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1 \u5d14\u5c79<\/b><\/strong>\uff08\u65af\u5766\u798f\u5927\u5b66\uff09<\/b><\/strong><\/p>\n 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mAh cm-2<\/sup>\uff09\uff0c\u5236\u5907\u7684\u7535\u6781\u5c31\u4f1a\u53d8\u5f97\u5f88\u539a\uff0c\u4ece\u800c\u4f1a\u663e\u8457\u589e\u52a0\u8f7d\u6d41\u5b50\u7684\u4f20\u8f93\u8ddd\u79bb\u3002\u800c\u4e14\uff0c\u7531\u4e8e\u7535\u6781\u5177\u6709\u5927\u7684\u4f53\u79ef\u548c\u8d28\u91cf\uff0c\u5236\u5907\u51fa\u7684\u7535\u6c60\u5f80\u5f80\u80fd\u91cf\u5bc6\u5ea6\u4e0d\u9ad8\u3002<\/p>\n 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V\uff09\u3002\u5728\u786e\u5b9a\u9009\u62e9\u4e86\u7ea2\u78f7\u6750\u6599\u540e\uff0c\u4f5c\u8005\u53c8\u6784\u5efa\u4e86\u5148\u8fdb\u7684\u7535\u6781\u7ed3\u6784\u3002\u65e0\u5b9a\u578b\u7684\u7ea2\u78f7\u88ab\u57cb\u8986\u5728\u5fae\u7c73\u5c3a\u5bf8\u7684\u591a\u5b54\u5bfc\u7535\u78b3\u7684\u5b54\u91cc\uff0c\u540c\u65f6\u53c8\u4fdd\u7559\u4e00\u90e8\u5206\u5b54\u3002\u6b64\u5916\u591a\u5b54\u5bfc\u7535\u78b3\u8868\u9762\u7684\u7ea2\u78f7\u53c8\u88ab\u53bb\u9664\u4ee5\u5f62\u6210\u65e0P\u7684\u8868\u9762\u7eaf\u78b3\u5c42\u3002\u8fd9\u79cd\u8bbe\u8ba1\u65e2\u4fdd\u8bc1\u4e86\u6750\u6599\u5177\u6709\u9ad8\u7684\u5bfc\u7535\u6027\uff0c\u53c8\u53ef\u4ee5\u7f13\u89e3\u7ea2\u78f7\u5728\u7535\u5316\u5b66\u53cd\u5e94\u65f6\u7684\u4f53\u79ef\u81a8\u80c0\u95ee\u9898\uff0c\u800c\u4e14\u6750\u6599\u7684\u5bc6\u5ea6\u9ad8\u8fbe1\u00a0g\u00a0cm–<\/sup>3<\/sup>\u3002\u5728\u5de5\u4e1a\u7ea7\u7684\u9762\u5bb9\u91cf\u4e0b\uff083 mAh cm-2<\/sup>\u6216\u66f4\u9ad8\uff09\uff0c\u76f8\u6bd4\u4e8e\u5546\u4e1a\u5316\u7684\u77f3\u58a8\u548c\u949b\u9178\u9502\u7535\u6781\uff0c\u8be5P\/C\u7535\u6781\u8868\u73b0\u51fa\u4e86\u66f4\u597d\u7684\u5feb\u5145\u6027\u80fd\u4ee5\u53ca\u66f4\u9ad8\u7684\u4f53\u79ef\u6bd4\u5bb9\u91cf\u548c\u8d28\u91cf\u6bd4\u5bb9\u91cf\uff08\u56fe1\uff09\u3002\uff08Y. Sun, L. Wang, Y. Li, Y. Li, H.R. Lee, A. Pei, X. He, Y. Cui, Joule, 3 (2019) 1080-1093\uff1bhttps:\/\/doi.org\/10.1016\/j.joule.2019.01.017\uff09<\/p>\n \u56fe1\u00a0\u5177\u6709\u5feb\u5145\u6027\u80fd\u7684\u9ad8\u80fd\u91cf\u5bc6\u5ea6\u7684\u7ea2\u78f7\u7535\u6781<\/p>\n \u9664\u4e86\u7ea2\u78f7\u4e4b\u5916\uff0c\u5d14\u5c79\u8bfe\u9898\u7ec4\u8fd8\u7d27\u5bc6\u5173\u6ce8\u7740\u9502\u91d1\u5c5e\u8d1f\u6781\u3002\u9502\u91d1\u5c5e\u8d1f\u6781\u88ab\u8a89\u4e3a\u8d1f\u6781\u6750\u6599\u754c\u7684\u201c\u5723\u676f\u201d\uff0c\u8fd9\u662f\u56e0\u4e3a\u5b83\u5177\u6709\u6700\u9ad8\u7406\u8bba\u6bd4\u5bb9\u91cf\uff083860 mAh\u00a0g–<\/sup>1<\/sup>\uff09\uff0c\u6700\u4f4e\u7684\u6c27\u5316\u8fd8\u539f\u7535\u4f4d\uff08\u76f8\u5bf9\u4e8e\u6807\u51c6\u6c22\u7535\u4f4d\u4e3a-3.04 V\uff09\uff0c\u8fd9\u4f7f\u5176\u975e\u5e38\u9002\u4e8e\u5236\u5907\u9ad8\u80fd\u91cf\u5bc6\u5ea6\u7684\u9502\u79bb\u5b50\u7535\u6c60\u3002\u4e0d\u8fc7\uff0c\u9502\u91d1\u5c5e\u8d1f\u6781\u4e5f\u5b58\u5728\u7740\u5f88\u591a\u7684\u95ee\u9898\uff0c\u6bd4\u5982\u4e0d\u53ef\u63a7\u7684\u9502\u6c89\u79ef\uff0c\u4e0d\u7a33\u5b9a\u7684SEI\u819c\uff0c\u4ee5\u53ca\u4f4e\u7684\u5e93\u4f26\u6548\u7387\u7b49\u3002\u5f53\u7535\u6c60\u7684\u9762\u5bb9\u91cf\u53ca\u5145\u653e\u7535\u7535\u6d41\u5bc6\u5ea6\u8fbe\u5230\u5b9e\u9645\u5546\u4e1a\u5e94\u7528\u6c34\u5e73\u65f6\uff0c\u8fd9\u4e9b\u95ee\u9898\u4f1a\u53d8\u5f97\u66f4\u52a0\u4e25\u91cd\u3002\u56e0\u6b64\uff0c\u5982\u4f55\u89e3\u51b3\u8fd9\u4e9b\u95ee\u9898\u5c31\u663e\u5f97\u975e\u5e38\u91cd\u8981\u3002<\/p>\n \u8003\u8651\u5230\u8304\u5b50\u5177\u6709\u8054\u901a\u7684\u7ba1\u9053\u72b6\u7ed3\u6784\uff0c\u8fd9\u4f7f\u5176\u5177\u6709\u9ad8\u7684\u6bd4\u8868\u9762\u79ef\uff0c\u5747\u5300\u7684\u9502\u878d\u5165\u7279\u6027\uff0c\u4ee5\u53ca\u5feb\u7684\u7535\u5b50\u548c\u79bb\u5b50\u4f20\u8f93\u3002\u56e0\u6b64\uff0c\u4f5c\u8005\u91c7\u7528\u78b3\u5316\u540e\u7684\u8304\u5b50\uff08EP\uff09\u4f5c\u4e3a\u9502\u91d1\u5c5e\u7684\u8f7d\u4f53\u6765\u8d1f\u8f7d\u91d1\u5c5e\u9502\u8d1f\u6781\u3002\u4e3a\u4e86\u8fdb\u4e00\u6b65\u6539\u5584SEI\u819c\u7684\u6027\u8d28\uff0c\u4f5c\u8005\u8fd8\u91c7\u7528LiF\u5bf9\u9502\u878d\u5165\u540e\u7684EP\u8fdb\u884c\u754c\u9762\u4fee\u9970\u4ee5\u5f97\u5230EP-LiF\u590d\u5408\u6750\u6599\u3002\u6d4b\u8bd5\u8868\u660e\u5236\u5907\u51fa\u7684EP-LiF\u590d\u5408\u6750\u6599\u5177\u6709\u5927\u7ea690%\u7684\u9502\u91d1\u5c5e\u7684\u7406\u8bba\u5bb9\u91cf\uff0c\u800c\u4e14\u6210\u529f\u6291\u5236\u4e86\u9502\u679d\u6676\u7684\u751f\u957f\u548c\u5927\u7684\u4f53\u79ef\u53d8\u5316\u3002\u6b64\u5916\uff0c\u65e0\u8bba\u662f\u5728\u5bf9\u79f0\u7535\u6c60\u8fd8\u662f\u5728\u5168\u7535\u6c60\u6d4b\u8bd5\u4e2d\uff0cEP-LiF\u90fd\u8868\u73b0\u51fa\u4e86\u4f18\u5f02\u7684\u5faa\u73af\u6027\u80fd\uff0c\u5177\u6709\u7740\u4f4e\u4e14\u7a33\u5b9a\u7684\u8fc7\u7535\u52bf\u3002\u4f5c\u8005\u8fd8\u628aEP\u4f5c\u4e3a\u4e00\u4e2a\u8f7b\u7684\u96c6\u6d41\u4f53\u6765\u6d4b\u8bd5\u5b83\u7684\u9502\u6c89\u79ef\/\u8131\u51fa\u6027\u80fd\u3002\u57282.2 mAh cm-2<\/sup>\u7684\u9762\u5bb9\u91cf\u4e0b\u8fdb\u884c\u5faa\u73af\u6d4b\u8bd5\uff0c\u6750\u6599\u7684\u5e73\u5747\u5e93\u4f26\u6548\u7387\u4ecd\u7136\u9ad8\u8fbe99.1%\u3002\u56e0\u6b64\u8be5\u6750\u6599\u5f88\u6709\u5e0c\u671b\u5e94\u7528\u5728\u4e0b\u4e00\u4ee3\u9ad8\u80fd\u91cf\u5bc6\u5ea6\u7535\u6c60\u4e2d\u3002\uff08H. Wang, D. Lin, J. Xie, Y. Liu, H. Chen, Y. Li, J. Xu, G. Zhou, Z. Zhang, A. Pei, Y. Zhu, K. Liu, K. Wang, Y. Cui, Advanced Energy Materials, 9 (2019)\uff1bhttps:\/\/doi.org\/10.1016\/10.1002\/aenm.201802720\uff09<\/p>\n \u56fe2\u00a0\u8304\u5b50\u884d\u751f\u7684\u8054\u901a\u7ba1\u9053\u72b6\u7684\u9502\u91d1\u5c5e\u8d1f\u6781\u8f7d\u4f53\u7528\u6765\u8d1f\u8f7d\u9502\u5e76\u7ecfLiF\u8fdb\u884c\u754c\u9762\u4fee\u9970\uff08a\uff09\u53ca\u5176\u7535\u5316\u5b66\u6027\u80fd\uff08b\uff0cc\uff09<\/p>\n 2<\/b><\/strong>\u00a0<\/b><\/strong>\u697c\u96c4\u6587\uff08\u5357\u6d0b\u7406\u5de5\u5927\u5b66\uff09<\/b><\/strong><\/p>\n \u697c\u96c4\u6587\u6559\u6388\u4e00\u76f4\u81f4\u529b\u4e8e\u5f00\u53d1\u65b0\u578b\u9ad8\u6027\u80fd\u7684\u7535\u6c60\u6750\u6599\uff0c\u5c24\u5176\u64c5\u957f\u5236\u5907\u51fa\u5177\u6709\u5404\u79cd\u4e2d\u7a7a\u7ed3\u6784\u7684\u7eb3\u7c73\u6750\u6599\u4ee5\u63d0\u9ad8\u6750\u6599\u7684\u6027\u80fd\u3002\u76f8\u6bd4\u4e8e\u9502\u79bb\u5b50\u7535\u6c60\uff0c\u94a0\u79bb\u5b50\u7535\u6c60\u5177\u6709\u66f4\u52a0\u4e30\u5bcc\u7684\u81ea\u7136\u8d44\u6e90\u4ee5\u53ca\u66f4\u4f4e\u7684\u6210\u672c\uff0c\u56e0\u6b64\u5f88\u6709\u5e0c\u671b\u5e94\u7528\u5728\u5927\u89c4\u6a21\u50a8\u80fd\u4e0a\u3002\u7531\u4e8e\u91d1\u5c5e\u786b\u5316\u7269\u5177\u6709\u7740\u9ad8\u5bb9\u91cf\u548c\u597d\u7684\u7535\u5316\u5b66\u53ef\u9006\u6027\u7684\u4f18\u70b9\uff0c\u5b83\u4eec\u5728\u94a0\u79bb\u5b50\u7535\u6c60\u9886\u57df\u53d7\u5230\u4e86\u5e7f\u6cdb\u7684\u5173\u6ce8\u3002\u7136\u800c\uff0c\u5728\u8fdb\u884c\u7535\u5316\u5b66\u53cd\u5e94\u65f6\uff0c\u786b\u5316\u7269\u4ecd\u7136\u5177\u6709\u7740\u5dee\u7684\u5bfc\u7535\u6027\u4ee5\u53ca\u5927\u7684\u4f53\u79ef\u53d8\u5316\u95ee\u9898\uff0c\u8fd9\u4f7f\u5f97\u5b83\u4eec\u5448\u73b0\u51fa\u5dee\u7684\u500d\u7387\u6027\u80fd\u548c\u5faa\u73af\u6027\u80fd\u3002\u89e3\u51b3\u8fd9\u4e9b\u95ee\u9898\u7684\u4e00\u6761\u6709\u6548\u8def\u5f84\u5c31\u662f\u5408\u7406\u5730\u8bbe\u8ba1\u5177\u6709\u7eb3\u7c73\u7ed3\u6784\u7684\u6750\u6599\u3002<\/p>\n \u57fa\u4e8e\u6b64\uff0c\u697c\u96c4\u6587\u6559\u6388\u7ec4\u5c31\u8bbe\u8ba1\u4e86\u4e00\u79cd\u5c42\u7ea7\u72b6\uff0c\u53cc\u58f3\u5c42\uff0c\u4e2d\u7a7a\u7684\u7eb3\u7c73CuS@CuS2<\/sub>\u76d2\u5b50\u3002\u5b9e\u9a8c\u7684\u603b\u4f53\u6d41\u7a0b\u5982\u56fe3\u6240\u793a\uff0c\u91c7\u7528\u7684\u662f\u4e00\u79cd\u6a21\u677f-\u786b\u5316-\u523b\u8680-\u786b\u5316\u7684\u8def\u7ebf\u3002\u8fd9\u79cd\u7ed3\u6784\u5177\u6709\u7740\u72ec\u7279\u7684\u4f18\u52bf\uff1a\uff081\uff09\u4e2d\u7a7a\u7684\u7ed3\u6784\u53ef\u4ee5\u6709\u6548\u5730\u7f13\u89e3\u6750\u6599\u5728\u53d1\u751f\u7535\u5316\u5b66\u53cd\u5e94\u65f6\u4ea7\u751f\u7684\u5e94\u529b\u5e76\u4fc3\u8fdb\u7535\u89e3\u6db2\u7684\u8fdb\u5165\uff1b\uff082\uff09\u4f4e\u7ef4\u7684\u7eb3\u7c73\u5c3a\u5bf8\u5355\u5143\u53ef\u4ee5\u7f29\u77ed\u7535\u5b50\u548c\u79bb\u5b50\u7684\u4f20\u8f93\u8ddd\u79bb\uff0c\u4ece\u800c\u63d0\u9ad8\u6750\u6599\u7684\u500d\u7387\u6027\u80fd\uff1b\uff083\uff09\u5185\u90e8\u7684CuS\u9aa8\u67b6\u53ef\u4ee5\u63d0\u9ad8\u6750\u6599\u7684\u7535\u5b50\u7535\u5bfc\u7387\uff1b\uff084\uff09\u53cc\u58f3\u5c42\u7684\u7ed3\u6784\u53ef\u4ee5\u6539\u5584\u6750\u6599\u7684\u7ed3\u6784\u5b8c\u6574\u6027\uff0c\u4ece\u800c\u6709\u5229\u4e8e\u5f97\u5230\u597d\u7684\u5faa\u73af\u6027\u80fd\u3002\u56e0\u6b64\uff0c\u8be5\u6750\u6599\u8868\u73b0\u51fa\u4e86\u4f18\u5f02\u7684\u50a8\u94a0\u6027\u80fd\uff1a\uff081\uff09\u57280.1 A\u00a0g–<\/sup>1<\/sup>\uff0c\u6750\u6599\u7684\u6bd4\u5bb9\u91cf\u9ad8\u8fbe612 mAh g-1<\/sup>\uff1b\uff082\uff09\u57285\u00a0A\u00a0g–<\/sup>1<\/sup>\uff0c\u6750\u6599\u7684\u6bd4\u5bb9\u91cf\u4ecd\u7136\u6709304 mAh g-1<\/sup>\uff1b\uff083\uff09\u57280.1 A\u00a0g–<\/sup>1<\/sup>\u5faa\u73af500\u5708\u540e\uff0c\u5bb9\u91cf\u4fdd\u6301\u7387\u9ad8\u8fbe79%\u3002\uff08X. Wang, Y. Chen, Y. Fang, J. Zhang, S. Gao, X.W.D. Lou, Angew Chem Int Ed Engl, 58 (2019) 2675-2679\uff1bhttps:\/\/doi.org\/10.1002\/anie.201812387\uff09<\/p>\n \u56fe3\u00a0CuS@CoS2 DSNBs\u6750\u6599\u7684\u5236\u5907\u8fc7\u7a0b\u3002<\/p>\n \u540c\u65f6\uff0c\u697c\u96c4\u6587\u8bfe\u9898\u7ec4\u8fd8\u8bbe\u8ba1\u51fa\u4e86\u591a\u5c42\u786b\u5316\u94b4\u7eb3\u7c73\u76d2\u5b50\uff0c\u4ee5\u671f\u5236\u5907\u51fa\u9ad8\u6027\u80fd\u94a0\u79bb\u5b50\u7535\u6c60\u8d1f\u6781\u6750\u6599\u3002\u4f5c\u8005\u91c7\u7528MOFs\uff08ZIF-67\uff09\u4f5c\u4e3a\u8d77\u59cb\u539f\u6599\uff0c\u901a\u8fc7\u201c\u79bb\u5b50\u8f6c\u6362\u4ea4\u6362\u201d\u6cd5\u6765\u5236\u5907\u8be5\u591a\u5c42\u7eb3\u7c73\u76d2\u5b50\u3002\u901a\u8fc7\u8c03\u8282\u6eb6\u5242\u70ed\u53cd\u5e94\u7684\u6e29\u5ea6\u4ee5\u53caMOFs\u7684\u9897\u7c92\u5927\u5c0f\uff0c\u53ef\u4ee5\u7cbe\u786e\u63a7\u5236\u6750\u6599\u7684\u7ed3\u6784\uff0c\u4ece\u800c\u5f97\u5230\u5177\u6709\u4e0d\u540c\u5c42\u6570\u7684\u786b\u5316\u94b4\u7eb3\u7c73\u76d2\u5b50\uff08\u4ece2\u5c42\u52305\u5c42\uff09\uff0c\u5982\u56fe4\u6240\u793a\u3002\u8fd9\u79cd\u591a\u5c42\u7ed3\u6784\u7684\u4e2d\u7a7a\u6750\u6599\u76f8\u6bd4\u4e8e\u7b80\u5355\u7684\u5355\u5c42\u4e2d\u7a7a\u6750\u6599\u5177\u6709\u7740\u66f4\u9ad8\u7684\u6d3b\u6027\u7269\u8d28\u5360\u6bd4\uff0c\u56e0\u6b64\u6709\u5229\u4e8e\u63d0\u9ad8\u7535\u6781\u6750\u6599\u7684\u80fd\u91cf\u5bc6\u5ea6\u3002\u6b64\u5916\uff0c\u76f8\u6bd4\u4e8e\u7403\u5f62\u7684\u9897\u7c92\uff0c\u5728\u76f8\u540c\u7684\u4f53\u79ef\u4e0b\uff0c\u65b9\u5757\u72b6\u7eb3\u7c73\u76d2\u5b50\u5177\u6709\u7740\u66f4\u5927\u7684\u6bd4\u8868\u9762\u79ef\uff0c\u8fd9\u4e5f\u6709\u5229\u4e8e\u6750\u6599\u6027\u80fd\u7684\u53d1\u6325\u3002\u5c06\u8fd9\u4e9b\u6750\u6599\u7528\u4f5c\u94a0\u79bb\u5b50\u7535\u6c60\u8d1f\u6781\uff0c\u5b83\u4eec\u8868\u73b0\u51fa\u4e86\u8f83\u597d\u7684\u7535\u5316\u5b66\u6027\u80fd\u3002\u5176\u4e2d\uff0c\u4e09\u5c42\u7684\u7eb3\u7c73\u76d2\u5b50\u5177\u6709\u7740\u6700\u597d\u7684\u6027\u80fd\uff0c\u5728500 mA\u00a0g–<\/sup>1<\/sup>\u5faa\u73af100\u5708\u540e\uff0c\u5bb9\u91cf\u4ecd\u7136\u9ad8\u8fbe438 mAh g-1<\/sup>\u3002\uff08X. Wang, Y. Chen, Y. Fang, J. Zhang, S. Gao, X.W.D. Lou, Angew Chem Int Ed Engl, 58 (2019) 2675-2679\uff1bhttps:\/\/doi.org\/10.1002\/anie.201812387\uff09<\/p>\n \u56fe4\u00a0\u4e09\u5c42\uff0c\u56db\u5c42\uff0c\u4e94\u5c42\u548c\u4e24\u5c42\u786b\u5316\u94b4\u7eb3\u7c73\u76d2\u5b50<\/p>\n 3 <\/b><\/strong>\u9648\u519b \uff08\u5357\u5f00\u5927\u5b66\uff09<\/b><\/strong><\/p>\n \u5f53\u4eca\uff0c\u5546\u7528\u7684\u9502\u79bb\u5b50\u7535\u6c60\u6b63\u6781\u6750\u6599\u5168\u90e8\u662f\u65e0\u673a\u6750\u6599\u3002\u4f46\u8fd9\u5e76\u4e0d\u610f\u5473\u7740\u672a\u6765\u7684\u9502\u79bb\u5b50\u7535\u6c60\u6b63\u6781\u6750\u6599\u53ea\u53ef\u80fd\u662f\u65e0\u673a\u6750\u6599\u3002\u6700\u8fd1\uff0c\u8bb8\u591a\u7814\u7a76\u8005\u5df2\u7ecf\u5f00\u59cb\u5c06\u76ee\u5149\u7784\u51c6\u6709\u673a\u6750\u6599\uff0c\u5c24\u5176\u662f\u6709\u673a\u7fb0\u57fa\u5316\u5408\u7269\u3002\u8bb8\u591a\u7814\u7a76\u5df2\u7ecf\u8868\u660eC=O\u57fa\u56e2\u53ef\u4ee5\u4f5c\u4e3a\u6d3b\u6027\u4f4d\u70b9\u6765\u53ef\u9006\u7684\u8fdb\u884c\u50a8\u9502\u3002\u4e0d\u8fc7\u7531\u4e8e\u8bbe\u8ba1\u7684\u6709\u673a\u7269\u4e2d\u540c\u65f6\u542b\u6709\u8bb8\u591a\u975e\u6d3b\u6027\u7684\u57fa\u56e2\uff0c\u6750\u6599\u7684\u6bd4\u5bb9\u91cf\u5f80\u5f80\u6bd4\u8f83\u4f4e\uff08<600 mAh g-1<\/sup>\uff09\uff0c\u56e0\u6b64\u80fd\u91cf\u5bc6\u5ea6\u4e5f\u4e0d\u9ad8\uff08<1300 Wh\u00a0kg-1<\/sup>\uff09\u3002\u56e0\u6b64\uff0c\u5982\u4f55\u51cf\u5c11\u975e\u6d3b\u6027\u57fa\u56e2\u6bd4\u4f8b\u4ee5\u63d0\u9ad8\u6750\u6599\u7684\u6bd4\u5bb9\u91cf\u548c\u6bd4\u80fd\u91cf\u5c31\u663e\u5f97\u5f88\u91cd\u8981\u3002 \u00a0<\/p>\n \u57fa\u4e8e\u6b64\uff0c\u5357\u5f00\u5927\u5b66\u7684\u9648\u519b\u56e2\u961f\u63d0\u51fa\u53ef\u4ee5\u91c7\u7528\u73af\u72b6\u7684\u916e\uff0c\u6bd4\u5982C6<\/sub>O6<\/sub>\uff0c\u6765\u5236\u5907\u51fa\u9ad8\u5bb9\u91cf\u7684\u6709\u673a\u6b63\u6781\u6750\u6599\u3002\u8fd9\u662f\u56e0\u4e3a\u8be5\u6750\u6599\u6ca1\u6709\u4efb\u4f55\u591a\u4f59\u7684\u975e\u6d3b\u6027\u6210\u5206\u3002\u4f5c\u8005\u91c7\u7528C6<\/sub>O6<\/sub>\u00b78H2<\/sub>O\u4f5c\u4e3a\u539f\u6599\uff0c\u901a\u8fc7\u8131\u6c34\u53cd\u5e94\u6765\u5236\u5907C6<\/sub>O6<\/sub>\uff08\u56fe5d\uff09\u3002\u968f\u540e\u91c7\u7528\u5085\u91cc\u53f6\u53d8\u6362\u7ea2\u5916\u5149\u8c31\u548c\u62c9\u66fc\u5149\u8c31\u5bf9\u6750\u6599\u7684\u7535\u5316\u5b66\u53cd\u5e94\u6d3b\u6027\u4f4d\u70b9\u8fdb\u884c\u63ed\u793a\u3002\u6b64\u5916\uff0c\u4f5c\u8005\u4e5f\u91c7\u7528\u4e86DFT\u7406\u8bba\u8ba1\u7b97\u5bf9C6<\/sub>O6<\/sub>\u5728\u9502\u5316\u548c\u53bb\u9502\u5316\u8fc7\u7a0b\u4e2d\u6d3b\u6027\u4e2d\u5fc3\u548c\u4e00\u7cfb\u5217\u7ed3\u6784\u7684\u6f14\u53d8\u8fdb\u884c\u4e86\u9a8c\u8bc1\u3002\u7814\u7a76\u53d1\u73b0\uff0c\u4f5c\u4e3a\u9502\u79bb\u5b50\u7535\u6c60\u6b63\u6781\u6750\u6599\uff0cC6<\/sub>O6<\/sub>\u53ef\u4ee5\u653e\u51fa902 mAh g-1<\/sup>\u7684\u5bb9\u91cf\uff0c\u5e73\u5747\u653e\u7535\u7535\u538b\u4e3a1.7 V\uff0c\u5bf9\u5e94\u77401533 Wh\u00a0kg–<\/sup>1<\/sup>\u7684\u80fd\u91cf\u5bc6\u5ea6\u3002\u8fd9\u662f\u8fc4\u4eca\u4e3a\u6b62\u6709\u673a\u6b63\u6781\u6750\u6599\u4e2d\u6700\u597d\u7684\u6027\u80fd\u3002\u9664\u6b64\u4e4b\u5916\uff0c\u7d2b\u5916\u53ef\u89c1\u5149\u8c31\u7814\u7a76\u4e5f\u53d1\u73b0C6<\/sub>O6<\/sub>\u5728\u9ad8\u6781\u5316\u7684\u79bb\u5b50\u6db2\u4f53\u7535\u89e3\u6db2\u4e2d\u6eb6\u89e3\u5ea6\u6709\u9650\uff0c\u56e0\u6b64\u6750\u6599\u4e5f\u5177\u6709\u7740\u5f88\u597d\u7684\u5faa\u73af\u7a33\u5b9a\u6027\u3002\u572850 mA g-1<\/sup>\u7684\u7535\u6d41\u5bc6\u5ea6\u4e0b\u5faa\u73af100\u6b21\u540e\u5bb9\u91cf\u4fdd\u6301\u7387\u4e3a82%\u3002\u8fd9\u4e9b\u7ed3\u6784\u90fd\u8868\u660eC6<\/sub>O6<\/sub>\u662f\u4e00\u79cd\u5f88\u6709\u6f5c\u529b\u7684\u53ef\u6301\u7eed\u7684\u9502\u79bb\u5b50\u7535\u6c60\u6b63\u6781\u6750\u6599\u3002\uff08Y. Lu, X. Hou, L. Miao, L. Li, R. Shi, L. Liu, J. Chen, Angew Chem Int Ed Engl, (2019)\uff1bhttps:\/\/doi.org\/10.1002\/anie.201902185\uff09<\/p>\n \u56fe5\u00a0\uff08a\uff09\u8ba1\u7b97\u7535\u6781\u6750\u6599\u7406\u8bba\u5bb9\u91cf\u7684\u516c\u5f0f\uff1b\uff08b\uff09\u7406\u8bba\u8ba1\u7b97\u5f97\u5230\u7684Cn<\/sub>On<\/sub>\u7535\u6781\u7684\u5de5\u4f5c\u7535\u538b\u548c\u80fd\u5792\u5927\u5c0f\uff1b\uff08c\uff09C6<\/sub>O6<\/sub>\u7684TPOS\uff0cHOMO\u548cLUMO\uff1b\uff08d\uff09C6<\/sub>O6<\/sub>\u7684\u5236\u5907\u8def\u7ebf\u3002<\/p>\n \u56fe6\u00a0C6<\/sub>O6<\/sub>\u7684\u7535\u5316\u5b66\u6027\u80fd<\/p>\n \u7531\u4e8e\u94a0\u8d44\u6e90\u7684\u4e30\u5bcc\u6027\u4ee5\u53ca\u4f4e\u6c89\u672c\u7684\u7279\u70b9\uff0c\u8fd1\u4e9b\u5e74\u4eba\u4eec\u5bf9\u94a0\u7535\u6c60\u8fdb\u884c\u4e86\u5e7f\u6cdb\u7684\u7814\u7a76\u3002\u6700\u8fd1\uff0c\u53ef\u5145\u7535\u7684Na-CO2<\/sub>\u7535\u6c60\u5f15\u8d77\u4e86\u4eba\u4eec\u7684\u5173\u6ce8\u3002\u8fd9\u662f\u56e0\u4e3a\u5b83\u4e0d\u4ec5\u5177\u6709\u7740\u9ad8\u7684\u80fd\u91cf\u5bc6\u5ea6\uff081125 Wh\u00a0kg-1<\/sup>\uff09\uff0c\u800c\u4e14\u8fd8\u53ef\u4ee5\u5b9e\u73b0\u6e29\u5ba4\u6c14\u4f53CO2<\/sub>\u7684\u6e05\u6d01\u5229\u7528\u3002\u4e0d\u8fc7\uff0c\u8be5\u7535\u6c60\u4f7f\u7528\u4f20\u7edf\u7684\u6db2\u4f53\u7535\u89e3\u6db2\u5b58\u5728\u5f88\u5927\u7684\u5b89\u5168\u95ee\u9898\uff0c\u56e0\u6b64\u6025\u9700\u5f00\u53d1\u51fa\u9002\u7528\u4e8e\u94a0\u7535\u6c60\u7684\u56fa\u6001\u7535\u89e3\u8d28\u3002\u5176\u4e2d\uff0c\u6700\u5173\u952e\u7684\u6311\u6218\u662f\u6784\u5efa\u8d77\u4e00\u4e2a\u7a33\u5b9a\u7684Na\u8d1f\u6781\/\u56fa\u6001\u7535\u89e3\u8d28\u754c\u9762\uff0c\u8fd9\u662f\u56e0\u4e3a\u5927\u591a\u6570\u56fa\u6001\u7535\u89e3\u8d28\u5728\u76f4\u63a5\u4e0eNa\u63a5\u89e6\u65f6\u90fd\u4e0d\u7a33\u5b9a\u3002\u7425\u73c0\u8148\uff08SN\uff09\u662f\u4e00\u4e2a\u5178\u578b\u7684\u4f8b\u5b50\uff0c\u5b83\u5177\u6709\u7740\u9ad8\u7684\u5ba4\u6e29\u79bb\u5b50\u7535\u5bfc\u7387\uff0810–<\/sup>3<\/sup>\u00a0S\u00a0cm–<\/sup>1<\/sup>\uff09\uff0c\u4f46\u5374\u5f88\u5bb9\u6613\u5728\u4e0eNa\u91d1\u5c5e\u63a5\u89e6\u540e\u6076\u5316\uff0c\u9020\u6210\u754c\u9762\u963b\u6297\u6025\u5267\u589e\u52a0\u3002\u8fc4\u4eca\u4e3a\u6b62\uff0c\u6709\u4e24\u79cd\u529e\u6cd5\u53ef\u4ee5\u6784\u4ef6\u8d77\u56fa\u6001\u7535\u89e3\u8d28\u4e0eNa\u91d1\u5c5e\u7684\u7a33\u5b9a\u754c\u9762\u3002\u4e00\u662f\u91c7\u7528\u94a0\u5408\u91d1\u6765\u66ff\u4ee3\u91d1\u5c5e\u94a0\uff0c\u4e0d\u8fc7\u8fd9\u4f1a\u964d\u4f4e\u7535\u6c60\u7684\u80fd\u91cf\u5bc6\u5ea6\uff1b\u4e8c\u662f\u6dfb\u52a0\u7f13\u51b2\u5c42\uff0c\u4e0d\u8fc7\u8fd9\u4e5f\u4f1a\u589e\u52a0\u754c\u9762\u963b\u6297\u548c\u964d\u4f4e\u7535\u6c60\u80fd\u91cf\u5bc6\u5ea6\uff0c\u4e14\u53ea\u6709\u7406\u8bba\u8ba1\u7b97\u800c\u65e0\u5b9e\u9a8c\u8bc1\u660e\u3002\u56e0\u6b64\uff0c\u5982\u4f55\u5f00\u53d1\u4e00\u79cd\u6709\u6548\u7684\u7b56\u7565\u4ee5\u5f97\u5230\u4e00\u4e2a\u76f8\u5bb9\u7684\u56fa\u6001\u7535\u89e3\u8d28\/Na\u91d1\u5c5e\u754c\u9762\u5e76\u907f\u514d\u526f\u53cd\u5e94\u7684\u53d1\u751f\u5c31\u663e\u5f97\u7279\u522b\u91cd\u8981\u3002<\/p>\n \u5728\u6b64\uff0c\u9648\u519b\u8bfe\u9898\u7ec4\u5c31\u63d0\u51fa\u4e86\u4e00\u79cd\u975e\u5e38\u7b80\u5355\u7684\u65b9\u6cd5\u6765\u5b9e\u73b0SN\u57fa\u7535\u89e3\u8d28\u4e0eNa\u91d1\u5c5e\u95f4\u7684\u7a33\u5b9a\u76f8\u5904\uff0c\u5373\u662f\u5728\u4e8c\u8005\u4e4b\u95f4\u6784\u5efa\u4e00\u4e2a\u5bccNaF\u7684\u4e2d\u95f4\u76f8\u3002\u4f5c\u8005\u662f\u91c7\u75281\u00a0M NaClO4<\/sub>\/FEC\u6765\u5bf9\u94a0\u91d1\u5c5e\u8fdb\u884c\u5316\u5b66\u5904\u7406\u4ece\u800c\u5f97\u5230\u5bccNaF\u7684\u4e2d\u95f4\u76f8\u7684\u3002\u8be5\u539f\u4f4d\u5f62\u6210\u7684\u5bccNaF\u7684\u4e2d\u95f4\u76f8\u4e0d\u4ec5\u53ef\u4ee5\u963b\u6b62SN\u57fa\u7535\u89e3\u8d28\u4e0eNa\u91d1\u5c5e\u95f4\u7684\u526f\u53cd\u5e94\uff0c\u800c\u4e14\u8fd8\u53ef\u4ee5\u5b9e\u73b0Na\u91d1\u5c5e\u5747\u5300\uff0c\u65e0\u679d\u6676\u7684\u6c89\u79ef\u3002\u7535\u5316\u5b66\u6d4b\u8bd5\u8868\u660e\uff0c\u6784\u5efa\u7684\u5bf9\u79f0\u7535\u6c60\u5728\u5faa\u73af4000 h\u540e\uff0c\u8fc7\u7535\u52bf\u4ecd\u7136\u53ea\u6709150 mV\u3002\u5168\u56fa\u6001Na-CO2<\/sub>\u7535\u6c60\u4e5f\u53ef\u4ee5\u8fd0\u884c50\u5708\uff0c\u800c\u4e14\u8fc7\u7535\u52bf\u4e5f\u4ec5\u589e\u52a00.33 V\u3002\u4e0e\u6b64\u540c\u65f6\uff0c\u8be5\u8bbe\u8ba1\u601d\u60f3\u4e5f\u53ef\u4ee5\u7528\u4e8e\u5176\u4ed6\u5168\u56fa\u6001Na\u91d1\u5c5e\u7535\u6c60\u4e2d\u53bb\uff0c\u6bd4\u5982Na\/Na3<\/sub>V2<\/sub>(PO4<\/sub>)3<\/sub>\u7535\u6c60\u3002\uff08Y. Lu, Y. Cai, Q. Zhang, L. Liu, Z. Niu, J. Chen, Chemical Science, 10 (2019) 4306-4312\uff1bhttps:\/\/doi.org\/10.1039\/c8sc05178j\uff09<\/p>\n \u56fe7\u00a0\u4e0d\u540c\u7684\u94a0\u91d1\u5c5e\u4e0eSN\u57fa\u56fa\u6001\u7535\u89e3\u8d28\u95f4\u7684\u76f8\u5bb9\u6027<\/p>\n 4 <\/b><\/strong>\u9ea6\u7acb\u5f3a \uff08\u6b66\u6c49\u7406\u5de5\u5927\u5b66\uff09<\/b><\/strong><\/p>\n \u9ea6\u7acb\u5f3a\u8001\u5e08\u8bfe\u9898\u7ec4\u540c\u6837\u4e5f\u7d27\u5bc6\u5173\u6ce8\u94a0\u79bb\u5b50\u7535\u6c60\u7684\u7814\u7a76\u8fdb\u5c55\u3002\u4ece\u50a8\u91cf\u548c\u6210\u672c\u6765\u770b\uff0c\u5bf9\u4e8e\u50a8\u80fd\u7535\u7ad9\uff0c\u94a0\u79bb\u5b50\u7535\u6c60\u53ef\u80fd\u662f\u672a\u6765\u6700\u4f18\u7684\u9009\u62e9\u3002\u800c\u5f00\u53d1\u5177\u6709\u591a\u7535\u5b50\u53cd\u5e94\u7684\u7535\u6781\u6750\u6599\u662f\u5b9e\u73b0\u5177\u6709\u9ad8\u6bd4\u5bb9\u91cf\u548c\u80fd\u91cf\u5bc6\u5ea6\u7684\u94a0\u79bb\u5b50\u7535\u6c60\u4e00\u5927\u5173\u952e\u3002\u7531\u4e8eNASICON\u7ed3\u6784\u7684\u5316\u5408\u7269\u5177\u6709\u7740\u7a33\u5b9a\u76843D\u6846\u67b6\u548c\u5927\u7684Na\u79bb\u5b50\u6269\u6563\u901a\u9053\uff0c\u5b83\u88ab\u8ba4\u4e3a\u975e\u5e38\u9002\u7528\u4e8e\u94a0\u79bb\u5b50\u7535\u6c60\uff0c\u56e0\u6b64\u4eba\u4eec\u5bf9\u5404\u79cdNASICON\u7ed3\u6784\u7684\u6750\u6599\u8fdb\u884c\u4e86\u5e7f\u6cdb\u7684\u50a8\u94a0\u7814\u7a76\uff0c\u6bd4\u5982Na3<\/sub>MnTi(PO4<\/sub>)3<\/sub>\uff0cNa3<\/sub>VTi(PO4<\/sub>)3<\/sub>\uff0cNa3<\/sub>MnV(PO4<\/sub>)3<\/sub>\u7b49\u7b49\u3002\u4f46\u662f\uff0c\u6240\u6709\u8fc4\u4eca\u4e3a\u6b62\u62a5\u9053\u7684NASICON\u7ed3\u6784\u7684\u5316\u5408\u7269\u6700\u591a\u53ea\u80fd\u5b9e\u73b02\u7535\u5b50\u7684\u53cd\u5e94\u3002\u56e0\u6b64\uff0c\u63a2\u7d22\u51fa\u80fd\u5b9e\u73b0\u7a33\u5b9a\u76843\u7535\u5b50\u53cd\u5e94\u7684NASICON\u7ed3\u6784\u7684\u6b63\u6781\u6750\u6599\u5c31\u663e\u5f97\u6781\u5177\u6709\u6311\u6218\u6027\u3002<\/p>\n \u9488\u5bf9\u8fd9\u4e2a\u6311\u6218\uff0c\u9ea6\u7acb\u5f3a\u7ec4\u91c7\u7528\u55b7\u96fe\u5e72\u71e5\u8f85\u52a9\u7684\u65b9\u6cd5\u5236\u5907\u51fa\u4e86NASICON\u7ed3\u6784\u7684Na3<\/sub>MnTi(PO4<\/sub>)3<\/sub>\/C\u4e2d\u7a7a\u5fae\u7c73\u7403\uff0c\u6210\u529f\u5b9e\u73b0\u4e86\u4e09\u7535\u5b50\u7684\u6c27\u5316\u8fd8\u539f\u53cd\u5e94\u3002\u5b83\u7684\u4e09\u7535\u5b50\u53cd\u5e94\u5206\u522b\u6765\u81eaTi3<\/sup>+\/<\/sup>4+<\/sup>(~2.1 V)\uff0cMn2<\/sup>+\/<\/sup>3+<\/sup>(~3.5 V)\u548cMn3<\/sup>+\/<\/sup>4+<\/sup>(~4.0 V)\u6c27\u5316\u7535\u5bf9\u3002\u56e0\u6b64\uff0c\u8be5\u6750\u6599\u8868\u73b0\u51fa\u4e86\u9ad8\u7684\u6bd4\u5bb9\u91cf\uff080.2 C\u65f6\u5bb9\u91cf\u4e3a160 mAh g-1<\/sup>\uff09\u3002\u4e0e\u6b64\u540c\u65f6\uff0cNASICON\u7ed3\u6784\u7a33\u5b9a\u5f00\u653e\u7684\u6846\u67b6\u4e5f\u4f7f\u5f97\u6750\u6599\u5177\u6709\u7a33\u5b9a\u7684\u5faa\u73af\u6027\u80fd\uff0c2\u00a0C\u5faa\u73af500\u5708\u540e\u5bb9\u91cf\u4fdd\u6301\u7387\u4ecd\u7136\u9ad8\u8fbe90%\u3002\u539f\u4f4dX\u5c04\u7ebf\u884d\u5c04\u7ed3\u679c\u8868\u660e\u6750\u6599\u5728\u8fdb\u884c\u94a0\u5316\/\u53bb\u94a0\u5316\u7684\u65f6\u5019\u6240\u53d1\u751f\u7684\u7535\u5316\u5b66\u53cd\u5e94\u673a\u7406\u4e3a\u56fa\u6eb6\u53cd\u5e94\u673a\u7406\u548c\u4e24\u76f8\u53cd\u5e94\u673a\u7406\u3002\uff08T. Zhu, P. Hu, X. Wang, Z. Liu, W. Luo, K.A. Owusu, W. Cao, C. Shi, J. Li, L. Zhou, L. Mai, Advanced Energy Materials, 9 (2019)\uff1bhttps:\/\/doi.org\/10.1002\/aenm.201803436\uff09<\/p>\n \u56fe8\u00a0Na3<\/sub>MnTi(PO4<\/sub>)3<\/sub>\/C\u7684\u7535\u5316\u5b66\u6027\u80fd<\/p>\n \u9664\u4e86\u94a0\u79bb\u5b50\u7535\u6c60\uff0c\u6c34\u7cfb\u950c\u79bb\u5b50\u7535\u6c60\u4e5f\u53d7\u5230\u4e86\u5e7f\u6cdb\u7684\u5173\u6ce8\uff0c\u5b83\u4e5f\u975e\u5e38\u6709\u5e0c\u671b\u5e94\u7528\u5728\u50a8\u80fd\u7535\u7ad9\u4e0a\u3002\u6c34\u7cfb\u950c\u79bb\u5b50\u7535\u6c60\u7684\u8d1f\u6781\u662f\u91d1\u5c5e\u950c\uff0c\u6bd4\u5bb9\u91cf\u4e3a820 mAh g-1<\/sup>\uff0c\u800c\u6c34\u7cfb\u950c\u79bb\u5b50\u7535\u6c60\u6b63\u6781\u6750\u6599\u53ef\u4ee5\u5206\u4e3a\u4e09\u5927\u7c7b\uff1a\u9530\u57fa\u6750\u6599\uff0c\u666e\u9c81\u58eb\u84dd\u548c\u9492\u57fa\u6750\u6599\u3002\u9530\u57fa\u6750\u6599\u7684\u7f3a\u70b9\u662f\u5728\u5faa\u73af\u65f6\u8870\u51cf\u5f88\u5feb\uff0c\u666e\u9c81\u58eb\u84dd\u53ca\u5176\u7c7b\u4f3c\u7269\u6750\u6599\u7684\u7f3a\u70b9\u662f\u5bb9\u91cf\u8f83\u4f4e\uff08~50 mAh g-1<\/sup>\uff09\u3002\u9492\u57fa\u6750\u6599\u5177\u6709\u7740\u6bd4\u8f83\u9ad8\u7684\u6bd4\u5bb9\u91cf\uff0c\u4e0d\u8fc7\u4e5f\u5b58\u5728\u7740\u653e\u7535\u7535\u538b\u4f4e\u7684\u7f3a\u70b9\uff0c\u8fd9\u4f7f\u5f97\u5b83\u4eec\u5728\u80fd\u91cf\u5bc6\u5ea6\u4e0a\u4e0d\u5177\u6709\u7ade\u4e89\u529b\u3002\u8003\u8651\u5230NASICON\u7ed3\u6784\u7684Na3<\/sub>V2<\/sub>(PO4<\/sub>)3<\/sub>\u53ef\u4ee5\u5bf9\u78b1\u91d1\u5c5e\u79bb\u5b50\u53ca\u591a\u4ef7\u91d1\u5c5e\u79bb\u5b50\u8fdb\u884c\u5b58\u50a8\uff0c\u4eba\u4eec\u4e5f\u5e0c\u671b\u5c06\u5b83\u5e94\u7528\u5728\u950c\u79bb\u5b50\u7535\u6c60\u4e0a\u3002\u7814\u7a76\u53d1\u73b0\uff0c\u91c7\u7528\u918b\u9178\u950c\u4f5c\u4e3a\u7535\u89e3\u6db2\uff0cNa3<\/sub>V2<\/sub>(PO4<\/sub>)3<\/sub>\u5728\u5145\u7535\u65f6\u4f1a\u5c06Na\u79bb\u5b50\u8131\u51fa\uff0c\u968f\u540e\u53ef\u9006\u5730\u63d2\u5165\/\u8131\u51fa\u950c\u79bb\u5b50\u3002\u5982\u679c\u91c7\u7528\u918b\u9178\u94a0\u548c\u918b\u9178\u950c\u7684\u6df7\u5408\u6eb6\u6db2\u4f5c\u4e3a\u7535\u89e3\u6db2\uff0c\u5219Na\u79bb\u5b50\u53ef\u4ee5\u53ef\u9006\u5730\u63d2\u5165\/\u8131\u51faNa3<\/sub>V2<\/sub>(PO4<\/sub>)3<\/sub>\u9aa8\u67b6\u3002\u4e0d\u8fc7\uff0c\u5728\u5355\u4e00\u6210\u5206\u7684\u7535\u89e3\u6db2\u4e0b\u8fd8\u6ca1\u6709\u540c\u65f6\u5b9e\u73b0Zn\u79bb\u5b50\u548cNa\u79bb\u5b50\u5171\u540c\u63d2\u5165\/\u8131\u51fa\u3002<\/p>\n \u9488\u5bf9\u4e0a\u8ff0\u95ee\u9898\uff0c\u4f5c\u8005\u5236\u5907\u4e86\u8fd8\u539f\u6c27\u5316\u77f3\u58a8\u70ef\u5305\u8986\u7684Na3<\/sub>V2<\/sub>(PO4<\/sub>)3<\/sub>\u6750\u6599\uff0c\u91c7\u7528\u5355\u4e00\u76842.0 M Zn(CF3<\/sub>SO3<\/sub>)2<\/sub>\u4f5c\u4e3a\u7535\u89e3\u6db2\uff0c\u4ee5\u671f\u80fd\u591f\u5b9e\u73b0Zn\u79bb\u5b50\u548cNa\u79bb\u5b50\u5171\u540c\u63d2\u5165\/\u8131\u51fa\u3002\u7814\u7a76\u53d1\u73b0\uff0c\u6750\u6599\u5728\u9996\u6b21\u5145\u7535\u65f6\u4f1a\u8131\u51fa\u90e8\u5206Na\u79bb\u5b50\uff0c\u5728\u968f\u540e\u7684\u5145\u653e\u7535\u8fc7\u7a0b\u4e2d\u5b9e\u73b0\u4e86Zn\u79bb\u5b50\u548cNa\u79bb\u5b50\u5171\u540c\u63d2\u5165\/\u8131\u51fa\uff0c\u5982\u56fe10\u6240\u793a\u3002\u8be5\u6750\u6599\u572850 mA\u00a0g-1<\/sup>\u7684\u7535\u6d41\u5bc6\u5ea6\u4e0b\uff0c\u653e\u7535\u6bd4\u5bb9\u91cf\u4e3a114 mAh g-1<\/sup>\u4e14\u5e73\u5747\u653e\u7535\u7535\u538b\u9ad8\u8fbe1.23 V\u3002\u6b64\u5916\uff0c\u6750\u6599\u8fd8\u5177\u6709\u7740\u7a33\u5b9a\u7684\u5faa\u73af\u6027\u80fd\uff0c50 mA\u00a0g-1<\/sup>\u7535\u6d41\u5bc6\u5ea6\u4e0b\u5faa\u73af200\u5708\u540e\u5bb9\u91cf\u4ecd\u7136\u9ad8\u8fbe74 mAh g-1<\/sup>\u3002\u5176\u4f18\u8d8a\u7684\u7535\u5316\u5b66\u6027\u80fd\u8d77\u6e90\u4e8e\u5176\u7a33\u5b9a\u5f00\u653e\u7684NASICON\u7ed3\u6784\uff0c\u5feb\u901f\u7684\u79bb\u5b50\u4f20\u8f93\u901f\u5ea6\u4ee5\u53ca\u8fde\u7eed\u7684\u7535\u5b50\u4f20\u5bfc\u7279\u6027\u3002\u8be5\u5de5\u4f5c\u4e5f\u7ed9\u4eba\u4eec\u5f00\u53d1\u5355\u4e00\u6210\u5206\u7535\u89e3\u6db2\u4e0b\u6df7\u5408\u79bb\u5b50\u63d2\u5165\/\u8131\u51fa\u578b\u4e8c\u6b21\u7535\u6c60\u63d0\u4f9b\u4e86\u501f\u9274\u3002\uff08P. Hu, T. Zhu, X. Wang, X. Zhou, X. Wei, X. Yao, W. Luo, C. Shi, K.A. Owusu, L. Zhou, L. Mai, Nano Energy, 58 (2019) 492-498\uff1bhttps:\/\/doi.org\/10.1016\/j.nanoen.2019.01.068\uff09<\/p>\n \u56fe9\u00a0NVP@rGO\u7684XRD\uff0cSEM\u548cTEM\u8868\u5f81<\/p>\n \u56fe10 \uff08c\uff09NVP@rGO\u7684\u975e\u539f\u4f4dXRD\u56fe\uff1b\uff08d\uff09\u79bb\u5b50\u5728NVP@rGO\u4e2d\u63d2\u5165\u8131\u51fa\u7684\u793a\u610f\u56fe<\/p>\n <\/p>\n \u5f80\u671f\u56de\u987e\uff1a<\/strong><\/p>\n \u7535\u6c60\u6027\u80fd\u63d0\u5347\u9047\u5230\u74f6\u9888\uff1f\u4f60\u8bbe\u8ba1\u7684\u65f6\u5019\u53ef\u80fd\u5c11\u8003\u8651\u4e86\u5b83<\/a><\/p>\n \u9502\u7535\u7814\u7a76\u4f60\u5fc5\u987b\u8981\u4e86\u89e3\u7684\u9502\u7535\u5b89\u5168\u77e5\u8bc6\uff01<\/a><\/p>\n \u534e\u4e3a5G\u6298\u53e0\u5c4f\u65f6\u4ee3\u5df2\u6765\u4e34\uff1f\uff01\u67d4\u6027\u7535\u6c60\u7684\u4eff\u751f\u5b66\u7075\u611f\u6765\u81ea\u54ea\u91cc\uff1f<\/a><\/p>\n \u201c\u6298\u53e0\u5c4f\u201d\u7684\u4e0b\u4e00\u7ad9\uff0c\u5168\u67d4\u6027\u7535\u5b50\u5668\u4ef6\u7684\u5173\u952e\uff1a\u67d4\u6027\u9502\u7535\u6c60\u84c4\u52bf\u5f85\u53d1<\/a><\/p>\n
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