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Potential of Electrolyte Filled MOF Membrane as Ionic Sieve in Rechargeable Batteries<\/b><\/strong>\u201d\u4e3a\u9898\u53d1\u8868\u5728Energy Environ. Sci.<\/b><\/strong>\u4e0a\u3002<\/p>\n \u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/b><\/strong><\/p>\n \u56fe\u4e00\u3001\u5177\u6709\u79bb\u5b50\u9009\u62e9\u6027\u7684M<\/b><\/strong>OF<\/b><\/strong>\u819c\u5e94\u7528\u4e8e\u5404\u79cd\u7535\u6c60\u4f53\u7cfb\uff0c\u4ee5\u53ca\u4e00\u4e9b\u5177\u6709\u4ee3\u8868\u6027\u7684M<\/b><\/strong>OF<\/b><\/strong>\u7ed3\u6784\u793a\u610f\u56fe<\/b><\/strong> <\/b>1.MOF\u819c\u7684\u5236\u5907<\/b><\/strong><\/p>\n 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\uff08e\uff09HKUST-1\u5728\u4fee\u9970\u4e86OH-\u548cCOOH-\u7684SAM-\u6539\u6027\u91d1\u8868\u9762\u57fa\u5e95\u4e0a\u5177\u6709\u4e0d\u540c\u7684\u751f\u957f\u65b9\u5411\u9009\u62e9\u6027\u3002<\/p>\n 1.3 \u6784\u5efa\u57fa\u4e8eMOF\u7684\u590d\u5408\u819c<\/b><\/strong><\/p>\n \u56fe\u56db\u3001MOF\u57fa\u590d\u5408\u819c\u7684\u5236\u5907<\/b><\/strong> \uff08a\uff09\u771f\u7a7a\u62bd\u6ee4\u6cd5\u5236\u5907MOF@GO\u9694\u819c\u7684\u8fc7\u7a0b\u793a\u610f\u56fe\uff1b<\/p>\n \uff08b\uff09\u67d4\u6027MOF@PVDF-HFP\u9694\u819c\u7684\u6570\u7801\u7167\u7247\uff1b<\/p>\n \uff08c\uff09\u901a\u8fc7\u522e\u5200\u5ef6\u6d41\u6cd5\u5236\u5907MOF\u57fa\u590d\u5408\u819c\u7684\u8fc7\u7a0b\u793a\u610f\u56fe\uff1b<\/p>\n \uff08d\uff09\u91c7\u7528\u522e\u5200\u5ef6\u6d41\u6cd5\u6240\u5236\u5907MOF\u57fa\u590d\u5408\u819c\u7684\u6570\u7801\u7167\u7247\u3002<\/p>\n 2.\u7a33\u5b9a\u9502\u6c89\u79ef<\/b><\/strong><\/p>\n \u5728\u4f7f\u7528\u9502\u91d1\u5c5e\u4f5c\u4e3a\u8d1f\u6781\u7684\u9502\u7535\u6c60\u4e2d\uff0c\u7531\u4e8e\u9502\u79bb\u5b50\u7684\u975e\u5747\u76f8\u6c89\u79ef\u9020\u6210\u4e86\u9502\u679d\u6676\u7684\u751f\u957f\u3002\u9502\u679d\u6676\u7684\u751f\u957f\u589e\u52a0\u4e86\u9502\u91d1\u5c5e\u4e0e\u7535\u89e3\u6db2\u526f\u53cd\u5e94\u7684\u53cd\u5e94\u9762\u79ef\uff0c\u52a0\u901f\u6d3b\u6027\u9502\u548c\u7535\u89e3\u6db2\u7684\u6d88\u8017\uff0c\u9020\u6210\u7535\u6c60\u5bb9\u91cf\u7684\u5feb\u901f\u8870\u51cf\uff0c\u7f29\u77ed\u7535\u6c60\u7684\u4f7f\u7528\u5bff\u547d\u3002\u66f4\u4e25\u91cd\u7684\u662f\uff0c\u5c16\u9510\u7684\u9502\u679d\u6676\u80fd\u591f\u523a\u7a7f\u7535\u6c60\u9694\u819c\uff0c\u9020\u6210\u7535\u6c60\u5185\u90e8\u77ed\u8def\uff0c\u5e26\u6765\u4e25\u91cd\u7684\u5b89\u5168\u9690\u60a3\u3002<\/p>\n \u56fe\u4e94\u3001\u57fa\u4e8eMOF\u7684\u9694\u819c\/\u7535\u89e3\u8d28\u4f53\u7cfb\u6709\u6548\u8c03\u63a7\u9502\u79bb\u5b50\u7684\u5747\u76f8\u6c89\u79ef<\/b><\/strong> \uff08b\uff09TFSI–<\/sup>\u6cbf\u4e24\u6761\u4e0d\u540c\u8def\u5f84\u901a\u8fc7MOF\u5b54\u9053\u7684\u793a\u610f\u56fe\uff1b<\/p>\n \uff08c\uff09\u8ba1\u7b97TFSI–<\/sup>\u9634\u79bb\u5b50\u6cbf\u7740\uff08b\uff09\u4e2d\u4e24\u6761\u9014\u5f84\u8fc1\u79fb\u7684\u80fd\u91cf\u58c1\u5792\uff1b<\/p>\n \uff08d\uff09Li+\u548cTFSI\u2012\u79bb\u5b50\u5728MOF\u57fa\u7535\u89e3\u8d28\u4e2d\u7684MSD\u968f\u6a21\u62df\u65f6\u95f4\u7684\u53d8\u5316\uff1b<\/p>\n \uff08e\uff09MOF\u57fa\u7535\u89e3\u8d28\u7684\u79bb\u5b50\u7b5b\u4f5c\u7528\u793a\u610f\u56fe\u3002<\/p>\n \u56fe\u516d\u3001Li\/\/Li\u5bf9\u79f0\u7535\u6c60\u6027\u80fd\u6d4b\u8bd5<\/b><\/strong> \uff08b\uff09\u5206\u522b\u4f7f\u7528PP\u9694\u819c\u548c\u4e8eMOF\u57fa\u9694\u819c\u7684\u9502\u91d1\u5c5e\u5faa\u73af\u540e\u7684SEM\u56fe\u50cf\uff1b<\/p>\n \uff08c\uff09\u91c7\u7528MOF\u57fa\u9694\u819c\u7684Li\/\/Li\u5bf9\u79f0\u7535\u6c60\u5728\u7535\u6d41\u5bc6\u5ea6\u75310.5\u589e\u52a0\u81f320 mA cm-2<\/sup>\u65f6\u7684\u9502\u6c89\u79ef\/\u5265\u79bb\u884c\u4e3a\uff1b<\/p>\n \uff08d\uff09\u4e0d\u540c\u9694\u819c\u7ec4\u88c5\u7684Li\/\/Li\u5bf9\u79f0\u7535\u6c60\u5728\u9ad8\u6e29\u4e0b\u7684\u5faa\u73af\u7a33\u5b9a\u6027\u6bd4\u8f83\u3002<\/p>\n \u56fe\u4e03\u3001Li\/\/Cu\u7535\u6c60\u7684\u7535\u5316\u5b66\u6027\u80fd<\/b><\/strong> \uff08b\uff09\u57280.25mA cm-2<\/sup>\uff0c1.0 mA h cm-2<\/sup>\u7684\u6761\u4ef6\u4e0b\uff0cLi\u6c89\u79ef\/\u5265\u79bb\u7684\u5e93\u4f26\u6548\u7387\uff1b<\/p>\n \uff08c\uff09\u57281.0\u00a0M LiTFSI in DOL\/DME with 2% LiNO3<\/sub>\u7535\u89e3\u6db2\u586b\u5145\u7684NH2<\/sub>-MIL-125\uff08Ti\uff09\u9694\u819c\u4f53\u7cfb\u4e2d\uff0c\u7a33\u6001\u7535\u6d41\u7684\u6d4b\u91cf\u548c\u9502\u79bb\u5b50\u8fc1\u79fb\u6570\u3002<\/p>\n 3.\u5728\u9502\u91d1\u5c5e\u7535\u6c60\u4e2d\u7684\u5e94\u7528<\/b><\/strong><\/p>\n \u9664\u6291\u5236\u9502\u679d\u6676\u751f\u957f\u5916\uff0c\u5728\u4e00\u4e9b\u65b0\u578b\u53ef\u5145\u7535\u9502\u91d1\u5c5e\u7535\u6c60\u4e2d\uff0c\u5982\u7531\u63d2\u5c42\u6b63\u6781\u6750\u6599\u7ec4\u88c5\u7684\u9502\u91d1\u5c5e\u7535\u6c60\u3001\u9502\u786b\u7535\u6c60\u4ee5\u53ca\u9502\u6c27\u7535\u6c60\uff0c\u5177\u6709\u79bb\u5b50\u9009\u62e9\u6027\u7684MOF\u57fa\u819c\u8fd8\u53ef\u4ee5\u6291\u5236\u5176\u4ed6\u4e0d\u826f\u526f\u53cd\u5e94\u3002<\/p>\n 3.1 \u5177\u6709\u63d2\u5c42\u6b63\u6781\u6750\u6599\u7684\u9502\u91d1\u5c5e\u7535\u6c60<\/b><\/strong><\/p>\n \u56fe\u516b\u3001Li-Li<\/b><\/strong>4<\/b><\/sub><\/strong>Ti<\/b><\/strong>5<\/b><\/sub><\/strong>O<\/b><\/strong>12<\/b><\/sub><\/strong>\u7535\u6c60\u7684\u5faa\u73af\u6027\u80fd<\/b><\/strong> \uff08b\uff09\u7535\u6c60\u91c7\u7528MOF@GO\u57fa\u7535\u89e3\u8d28\u7684\u5145\/\u653e\u7535\u66f2\u7ebf\u3002<\/p>\n 3.2 \u9502\u786b\u7535\u6c60<\/b><\/strong><\/p>\n \u56fe\u4e5d\u3001Li-S\u7535\u6c60\u91c7\u7528\u4e0d\u540c\u9694\u819c\u7684\u793a\u610f\u56fe<\/b><\/strong> \uff08b\uff09\u5177\u6709\u9ad8\u5ea6\u6709\u5e8f\u591a\u5b54\u7ed3\u6784\u7684MOF@PVDF-HFP\u9694\u819c\u4e0d\u4ec5\u53ef\u4ee5\u963b\u6321\u591a\u786b\u79bb\u5b50\u7684\u6269\u6563\uff0c\u8fd8\u80fd\u591f\u5f15\u5bfc\u9502\u79bb\u5b50\u7684\u5747\u5300\u6c89\u79ef\uff0c\u4ece\u800c\u6291\u5236\u9502\u679d\u6676\u7684\u751f\u957f\u3002<\/p>\n \u56fe\u5341\u3001Li-S\u7535\u6c60\u7684\u5faa\u73af\u6027\u80fd<\/b><\/strong> \uff08b\uff09\u4f7f\u7528\u4e0d\u540c\u9694\u819c\u7684Li-S\u7535\u6c60\u7684\u5faa\u73af\u6027\u80fd\uff1b<\/p>\n \uff08c\uff09\u4f7f\u7528MOF@PVDF-HFP\/GO\u9694\u819c\u7684Li-S\u7535\u6c60\u5728\u4e0d\u540c\u786b\u8f7d\u91cf\u4e0b\u7684\u5faa\u73af\u6027\u80fd\uff1b<\/p>\n \uff08d\uff09\u4f7f\u7528MOF@PVDF-HFP\u9694\u819c\u7ec4\u88c5\u7684\u67d4\u6027Li-S\u8f6f\u5305\u7535\u6c60\u7684\u5faa\u73af\u6027\u80fd\uff1b<\/p>\n \uff08e\uff09MOF@GO\u9694\u819c\u5728\u5728\u5faa\u73af\u524d\u540e\u7684FT-IR\u5149\u8c31\u3002<\/p>\n 3.3 \u9502\u6c27\u7535\u6c60<\/b><\/strong><\/p>\n \u56fe\u5341\u4e00\u3001\u57fa\u4e8eMOF\u9694\u819c\u7ec4\u88c5\u7684Li-O<\/b><\/strong>2<\/b><\/sub><\/strong>\u6027\u80fd<\/b><\/strong> \uff08b\uff09Li-O2<\/sub>\u7535\u6c60\u5728\u4e0d\u540c\u60c5\u51b5\u4e0b\u7684\u7535\u538b\u5206\u5e03\uff0c\u622a\u6b62\u5bb9\u91cf\u8bbe\u7f6e\u4e3a0 mAh\uff0c\u622a\u6b62\u7535\u538b\u8303\u56f4\u57282.0-4.5 V\u8303\u56f4\u5185\uff0c\u7535\u6d41\u5bc6\u5ea6\u4e3a1000 mA g-1<\/sup>\uff1b<\/p>\n \uff08c\uff09\u4e0d\u540c\u9502-\u6c27\u7535\u6c60\u4e2d\u6b63\u6781\u7684\u539f\u4f4d\u62c9\u66fc\u5149\u8c31\uff1b<\/p>\n \uff08d\uff09\u4f7f\u7528MOF\u57fa\u9694\u819c\u7ec4\u88c5\u7684Li-O2<\/sub>\u8f6f\u5305\u7535\u6c60\u57282 mA\u7535\u6d41\u500d\u7387\uff08\u622a\u6b62\u5bb9\u91cf20 mA h\uff09\u4e0b\u7684\u6027\u80fd\u3002<\/p>\n 4.\u5728\u9502\u79bb\u5b50\u7535\u6c60\u4e2d\u7684\u5e94\u7528<\/b><\/strong><\/p>\n \u56fe\u5341\u4e8c\u3001\u7ec4\u5408\u7535\u89e3\u8d28\u4f53\u7cfb<\/b><\/strong> \uff08b\uff09\u91c7\u7528MOF\u57fa\u9694\u819c\u7684\u6e17\u900f\u6d4b\u8bd5\uff0c\u7528\u4e8e\u8bc4\u4f30\u9694\u819c\u5bf9\u53cc\u7535\u89e3\u8d28\u7684\u963b\u6321\u6548\u679c\uff1b<\/p>\n \uff08c\uff09\u91c7\u7528\u7ec4\u5408\u7535\u89e3\u6db2\u7684\u5145\u653e\u7535\u66f2\u7ebf\uff1b<\/p>\n \uff08d\uff09\u5728\u5168\u7535\u6c60\u4e2d\u5f15\u5165MOF\u57fa\u9694\u819c\/\u7ec4\u5408\u7535\u89e3\u8d28\u7684\u957f\u5faa\u73af\u6027\u80fd\u3002<\/p>\n 5.\u5728\u5176\u4ed6\u53ef\u5145\u7535\u7535\u6c60\u4e2d\u7684\u6f5c\u529b<\/b><\/strong><\/p>\n 5.1 \u94a0\u79bb\u5b50\u7535\u6c60<\/b><\/strong><\/p>\n \u56fe\u5341\u4e09\u3001\u94a0\u6c89\u79ef\/\u5265\u79bb\u539f\u7406\u56fe<\/b><\/strong> \uff08b\uff09\u5f15\u5165\u5177\u6709\u5747\u5300\u5b54\u5f84\u7684MOF\u57fa\u9694\u819c\uff0c\u53ef\u4ee5\u83b7\u5f97\u5747\u5300\u7684Na+<\/sup>\u901a\u91cf\uff0c\u4ece\u6839\u672c\u4e0a\u89e3\u51b3Na\u679d\u6676\u95ee\u9898\uff0c\u5b9e\u73b0\u7a33\u5b9a\u7684Na\u79bb\u5b50\u6c89\u79ef\u3002<\/p>\n 5.2 \u6709\u673a\u6c27\u5316\u8fd8\u539f\u6db2\u6d41\u7535\u6c60<\/b><\/strong><\/p>\n \u56fe\u5341\u56db\u3001\u4f7f\u7528\u5177\u6709\u79bb\u5b50\u9009\u62e9\u6027\u7684MOF\u57fa\u9694\u819c\u7684\u6709\u673a\u6c27\u5316\u8fd8\u539f\u6db2\u6d41\u7535\u6c60\u7684\u7b80\u5316\u793a\u610f\u56fe<\/b><\/strong> 5.3 \u6db2\u4f53\u8d1f\u6781\u7535\u6c60<\/b><\/strong><\/p>\n \u56fe\u5341\u4e94\u3001\u4f7f\u7528\u5177\u6709\u79bb\u5b50\u9009\u62e9\u6027MOF\u57fa\u9694\u819c\u7684\u6db2\u4f53-\u8d1f\u6781\u7535\u6c60\u7684\u7b80\u5316\u793a\u610f\u56fe<\/b><\/strong> <\/p>\n \u3010\u5c0f\u7ed3\u3011<\/b><\/strong><\/p>\n \u603b\u7684\u6765\u770b\uff0c\u672c\u6587\u603b\u7ed3\u4e86\u5404\u79cd\u6784\u5efa\u9ad8\u8d28\u91cfMOF\u819c\u7684\u5148\u8fdb\u624b\u6bb5\uff0c\u5176\u4e2d\u5305\u62ec\u81ea\u652f\u6491MOF\u819c\uff0c MOF\u6d82\u5c42\/\u57fa\u5e95\u819c\u4ee5\u53caMOF\u57fa\u590d\u5408\u819c\u3002\u540c\u65f6\uff0c\u6982\u8ff0\u4e86MOF\u57fa\u819c\u5728\u9502\u91d1\u5c5e\u7535\u6c60\u548c\u9502\u79bb\u5b50\u7535\u6c60\u7cfb\u7edf\u4e2d\u7684\u6700\u65b0\u7814\u7a76\u8fdb\u5c55\u3002\u867d\u7136\u5728\u6784\u5efa\u57fa\u4e8eMOF\u7684\u819c\u7684\u65b9\u9762\u5df2\u7ecf\u53d6\u5f97\u4e86\u91cd\u5927\u8fdb\u5c55\uff0c\u4f46\u5236\u5907\u9ad8\u8d28\u91cfMOF\u819c\u7684\u6280\u672f\u4ecd\u6709\u5f85\u8fdb\u4e00\u6b65\u63d0\u9ad8\u3002\u4ece\u5b9e\u9645\u5e94\u7528\u7684\u89d2\u5ea6\uff0c\u672c\u6587\u63d0\u51fa\u4e86\u51e0\u70b9\u5efa\u8bae\uff1a<\/p>\n \u00a0 \u00a0 \u00a0\uff081\uff09\u5230\u76ee\u524d\u4e3a\u6b62\uff0c\u5df2\u7ecf\u901a\u8fc7\u8bbe\u8ba1\u4e0d\u540c\u7684\u65e0\u673a\u91d1\u5c5e\u79bb\u5b50\/\u7c07\u548c\u6709\u673a\u7269\u7684\u8fde\u63a5\u65b9\u5f0f\u6210\u529f\u5236\u5907\u4e8620000\u591a\u79cdMOFs\uff0c\u4f46\u53ea\u6709\u51e0\u79cdMOFs\u88ab\u7528\u4e8e\u5236\u5907\u7535\u6c60\u9694\u819c\uff0c\u8fd9\u662f\u7531\u4e8eMOF\u4e2d\u7684\u4e00\u4e9b\u91d1\u5c5e\u79bb\u5b50\u53ef\u80fd\u4f1a\u4e0e\u7535\u6c60\u4e2d\u7684\u6d3b\u6027\u7269\u8d28\u53d1\u751f\u53cd\u5e94\uff0c\u5bfc\u81f4\u7535\u6c60\u5bb9\u91cf\u7684\u5feb\u901f\u8870\u51cf\u3002\u57fa\u4e8e\u6b64\uff0cMOF\u4e0e\u5404\u79cd\u7535\u6c60\u7684\u517c\u5bb9\u6027\u5e94\u8be5\u5728\u8bbe\u8ba1MOF\u819c\u4e4b\u524d\u4ed4\u7ec6\u8003\u5bdf\uff0c\u901a\u8fc7\u9002\u5f53\u9884\u5904\u7406\u53ef\u4ee5\u6709\u6548\u907f\u514d\u4e0d\u826f\u53cd\u5e94\uff0c\u4fdd\u8bc1\u7535\u6c60\u6027\u80fd\uff1b<\/p>\n \u00a0 \u00a0 \u00a0\uff082\uff09\u4e3a\u4e86\u5b9e\u73b0\u53ef\u5145\u7535\u9502\u7535\u6c60\u7684\u9ad8\u80fd\u91cf\u5bc6\u5ea6\uff0c\u5f15\u5165\u7684\u57fa\u4e8eMOF\u7684\u819c\u5e94\u8be5\u5c3d\u53ef\u80fd\u7684\u8f7b\uff0c\u4ee5\u51cf\u5c11\u975e\u6d3b\u6027\u7269\u8d28\u5bf9\u4e8e\u7535\u6c60\u80fd\u91cf\u5bc6\u5ea6\u7684\u5f71\u54cd\uff1b<\/p>\n \u00a0 \u00a0 \u00a0\uff083\uff09\u79bb\u5b50\u7535\u5bfc\u7387\u8861\u91cf\u9694\u819c\u6027\u80fd\u662f\u4e00\u4e2a\u91cd\u8981\u56e0\u7d20\u3002\u819c\u9002\u5f53\u7684\u5b54\u9699\u7387\u548c\u826f\u597d\u7684\u7535\u89e3\u8d28\u6da6\u6e7f\u6027\u6709\u76ca\u63d0\u9ad8\u5bf9\u7535\u89e3\u6db2\u5438\u6536\u548c\u5b58\u50a8\u3002\u6b64\u5916\uff0c\u9694\u819c\u7684\u539a\u5ea6\u4e5f\u5f88\u5927\u5f71\u54cd\u5176\u79bb\u5b50\u7535\u5bfc\u7387\uff0c\u901a\u8fc7\u6dfb\u52a0\u5408\u9002\u7684\u6dfb\u52a0\u5242\u4e5f\u6709\u52a9\u4e8e\u5f62\u6210\u9ad8\u79bb\u5b50\u7535\u5bfc\u7387\u7684MOF\u819c\uff1b<\/p>\n \u00a0 \u00a0 \uff084\uff09\u867d\u7136\u4f9d\u9760\u76ee\u524d\u7684\u6280\u672f\u53ef\u4ee5\u83b7\u5f97\u7ed3\u6676\u5ea6\u9ad8\uff0c\u7d27\u5bc6\u5806\u79ef\u548c\u5747\u5300\u5206\u5e03MOF\u6676\u4f53\uff0c\u4f46\u5176\u529b\u5b66\u6027\u80fd\u4ecd\u7136\u5f88\u96be\u6ee1\u8db3\u6076\u52a3\u7684\u5de5\u4f5c\u73af\u5883\u3002\u6b64\u5916\uff0c\u590d\u6742\u7684\u5408\u6210\u8fc7\u7a0b\u53ef\u4ee5\u5728\u5b9e\u9a8c\u5ba4\u4e2d\u5f88\u5bb9\u6613\u5730\u5b9e\u73b0\uff0c\u4f46\u5728\u5de5\u5382\u5b9e\u73b0\u5927\u89c4\u6a21\u751f\u4ea7\u4ecd\u7136\u9762\u4e34\u6311\u6218\uff1b<\/p>\n \u00a0 \u00a0 \uff085\uff09\u5e94\u8be5\u66f4\u6df1\u5165\u5730\u4e86\u89e3\u5728\u53ef\u5145\u7535\u7535\u6c60\u4e2d\uff0cMOF\u4f5c\u4e3a\u7535\u89e3\u8d28\u6216\u79bb\u5b50\u7b5b\u7684\u673a\u7406\u53ca\u5176\u7535\u5316\u5b66\u76f8\u4e92\u4f5c\u7528\u3002<\/p>\n \u603b\u7684\u6765\u8bf4\uff0c\u867d\u7136MOF\u819c\u7684\u6f5c\u80fd\u4ecd\u7136\u9700\u8981\u7ee7\u7eed\u63a2\u7d22\u548c\u6316\u6398\uff0c\u4f46\u901a\u8fc7\u672a\u6765\u8fdb\u4e00\u6b65\u7684\u53d1\u5c55\u548c\u521b\u65b0\uff0c\u6709\u671b\u5e94\u7528\u4e8e\u5148\u8fdb\u7684\u5b58\u50a8\u7cfb\u7edf\u3002<\/p>\n \u3010\u56e2\u961f\u4ecb\u7ecd\u3011<\/b><\/strong> \u5468\u8c6a\u614e\uff1a\u5357\u4eac\u5927\u5b66\u6559\u6388\uff0c\u56fd\u5bb6\u201c\u5343\u4eba\u8ba1\u5212\u201d\u7279\u8058\u4e13\u5bb6\uff0c\u957f\u6c5f\u5b66\u8005\u3001973\u9996\u5e2d\u79d1\u5b66\u5bb6\uff0c\u517c\u4efb\u65e5\u672c\u56fd\u7acb\u4ea7\u4e1a\u6280\u672f\u7efc\u5408\u7814\u7a76\u6240\uff08AIST\uff09\u9996\u5e2d\u7814\u7a76\u5458\u548c\u7b51\u6ce2\u5927\u5b66\u6559\u6388\u3002\u4ece\u4e8b\u9502\u79bb\u5b50\u7535\u6c60\uff0c\u94a0\u79bb\u5b50\u7535\u6c60\uff0c\u9502\u7a7a\u6c14\u7535\u6c60\uff0c\u9502\u786b\u7535\u6c60\uff0c\u9502\u6db2\u6d41\u7535\u6c60\u548c\u56fa\u6001\u7535\u6c60\u7684\u7814\u7a76\u548c\u5f00\u53d1\u3002\u5728Nat. Mater.; Nat. Energy, Nat. Commun. (5\u7bc7); Joule (5\u7bc7); Angew. Chem. Int. Ed.(13\u7bc7); Energy Environ. Sci. (26\u7bc7); J. Am. Chem. Soc. (5\u7bc7); Adv. Mater. (16\u7bc7); Adv. Energy Mater.\u00a0(18\u7bc7) \u7b49\u56fd\u9645\u9876\u7ea7\u5b66\u672f\u671f\u520a\u4e0a\u53d1\u8868\u8bba\u6587400 \u4f59\u7bc7\uff0c\u4ed6\u5f15\u8d8533350 \u4f59\u6b21\uff0cH\u56e0\u5b5097\u3002<\/p>\n \u8d3a\u4ea6\u67cf : 2016\u5e747\u6708\u6bd5\u4e1a\u4e8e\u9655\u897f\u5e08\u8303\u5927\u5b66\uff0c\u83b7\u5de5\u5b66\u7855\u58eb\u5b66\u4f4d\uff1b\u540c\u5e7410\u6708\u8fdb\u5165\u65e5\u672c\u7b51\u6ce2\u5927\u5b66\u5468\u8c6a\u614e\u6559\u6388\u8bfe\u9898\u7ec4\u653b\u8bfb\u535a\u58eb\u5b66\u4f4d\u3002\u4e3b\u8981\u7814\u7a76\u9886\u57df\u4e3a\u5f00\u53d1\u529f\u80fd\u6027\u9694\u819c\u5e94\u7528\u4e8e\u5404\u79cd\u57fa\u4e8e\u91d1\u5c5e\u9502\u8d1f\u6781\u7684\u9502-\u91d1\u5c5e\u7535\u6c60\u3002\u5148\u540e\u4ee5\u7b2c\u4e00\u4f5c\u8005\u5728\u80fd\u6e90\u6750\u6599\u53ca\u7535\u5316\u5b66\u9886\u57df\u7684\u56fd\u9645\u9ad8\u6c34\u5e73\u520a\u7269\u5982Energy Environment Sci.\u548c Adv. Energy Mater. \u7b49\u671f\u520a\u4e0a\u53d1\u8868\u591a\u7bc7\u6587\u7ae0\u3002<\/p>\n \u3010<\/b>\u56e2\u961f\u5728\u8be5\u9886\u57df\u5de5\u4f5c\u6c47\u603b\u3011<\/b><\/strong><\/p>\n<\/b><\/strong><\/p>\n
<\/b><\/strong>\uff08a\uff09\u5728\u542b\u6709\u91d1\u5c5e\u79bb\u5b50\u6c34\u6eb6\u6db2\u548c\u6709\u673a\u914d\u4f53\u6eb6\u6db2\u7684\u53cc\u76f8\u754c\u9762\u5408\u6210MOF\u5c42\uff1b<\/p>\n
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\uff08a\uff09\u91c7\u7528MOF@PVDF-HFP\u9694\u819c\u7ec4\u88c5\u7684\u53ef\u89c6\u5316H\u578bLi-S\u7535\u6c60\u5728\u653e\u7535\u8fc7\u7a0b\u4e2d\u7684\u5149\u5b66\u56fe\u50cf\uff1b<\/p>\n
\uff08a\uff09\u5229\u7528MOF\u57fa\u9694\u819c\u5f00\u53d1\u53cc\u6c27\u5316\u8fd8\u539f\u4ecb\u8d28\u7b56\u7565\u7684\u793a\u610f\u56fe\uff1b<\/p>\n
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