{"id":175010,"date":"2019-05-13T06:23:50","date_gmt":"2019-05-12T22:23:50","guid":{"rendered":"\/\/m.iemloyee.com\/?p=175010"},"modified":"2019-05-12T22:24:41","modified_gmt":"2019-05-12T14:24:41","slug":"%e4%b8%8a%e6%b5%b7%e5%a4%a7%e5%ad%a6macromolecules%ef%bc%9a%e5%85%89%e6%8e%a7%e9%99%8d%e8%a7%a3%e5%9e%8b%e6%b8%a9%e5%ba%a6%e6%95%8f%e6%84%9f%e7%8e%af%e7%b3%8a%e7%b2%be%e8%81%9a%e8%bd%ae%e7%83%b7","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=175010","title":{"rendered":"\u4e0a\u6d77\u5927\u5b66Macromolecules\uff1a\u5149\u63a7\u964d\u89e3\u578b\u6e29\u5ea6\u654f\u611f\u73af\u7cca\u7cbe\u805a\u8f6e\u70f7"},"content":{"rendered":"<p><strong>\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n<p>\u672c\u6587\u4ecb\u7ecd\u4e86\u4e00\u7c7b\u5149\u63a7\u964d\u89e3\u578b\u70f7\u6c27\u919a\u5316\u73af\u7cca\u7cbe\u805a\u8f6e\u70f7\uff08PRX\uff09\u7684\u5408\u6210\u53ca\u6027\u80fd\u8868\u5f81\u3002\u8be5\u7c7b\u805a\u8f6e\u70f7\u5728\u6c34\u76f8\u4e2d\u5747\u8868\u73b0\u51fa\u7279\u5f81\u7684\u6e29\u5ea6\u654f\u611f\u884c\u4e3a\uff1a\u76f8\u53d8\u8fc5\u901f\u4e14\u8fc7\u7a0b\u53ef\u9006\uff0c\u6ede\u540e\u73b0\u8c61\u5c0f\u4e14\u76f8\u53d8\u6e29\u5ea6\u53ef\u8c03\uff0c\u8fd9\u4e0e\u4e4b\u524d\u62a5\u9053\u7684\u7532\u57fa\u5316PRX\u660e\u663e\u4e0d\u540c\u3002\u57fa\u4e8e\u673a\u68b0\u4e92\u9501\u7ed3\u6784\uff0cPRX\u5728\u6eb6\u6db2\u4e2d\u7a33\u5b9a\uff0c\u4f46\u5f53\u5c01\u7aef\u57fa\u56e2\u88abUV\u88c2\u89e3\u540e\u53ef\u5b8c\u5168\u964d\u89e3\u6210\u4eb2\u6c34\u6027\u7ec4\u5206\uff0cPRX\u7684\u6e29\u654f\u884c\u4e3a\u4e5f\u968f\u4e4b\u6d88\u5931\u3002\u6b64\u5916\uff0c\u70f7\u6c27\u919a\u5316\u805a\u8f6e\u70f7\u5728\u76f8\u53d8\u6e29\u5ea6\u4ee5\u4e0a\u805a\u96c6\u5f62\u6210\u5fae\u7c73\u7ea7\u7403\u72b6\u805a\u96c6\u4f53\uff0c\u4f46\u5728\u51b7\u5374\u6216UV\u7167\u5c04\u4e0b\u5feb\u901f\u89e3\u805a\u3002\u8fd9\u79cd\u53cc\u63a7\u7684\u805a\u96c6\u4e0e\u89e3\u805a\u96c6\u884c\u4e3a\u53ef\u7528\u4e8e\u5bf9\u758f\u6c34\u6027\u5ba2\u4f53\u5206\u5b50\u7684\u53ef\u63a7\u91ca\u653e\u3002\u672c\u5de5\u4f5c\u63d0\u4f9b\u4e86\u4e00\u7c7b\u53ef\u964d\u89e3\u7684\u6e29\u5ea6\u654f\u611f\u578b\u805a\u8f6e\u70f7\u7684\u6709\u6548\u5408\u6210\u65b9\u6cd5\uff0c\u540c\u65f6\u9610\u660e\u4e86\u805a\u8f6e\u70f7\u62d3\u6251\u7ed3\u6784\u5bf9\u6e29\u654f\u6027\u80fd\u53ca\u964d\u89e3\u884c\u4e3a\u7684\u91cd\u8981\u5f71\u54cd\u3002<\/p>\n<p><strong>\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n<p>\u73af\u7cca\u7cbe\u805a\u8f6e\u70f7\u7531\u4e8e\u5176\u5408\u6210\u7b80\u5355\uff0c\u751f\u7269\u76f8\u5bb9\u6027\u597d\u548c\u6613\u4e8e\u5b98\u80fd\u5316\u7b49\u7279\u70b9\uff0c\u88ab\u5e7f\u6cdb\u5e94\u7528\u4e8e\u751f\u7269\u533b\u836f\u9886\u57df\u3002\u5404\u7c7b\u73af\u7cca\u7cbe\u805a\u8f6e\u70f7\u884d\u751f\u7269\u76f8\u7ee7\u5f97\u4ee5\u62a5\u9053\uff0c\u7279\u522b\u5730\uff0c\u7532\u57fa\u5316\u73af\u7cca\u7cbe\u805a\u8f6e\u70f7\u5177\u6709\u7279\u5f81\u7684\u6e29\u5ea6\u654f\u611f\u884c\u4e3a\uff0c\u4f46\u5176\u76f8\u53d8\u533a\u95f4\u901a\u5e38\u8f83\u5bbd\uff0c\u4e14\u56de\u590d\u6ede\u540e\u6027\u660e\u663e\u3002\u5c3d\u7ba1\u5df2\u6709\u62a5\u9053\u91c7\u7528\u5be1\u805a\u70f7\u6c27\u919a\u4fee\u9970\u805a\u8f6e\u70f7\u4ee5\u8c03\u8282\u5176\u6c34\u6eb6\u6027\u548c\u7ec6\u80de\u5185\u5316\u6548\u7387\uff0c\u4f46\u83b7\u5f97\u7684PRX\u884d\u751f\u7269\u4ecd\u5177\u6709\u8f83\u5bbd\u7684\u76f8\u53d8\u6e29\u5ea6\u8303\u56f4\uff0c\u6ede\u540e\u884c\u4e3a\u5219\u9c9c\u6709\u7814\u7a76\u3002\u6b64\u5916\uff0c\u805a\u8f6e\u70f7\u62d3\u6251\u7ed3\u6784\u5bf9\u6e29\u5ea6\u654f\u611f\u884c\u4e3a\u7684\u5f71\u54cd\u4e5f\u5c1a\u4e0d\u6e05\u695a\u3002<\/p>\n<p>\u8fd1\u65e5\uff0c<strong>\u4e0a\u6d77\u5927\u5b66<\/strong>\u7684<strong>\u5f20\u963f\u65b9<\/strong>\u6559\u6388\u548c<strong>\u95eb\u5bb6\u6d9b<\/strong>\u535a\u58eb\uff08\u5171\u540c\u901a\u8baf\uff09\u5728<strong>Macromolecules<\/strong>\u4e0a\u53d1\u8868\u4e86\u4e00\u7bc7\u9898\u4e3a \u201c<strong>OEGylated Cyclodextrin-Based Polyrotaxanes Showing Remarkable Thermoresponsive Behavior and Photocontrolled Degradation<\/strong>\u201d\u7684\u6587\u7ae0\u3002\u7814\u7a76\u4eba\u5458\u91c7\u7528\u4ed6\u4eec\u4e4b\u524d\u62a5\u9053\u7684\u70f7\u6c27\u919a\u5316\u73af\u7cca\u7cbe\u884d\u751f\u7269\uff08<em>J. Mater. Chem.<\/em> <strong>2012<\/strong>, <em>22<\/em>, 17424; <em>Polym. Chem.<\/em> <strong>2015<\/strong>, <em>6<\/em>, 1300; <em>ACS Appl. Mater. Interfaces <\/em><strong>2018<\/strong>, <em>10<\/em>, 13258\uff09\u4e3a\u6784\u7b51\u57fa\u5143\uff0c\u7ed3\u5408\u5c01\u7aef\u57fa\u56e2\u7684\u5149\u63a7\u88c2\u89e3\u884c\u4e3a\uff0c\u5236\u5907\u4e86\u4e00\u7c7b\u53ef\u964d\u89e3\u7684\u6e29\u654f\u73af\u7cca\u7cbe\u805a\u8f6e\u70f7\u3002<\/p>\n<p><strong>\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n<p><strong>\u56fe<\/strong><strong>1 <\/strong><strong>\u6e29\u5ea6\u654f\u611f\u578b\u73af\u7cca\u7cbe\u805a\u8f6e\u70f7\u53ca\u5176\u5149\u63a7\u964d\u89e3\u884c\u4e3a<\/strong><\/p>\n<p><strong>\u00a0<img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-175013 aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2019\/05\/1-3.png\" alt=\"\" width=\"700\" height=\"278\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2019\/05\/1-3.png 700w, \/\/m.iemloyee.com\/wp-content\/uploads\/2019\/05\/1-3-300x119.png 300w\" sizes=\"(max-width: 700px) 100vw, 700px\" \/><\/strong><\/p>\n<p><strong>\u56fe<\/strong><strong>2 <\/strong><strong>\u70f7\u6c27\u919a\u5316\u73af\u7cca\u7cbe\u805a\u8f6e\u70f7\u7684\u5408\u6210\u793a\u610f\u56fe<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-175014 aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2019\/05\/2-3.png\" alt=\"\" width=\"700\" height=\"471\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2019\/05\/2-3.png 700w, \/\/m.iemloyee.com\/wp-content\/uploads\/2019\/05\/2-3-300x202.png 300w\" sizes=\"(max-width: 700px) 100vw, 700px\" \/><\/p>\n<p><strong>\u56fe<\/strong><strong>3 <\/strong><strong>\u73af\u7cca\u7cbe\u805a\u8f6e\u70f7<\/strong><strong>\u7684<\/strong><strong><sup>1<\/sup><\/strong><strong>H NMR<\/strong><strong>\u8c31\u56fe<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-175015 aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2019\/05\/3-3.png\" alt=\"\" width=\"700\" height=\"541\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2019\/05\/3-3.png 700w, \/\/m.iemloyee.com\/wp-content\/uploads\/2019\/05\/3-3-300x232.png 300w\" sizes=\"(max-width: 700px) 100vw, 700px\" \/><\/p>\n<p><strong>\u56fe<\/strong><strong>4 <\/strong><strong>\u70f7\u6c27\u919a\u5316\u73af\u7cca\u7cbe\u805a\u8f6e\u70f7\u7684\u6d4a\u5ea6\u66f2\u7ebf\u53ca\u6d4a\u70b9\u7684\u6d53\u5ea6\u4f9d\u8d56\u6027<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-175016 aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2019\/05\/4-2.png\" alt=\"\" width=\"700\" height=\"289\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2019\/05\/4-2.png 700w, \/\/m.iemloyee.com\/wp-content\/uploads\/2019\/05\/4-2-300x124.png 300w\" sizes=\"(max-width: 700px) 100vw, 700px\" \/><\/p>\n<p>\uff08a\uff090.25 wt\uff05\u7684\u70f7\u6c27\u919a\u5316PRX\u6c34\u6eb6\u6db2\u7684\u900f\u5c04\u7387\u5bf9\u6e29\u5ea6\u7684\u66f2\u7ebf\u56fe\u3002 \u5b9e\u7ebf\u5bf9\u5e94\u4e8e\u52a0\u70ed\u8fc7\u7a0b\uff0c\u865a\u7ebf\u5bf9\u5e94\u4e8e\u51b7\u5374\u8fc7\u7a0b\uff1b<\/p>\n<p>\uff08b\uff09<em>T<\/em><sub>cp<\/sub>s\u7684\u6d53\u5ea6\u4f9d\u8d56\u6027\u3002<\/p>\n<p>&nbsp;<\/p>\n<p><strong>\u56fe<\/strong><strong>5 <\/strong><strong>\u70f7\u6c27\u919a\u5316\u73af\u7cca\u7cbe\u805a\u8f6e\u70f7\u7684\u53d8\u6e29<\/strong><strong><sup>1<\/sup><\/strong><strong>H NMR<\/strong><strong>\u8c31\u56fe<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-175017 aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2019\/05\/5.png\" alt=\"\" width=\"700\" height=\"394\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2019\/05\/5.png 700w, \/\/m.iemloyee.com\/wp-content\/uploads\/2019\/05\/5-300x169.png 300w\" sizes=\"(max-width: 700px) 100vw, 700px\" \/><\/p>\n<p>\uff08a\uff09\u5728D<sub>2<\/sub>O\u4e2dPRX1-DEG<sub>1<\/sub>\uff1b<\/p>\n<p>\uff08b\uff09UV\u7167\u5c04\u540e\u7684PRX1-DEG<sub>11.1<\/sub>\u3002<\/p>\n<p><strong>\u56fe<\/strong><strong>6<\/strong><strong>\u73af\u7cca\u7cbe\u805a\u8f6e\u70f7\u7684\u5149\u964d\u89e3\u884c\u4e3a<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-175018 aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2019\/05\/6.png\" alt=\"\" width=\"700\" height=\"263\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2019\/05\/6.png 700w, \/\/m.iemloyee.com\/wp-content\/uploads\/2019\/05\/6-300x113.png 300w\" sizes=\"(max-width: 700px) 100vw, 700px\" \/><\/p>\n<p>\uff08a\uff09\u7528350nm\u7d2b\u5916\u5149\u7167\u5c04\u4e0d\u540c\u65f6\u95f4\u76840.25 wt\uff05 PRX1-DEG<sub>11.1<\/sub>\u6c34\u6eb6\u6db2\u7684\u7d2b\u5916-\u53ef\u89c1\u5149\u8c31\uff1b<\/p>\n<p>\uff08b\uff09PEG1\u548cUV\u7167\u5c04\u524d\u540ePRX1-DEG<sub>11.1<\/sub>\u7684GPC\u66f2\u7ebf\u3002\u6d17\u8131\u6db2\u662fDMF\u3002<\/p>\n<p><strong>\u56fe<\/strong><strong>7 <\/strong><strong>\u5149\u964d\u89e3\u5bf9\u6e29\u654f\u884c\u4e3a\u7684\u5f71\u54cd<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-175019 aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2019\/05\/7.png\" alt=\"\" width=\"700\" height=\"263\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2019\/05\/7.png 700w, \/\/m.iemloyee.com\/wp-content\/uploads\/2019\/05\/7-300x113.png 300w\" sizes=\"(max-width: 700px) 100vw, 700px\" \/><\/p>\n<p>\uff08a\uff09UV\u7167\u5c04\u524d\u540e\u7684PRX1-DEG<sub>11.1<\/sub>\uff0cPRX1-TEG<sub>11.8<\/sub>\u548cPRX1-TEG<sub>13.6<\/sub>-F\u76840.25 wt\uff05\u6c34\u6eb6\u6db2\u7684\u900f\u5c04\u7387\u4e0e\u6e29\u5ea6\u7684\u5173\u7cfb\u66f2\u7ebf\uff1b<\/p>\n<p>\uff08b\uff09\u572837\u2103\u4e0b0.25 wt\uff05PRX1-DEG<sub>11.1<\/sub>\u6eb6\u6db2\u7684\u900f\u5c04\u7387\u4e0eUV\u7167\u5c04\u65f6\u95f4\u7684\u5173\u7cfb\u56fe\u3002<\/p>\n<p><strong>\u56fe<\/strong><strong>8 <\/strong><strong>\u5728\u4e0d\u540c\u6761\u4ef6\u4e0b<\/strong><strong>0.25 wt<\/strong><strong>\uff05<\/strong><strong> PRX1-DEG<sub>11.1<\/sub><\/strong><strong>\u6c34\u6eb6\u6db2\u7684\u5149\u5b66\u663e\u5fae\u7167\u7247<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-175020 aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2019\/05\/8.png\" alt=\"\" width=\"700\" height=\"264\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2019\/05\/8.png 700w, \/\/m.iemloyee.com\/wp-content\/uploads\/2019\/05\/8-300x113.png 300w\" sizes=\"(max-width: 700px) 100vw, 700px\" \/><\/p>\n<p><strong>\u56fe<\/strong><strong>9 <\/strong><strong>\u8367\u5149\u5ba2\u4f53\u5206\u5b50\u7684\u91ca\u653e\u884c\u4e3a\u7814\u7a76<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-175021 aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2019\/05\/9.png\" alt=\"\" width=\"700\" height=\"286\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2019\/05\/9.png 700w, \/\/m.iemloyee.com\/wp-content\/uploads\/2019\/05\/9-300x123.png 300w\" sizes=\"(max-width: 700px) 100vw, 700px\" \/><\/p>\n<p>\uff08a\uff09\u4e39\u78fa\u9170\u80fa\u57280.25 wt\uff05 PRX1-DEG<sub>11.1<\/sub>\u6c34\u6eb6\u6db2\u4e2d\u7684\u8367\u5149\u5f3a\u5ea6\u6bd4\u503cF<sub>T<\/sub> \/ F<sub>24<\/sub>\u5bf9\u6e29\u5ea6\u7684\u53d8\u5316\u66f2\u7ebf\u3002 F<sub>T<\/sub>\u548cF<sub>24<\/sub>\u5206\u522b\u4ee3\u8868\u7279\u5b9a\u6e29\u5ea6\u548c24\u2103\u4e0b\u7684\u8367\u5149\u5f3a\u5ea6\uff1b<\/p>\n<p>\uff08b\uff09\u4e39\u78fa\u9170\u80fa\u57280.25 wt\uff05PRX1-DEG11.1\u6c34\u6eb6\u6db2\u4e8e37\u2103\u4e0b\u7684\u8367\u5149\u5f3a\u5ea6\u6bd4\u503cF<sub>37<\/sub>-UV \/ F<sub>37<\/sub>\u5bf9\u7d2b\u5916\u7167\u5c04\u65f6\u95f4\u7684\u66f2\u7ebf\u56fe\u3002 F<sub>37<\/sub>\u548cF<sub>37<\/sub>-UV\u5206\u522b\u8868\u793a\u572837\u2103\u4e0b\u4e0d\u7ecf\u8fc7UV\u7167\u5c04\u548c\u7ecf\u8fc7\u4e0d\u540c\u65f6\u95f4UV\u7167\u5c04\u7684\u8367\u5149\u5f3a\u5ea6\u3002<\/p>\n<p>&nbsp;<\/p>\n<p><strong>\u3010\u7ed3\u8bba\u548c\u5c55\u671b\u3011<\/strong><\/p>\n<p>\u8bba\u6587\u62a5\u9053\u4e86\u4e00\u7c7b\u5149\u964d\u89e3\u578b\u70f7\u6c27\u919a\u5316\u73af\u7cca\u7cbe\u805a\u8f6e\u70f7\u7684\u5408\u6210\uff0c\u4ee5\u53ca\u805a\u8f6e\u70f7\u62d3\u6251\u7ed3\u6784\u5bf9\u805a\u8f6e\u70f7\u6e29\u5ea6\u654f\u611f\u884c\u4e3a\u548c\u964d\u89e3\u884c\u4e3a\u7684\u663e\u8457\u5f71\u54cd\u3002\u8be5\u7c7bPRX\u5728\u6c34\u6eb6\u6db2\u4e2d\u8868\u73b0\u51fa\u7279\u5f81\u7684\u70ed\u54cd\u5e94\u884c\u4e3a\uff0c\u5177\u6709\u5feb\u901f\u548c\u53ef\u9006\u7684\u76f8\u53d8\uff0c\u6ede\u540e\u6027\u5c0f\uff0c\u4e14\u76f8\u53d8\u6e29\u5ea6\u53ef\u901a\u8fc7\u6539\u53d8\u4f4e\u805a\u70f7\u6c27\u919a\u7684\u63a5\u679d\u7387\u6216\u94fe\u957f\u572830-55\u2103\u7684\u8303\u56f4\u5185\u8c03\u63a7\u3002\u6709\u8da3\u7684\u662f\uff0c\u70f7\u6c27\u919a\u5316\u73af\u7cca\u7cbe\u201c\u8f6e\u5b50\u201d\u5728\u76f8\u53d8\u6e29\u5ea6\u4ee5\u4e0a\u53d1\u751f\u8131\u6c34\u584c\u9677\uff0c\u800cPEG\u4e3b\u94fe\u7f3a\u4fdd\u6301\u8f83\u9ad8\u7684\u6c34\u5408\u72b6\u6001\uff0c\u8fd9\u53ef\u80fd\u4fc3\u8fdb\u4e86\u73af\u7cca\u7cbe\u201c\u8f6e\u5b50\u201d\u6cbf\u4e3b\u94fe\u7684\u6ed1\u79fb\u3002\u57fa\u4e8e\u5176\u673a\u68b0\u4e92\u9501\u7684\u7ed3\u6784\uff0cPRX\u5728\u6eb6\u6db2\u4e2d\u7a33\u5b9a\uff0c\u4f46\u5728\u5c01\u7aef\u57fa\u56e2UV\u88c2\u89e3\u540e\u53ef\u5b8c\u5168\u964d\u89e3\u6210\u4eb2\u6c34\u7684\u7ec4\u5206\uff0c\u5176\u6e29\u654f\u884c\u4e3a\u968f\u4e4b\u6d88\u5931\u3002\u8fd9\u8bc1\u660e\u4e86\u5c01\u7aef\u57fa\u56e2\u5bf9\u4e8e\u63a7\u5236PRX\u7684\u6e29\u5ea6\u654f\u611f\u884c\u4e3a\u548c\u964d\u89e3\u884c\u4e3a\u81f3\u5173\u91cd\u8981\u3002\u6b64\u5916\uff0c\u6e29\u654fPRX\u5728\u76f8\u53d8\u6e29\u5ea6\u4ee5\u4e0a\u5f62\u6210\u5fae\u7c73\u7ea7\u7403\u72b6\u805a\u96c6\u4f53\uff0c\u4f46\u5728\u51b7\u5374\u6216UV\u7167\u5c04\u65f6\u5feb\u901f\u89e3\u805a\uff0c\u4ece\u800c\u88ab\u5e94\u7528\u4e8e\u5bf9\u5ba2\u4f53\u5206\u5b50\u7684\u63a7\u5236\u91ca\u653e\u3002\u57fa\u4e8e\u72ec\u7279\u7684\u8f6e\u70f7\u7ed3\u6784\u3001\u5353\u8d8a\u7684\u70ed\u54cd\u5e94\u6027\u548c\u5149\u63a7\u964d\u89e3\u6027\uff0c\u8fd9\u4e9b\u70f7\u6c27\u919a\u5316\u73af\u7cca\u7cbe\u805a\u8f6e\u70f7\u5c06\u5728\u836f\u7269\u8f93\u9001\u3001\u667a\u80fd\u751f\u7269\u6750\u6599\u548c\u9a71\u52a8\u5668\u7b49\u65b9\u9762\u5177\u6709\u5e7f\u9614\u7684\u5e94\u7528\u524d\u666f\u3002<\/p>\n<p>&nbsp;<\/p>\n<p>\u6587\u732e\u94fe\u63a5\uff1a <a href=\"https:\/\/pubs.acs.org.ccindex.cn\/doi\/10.1021\/acs.macromol.9b00267\">OEGylated Cyclodextrin-Based Polyrotaxanes Showing Remarkable Thermoresponsive Behavior and Photocontrolled Degradation<\/a> (Macromolecules\uff0c2019\uff0cDOI: 10.1021\/acs.macromol.9b00267)<\/p>\n<p><strong>\u3010\u56e2\u961f\u6210\u679c\u3011<\/strong><\/p>\n<p>\u6b64\u5916\uff0c\u8be5\u56e2\u961f\u8fd1\u5e74\u6765\u5728\u70f7\u6c27\u919a\u7c7b\u6e29\u5ea6\u654f\u611f\u578b\u805a\u5408\u7269\u9886\u57df\u53d6\u5f97\u4e86\u4e30\u5bcc\u7814\u7a76\u6210\u679c\uff0c\u8bbe\u8ba1\u5408\u6210\u4e86\u4e00\u7cfb\u5217\u6811\u5f62\u70f7\u6c27\u919a\u805a\u5408\u7269\u3001\u6811\u679d\u5316\u591a\u80bd\u805a\u5408\u7269\u53ca\u5176\u6c34\u51dd\u80f6\u6750\u6599\uff0c\u5e76\u5b9e\u73b0\u4e86\u5728\u86cb\u767d\u8d28\u8d1f\u8f7d\u53ca\u6d3b\u6027\u4fdd\u62a4\u3001\u5206\u5b50\u8bc6\u522b\u548c\u4f20\u611f\u5668\u7b49\u9886\u57df\u7684\u5e94\u7528\uff0c\u76f8\u5173\u5de5\u4f5c\u53d1\u8868\u5728<em>Macromolecules<\/em>, <em>Poly. Chem.<\/em>\u548c<em>J. Mater. Chem. B<\/em>\u7b49\u520a\u7269\u4e0a\u3002<\/p>\n<p>\u6587\u732e\u94fe\u63a5\uff1a<\/p>\n<p><a href=\"https:\/\/pubs.rsc.org\/en\/content\/articlelanding\/2018\/TB\/C7TB03352D#!divAbstract\">https:\/\/pubs.rsc.org\/en\/content\/articlelanding\/2018\/TB\/C7TB03352D#!divAbstract<\/a><\/p>\n<p><a href=\"https:\/\/pubs.rsc.org\/en\/content\/articlelanding\/2018\/PY\/C7PY01865G#!divAbstract\">https:\/\/pubs.rsc.org\/en\/content\/articlelanding\/2018\/PY\/C7PY01865G#!divAbstract<\/a><\/p>\n<p><a href=\"https:\/\/pubs.rsc.org\/en\/content\/articlelanding\/2018\/PY\/C7PY01284E#!divAbstract\">https:\/\/pubs.rsc.org\/en\/content\/articlelanding\/2018\/PY\/C7PY01284E#!divAbstract<\/a><\/p>\n<p><a href=\"https:\/\/pubs.acs.org.ccindex.cn\/doi\/10.1021\/acs.macromol.5b02259\">https:\/\/pubs.acs.org.ccindex.cn\/doi\/10.1021\/acs.macromol.5b02259<\/a><\/p>\n<p>\u672c\u6587\u7531\u6c34\u624b\u4f9b\u7a3f\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u3010\u5f15\u8a00\u3011 \u672c\u6587\u4ecb\u7ecd\u4e86\u4e00\u7c7b\u5149\u63a7\u964d\u89e3\u578b\u70f7\u6c27\u919a\u5316\u73af\u7cca\u7cbe\u805a\u8f6e\u70f7\uff08PRX\uff09\u7684\u5408\u6210\u53ca\u6027\u80fd\u8868\u5f81\u3002\u8be5\u7c7b\u805a\u8f6e\u70f7\u5728\u6c34\u76f8\u4e2d\u5747\u8868\u73b0\u51fa\u7279\u5f81\u7684\u6e29\u5ea6\u654f\u611f\u884c\u4e3a\uff1a\u76f8\u53d8\u8fc5\u901f\u4e14\u8fc7\u7a0b\u53ef\u9006\uff0c\u6ede\u540e\u73b0\u8c61\u5c0f\u4e14&#8230;<\/p>\n","protected":false},"author":3247,"featured_media":175013,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[42],"class_list":["post-175010","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-jiedu","tag-gaofenzi"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/175010"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/3247"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=175010"}],"version-history":[{"count":3,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/175010\/revisions"}],"predecessor-version":[{"id":175338,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/175010\/revisions\/175338"}],"wp:featuredmedia":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/media\/175013"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=175010"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=175010"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=175010"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}