{"id":173174,"date":"2019-04-18T06:33:12","date_gmt":"2019-04-17T22:33:12","guid":{"rendered":"\/\/m.iemloyee.com\/?p=173174"},"modified":"2019-04-17T17:33:26","modified_gmt":"2019-04-17T09:33:26","slug":"%e9%98%bf%e5%8d%9c%e6%9d%9c%e6%8b%89%e5%9b%bd%e7%8e%8b%e7%a7%91%e6%8a%80%e5%a4%a7%e5%ad%a6husam-n-alshareef%e7%bb%84aem%ef%bc%9a%e5%af%bc%e7%94%b5mof%e5%ba%94%e7%94%a8%e4%ba%8e%e5%be%ae%e5%9e%8b","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=173174","title":{"rendered":"\u963f\u535c\u675c\u62c9\u56fd\u738b\u79d1\u6280\u5927\u5b66Husam N. Alshareef\u7ec4AEM\uff1a\u5bfc\u7535MOF\u5e94\u7528\u4e8e\u5fae\u578b\u7535\u5bb9\u5668"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/b><\/strong><\/p>\n

\u80fd\u91cf\u5b58\u50a8\u7cfb\u7edf\u5fae\u578b\u5316\u5bf9\u4e8e\u4fbf\u643a\u5f0f\u7535\u5b50\u5668\u4ef6\uff0c\u53ef\u690d\u5165\u5f0f\u5fae\u578b\u5668\u4ef6\uff0c\u4f20\u611f\u5668\u4ee5\u53ca\u7269\u8054\u7f51\u7b49\u7684\u5feb\u901f\u53d1\u5c55\u5fc5\u4e0d\u53ef\u5c11\u3002\u5176\u4e2d\uff0c\u7535\u5316\u5b66\u5fae\u7535\u5bb9\u5668\u662f\u4e00\u79cd\u6781\u5177\u6f5c\u529b\u7684\u5fae\u578b\u80fd\u6e90\u5b58\u50a8\u5668\u4ef6\u3002\u8fd1\u51e0\u5e74\u6765\uff0c\u5229\u7528CO2<\/sub>\u6fc0\u5149\u5265\u79bb\u77f3\u58a8\u70ef\uff08laser-scribed graphene, LSG\uff09\u6280\u672f\u88ab\u8bc1\u660e\u662f\u4e00\u79cd\u80fd\u591f\u76f4\u63a5\u5236\u5907\u5fae\u7535\u5bb9\u5668\u7535\u6781\u7684\u6709\u6548\u65b9\u6cd5\u3002\u8be5\u65b9\u6cd5\u80fd\u591f\u6709\u6548\u5730\u5728\u591a\u79cd\u57fa\u5e95\u4e0a\uff08\u5982PI\u819c\u7b49\uff09\u5b9e\u73b0\u7535\u6781\u56fe\u6848\u7684\u76f4\u63a5\u201c\u4e66\u5199\u201d\uff0c\u907f\u514d\u4f7f\u7528\u590d\u6742\u4e14\u8017\u65f6\u7684\u5149\u523b\u7b49\u5de5\u827a\u3002\u7136\u800c\uff0c\u8fd9\u7c7b\u65b9\u6cd5\u76f4\u63a5\u5236\u5907\u7684LSG\u7684\u6bd4\u7535\u5bb9\u5c1a\u4e14\u8f83\u4f4e\u3002\u7531\u4e8e\u4f7f\u7528CO2<\/sub>\u6fc0\u5149\u5c06sp3<\/sup>-C\u5411sp2<\/sup>-C\u8f6c\u5316\u7684\u8fc7\u7a0b\u4e2d\u4f1a\u4ea7\u751f\u5927\u91cf\u7684\u5b54\u9053\u548c\u8868\u9762\u7f3a\u9677\uff0c\u56e0\u6b64\u901a\u8fc7\u6784\u7b51\u4e30\u5bcc\u7684\u8868\u9762\u5b98\u80fd\u56e2\u53ef\u4ee5\u4f7fLSG\u4f5c\u4e3a\u4e00\u79cd\u7406\u60f3\u7684\u5bfc\u7535\u5e73\u53f0\u4ee5\u5b9e\u73b0\u548c\u5176\u5b83\u9ad8\u7535\u5bb9\u6027\u6750\u6599\u4e4b\u95f4\u7684\u8026\u5408\u3002\u91d1\u5c5e\u6709\u673a\u9aa8\u67b6\uff08MOFs\uff09\u4f5c\u4e3a\u4e00\u7c7b\u591a\u5b54\u9053\u9ad8\u6bd4\u8868\u9762\u7684\u8f7b\u8d28\u6750\u6599\u4f5c\u4e3a\u7535\u6781\u6750\u6599\u6781\u5177\u6f5c\u8d28\uff0c\u5176\u5206\u679d\u5bfc\u7535MOF\u66f4\u662f\u5177\u6709\u4f18\u4e8e\u4f20\u7edfMOF\u7684\u7279\u6027\u3002\u8fd1\u51e0\u5e74\u6765\uff0c\u4e8c\u7ef4\u5bfc\u7535MOF\uff082D MOF\uff09\u5f97\u76ca\u4e8e\u6709\u6548\u7684\u5c42\u5c42\u95f4\u7684\u03c0\u2013\u03c0\u5806\u79ef\u4f7f\u5176\u62e5\u6709\u8f83\u591a\u7684\u03c0\u2013\u03c0 \u548c\u03c0\u2013d \u8f68\u9053\u91cd\u53e0\uff0c\u56e0\u6b64\u5c55\u73b0\u51fa\u4e86\u4f18\u5f02\u7684\u5bfc\u7535\u6027\u80fd\u30022D MOF\u4f5c\u4e3a\u7535\u6781\u6750\u6599\u4e5f\u56e0\u6b64\u88ab\u5e94\u7528\u4e8e\u7535\u5316\u5b66\u7535\u5bb9\u5668\u4e2d\u3002\u7136\u800c\uff0c\u57fa\u4e8e2D MOF\u7684\u7535\u6781\u6750\u6599\u5c1a\u672a\u5e94\u7528\u4e8e\u5fae\u7535\u5bb9\u5668\uff0c\u539f\u56e0\u53ef\u80fd\u6709\u4ee5\u4e0b\u51e0\u79cd\uff1a1.\u00a0\u5927\u591a\u6570MOF\u90fd\u662f\u7c89\u4f53\u5f62\u5f0f\u88ab\u5236\u5907\u51fa\u6765\uff0c\u5728\u5668\u4ef6\u5236\u5907\u4e2d\u901a\u5e38\u4f7f\u7528\u7684\u70ed\u84b8\u9540\uff0c\u6e85\u5c04\u4ee5\u53ca\u523b\u8680\u7b49\u8fc7\u7a0b\u4f1a\u9020\u6210MOF\u7684\u635f\u574f\u30022.\u00a0\u5bfc\u7535MOF\u7684\u9009\u62e9\u6027\uff08\u9700\u53ea\u4e0e\u5bfc\u7535\u96c6\u6d41\u4f53\u7ed3\u5408\uff09\u751f\u957f\u662f\u5f88\u5927\u7684\u6311\u6218\u30023.\u00a0\u7edd\u5927\u591a\u65702D MOF\u5e76\u4e0d\u80fd\u540c\u65f6\u4f5c\u4e3a\u6b63\u6781\u548c\u8d1f\u6781\u5de5\u4f5c\uff08\u5373\u5bf9\u79f0\u578b\uff09\uff0c\u4f7f\u5f97\u5236\u5907\u5de5\u827a\u66f4\u52a0\u590d\u6742\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/b><\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u963f\u535c\u675c\u62c9\u56fd\u738b\u79d1\u6280\u5927\u5b66\uff08KAUST\uff09\u7684Husam\u00a0N. Alshareef \u6559\u6388\u548cMohamed Eddaoudi\u6559\u6388\u5408\u4f5c\uff0c\u5236\u5907\u4e00\u79cd\u57fa\u4e8e\u5bfc\u7535MOF\u7684\u5fae\u7535\u5bb9\u5668\u3002\u4f5c\u8005\u9996\u5148\u901a\u8fc7CO2<\/sub>\u6fc0\u5149\u5728PI\u819c\u4e0a\u5236\u5907\u51fa\u00a0LSG\u7535\u6781\uff0c\u7136\u540e\u901a\u8fc7\u5bf9LSG\u8868\u9762\u6539\u6027\u5e76\u7528\u4f5c\u4e09\u7ef4\u5bfc\u7535\u57fa\u5e95\uff0c\u63a5\u7740\u7528\u4e00\u6b65\u4f4e\u6e29\u6eb6\u5242\u70ed\u6cd5\u5c06\u5bfc\u75352D MOF Ni-CAT\u7eb3\u7c73\u68d2\u9009\u62e9\u6027\u5730\u6c89\u79ef\u5728LSG\u4e0a\uff0c\u5f62\u6210LSG\/Ni-CAT MOF\u590d\u5408\u7535\u6781\u6750\u6599\u3002\u8be5\u7535\u6781\u6750\u6599\u53ef\u540c\u65f6\u4f5c\u4e3a\u7535\u5bb9\u5668\u7684\u6b63\u6781\u548c\u8d1f\u6781\uff0c\u4e14\u5c55\u73b0\u51fa\u4e86\u8fdc\u9ad8\u4e8eLSG\u7684\u7535\u5316\u5b66\u6027\u80fd\uff08\u6bd4\u7535\u5bb9\uff0c\u80fd\u91cf\u5bc6\u5ea6\u7b49\uff09\u3002\u540c\u65f6\uff0c\u8be5\u590d\u5408\u7535\u6781\u4e5f\u5c55\u73b0\u51fa\u4e86\u8f83\u597d\u7684\u500d\u7387\u6027\u80fd\u548c\u5faa\u73af\u7a33\u5b9a\u6027\u3002\u8be5\u6210\u679c\u4ee5\u9898\u4e3a\u201cConductive Metal\u2013Organic Frameworks Selectively Grown on Laser-Scribed Graphene for Electrochemical Microsupercapacitors\u201d\u53d1\u8868\u5728Adv. Energy\u00a0Mater.\u4e0a\uff0c\u8bba\u6587\u7b2c\u4e00\u4f5c\u8005\u4e3aKAUST\u535a\u58eb\u540e\u5434\u660a\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/b><\/strong><\/p>\n

\u56fe1.\u00a0<\/b><\/strong>LSG\/Ni-CAT MOF\u590d\u5408\u7535\u6781\u6750\u6599\u5236\u5907\u6d41\u7a0b\u53caNi-CAT\u7ed3\u6784\u793a\u610f\u56fe\u3002<\/p>\n

\"\"<\/p>\n

(a)-(c) \u7535\u6781\u5236\u5907\u8fc7\u7a0b;\u00a0(d)-(g) 2D\u5c42\u72b6Ni-CAT\u7ed3\u6784\u793a\u610f\u56fe\u3002<\/p>\n

\u56fe2.\u00a0\u5f62\u8c8c\u53ca\u7ec4\u5206\u8868\u5f81\u3002<\/p>\n

\"\"<\/p>\n

(a), (b) \u5206\u522b\u4e3aLSG\u548c\u00a0LSG\/Ni-CAT\u626b\u63cf\u7535\u955c\u56fe; (c) LSG\/Ni-CAT\u900f\u5c04\u7535\u955c\u56fe;\u00a0(d), (e) \u5206\u522b\u4e3a\u7535\u5b50\u675f\u5782\u76f4\u548c\u5e73\u884c\u4e8e\u4e00\u7ef4\u5b54\u9053\u7684\u9ad8\u500d\u900f\u5c04\u7535\u955c\u56fe; (f) XRD\u56fe\u8c31; (g) FTIR \u56fe\u8c31\u3002<\/p>\n

\u56fe3.\u00a0\u6c34\u7cfb\u7535\u89e3\u6db2\u4e2d\u7535\u5316\u5b66\u6027\u80fd\u5bf9\u6bd4\u3002<\/p>\n

\"\"<\/p>\n

(a) LSG\/Ni-CAT\u4f5c\u4e3a\u6b63\u8d1f\u6781\u7684CV\u56fe; (b) LSG\/Ni-CAT\u4e0d\u540c\u5de5\u4f5c\u7535\u538b\u533a\u95f4CV\u56fe; (c) LSG\u548cLSG\/Ni-CAT \u7684CV\u5bf9\u6bd4\u56fe; (d) LSG\u548cLSG\/Ni-CAT \u7684\u5145\u653e\u7535\u5bf9\u6bd4\u56fe\u3002<\/p>\n

\u56fe4.\u51c6\u56fa\u6001\u7535\u89e3\u6db2\u4e2d\u7535\u5316\u5b66\u6027\u80fd\u5bf9\u6bd4\u3002<\/p>\n

\"\"<\/p>\n

(a) \u4e0d\u540c\u6c89\u79ef\u65f6\u95f4CV\u5bf9\u6bd4; (b) LSG\/Ni-CAT\u4e0d\u540c\u626b\u901f\u7684CV; (c) LSG\u548c\u00a0LSG\/Ni-CAT\u5145\u653e\u7535\u5bf9\u6bd4\u56fe; (d)\u00a0LSG\/Ni-CAT\u5728\u4e0d\u540c\u7535\u6d41\u5bc6\u5ea6\u4e0b\u5145\u653e\u7535\u56fe;\u00a0(e)\u00a0LSG\u548c\u00a0LSG\/Ni-CAT\u6bd4\u7535\u5bb9\u5bf9\u6bd4\u56fe;\u00a0(f)\u00a0\u5faa\u73af\u7a33\u5b9a\u6027\u6d4b\u8bd5\u3002<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/b><\/strong><\/p>\n

\u8be5\u5de5\u4f5c\u901a\u8fc7\u8868\u9762\u6539\u6027\uff0c\u9009\u62e9\u6027\u6c89\u79ef\u5bfc\u7535MOF\uff0c\u5e76\u9996\u6b21\u5b9e\u73b0\u4e86\u5c06\u5bfc\u7535MOF\u4f5c\u4e3a\u7535\u6781\u6750\u6599\u5e94\u7528\u4e8e\u5fae\u7535\u5bb9\u5668\u4e2d\u30022D Ni-CAT\u00a0MOF\u4f5c\u4e3a\u7535\u6781\u6750\u6599\u5de5\u4f5c\u7535\u538b\u53ef\u4ee5\u8fbe\u52301.4\u00a0V\uff0c\u6bd4\u7535\u5bb9\u9ad8\u8fbe15.2\u00a0mF cm-2<\/sup>\uff0c\u80fd\u91cf\u5bc6\u5ea6\u548c\u529f\u7387\u5bc6\u5ea6\u5206\u522b\u53ef\u4ee5\u8fbe\u52304.1\u00a0\u00b5Wh cm-2<\/sup>\u548c7\u00a0mW cm-2<\/sup>\u3002\u8be5\u5de5\u4f5c\u4e3a\u5bfc\u7535MOF\u4f5c\u4e3a\u7535\u6781\u6750\u6599\u5e94\u7528\u4e8e\u5fae\u578b\u7535\u5316\u5b66\u80fd\u91cf\u5b58\u50a8\u5668\u4ef6\u63d0\u4f9b\u4e86\u53c2\u8003\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1aConductive Metal\u2013Organic Frameworks Selectively Grown on Laser-Scribed Graphene for Electrochemical Microsupercapacitors\u00a0\u00a0(Adv. Energy Mater<\/i><\/em>. 2019,\u00a0DOI: 10.1002\/aenm.201900482)<\/p>\n

\u672c\u6587\u7531\u5434\u660a\u00a0<\/strong>\u4f9b\u7a3f\u3002<\/p>\n

\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1: tougao@cailiaoren.com.<\/p>\n

\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1acailiaorenVIP.<\/p>\n","protected":false},"excerpt":{"rendered":"

\u3010\u5f15\u8a00\u3011 \u80fd\u91cf\u5b58\u50a8\u7cfb\u7edf\u5fae\u578b\u5316\u5bf9\u4e8e\u4fbf\u643a\u5f0f\u7535\u5b50\u5668\u4ef6\uff0c\u53ef\u690d\u5165\u5f0f\u5fae\u578b\u5668\u4ef6\uff0c\u4f20\u611f\u5668\u4ee5\u53ca\u7269\u8054\u7f51\u7b49\u7684\u5feb\u901f\u53d1\u5c55\u5fc5\u4e0d\u53ef\u5c11\u3002\u5176\u4e2d\uff0c\u7535\u5316\u5b66\u5fae\u7535\u5bb9\u5668\u662f\u4e00\u79cd\u6781\u5177\u6f5c\u529b\u7684\u5fae\u578b\u80fd\u6e90\u5b58\u50a8\u5668\u4ef6\u3002\u8fd1…<\/p>\n","protected":false},"author":10213,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[],"class_list":["post-173174","post","type-post","status-publish","format-standard","hentry","category-jiedu"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/173174"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/10213"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=173174"}],"version-history":[{"count":1,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/173174\/revisions"}],"predecessor-version":[{"id":173179,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/173174\/revisions\/173179"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=173174"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=173174"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=173174"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}