{"id":172051,"date":"2019-04-10T11:54:42","date_gmt":"2019-04-10T03:54:42","guid":{"rendered":"\/\/m.iemloyee.com\/?p=172051"},"modified":"2019-04-10T20:08:51","modified_gmt":"2019-04-10T12:08:51","slug":"%e5%8d%97%e6%b4%8b%e7%90%86%e5%b7%a5%e7%8e%8b%e6%98%95%e3%80%81%e5%be%90%e6%a2%bd%e5%b7%9dnature-energy%ef%bc%9aco-zn%e7%be%9f%e5%9f%ba%e6%b0%a7%e5%8c%96%e7%89%a9%e4%bd%9c%e4%b8%baoer%e5%82%ac","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=172051","title":{"rendered":"\u5357\u6d0b\u7406\u5de5\u738b\u6615\u3001\u5f90\u68bd\u5dddNature Energy\uff1aCo-Zn\u7f9f\u57fa\u6c27\u5316\u7269\u4f5c\u4e3aOER\u50ac\u5316\u5242\u53d1\u751f\u6676\u683c\u6c27\u6c27\u5316\u673a\u7406\u7684\u5316\u5b66\u548c\u7ed3\u6784\u8d77\u6e90"},"content":{"rendered":"
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\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n \u8fd1\u65e5\uff0c\u65b0\u52a0\u5761\u5357\u6d0b\u7406\u5de5\u5927\u5b66<\/strong>\u7684\u738b\u6615\u6559\u6388<\/strong>\u548c\u5f90\u68bd\u5ddd\uff08\u5171\u540c\u901a\u8baf\uff09<\/strong>\u6559\u6388<\/strong>\u7b49\u4eba\uff0c\u5c06\u50ac\u5316\u60f0\u6027\u7684Zn2+<\/sup>\u63ba\u5165CoOOH\u4f5c\u4e3a\u6a21\u578b\uff0c\u7814\u7a76\u8868\u660eOER\u673a\u7406\u53d6\u51b3\u4e8e\u50ac\u5316\u5242\u4e2dZn2+<\/sup>\u7684\u91cf\u3002Zn2+<\/sup>\u63ba\u6742\u5728CoOOH\u4e2d\u5f15\u5165\u6c27\u7684\u975e\u952e\u6001\uff1bZn2+<\/sup>\u7684\u63ba\u6742\u91cf\u51b3\u5b9a\u4e86\u6c27hole\u7684\u4e0d\u540c\u5c40\u90e8\u6784\u578b\u3002\u7814\u7a76\u8005\u63d0\u51fa\u4e86\u91d1\u5c5e\u7f9f\u57fa\u6c27\u5316\u7269\u4e0a\u53d1\u751f\u6676\u683c\u6c27\u6c27\u5316\u673a\u7406\u7684\u6761\u4ef6\uff1a\u53ea\u6709\u5f53\u4e24\u4e2a\u76f8\u90bb\u7684\u6c27\u5316\u7684\u6c27\u53ef\u4ee5\u6742\u5316\u5b83\u4eec\u7684\u6c27hole\u800c\u4e0d\u663e\u8457\u727a\u7272\u91d1\u5c5e-\u6c27\u6742\u5316\uff08\u5373\u5b58\u5728Zn-O2-Co-O2-Zn\u7684\u5c40\u90e8\u6784\u578b\uff09\u3002\u76f8\u5173\u6210\u679c\u4ee5\u201c<\/strong>Chemical and structural origin of lattice oxygen oxidation in Co\u2013Zn oxyhydroxide oxygen evolution electrocatalysts<\/strong>\u201d\u4e3a\u9898\u53d1\u8868\u5728Nature Energy<\/strong>\u4e0a\u3002<\/p>\n \u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n \u56fe<\/strong> 1 <\/strong>\u6c27\u7684\u975e\u952e\u6001\u4e2d\u6c27<\/strong>hole<\/strong>\u7684\u5f62\u6210<\/strong><\/p>\n \uff08a\uff09\u950c\u53d6\u4ee3\u7684MO2<\/sub>\u6a21\u578b\uff1b<\/p>\n \uff08b\uff09\u516b\u9762\u4f53MO6<\/sub>\u7684\u5206\u5b50\u8f68\u9053\u80fd\u7ea7\u56fe\u5305\u62ecONB<\/sub>\u7684\u5f62\u6210\uff1b<\/p>\n \uff08c\uff0cd\uff09CoO2<\/sub>\u548c\u950c\u53d6\u4ee3\u7684CoO2<\/sub>\u6a21\u578b\u7684\u7535\u8377\u5bc6\u5ea6\u5dee\u5206\u56fe\uff08c\uff09\u548cPDOS\uff08d\uff09\uff1b<\/p>\n \uff08e\uff09\u8003\u8651Mott-Hubbard\u5206\u88c2\u540e\u7684CoO2<\/sub>\u548c\u950c\u53d6\u4ee3\u7684CoO2<\/sub>\u6a21\u578b\u7684\u80fd\u5e26\u3002<\/p>\n \u56fe<\/strong> 2 OER<\/strong>\u673a\u7406\u548c\u5c40\u90e8\u6784\u578b\u7684\u5173\u8054<\/strong><\/p>\n \uff08a\uff09\u4e24\u79cdOER\u673a\u7406\uff0cAEM\uff08\u5de6\uff09\u548cLOM\uff08\u53f3\uff09\uff1b<\/p>\n \uff08b\uff09CoO2<\/sub>\u548c\u950c\u53d6\u4ee3\u7684CoO2<\/sub>\u4e24\u79cd\u673a\u7406\u7684\u5404\u4e2aOER\u6b65\u9aa4\u7684\u81ea\u7531\u80fd\u53d8\u5316\uff1b<\/p>\n \uff08c\uff09\u5728Zn0.2<\/sub>Co0.8<\/sub>O2<\/sub>\u4e0a\u7684\u53d1\u751fLOM\u548cAEM\u7684\u5404\u4e2a\u5438\u9644\u4e2d\u95f4\u4f53\u7684\u5438\u9644\u6784\u578b\uff1b<\/p>\n \uff08d\uff09Zn0.2<\/sub>Co0.8<\/sub>O2<\/sub>\u4e0a\u7684L2\u4e2d\u95f4\u4f53\u4e2d\u7684O\uff082p\uff09\u548cCo\uff083d\uff09\u8f68\u9053\u7684pDOS\uff1b<\/p>\n \uff08e\uff09\u5728Zn0.2<\/sub>Co0.8<\/sub>O2<\/sub>\u4e0aOER\u53d1\u751fLOM\u65f6\u6d88\u9664\u672a\u5360\u636e\u7684\u6c27\u7684\u975e\u952e\u6001\u7684\u793a\u610f\u56fe\u3002<\/p>\n \u56fe<\/strong> 3 <\/strong>\u950c\u53d6\u4ee3<\/strong>CoOOH<\/strong>\u7684\u8bbe\u8ba1\u548c\u7ed3\u6784\u8868\u5f81<\/strong><\/p>\n \uff08a\uff09\u950c\u53d6\u4ee3\u7684CoOOH\u7684\u5236\u5907\u65b9\u6cd5\u7684\u793a\u610f\u56fe\uff1b<\/p>\n \uff08b\uff0cc\uff09SEM\u56fe\uff08b\uff09\u548cTEM\u56fe\u4ee5\u53caZn0.2<\/sub>Co0.8<\/sub>OOH\u7684STEM-EELS\u5143\u7d20\u5206\u5e03\u56fe\uff08c\uff09\uff1b<\/p>\n \uff08d\uff0ce\uff09Znx<\/sub><\/em>Co1-x<\/em><\/sub>OOH\u7684EXAFS k2<\/sup>\u03c7\uff08k\uff09\u5085\u91cc\u53f6\u53d8\u6362\uff08FT\uff09\u8c31\uff08d\uff09\u548c\u5f52\u4e00\u5316\u94b4K-\u8fb9XANES\u8c31\uff08e\uff09\uff1b<\/p>\n \uff08f\uff0cg\uff09Zn0.2<\/sub>Co0.8<\/sub>OOH\u548cCoOOH\u7684Co\uff082p\uff09XPS\u8c31\u56fe\uff08f\uff09\u548cO\uff081s\uff09XPS\u8c31\u56fe\uff08g\uff09\u3002<\/p>\n \u56fe<\/strong> 4<\/strong>\u7535\u50ac\u5316<\/strong>OER<\/strong>\u5206\u6790<\/strong><\/p>\n \uff08a\uff09Znx<\/sub><\/em>Co1-<\/sub>x<\/sub><\/em>OOH\u7684\u6781\u5316\u66f2\u7ebf\uff1b<\/p>\n \uff08b\uff091.5 V vs. RHE\u7535\u4f4d\u65f6\u5404\u50ac\u5316\u5242\u57fa\u4e8eBET\u8868\u9762\u79ef\u548c\u8d28\u91cf\u5f52\u4e00\u5316\u7684\u7535\u6d41\u5bc6\u5ea6\uff1b<\/p>\n \uff08c\uff09Zn0.2<\/sub>Co0.8<\/sub>OOH\u7684\u7a33\u5b9a\u6027\u6d4b\u8bd5\uff1b<\/p>\n \uff08d\uff09\u662f\uff08a\uff09\u5bf9\u5e94\u7684\u5854\u83f2\u5c14\u56fe\uff1b<\/p>\n \uff08e\uff09\u4e0d\u540cpH\u4e0bZn0.2<\/sub>Co0.8<\/sub>OOH\u7684OER\u6d3b\u6027\uff1b<\/p>\n \uff08f\uff091.5 V vs. RHE\u7535\u4f4d\u4e0b\u7684Zn0.1<\/sub>Co0.9<\/sub>OOH\uff0cZn0.2<\/sub>Co0.8<\/sub>OOH\u548cCoOOH\u7684\u7535\u6d41\u5bc6\u5ea6\u4e0epH\u7684\u5173\u7cfb\u3002<\/p>\n \u56fe<\/strong> 5 LOM<\/strong>\u4e2d\u7684\u8fc7\u6c27\u7269\u79cd\u7684\u5316\u5b66\u8bc6\u522b<\/strong><\/p>\n \uff08a\uff09O2<\/sub>2-<\/sup>\u548cO2<\/sub>–<\/sup>\u7269\u79cd\u4e4b\u95f4\u7684\u70ed\u529b\u5b66\u7a33\u5b9a\u6027\u6bd4\u8f83\uff1b<\/p>\n \uff08b\uff09TMA+<\/sup>\u63a2\u9488\u5bf9O2<\/sub>2-<\/sup>\u7269\u8d28\u5316\u5b66\u8bc6\u522b\u7684\u793a\u610f\u56fe\uff1b<\/p>\n \uff08c\uff09CoOOH\uff081\u548c2\uff09\u548cZn0.2<\/sub>Co0.8<\/sub>OOH\uff083\u548c4\uff09\u7684\u62c9\u66fc\u5149\u8c31\u56fe\uff1b<\/p>\n \uff08d\uff09\u57281 M KOH\u548cTMAOH\uff08\u5206\u522b\u6eb6\u89e3\u5728\u6c34\u548c\u91cd\u6c34\uff09\u4e2d\uff0cZn0.2<\/sub>Co0.8<\/sub>OOH\u7684\u6781\u5316\u66f2\u7ebf\u53ca\u5176Tafel\u659c\u7387\u56fe\u3002<\/p>\n \u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n \u672c\u6587\u91c7\u7528\u4e0d\u540c\u6d53\u5ea6Zn2+<\/sup>\u63ba\u6742\u7684CoOOH\u4f5c\u4e3aOER\u7684\u6a21\u578b\u50ac\u5316\uff0c\u7814\u7a76\u8868\u660e\u5f53\u4e24\u4e2a\u76f8\u90bb\u7684\u6c27\u5316\u6c27\u539f\u5b50\u5728\u4e0d\u727a\u7272\u91d1\u5c5e-\u6c27\u6742\u5316\u7684\u60c5\u51b5\u4e0b\u7ed3\u5408\u65f6\uff0cOER\u673a\u5236\u624d\u80fd\u4eceAEM\u8f6c\u53d8\u4e3aLOM\u3002\u7279\u522b\u662f\uff0c\u7cbe\u51c6\u8bbe\u8ba1\u7684\u5177\u6709Zn-O2-Co-O2-Zn\u6784\u578b\u7684\u50ac\u5316\u5242Zn0.2<\/sub>Co0.8<\/sub>OOH\u5177\u6709\u6700\u4f73\u7684\u6d3b\u6027\u3002\u5316\u5b66\u63a2\u9488\u6280\u672f\u8026\u5408\u62c9\u66fc\u5149\u8c31\u9274\u5b9a\u4e86LOM\u4e2d\u7684\u8fc7\u6c27\u5173\u952e\u7269\u79cd\u3002\u6b64\u5916\uff0cZn-O2-Co-O2-Zn\u6784\u578b\u80fd\u591f\u5728\u70ed\u529b\u5b66\u548c\u52a8\u529b\u5b66\u4e0a\u5e73\u8861O-O\u7ed3\u5408\u548c\u6c27\u7a7a\u4f4d\u7684\u586b\u8865\u8fc7\u7a0b\uff0c\u786e\u4fdd\u50ac\u5316\u5242\u7684\u7a33\u5b9a\u6027\u3002\u8fd9\u9879\u5de5\u4f5c\u4e3a\u5f00\u53d1\u6709\u6548\u548c\u7a33\u5b9a\u7684\u6c34\u6c27\u5316\u50ac\u5316\u5242\u548c\u5176\u4ed6\u6d89\u53ca\u6676\u683c\u6c27\u7684\u591a\u76f8\u50ac\u5316\u63d0\u4f9b\u4e86\u6307\u5bfc\u3002<\/p>\n<\/p>\n
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