{"id":174339,"date":"2019-04-29T06:30:26","date_gmt":"2019-04-28T22:30:26","guid":{"rendered":"\/\/m.iemloyee.com\/?p=174339"},"modified":"2019-04-28T11:53:42","modified_gmt":"2019-04-28T03:53:42","slug":"%e8%82%96%e6%b3%bd%e6%96%87-%e9%84%a2%e7%82%8e%e5%8f%91%e6%95%99%e6%8e%88am%e8%89%af%e5%bf%83%e7%bb%bc%e8%bf%b0%ef%bc%9a%e9%92%99%e9%92%9b%e7%9f%bf%e6%97%a0%e9%93%85%e5%8c%96%e7%9a%84","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=174339","title":{"rendered":"\u8096\u6cfd\u6587\/\u9122\u708e\u53d1\u6559\u6388AM\u826f\u5fc3\u7efc\u8ff0\uff1a\u9499\u949b\u77ff\u65e0\u94c5\u5316\u7684\u201c\u56e0\u201d\u4e0e\u201c\u679c\u201d"},"content":{"rendered":"
\u3010\u5f15\u8a00<\/strong>\u3011<\/b><\/p>\n \u94c5\u57fa\u5364\u5316\u7269\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u56e0\u5176\u4f18\u5f02\u7684\u5149\u7535\u6027\u80fd\u548c\u4f4e\u5236\u4f5c\u6210\u672c\uff08\u4f4e\u95e8\u69db\uff09\u800c\u6210\u4e3a\u5f53\u4eca\u7814\u7a76\u70ed\u70b9\u3002\u7136\u800c\uff0c\u5176\u6b20\u4f73\u7684\u7a33\u5b9a\u6027\u548c\u94c5\u7684\u6bd2\u6027\uff0c\u4f7f\u5176\u5546\u4e1a\u5316\u9762\u4e34\u6311\u6218\u3002\u56e0\u6b64\uff0c\u5bfb\u627e\u65e0\u6bd2\u3001\u7a33\u5b9a\u3001\u9ad8\u6548\u7684\u9499\u949b\u77ff\u578b\u592a\u9633\u80fd\u7535\u6c60\u6750\u6599\u6210\u4e86\u53c8\u4e00\u7814\u7a76\u70ed\u70b9\u3002\u7136\u800c\uff0c\u5728\u592a\u9633\u80fd\u7535\u6c60\u5e94\u7528\u65b9\u9762\uff0c\u76ee\u524d\u6240\u5f97\u7684\u201c\u65e0\u94c5\u201d\u9499\u949b\u77ff\u7686\u65e0\u6cd5\u4e0e\u94c5\u57fa\u9499\u949b\u77ff\u76f8\u5ab2\u7f8e\u3002<\/p>\n \u3010\u6210\u679c\u7b80\u4ecb<\/strong>\u3011<\/b><\/p>\n \u6700\u8fd1\uff0c\u534e\u4e2d\u79d1\u6280\u5927\u5b66\u6b66\u6c49\u5149\u7535\u56fd\u5bb6\u7814\u7a76\u4e2d\u5fc3\u8096\u6cfd\u6587(<\/b><\/strong>Zewen Xiao)<\/b><\/strong>\u6559\u6388<\/b><\/strong>\u4e0e\u7f8e\u56fdToledo\u5927\u5b66\u7269\u7406\u4e0e\u5929\u6587\u5b66\u7cfb\u5b8b\u8087\u5b81(<\/b><\/strong>Zhaoning Song)<\/b><\/strong>\u52a9\u7406\u6559\u6388\u548c\u9122\u708e\u53d1(<\/b><\/strong>Yanfa Yan)<\/b><\/strong>\u6559\u6388<\/b><\/strong>\u5408\u4f5c\uff0c\u5728 Advanced<\/b><\/strong>\u00a0<\/b><\/strong>Materials<\/b><\/strong>\u00a0<\/b><\/strong>\u4e0a\u53d1\u8868\u4e86\u4e00\u7bc7\u540d\u4e3a\u201cFrom Lead Halide Perovskites to Lead-Free Metal<\/b><\/strong>\u00a0<\/b><\/strong>Halide Perovskites and Perovskite Derivatives<\/b><\/strong>\u201d\u7684\u7279\u9080\u7efc\u8ff0\u6587\u7ae0\u3002<\/p>\n 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\uff08ii\uff09\u4ee5\u65e0\u6bd2\u7684\u5f02\u4ef7\u5143\u7d20In(I)\u3001Sb(III)\u548cBi(III)\u548c\u540c\u4ef7\u5143\u7d20Ge(II)\u3001Sn(II)\u7b49\u66ff\u4ee3Pb\u53ef\u4ee5\u7ef4\u6301\u5b64\u5bf9s\u7535\u5b50\u548c\u975e\u6d3b\u6027p\u8f68\u9053\u7684\u7535\u5b50\u7279\u6027\u3002In(I)\u7531\u4e8e\u9ad8\u80fd\u91cf\u76845s\u8f68\u9053\u5bfc\u81f4\u5176\u6781\u4e0d\u7a33\u5b9a\uff1bSb(III)\u548cBi(III)\u5219\u4f1a\u5bfc\u81f4\u9499\u949b\u77ff\u5177\u6709\u4f4e\u7ef4\u7ed3\u6784\u6216\u4f4e\u7535\u5b50\u7ef4\u5ea6\uff0c\u8fd9\u6781\u5927\u5730\u9650\u5236\u4e86\u57fa\u4e8e\u5b83\u4eec\u5236\u4f5c\u7684\u592a\u9633\u80fd\u7535\u6c60\u7684\u6027\u80fd\u3002\u4f46\u662f\uff0c\u8fd9\u4e9b\u5316\u5408\u7269\u5728\u5149\u7535\u63a2\u6d4b\u5668\u548c\u53d1\u5149\u5668\u4ef6\u7b49\u5176\u4ed6\u5e94\u7528\u4e2d\u6781\u5177\u6f5c\u529b\u3002<\/b><\/strong><\/p>\n \uff08iii\uff09\u7528Sn(II)\u6216Ge(II)\u66ff\u4ee3Pb(II)\u7684\u9499\u949b\u77ff\u7ed3\u6784\u80fd\u591f\u7ef4\u6301\u4e09\u7ef4\u7ed3\u6784\u548c\u7535\u5b50\u7ef4\u5ea6\u3002\u7531\u4e8e\u5177\u6709\u66f4\u4f4e\u7684\u6210\u672c\u548c\u66f4\u9ad8\u7684\u7a33\u5b9a\u6027\uff0cSn(II)\u662f\u6bd4Ge(II)\u66f4\u597d\u7684\u9009\u62e9\u3002 \u5b9e\u9645\u4e0a\uff0cSn\u57fa\u7535\u6c60\u5df2\u7ecf\u5728\u65e0\u94c5\u5364\u5316\u7269\u9499\u949b\u77ff\u7535\u6c60\u4e2d\u8868\u73b0\u51fa\u4e86\u6700\u597d\u7684\u6548\u679c\u3002\u56e0\u4e3aSn\u76845s\u80fd\u91cf\u9ad8\u4e8ePb\u76846s\uff0c \u5bfc\u81f4\u7a33\u5b9a\u6027\u4e0d\u5982\u94c5\u5364\u5316\u7269\u9499\u949b\u77ff\u3002\u8fdb\u4e00\u6b65\u63d0\u9ad8Sn\u57fa\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u6548\u7387\u7684\u65b9\u6cd5\u5305\u62ec\u4f7f\u7528\u4e8c\u7ef4\u4e09\u7ef4\u6df7\u5408\u7ed3\u6784\u6765\u907f\u514dSn\u7684\u635f\u5931\uff0c\u63ba\u5165\u65bd\u4e3b\u5143\u7d20\u6216\u8005\u6297\u6c27\u5316\u5242\u7b49\u3002<\/p>\n \u867d\u7136\u5bf9\u4e8e\u65e0\u94c5\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u7684\u7814\u7a76\u4ecd\u7136\u9762\u4e34\u6311\u6218\uff0c\u4f46\u662f\u76ee\u524d\u7684\u7814\u7a76\u8fdb\u5c55\u4ecd\u7136\u5bf9\u6b64\u9886\u57df\u4ea7\u751f\u4e86\u91cd\u5927\u5f71\u54cd\uff0c\u8fd9\u4ecd\u5c06\u662f\u4e00\u4e2a\u6781\u5177\u5438\u5f15\u529b\u7684\u7814\u7a76\u65b9\u5411\u3002<\/p>\n \u3010\u56fe\u6587\u5bfc\u8bfb<\/strong>\u3011<\/b><\/p>\n \u56fe1\u94c5\uff08Pb\uff09\u5143\u7d20\u66ff\u6362\u5404\u79cd\u65b9\u6cd5\u548c\u7ed3\u679c\u793a\u610f\u56fe<\/b><\/strong><\/p>\n \u56fe2<\/b><\/strong>\u00a0<\/b><\/strong>\u94c5\u57fa\u5364\u5316\u7269\u9499\u949b\u77ff\u7684\u9ad8\u5149\u5b66\u5438\u6536\u6548\u7387<\/b><\/strong><\/p>\n \uff08a\uff09Si(\u5de6)\u3001GaAs(\u4e2d)\u548cMAPbI3<\/sub>\u9499\u949b\u77ff(\u53f3)\u7684\u5149\u5438\u6536\u539f\u7406\u56fe\u3002<\/p>\n \uff08b\uff09MAPbI3<\/sub>\u548cGaAs\u7684\u6001\u5bc6\u5ea6\u793a\u610f\u56fe\u3002<\/p>\n \uff08c\uff09MAPbI3<\/sub>\u548cGaAs\u7684\u8054\u5408\u6001\u5bc6\u5ea6\u793a\u610f\u56fe\u3002<\/p>\n \uff08d\uff09MAPbI3<\/sub>\u548cGaAs\u7684\u5149\u5b66\u5438\u6536\u8c31\u3002<\/p>\n \uff08e\uff09\u7406\u8bba\u8ba1\u7b97\u5f97\u5230\u7684MAPbI3<\/sub>\u3001CIS\u3001CZTS\u3001GaAs\u7684\u6700\u5927\u6548\u7387\u968f\u819c\u539a\u7684\u53d8\u5316\u66f2\u7ebf\u3002<\/p>\n \u56fe3<\/b><\/strong>\u00a0<\/b><\/strong>\u94c5\u57fa\u5364\u5316\u7269\u9499\u949b\u77ff\u7684\u80fd\u5e26\u7ed3\u6784\uff1a\u4f4e\u8f7d\u6d41\u5b50\u6709\u6548\u8d28\u91cf<\/b><\/strong><\/p>\n \u00a0 \uff08a\uff09LDA\u8ba1\u7b97\u7684\u7acb\u65b9CsPbI3<\/sub>\u9499\u949b\u77ff\u7684\u80fd\u5e26\u7ed3\u6784\u793a\u610f\u56fe\u3002<\/p>\n \uff08b\uff09GW+SOC\u8ba1\u7b97\u7684MAPbI3<\/sub>\u7684\u80fd\u5e26\u7ed3\u6784\u793a\u610f\u56fe<\/p>\n \u56fe4<\/b><\/strong>\u00a0<\/b><\/strong>\u94c5\u57fa\u5364\u5316\u7269\u9499\u949b\u77ff\u7684\u9ad8\u7f3a\u9677\u5bb9\u5fcd\u6027<\/b><\/strong><\/p>\n \u00a0 \uff08a\uff09\u5728\u94c5\u5364\u5316\u7269\u9499\u949b\u77ff\u4e2dCBM\u548cCBM\u7f3a\u9677\u5f62\u6210\u793a\u610f\u56fe(\u5de6)\uff0c\u9633\u79bb\u5b50\u548c\u9634\u79bb\u5b50\u5f62\u6210\u7684\u65bd\u4e3b\u548c\u53d7\u4e3b\u7f3a\u9677\u793a\u610f\u56fe(\u4e2d)\uff0c\u9633\u79bb\u5b50-\u9633\u79bb\u5b50\u548c\u9634\u79bb\u5b50-\u9634\u79bb\u5b50\u8bef\u6210\u952e\u7684\u7f3a\u9677\u793a\u610f\u56fe(\u53f3)\u3002<\/p>\n \uff08b\uff09MAPbI3<\/sub>\u4e2d\u70b9\u7f3a\u9677\u7684\u8fc7\u6e21\u80fd\u7ea7\u56fe\u3002<\/p>\n \uff08c\uff09\u5206\u522b\u5728\u5728\u5bccI\/\u8d2bPb(\u5de6), \u4e2d\u6027(\u4e2d)\u548c\u5bccPb\/\u8d2bI\u7684\u5316\u5b66\u6761\u4ef6\u4e0b\u7684MAPbI3<\/sub>\u7684\u56fa\u6709\u70b9\u7f3a\u9677\u5f62\u6210\u80fd\u3002<\/p>\n \uff08d\uff09\u6df7\u5408\u94c5\u5364\u5316\u7269\u9499\u949b\u77ff\u4e2d\u7684\u5927\u6781\u5316\u5b50\u793a\u610f\u56fe\u3002<\/p>\n \u56fe5 \u4f18\u4e8e\u4f20\u7edf\u7ed3\u6784\u7ef4\u5ea6\u7684\u7535\u5b50\u7ef4\u5ea6\u65b0\u6982\u5ff5<\/b><\/strong><\/p>\n \u00a0 \uff08a\uff09\u4e0d\u540c\u7ef4\u5ea6\u9499\u949b\u77ff\u7ed3\u6784\u7684\u6676\u4f53\u7ed3\u6784\u56fe\uff0c\u4ece\u5de6\u81f3\u53f3\u5206\u522b\u4e3a3D\u30012D\u30011D\u548c0D\u3002<\/p>\n \uff08b\uff09\u4e0d\u540c\u7ef4\u5ea6\u9499\u949b\u77ff\u7ed3\u6784\u7684\u80fd\u5e26\u7ed3\u6784\u56fe\u3002<\/p>\n \uff08c\uff09\u4e0d\u540c\u7ef4\u5ea6\u9499\u949b\u77ff\u7ed3\u6784\u7684\u5149\u5b66\u5438\u6536\u5149\u8c31\u3002<\/p>\n \uff08d\uff09\u4e09\u7ef4\u7ed3\u6784\u7684Cs2<\/sub>PbPbI6<\/sub>(\u5de6)\u548cCs2<\/sub>Sr[PbI6<\/sub>](\u53f3)\u7684\u6676\u4f53\u7ed3\u6784\u56fe\u3002<\/p>\n \uff08e\uff09Cs2<\/sub>PbPbI6<\/sub>(\u5de6)\u548cCs2<\/sub>Sr[PbI6<\/sub>](\u53f3)\u7684\u80fd\u5e26\u7ed3\u6784\u56fe\u3002<\/p>\n \uff08f\uff09Cs2<\/sub>PbPbI6<\/sub>(\u5de6)\u548cCs2<\/sub>Sr[PbI6<\/sub>](\u53f3)\u7684(100)\u9762VBM\u548cCBM\u7684\u7535\u8377\u5bc6\u5ea6\u56fe\u3002<\/p>\n \u56fe6<\/b><\/strong>\u00a0<\/b><\/strong>\u540c\u4ef7\u66ff\u6362\uff08\u4e00\uff09\uff1a<\/b><\/strong>\u00a0<\/b><\/strong>Sn<\/b><\/strong>(II)<\/b><\/strong>\u57fa\u5364\u5316\u7269\u9499\u949b\u77ff<\/b><\/strong><\/p>\n \u00a0 \uff08a\uff09GW+SOC\u65b9\u6cd5\u8ba1\u7b97\u5f97\u5230\u7684MASnI3<\/sub>\u7684\u80fd\u5e26\u7ed3\u6784\u56fe\u3002<\/p>\n \uff08b\uff09GW+SOC\u65b9\u6cd5\u8ba1\u7b97\u5f97\u5230\u7684MASnI3<\/sub>\u548cMAPbI3<\/sub>\u7684\u6001\u5bc6\u5ea6\u548c\u5149\u5b66\u5438\u6536\u5149\u8c31\u7684\u5bf9\u6bd4\u793a\u610f\u56fe\u3002<\/p>\n \uff08c\uff09\u5728\u5bccSn\u548c\u8d2bSn\u6761\u4ef6\u4e0b\u8ba1\u7b97\u5f97\u5230\u7684\u7f3a\u9677\u5f62\u6210\u80fd\u3002<\/p>\n \uff08d\uff09CsSnI3<\/sub>\u7684\u5404\u79cd\u56fa\u6709\u70b9\u7f3a\u9677\u7684\u8fc7\u6e21\u80fd\u7ea7\u793a\u610f\u56fe\u3002<\/p>\n \uff08e\uff09\u7528\u4e0d\u540c\u65b9\u6cd5\u5236\u9020\u7684\u5149\u4f0f\u5668\u4ef6\u7684J-V\u66f2\u7ebf<\/p>\n \uff08f\uff09\u56fa\u5b9a\u8d39\u7c73\u80fd\u7ea7\u4e0b\uff0cSn\u7684\u7a7a\u4f4d\u5f62\u6210\u80fd\u968f\u5316\u5b66\u52bf\u7684\u51fd\u6570\u53d8\u5316\u793a\u610f\u56fe\u3002<\/p>\n \u56fe7<\/b><\/strong>\u00a0<\/b><\/strong>\u540c\u4ef7\u66ff\u6362\uff08\u4e8c\uff09\uff1aGe<\/b><\/strong>(II)<\/b><\/strong>\u57fa\u5364\u5316\u7269\u9499\u949b\u77ff<\/b><\/strong><\/p>\n \u00a0 \uff08a\uff09CsGeI3<\/sub>\u7684\u6676\u4f53\u7ed3\u6784\u56fe\u3002<\/p>\n \uff08b\uff09MAGeI3<\/sub>\u7684\u6676\u4f53\u7ed3\u6784\u56fe\u3002<\/p>\n \uff08c\uff09CsGeI3<\/sub>\u3001MAGeI3<\/sub>\u3001FAGeI3<\/sub>\u548cCsSnI3<\/sub>\u7684\u5149\u5b66\u5438\u6536\u8c31\u5bf9\u6bd4\u56fe\u3002<\/p>\n \uff08d\uff09CsGeI3<\/sub>\u7684\u80fd\u5e26\u7ed3\u6784\u548c\u6295\u5f71\u6001\u5bc6\u5ea6\u56fe\u3002<\/p>\n \uff08e\uff09CsGeI3<\/sub>\u3001MAGeI3<\/sub>\u548cFAGeI3<\/sub>\u7684\u80fd\u7ea7\u793a\u610f\u56fe\u3002<\/p>\n \uff08f\uff09\u7528CsGeI3<\/sub>\u548cMAGeI3<\/sub>\u5236\u9020\u7684\u5149\u4f0f\u5668\u4ef6\u7684J-V\u66f2\u7ebf<\/p>\n \u56fe<\/b><\/strong>8 <\/b><\/strong>\u540c\u4ef7\u66ff\u6362\uff08\u4e09\uff09\uff1a\u8fc7\u6e21\u91d1\u5c5e\u57fa\u5364\u5316\u7269\u9499\u949b\u77ff<\/b><\/strong><\/p>\n \u00a0 \uff08a\uff09MA2<\/sub>CuCl2<\/sub>Br2<\/sub>\u7684\u6676\u4f53\u7ed3\u6784\u56fe\u3002<\/p>\n \uff08b\uff09MA2<\/sub>CuCl2<\/sub>Br2<\/sub>\u7684\u80fd\u5e26\u7ed3\u6784\u56fe\u3002<\/p>\n \uff08c\uff09\u7528MA2<\/sub>CuCl2<\/sub>Br2<\/sub>\u548cMA2<\/sub>CuCl0.5<\/sub>Br3.5<\/sub>\u5236\u9020\u7684\u592a\u9633\u80fd\u7535\u6c60\u7684I-V\u66f2\u7ebf\u3002<\/p>\n \u56fe9\u5f02<\/b><\/strong>\u4ef7\u66ff\u6362<\/b><\/strong>\uff08\u4e00\uff09\uff1a\u201c\u96f6\u7ef4\u201d\u9499\u949b\u77ff\u884d\u751f\u7269A<\/b><\/strong>2<\/b><\/sub><\/strong>BX<\/b><\/strong>6<\/b><\/sub><\/strong>\u7684\u7535\u5b50\u7ed3\u6784<\/b><\/strong><\/p>\n \u00a0 \uff08a\uff09HSE\u8ba1\u7b97\u7684Cs2<\/sub>SnI6<\/sub>\u80fd\u5e26\u7ed3\u6784\u548c\u6001\u5bc6\u5ea6\u3002<\/p>\n \uff08b\uff09HSE\u8ba1\u7b97\u7684Cs2<\/sub>PdBr6<\/sub>\u80fd\u5e26\u7ed3\u6784\u548c\u6001\u5bc6\u5ea6\u3002<\/p>\n \uff08c\uff09PBE\u8ba1\u7b97\u7684Cs2<\/sub>TiBr6<\/sub>\u80fd\u5e26\u7ed3\u6784\u548cHSE\u8ba1\u7b97\u7684\u6001\u5bc6\u5ea6\u3002<\/p>\n \uff08d\uff09Cs2<\/sub>SnI6<\/sub>\u4e2d\u56fa\u6709\u7f3a\u9677\u7684\u8f6c\u53d8\u80fd\u7ea7\u3002<\/p>\n \u56fe1<\/b><\/strong>0 <\/b><\/strong>\u5f02<\/b><\/strong>\u4ef7\u66ff\u6362<\/b><\/strong>\uff08\u4e00\uff09\uff1a\u201c\u96f6\u7ef4\u201d\u9499\u949b\u77ff\u884d\u751f\u7269A<\/b><\/strong>2<\/b><\/sub><\/strong> \u00a0\u00a0\u00a0<\/p>\n
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\n <\/b><\/strong><\/p>\n<\/b><\/strong><\/p>\n
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