{"id":173103,"date":"2019-04-18T11:50:00","date_gmt":"2019-04-18T03:50:00","guid":{"rendered":"\/\/m.iemloyee.com\/?p=173103"},"modified":"2019-04-17T22:50:15","modified_gmt":"2019-04-17T14:50:15","slug":"am%ef%bc%9a%e5%8f%af%e5%90%b8%e9%99%84%e9%98%b4%e7%a6%bb%e5%ad%90%e7%9a%84%e5%a4%8d%e5%90%88%e9%9a%94%e8%86%9c%e7%94%a8%e4%ba%8e%e9%ab%98%e5%80%8d%e7%8e%87%e9%94%82%e7%a6%bb%e5%ad%90%e7%94%b5%e6%b1%a0","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=173103","title":{"rendered":"AM\uff1a\u53ef\u5438\u9644\u9634\u79bb\u5b50\u7684\u590d\u5408\u9694\u819c\u7528\u4e8e\u9ad8\u500d\u7387\u9502\u79bb\u5b50\u7535\u6c60"},"content":{"rendered":"<p><strong>\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n<p>\u672c\u6587\u901a\u8fc7\u9759\u7535\u7eba\u4e1d\u5de5\u827a\u5236\u9020\u542b\u6709\u91d1\u5c5e\u6709\u673a\u9aa8\u67b6\uff08MOF\uff09\u9897\u7c92\u548c\u805a\u4e59\u70ef\u9187\u7684\u65b0\u578b\u590d\u5408\u9694\u819c\u3002\u542b\u6709\u91d1\u5c5e\u6d3b\u6027\u4e2d\u5fc3\u7684MOF\u9897\u7c92\u53ef\u4ee5\u81ea\u53d1\u5730\u5438\u9644\u9634\u79bb\u5b50\uff0c\u540c\u65f6\u5141\u8bb8\u9502\u79bb\u5b50\u5728\u7535\u89e3\u8d28\u4e2d\u6709\u6548\u4f20\u8f93\uff0c\u4ece\u800c\u663e\u8457\u6539\u5584\u9502\u79bb\u5b50\u8fc1\u79fb\u6570t<sub>Li<\/sub> <sup>+<\/sup>\uff08\u9ad8\u8fbe0.79\uff09\u548c\u9502\u79bb\u5b50\u7535\u5bfc\u7387\u3002\u540c\u65f6\uff0c\u591a\u5b54\u7684\u590d\u5408\u9694\u819c\u51cf\u5c11\u4e86\u7535\u89e3\u8d28\u7684\u5206\u89e3\uff0c\u4ece\u52a8\u529b\u5b66\u4e0a\u52a0\u5feb\u4e86\u7535\u6781\u53cd\u5e94\uff0c\u5e76\u964d\u4f4e\u4e86\u7535\u89e3\u8d28\u548c\u7535\u6781\u4e4b\u95f4\u7684\u754c\u9762\u7535\u963b\u3002 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<sup>+<\/sup>\u3002\u5c3d\u7ba1\u6709\u90e8\u5206\u62a5\u9053\u4f8b\u5982\u78fa\u5316\u5171\u805a\u7269\u4e0e\u9694\u819c\u7ed3\u5408\u7528\u4ee5\u6539\u5584t<sub>Li<\/sub> <sup>+<\/sup>\uff0c\u4f46\u662f\u8fd9\u79cd\u9694\u819c\u901a\u5e38\u53d7\u9694\u819c\u4e2d\u4f4e\u9502\u79bb\u5b50\u6d53\u5ea6\u7684\u9650\u5236\uff0c\u4ece\u800c\u8868\u73b0\u51fa\u8f83\u4f4e\u7684\u9502\u79bb\u5b50\u4f20\u5bfc\u6027\u3002<\/p>\n<p>\u8fd1\u65e5\uff0c<strong>\u4e0a\u6d77\u7535\u529b\u5927\u5b66<\/strong>\u7684<strong>\u5f6d\u6021\u5a77<\/strong>\u548c<strong>\u52a0\u5229\u798f\u5c3c\u4e9a\u5927\u5b66<\/strong>\u7684<strong>\u5362\u4e91\u5cf0<\/strong>\u6559\u6388<strong>\uff08\u5171\u540c\u901a\u8baf\uff09<\/strong>\u5728<strong>Adv.Mater.<\/strong> \u4e0a\u53d1\u8868\u4e86\u4e00\u7bc7\u9898\u4e3a\u201c<strong>Anion<\/strong><strong>\u2010<\/strong><strong>Sorbent Composite Separators for High<\/strong><strong>\u2010<\/strong><strong>Rate Lithium<\/strong><strong>\u2010<\/strong><strong>Ion Batteries<\/strong>\u201d\u7684\u6587\u7ae0\u3002\u5728\u8fd9\u9879\u5de5\u4f5c\u4e2d\uff0cMOF\u4f5c\u4e3a\u4e00\u79cd\u65b0\u578b\u529f\u80fd\u7ec4\u4ef6\u901a\u8fc7\u9759\u7535\u7eba\u4e1d\u5f15\u5165\u805a\u5408\u7269\u5206\u79bb\u5668\u4e2d\u3002\u4ed6\u4eec\u6700\u8fd1\u53d1\u8868\u4e86\u4e00\u7cfb\u5217\u57fa\u4e8eMOF\u7684\u56fa\u4f53\u7535\u89e3\u8d28\u548c\u6db2\u4f53\u7535\u89e3\u8d28\uff0c\u5176\u4e2dMOF\u4e2d\u7684\u91d1\u5c5e\u6d3b\u6027\u4e2d\u5fc3\uff08OMS\uff09\u53ef\u4ee5\u4e0e\u6eb6\u5242\u586b\u5145\u7684\u5b54\u9053\u4e2d\u7684\u9634\u79bb\u5b50\u7edc\u5408\uff0c\u91ca\u653eLi<sup>+<\/sup>\u5e76\u63d0\u4f9b\u9ad8Li<sup>+<\/sup>\u7535\u5bfc\u7387\u3002\u4e0e\u5177\u6709\u4f4e\u8868\u9762\u79ef\u9676\u74f7\u9897\u7c92\u7684\u9676\u74f7\u6d82\u5c42\u9694\u819c\u6216\u5177\u6709\u4f4eLi<sup>+<\/sup>\u5bfc\u7535\u6027\u7684\u805a\u5408\u7269\u6750\u6599\u4e0d\u540c\uff0cMOF\u7ed3\u5408\u7684\u9694\u819c\u63d0\u4f9b\u9ad8\u8868\u9762\u79ef\u548c\u4e30\u5bcc\u7684OMS\uff0c\u53ef\u63d0\u4f9b\u5feb\u901f\u6709\u6548\u7684\u9502\u79bb\u5b50\u4f20\u8f93\u3002 \u6b64\u5916\uff0c\u4f7f\u7528\u8fd9\u79cd\u542bMOF\u7684\u9694\u819c\u6709\u52a9\u4e8e\u6291\u5236\u7535\u89e3\u8d28\u7684\u5206\u89e3\uff0c\u4ece\u800c\u6539\u5584\u5faa\u73af\u8010\u4e45\u6027\u3002<\/p>\n<p><strong>\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n<p><strong>\u56fe1 MOF-PVA\u590d\u5408\u6750\u6599\u819c\u7684\u5236\u9020\u8fc7\u7a0b<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-173108 aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2019\/04\/1-3.png\" alt=\"\" width=\"700\" height=\"580\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2019\/04\/1-3.png 700w, \/\/m.iemloyee.com\/wp-content\/uploads\/2019\/04\/1-3-300x249.png 300w\" sizes=\"(max-width: 700px) 100vw, 700px\" \/><\/p>\n<p>a\uff09\u793a\u610f\u56fe\uff0c\u663e\u793a\u901a\u8fc7\u9759\u7535\u7eba\u4e1dMOF\u9897\u7c92\u548cPVA\u7684\u6df7\u5408\u7269\u5236\u5907\u9759\u7535\u7eba\u4e1dMOF-polymer\u590d\u5408\u819c\uff08EMP\uff09\uff1b<\/p>\n<p>b\uff0cc\uff09\u793a\u610f\u56fe\uff0c\u663e\u793a\u7528\u4e8e\u5438\u9644\u9634\u79bb\u5b50\u548c\u4fc3\u8fdb\u9502\u79bb\u5b50\u4f20\u8f93\u7684\u529f\u80fd\u6027EMP\u3002<\/p>\n<p>&nbsp;<\/p>\n<p><strong>\u56fe<\/strong><strong>2 EMP<\/strong><strong>\u7684\u7ed3\u6784\u7279\u5f81<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-173104 aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2019\/04\/2-3.png\" alt=\"\" width=\"700\" height=\"442\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2019\/04\/2-3.png 700w, \/\/m.iemloyee.com\/wp-content\/uploads\/2019\/04\/2-3-300x189.png 300w\" sizes=\"(max-width: 700px) 100vw, 700px\" \/><\/p>\n<p>a\uff09EMP\u7684N2\u5438\u9644\/\u89e3\u5438\u7b49\u6e29\u7ebf\u3002 \u63d2\u56fe\u663e\u793a\u4e86DFT\u5b54\u5f84\u5206\u5e03\uff1b<\/p>\n<p>b\uff09MOF\u9897\u7c92\uff0c\u7535\u7ebaPVA\u819c\uff08EP\uff09\u548cEMP\u7684XRD\u56fe\u6848\uff1b<\/p>\n<p>c\uff09MOF\u9897\u7c92\uff0cEP\u548cEMP\u7684FTIR\u5149\u8c31\uff1b<\/p>\n<p>d-f\uff09SEM\u56fe\u50cf\uff1ad\uff09MOF\u9897\u7c92\uff0ce\uff09EP\u548cf\uff09EMP\uff1b<\/p>\n<p>g\uff09\u901a\u8fc7x\u5c04\u7ebf\u5149\u7535\u5b50\u80fd\u8c31\u7ed8\u5236\u7684EMP\u4e2dZr\u5143\u7d20\u7684\u5206\u5e03\uff1b<\/p>\n<p>h\uff09EMP\u7684TEM\u56fe\u50cf\u3002<\/p>\n<p>&nbsp;<\/p>\n<p><strong>\u56fe<\/strong><strong>3 PP<\/strong><strong>\u548c<\/strong><strong>EMP<\/strong><strong>\u7684\u7535\u5316\u5b66\u8868\u5f81<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-173105 aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2019\/04\/3-3.png\" alt=\"\" width=\"700\" height=\"488\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2019\/04\/3-3.png 700w, \/\/m.iemloyee.com\/wp-content\/uploads\/2019\/04\/3-3-300x209.png 300w\" sizes=\"(max-width: 700px) 100vw, 700px\" \/><\/p>\n<p>a\uff09\u5728\u4e0d\u540c\u6e29\u5ea6\u4e0b\u7684\u79bb\u5b50\u7535\u5bfc\u7387\u548c\u4eceArrhenius\u65b9\u7a0b\u7684\u7ebf\u6027\u62df\u5408\u83b7\u5f97\u7684\u6d3b\u5316\u80fd\uff1b<\/p>\n<p>b\uff09\u6bd4\u8f83Li +\u8fc1\u79fb\u6570\u548c\u79bb\u5b50\u7535\u5bfc\u7387\uff1b<\/p>\n<p>c\uff0cd\uff09SS |\u7535\u89e3\u8d28| Li\u7535\u6c60\u7684\u5faa\u73af\u4f0f\u5b89\u66f2\u7ebf\uff0c\u5176\u4e2d\uff1ac\uff09LP-PP\u548cLP-EMP\uff0c\u548cd\uff09LC-PP\u548cLC-EMP\uff0c\u626b\u63cf\u901f\u7387\u4e3a1mV s<sup>-1<\/sup>\u3002<\/p>\n<p>&nbsp;<\/p>\n<p><strong>\u56fe<\/strong><strong>4 <\/strong><strong>\u7535\u89e3\u8d28<\/strong><strong> &#8211; <\/strong><strong>\u7535\u6781\u754c\u9762\u7684\u7814\u7a76<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-173106 aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2019\/04\/4-3.png\" alt=\"\" width=\"700\" height=\"256\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2019\/04\/4-3.png 700w, \/\/m.iemloyee.com\/wp-content\/uploads\/2019\/04\/4-3-300x110.png 300w\" sizes=\"(max-width: 700px) 100vw, 700px\" \/><\/p>\n<p>a\uff09Li | LP-PP | Li\u7535\u6c60\u548cLi | LP-EMP | Li\u7535\u6c60\u57285mA cm -2\u4e0b\u7684\u6052\u7535\u6d41\u5faa\u73af\uff1b<\/p>\n<p>b\uff09\u663e\u793a\u6700\u540e\u4e94\u4e2a\u5faa\u73af\u7684\u76f8\u5e94\u653e\u5927\u56fe\uff1b<\/p>\n<p>c\uff09\u5faa\u73afLi | LP-PP | Li\u548cLi | LP-EMP | Li\u7535\u6c60\u7684\u5948\u594e\u65af\u7279\u56fe\uff08200\u6b21\u5faa\u73af\u540e\uff09<\/p>\n<p>d\uff09200\u6b21\u5faa\u73af\u540e\u4eceLi | LP-PP | Li\u548cLi | LP-EMP | Li\u7535\u6c60\u6536\u83b7\u7684XPS\u7684F 1s\u5149\u8c31\u548c\u5faa\u73afLi\u7684\u53bb\u5377\u79ef\u5cf0\uff1b<\/p>\n<p>e-h\uff09\u6765\u81ea\u4ee5\u4e0b\u7684\u5faa\u73afLi\u7535\u6781\u7684SEM\u56fe\u50cf\uff1ae\uff0cf\uff09Li | LP-PP | Li\u548cg\uff0ch\uff09Li | LP-EMP | Li\u7535\u6c60\u3002<\/p>\n<p>&nbsp;<\/p>\n<p><strong>\u56fe<\/strong><strong>5 <\/strong><strong>\u4e0d\u540c\u7535\u89e3\u8d28\u7535\u6c60\u7684\u7535\u5316\u5b66\u6027\u80fd<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-173107 aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2019\/04\/5-1.png\" alt=\"\" width=\"700\" height=\"371\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2019\/04\/5-1.png 700w, \/\/m.iemloyee.com\/wp-content\/uploads\/2019\/04\/5-1-300x159.png 300w\" sizes=\"(max-width: 700px) 100vw, 700px\" \/><\/p>\n<p>a\uff0cb\uff09\u4f7f\u7528LP\u7535\u89e3\u8d28\u7684NCM |\u77f3\u58a8\u7535\u6c60\u7684\u7535\u5316\u5b66\u6027\u80fd\uff1aa\uff09\u57281,0.2,0.5,1\u548c2\u2103\u4e0b\u7684\u500d\u7387\u6027\u80fd; b\uff09\u57281C\u4e0b\u8fdb\u884c\u6052\u7535\u6d41\u5faa\u73af\uff08\u6700\u521d\u76845\u4e2a\u5faa\u73af\uff0c0.2\u2103\uff09\u3002<\/p>\n<p>c\uff0cd\uff09\u4f7f\u7528LC\u7535\u89e3\u8d28\u7684LFP | LTO\u7535\u6c60\u7684\u7535\u5316\u5b66\u6027\u80fd\uff1ac\uff09\u57281,0.2,0.5,1\u548c2\u2103\u4e0b\u7684\u500d\u7387\u6027\u80fd; d\uff09\u57281C\u4e0b\u7684\u6052\u7535\u6d41\u5faa\u73af\uff08\u57280.2C\u4e0b\u7684\u6700\u521d\u5341\u4e2a\u5faa\u73af\uff09\u3002<\/p>\n<p>&nbsp;<\/p>\n<p><strong>\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n<p>\u7814\u7a76\u4eba\u5458\u8bc1\u660e\u4e86\u4f7f\u7528\u9759\u7535\u7eba\u4e1d\u6280\u672f\u5236\u9020\u5d4c\u5165MOF\u9897\u7c92\u4f5c\u4e3a\u6709\u6548\u9634\u79bb\u5b50\u5438\u9644\u5242\u7684\u590d\u5408\u6750\u6599\u9694\u819c\u3002\u7535\u89e3\u8d28\u4e2d\u7684\u9634\u79bb\u5b50\u4e0eMOF\u9897\u7c92\u7684OMS\u7684\u7edc\u5408\u6539\u5584\u4e86t<sub>Li<\/sub> <sup>+<\/sup>\u548cLi<sup> 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