{"id":173328,"date":"2019-04-22T06:01:42","date_gmt":"2019-04-21T22:01:42","guid":{"rendered":"\/\/m.iemloyee.com\/?p=173328"},"modified":"2019-04-21T22:02:28","modified_gmt":"2019-04-21T14:02:28","slug":"%e4%b8%ad%e7%a7%91%e9%99%a2%e5%8c%96%e5%ad%a6%e6%89%80%e9%83%ad%e7%8e%89%e5%9b%bdangew-chem-int-ed-%e6%b0%ae%e5%8c%96%e7%95%8c%e9%9d%a2%e5%8a%a9%e5%8a%9b%e9%ab%98%e9%98%bb%e7%87%83%e9%94%82","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=173328","title":{"rendered":"\u4e2d\u79d1\u9662\u5316\u5b66\u6240\u90ed\u7389\u56fdAngew. Chem. Int. Ed. : \u6c2e\u5316\u754c\u9762\u52a9\u529b\u9ad8\u963b\u71c3\u9502\u91d1\u5c5e\u7535\u6c60"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong> \u57fa\u4e8e\u91d1\u5c5e\u9502\u8d1f\u6781\u7684\u7535\u6c60\u6709\u7740\u9ad8\u7684\u6bd4\u80fd\u91cf\uff0c\u7136\u800c\uff0c\u91d1\u5c5e\u9502\u6c89\u79ef\u8fc7\u7a0b\u4e2d\u4e0d\u53d7\u63a7\u751f\u957f\u7684\u9502\u679d\u6676\u53ef\u80fd\u523a\u7a7f\u9694\u819c\uff0c\u5f15\u8d77\u7535\u6c60\u7684\u77ed\u8def\u3002\u800c\u7535\u6c60\u77ed\u8def\u5f80\u5f80\u4f34\u968f\u7740\u7535\u6c60\u7684\u70ed\u5931\u63a7\uff0c\u751a\u81f3\u4f1a\u5bfc\u81f4\u9ad8\u5ea6\u6613\u71c3\u6027\u7535\u89e3\u6db2\u7684\u71c3\u70e7\u548c\u7535\u6c60\u7684\u7206\u70b8\u3002\u56e0\u6b64\uff0c\u91c7\u7528\u4e0d\u71c3\/\u963b\u71c3\u6027\u7535\u89e3\u6db2\uff0c\u6709\u671b\u4e8e\u5927\u5e45\u5ea6\u63d0\u9ad8\u7535\u6c60\u7684\u5b89\u5168\u6027\u3002\u4e0d\u71c3\u6027\u7535\u89e3\u6db2\uff0c\u5305\u62ec\u79bb\u5b50\u6db2\u4f53\u3001\u6c22\u6c1f\u919a\u548c\u78f7\u9178\u916f\u7c7b\u7535\u89e3\u6db2\u5f15\u8d77\u7814\u7a76\u4eba\u5458\u7684\u5173\u6ce8\u3002\u5176\u4e2d\uff0c\u6709\u673a\u78f7\u9178\u916f\u5177\u6709\u7a81\u51fa\u7684\u963b\u71c3\u80fd\u529b\u3001\u826f\u597d\u7684\u7406\u5316\u6027\u8d28\u548c\u7ecf\u6d4e\u53cb\u597d\u6027\uff0c\u88ab\u5c1d\u8bd5\u7528\u4f5c\u4e3a\u7535\u89e3\u6db2\u7684\u963b\u71c3\u6dfb\u52a0\u5242\u3001\u5171\u6eb6\u5242\u751a\u81f3\u662f\u552f\u4e00\u6eb6\u5242\u3002\u7136\u800c\uff0c\u4e0e\u7535\u6781\u7684\u5dee\u7684\u517c\u5bb9\u6027\u9650\u5236\u4e86\u5176\u5e94\u7528\u3002\u6700\u8fd1\uff0c\u6709\u673a\u78f7\u9178\u916f\u7535\u89e3\u6db2(OPEs)\u91c7\u7528\u4e86\u9ad8\u76d0\u6d53\u5ea6\u7684\u6982\u5ff5\uff0c\u8bd5\u56fe\u6269\u5927\u5176\u5728Li\/Na\u7535\u6c60\u4e2d\u5bf9\u77f3\u58a8\u3001\u786c\u78b3\u548c\u78b1\u91d1\u5c5e\u8d1f\u6781\u7684\u76f8\u5bb9\u6027\u3002\u7136\u800c\uff0c\u542b\u6709\u5927\u91cf\u9502\u76d0\u7684\u9ad8\u76d0\u6d53\u5ea6\u7535\u89e3\u6db2\u589e\u52a0\u4e86\u7535\u6c60\u7684\u5236\u9020\u6210\u672c\uff0c\u540c\u65f6\u4f1a\u5bfc\u81f4\u7535\u89e3\u6db2\u9ad8\u7684\u7c98\u5ea6\u548c\u4f4e\u7684\u79bb\u5b50\u7535\u5bfc\u7387\u3002\u4e0e\u6b64\u540c\u65f6\uff0c\u5c3d\u7ba1\u4e00\u4e9b\u5de5\u4f5c\u8bd5\u56fe\u6269\u5927\u5176\u4e0e\u91d1\u5c5e\u9502\u8d1f\u6781\u7684\u76f8\u5bb9\u6027\uff0c\u4f46\u662f\u6548\u679c\u5e76\u4e0d\u662f\u7279\u522b\u597d\uff1b\u800c\u4e14\u5173\u4e8e\u91d1\u5c5e\u9502\u8d1f\u6781\u548cOPEs\u4e4b\u95f4\u7684\u754c\u9762\u4ee5\u53caOPEs\u4e2d\u7684\u9502\u6c89\u79ef\u884c\u4e3a\u7684\u8be6\u7ec6\u4fe1\u606f\u4ecd\u7136\u4e0d\u8db3\u3002\u56e0\u6b64\uff0c\u63a2\u7d22\u91d1\u5c5e\u9502\u5728OPEs\u4e2d\u7684\u751f\u957f\u673a\u5236\uff0c\u62d3\u5bbdOPEs\u4e0eLi\u91d1\u5c5e\u8d1f\u6781\u7684\u76f8\u5bb9\u6027\u5c24\u4e3a\u91cd\u8981\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u4e2d\u79d1\u9662\u5316\u5b66\u6240\u90ed\u7389\u56fd\u7814\u7a76\u5458\u56e2\u961f(\u901a\u8baf\u4f5c\u8005)\u7b49<\/strong>\u901a\u8fc7\u975e\u539f\u4f4d\u548c\u539f\u4f4d\u6280\u672f\u7814\u7a76\u4e86OPES\u4e2d\u7684\u9502\u6c89\u79ef\u8fc7\u7a0b\u548cLi\/OPES\u754c\u9762\u5316\u5b66\uff0c\u5e76\u5728Angew. Chem. Int. Ed.<\/strong>\u4e0a\u53d1\u8868\u4e86\u9898\u4e3a\u201cNitriding Interface Regulated Lithium Plating Enables Flame-Retardant Electrolytes for High-Voltage Lithium Metal Batteries<\/strong>\u201d\u7684\u7814\u7a76\u8bba\u6587\u3002\u4f5c\u8005\u63ed\u793a\u4e86\u4e0a\u8ff0\u4e0d\u517c\u5bb9\u7684\u539f\u56e0\u4e3b\u8981\u6765\u81ea\u4e8e\u9ad8\u7535\u963b\u6027\u548c\u4e0d\u5747\u5300Li\/OPEs\u754c\u9762\u5c42\u3002\u8fdb\u4e00\u6b65\u5730\uff0c\u4f5c\u8005\u63d0\u51fa\u4e86\u6c2e\u5316\u754c\u9762\u7b56\u7565\u4ee5\u6539\u5584\u8be5\u95ee\u9898\uff0c\u5e76\u4e14\u5b9e\u73b0\u4e86\u7a33\u5b9a\u7684\u65e0\u679d\u6676\u7684\u9502\u5faa\u73af\u3002\u540c\u65f6\uff0c\u642d\u914d\u9ad8\u954d\u4e09\u5143\u6b63\u6781(\u5982LiNi0.8<\/sub>Co0.1<\/sub>Mn0.1<\/sub>O2<\/sub>)\u7684\u5168\u7535\u6c60\u5177\u6709\u826f\u597d\u7684\u5faa\u73af\u7a33\u5b9a\u6027\u548c\u7a81\u51fa\u7684\u5b89\u5168\u6027(\u901a\u8fc7\u9488\u523a\u5b9e\u9a8c)\u3002\u8fd9\u79cd\u6c2e\u5316\u754c\u9762\u7b56\u7565\u7684\u601d\u60f3\u4e30\u5bcc\u4e86\u7535\u6781\/\u7535\u89e3\u6db2\u754c\u9762\u8bbe\u8ba1\u7684\u5185\u5bb9\uff0c\u4e5f\u4e3a\u5904\u7406\u7535\u6781\u548c\u7535\u89e3\u8d28\u4e4b\u95f4\u7684\u4e0d\u76f8\u5bb9\u6027\u63d0\u4f9b\u4e86\u65b0\u7684\u89e3\u51b3\u65b9\u6848\u3002<\/p>\n

\u3010\u56fe\u6587\u7b80\u4ecb\u3011<\/strong>
\n \u56fe1 OPEs\/MOPEs(\u6c2e\u4fee\u9970\u7684OPEs)\u4e0e\u9502\u91d1\u5c5e\u8d1f\u6781\u7684\u517c\u5bb9\u6027<\/strong><\/p>\n

\"\"<\/p>\n

a) OPEs\u4e2d\u9502\u751f\u957f\u8fc7\u7a0b\u7684\u793a\u610f\u56fe\uff1b
\n b) MOPEs\u4e2d\u9502\u751f\u957f\u8fc7\u7a0b\u7684\u793a\u610f\u56fe\uff1b
\n c) \u5728MOPEs\u4e2d\u6c89\u79ef\u7684\u9502\u7684\u5f62\u8c8c\uff1b
\n d) \u653e\u5927SEM\u56fe\u50cf\uff1b
\n e) Li-Cu\u7535\u6c60\u4e2d\u7684\u7535\u538b\u66f2\u7ebf\u6bd4\u8f83\uff1b
\n f) Li-Cu\u7535\u6c60\u4e2d\u7684\u5e73\u5747CE\u6bd4\u8f83\uff1b
\n g) Li-Li\u5bf9\u79f0\u7535\u6c60\u4e2d\u7684\u7535\u538b\u66f2\u7ebf\u3002<\/p>\n

\u56fe2 OPEs\/MOPEs\u4e2d\u7684\u9502\u6c89\u79ef\u8fc7\u7a0b<\/strong><\/p>\n

\"\"<\/p>\n

a) \u5149\u5b66\u663e\u5fae\u955c\u7684\u88c5\u7f6e\u793a\u610f\u56fe\uff1b
\n b) \u6c89\u79ef\u7535\u538b\u66f2\u7ebf\uff1b
\n c-h) MOPEs\u4e2d\u9502\u6c89\u79ef\u8fc7\u7a0b\u7684\u5149\u5b66\u7167\u7247\uff0c\u6bd4\u4f8b\u5c3a50 \u03bcm(\u4e0b\u540c)\uff1b
\n i-n) OPEs\u4e2d\u9502\u6c89\u79ef\u8fc7\u7a0b\u7684\u5149\u5b66\u7167\u7247\u3002<\/p>\n

\u56fe3 \u9502\u8868\u9762\u7684\u5f62\u8c8c\u548c\u7ec4\u6210<\/strong><\/p>\n

\"\"<\/p>\n

a,b) OPEs\u4e2d\u5316\u6210\u8fc7\u7a0b\u4e4b\u540e\u7684\u9502\u8868\u9762\u76842D\u548c3D AFM\u56fe\u50cf\uff1b
\n c,d) MOPEs\u4e2d\u5316\u6210\u8fc7\u7a0b\u4e4b\u540e\u7684\u9502\u8868\u9762\u76842D\u548c3D AFM\u56fe\u50cf\uff1b
\n e) \u6d78\u6ce1\u4e8eOPEs 4 h\u540e\u9502\u8d1f\u6781\u7684N 1s XPS\u5149\u8c31\uff1b
\n f) \u6d78\u6ce1\u4e8eMOPEs 4 h\u540e\u9502\u8d1f\u6781\u7684N 1s XPS\u5149\u8c31\uff1b
\n g) \u5316\u6210\u8fc7\u7a0b\u540eOPEs\u7684N 1s XPS\u5149\u8c31\uff1b
\n h) \u5316\u6210\u8fc7\u7a0b\u540eMOPEs\u7684N 1s XPS\u5149\u8c31\uff1b
\n i) \u5316\u6210\u8fc7\u7a0b\u540eMOPEs\u7684P 2p XPS\u5149\u8c31\uff1b
\n j) \u5316\u6210\u8fc7\u7a0b\u540eMOPEs\u7684F 1s XPS\u5149\u8c31\uff1b
\n k) \u5316\u6210\u8fc7\u7a0b\u540eMOPEs\u7684C 1s XPS\u5149\u8c31\uff1b
\n l) 150\u6b21\u5faa\u73af\u540eMOPEs\u7684N 1s XPS\u5149\u8c31\u3002<\/p>\n

\u56fe4 \u5168\u7535\u6c60\u7684\u7535\u5316\u5b66\u6027\u80fd<\/strong><\/p>\n

\"\"<\/p>\n

a) Li | MOPEs | NCM622\u7535\u6c60\u7684\u7535\u538b\u66f2\u7ebf\uff1b
\n b) Li | MOPEs | NCM622\u7535\u6c60\u7684\u7535\u5316\u5b66\u963b\u6297\u8c31\uff1b
\n c) Li | MOPEs | NCM622\u7535\u6c60\u7684\u5faa\u73af\u6027\u80fd\uff1b
\n d) Li | MOPEs | NCM811\u7535\u6c60\u7684\u5faa\u73af\u6027\u80fd\uff1b
\n e) \u7535\u6c60\u7a7f\u523a\u6d4b\u8bd5\u3002<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n

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\u3010\u56e2\u961f\u4ecb\u7ecd\u3011<\/strong> \u4e2d\u56fd\u79d1\u5b66\u9662\u5316\u5b66\u7814\u7a76\u6240\u90ed\u7389\u56fd\u7814\u7a76\u5458<\/strong>\u662f\u79d1\u6280\u90e8\u7acb\u9879\u7684\u56fd\u5bb6\u91cd\u70b9\u7814\u53d1\u8ba1\u5212\u201c\u9ad8\u80fd\u91cf\u5bc6\u5ea6\u7eb3\u7c73\u56fa\u6001\u91d1\u5c5e\u9502\u7535\u6c60\u7814\u7a76\u201d\u9879\u76ee\u7684\u9996\u5e2d\u79d1\u5b66\u5bb6\u3002\u901a\u8fc7\u8be5\u9879\u76ee\u7684\u5b9e\u65bd\uff0c\u6709\u671b\u4e3a\u4e0b\u4e00\u4ee3\u9ad8\u80fd\u91cf\u5bc6\u5ea6\u9502\u4e8c\u6b21\u7535\u6c60\u5173\u952e\u6750\u6599\u4e0e\u6280\u672f\u53d1\u5c55\u5960\u5b9a\u575a\u5b9e\u7684\u79d1\u5b66\u57fa\u7840\uff0c\u4e3a\u9ad8\u7aef\u6d88\u8d39\u7535\u5b50\u3001\u7535\u52a8\u6c7d\u8f66\u3001\u56fd\u5bb6\u5b89\u5168\u3001\u822a\u7a7a\u822a\u5929\u3001\u89c4\u6a21\u50a8\u80fd\u7b49\u76f8\u5173\u4ea7\u4e1a\u7684\u53d1\u5c55\u63d0\u4f9b\u5173\u952e\u652f\u6491\u3002\u8fd1\u5e74\u6765\uff0c\u5176\u7814\u7a76\u56e2\u961f\u9510\u610f\u8fdb\u53d6\uff0c\u5728\u91d1\u5c5e\u9502\u7535\u6c60\u9886\u57df\u8fdb\u884c\u4e86\u7cfb\u7edf\u800c\u6df1\u5165\u7684\u7814\u7a76\uff0c\u53d6\u5f97\u4e86\u4e00\u7cfb\u5217\u7684\u91cd\u8981\u6210\u679c\u548c\u8fdb\u5c55\u3002<\/p>\n

\u3010\u56e2\u961f\u5728\u8be5\u9886\u57df\u5de5\u4f5c\u6c47\u603b\u3011<\/strong><\/p>\n

\u8be5\u56e2\u961f\u7814\u7a76\u4eba\u5458\u81f4\u529b\u4e8e\u5f00\u53d1\u517c\u5177\u957f\u5faa\u73af\u7a33\u5b9a\u6027\u3001\u9ad8\u6bd4\u80fd\u91cf\u548c\u4f18\u5f02\u5b89\u5168\u6027\u7684\u91d1\u5c5e\u9502\u7535\u6c60\uff0c\u5206\u522b\u4ece\u7535\u6781\u7ed3\u6784\u3001\u754c\u9762\u3001\u7535\u89e3\u8d28\u7b49\u591a\u89d2\u5ea6\u5168\u65b9\u9762\u5bf9\u91d1\u5c5e\u9502\u57fa\u7535\u6c60\u8fdb\u884c\u4e86\u7cfb\u7edf\u6df1\u5165\u7684\u7814\u7a76\u3002
\n \u5728\u7535\u6781\u7ed3\u6784\u65b9\u9762\uff0c\u4e3a\u89e3\u51b3\u91d1\u5c5e\u9502\u679d\u6676\u548c\u5faa\u73af\u7a33\u5b9a\u6027\u7684\u95ee\u9898\uff0c\u56e2\u961f\u5206\u522b\u4ece\u57fa\u7840\u6a21\u578b\u7814\u7a76\u4f53\u7cfb(Nat. Commun., 2015, 6,8058; Adv. Mater. 2017, 29, 1703729; J. Am. Chem. Soc., 2018, 140, 18051-18057)\u5230\u5b9e\u9645\u5e94\u7528\u4f53\u7cfb(Adv. Mater., 2017, 29, 1700389; J. Am. Chem. Soc., 2017, 139, 5916; Angew. Chem. Int. Ed., 2019, 131, 1106-1111)\u8bbe\u8ba1\u4e86\u4e00\u7cfb\u5217\u5177\u6709\u4e09\u7ef4\u7ed3\u6784\u7684\u7684\u7535\u6781\uff0c\u5bf9\u91d1\u5c5e\u9502\u8d1f\u6781\u7684\u6210\u6838\u53ca\u751f\u957f\u884c\u4e3a\u3001\u4f4e\u8d1f\u6781\u8fc7\u91cf\u7684\u7a33\u5b9a\u5faa\u73af\u3001\u9ad8\u9762\u5bb9\u91cf\u7b49\u5173\u952e\u95ee\u9898\u8fdb\u884c\u4e86\u5168\u9762\u800c\u6df1\u5165\u7684\u63a2\u7a76\uff0c\u662f\u56fd\u9645\u4e0a\u8be5\u9886\u57df\u7684\u62d3\u8352\u8005\u548c\u5f15\u9886\u8005\u3002\u5728\u7535\u6781\/\u7535\u89e3\u8d28\u754c\u9762\u65b9\u9762\uff0c\u4e3a\u51cf\u5c11\u91d1\u5c5e\u9502\u4e0e\u7535\u89e3\u6db2\u4e4b\u95f4\u7684\u526f\u53cd\u5e94\uff0c\u56e2\u961f\u57fa\u4e8e\u539f\u4f4d\u5904\u7406\u6280\u672f\u5f00\u53d1\u4e86\u5177\u6709\u9ad8\u673a\u68b0\u5f3a\u5ea6\u7684\u78f7\u9178\u9502(Adv. Mater., 2016, 28, 1853)\u548c\u53ef\u81ea\u9002\u5e94\u7684\u805a\u4e19\u70ef\u9178\u9502(Angew. Chem. Int. Ed. 2018, 57, 1505 \u20131509)\u56fa\u6001\u7535\u89e3\u8d28\u754c\u9762\u819c\uff0c\u8f83\u597d\u5730\u907f\u514d\u4e86\u526f\u53cd\u5e94\uff0c\u6291\u5236\u4e86\u679d\u6676\u7684\u751f\u957f\uff0c\u9664\u6b64\u4e4b\u5916\uff0c\u5728\u916f\u7c7b\u7535\u89e3\u6db2\u4f53\u7cfb\u4e2d\u901a\u8fc7\u6dfb\u52a0AlCl3<\/sub>\uff0c\u4e5f\u83b7\u5f97\u4e86\u7a33\u5b9a\u7684\u91d1\u5c5e\u9502\u4e0e\u916f\u7c7b\u7535\u89e3\u6db2\u4e4b\u95f4\u7684\u754c\u9762(Nano Energy, 2017, 36, 411)\u3002\u5728\u91d1\u5c5e\u9502\u7528\u56fa\u4f53\u7535\u89e3\u8d28\u65b9\u9762\uff0c\u56e2\u961f\u8bbe\u8ba1\u4e86\u4e00\u7cfb\u5217\u9ad8\u7535\u5bfc\uff0c\u754c\u9762\u7a33\u5b9a\u6027\u597d\uff0c\u6291\u5236\u9502\u679d\u6676\u7684\u65b0\u578b\u7535\u89e3\u8d28\u3002\u56e2\u961f\u4ece\u7535\u89e3\u8d28\u5236\u5907\u65b9\u5f0f\u51fa\u53d1\uff0c\u5229\u7528\u5149\u805a\u5408\u5f00\u53d1\u4e86\u517c\u5177\u9ad8\u79bb\u5b50\u7535\u5bfc\u4e0e\u673a\u68b0\u5f3a\u5ea6\u7684ipn-PEA\u56fa\u4f53\u7535\u89e3\u8d28(J. Am. Chem. Soc., 2016, 138, 15825)\uff1b\u5229\u7528\u9502\u76d0\u7684\u81ea\u5f15\u53d1\u805a\u5408\u7684\u80fd\u529b\uff0c\u5728\u7535\u6c60\u5185\u90e8\u539f\u4f4d\u6784\u7b51\u4e86\u56fa\u6001\u7535\u89e3\u8d28\uff0c\u6709\u6548\u5730\u89e3\u51b3\u4e86\u56fa\u4f53\u7535\u89e3\u8d28\u4e0e\u7535\u6781\u7684\u754c\u9762\u63a5\u89e6\u7684\u95ee\u9898(Sci. Adv. 2018; 4 : eaat5383)\u3002\u4e0e\u6b64\u540c\u65f6\uff0c\u56e2\u961f\u8fd8\u7ed3\u5408\u805a\u5408\u7269\u548c\u9676\u74f7\u7535\u89e3\u8d28\u7684\u4f18\u52bf\uff0c\u521b\u9020\u6027\u5730\u63d0\u51fa\u4e86\u975e\u5bf9\u79f0\u7ed3\u6784\u7684\u56fa\u4f53\u7535\u89e3\u8d28\uff0c\u6539\u5584\u4e86\u7535\u6781\u7535\u89e3\u8d28\u754c\u9762\u63a5\u89e6(J. Am. Chem. Soc., 2018, 140, 82)\uff0c\u62d3\u5bbd\u4e86\u7535\u89e3\u8d28\u7684\u7535\u538b\u8010\u53d7\u533a\u95f4(Adv. Mater., 2019, 31, 1807789)\u3002\u8fd1\u6765\uff0c\u5728\u4ee5\u4e0a\u5de5\u4f5c\u7684\u57fa\u7840\u4e0a\uff0c\u56e2\u961f\u63d0\u51fa\u4e86\u6c2e\u5316\u754c\u9762\u7684\u601d\u60f3(Angew. Chem. Int. Ed., 2019, DOI: 10.1002\/anie.201903466)\uff0c\u6709\u6548\u5730\u89e3\u51b3\u4e86\u78f7\u9178\u916f\u7c7b\u7535\u89e3\u6db2\u4e0e\u91d1\u5c5e\u9502\u4e4b\u95f4\u7684\u4e0d\u517c\u5bb9\u6027\uff0c\u53d1\u5c55\u51fa\u4e86\u517c\u5177\u6db2\u6001\u7535\u89e3\u6db2\u9ad8\u79bb\u5b50\u7535\u5bfc\u7387\u3001\u826f\u597d\u754c\u9762\u63a5\u89e6\u548c\u56fa\u4f53\u7535\u89e3\u8d28\u9ad8\u5b89\u5168\u6027\u80fd\u4f18\u70b9\u7684\u5177\u6709\u963b\u71c3\u6027\u8d28\u7684\u7535\u89e3\u6db2\u3002\u5f97\u76ca\u4e8e\u6c2e\u5316\u754c\u9762\u7684\u6784\u9020\uff0c\u56e2\u961f\u5b9e\u73b0\u4e86\u7a33\u5b9a\u7684\u65e0\u679d\u6676\u7684\u9502\u5faa\u73af\uff0c\u5f97\u5230\u4e86\u517c\u5177\u957f\u5faa\u73af\u5bff\u547d\u548c\u4f18\u5f02\u5b89\u5168\u6027\u7684\u9ad8\u80fd\u91cf\u5bc6\u5ea6\u7535\u6c60\u3002\u56e2\u961f\u63d0\u51fa\u7684\u6c2e\u5316\u754c\u9762\u7684\u601d\u60f3\u4e5f\u4e30\u5bcc\u4e86\u7535\u6781\u7535\u89e3\u6db2\u754c\u9762\u8bbe\u8ba1\u7684\u5185\u5bb9\uff0c\u4e5f\u53ef\u9002\u7528\u4e8e\u6539\u5584\u5176\u5b83\u91d1\u5c5e\u8d1f\u6781\u4e0e\u7535\u89e3\u8d28\u4e4b\u95f4\u7684\u517c\u5bb9\u6027\u3002<\/p>\n

\u3010\u76f8\u5173\u4f18\u8d28\u6587\u732e\u63a8\u8350\u3011<\/strong>
\n (1)Nat. Commun., 2015, 6,8058\uff1b
\n (2)Angew. Chem. Int. Ed., 2019, 131, 1106-1111\uff1b
\n (3)Angew. Chem. Int. Ed. 2018, 57, 1505 -1509\uff1b
\n (4)Sci. Adv. 2018; 4 : eaat5383\uff1b
\n (5)J. Am. Chem. Soc., 2018, 140, 82\uff1b
\n (6)Electrochemical Energy Reviews (2018) 1:113-138.<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1aNitriding Interface Regulated Lithium Plating Enables Flame-Retardant Electrolytes for High-Voltage Lithium Metal Batteries<\/a> <\/strong>(Angew. Chem. Int. Ed.<\/strong>, 2019, DOI: 10.1002\/anie.201903466)<\/p>\n

\u672c\u6587\u7531abc940504\u7f16\u8bd1\u6574\u7406<\/p>\n

\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1acailiaorenvip\u3002<\/strong><\/p>\n

\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1tougao@cailiaoren.com\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"

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