{"id":174918,"date":"2019-05-14T06:30:08","date_gmt":"2019-05-13T22:30:08","guid":{"rendered":"\/\/m.iemloyee.com\/?p=174918"},"modified":"2019-05-13T19:37:58","modified_gmt":"2019-05-13T11:37:58","slug":"%e3%80%90%e5%b7%b2%e6%a0%a1%e7%a8%bf%e3%80%91%e5%8c%97%e7%90%86%e5%b7%a5%e5%86%af%e9%9c%84%e7%89%b9%e5%88%ab%e7%a0%94%e7%a9%b6%e5%91%98angew-chem-int-ed-%ef%bc%9a%e7%94%b5%e8%81%9a%e5%90%88","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=174918","title":{"rendered":"\u5317\u7406\u5de5\u51af\u9704\u7279\u522b\u7814\u7a76\u5458Angew. Chem. Int. Ed.\uff1a\u7535\u805a\u5408\u5236\u5907\u805a\u567b\u5429H2\u5206\u79bb\u8584\u819c"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/p>\n

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\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/p>\n

\u5317\u4eac\u7406\u5de5\u5927\u5b66\u7684\u51af\u9704\u7279\u522b\u7814\u7a76\u5458\uff08\u901a\u8baf\u4f5c\u8005\uff09\u5728Angew. Chem. Int. Ed.\u4e0a\u62a5\u9053\u4e86\u901a\u8fc7\u7535\u805a\u5408\u6cd5\u5236\u5907\u67d4\u6027\u81ea\u652f\u6491\u3001\u5206\u5b50\u7b5b\u5206\u7684\u805a\u567b\u5429\u8584\u819c\u3002\u8be5\u56e2\u961f\u901a\u8fc7\u6539\u53d8\u5355\u4f53\u6d3b\u6027\u805a\u5408\u4f4d\u70b9\u6570\u76ee\u548c\u70f7\u57fa\u94fe\u957f\u5ea6\u5408\u6210\u4e86\u591a\u79cd\u8584\u819c\uff0c\u5e76\u7814\u7a76\u4e86\u5b83\u4eec\u7684\u6c14\u4f53\u5206\u79bb\u6027\u80fd\uff0c\u5bf9H2<\/sub>\/CO2<\/sub>\u3001H2<\/sub>\/N2<\/sub> \u548cH2<\/sub>\/CH4<\/sub>\u7684\u5206\u79bb\u6027\u80fd\u5747\u7a81\u7834\u4e86\u805a\u5408\u7269\u7684Robeson\u4e0a\u9650\u3002\u826f\u597d\u7684\u5316\u5b66\u7a33\u5b9a\u6027\u3001\u70ed\u7a33\u5b9a\u6027\u53ca\u957f\u671f\u7a33\u5b9a\u6027\u8868\u660e\u5b83\u4eec\u5177\u6709\u4e00\u5b9a\u7684\u5de5\u4e1a\u5316\u5e94\u7528\u6f5c\u529b\u3002\u8fd9\u79cd\u5236\u5907\u7b80\u4fbf\u3001\u62d3\u5c55\u6027\u53ca\u53ef\u63a7\u6027\u5f3a\u7684\u7b56\u7565\u7ed9\u8bbe\u8ba1\u5176\u5b83\u9ad8\u6027\u80fd\u805a\u5408\u7269\u6c14\u4f53\u5206\u79bb\u819c\u63d0\u4f9b\u4e86\u65b0\u601d\u8def\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/p>\n

Scheme 1. a) \u521a\u67d4\u5e76\u6d4e\uff08SAR\uff09\u7684\u7b56\u7565\uff1bb) \u7535\u805a\u5408\u6cd5\u5236\u5907\u8584\u819c\u7684\u793a\u610f\u56fe<\/p>\n

\"\"<\/p>\n

Scheme 2. \u7535\u805a\u5408\u53cd\u5e94<\/p>\n

\"\"<\/p>\n

Figure 1. a) \u81ea\u652f\u6491\u5171\u805a\u8584\u819c\u7167\u7247\uff1bb) \u5171\u805a\u819c\u7684\u5355\u7ec4\u5206\u6c14\u4f53\u6e17\u900f\u7387\uff1bc-e)\u5171\u805a\u819c\u548c\u5df2\u62a5\u9053\u805a\u5408\u7269\u819c\u5206\u79bb\u6027\u80fd\u5bf9\u6bd4\u3002<\/p>\n

\"\"<\/p>\n

Figure 2.a) P33DT-ThC4\u7684\u957f\u5faa\u73af\u7a33\u5b9a\u6027\uff1bb) \u4e0d\u540c\u8584\u819c\u7684\u6c14\u4f53\u6eb6\u89e3\u5ea6\uff1bc) \u4e0d\u540c\u8584\u819c\u7684\u6c14\u4f53\u6269\u6563\u7cfb\u6570<\/p>\n

\"\"<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/p>\n

\u7814\u7a76\u56e2\u961f\u5728\u805a\u567b\u5429\u57fa\u521a\u6027\u591a\u5b54\u9aa8\u67b6\u4e2d\u5f15\u5165\u70f7\u57fa\u94fe\uff0c\u9996\u6b21\u901a\u8fc7\u64cd\u4f5c\u7b80\u4fbf\u7684\u7535\u805a\u5408\u6cd5\u5236\u5907\u4e86\u5747\u5300\u3001\u81ea\u652f\u6491\u7684\u6c14\u4f53\u5206\u5b50\u7b5b\u5206\u819c\u3002\u5b83\u4eec\u5177\u6709\u4f18\u5f02\u7684\u6c22\u6c14\u5206\u79bb\u6027\u80fd\uff0c\u5e76\u5f88\u597d\u5730\u5e73\u8861\u4e86\u52a0\u5de5\u6027\u3001\u6e17\u900f\u6027\u548c\u9009\u62e9\u6027\u3002\u8fd9\u9879\u6210\u679c\u6709\u671b\u4e3a\u9ad8\u6027\u80fd\u6c14\u4f53\u5206\u79bb\u819c\u63d0\u4f9b\u65b0\u7684\u5236\u5907\u65b9\u6cd5\u3002<\/p>\n

\u5bfc\u5e08\u4ecb\u7ecd\uff1a<\/p>\n

\u51af\u9704\uff0c\u4e8e2008\u548c2013\u5e74\u4e8e\u5317\u4eac\u7406\u5de5\u5927\u5b66\u6750\u6599\u5b66\u9662\u53d6\u5f97\u672c\u79d1\u4e0e\u535a\u58eb\u5b66\u4f4d\uff0c\u5728\u653b\u8bfb\u535a\u58eb\u671f\u95f4\u4ee5\u8054\u5408\u57f9\u517b\u535a\u58eb\u7814\u7a76\u751f\u8eab\u4efd\u7559\u5b66\u4e8e\u65e5\u672c\u56fd\u5bb6\u81ea\u7136\u79d1\u5b66\u7814\u7a76\u673a\u6784\u2014\u5206\u5b50\u79d1\u5b66\u7814\u7a76\u6240\u30022013\u5e747\u6708\u5c31\u804c\u4e8e\u5317\u4eac\u7406\u5de5\u5927\u5b66\u5316\u5b66\u5b66\u9662\uff08\u73b0\u5316\u5b66\u4e0e\u5316\u5de5\u5b66\u9662\uff09\u3002\u4e3b\u8981\u4ece\u4e8b\u5173\u4e8e\u5171\u4ef7\u6709\u673a\u6846\u67b6\u6750\u6599\u7b49\u4ee5\u5171\u4ef7\u6709\u673a\u6846\u67b6\u4e3a\u4ee3\u8868\u7684\u6676\u6001\u591a\u5b54\u6750\u6599\u6784\u6548\u5173\u7cfb\u7814\u7a76\u4ee5\u53ca\u819c\u5206\u79bb\u76f8\u5173\u7814\u7a76\u3002\u4ee5\u7b2c\u4e00\u6216\u901a\u8baf\u4f5c\u8005\u53d1\u8868\u5305\u62ec5\u7bc7J. Am. Chem. Soc.\u30016\u7bc7Angew. Chem. Int. Ed.\u30012\u7bc7Adv. Mater.\u7b4929\u7bc7\u6587\u7ae0\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1aElectropolymerization of molecular\u2010sieving polythiophene membranes for H2<\/sub> separation<\/a><\/p>\n

\uff08Angew. Chem. Int. Ed., 2019, DOI: 10.1002\/anie.201904385\uff09<\/p>\n

\u672c\u6587\u7531kv1004\u4f9b\u7a3f\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"

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