{"id":175196,"date":"2019-05-17T12:00:49","date_gmt":"2019-05-17T04:00:49","guid":{"rendered":"\/\/m.iemloyee.com\/?p=175196"},"modified":"2019-05-17T00:01:38","modified_gmt":"2019-05-16T16:01:38","slug":"%e4%b8%ad%e7%89%a9%e9%99%a2%e5%8c%96%e5%b7%a5%e6%9d%90%e6%96%99%e7%a0%94%e7%a9%b6%e6%89%80%e5%bc%a0%e6%96%87%e5%8d%8e%e5%91%a8%e6%96%8cacs-nano%ef%bc%9a%e9%94%91%e9%87%91%e5%b1%9e%e7%ba%b3","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=175196","title":{"rendered":"\u4e2d\u7269\u9662\u5316\u5de5\u6750\u6599\u7814\u7a76\u6240\u5f20\u6587\u534e&#038;\u5468\u658cACS\u00a0 Nano\uff1a\u9511\u91d1\u5c5e\u7eb3\u7c73\u7ba1\u7684\u7535\u7f6e\u6362\u53cd\u5e94\u6cd5\u5236\u5907\u53ca\u5176\u50a8\u94a0\u6027\u80fd\u7684\u7814\u7a76"},"content":{"rendered":"<p>\u3010\u5f15\u8a00\u3011<\/p>\n<p>\u76ee\u524d\u5f88\u591a\u7814\u7a76\u5b66\u8005\u5728\u81f4\u529b\u4e8e\u5f00\u53d1\u94a0\u79bb\u5b50\u7535\u6c60\u7684\u500d\u7387\u6027\u80fd\u9ad8\u3001\u5faa\u73af\u7a33\u5b9a\u6027\u5f3a\u7684\u8d1f\u6781\u6750\u6599\u3002\u5728\u8fd9\u4e9b\u6750\u6599\u4e2d\uff0c\u9511\u91d1\u5c5e\u8d1f\u6781\u7531\u4e8e\u7406\u8bba\u5bb9\u91cf\u9ad8\u3001\u5bfc\u7535\u6027\u5f3a\u3001\u5de5\u4f5c\u7535\u538b\u5408\u9002\u800c\u5177\u6709\u5f88\u5927\u7684\u5e0c\u671b\u3002\u4f46\u662f\uff0c\u5b83\u5728\u5d4c\u94a0\/\u8131\u94a0\u8fc7\u7a0b\u4e2d\u4f53\u79ef\u53d8\u5316\u5de8\u5927\uff0c\u4ece\u800c\u53d1\u751f\u4e25\u91cd\u7684\u7c89\u5316\u73b0\u8c61\uff0c\u5bfc\u81f4\u5bb9\u91cf\u8fc5\u901f\u8870\u51cf\u3002\u4e00\u7ef4\u7ba1\u72b6\u7ed3\u6784\u80fd\u51cf\u8f7b\u5b83\u7684\u4f53\u79ef\u53d8\u5316\u7684\u95ee\u9898\u3002\u6700\u8fd1\uff0c\u5927\u91cf\u9511\u91d1\u5c5e\u7ba1\u72b6\u590d\u5408\u7535\u6781\u8868\u73b0\u51fa\u4e0d\u9519\u7684\u500d\u7387\u6027\u80fd\u548c\u957f\u671f\u5faa\u73af\u6027\u80fd\uff0c\u4f8b\u5982\u53cc\u58c1Sb@TiO<sub>2-x<\/sub>\u7eb3\u7c73\u7ba1\u548cSb@C\u540c\u8f74\u7eb3\u7c73\u7ba1\u3002\u7136\u800c\uff0c\u548c\u9511\u91d1\u5c5e\u76f8\u6bd4\uff0c\u5f15\u5165\u78b3\u6216\u8005TiO<sub>2-x<\/sub>\u4f1a\u964d\u4f4e\u590d\u5408\u7535\u6781\u7684\u6bd4\u5bb9\u91cf\u3002\u56e0\u6b64\u9511\u91d1\u5c5e\u7eb3\u7c73\u7ba1\u662f\u8f83\u597d\u7684\u9009\u62e9\u3002<\/p>\n<p>\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/p>\n<p>\u4e2d\u56fd\u5de5\u7a0b\u7269\u7406\u7814\u7a76\u9662\u5316\u5de5\u6750\u6599\u7814\u7a76\u6240\u7684\u7814\u7a76\u5458\u5f20\u6587\u534e\u548c\u535a\u58eb\u540e\u5468\u658c\uff08\u5171\u540c\u901a\u8baf\u4f5c\u8005\uff09\u7b49\u4eba\u5229\u7528\u7535\u7f6e\u6362\u53cd\u5e94\u5236\u5907\u4e86\u7ed3\u6784\u89c4\u6574\u7684\u9511\u91d1\u5c5e\u7eb3\u7c73\u7ba1\u3002\u4ed6\u4eec\u901a\u8fc7\u4e00\u7cfb\u5217\u8868\u5f81\u7684\u624b\u6bb5\u786e\u5b9a\u8be5\u53cd\u5e94\u7684\u4e2d\u95f4\u4ea7\u7269\u662f\u00a0Cu<sub>2<\/sub>Sb\u3002\u9511\u91d1\u5c5e\u7eb3\u7c73\u7ba1\u4f5c\u4e3a\u94a0\u79bb\u5b50\u7535\u6c60\u7684\u8d1f\u6781\u6750\u6599\uff0c\u5728\u7535\u6d41\u5bc6\u5ea6\u4e3a10 A g<sup>-1<\/sup>\u65f6\u7684\u50a8\u94a0\u5bb9\u91cf\u4e3a286 mAh g<sup>-1<\/sup>\uff0c\u5728\u7535\u6d41\u5bc6\u5ea6\u4e3a1.0 A g<sup>-1<\/sup>\u7684\u6761\u4ef6\u4e0b\u8fdb\u884c6000\u6b21\u5faa\u73af\u540e\u4fdd\u7559\u4e8674%\u7684\u5bb9\u91cf\u3002\u800c\u4e14\uff0c\u9511\u91d1\u5c5e\u7eb3\u7c73\u7ba1\u548cNa<sub>3<\/sub>(VOPO<sub>4<\/sub>)<sub>2<\/sub>F \u5206\u522b\u4f5c\u4e3a\u8d1f\u6781\u548c\u6b63\u6781\u7684\u5168\u7535\u6c60\u7684\u80fd\u91cf\u5bc6\u5ea6\u9ad8\u8fbe252 Wh kg<sup>-1<\/sup>\uff0c\u8f93\u51fa\u7535\u538b\u4e3a2.7V\u3002\u4e0a\u8ff0\u6210\u679c\u4e8e\u8fd1\u65e5\u53d1\u8868\u5728ACS\u00a0 Nano\u4e0a\u3002<\/p>\n<p>\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/p>\n<p>Figure 1. a)\u9511\u91d1\u5c5e\u7eb3\u7c73\u7ba1\u7684\u5408\u6210\u65b9\u6cd5\u7684\u793a\u610f\u56fe\uff1bb) \u94dc\u91d1\u5c5e\u7eb3\u7c73\u7ebf\u7684TEM\u56fe\uff1b c)\u9511\u91d1\u5c5e\u7eb3\u7c73\u7ba1\u7684XRD\u56fe\uff1b d,e)\u9511\u91d1\u5c5e\u7eb3\u7c73\u7ba1\u7684 TEM\u56fe\uff1bf,g) \u9511\u91d1\u5c5e\u7eb3\u7c73\u7ba1\u7684 SEM\u56fe\uff1b h) \u9511\u91d1\u5c5e\u7eb3\u7c73\u7ba1\u7684HRTEM\u56fe\uff1b i) \u9511\u91d1\u5c5e\u7eb3\u7c73\u7ba1\u7684\u5143\u7d20\u5206\u5e03\u548c\u80fd\u91cf\u8272\u6563X\u5c04\u7ebf\u8c31\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-175288\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2019\/05\/QQ\u622a\u56fe20190511143553.jpg\" alt=\"\" width=\"580\" height=\"517\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2019\/05\/QQ\u622a\u56fe20190511143553.jpg 580w, \/\/m.iemloyee.com\/wp-content\/uploads\/2019\/05\/QQ\u622a\u56fe20190511143553-300x267.jpg 300w\" sizes=\"(max-width: 580px) 100vw, 580px\" \/><\/p>\n<p>Figure 2. a) CuCl-DMSO\u6eb6\u6db2\u3001CuCl<sub>2<\/sub>-DMSO\u6eb6\u6db2\u548c\u7535\u7f6e\u6362\u53cd\u5e94\u540e\u6536\u96c6\u7684\u4e0a\u6e05\u6db2\u7684UV-vis\u8c31\u56fe\uff1bb) CuCl-DMSO\u6eb6\u6db2\u3001CuCl<sub>2<\/sub>-DMSO\u6eb6\u6db2\u548c\u7535\u7f6e\u6362\u53cd\u5e94\u540e\u6536\u96c6\u7684\u4e0a\u6e05\u6db2\u7684EPR\u8c31\u56fe\uff1b c) \u4e0d\u540c\u53cd\u5e94\u65f6\u95f4\u7684\u7535\u7f6e\u6362\u53cd\u5e94\u540e\u7684\u4ea7\u7269\u7684XRD\u8c31\u56fe \uff1b d)\u00a0Cu\/Sb \u4e0d\u540c\u7684\u6761\u4ef6\u4e0b\u5236\u5907\u7684\u4ea7\u7269\u7684XRD\u8c31\u56fe\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-175291\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2019\/05\/QQ\u622a\u56fe20190511143611.jpg\" alt=\"\" width=\"547\" height=\"524\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2019\/05\/QQ\u622a\u56fe20190511143611.jpg 547w, \/\/m.iemloyee.com\/wp-content\/uploads\/2019\/05\/QQ\u622a\u56fe20190511143611-300x287.jpg 300w\" sizes=\"(max-width: 547px) 100vw, 547px\" \/><\/p>\n<p>Figure 3.a)\u9511\u91d1\u5c5e\u7eb3\u7c73\u7ba1\u8d1f\u6781\u7684CV\u66f2\u7ebf\uff1bb) \u9511\u91d1\u5c5e\u7eb3\u7c73\u7ba1\u8d1f\u6781\u5728\u7b2c1\u30012\u30015\u300110\u300125\u300150\u4e2a\u5faa\u73af\u7684\u5145\u653e\u7535\u66f2\u7ebf\uff1bc) \u9511\u91d1\u5c5e\u7eb3\u7c73\u7ba1\u8d1f\u6781\u3001Cu<sub>2<\/sub>Sb@Sb\u7eb3\u7c73\u7ba1\u8d1f\u6781\u548cCu@Cu<sub>2<\/sub>Sb\u7eb3\u7c73\u7ba1\u8d1f\u6781\u7684\u500d\u7387\u6027\u80fd\uff1b d,e) \u9511\u91d1\u5c5e\u7eb3\u7c73\u7ba1\u8d1f\u6781\u3001Cu<sub>2<\/sub>Sb@Sb\u7eb3\u7c73\u7ba1\u8d1f\u6781\u548cCu@Cu<sub>2<\/sub>Sb\u7eb3\u7c73\u7ba1\u8d1f\u6781\u7684\u5faa\u73af\u6027\u80fd<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-175290\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2019\/05\/QQ\u622a\u56fe20190511143624.jpg\" alt=\"\" width=\"507\" height=\"508\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2019\/05\/QQ\u622a\u56fe20190511143624.jpg 507w, \/\/m.iemloyee.com\/wp-content\/uploads\/2019\/05\/QQ\u622a\u56fe20190511143624-150x150.jpg 150w, \/\/m.iemloyee.com\/wp-content\/uploads\/2019\/05\/QQ\u622a\u56fe20190511143624-300x300.jpg 300w\" sizes=\"(max-width: 507px) 100vw, 507px\" \/><\/p>\n<p>Figure 4. a) Na<sub>3<\/sub>(VOPO<sub>4<\/sub>)<sub>2<\/sub>F\u548c\u9511\u91d1\u5c5e\u7eb3\u7c73\u7ba1\u7ec4\u6210\u7684\u94a0\u79bb\u5b50\u5168\u7535\u6c60\u7684\u793a\u610f\u56fe\uff1bb)\u5168\u7535\u6c60\u7684\u6052\u7535\u6d41\u5145\u653e\u7535\u66f2\u7ebf\uff1bc)\u5168\u7535\u6c60\u7684\u5faa\u73af\u6027\u80fd\uff1bd) \u5168\u7535\u6c60\u7684Ragone\u56fe<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-175289\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2019\/05\/QQ\u622a\u56fe20190511143841.jpg\" alt=\"\" width=\"600\" height=\"464\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2019\/05\/QQ\u622a\u56fe20190511143841.jpg 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2019\/05\/QQ\u622a\u56fe20190511143841-300x232.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>\u3010\u5c0f\u7ed3\u3011<\/p>\n<p>\u4f5c\u8005\u56e2\u961f\u901a\u8fc7\u7535\u7f6e\u6362\u53cd\u5e94\u5236\u5907\u7684\u9511\u91d1\u5c5e\u7eb3\u7c73\u7ba1\u4f5c\u4e3a\u94a0\u79bb\u5b50\u7535\u6c60\u7684\u8d1f\u6781\u6750\u6599\uff0c\u8868\u73b0\u51fa\u4f18\u5f02\u7684\u50a8\u94a0\u6027\u80fd\u3001\u500d\u7387\u6027\u80fd\u548c\u5faa\u73af\u7a33\u5b9a\u6027\u3002\u800c\u4e14\uff0c\u9511\u91d1\u5c5e\u7eb3\u7c73\u7ba1\u548cNa<sub>3<\/sub>(VOPO<sub>4<\/sub>)<sub>2<\/sub>F\u7ec4\u6210\u7684\u94a0\u79bb\u5b50\u5168\u7535\u6c60\u5177\u6709\u9ad8\u80fd\u91cf\u5bc6\u5ea6\u548c\u9ad8\u8f93\u51fa\u7535\u538b\u7684\u7279\u70b9\u3002\u8be5\u56e2\u961f\u5c06\u9511\u91d1\u5c5e\u7eb3\u7c73\u7ba1\u51fa\u8272\u7684\u50a8\u94a0\u6027\u80fd\u5f52\u56e0\u4e8e\u5176\u4e00\u7ef4\u7684\u3001\u4e2d\u7a7a\u7684\u3001\u5177\u6709\u8584\u58c1\u7684\u7ed3\u6784\u3002\u8fd9\u9879\u6210\u679c\u4e3a\u9664\u4e86\u9511\u4e4b\u5916\u7684\u5176\u5b83\u5408\u91d1\u578b\u91d1\u5c5e\u7684\u7eb3\u7c73\u7ba1\u5e7f\u6cdb\u5e94\u7528\u4e8e\u94a0\u79bb\u5b50\u7535\u6c60\u7684\u8d1f\u6781\u6750\u6599\u63d0\u4f9b\u4e86\u673a\u9047\u3002<\/p>\n<p>\u6587\u732e\u94fe\u63a5\uff1a<strong><a title=\"Galvanic Replacement Synthesis of Highly Uniform Sb Nanotubes: Reaction Mechanism and Enhanced Sodium Storage Performance\" href=\"https:\/\/www.x-mol.com\/paperRedirect\/5674516\" target=\"_blank\" rel=\"noopener\">Galvanic Replacement Synthesis of Highly Uniform Sb Nanotubes: Reaction Mechanism and Enhanced Sodium Storage Performance<\/a><\/strong>\uff08ACS Nano\uff0c2019\uff0cDOI:10.1021\/acsnano.9b01660\u00a0\uff09<\/p>\n<p>\u672c\u6587\u7531kv1004\u4f9b\u7a3f\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u3010\u5f15\u8a00\u3011 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