08\u6a59\u5706\uff09\uff1b\u540c\u65f6\uff0cRM+<\/sup><\/strong>\u88ab\u8fd8\u539f\u4e3a\u8d77\u521d\u7684RM\uff08step 2\uff09\uff1bb\u4e3a\u56fe\u89e3Li-O2<\/sub>\u7535\u6c60\u7684\u653e\u7535\u66f2\u7ebf\uff08\u9ed1\u7ebf\uff09\u548c\u542bRM\uff08\u84dd\u7ebf\uff09\u548c\u4e0d\u542bRM\uff08\u7ea2\u7ebf\uff09\u7684\u5145\u7535\u66f2\u7ebf\u3002<\/p>\n

\u56fe1a\u8868\u660e\uff0cLiO2<\/sub>\u7535\u6c60\u5185\u6c27\u5316\u8fd8\u539f\u4ecb\u8d28\u7684\u53cd\u5e94\u673a\u7406\u53ef\u4ee5\u770b\u4f5c\u4e24\u4e2a\u8fc7\u7a0b\uff1a\u7535\u5316\u5b66\u53cd\u5e94\u9636\u6bb5\u548c\u5316\u5b66\u53cd\u5e94\u9636\u6bb5\u3002\u5728\u7b2c\u4e00\u6b65\u53cd\u5e94\uff0c\u5373\u7535\u5316\u5b66\u53cd\u5e94\u9636\u6bb5\u4e2d\uff0c\u867d\u7136Li2<\/sub>O2<\/sub>\u5206\u89e3\u65f6\u7684\u9ad8\u5145\u7535\u70b9\u4f4d\u4f7f\u5f97RM\u7684\u6c27\u5316\u8fd8\u539f\u7535\u52bf\u4e00\u822c\u9ad8\u4e8eLi2<\/sub>O2<\/sub>\uff0c\u4f46\u5728\u5145\u7535\u8fc7\u7a0b\u4e2d\uff0cRM\u4ecd\u4f1a\u5728Li2<\/sub>O2<\/sub>\u5145\u7535\u524d\uff08\u6216\u540c\u65f6\uff09\u5728\u7535\u6781\u8868\u9762\u5904\u88ab\u6c27\u5316\u3002\u5728\u7b2c\u4e8c\u6b65\u53cd\u5e94\u4e2d\uff0c\u6c27\u5316\u6001\u7684RM\u5927\u91cf\u6269\u6563\u81f3\u7535\u89e3\u6db2\u4e2d\uff0c\u4e0eLi2<\/sub>O2<\/sub>\u53d1\u751f\u5316\u5b66\u53cd\u5e94\uff0c\u4f7fLi2<\/sub>O2<\/sub>\u5206\u89e3\u4e3a2Li+\u548c\u6c27\u6c14\uff0c\u540c\u65f6\u81ea\u8eab\u88ab\u8fd8\u539f\u4e3a\u521d\u59cb\u6001\u7684RM\u3002<\/p>\n

\u56fe1b\u663e\u793a\uff0c\u7531\u4e8e\u7b2c\u4e00\u6b65\u53cd\u5e94\u6d4b\u5f97\u4e86\u7535\u6c60\u7684\u5145\u7535\u7535\u538b\uff08\u5373RM\u7684\u7535\u5316\u5b66\u6c27\u5316\u8fc7\u7a0b\uff09\uff0c\u901a\u8fc7\u9009\u62e9\u5408\u9002\u7684\u6c27\u5316\u8fd8\u539f\u4ecb\u8d28\u53ef\u4ee5\u964d\u4f4e\u7535\u8377\u6781\u5316\u3002 \u4e3a\u4e86\u51cf\u5c11Li2<\/sub>O2<\/sub>\u7684\u5316\u5b66\u6c27\u5316\u6216\u5206\u89e3\uff0c\u9ad8\u4e8eLi2<\/sub>O2<\/sub>\u5f62\u6210\u7684RM\/RM+\u6c27\u5316\u8fd8\u539f\u7535\u52bf\u5fc5\u4e0d\u53ef\u5c11\u3002 \u56e0\u6b64\uff0c\u9009\u62e9\u5177\u6709\u5408\u9002\u6c27\u5316\u8fd8\u539f\u7535\u52bf\u7684RM\u81f3\u5173\u91cd\u8981\u3002<\/p>\n

\u8003\u8651\u5230\u53cd\u5e94\u673a\u7406\uff0c\u6c27\u5316\u8fd8\u539f\u7535\u52bf\u5e94\u6210\u4e3a\u9009\u62e9\u5408\u9002RM\u7684\u9996\u8981\u6807\u51c6\u3002RM\u6c27\u5316\u65f6\u7535\u538b\u5e94\u9ad8\u4e8e2.96V\uff08Li2<\/sub>O2<\/sub>\u5f62\u6210\u7684\u7406\u8bba\u7535\u538b\uff09\uff0c\u624d\u80fd\u4f7fLi2<\/sub>O2<\/sub>\u5206\u89e3\u3002\u4f46\u662f\uff0c\u4e3a\u4e86\u4f7f\u80fd\u91cf\u5229\u7528\u7387\u6700\u5927\u5316\uff0c\u6b64\u7535\u538b\u503c\u5e94\u7565\u9ad8\u4e8e2.96V\u3002 \u56e0\u6b64\uff0c\u6839\u636eRM\uff08\u672c\u8eab\u7684\uff09\u6c27\u5316\u8fd8\u539f\u7535\u52bf\u7b5b\u9009\uff08\u76ee\u6807\uff09RM\u8f83\u4e3a\u5408\u7406\u3002\u5728\u7535\u89e3\u6db2\u4e2d\uff0c\u6c27\u5316\u8fd8\u539f\u7535\u52bf\u503c\u4ecb\u4e8e3-4V\uff0c\u5177\u6709\u6c27\u5316\u8fd8\u539f\u6d3b\u6027\u7684\u53ef\u6eb6\u6027\u6709\u673a\u7269\u53ef\u80fd\u6210\u4e3a\u7406\u60f3\u7684RM\u3002 \u7136\u800c\uff0c\u6709\u673a\u6750\u6599\u7684\u6c27\u5316\u8fd8\u539f\u7535\u52bf\u5728\u7535\u5316\u5b66\u7535\u6c60\u4e0d\u540c\u7c7b\u578b\u7684\u6eb6\u5242\u4e2d\u4e0d\u5c3d\u76f8\u540c\uff0c\u56e0\u6b64\u5f88\u96be\u4ece\u6587\u732e\u4e2d\u83b7\u5f97\u3002 \u5728\u7b5b\u9009RM\u7684\u8fc7\u7a0b\u4e2d\uff0c\u6211\u4eec\u5c06\u771f\u7a7a\u72b6\u6001\u4e0b\u5206\u5b50\u7684\u79bb\u5b50\u80fd\u4f5c\u4e3a\u6c27\u5316\u8fd8\u539f\u7535\u52bf\u7684\u53c2\u8003\u3002\u6839\u636e\u7edd\u5bf9\u771f\u7a7a\u8868\uff08AVS\uff09\u5f97\u77e5\uff0c\u79bb\u5b50\u80fd\u80fd\u591f\u4ee3\u8868\u771f\u7a7a\u4e2d\u7684\u6c27\u5316\u8fd8\u539f\u7535\u52bf\uff0c\u6545\u5176\u53ef\u88ab\u8ba4\u5b9a\u4e3a\u7535\u89e3\u6db2\u4e2dRM\u7684\u6c27\u5316\u8fd8\u539f\u7535\u52bf\u7684\u5224\u5b9a\u6807\u51c6\u3002\u6b64\u5916\uff0c\u5229\u7528\u5149\u7535\u5b50\u5149\u8c31\u5404\u4e2a\u5206\u5b50\u7684\u5927\u6570\u636e\u5e93\uff0c\u5f88\u5bb9\u6613\u4f30\u7b97\u5f97\u51fa\u79bb\u5b50\u80fd\u503c\u3002 \u7684\u786e\uff0c\u5bc6\u5ea6\u6cdb\u51fd\u7406\u8bba\u7684\u8ba1\u7b97\u7ed3\u679c\u4e0e\u6587\u732e\u4e2d\u8bb8\u591a\u6709\u673a\u7269\u7684\u79bb\u5b50\u80fd\u6570\u503c\u5747\u663e\u793a\uff0c\u79bb\u5b50\u80fd\u4e0e\u7535\u89e3\u6db2\u4e2dLi\/Li+\u7684\u6c27\u5316\u7535\u538b\u5448\u73b0\u51fa\u5927\u81f4\u7684\u7ebf\u6027\u5173\u7cfb\u3002<\/p>\n

\u9a8c\u8bc1\u50ac\u5316\u5242\u5bf9\u6c27\u5316\u8fd8\u539f\u4ecb\u8d28\u7684\u4f5c\u7528<\/strong><\/p>\n

\"fig2\"<\/p>\n

\u56fe2. \u4e0d\u540cRM\u7684\u7535\u5316\u5b66\u6027\u80fd\u3002 a\u4e3a\u542b\u4e0d\u540cRM\u7684Li-O2<\/sub>\u7535\u6c60\u7684\u5f00\u8def\u7535\u538b\u53d8\u5316\u56fe\uff0c\u663e\u7136\u9664\u4e86Naphthacene\u5916\uff0c\u5176\u5b83\u5747\u6709\u5f88\u597d\u7684\u7a33\u5b9a\u6027\u3002 b\u56fe\u4e3a\u4e0d\u540cRM\u7684\u7535\u5316\u5b66\u6c27\u5316\u7535\u538b\uff0c\u865a\u7ebf\u662fLi2<\/sub>O2<\/sub>\u7684\u7406\u8bba\u5f62\u6210\u7535\u4f4d\u503c\uff0c\u660e\u663e\u6839\u636eI.E.\u6240\u9009\u62e9\u7684RMs\u5747\u5177\u6709\u9ad8\u4e8e2.96V\u7684\u6c27\u5316\u7535\u4f4d\u503c\uff0c\u5e76\u4e14DMPZ\u5177\u6709\u6700\u4f4e\u7684\u6c27\u5316\u7535\u538b\u503c\uff0c\u610f\u5473\u7740\u5176\u53ef\u80fd\u662f\u6700\u4f18\u7684RM\u5019\u9009\u8005\u3002 c\u4e3a\u542b\u4e0d\u540cRM\u7684Li-O2<\/sub>\u7535\u6c60\u7684\u9996\u5708\u5145\u653e\u7535\u66f2\u7ebf\u56fe\uff0c\u53ef\u4ee5\u770b\u51faNDA, TMA, PPD\u548cDMPZ\u53ef\u4ee5\u5927\u5e45\u964d\u4f4eLi-O2<\/sub>\u7535\u6c60\u7684\u6781\u5316\uff0c\u5747\u7b26\u5408\u88681\u7684\u7edf\u8ba1\u7ed3\u679c\u548c\u56fe2b\u7684\u5b9e\u9a8c\u7ed3\u679c<\/p>\n

\u7531\u4e8e\u53ef\u6eb6\u6027\u50ac\u5316\u5242\u5373\u4f7f\u5728\u6c27\u6c14\u6c1b\u56f4\u4e2d\u4ecd\u80fd\u5728\u7535\u89e3\u6db2\u4e2d\u6eb6\u89e3\u5e76\u4fdd\u6301\u8f83\u957f\u65f6\u95f4\uff0c\u4f5c\u8005\u5c06\u4e4b\u524d\u7b5b\u9009\u7684\u6c27\u5316\u8fd8\u539f\u4ecb\u8d28\u5e94\u7528\u5230Li\u2013O2<\/sub><\/strong>\u7535\u6c60\u4e2d\u8fdb\u884c\u68c0\u6d4b\u3002\u6240\u6709\u7684\u5907\u9009\u6750\u6599\u5747\u53ef\u4ee5\u8f83\u597d\u7684\u6eb6\u89e3\u5728TEGDME\u57fa\u7535\u89e3\u6db2\u4e2d\u5e76\u4e14\u65e0\u6d41\u52a8\u6c27\u73af\u5883\u4e0b\u4fdd\u6301\u8f83\u957f\u65f6\u95f4\u3002\u56fe2a\u8868\u660e\uff0c\u901a\u8fc7\u76d1\u6d4bLi\u2013O2<\/sub><\/strong>\u7535\u6c60\u7684\u5f00\u8def\u7535\u538b\uff08Voc<\/sub>\uff09\u53ef\u4ee5\u5bf9\u6d41\u52a8\u6c27\u73af\u5883\u4e2d\u7684\u7a33\u5b9a\u6027\u8fdb\u884c\u8bc4\u6d4b\u3002\u867d\u7136\u5728DMPZ, NDA\uff081,5-naphthalenediamine\uff09, TMA \u548cPPD\uff081-phenylpyrrolidine\uff09\u4e2d\u5f00\u8def\u7535\u538b\u5e76\u6ca1\u6709\u8f83\u5927\u53d8\u5316\uff0c\u4f46\u662fNC\uff08naphthacene\uff09\u7684\u5f00\u8def\u7535\u538b\u5374\u6301\u7eed\u51cf\u5c11\uff0c\u8868\u660e\u4e86\u5176\u5728\u7535\u5316\u5b66\u7535\u6c60\u4e2d\u7684\u4e0d\u7a33\u5b9a\u6027\u3002\u9020\u6210\u5176\u4e0d\u7a33\u5b9a\u884c\u7684\u539f\u56e0\u662f\u7531\u4e8e\u5e76\u82ef\u57fa\u6750\u6599\u5728\u7a7a\u6c14\u4e2d\u89c1\u5149\u6613\u5206\u89e3\u3002<\/p>\n

\u56fe2b\u8868\u660e\uff0cDMPZ, NDA, TMA ,PPD\u7684\u5e73\u5747\u7535\u538b\u4f9d\u6b21\u662f3.29, 3.64,3.88,3.93 V\uff0c\u548c\u6211\u4eec\u7406\u8bba\u8ba1\u7b97\u7684\u76f8\u543b\u5408\u3002\u6b63\u5982\u9884\u6599\u7684\u90a3\u6837\uff0cDMPZ\u8868\u73b0\u51fa\u4e86\u8f83\u4f4e\u7684\u6c27\u5316\u7535\u4f4d\uff0c\u8fd9\u5c31\u610f\u5473\u7740\u5982\u679c\u6c27\u5316\u8fd8\u539f\u53cd\u5e94\u662f\u53ef\u9006\u7684\u8bdd\uff0c\u5bf9\u4e8eLi\u2013O2<\/strong>\u7535\u6c60DMPZ\u5c06\u4f1a\u6210\u4e3a\u9ad8\u6548\u50ac\u5316\u5242\u3002\u53e6\u5916\uff0c\u5728\u76f8\u540c\u7684\u6d4b\u8bd5\u73af\u5883\u4e0b\u53e6\u6709\u4e24\u79cd\u6709\u673a\u72691,4-dioxane\u548cN,N-dimethylformamide \u7684\u79bb\u5b50\u80fd\u7565\u9ad8\u4e8e6.7eV\u3002\u4ee5\u4e0a\u4e00\u7cfb\u5217\u5b9e\u9a8c\u6240\u6d4b\u8bd5\u51fa\u7684\u51fa\u7684\u6c27\u5316\u8fd8\u539f\u4ecb\u8d28\u7684\u7535\u538b\u4e0e\u6211\u4eec\u7528\u79bb\u5b50\u80fd\u9884\u8a00\u7684\u7ed3\u679c\u6781\u5176\u7b26\u5408\uff01<\/p>\n

\u56fe2c\u8868\u660e\u4e86\u4e0d\u540c\u6c27\u5316\u8fd8\u539f\u4ecb\u8d28\u548c\u65e0\u6c27\u5316\u8fd8\u539f\u4ecb\u8d28\u76f8\u6bd4\u8f83\u7684\u7b2c\u4e00\u6b21\u5145\u653e\u7535\u56fe\u3002\u6240\u6709\u7684\u7535\u6c60\u7684\u5145\u653e\u7535\u5747\u9075\u5faa1 mAh\u4e0b0.2 mA cm\u2212<\/sup>2<\/sup> \u7684\u5145\u653e\u7535\u901f\u7387\u4ece\u800c\u786e\u4fdd\u786e\u4fdd\u4e0d\u540c\u7535\u6c60\u5177\u6709\u540c\u6837\u7684Li2<\/sub>O2<\/sub>\u5f62\u6210\u6eb6\u89e3\u91cf\u3002\u53ef\u4ee5\u660e\u663e\u770b\u51fa\uff0c\u4e0e\u6ca1\u6709\u6c27\u5316\u8fd8\u539f\u4ecb\u8d28\u7684\u7535\u6c60\u76f8\u6bd4\uff0c \u6c27\u5316\u8fd8\u539f\u4ecb\u8d28\u4e3aNDA, TMA ,PPD, DMPZ\u7535\u6c60\u7684\u5145\u7535\u6781\u5316\u73b0\u8c61\u660e\u663e\u51cf\u5f31\u3002\u503c\u5f97\u6ce8\u610f\u7684\u662f\u6b64\u7ed3\u679c\u4e0e\u56fe\u88681\u7684\u9884\u6d4b\u4ee5\u53ca\u5b9e\u9a8c\u7ed3\u679c\u5b8c\u5168\u543b\u5408\uff01\u4e0e\u56fe 2b\u4e2d\u6ca1\u6709\u653e\u7535\u7684\u7535\u6c60\u76f8\u6bd4\uff0c\u5145\u7535\u7535\u538b\u5728\u5145\u7535\u7ed3\u675f\u524d\u6709\u7565\u5fae\u63d0\u5347\uff0c\u8fd9\u4e3b\u8981\u662f\u7531\u4e8e\u591a\u5b54\u78b3\u7ed3\u6784\u4f20\u8f93\u9650\u5236\u7684\u539f\u56e0\u3002\u5982\u4e4b\u524d\u62a5\u544a\u4e2d\u63d0\u5230\u7684\u90a3\u6837\uff0c\u56fe3\u4e2d\u4e24\u5bf9\u63a7\u5236\u7684\u6c27\u5316\u8fd8\u539f\u4ecb\u8d28\uff081,4-dioxane \u548cN,N-dimethylformamide\uff09\u4ed6\u4eec\u7684\u79bb\u5b50\u80fd\u63a5\u8fd19eV\uff0c\u4f46\u662f\u4e0e\u6ca1\u6709\u6c27\u5316\u8fd8\u539f\u4ecb\u8d28\u7684\u7535\u6c60\u76f8\u6bd4\uff0c\u5e76\u672a\u770b\u5230\u5176\u5bf9\u6709\u5145\u7535\u56fe\u8c31\u4e0a\u4efb\u4f55\u5f71\u54cd\u3002\u8fd9\u662f\u56e0\u4e3a\u5982\u56fe2b\u4e2d\u663e\u793a\u7684\u90a3\u6837\uff0c\u57285V\u4ee5\u4e0b\uff0c\u63a7\u5236\u7ec4\u5e76\u6ca1\u6709\u88ab\u6c27\u5316\uff0c\u6240\u4ee5\u6c27\u5316\u8fd8\u539f\u4ecb\u8d28\u5e76\u672a\u8d77\u5230\u4efb\u4f55\u4f5c\u7528\u3002<\/p>\n

\"fig3\"<\/p>\n

\u56fe3 \u4e0d\u540cRM\u7684\u6548\u679c\u6c14\u4f53\u5206\u6790\u56fe\u3002 a\u4e3a\u6c14\u4f53\u5206\u6790\u8fc7\u7a0b\u793a\u610f\u56fe\u3002\u6790\u6c27\u68c0\u6d4b\u7ed3\u679c\u56feTTF and LiI (b), NDA (c), TMA (d), PPD (e) and DMPZ (f)<\/p>\n

\u5982\u56fe3a\u6240\u793a\uff0c\u4e3a\u4e86\u9a8c\u8bc1\u7535\u6c60\u7684\u5145\u7535\u8fc7\u7a0b\u662f\u5426\u4f34\u968f\u7740Li2<\/sub>O2<\/sub>\u7684\u5206\u89e3\uff0c\u6211\u4eec\u5bf9\u6c27\u5316\u6001RM (RM+)\u751f\u6210\u7684\u6c14\u4f53\u8fdb\u884c\u4e86\u68c0\u6d4b\u5206\u6790\u3002\u56fe3b\u8868\u660eTTF\u548cLiI\u7684\u6548\u7387\u5206\u522b\u4e3a2.08\u548c2.22\uff0c\u4e0e\u7406\u8bba\u503c2\u76f8\u543b\u5408\uff0c\u8fd9\u4e5f\u5c31\u8bc1\u5b9e\u4e86\u5176\u5bf9\u4fc3\u8fdbLi2<\/sub>O2<\/sub>,\u5206\u89e3\u7684\u4f5c\u7528\u3002\u5982\u56fe3c-e\u6240\u793a\uff0cNDA\uff0cTMA\u548cPPD\u7684\u5b9e\u9645\u4ea7\u6c27\u91cf\u4e0e\u7406\u8bba\u4ea7\u6c27\u91cf\u5374\u76f8\u5dee\u751a\u8fdc\u3002\u8fd9\u4e9b\u7ed3\u679c\u8868\u660e\uff0c\u5728\u53cd\u5e94\u8fc7\u7a0b\u6c47\u603b\u4e0d\u4ec5\u6709Li2<\/sub>O2<\/sub>\u7684\u5206\u89e3\uff0c\u540c\u65f6\u4e5f\u4f34\u968f\u7740\u5927\u91cf\u7684\u526f\u53cd\u5e94\u3002\u503c\u5f97\u6ce8\u610f\u7684\u662f\uff0c\u5728\u4f17\u591a\u6c27\u5316\u8fd8\u539f\u4ecb\u8d28\u4e2d\uff0cDMPZ\u7684\u4ea7\u6c27\u91cf\u4e0d\u4ec5\u548c\u671f\u671b\u503c\u76f8\u7b26\u540c\u65f6\u540c\u65f6\u8fd8\u5177\u5907\u4e86\u9ad8\u6548\u6027\u3002\u8fd9\u8868\u660eDMPZ\u662f\u4e00\u79cd\u8f83\u597d\u7684\u50ac\u5316\u5242\u3002<\/p>\n

\u6c27\u5316\u8fd8\u539f\u4ecb\u8d28\u7684\u53cd\u5e94\u673a\u7406<\/strong><\/p>\n

\"fig4\"<\/p>\n

\u56fe4. RMs\u548cTEGDME(\u56db\u4e59\u4e8c\u9187\u4e8c\u7532\u57fa\u919a,\u7535\u89e3\u6db2)\u7684\u5206\u5b50\u8f68\u9053\u80fd\u3002\u9ed1\u6761\u548c\u7ea2\u6761\u5206\u522b\u4ee3\u8868\u8d77\u521d\u7684\u548c\u9996\u6b21\u6c27\u5316\u540eRMs\u7684HOMO\u548cLUMO\u80fd\uff1b\u84dd\u865a\u7ebf– Li2<\/sub>O2<\/sub>\u7684\u7406\u8bba\u5f62\u6210\u7535\u4f4d\u503c\uff0c\u9ec4\u533a–RM+ + e\u2212\u2192 RM\uff08RM\/RM+\uff09\u7684\u6c27\u5316\u8fd8\u539f\u7535\u538b\uff08\u9700 > Li2<\/sub>O2<\/sub>\u7684\u7406\u8bba\u5f62\u6210\u7535\u4f4d\u503c2.96V\uff09\uff0c\u9ed1\u865a\u7ebf–TEGDME\u7684HOMO\u80fd\uff0c\u7d2b\u6846–RM\u4f1a\u4e0e\u7535\u89e3\u6db2TEGDME\u53d1\u751f\u53cd\u5e94\uff0c\u7eff\u6846–RM\u5728TEGDME\u4e2d\u662f\u7a33\u5b9a\u7684\uff0c\u7070\u533a–RM\u4e0d\u7a33\u5b9a\uff0c\u53ef\u80fd\u4e0eTEGDME\u53d1\u751f\u53cd\u5e94<\/p>\n

\u56fe4\u662f\u57fa\u4e8e\u5bc6\u5ea6\u6001\u6cdb\u51fd\u6570\u8ba1\u7b97\uff08DFT\uff09\u51fa\u7684\u521d\u59cbRMs\uff08\u9ed1\u8272\u6761\u72b6\uff09\u7684\u6700\u9ad8\u5360\u636e\u5206\u5b50\u8f68\u9053\u80fd\u7ea7\u548c\u7b2c\u4e00\u6b21\u6c27\u5316\u7684RMs\uff08\u7ea2\u8272\u6761\u72b6\uff09\u7684\u6700\u4f4e\u4e3a\u5360\u6709\u5206\u5b50\u8f68\u9053\u80fd\u7ea7\u3002\u84dd\u7ebf\u4ee3\u8868Li2<\/sub>O2<\/sub> (2Li+<\/sup> + O2<\/sub> + 2e\u2212<\/sup>\u2194Li2<\/sub>O2<\/sub>)\u7684\u5f62\u6210\u80fd\uff082.96V\uff09\uff0c\u7528\u9ec4\u8272\u533a\u57df\u8868\u793aRM+ + e\u2212\u2194 RM\u7684\u6c27\u5316\u8fd8\u539f\u7535\u52bf\uff08\u9ad8\u4e8e2.96V\uff09\u3002\u9ed1\u7ebf\u8868\u793aTEGDME\u7684HOMO\u80fd\u7ea7\u5f53\u6c27\u5316\u6001RM\u7684SOMO\u80fd\u7ea7\u4f4e\u4e8eTEGDME\u7684HOMO\u80fd\u7ea7\u65f6\uff0cRM\u53ef\u4ee5\u4e0e\u7535\u89e3\u6db2\u53cd\u5e94\uff08\u5982\u7d2b\u8272\u6846\u4e2d\u6240\u793a\uff09\u3002\u5426\u5219\u5c06\u4f1a\u7a33\u5b9a\u5b58\u5728\u3002\u7070\u8272\u533a\u57df\u8868\u793a\u76f8\u5173\u4e0d\u7a33\u5b9a\u5206\u5b50\u53ef\u80fd\u4e0eTEGME\u53cd\u5e94\u3002<\/p>\n

\"fig5\"<\/p>\n

\u56fe5 \u4e0d\u540c\u6c27\u5316\u8fd8\u539f\u4ecb\u8d28\u7684\u7535\u5316\u5b66CV\u56fe\u3002 NDA (a), TMA (b), PPD (c) and DMPZ (d) \u5728 1 M LiTFSI\/TEGDME\u7535\u89e3\u6db2\u4e2d Ar\u6c14\u6c1b\u4e0b\u7684CV\u56fe\uff1be\u4e3aDMPZ \u5faa\u73af200\u5708\u7684CV\u56fe\uff08\u7535\u538b\u8303\u56f4\u4e3a2.0-4.5 V versus Li\/Li+<\/sup>\uff09\uff1bf\u4e3aDMPZ\u57281 M TBATFSI\/DMSO\u7535\u89e3\u6db2 Ar\u548cO2<\/sub>\u6c14\u6c1b\u4e0b\u7684CV\u56fe<\/p>\n

\u5982\u56fe5\u6240\u793a\uff0c\u4e3a\u4e86\u8fdb\u4e00\u6b65\u8bc1\u660eRMs\u7684\u6548\u7387\u4ee5\u53ca\u53ef\u9006\u6027\u5bf9\u5176\u8fdb\u884c\u5faa\u73af\u4f0f\u5b89\u6d4b\u8bd5\uff08CV\uff09\u3002\u5f53RMs\u548c\u7535\u89e3\u6db2\u4e4b\u95f4\u53d1\u751f\u5fae\u5c0f\u526f\u53cd\u5e94\u65f6\uff0cRM\/RM+\u7684\u53ef\u9006\u7684\u6c27\u5316\u8fd8\u539f\u5cf0\u5728\u6b63\u6781\u548c\u8d1f\u6781\u4e4b\u95f4\u51fa\u73b0\u3002\u56fe5a\u6240\u793a\uff0cNDA\u7684\u7b2c\u4e00\u4e2a\u6c27\u5316\u5cf0\u51fa\u73b0\u57283.75V\uff0c\u4f46\u662f\u8fd8\u539f\u5cf0\u5374\u4e0d\u660e\u663e\uff0c\u53ea\u662f\u57283.1V\u548c2.4V\u9644\u8fd1\u51fa\u73b0\u4e86\u4e00\u4e2a\u5c0f\u7684\u8fd8\u539f\u5cf0\uff0c\u8fd9\u4e2a\u7ed3\u679c \u8868\u660eNDA\/NDA+\u5728TEGDME\u4e2d\u4e0d\u4ec5\u4e0d\u80fd\u7a33\u5b9a\u5b58\u5728\u8fd8\u4f1a\u548c\u7535\u89e3\u6db2\u53d1\u751f\u526f\u53cd\u5e94\u3002\u5bf9\u4e8eTMA\u548cPPD\u60c5\u51b5\u4e5f\u662f\u4e00\u6837\uff0c\u6c27\u5316\u5cf0\u51fa\u73b0\u57283.5V\u52304V\u4e4b\u95f4\uff0c\u800c\u4e0e\u4e4b\u76f8\u5bf9\u7684\u8fd8\u539f\u5cf0\u5374\u6ca1\u6709\u6e05\u695a\u7684\u663e\u73b0\u51fa\u6765\u3002CV\u6d4b\u8bd5\u7684\u7ed3\u679c\u4e0e\u6c14\u4f53\u5206\u6790\u5b9e\u9a8c\u548c\u7406\u8bba\u8ba1\u7b97\u7ed3\u679c\u76f8\u4e00\u81f4\uff0c\u53cd\u6620\u4e86NDA\uff0cTMA\u548cPPD\u7684\u4f4e\u6548\u3002\u76f8\u53cd\uff0c\u56fe5d\u8868\u660e\u7b2c\u4e00\u4e2a\u6c27\u5316\u8fc7\u7a0b\u53d1\u751f\u5728\u7ea63.4V\u5904\uff0c\u8fd9\u4e0e\u8fd8\u539f\u5cf0\u76843.3V\u76f8\u5bf9\u5e94\uff0c\u4e14\u5176\u53d1\u751f\u7684\u6781\u5316\u53ef\u4ee5\u5ffd\u7565\u4e0d\u8ba1\u3002DMPZ+\/DMPZ2+\u7684\u7b2c\u4e8c\u6b21\u7684\u6c27\u5316\u8fd8\u539f\u53cd\u5e94\u53d1\u751f\u5728\u9ad8\u7535\u4f4d\u7ea64V\u5904\uff0c\u4e14\u5728\u6570\u767e\u6b21\u5faa\u73af\u4e4b\u540e\u6ca1\u6709\u526f\u53cd\u5e94\u5cf0\u7684\u51fa\u73b0\u3002\u8fd9\u8868\u660e\u5373\u4f7f\u662f\u8fc7\u51b2\u60c5\u51b5\u4e0b\u7684RM\uff0cDMPZ\u4ecd\u65e7\u53ef\u4ee5\u901a\u8fc7\u6c27\u5316\u8fd8\u539f\u53cd\u5e94\u4fdd\u6301\u5176\u5316\u5b66\u7a33\u5b9a\u6027\u3002\u56fe5f\u662fDMPZ\u5728\u4e8c\u7532\u57fa\u4e9a\u781c\uff08DMSO\uff09\u57fa\u7535\u89e3\u6db2\u548c\u7eaf\u6c27\u6c1b\u56f4\u4e0b\u7684\u53ef\u9006\u6d3b\u6027\u56fe\uff0c\u8868\u660e\u5728\u4e0d\u540c\u7535\u89e3\u6db2\u6761\u4ef6\u4e0bDMPZ\/DMPZ+\u5747\u8868\u73b0\u51fa\u4e86\u9ad8\u5f97\u53ef\u9006\u6027\u3002<\/p>\n

DMPZ<\/strong>\u5bf9Li\u2013O2<\/strong>\u7535\u6c60<\/strong>\u7684\u50ac\u5316\u4f5c\u7528<\/strong><\/p>\n

\"fig6\"<\/p>\n

\u56fe6. DMPZ\u50ac\u5316\u5242\u5bf9Li-O2<\/sub>\u7535\u6c60\u6027\u80fd\u5f71\u54cd\u3002a\u4e3a\u4e0d\u540c\u9636\u6bb5\u7684DMPZ\u7684XRD\u68c0\u6d4b\uff1bb\u4e3a\u542bDMPZ\u7684Li-O2<\/sub>\u7535\u6c60\u7684GITT\uff08\u6052\u7535\u6d41\u95f4\u6b47\u6ef4\u5b9a\u6280\u672f\uff09\u68c0\u6d4b\u56fe\uff1b\u7a7a\u6c14\u7535\u6781\u7684FE-SEM\u56fe\uff1ac\u521a\u5236\u5907\u7684\uff0cd\u653e\u7535\u540e\u7684\uff0cf\u5145\u7535\u540e\u7684<\/p>\n

\u901a\u8fc7\u9884\u5148\u7b5b\u67e5\u8ba1\u7b97\u548c\u5b9e\u9a8c\u9a8c\u8bc1\uff0c\u4f5c\u8005\u6700\u7ec8\u9009\u5b9aDMPZ\u4e3a\u6700\u6709\u6548\u7684\u50ac\u5316\u5242\uff0c\u5e76\u5728LiO2<\/sub>\u7535\u6c60\u4e2d\u5bf9\u5176\u50ac\u5316\u6d3b\u6027\u8fdb\u884c\u4e86\u7814\u7a76\u3002\u56fe6\u5206\u522b\u4e3a \u4e3aX\u5c04\u7ebf\u884d\u5c04\uff08XRD\uff09\u3001\u6052\u7535\u6d41\u95f4\u6b47\u6ef4\u5b9a\uff08GITT\uff09\u4ee5\u53ca\u573a\u53d1\u5c04\u626b\u63cf\u7535\u5b50\u663e\u5fae\u955c\u7684\u7ed3\u679c\u3002\u7a7a\u6c14\u7535\u6781\u7528TEGDME\u4ed4\u7ec6\u6e05\u6d17\uff0c\u9632\u6b62\u88ab\u7a7a\u6c14\u4e2d\u6c27\u6c14\u6c27\u5316\u3002\u867d\u7136\u5df2\u5236\u5907\u7535\u6781\u7684X\u5c04\u7ebf\u884d\u5c04\u56fe\u8c31\u53ea\u4e0e\u954d\u7f51\u72b6\u5c42\u76f8\u4e00\u81f4\uff0c\u653e\u7535\u540e\uff0c\u4e00\u7ec4\u65b0\u51fa\u73b0\u7684Li2<\/sub>O2<\/sub>\u5cf0\u6e05\u6670\u53ef\u89c1\uff08\u56fe6a\uff09\u3002\u518d\u5145\u7535\u540e\u5cf0\u5b8c\u5168\u6d88\u5931\uff0c\u8868\u660e\u5145\u7535\u8fc7\u7a0b\u4e2d\uff0cDMPZ\u53ef\u4ee5\u6709\u6548\u5206\u89e3Li2<\/sub>O2<\/sub>\u3002\u540c\u65f6\u4e5f\u7528\u6052\u7535\u6d41\u95f4\u6b47\u6ef4\u5b9a\u6cd5\u8fdb\u884c\u4e86Li2<\/sub>O2<\/sub>\u5f62\u6210\u5206\u89e3\u53ef\u9006\u53cd\u5e94\u5b9e\u9a8c\uff08\u56fe6b\uff09\u3002\u5982\u56fe6b\u6240\u793a\uff0c\u5728\u653e\u7535\uff08\u84dd\u7ebf\uff09\u548c\u5145\u7535\uff08\u7ea2\u7ebf\uff09\u8fc7\u7a0b\u4e2d\uff0c\u6bcf\u4e00\u6b65\u7684\u8212\u5f20\u7535\u4f4d\u63a5\u8fd1Li2<\/sub>O2<\/sub>\u7684\u7406\u8bba\u5f62\u6210\u7535\u538b\uff082.96\u4f0f\uff0c\u865a\u7ebf\uff09\uff0c\u8868\u660e\u5728\u6574\u4e2a\u8fc7\u7a0b\u4e2d\u6d89Li2<\/sub>O2<\/sub>\u51fa\u73b0\u5728\u521d\u7ea7\u53cd\u5e94\u4e2d\u3002<\/p>\n

\u6b64\u5916\uff0c\u7a7a\u6c14\u7535\u6781\u7684\u5f62\u6001\u5b66\u7814\u7a76\uff08\u56fe6c-e\uff09\u4e5f\u9a8c\u8bc1\u4e86DMPZ\u5728\u5145\u7535\u8fc7\u7a0b\u4e2d\u80fd\u6709\u6548\u5206\u89e3Li2<\/sub>O2<\/sub>\u8fd9\u4e00\u7ed3\u8bba\u3002\u56fe6c\u4e3a\u5236\u5907\u51fa\u7684\u5177\u6709\u591a\u5b54\u5f84\u79d1\u7434\u9ed1\u78b3\u7535\u6781\u8868\u9762\u7684\u7a7a\u6c14\u7535\u6781\u3002\u5982\u56fe\u56fe 6d\uff0c\u653e\u7535\u540e\u5f62\u6210\u7684Li2<\/sub>O2<\/sub>\u73af\u5f62\u653e\u7535\u4ea7\u7269\u4e0e\u4e4b\u524d\u6587\u732e\u62a5\u9053\u4e00\u81f4\u3002\u7136\u800c\uff0c\u653e\u7535\u4ea7\u7269\u5728\u5145\u7535\u540e\u660e\u663e\u5206\u89e3(\u56fe6e)\u3002<\/p>\n

\u8bbe\u8ba1RM\u7684\u57fa\u672c\u539f\u5219\u548c\u6761\u4ef6\u5982\u4e0b\u3002\u9996\u6b21\u7b5b\u9009\u4e2d\uff0c\u5728\u771f\u7a7a\u4e2d\u79bb\u5b50\u80fd\u503c\u7ea6\u4e3a6 eV\u7684\u6709\u673a\u7269\u5206\u5b50\u8f83\u4e3a\u7406\u60f3\u3002\u4f46\u9700\u6ce8\u610f\uff0c\u968f\u7740\u6240\u9009\u5b9a\u6eb6\u5242\u79cd\u7c7b\u7684\u4e0d\u540c\uff0cLi \/ Li+\u6c27\u5316\u8fd8\u539f\u7535\u4f4d\u548c\u5206\u5b50\u7684\u79bb\u5b50\u4e5f\u4e0d\u540c\uff0c\u56e0\u6b64\uff0c\u5f53\u6839\u636e\u5206\u5b50\u7684\u79bb\u5b50\u80fd\u9009\u62e9\u6c27\u5316\u8fd8\u539f\u4ecb\u8d28\u65f6\uff0c\u5e94\u8003\u8651\u5230\u6eb6\u5242\u5bf9\u6c27\u5316\u8fd8\u539f\u7535\u4f4d\u7684\u5f71\u54cd\uff08\u4e0a\u6587\u76846 eV\u6807\u51c6\u53ea\u9002\u7528\u4e8e\u4f4e\u7535\u5b50\u4f9b\u4f53\u6eb6\u5242\uff0c\u5982\u4e59\u4e8c\u9187\u4e8c\u7532\u919a\u6eb6\u5242\uff09\u3002\u5176\u6b21\uff0cRM\u79bb\u5b50\u80fd\u503c\u5e94\u5c0f\u4e8eLi2<\/sub>O2<\/sub>\u7684\u5f62\u6210\u80fd\u3002\u5404\u79bb\u5b50\u80fd\u503c\u4e4b\u95f4\u7565\u6709\u4e0d\u540c\uff0c\u53ef\u80fd\u4e0e\u80fd\u91cf\u5229\u7528\u7387\u6709\u5173\u3002\u6b64\u5916\uff0c\u4e3a\u907f\u514d\u526f\u53cd\u5e94\uff0cRM+\u7684SOMO\u80fd\u7ea7\u5e94\u9ad8\u4e8e\u7535\u89e3\u6db2\u7684HOMO\u80fd\u7ea7\u3002\u7535\u89e3\u6db2\u7684HOMO\u80fd\u7ea7\u53ef\u4ee5\u8fbe\u5230\u66f4\u597d\u7684\u5316\u5b66\u7a33\u5b9a\u6027\u3002\u6700\u540e\uff0c\u5728\u6709\u6c27\u6761\u4ef6\u4e0b\uff0c\u8fd9\u4e9b\u5206\u5b50\u5e94\u6eb6\u4e8e\u7535\u89e3\u6db2\u5e76\u7a33\u5b9a\u5b58\u5728\u3002\u672c\u6587\u5c06\u5206\u5b50\u79bb\u5b50\u80fd\u8fd9\u4e00\u7b80\u5355\u7684\u7269\u7406\u53c2\u6570\u4f5c\u4e3a\u9009\u62e9RM\u7684\u6807\u51c6\uff0c\u65b9\u6cd5\u7b80\u4fbf\u6613\u5f97\uff0c\u6709\u52a9\u4e8e\u4e8e\u8fdb\u4e00\u6b65\u5f00\u53d1\u51fa\u4e00\u7cfb\u5217\u53ef\u6eb6\u6027\u50ac\u5316\u5242\u3002<\/p>\n

\u4e00\u53e5\u8bdd\u603b\u7ed3\uff1a<\/strong><\/p>\n

Lim\u7b49\u4eba\u63d0\u51fa\u7684\u7528\u6765\u5bfb\u627e\u53ef\u6eb6\u6027\u50ac\u5316\u5242\u8bbe\u8ba1\u7b56\u7565\uff0c\u5e76\u7528DFT\u8ba1\u7b97\u548c\u5b9e\u9a8c\u6765\u8bc1\u5b9e\u5176\u6709\u6548\u6027\u3002\u4ed6\u4eec\u6307\u51fa\uff0c\u79bb\u5b50\u80fd\u662f\u8bbe\u8ba1\u50ac\u5316\u5242\u7684\u5173\u952e\uff0c\u4e00\u4e9b\u79bb\u5b50\u80fd\u57285.8\u52306.8eV\u4e14\u5176HOMO\u80fd\u7ea7\u6bd4Li2<\/sub>O2<\/sub>\u7684\u5f62\u6210\u80fd\u548c\u7535\u89e3\u6db2\u7684HOMO\u80fd\u7ea7\u9ad8\u7684\u6709\u673a\u6750\u6599\u53ef\u4ee5\u88ab\u7528\u4f5c\u50ac\u5316\u5242\u3002\u57fa\u4e8e\u4ee5\u4e0a\u6761\u4ef6\uff0c\u4ee5\u53ca\u5728Li\u2013O2<\/sub>\u7535\u6c60\u4e2d\u7684\u4f4e\u8fc7\u7535\u52bf\u3001\u9ad8\u7a33\u5b9a\u6027\u7684\u8868\u73b0\uff0cDMPZ\u88ab\u8ba4\u4e3a\u662f\u6700\u6709\u6548\u7684\u6750\u6599\u3002Lim\u8ba4\u4e3a\u4ee5\u4e0a\u6c27\u5316\u8fd8\u539f\u4ecb\u8d28\u7684\u8bbe\u8ba1\u7b56\u7565\u5c06\u4f1a\u4e3a\u53d1\u5c55\u9ad8\u6548\u50ac\u5316\u5242\u6253\u5f00\u4e00\u6761\u65b0\u7684\u601d\u8def\uff0c\u4f7fLi\u2013O2<\/sub>\u7535\u6c60\u7684\u9ad8\u6548\u6027\u548c\u957f\u5bff\u547d\u66f4\u4e0a\u4e00\u4e2a\u53f0\u9636\uff01<\/p>\n

\u672c\u6587\u4e8e2016\u5e745\u6708\u53d1\u8868\u5728NATURE ENERGY\u4e0a\uff0c\u539f\u6587\u94fe\u63a5\uff1aRational design of redox mediators for advanced Li-O2<\/sub> batteries<\/a><\/p>\n

\u8be5\u6587\u732e\u5bfc\u8bfb\u7531\u6750\u6599\u4eba\u65b0\u80fd\u6e90\u5b66\u4e60\u5c0f\u7ec4\u00a0 \u5927\u5b8b\u3001\u9189\u5fc3 \u4f9b\u7a3f\uff0c\u53c2\u4e0e\u65b0\u80fd\u6e90\u8bdd\u9898\u8ba8\u8bba\u8bf7\u52a0\u5165\u201c\u6750\u6599\u4eba\u65b0\u80fd\u6e90\u6750\u6599\u4ea4\u6d41\u7fa4 422065952\u201d\uff0c\u82e5\u60f3\u53c2\u4e0e\u65b0\u80fd\u6e90\u6587\u732e\u89e3\u8bfb\u548c\u6587\u732e\u6c47\u603b\u3001\u65b0\u80fd\u6e90\u77e5\u8bc6\u79d1\u666e\u548c\u6df1\u5ea6\u6316\u6398\u65b0\u80fd\u6e90\u5b66\u672f\u4ea7\u4e1a\u4fe1\u606f\uff0c\u8bf7\u52a0qq 2728811768\u3002<\/p>\n

\u6b22\u8fce\u5404\u5927\u8bfe\u9898\u7ec4\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1tougao@cailiaoren.com<\/p>\n","protected":false},"excerpt":{"rendered":"

\u5bf9\u4e8eLi-O2\u7535\u6c60\u800c\u8a00\uff0c\u5f00\u53d1\u65b0\u578b\u9ad8\u6548\u50ac\u5316\u5242\u662f\u63d0\u9ad8\u5faa\u73af\u5bff\u547d\u548c\u5f80\u8fd4\u6548\u7387\u7684\u91cd\u8981\u73af\u8282\u3002\u548c\u5e38\u89c4\u56fa\u4f53\u50ac\u5316\u5242\u76f8\u6bd4\uff0c\u53ef\u6eb6\u6027\u50ac\u5316\u5242\u6216\u8005\u6c27\u5316\u8fd8\u539f\u4ecb\u8d28\uff08redox mediators…<\/p>\n","protected":false},"author":90,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[129],"class_list":["post-17675","post","type-post","status-publish","format-standard","hentry","category-jiedu","tag-battery"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/17675"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/90"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=17675"}],"version-history":[{"count":2,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/17675\/revisions"}],"predecessor-version":[{"id":17683,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/17675\/revisions\/17683"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=17675"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=17675"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=17675"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}