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O2<\/sub>\u8f6c\u5316\u4e3a1<\/sup>O2<\/sub>\u3002\u76f8\u5e94\u7684MOF\u4e0d\u4ec5\u4fdd\u62a4\u4e86\u8fc7\u6c27\u5316\u6c22\u9176\u5728\u9178\u6027\u80bf\u7624\u5fae\u73af\u5883\u4e0b\u7684\u50ac\u5316\u6d3b\u6027\uff0c\u4f7f\u5176\u80fd\u591f\u81ea\u4f9b\u7ed9\u8db3\u591f\u7684O2<\/sub>\uff0c\u5c06O2<\/sub>\u76f4\u63a5\u6ce8\u5165MOF\u654f\u5316\u7684BQ\u5185\uff0c\u00a0\u4f7f\u5f97\u5355\u7ebf\u6001\u6c27\u7684\u91cf\u5b50\u4ea7\u7387\u8f83\u9ad8\u3002\u654f\u5316\u540eMOF\u7cfb\u7edf\u7684\u5149\u52a8\u529b\u6cbb\u7597\u6548\u7387\u662f\u672a\u52a0\u8fc7\u6c27\u5316\u6c22\u9176\u76848.7\u500d\uff0c\u5bf9\u7f3a\u6c27\u80bf\u7624\u7ec6\u80de\u7684\u6cbb\u7597\u6548\u679c\u589e\u5f3a\u3002\u6b64\u5916\uff0c\u901a\u8fc7\u4e0eBQs\u5149\u70ed\u6cbb\u7597\u7684\u7ed3\u5408\uff0c\u5728\u4f53\u5185\u5916\u5b9e\u73b0\u4e86\u5149\u52a8\u529b-\u70ed\u534f\u540c\u6cbb\u7597\u3002\u9010\u6b65\u5c01\u88c5\u7684\u540c\u6e90MOF\u6742\u5316\u4f53\u4e0d\u4ec5\u4fdd\u6301\u4e86\u751f\u7269\u5206\u5b50\u7684\u529f\u80fd\uff0c\u800c\u4e14\u52a0\u901f\u4e86\u534f\u540c\u6548\u5e94\uff0c\u4e3a\u5e7f\u6cdb\u5e94\u7528\u63d0\u4f9b\u4e86\u53ef\u7f16\u7a0b\u5e73\u53f0\u3002\u76f8\u5173\u6587\u7ae0\u5728\u7ebf\u53d1\u8868\u5728Angewandte Chemie International Edition\u4e0a\u3002<\/p>\n \u56fe4\u00a0 \u540c\u6e90MOFs\u4e2d\u7684\u9010\u6b65\u7ec4\u88c5\u53ca\u5176\u4f5c\u5bf9\u7f3a\u6c27\u80bf\u7624\u7ec6\u80de\u7684\u589e\u5f3a\u6cbb\u7597<\/p>\n \u56db\u3001\u8282\u70b9\u4fee\u9970\u5b9e\u73b0\u8d85\u758f\u6c34M<\/b><\/strong>OF<\/b><\/strong><\/p>\n MOFs\u7684\u758f\u6c34\u5316\u5bf9\u4fc3\u8fdb\u5176\u5b9e\u9645\u5e94\u7528\u5177\u6709\u91cd\u8981\u610f\u4e49\uff0c\u56e0\u6b64\u5f15\u8d77\u4e86\u8d8a\u6765\u8d8a\u591a\u7684\u5173\u6ce8\u3002\u4e0e\u5148\u524d\u62a5\u9053\u7684\u4e3b\u8981\u96c6\u4e2d\u5728MOF\u4e2d\u6709\u673a\u914d\u4f53\u7684\u6539\u6027\u4e0d\u540c, \u97e9\u56fd\u6d66\u9879\u79d1\u6280\u5927\u5b66\u7684Dong-Pyo Kim\u6559\u6388\u62a5\u9053\u4e00\u9879\u65b0\u7b56\u7565\u6765\u4fee\u9970MOF\u7684metal-oxo\u8282\u70b9\uff0c\u5b9e\u73b0\u4e86\u9ad8\u63a5\u89e6\u89d2161\u00b0\u7684\u82ef\u57fa\u7845\u70f7\u5236\u5907\u7684\u8d85\u758f\u6c34NH2<\/sub>-UiO-66(Zr)-shp, \u4e0eNH2<\/sub>-UiO-66(Zr)\u76f8\u6bd4\uff0cNH2-UiO-66(Zr)-shp\u5177\u6709\u8f83\u5f3a\u7684\u758f\u6c34\u80fd\u529b\uff0c\u4ece\u800c\u4f7f\u78b1\u57fa\u7535\u963b\u5927\u5927\u63d0\u9ad8\uff0c\u56e0\u4e3aNH2-UiO-66(Zr)\u5728\u78b1\u6027\u6761\u4ef6\u4e0b\u8fc5\u901f\u5206\u89e3\u3002NH2-UiO-66(Zr)- shp\u7684\u8d85\u758f\u6c34\u6027\u548c\u4f18\u5f02\u7684\u7a33\u5b9a\u6027\u4e5f\u4f7f\u5176\u5177\u6709\u5e7f\u6cdb\u7684\u5e94\u7528\u524d\u666f\uff0c\u5305\u62ec\u7528\u4e8e\u5fae\u6d41\u4f53\u8bbe\u5907\u548c\u4f20\u611f\u7684\u6709\u673a\/\u6c34\u5206\u79bb\u3001\u81ea\u6e05\u6d17\u548c\u6db2\u4f53\u5f39\u73e0\u3002\u8003\u8651\u5230\u82ef\u57fa\u7845\u70f7\u53ef\u4ee5\u5f88\u5bb9\u6613\u5730\u63a5\u679d\u5230\u7f9f\u57fa\u8868\u9762\uff0c\u4e14metal-oxo\u8282\u70b9\u5728MOFs\u4e2d\u5e7f\u6cdb\u5b58\u5728\uff0c\u56e0\u6b64\u8bbe\u8ba1\u7684\u8d85\u758f\u6c34MOFs\u7684metal-oxo\u8282\u70b9\u4fee\u9970\u7b56\u7565\u53ef\u4ee5\u63a8\u5e7f\u5230\u591a\u79cdMOFs\uff0c\u4ece\u800c\u4ea7\u751f\u5927\u91cf\u7684\u8d85\u758f\u6c34MOFs\u3002\u56e0\u6b64\uff0c\u8fd9\u9879\u7814\u7a76\u5de5\u4f5c\u4e0d\u4ec5\u4e3a\u5404\u79cd\u529f\u80fd\u5e94\u7528\u63d0\u4f9b\u4e86\u4e00\u79cd\u6709\u524d\u666f\u7684\u6750\u6599\uff0c\u800c\u4e14\u66f4\u91cd\u8981\u7684\u662f\u4e3a\u8bbe\u8ba1\u5b9e\u7528\u7684\u8d85\u758f\u6c34MOFs\u63d0\u4f9b\u4e86\u4e00\u79cd\u65b0\u7684\u901a\u7528\u65b9\u6cd5\u3002\u76f8\u5173\u6587\u7ae0\u5728\u7ebf\u53d1\u8868\u5728Angewandte Chemie International Edition\u4e0a\u3002<\/p>\n \u56fe5\u00a0 \u8d85\u758f\u6c34NH2<\/sub>-UiO-66\uff08Zr\uff09-shp\u7684\u5236\u5907\u53ca\u5176\u591a\u7528\u9014<\/p>\n \u4e94\u3001\u91d1\u5c5e\u53d6\u4ee3\u4fee\u9970M<\/b><\/strong>OF<\/b><\/strong>\u7535\u5b50\u7ed3\u6784<\/b><\/strong><\/p>\n \u7535\u5b50\u7ed3\u6784\u7684\u5b9a\u5411\u6539\u6027\u662f\u4f18\u5316\u5728\u5149\u4f0f\u3001\u4f20\u611f\u548c\u5149\u50ac\u5316\u5e94\u7528\u7684MOFs\u7684\u4e00\u4e2a\u91cd\u8981\u6b65\u9aa4\u3002\u9700\u8981\u63a7\u5236\u7684\u5173\u952e\u53c2\u6570\u5305\u62ec\u5e26\u9699\u3001\u5e26\u8fb9\u7f18\u7684\u7edd\u5bf9\u80fd\u91cf\u4f4d\u7f6e\u3001\u6fc0\u53d1\u6001\u7535\u8377\u5206\u79bb\u4ee5\u53ca\u91d1\u5c5e\u4e0e\u914d\u4f53\u4f4d\u70b9\u7684\u6742\u5316\u7a0b\u5ea6\u7b49\u7b49\u3002\u7136\u800c\u4e8c\u7ea7\u5efa\u7b51\u5355\u5143\u5185\u7684\u90e8\u5206\u91d1\u5c5e\u7f6e\u6362\u6216\u91d1\u5c5e\u63ba\u6742\u662f\u4e00\u79cd\u5f88\u6709\u524d\u9014\u7684\u65b9\u6cd5\uff0c\u4f46\u5728MOFs\u4e2d\u8c03\u8282\u8fd9\u4e9b\u6027\u80fd\u7684\u65b9\u6cd5\u8fd8\u672a\u88ab\u63a2\u7d22\u3002\u4e3a\u6b64\uff0c\u83ab\u65af\u79d1\u56fd\u7acb\u5927\u5b66\u7684Maria A. Syzgantseva\u548c\u6d1b\u6851\u8054\u90a6\u7406\u5de5\u5b66\u9662\u7684Olga A. Syzgantseva\u6559\u6388\u4ece\u7406\u8bba\u4e0a\u63d0\u51fa\u4e86\u4e00\u79cd\u9009\u62e9\u91d1\u5c5e\u63ba\u6742\u5242\u7684\u901a\u7528\u65b9\u6cd5\uff0c\u5e76\u4ee5MIL-125\u548cUiO-66\u4e3a\u6a21\u578b\u7cfb\u7edf\u8fdb\u884c\u4e86\u5b9e\u9a8c\u9a8c\u8bc1\u3002\u5728MOFs\u4e2d\u63ba\u6742\u91d1\u5c5e\u8282\u70b9\u53ef\u4ee5\u6539\u53d8\u5e26\u9699\u548c\u5e26\u8fb9\u7f18\u4f4d\u7f6e\uff0c\u5b9e\u73b0\u4ee5\u91d1\u5c5e\u4e3a\u4e2d\u5fc3\u7684\u7535\u5b50\u5b9a\u4f4d\uff0c\u8fd8\u53ef\u4ee5\u6539\u53d8\u914d\u4f53-\u91d1\u5c5e\u7684\u6742\u5316\u7a0b\u5ea6\uff0c\u662f\u4e00\u79cd\u6709\u6548\u7684\u7b56\u7565\u3002\u6c27\u5316\u7269\u7684\u80fd\u5e26\u6392\u5217\u548c\u5e26\u9699\u662f\u63ba\u6742\u5242\u9884\u7b5b\u7684\u6709\u6548\u6807\u51c6\u3002\u7279\u522b\u662f\uff0c\u4e3a\u4e86\u901a\u8fc7\u91d1\u5c5e\u4e2d\u5fc3\u7535\u5b50\u9677\u9631\u7684\u4ea7\u751f\u6765\u5b9e\u73b0\u6709\u6548\u7684\u7535\u8377\u5206\u79bb\uff0c\u63ba\u6742\u91d1\u5c5e\u5e94\u8be5\u6bd4\u4e3b\u4f53\u91d1\u5c5e\u66f4\u5bb9\u6613\u5f62\u6210\u53ef\u8fd8\u539f\u7684\u91d1\u5c5e\u6c27\u5316\u7269\uff0c\u8fd9\u610f\u5473\u7740\u4ea7\u751f\u66f4\u5c0f\u7684\u5e26\u9699\u548c\u66f4\u4f4e\u7684\u4f20\u5bfc\u5e26\u8fb9\u7f18\u7684\u7edd\u5bf9\u4f4d\u7f6e\u3002\u4e00\u822c\u6765\u8bf4\uff0c\u9075\u5faa\u8fd9\u4e9b\u6807\u51c6\u53ef\u4ee5\u5b9e\u73b0\u7535\u5b50\u7ed3\u6784\u7684\u6709\u5229\u6539\u53d8\u3002\u5b9e\u9a8c\u8bc1\u660e\uff0c\u5728UiO-66-NH2<\/sub>(Zr,Nb)\u548cMIL-125-NH2<\/sub>(Ti,V)\u7cfb\u7edf\u4e2d\uff0c\u5229\u7528\u8fd9\u4e9b\u89c4\u5219\u8bbe\u8ba1\u5177\u6709\u9884\u5b9a\u7535\u5b50\u7ed3\u6784\u7279\u5f81\u7684MOFs\u662f\u53ef\u884c\u7684\u3002\u6240\u8ff0\u7684\u4e00\u822c\u539f\u5219\u9002\u7528\u4e8e\u4efb\u4f55MOF\u4f53\u7cfb\u7ed3\u6784\uff0c\u5e76\u53ef\u7528\u4e8e\u4ee5\u6709\u9488\u5bf9\u6027\u7684\u65b9\u5f0f\u5fae\u8c03\u73b0\u6709MOFs\u7684\u7535\u5b50\u7279\u6027\u3002\u76f8\u5173\u6587\u7ae0\u5728\u7ebf\u53d1\u8868\u5728J. Am. Chem. Soc\u4e0a\u3002<\/p>\n \u56fe6\u00a0 \u5206\u522b\u63ba\u6742V\u3001Nb\u91d1\u5c5e\u8282\u70b9\u7684MOF\u7ed3\u6784<\/p>\n \u516d\u3001\u534f\u8c03\u8fd8\u539f\u589e\u5f3aM<\/b><\/strong>OF<\/b><\/strong>s\u6c34\u89e3\u7a33\u5b9a\u6027<\/b><\/strong><\/p>\n \u63d0\u9ad8MOFs\u7684\u6c34\u89e3\u7a33\u5b9a\u6027\u662fMOFs\u5316\u5b66\u4e2d\u4e00\u4e2a\u5177\u6709\u6311\u6218\u6027\u7684\u95ee\u9898\uff0c\u56e0\u4e3a\u5927\u591a\u6570MOFs\u5728\u6f6e\u6e7f\u73af\u5883\u4e0b\u7684\u5e94\u7528\u90fd\u5b58\u5728\u5c40\u9650\u6027\u3002\u540c\u65f6\uff0c\u5185\u7403\u7535\u5b50\u8f6c\u79fb\u5df2\u6210\u4e3a\u5f53\u4ee3\u5316\u5b66\u7814\u7a76\u7684\u70ed\u70b9\u4e4b\u4e00\u3002\u8fd1\u65e5\uff0c\u97e9\u56fdDGIST\u7684Dohyun Moon\u6559\u6388\u53ca\u00a0<\/b><\/strong>Nak Cheon Jeong\u6559\u6388\u9996\u6b21\u63d0\u51fa\u4e86\u4e00\u79cd\u65b0\u6982\u5ff5\u4e0a\u7684Cu2+<\/sup>\u79bb\u5b50\u534f\u540c\u8fd8\u539f\u65b9\u6cd5\uff0c\u8be5\u65b9\u6cd5\u662f\u5728\u6868\u8f6e\u7ed3\u6784\u7684MOF (HKUST-1)\u4e0a\u5b9e\u73b0\u7684\uff0c\u901a\u8fc7\u5176\u914d\u4f4d\u952e\u5c06\u5185\u7403\u4f53\u5355\u7535\u5b50\u4ece\u5bf9\u82ef\u4e8c\u915a(H2<\/sub>Q)\u8f6c\u79fb\u5230Cu2+<\/sup>\u3002\u8fd9\u79cd\u914d\u4f4d\u8fd8\u539f\u662f\u4e00\u79cd\u5728\u94dc\u7684\u6c27\u5316\u6001\u548c\u6570\u91cf\u4e0a\u90fd\u80fd\u81ea\u6211\u63a7\u5236\u7684\u4f18\u826f\u5316\u5b66\u8fc7\u7a0b\u3002H2<\/sub>Q\u5904\u7406\u540e\u7684HKUST-1\u5728\u65e0\u6c34\u6761\u4ef6\u4e0b\u53ef\u4ee5\u5c06\u7ea630% Cu2+<\/sup>\u8fd8\u539f\u6210\u5355\u7535\u8377\u7684Cu+<\/sup>\u3002\u800c\u4e14\u4e00\u65e6Cu2+<\/sup>\u79bb\u5b50\u88ab\u8fd8\u539f\u4e3aCu+<\/sup>\uff0c\u65e0\u8bba\u662f\u6c27\u5316\u6001\u8fd8\u662f\u8fd8\u539f\u91cf\uff0c\u8fd8\u539f\u53cd\u5e94\u90fd\u4e0d\u4f1a\u8fdb\u4e00\u6b65\u8fdb\u884c\u3002\u7814\u7a76\u4eba\u5458\u8fd8\u8bc1\u660e\u4e86\u4e00\u534a\u7684Cu+<\/sup>\u79bb\u5b50(\u7ea615%)\u5728\u4f2a\u6b63\u65b9\u5f62\u5e73\u9762\u51e0\u4f55\u7684\u6846\u67b6\u4e2d\u6b8b\u7559\uff0c\u53e6\u4e00\u534a\u7684Cu+<\/sup>\u79bb\u5b50(\u7ea615%)\u4e0e\u6846\u67b6\u5206\u79bb\u540e\u5728\u5c0f\u7b3c\u4e2d\u5f62\u6210[Cu(MeCN)4<\/sub>]+<\/sup>\u7edc\u5408\u7269\u3002\u5373\u4f7f\u5728\u6f6e\u6e7f\u7a7a\u6c14\u4e2d\u66b4\u9732\u4e24\u5e74\u4e4b\u540e\uff0cHKUST-1\u7684\u7ed3\u6784\u4ecd\u7136\u4fdd\u6301\u5b8c\u6574\uff0c\u8fd9\u79cd\u534f\u540c\u8fd8\u539f\u663e\u8457\u63d0\u9ad8HKUST-1\u7684\u6c34\u89e3\u7a33\u5b9a\u6027\u3002\u8fd9\u79cd\u589e\u5f3a\u5f52\u56e0\u4e8e\u6c27\u542b\u91cf\u4e30\u5bcc\u7684\u7535\u8d1f\u6027\u91d1\u5c5e\u8282\u70b9\u968f\u7740\u914d\u4f4d\u5f3a\u5ea6\u7684\u589e\u52a0\u800c\u8d8b\u4e8e\u7a33\u5b9a\u3002\u76f8\u5173\u6587\u7ae0\u5728\u7ebf\u53d1\u8868\u5728J. Am. Chem. Soc\u4e0a\u3002<\/p>\n \u56fe7 H2<\/sub>Q\u4fee\u9970\u7684HKUST-1\u7ed3\u6784\u53ca\u516b\u9762\u4f53\u7b3c\u4e2d\u5f62\u6210\u7684\u7edc\u5408\u7269\u6a21\u578b<\/p>\n \u53c2\u8003\u6587\u732e\uff1a<\/b><\/strong><\/p>\n 1\u3001Unidirectional rotary motion in a metal\u2013organic framework\uff1ahttps:\/\/doi.org\/10.1038\/s41565-019-0401-6<\/u><\/a><\/p>\n 2\u3001Rational approach to guest confinement inside MOF cavities for low-temperature catalysis:\u00a0Nature Communications | (2019) 10:1340 |https:\/\/doi.org\/10.1038\/s41467-019-08972-x|www.nature.com\/naturecommunications<\/p>\n 3\u3001Homologous Metal-Organic Framework Hybrid as Tandem Catalyst for Enhanced Therapy against Hypoxic Tumor Cells:\u00a0https:\/\/doi.org\/10.1002\/anie.201903475<\/a><\/p>\n 4\u3001Pore Surface Engineering by Decorating Metal-oxo Nodes with Phenylsilane for Versatile Super-\u00a0Hydrophobic Metal-Organic Frameworks (MOFs)\uff1ahttps:\/\/doi.org\/10.1002\/anie.201902961<\/a><\/p>\n 5\u3001Metal Substitution as the Method of Modifying Electronic Structureof Metal-Organic Frameworks: DOI: 10.1021\/jacs.8b13667<\/p>\n 6\u3001Coordinative Reduction of Metal Nodes Enhances the Hydrolytic Stability of a Paddlewheel Metal-Organic Framework : DOI: 10.1021\/jacs.9b02114<\/p>\n \u5f80\u671f\u56de\u987e\uff1a<\/strong><\/p>\n \u53d8\u5f62\u8bb0\uff1a\u5982\u4f55\u6784\u5efaMOF\u7684\u516b\u9762\u73b2\u73d1\u5fc3<\/a><\/p>\n MOF\u4e13\u680f & PPT \u2014\u2014 \u56fd\u9645\u77e5\u540dMOF\u5927\u725b\u96c6\u9526<\/a><\/p>\n MOF\u4e13\u680f & PPT\u2014\u2014\u56fd\u5185MOF\u5927\u725b\u96c6\u9526<\/a><\/p>\n
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