{"id":172070,"date":"2019-04-05T08:47:27","date_gmt":"2019-04-05T00:47:27","guid":{"rendered":"\/\/m.iemloyee.com\/?p=172070"},"modified":"2019-04-05T08:47:27","modified_gmt":"2019-04-05T00:47:27","slug":"%e6%9c%80%e6%96%b0-science-%e6%8a%a5%e9%81%93-%e5%bb%b6%e8%bf%9f%e5%82%ac%e5%8c%96%e5%89%82%e5%8a%9f%e8%83%bd%e4%bd%bf%e8%85%88%e7%b1%bb%e5%8c%96%e5%90%88%e7%89%a9%e5%8f%af%e4%bb%a5%e7%9b%b4%e6%8e%a5","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=172070","title":{"rendered":"\u6700\u65b0 Science \u62a5\u9053: \u5ef6\u8fdf\u50ac\u5316\u5242\u529f\u80fd\u4f7f\u8148\u7c7b\u5316\u5408\u7269\u53ef\u4ee5\u76f4\u63a5\u5bf9\u6620\u9009\u62e9\u6027\u7684\u8f6c\u5316\u4e3a\u80fa\u7c7b\u5316\u5408\u7269\uff08R-NH2\uff09"},"content":{"rendered":"

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\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u4eca\u65e5\uff0cScience<\/strong>\u6700\u65b0\u62a5\u9053\u4e86\u6cd5\u56fd\u65af\u7279\u62c9\u65af\u5821\u5927\u5b66\u7684Amir H. Hoveyda\u6559\u6388\uff08\u901a\u8baf\u4f5c\u8005\uff09<\/strong>\u7b49\u4eba\u62a5\u9053\u4e86\u901a\u8fc7\u5bf9\u6620\u9009\u62e9\u6027\u5730\u6dfb\u52a0\u78b3\u57fa\u4eb2\u6838\u8bd5\u5242\u548c\u5bf9\u6620\u5f02\u6784\u4f53\u8fd8\u539f\u5f97\u5230\u7684\u916e\u4e9a\u80fa\uff0c\u4f7f\u5f97\u5927\u90e8\u5206\u53cd\u5e94\u6d3b\u6027\u4e0d\u591f\u7684\u8148\u7c7b\u5316\u5408\u7269\u76f4\u63a5\u8f6c\u5316\u4e3a\u591a\u5b98\u80fd\u7684\u65e0\u4fdd\u62a4\u7684\u70ef\u4e19\u57fa\u80fa\u3002\u6210\u529f\u7684\u5408\u6210\u51fa\u6765\u9700\u8981\u540c\u65f6\u5b58\u5728\u4e0e\u4e4b\u7ade\u4e89\u7684\u94dc\u57fa\u50ac\u5316\u5242\uff0c\u800c\u8f83\u6162\u7684\u5f62\u6210\u548c\u53cd\u5e94\u6027\u8f83\u5dee\u7684\u50ac\u5316\u5242\u9996\u5148\u53c2\u4e0e\u3002\u901a\u8fc7\u52a0\u5165\u975e\u751f\u4ea7\u6027\u7684\u4fa7\u5faa\u73af\u6765\u89e3\u51b3\u8be5\u6311\u6218\uff0c\u5176\u4e2d\uff0c\u8fd9\u79cd\u4fa7\u5faa\u73af\u7531\u5ec9\u4ef7\u7684\u6dfb\u52a0\u5242\u9009\u62e9\u6027\u5730\u63d0\u4f9b\u539f\u6599\uff0c\u4ee5\u5ef6\u8fdf\u6d3b\u6027\u66f4\u9ad8\u7684\u50ac\u5316\u5242\u7684\u529f\u80fd\u3002\u901a\u8fc7\u5229\u7528\u8be5\u65b9\u6cd5\u9ad8\u6548\u7684\u5236\u5907\u51fa\u6297\u764c\u836f\u7269(+)-\u767d\u523a\u65b0\u78b1\u7a81\u51fa\u4e86\u8be5\u65b9\u6cd5\u7684\u5b9e\u7528\u6027\u3002\u6587\u7ae0\u9898\u76ee\u4e3a\u201cDelayed catalyst function enables direct enantioselective conversion of nitriles to NH2<\/sub>-amines\u201d<\/strong>\u3002<\/p>\n

\u3010\u56fe\u6587\u89e3\u8bfb\u3011<\/strong><\/p>\n

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\"\"<\/p>\n

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\n \"\"
\n \u56fe\u4e09\u3001\u53cc\u50ac\u5316\u5242\u50ac\u5316\u975e\u5bf9\u6620\u5f02\u6784\u4f53\u7684\u56db\u7ec4\u5206\u548c\u5bf9\u6620\u9009\u62e9\u6027\u8fc7\u7a0b<\/strong><\/p>\n

\"\"<\/p>\n

\u56fe\u56db\u3001\u5e94\u7528\u8303\u56f4<\/strong>
\n \"\"
\n \u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n

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\u6587\u732e\u94fe\u63a5\uff1aDelayed catalyst function enables direct enantioselective conversion of nitriles to NH2-amines<\/a><\/strong>\u00a0(Science, 2019, DOI:10.1126\/science.aaw4029)<\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4ebaCQR\u7f16\u8bd1\uff0c\u6750\u6599\u4eba\u6574\u7406\u3002<\/p>\n

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