{"id":172607,"date":"2019-04-13T06:27:13","date_gmt":"2019-04-12T22:27:13","guid":{"rendered":"\/\/m.iemloyee.com\/?p=172607"},"modified":"2019-04-12T10:30:11","modified_gmt":"2019-04-12T02:30:11","slug":"acs-applied-materials-interfaces%ef%bc%9a%e7%a3%b7%e6%8e%ba%e6%9d%82%e7%89%a9%e7%a7%8d%e5%9c%a8%e7%9f%b3%e5%a2%a8%e7%83%af%e4%b8%ad%e7%9a%84%e7%bb%93%e6%9e%84%e6%bc%94%e5%8f%98%e5%8f%8a%e5%85%b6","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=172607","title":{"rendered":"ACS Applied Materials & Interfaces\uff1a\u78f7\u63ba\u6742\u7269\u79cd\u5728\u77f3\u58a8\u70ef\u4e2d\u7684\u7ed3\u6784\u6f14\u53d8\u53ca\u5176\u7a33\u5b9a\u7535\u5316\u5b66\u754c\u9762\u7814\u7a76"},"content":{"rendered":"

\u3010\u80cc\u666f\u4ecb\u7ecd\u3011<\/strong><\/p>\n

\u78f7\u63ba\u6742\u662f\u8c03\u63a7\u70ad\u6750\u6599\u8868\u9762\u6027\u80fd\u7684\u91cd\u8981\u624b\u6bb5\u4e4b\u4e00\uff0c\u5728\u80fd\u6e90\u5b58\u50a8\u4e0e\u8f6c\u5316\u9886\u57df\u53d7\u5230\u5e7f\u6cdb\u5173\u6ce8\u3002\u867d\u7136\u76ee\u524d\u78f7\u63ba\u6742\u70ad\u6750\u6599\u5df2\u7ecf\u6709\u5927\u91cf\u7814\u7a76\uff0c\u4f46\u7531\u4e8e\u5e38\u89c4\u78f7\u63ba\u6742\u70ad\u6750\u6599\u7684\u5b54\u7ed3\u6784\u53d1\u8fbe\uff0c\u542b\u6c27\u5b98\u80fd\u56e2\u4e30\u5bcc\uff0c\u4f7f\u5f97\u5927\u91cf\u7684\u78f7\u63ba\u6742\u7269\u79cd\u4e0d\u53ef\u907f\u514d\u5730\u88ab\u5305\u57cb\u5165\u590d\u5408\u78b3\u57fa\u4f53\u4e2d\uff0c\u8fd9\u79cd\u78f7\u7269\u79cd\u7684\u4e0d\u5145\u5206\u66b4\u9732\u6027\u548c\u53ef\u83b7\u5f97\u6027\u5dee\u5bfc\u81f4\u4e86\u5173\u4e8e\u78b3\u6676\u683c\u4e2d\u78f7\u7269\u79cd\u7684\u5b58\u5728\u5f62\u5f0f\uff0c\u7ed3\u6784\u6f14\u53d8\u89c4\u5f8b\u548c\u7535\u5316\u5b66\u884c\u4e3a\u4f5c\u7528\u673a\u5236\u4e0a\u7684\u8ba4\u8bc6\u6709\u8bb8\u591a\u6a21\u7cca\u7684\u5730\u65b9\u3002\u5bf9\u4e8e\u8fd9\u65b9\u9762\u8ba4\u8bc6\u7684\u4e0d\u5145\u5206\u6027\uff0c\u5f88\u5927\u7a0b\u5ea6\u4e0a\u963b\u788d\u4e86\u5bf9\u4e8e\u8bbe\u8ba1\u66f4\u52a0\u5408\u7406\u7684\u65b0\u578b\u9ad8\u6027\u80fd\u78f7\u63ba\u6742\u70ad\u6750\u6599\u7684\u8fdb\u7a0b\u3002<\/p>\n

\u8fd1\u671f\uff0c\u4e2d\u79d1\u9662\u7164\u5316\u6240\u9648\u6210\u731b\u56e2\u961f\u5728\u78f7\u63ba\u6742\u70ad\u6750\u6599\u8868\u9762\u5316\u5b66\u673a\u5236\u7814\u7a76\u65b9\u9762\u53d6\u5f97\u8fdb\u5c55<\/b><\/strong>\u3002\u524d\u671f\u5de5\u4f5c\u4e2d\uff0c\u8be5\u56e2\u961f\u4ee5\u65e0\u70df\u7164\u4e3a\u539f\u6599\uff0c\u901a\u8fc7\u78f7\u9178\u6d3b\u5316\u5408\u6210\u4e86\u4ecb\u5b54\u70ad\u6750\u6599\u3002\u7814\u7a76\u53d1\u73b0\u78f7\u9178\u5728\u6d3b\u5316\u9020\u5b54\u7684\u540c\u65f6\uff0c\u8fd8\u5177\u6709\u540c\u6b65\u63ba\u78f7\u7684\u4f5c\u7528\uff0c\u5176\u63ba\u6742\u91cf\u8fbe0.49 wt%\uff0c\u8fd9\u79cd\u78f7\u6742\u591a\u5b54\u70ad\u5728\u5e94\u7528\u4e8e\u8d85\u7ea7\u7535\u5bb9\u5668\u65f6\uff0c\u5176\u5728Et4<\/sub>NBF4<\/sub>\/PC\u6709\u673a\u7535\u89e3\u6db2\u4e2d\u7684\u7535\u538b\u7a97\u53e3\u53ef\u4ece2.7\u00a0V\u6269\u5927\u52303.0\u00a0V\uff0c\u4e14\u5c55\u793a\u51fa\u4f18\u5f02\u7684\u5faa\u73af\u7a33\u5b9a\u6027\uff08Electrochimica Acta. 2018, 266, 420-430\uff09\u3002\u7136\u800c\u5728\u4e0a\u8ff0\u8fc7\u7a0b\u4e2d\uff0c\u9274\u4e8e\u7164\u57fa\u591a\u5b54\u70ad\u7684\u7ed3\u6784\u590d\u6742\u6027\u5e76\u672a\u5c31\u78f7\u539f\u5b50\u5bf9\u70ad\u6750\u6599\u7684\u63ba\u6742\u673a\u5236\u3001\u542b\u78f7\u5b98\u80fd\u56e2\u7684\u5b58\u5728\u5f62\u5f0f\u53ca\u6f14\u53d8\u89c4\u5f8b\u3001\u5176\u4e0e\u7535\u5316\u5b66\u6027\u80fd\u95f4\u7684\u6784\u6548\u5173\u7cfb\u7b49\u8fdb\u884c\u66f4\u52a0\u6df1\u5165\u7684\u89e3\u6790\uff0c\u4e5f\u7ed9\u4e0a\u8ff0\u5171\u6027\u79d1\u5b66\u95ee\u9898\u7684\u7814\u7a76\u5e26\u6765\u6311\u6218\u3002<\/p>\n

\u800c\u77f3\u58a8\u70ef\u4f5c\u4e3a\u70ad\u6750\u6599\u7684\u57fa\u672c\u7ed3\u6784\u5355\u5143\uff0c\u5177\u6709\u5178\u578b\u7684\u4e8c\u7ef4\u7ed3\u6784\uff0c\u8be5\u56e2\u961f\u4ee5\u5176\u4e3a\u7b80\u5316\u7684\u7814\u7a76\u6a21\u578b\uff0c\u8fdb\u4e00\u6b65\u63a2\u7a76\u4e86\u70ad\u6750\u6599\u8868\u9762\u78f7\u7269\u79cd\u7684\u63ba\u6742\u3001\u6f14\u53d8\u53ca\u4f5c\u7528\u673a\u5236\u3002\u4f5c\u8005\u4ee5\u90e8\u5206\u70ed\u8fd8\u539f\u7684\u6c27\u5316\u77f3\u58a8\u70ef\u4e3a\u539f\u6599\uff0c\u5148\u901a\u8fc7H3<\/sub>PO4<\/sub>\u8fdb\u884c\u9ad8\u6e29\u6d3b\u5316\uff0c\u800c\u540e\u5728\u9ad8\u6e29\u60f0\u6027\u6c14\u6c1b\u4e0b\u4f5c\u949d\u5316\u5904\u7406\uff0c\u5f97\u5230\u4e00\u7cfb\u5217\u78f7\u63ba\u6742\u77f3\u58a8\u70ef\u6837\u672c\u5e76\u505a\u4e86\u7cfb\u7edf\u7814\u7a76\u3002\u76f8\u5173\u7814\u7a76\u6210\u679c\u8fd1\u671f\u5df2\u5728\u7ebf\u53d1\u8868\u5728ACS Applied Materials & Interfaces<\/i><\/b><\/em><\/strong>.<\/i><\/em>\u6742\u5fd7\u4e0a\u00a0<\/i><\/em>(DOI:10.1021\/acsami.8b21903)\uff0c\u8bba\u6587\u7b2c\u4e00\u4f5c\u8005\u4e3a\u7855\u58eb\u7814\u7a76\u751f\u6bd5\u5fd7\u5b8f\uff0c\u901a\u8baf\u4f5c\u8005\u4e3a\u9648\u6210\u731b\u7814\u7a76\u5458\u3001\u8c22\u8389\u5a67\u526f\u7814\u7a76\u5458\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n

\u56fe1\u3001\u4e0d\u540c\u77f3\u58a8\u70ef(a)\u00a0G600\uff0c(b) G800\uff0c(c) PG800\uff0c(d) PG800S\u7684TEM\u5f62\u8c8c\u6bd4\u8f83\u53caPG800S\u7684EDS\u00a0mapping\u56fe\u3002<\/p>\n

\"\"<\/p>\n

\u56fe2\u3001\u77f3\u58a8\u70ef\u4e2d\u78f7\u6784\u578b\u7684\u5b58\u5728\u5f62\u5f0f\u53ca\u6784\u578b\u6f14\u53d8\u89c4\u5f8b\u89e3\u6790<\/p>\n

\"\"<\/p>\n

\u4ece\u7ea2\u5916\u7ed3\u679c\u53ef\u521d\u6b65\u786e\u5b9a\uff1a\u5728668 cm-1<\/sup>\u5904\uff0c\u78b3\u6676\u683c\u4e2d\u5f62\u6210\u4e86C-P\u952e\u5e76\u4e14\u7ecf\u8fc7\u8fdb\u4e00\u6b65\u9ad8\u6e29\u949d\u5316\u5904\u7406C-P\u952e\u4fe1\u53f7\u660e\u663e\u589e\u5f3a\uff0c\u542b\u91cf\u8fdb\u4e00\u6b65\u589e\u591a\uff1b\u800c\u57281085-1193 cm-1<\/sup>\u533a\u95f4\u5185\u662f\u591a\u79cd\u5b98\u80fd\u56e2\u7684\u4fe1\u53f7\u53e0\u52a0\u533a\uff0c\u5305\u542b\u6709\u6c22\u952e\u7684P=O\u57fa\u56e2\u4f38\u7f29\u632f\u52a8\uff1bP-O-C\uff08\u82b3\u73af\u7cfb\uff09\u4e2d\u542bO-C\u952e\u7684\u4f38\u7f29\u632f\u52a8\uff1b\u542b-OH\u7684P=OOH\u952e\u4f38\u7f29\u632f\u52a8\u3002<\/p>\n

\u8fdb\u4e00\u6b65\u901a\u8fc7XPS\u5f97\u51fa\uff1a\u4e0d\u540c\u5143\u7d20\u7684\u542b\u91cf\u5982\u88681\u6240\u793a\uff1b\u78b3\u6676\u683c\u4e2d\u5b58\u5728C3<\/sub>-P=O\uff0cC-P-O\uff0cC3<\/sub>-P\u548cC-O-P\u56db\u79cd\u57fa\u672c\u78f7\u6784\u578b\uff0c\u5404\u81ea\u5728\u4e0d\u540c\u70ed\u5904\u7406\u9636\u6bb5\u7684\u5360\u6bd4\u5982\u88682\u6240\u793a\uff0c\u4e3b\u8981\u4ee5C3<\/sub>-P=O\u4e3a\u4e3b\u4f53\uff0cC-P-O\u6b21\u4e4b\uff1b\u800c\u5728\u949d\u5316\u5904\u7406\u8fc7\u7a0b\u4e2d\uff0c\u901a\u8fc7\u5206\u6790\u4e0d\u540c\u6784\u578b\u7684\u542b\u91cf\u53d8\u5316\u60c5\u51b5\u53ef\u5f97\u51fa\u4e00\u4e2a\u91cd\u8981\u7684\u6784\u578b\u6f14\u53d8<\/b><\/strong>\u2014\u2014\u4eceC<\/b><\/strong>3<\/b><\/sub><\/strong>-P\u548cC-O-P<\/b><\/strong>\u5411C<\/b><\/strong>3<\/b><\/sub><\/strong>-P=O\u548cC-P-O<\/b><\/strong>\u7684\u6f14\u53d8\u3002<\/p>\n

\u88681\u00a0G800\uff0cPG800\uff0cPG800S\u7684XPS\u534a\u5b9a\u91cf\u5143\u7d20\u5206\u6790<\/strong><\/p>\n\n\n\n\n\n\n\n
\n

\u00a0<\/b><\/strong><\/p>\n

Sample<\/b><\/strong><\/p>\n<\/td>\n

\n

Elemental Content (at. %)<\/b><\/strong><\/p>\n<\/td>\n<\/tr>\n

\n

C 1s<\/b><\/strong><\/p>\n<\/td>\n

\n

O 1s<\/b><\/strong><\/p>\n<\/td>\n

\n

P 2p<\/b><\/strong><\/p>\n<\/td>\n<\/tr>\n

\n

G800<\/b><\/strong><\/p>\n<\/td>\n

\n

95.69<\/b><\/strong><\/p>\n<\/td>\n

\n

4.31<\/b><\/strong><\/p>\n<\/td>\n

\n

0.00<\/b><\/strong><\/p>\n<\/td>\n<\/tr>\n

\n

PG800<\/b><\/strong><\/p>\n<\/td>\n

\n

93.16<\/b><\/strong><\/p>\n<\/td>\n

\n

4.90<\/b><\/strong><\/p>\n<\/td>\n

\n

1.93<\/b><\/strong><\/p>\n<\/td>\n<\/tr>\n

\n

PG800S<\/b><\/strong><\/p>\n<\/td>\n

\n

90.20<\/b><\/strong><\/p>\n<\/td>\n

\n

6.95<\/b><\/strong><\/p>\n<\/td>\n

\n

2.85<\/b><\/strong><\/p>\n<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n

\u88682\u3001\u00a0PG800\uff0cPG800S\u7684\u5404\u79cd\u78f7\u6784\u578b\u542b\u91cf\u5360\u6bd4\u60c5\u51b5\u3002<\/strong><\/p>\n\n\n\n\n\n\n
\n

\u00a0<\/p>\n

Sample<\/b><\/strong><\/p>\n<\/td>\n

\n

P 2p peak (eV) <\/b><\/strong><\/p>\n

Relative content of phosphorus species (%)<\/b><\/strong><\/p>\n<\/td>\n<\/tr>\n

\n

P<\/b><\/strong>1<\/b><\/sub><\/strong>\u00a0(C<\/b><\/strong>3<\/b><\/sub><\/strong>-P)<\/b><\/strong><\/p>\n

130.2<\/b><\/strong><\/p>\n<\/td>\n

\n

P<\/b><\/strong>2<\/b><\/sub><\/strong>\u00a0(C<\/b><\/strong>3<\/b><\/sub><\/strong>-P=O)<\/b><\/strong><\/p>\n

132.3<\/b><\/strong><\/p>\n<\/td>\n

\n

P<\/b><\/strong>3<\/b><\/sub><\/strong>\u00a0(C-P-O)<\/b><\/strong><\/p>\n

133.1<\/b><\/strong><\/p>\n<\/td>\n

\n

P<\/b><\/strong>4 <\/b><\/sub><\/strong>(C-O-P)<\/b><\/strong><\/p>\n

134.0<\/b><\/strong><\/p>\n<\/td>\n<\/tr>\n

\n

PG800<\/b><\/strong><\/p>\n<\/td>\n

\n

13.6<\/b><\/strong><\/p>\n<\/td>\n

\n

46.6<\/b><\/strong><\/p>\n<\/td>\n

\n

22.5<\/b><\/strong><\/p>\n<\/td>\n

\n

17.4<\/b><\/strong><\/p>\n<\/td>\n<\/tr>\n

\n

PG800S<\/b><\/strong><\/p>\n<\/td>\n

\n

0.0<\/b><\/strong><\/p>\n<\/td>\n

\n

54.3<\/b><\/strong><\/p>\n<\/td>\n

\n

32.5<\/b><\/strong><\/p>\n<\/td>\n

\n

13.2<\/b><\/strong><\/p>\n<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n

\u56fe3\u3001\u4e0d\u540c\u78f7\u6784\u578b\u7684\u7ed3\u5408\u80fd\u53ca\u5f62\u6210\u80fd\u7406\u8bba\u8ba1\u7b97<\/strong><\/p>\n

\"\"<\/p>\n

\u4e3a\u4e86\u8fdb\u4e00\u6b65\u9a8c\u8bc1\u786e\u5b9a\u542b\u78f7\u6784\u578b\u7684\u7a33\u5b9a\u6027\uff0c\u57fa\u4e8eXPS\u7ed3\u679c\uff0c\u53ef\u4ee5\u6784\u5efa\u4e86\u5982\u56fe3 (a)\u00a0\u6240\u793a\u516b\u79cd\u4e0d\u540c\u6784\u578b\u7684\u78f7\u6784\u578b\u6a21\u578b\uff0c\u901a\u8fc7\u7ed3\u5408\u5bc6\u5ea6\u6cdb\u51fd\u7406\u8bba\u8ba1\u7b97\u7ed3\u679c\uff0c\u7531\u7ed3\u5408\u80fd\u7ed3\u679c\u53ef\u4ee5\u770b\u51faC3<\/sub>-P=O\u5177\u6709\u6700\u9ad8\u7684\u7a33\u5b9a\u6027\uff0cC-P-O\u6784\u578b\u6b21\u4e4b\uff1b\u4e14\u4ece\u5f62\u6210\u80fd\u7684\u7ed3\u679c\u5f97\u51faC3<\/sub>-P=O\u662f\u5b9e\u9a8c\u6761\u4ef6\u4e0b\u6700\u6613\u5f62\u6210\u7684\u6784\u578b\uff0c\u5176\u6b21\u4e3aC-P-O\u3002\u4e8c\u8005\u7684\u7ed3\u8bba\u8fdb\u4e00\u6b65\u9a8c\u8bc1\u4e86\u7531XPS\u5206\u6790\u6240\u5f97\u78f7\u6784\u578b\u6f14\u53d8\u89c4\u5f8b\u7684\u5408\u7406\u6027<\/p>\n

\u56fe4\u3001\u4e0d\u540c\u78f7\u6784\u578b\u7684\u90e8\u5206\u6001\u5bc6\u5ea6\u8ba1\u7b97<\/strong><\/p>\n

\"\"<\/p>\n

\uff08a\uff09\u4e0d\u540c\u78f7\u6784\u578b\u5b58\u5728\u7684\u7a33\u5b9a\u6027\u5f3a\u5f31\u5206\u6790\uff1a<\/p>\n

\uff08b\uff09\u8d39\u7c73\u80fd\u7ea7\u5904\u5171\u632f\u6001\u7684\u5f3a\u5f31\u2014\u2014\u51b3\u5b9a\u4e86\u78f7\u6784\u578b\u7684\u7a33\u5b9a\u6027\uff1b<\/p>\n

\uff08c\uff09\u78f7\u6784\u578b\u4e2dC\u3001P\u3001O\u7684\u8fde\u63a5\u987a\u5e8f\u53caP\u539f\u5b50\u4e0e\u5468\u56f4C\u539f\u5b50\u7684\u8fde\u63a5\u6570\u91cf\u76f4\u63a5\u5f71\u54cd\u5176\u7a33\u5b9a\u6027\uff0c\u5373CX<\/sub>-P-O\u4e2d,\u00a0X\u8d8a\u5927\u6784\u578b\u8d8a\u7a33\u5b9a\uff1b<\/p>\n

\uff08d\uff09C3<\/sub>-P=O\u53caC2<\/sub>-P-O\u5171\u632f\u6700\u660e\u663e\uff0c\u800cC3<\/sub>-P=O\u5171\u632f\u80fd\u91cf\u6700\u4f4e\u6700\u7a33\u5b9a\u3002<\/p>\n

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\"\"<\/p>\n

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\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n

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\u6587\u732e\u94fe\u63a5\uff1a<\/strong><\/p>\n

https:\/\/pubs.acs.org.ccindex.cn\/doi\/10.1021\/acsami.8b21903<\/u><\/a><\/p>\n

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