{"id":171941,"date":"2019-04-08T06:30:21","date_gmt":"2019-04-07T22:30:21","guid":{"rendered":"\/\/m.iemloyee.com\/?p=171941"},"modified":"2019-04-07T22:22:21","modified_gmt":"2019-04-07T14:22:21","slug":"%e3%80%90%e6%9c%aa%e5%9b%9e%e5%a4%8d%e3%80%91%e4%b8%ad%e7%a7%91%e9%99%a2%e5%94%90%e6%b0%b8%e7%82%b3%e3%80%81%e6%b8%85%e5%8d%8e-%e4%bc%af%e5%85%8b%e5%88%a9%e6%b7%b1%e5%9c%b3%e5%ad%a6%e9%99%a2%e6%88%90","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=171941","title":{"rendered":"\u4e2d\u79d1\u9662\u5510\u6c38\u70b3\u3001\u6e05\u534e-\u4f2f\u514b\u5229\u6df1\u5733\u5b66\u9662\u6210\u4f1a\u660e\u548c\u4fc4\u52d2\u5188\u5dde\u7acb\u5927\u5b66\u7eaa\u79c0\u78caAngew\uff1a\u9ad8\u6027\u80fd\u4f4e\u6210\u672c\u53cc\u79bb\u5b50\u7535\u6c60\u7684\u6700\u65b0\u8fdb\u5c55\u548c\u53d1\u5c55\u7b56\u7565"},"content":{"rendered":"

\u3010\u6210\u679c\u7b80\u4ecb<\/strong>\u3011<\/p>\n

\u8fd1\u65e5\uff0c\u4e2d\u56fd\u79d1\u5b66\u9662\u6df1\u5733\u5148\u8fdb\u6280\u672f\u7814\u7a76\u9662<\/strong>\u7684\u5510\u6c38\u70b3<\/strong>\uff0c\u6e05\u534e<\/strong>–<\/strong>\u4f2f\u514b\u5229\u6df1\u5733\u5b66\u9662<\/strong>\u7684\u6210\u4f1a\u660e<\/strong>\u548c\u7f8e\u56fd\u4fc4\u52d2\u5188\u5dde\u7acb\u5927\u5b66<\/strong>\u7684\u7eaa\u79c0\u78ca\uff08\u5171\u540c\u901a\u8baf\uff09<\/strong>\u4f5c\u8005\u7b49\u4eba\uff0c\u56de\u987e\u4e86\u53cc\u79bb\u5b50\u7535\u6c60\uff08DIB\uff09\u7684\u53d1\u5c55\u5386\u53f2\u548c\u73b0\u72b6\uff0c\u5206\u6790DIB\u4e2d\u6b63\u6781\u4e2d\u9634\u79bb\u5b50\u63d2\u5c42\u673a\u7406\uff1b\u8d1f\u6781\u7684\u63d2\u5c42\u3001\u5408\u91d1\u5316\u548c\u52a8\u529b\u5b66\u53cd\u5e94\u673a\u5236\uff1b\u5206\u6790\u4e86\u4f4e\u6210\u672c\u3001\u9ad8\u6027\u80fdDIB\u7684\u53d1\u5c55\u524d\u666f\u548c\u7814\u7a76\u7b56\u7565\u3002\u76f8\u5173\u6210\u679c\u4ee5\u201cBeyond Conventional Batteries: Strategies towards Low-Cost Dual-Ion Batteries with High Performances<\/strong>\u201d\u4e3a\u9898\u53d1\u8868\u5728Angewandte Chemie-International Edition<\/strong>\u4e0a\u3002<\/p>\n

1\u3001\u524d\u8a00<\/h1>\n

\u76ee\u524d\u5168\u7403\u5316\u77f3\u71c3\u6599\u8017\u5c3d\u548c\u73af\u5883\u6c61\u67d3\u95ee\u9898\uff0c\u4fc3\u8fdb\u4e86\u9502\u79bb\u5b50\u7535\u6c60\uff08LIB\uff09\u5728\u7535\u5b50\u548c\u7535\u52a8\u8f66\u8f86\uff08EV\uff09\u4e2d\u7684\u5e94\u7528\u3002\u7535\u52a8\u6c7d\u8f66\u548c\u7535\u7f51\u89c4\u6a21\u50a8\u80fd\u7ad9\u7684\u9700\u6c42\u65e5\u76ca\u589e\u957f\uff0c\u9502\u548c\u94b4\u7684\u8d44\u6e90\u8f83\u5c11\u548c\u6210\u672c\u589e\u52a0\uff0c\u63a8\u52a8\u4e86\u4f4e\u6210\u672c\u7535\u7535\u6c60\u7cfb\u7edf\u7684\u7814\u7a76\u3002\u53cc\u79bb\u5b50\u7535\u6c60\uff08DIB\uff09\u7684\u9633\u79bb\u5b50\u548c\u9634\u79bb\u5b50\u90fd\u53c2\u4e0e\u7535\u5316\u5b66\u6c27\u5316\u8fd8\u539f\u53cd\u5e94\uff0c\u5177\u6709\u9ad8\u5de5\u4f5c\u7535\u538b\uff0c\u9ad8\u7684\u5b89\u5168\u6027\uff0c\u5bf9\u73af\u5883\u66f4\u53cb\u597d\uff0c\u80fd\u591f\u6ee1\u8db3\u5546\u4e1a\u7684\u4f4e\u6210\u672c\u8981\u6c42\u3002\u7136\u800c\uff0cDIB\u6280\u672f\u4ecd\u7136\u5904\u4e8e\u57fa\u7840\u7814\u7a76\u7684\u9636\u6bb5\uff0c\u4ecd\u9700\u8981\u8fdb\u4e00\u6b65\u63d0\u9ad8\u80fd\u91cf\u5bc6\u5ea6\u548c\u5faa\u73af\u5bff\u547d\u3002<\/p>\n

2\u3001DIB\u7535\u6c60\u7684\u53d1\u5c55\u73b0\u72b6<\/h1>\n

2.1 DIB\u7535\u6c60\u7684\u4e3b\u8981\u74f6\u9888<\/h2>\n

\u8bb8\u591a\u56fd\u5bb6\u90fd\u5c06\u653f\u7b56\u5f15\u5165\u5f00\u53d1\u7535\u52a8\u6c7d\u8f66\uff0c\u5bfc\u81f4\u9502\u8d44\u6e90\u9700\u6c42\u6025\u5267\u589e\u52a0\u3002\u5982\u56fe1a\u6240\u793a\uff0c\u52302050\u5e74\uff0c\u9502\u7684\u603b\u6d88\u8017\u91cf\u5c06\u8fbe\u5230\u9646\u5730\u4e0a\u9502\u50a8\u91cf\u603b\u91cf\u76841\/3\u4ee5\u4e0a\u3002\u76ee\u524d\u9502\u79bb\u5b50\u7535\u6c60\u7684\u7535\u6781\u6750\u6599\u51e0\u4e4e\u8fbe\u5230\u4e86\u7406\u8bba\u80fd\u529b\u6781\u9650\uff0c\u7535\u6c60\u6c34\u5e73\u7684\u6bd4\u5bb9\u91cf\u5f88\u96be\u8d85\u8fc7350 Wh kg-1<\/sup>\u3002\u9884\u60f3\u52302030\u5e74\uff0c\u7535\u6c60\u7684\u6210\u672c\u5c06\u5c11\u4e8e\u7535\u52a8\u6c7d\u8f66\u603b\u6210\u672c20\uff05\uff0c\u5982\u56fe1b\u6240\u793a\u3002\u7136\u800c\uff0c\u6b63\u6781\u6750\u6599\u4e2d\u94b4\u7684\u4ef7\u683c\u57282017\u5e74\u5c31\u4e0a\u6da8\u4e86145\uff05\u3002\u56e0\u6b64\uff0c\u9ad8\u6027\u80fd\u4f4e\u6210\u672c\u53ef\u5145\u7535\u7535\u6c60\u6210\u4e3a\u4e86\u4e0b\u4e00\u4ee3\u7535\u6c60\u7684\u53d1\u5c55\u4e3b\u9898\u3002\u975e\u94b4\u548c\u954d\u7684\u6b63\u6781\u6750\u6599\u6210\u4e3a\u7814\u7a76\u7684\u70ed\u70b9\uff0c\u94a0\u79bb\u5b50\u548c\u94be\u79bb\u5b50\u7535\u6c60\u5f97\u5230\u4e86\u5feb\u901f\u53d1\u5c55\u3002\u6b64\u5916\uff0c\u65b0\u578b\u7535\u7684\u9502-\u786b\uff08Li-S\uff09\u3001\u78b1\u91d1\u5c5e-\u7a7a\u6c14\uff08Li-O2<\/sub>\uff09\u3001\u950c-\u7a7a\u6c14\uff08ZnO2<\/sub>\uff09\u548c\u53cc\u79bb\u5b50\u7535\u6c60\uff08DIB\uff09\u5f97\u5230\u4e86\u5feb\u901f\u53d1\u5c55\u3002DIB\u5177\u6709\u6210\u672c\u4f4e\u3001\u73af\u4fdd\u3001\u5de5\u4f5c\u7535\u538b\u9ad8\u7b49\u7279\u70b9\uff0c\u5f15\u8d77\u4e86\u76f8\u5f53\u5927\u7684\u5173\u6ce8\u3002\u5e38\u89c4\u7684LiFePO4<\/sub>\/\u77f3\u58a8\uff08LFP\/Gr\uff09LIB\uff0c\u6b63\u6781\u6750\u6599\u7684\u6210\u672c\u5360\u603b\u6210\u672c\u76841\/3\u3002\u5728DIB\u4e2d\u7528\u77f3\u58a8\u6750\u6599\u4ee3\u66ffLiFePO4<\/sub>\u5c06\u964d\u4f4e\u6b63\u6781\u6750\u6599\u6210\u672c\u768470\uff05\u3002\u975e\u9502DIB\uff08\u4f8b\u5982Na\u548cK\uff09\u7684\u6210\u672c\u660e\u663e\u4f4e\u4e8eLIB\u3002\u8fc4\u4eca\u4e3a\u6b62\uff0cDIB\u7814\u7a76\u53d6\u5f97\u4e86\u4e00\u7cfb\u5217\u4ee4\u4eba\u5174\u594b\u7684\u8fdb\u5c55\uff0c\u7136\u800c\uff0c\u73b0\u6709\u7684\u7efc\u8ff0\u5f88\u5c11\u6d89\u53ca\u5b83\u4eec\u7684\u7535\u5316\u5b66\u673a\u7406\uff0c\u53cd\u5e94\u52a8\u529b\u5b66\u548c\u9ad8\u6027\u80fd\u7684\u4f4e\u6210\u672c\u7684\u8bbe\u8ba1\u7b56\u7565\u3002\u56e0\u6b64\uff0c\u672c\u6587\u603b\u7ed3DIB\u7684\u4e3b\u8981\u6311\u6218\uff0c\u5206\u6790\u4e86DIB\u548cLIB\u53cd\u5e94\u673a\u5236\u7684\u533a\u522b\uff0c\u63d0\u4f9bDIB\u7684\u7535\u5316\u5b66\u8fc7\u7a0b\u7684\u65b0\u7406\u89e3\uff1b\u63d0\u51fa\u4e86\u589e\u5f3a\u7535\u6781\u79bb\u5b50\u4f20\u8f93\uff0c\u6539\u5584\u4f4e\u6210\u672cDIB\u7684\u7535\u5316\u5b66\u6027\u8d28\u7684\u7b56\u7565\u3002<\/p>\n

\"\"<\/p>\n

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2.2 DIB\u7535\u6c60\u548cLIB\u7684\u533a\u522b<\/h2>\n

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\u56fe 2\uff08a\uff09LIB\u548c\uff08b\uff09\u53cc\u79bb\u5b50\u7535\u6c60\u7684\u5145\u7535\/\u653e\u7535\u8fc7\u7a0b\u793a\u610f\u56fe\u3002<\/strong><\/p>\n

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\u56fe 3 DIB\u53d1\u5c55\u7684\u7b80\u8981\u5386\u53f2\uff1a\uff08a\uff09Schafh\u00e4utl\u9996\u5148\u53d1\u73b0\u7684\u9634\u79bb\u5b50\u63d2\u5c42\uff1b\uff08b\uff09R\u00fcdorff\u7b49\u4eba\u5f00\u53d1\u7b2c\u4e00\u4e2a\u53cc\u77f3\u58a8\u7535\u6c60\uff1b\uff08c\uff09McCullough\u7b49\u4eba\u64b0\u5199\u4e86\u7b2c\u4e00\u4e2aDGB\u4e13\u5229\uff1b\uff08d\uff09Seel\u62a5\u544a\u7684\u7b2c\u4e00\u4e2a\u5b9e\u7528DCB\uff1b\uff08e\uff09Placke\u7b49\u4eba\u62a5\u9053\u7684\u7b2c\u4e00\u79cd\u91d1\u5c5e-\u77f3\u58a8\u9502-\u91d1\u5c5e-DIB\uff1b\uff08f\uff09Read\u7b49\u4eba\u9996\u6b21\u5bf9DGBs\u9ad8\u538b\u7535\u89e3\u8d28\u7684\u7814\u7a76\uff1b\uff08g\uff09Rothermel\u7b49\u4eba\u62a5\u9053\u7684\u7b2c\u4e00\u6279\u57fa\u4e8eLi+<\/sup>\/TFSI\u7684DGB\uff1b\uff08h\uff09Lin\u7b49\u4eba\u53d1\u73b0\u7684\u7b2c\u4e00\u4e2aAl\uff08AlCl4<\/sub>-\uff09-DIB\uff1b\uff08i\uff09\u57fa\u4e8eAlgraphite Li\u79bb\u5b50\u7684DIB\uff0c\u5f00\u53d1\u7684\u91d1\u5c5e-\u77f3\u58a8DIB\uff1b\uff08j\uff09\u53cc\u77f3\u58a8\u7cfb\u7edf\u7684\u7b2c\u4e00\u79cdNa\u79bb\u5b50\u7684DIB\uff1b\uff08k\uff09Sn-\u77f3\u58a8\u7cfb\u7edf\u7684Na\u79bb\u5b50\u7684DIB\uff1b\uff08l\uff09Sn-\u77f3\u58a8\u7cfb\u7edf\u7684\u7b2c\u4e00\u79cd\u57fa\u4e8eK\u79bb\u5b50\u7684DIB\uff1b\uff08m\uff09\u7b2c\u4e00\u79cdCa\u79bb\u5b50\u7684DIB\uff1b\uff08n\uff09Chen\u7b49\u4eba\u5bf9\u56fa\u6001DIB\u7684\u9996\u6b21\u5c1d\u8bd5\u3002<\/strong><\/p>\n

3\u3001DIB\u7535\u6c60\u7684\u53cd\u5e94\u673a\u5236<\/h1>\n

3.1 \u6b63\u6781\u6750\u6599\u7684\u53cd\u5e94\u673a\u5236\uff1a\u9634\u79bb\u5b50\u63d2\u5c42<\/h2>\n

\u5728DIB\u4e2d\uff0c\u9634\u79bb\u5b50\u7684\u63d2\u5c42\u673a\u5236\u662f\u6700\u91cd\u8981\u7684\u53cd\u5e94\u3002\u77f3\u58a8\u5177\u6709\u72ec\u7279\u7684\u5c42\u72b6\u7ed3\u6784\uff0c\u53ef\u4ee5\u5bb9\u7eb3\u9634\u79bb\u5b50\u3002\u77f3\u58a8\u7684\u63d2\u5c42\u5316\u5408\u7269\uff08GIC\uff09\u5177\u6709\u8f83\u5927\u7684\u78b3\u5e73\u9762\u9ad8\u5ea6\uff0c\u5c42\u95f4\u76f8\u4e92\u4f5c\u7528\u8f83\u5f31\u3002\u56e0\u6b64\uff0c\u9634\u79bb\u5b50\u4e4b\u95f4\u7684\u9759\u7535\u548c\u5f39\u6027\u76f8\u4e92\u4f5c\u7528\uff0c\u5f71\u54cd\u9634\u79bb\u5b50\u7684\u5d4c\u5165\u52a8\u529b\u5b66\u548c\u9634\u79bb\u5b50\u50a8\u5b58\u7684\u80fd\u529b\u3002\u5728\u5145\u7535\u8fc7\u7a0b\u4e2d\uff0c\u9634\u79bb\u5b50\u5d4c\u5165\u77f3\u58a8\u6b63\u6781\u4e2d\uff0c\u4e24\u4e2a\u76f8\u90bb\u79bb\u5b50\u5c42\u5185\u7684\u77f3\u58a8\u70ef\u5c42\u6570\u4e0e\u6bd4\u5bb9\u91cf\u6b63\u76f8\u5173\u3002\u9636\u6bb5\u7684\u5b9a\u4e49\u57fa\u4e8e\u5728\u65e0\u7f3a\u9677\u77f3\u58a8\u6676\u683c\u4e2d\u5f62\u6210\u8fde\u7eedGIC\u76f8\u7684\u5047\u8bbe\u3002\u4e0d\u540c\u9636\u6bb5\u6570\u7684\u77f3\u58a8\u6b63\u6781\uff0c\u5982\u56fe4\u6240\u793a\u3002\u5468\u671f\u6027\u91cd\u590d\u8ddd\u79bb\uff08Ic<\/sub><\/em>\uff09\uff0c\u63d2\u5c42\u9ad8\u5ea6\uff08Ic<\/sub><\/em>\uff09\u548c\u81a8\u80c0\uff08\u0394d<\/em>\uff09\u7531\u4ee5\u4e0b\u7b49\u5f0f\u786e\u5b9a\uff1a<\/p>\n

Ic<\/sub><\/em> = Ic<\/sub><\/em>+\uff08n-1\uff09\u00d73.35 \u00c5=\u0394d+ n\u00d73.35 \u00c5=I<\/em>\u00d7dobs\u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0\u00a0<\/sub>\uff081\uff09<\/p>\n

\u00a0 \u00a0 \u5176\u4e2dI<\/em>\u662f\u5728\u5806\u53e0\u65b9\u5411\u4e0a\u53d6\u5411\u7684\uff0800l\uff09\u9762\u7684\u6307\u6570\uff0cdobs<\/sub>\u662f\u4e24\u4e2a\u76f8\u90bb\u9762\u7684\u95f4\u8ddd\u3002<\/p>\n

\u6839\u636eGIC\u4e2d\uff0800n\uff09\u548c\uff0800n + x\uff09\u5cf0\u7684\u5e03\u62c9\u683c\u89d2\u4e4b\u95f4\u7684\u5173\u7cfb\uff0c\uff0800n\uff09\u9762\u7684\u95f4\u8dddd00n<\/sub>\u53ef\u7531\u4e0b\u5f0f\u7ed9\u51fa\uff1a<\/p>\n

d00n<\/sub>=Ic<\/em>\/n=\u03bb<\/em>\/\uff082sin\u03b8<\/em>00n<\/sub>\uff09\u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \uff082\uff09<\/p>\n

\u00a0 \u00a0\u03bb\u662fX\u5c04\u7ebf\u6ce2\u957f\u3002\u5bf9\u4e8e\u4e24\u4e2a\u4e0d\u540c\u7684\u5e73\u9762\uff0c\uff0800n\uff09\u548c\uff0800n+x\uff09\uff0c\u901a\u8fc7\u6c42\u89e3d00n<\/sub>\u548cd00n + x<\/sub>\uff08x\u662f\u6574\u6570\uff09\u7684\u65b9\u7a0b\u7ec4\uff0cn\u53ef\u4ee5\u8868\u793a\u5982\u4e0b\uff1a<\/p>\n

n=x\/[\uff08sin\u03b8<\/em>00n<\/sub>+x\/sin\u03b8<\/em>00n<\/sub>+x\uff09-1]\u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0\uff083\uff09<\/p>\n

\u5bf9\u4e8e\u67d0\u4e2aX\u5c04\u7ebf\u884d\u5c04\uff08XRD\uff09\u5cf0\uff0c\u76f8\u5e94\u7684n\u53ef\u4ee5\u4ece2\u03b8\u5904\u7684\u5cf0\u5bfc\u51fa\u3002\u53e6\u5916\uff0cSolin\u7b49\u4eba\u63d0\u51fa\u7684\u6700\u8fd1\u7684\u5c42\u6a21\u578b\u3002\u8fd8\u7ed9\u51fa\u4e86E2g<\/sub>\u7684\u62c9\u66fc\u53cc\u5cf0\u7684\u76f8\u5bf9\u5f3a\u5ea6\u7684\u9636\u6bb5\u4f9d\u8d56\u6027\uff0c\u5176\u4e2dGIC\u7684\u5b9a\u91cf\u9636\u6bb5\u4fe1\u606f\uff08n\u22652\uff09\u7531\u4e0b\u5f0f\u7ed9\u51fa\uff1a<\/p>\n

Ii<\/sub><\/em>\/Ib<\/sub><\/em>=\uff08\u03c3i<\/sub>\/\u03c3b<\/sub>\uff09[\uff08n-2\uff09\/2\uff09]\u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \uff084\uff09<\/p>\n

\u5728\u6b64\uff0cIi<\/sub><\/em>\u548cIb<\/sub><\/em>\u5206\u522b\u8868\u793aE2g2<\/sub>\uff08i\uff09\u548cE2g2<\/sub>\uff08b\uff09\u6a21\u5f0f\u7684\u5f3a\u5ea6\uff0c\u6bd4\u7387\u03c3i<\/sub>\/\u03c3b<\/sub>\u662f\u4e0e\u9636\u6bb5\u65e0\u5173\u7684\u503c\uff0c\u5e76\u4e14\u8868\u793a\u622a\u9762\u7684\u6bd4\u7387\u3002\u5185\u90e8\u548c\u8fb9\u754c\u78b3\u5c42\u7684\u62c9\u66fc\u6563\u5c04\u3002\u5173\u4e8e\u9634\u79bb\u5b50\u63d2\u5165\u77f3\u58a8\u9634\u6781\u7684\u5206\u671f\u673a\u5236\u5df2\u7ecf\u6709\u5f88\u591a\u7814\u7a76\u3002\u8fd9\u4e9b\u7814\u7a76\u6d89\u53ca\u4e0d\u540c\u7684\u9634\u79bb\u5b50\uff0c\u5982\uff1a\u516d\u6c1f\u78f7\u9178\u76d0\uff08PF6<\/sub>–<\/sup>\uff09\uff0c\u56db\u6c2f\u94dd\u9178\u76d0\uff08AlCl4<\/sub>–<\/sup>\uff09\uff0c\u53cc\uff08\u4e09\u6c1f\u7532\u78fa\u9170\uff09\u9170\u4e9a\u80fa\uff08TFSI–<\/sup>\uff09\uff0c\u6c1f\u78fa\u9170\u57fa-\uff08\u4e09\u6c1f\u7532\u78fa\u9170\u57fa\uff09\u9170\u4e9a\u80fa\uff08FTFSI–<\/sup>\uff09\uff0c\u9ad8\u6c2f\u9178\u76d0\uff08ClO4<\/sub>–<\/sup>\uff09\uff0c\u53cc\uff08\u6c1f\u78fa\u9170\u57fa\uff09\u9170\u4e9a\u80fa\uff08FSI–<\/sup>\uff09\uff0c\u56db\u6c1f\u787c\u9178\u76d0\uff08BF4<\/sub>–<\/sup>\uff09\u548c\u4e09\uff08\u4e94\u6c1f\u4e59\u57fa\uff09\u4e09\u6c1f\u78f7\u9178\u76d0[\uff08C2<\/sub>F5<\/sub>\uff093<\/sub>PF3<\/sub>–<\/sup>]\uff0c\u53cc\uff08\u5168\u6c1f-\u4e59\u57fa\u78fa\u9170\u57fa\uff09\u4e9a\u80fa\uff08BETI–<\/sup>\uff09\uff0c\u4e09\u6c1f\u7532\u78fa\u9178\uff08CF3<\/sub>SO3<\/sub>–<\/sup>\uff09\uff0c\u4e8c\u6c1f\uff08\u8349\u9178\uff09\u787c\u9178\u76d0\uff08DFOB–<\/sup>\uff09\uff0c\u56db\u6c1f\u94dd\u9178\u76d0\uff08AlF4<\/sub>–<\/sup>\uff09\uff0c\u5982\u56fe5\u6240\u793a\u3002<\/p>\n

\"\"<\/p>\n

\u56fe 4 R\u00fcdorff\u548cDaumas-Herold\u6a21\u578b\u7684\u79bb\u5fc3\u5206\u7ea7\u673a\u5236\uff0c\u7528\u4e8e\u6cbf\u5806\u53e0\u65b9\u5411\u79bb\u5b50\u63d2\u5165\u77f3\u58a8\u9634\u6781;\u5468\u671f\u6027\u91cd\u590d\u8ddd\u79bbIc\uff0c\u63d2\u5165\u5eca\u9053\u9ad8\u5ea6di\uff0c\u5eca\u9053\u6269\u5c55\u0394d\u3002<\/strong><\/p>\n

\"\"<\/p>\n

\u56fe 5 \u6b63\u6781\u6750\u6599\u4e2d\u4e0d\u540c\u9634\u79bb\u5b50\u7684\u63d2\u5c42\u793a\u610f\u56fe\u3002<\/strong><\/p>\n

3.1.1 PF6<\/sub>–<\/sup>\u9634\u79bb\u5b50\u7684\u63d2\u5c42\u673a\u5236<\/h3>\n

PF6<\/sub>–<\/sup>\u9634\u79bb\u5b50\u7684\u7535\u89e3\u8d28\u5e7f\u6cdb\u5e94\u7528\u4e8eDIB\u3002\u5728\u5145\u7535\/\u653e\u7535\u8fc7\u7a0b\u4e2d\uff0c\u539f\u4f4dXRD\u53d1\u73b0PF6<\/sub>–<\/sup>\u5728\u77f3\u58a8\u4e2d\u7684\u7535\u5316\u5b66\u5d4c\u5165\/\u8131\u5d4c\u8fc7\u7a0b\u4e2d\uff0c\u53d1\u751f\u4e86\u4e00\u7cfb\u5217\u53ef\u9006\u7684\u9636\u6bb5\u8f6c\u6362\u3002\u539f\u4f4dXRD\u548c\u81a8\u80c0\u6d4b\u5b9a\u6cd5\uff08\u56fe6a-b\uff09\u89c2\u5bdf\u9634\u79bb\u5b50\u63d2\u5c42\u8fc7\u7a0b\u4e2d\u7684\u5f62\u6210\u548c\u8f6c\u53d8\uff1aC24<\/sub>PF6<\/sub>\uff08\u9636\u6bb54\uff09\u2192C24<\/sub>PF6<\/sub>\uff08\u9636\u6bb53\uff09\u2192C24<\/sub>PF6<\/sub>\uff08\u9636\u6bb52\uff09\u2192C20<\/sub>PF6<\/sub>\uff08\u9636\u6bb52\uff09\u2192C24<\/sub>PF6<\/sub>\uff08\u9636\u6bb51\uff09\u2192C20<\/sub>PF6<\/sub>\uff08\u9636\u6bb51\uff09\u3002\u5149\u5b66\u5e73\u53f0\u5b9e\u65f6\u76d1\u6d4b\u77f3\u58a8\u6b63\u6781\u5728\u5145\u7535\/\u653e\u7535\u8fc7\u7a0b\u4e2d\u7684\u539a\u5ea6\u6f14\u53d8\uff0c\u53d1\u73b0\u77f3\u58a8\u6b63\u6781\u7684\u4e0d\u53ef\u9006\u7684\u539a\u5ea6\u53d8\u5316\u4e0e\u9634\u79bb\u5b50\u548c\u5316\u5b66\u7ec4\u5206\u7684\u4e0d\u53ef\u9006\u5206\u89e3\u6709\u5173\u3002\u63d2\u5c42PF6<\/sub>–<\/sup>\u9634\u79bb\u5b50\u7684\u4f18\u5316\u51e0\u4f55\u5f62\u72b6\uff0c\u5982\u56fe6\u6240\u793a\u3002PF6<\/sub>–<\/sup>\u9634\u79bb\u5b50\u6269\u6563\u7684\u7406\u8bba\u6d3b\u5316\u80fd\u4f30\u8ba1\u4e3a\u7ea60.23 eV\uff08\u56fe6d\uff09\u3002\u8003\u8651\u5230\u5927\u7684\u79bb\u5b50\u5c3a\u5bf8\uff0cPF6<\/sub>–<\/sup>\u9634\u79bb\u5b50\u4f18\u5148\u6cbf\uff08100\uff09\u65b9\u5411\u6269\u6563\u3002\u53e6\u5916\uff0c\u968f\u7740PF6<\/sub>–<\/sup>\u9634\u79bb\u5b50\u7684\u5206\u7ea7\u6c34\u5e73\u589e\u52a0\uff0c\u6269\u6563\u5e38\u6570\u964d\u4f4e\u3002PF6<\/sub>–<\/sup>\u9634\u79bb\u5b50\u5728\u8f83\u9ad8\u7535\u4f4d\u4e0b\uff0c\u5bf9\u77f3\u58a8\u78b3\u7684\u5d4c\u5165\u884c\u4e3a\u4e0d\u4ec5\u4e0e\u9634\u79bb\u5b50\u5d4c\u5165\u7684\u9636\u6bb5\u7ed3\u6784\u6709\u5173\uff0c\u800c\u4e14\u8fd8\u4e0e\u7eb3\u7c73\u6c14\u6ce1\u7ed3\u6784\u7684\u5f62\u6210\u6709\u5173\u3002<\/p>\n

\"\"<\/p>\n

\u56fe 6 \uff08a\uff09\u539f\u4f4dXRD\u5149\u8c31\u53ca\u5176\u7535\u538b-\u5bb9\u91cf\u66f2\u7ebf\uff1b\uff08b\uff09\u539f\u4f4d\u81a8\u80c0\u6d4b\u91cf\u66f2\u7ebf\uff1b\uff08c\uff09PF6-\u5d4c\u5165\u77f3\u58a8\u78b3\u7684\u7b2cI\u9636\u6bb5\u7684\u4f18\u5316\u51e0\u4f55\u5f62\u72b6\uff1b\uff08d\uff09\u6cbf<100>\u65b9\u5411\u7684\u6269\u6563\u80fd\u5792\u7684\u80fd\u91cf\u52bf\u5792\u7684CI-NEB\u8ba1\u7b97\u7ed3\u679c\u3002<\/strong><\/p>\n

3.1.2 AlCl4<\/sub>–<\/sup>\u9634\u79bb\u5b50\u7684\u63d2\u5c42\u673a\u5236<\/h3>\n

AlCl4<\/sub>–<\/sup>\u662f\u53e6\u4e00\u79cd\u6709\u6548\u7684\u63d2\u5165\u77f3\u58a8\u6b63\u6781\u7684\u9634\u79bb\u5b50\u3002\u56fe7a\u4e2d\u7684\u539f\u4f4d\u62c9\u66fc\u5149\u8c31\uff0c\u63ed\u793a\u4e86\u5145\u7535\u8fc7\u7a0b\u4e2dAlCl4<\/sub>–<\/sup>\u9634\u79bb\u5b50\u8fdb\u5165\u5929\u7136\u77f3\u58a8\u7684\u5d4c\u5165\u8fc7\u7a0b\uff0c\u5373G\u5cf0\u5206\u88c2\u548cE2g2<\/sub>\uff08i\uff09\u84dd\u79fb\u3002\u7b2c\u4e00\u4e2a\u8fc7\u7a0b\uff0c\u5448\u73b0E2g2<\/sub>\uff08i\uff09\u6a21\u5f0f\uff081586 cm-1<\/sup>\uff09\u548cE2g2<\/sub>\uff08b\uff09\u6a21\u5f0f\uff081607 cm-1<\/sup>\uff09\u7684\u53cc\u5cf0\uff0c\u5982\u56fe7a-b\u6240\u793a\u3002\u5728\u5145\u7535\u8fc7\u7a0b\u4e2d\uff0c\u56fe7c\u4e2d\uff08002\uff09\u5cf0\u5206\u88c2\u73b0\u8c61\u4e3a\u4e24\u4e2a\u65b0\u5cf0\uff0c\u610f\u5473\u7740AlCl4<\/sub>–<\/sup>\u9634\u79bb\u5b50\u5d4c\u5165\u5929\u7136\u77f3\u58a8\u4e2d\u3002\u653e\u7535\u8fd9\u4e24\u4e2aXRD\u5cf0\u9010\u6e10\u5408\u5e76\u5728~26.6\u00b0\u6062\u590d\u4e3a\u5355\u5cf0\u3002\u7b2c\u4e00\u539f\u7406DFT\u8ba1\u7b97\u8868\u660e\uff0c\u6765\u81ea\u77f3\u58a8\u5c42\u7684\u538b\u529b\uff0c\u5bfc\u81f4\u56db\u9762\u4f53AlCl4<\/sub>–<\/sup>\u9634\u79bb\u5b50\u7684\u7ed3\u6784\u53d8\u5f62\uff0c\u5176\u56db\u4e2a\u952e\u89d2\u4ece\u81ea\u7531\u6001\u7684109.5\u00b0\u53d8\u4e3a107.8\u00b0\uff0c106.8\u00b0\uff0c110.1\u00b0\u548c107.6\u00b0\u5206\u522b\u5904\u4e8e\u626d\u66f2\u72b6\u6001\u3002AlCl4<\/sub>–<\/sup>\u9634\u79bb\u5b50\u7684\u5c3a\u5bf8\u4ece4.88 \u00c5\u964d\u4f4e\u5230~4.79 \u00c5\uff08\u56fe7d\uff09\u3002\u7406\u8bba\u8ba1\u7b97\u53d1\u73b0AlCl4<\/sub>–<\/sup>\u9634\u79bb\u5b50\u5d4c\u5165\u77f3\u58a8\u540e\uff0c\u5e73\u9762\u56db\u8fb9\u5f62\u7684\u51e0\u4f55\u5f62\u72b6\u5bf9\u50a8\u80fd\u662f\u6709\u5229\u7684\u3002\u5e73\u9762\u51e0\u4f55\u5f62\u72b6\u4e0e\u5e73\u8eba\u6784\u578b\u76f8\u6bd4\u603b\u80fd\u91cf\u9ad80.69 eV\uff0c\u53cc\u5c42\u5806\u53e0\u56db\u9762\u4f53\u51e0\u4f55\u5f62\u72b6\uff0c\u5728\u6b63\u5e38\u6761\u4ef6\u4e0b\u6bd4\u5355\u5c42\u56db\u9762\u4f53\u51e0\u4f55\u5f62\u72b6\u66f4\u4e0d\u7a33\u5b9a\u3002\u6b64\u5916\uff0c\u4ece\u56db\u9762\u4f53\u51e0\u4f55\u5f62\u72b6\u5230\u5e73\u9762\u51e0\u4f55\u5f62\u72b6\u7684\u7ed3\u6784\u8f6c\u53d8\u7684\u80fd\u5792\uff08\u56fe7g\uff09\u8fdc\u8fdc\u9ad8\u4e8e\u56db\u9762\u4f53\u51e0\u4f55\u5f62\u72b6\u7684\u6269\u6563\u3002\u968f\u7740\u4e2d\u6027AlCl4<\/sub>\u5728\u77f3\u58a8\u4e2d\u6269\u6563\u7684\u4e0d\u540c\u9014\u5f84\uff0c\u80fd\u91cf\u52bf\u5792\u8ba1\u7b97\u5f97\u975e\u5e38\u5c0f\uff0c\u8303\u56f4\u4ece0.012\u52300.029eV\u3002\u7ed3\u679c\uff0cAlCl4<\/sub>\uff0cD\u7684\u6269\u6563\u5e38\u6570\u4f30\u8ba1\u572810-4<\/sup> cm2<\/sup> s-1<\/sup>\u7684\u6570\u91cf\u7ea7\uff0c\u901a\u8fc7\u4ee5\u4e0b\u7b49\u5f0f\uff1a<\/p>\n

D = 1\/6l<\/em>2<\/sup>v0<\/sub>exp[-E<\/em>d<\/sub>\/\uff08kb<\/sub>T<\/em>\uff09]\u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \uff085\uff09<\/p>\n

\u00a0 \u00a0\u8fd9\u91ccI<\/em>\u8868\u793a\u6cbf\u67d0\u4e00\u8def\u5f84\u7684\u521d\u59cb\u548c\u6700\u7ec8\u4f4d\u7f6e\u4e4b\u95f4\u7684\u6269\u6563\u8ddd\u79bb\uff0cv0<\/sub>\u8868\u793a\u65bd\u52a0\u7684\u9891\u7387\uff081013 Hz\uff09\uff1bEd<\/sub>\u662f\u9634\u79bb\u5b50\u6269\u6563\u7684\u80fd\u5792\uff1bkb<\/sub>\u8868\u793a\u73bb\u5c14\u5179\u66fc\u5e38\u6570\uff0cT\u8868\u793a\u7edd\u5bf9\u6e29\u5ea6\u3002<\/p>\n

\"\"<\/p>\n

\u56fe 7 \uff08a\uff09\u5728\u5145\u7535\u7535\u538b1.99\u30012.37\u30012.42\u548c2.45 V\u4ee5\u53ca\u653e\u7535\u7535\u538b\u4e3a2.3\u30012.24\u30011.8\u548c0.5 V\u65f6\u7684NG\u7684\u62c9\u66fc\u5149\u8c31\uff1b\uff08b\uff09\u5145\u7535-\u653e\u7535\u5faa\u73af\u8bb0\u5f55NG\u9634\u6781\u7684\u539f\u4f4d\u62c9\u66fc\u5149\u8c31\uff1b\uff08c\uff09\u7b2c\u4e8c\u4e2a\u5faa\u73af\u4e2d\u5404\u79cd\u5145\u7535\u548c\u653e\u7535\u72b6\u6001\u7684NG\u7684\u975e\u539f\u4f4dXRD\u56fe\u8c31\uff1b\uff08d\uff09\u5d4c\u5165\u77f3\u58a8\u5c42\u4e2d\u7684AlCl4-<\/sub>\u9634\u79bb\u5b50\u6a21\u578b;\uff08e\uff09\u77f3\u58a8\u4e2d\u7684\u4e2d\u6027AlCl4<\/sub>\u7684\u56db\u4e2a\u57fa\u672c\u6269\u6563\u9014\u5f84;\uff08f\uff09\u4e0d\u540c\u9636\u6bb5-4GIC\u7684\u539f\u5b50\u7ed3\u6784\u548c\u603b\u80fd\u91cf\uff0c\u5305\u62ec\u5e73\u9762\u548c\u56db\u9762\u4f53\uff08\u5e73\u8eba\u548c\u76f4\u7acb\uff09\u51e0\u4f55\u5f62\u72b6;\uff08g\uff09\u5e73\u8eba\u56db\u9762\u4f53\u51e0\u4f55\u7684\u80fd\u91cf\u53d6\u4e3a\u96f6\u3002<\/strong><\/p>\n

3.1.3 TFSI–<\/sup>\u9634\u79bb\u5b50\u7684\u63d2\u5c42\u673a\u5236<\/h3>\n

\u79bb\u5b50\u6db2\u4f53\u7535\u89e3\u8d28\u56e0\u5176\u72ec\u7279\u7684\u4f18\u70b9\u800c\u53d7\u5230\u5173\u6ce8\uff0c\u4f8b\u5982\u4f4e\u53ef\u71c3\u6027\uff0c\u5bbd\u7535\u5316\u5b66\u7a97\u53e3\uff0c\u4e0e\u6eb6\u5242\u5206\u89e3\u548c\u6eb6\u5242\u5171\u63d2\u5165\u9634\u6781\u65e0\u5173\u3002\u77f3\u58a8\u6b63\u6781\u4e2dTFSI–<\/sup>\u9634\u79bb\u5b50\u7684\u5d4c\u5165\u79bb\u5b50\u6db2\u4f53\u7535\u89e3\u8d28\u7684\u5206\u6790\u53d1\u73b0\uff0c\u9634\u79bb\u5b50\u63d2\u5c42\u7684\u5206\u7ea7\u73b0\u8c61\u4e0e\u5de5\u4f5c\u6e29\u5ea6\u548c\u622a\u6b62\u7535\u4f4d\u6709\u5173\u3002\u539f\u4f4dXRD\u7ed3\u5408\u5faa\u73af\u4f0f\u5b89\u6cd5\uff08CV\uff09\u63ed\u793a\u4e86GIC\u7684\u7279\u5b9a\u9636\u6bb5\u76f8\u8f6c\u53d8\uff08\u56fe8\uff09\u3002\u5728\u5145\u7535\/\u653e\u7535\u8fc7\u7a0b\u4e2d\uff0cXRD\u5cf0\u51fa\u73b0\u5206\u88c2\u548c\u79fb\u4f4d\u884c\u4e3a\u3002\u5e73\u5747TFSI–<\/sup>\u63d2\u5165\u7684\u5eca\u9053\u9ad8\u5ea6di<\/sub><\/em>\u548c\u76f8\u5e94\u7684\u5eca\u9053\u6269\u5c55\u0394d<\/em>\u4e3a7.96\u00b10.05\u548c4.61\u00b10.05\uff0c\u4f53\u79ef\u81a8\u80c0\u4e3a137\uff05\u3002\u572820\u2103\u4e0b\uff0cTFSI–<\/sup>\u5d4c\u5165\u77f3\u58a8\u7684\u6700\u5927\u5316\u5b66\u8ba1\u91cf\u7ea6\uff08TFSI\uff09C26\uff0c\u572860\u2103\u4e0b\uff0c\u4e3a\uff08TFSI\uff09C20\u3002<\/p>\n

\"\"<\/p>\n

\u56fe 8 \uff08a\uff09\u5faa\u73af\u4f0f\u5b89\u5b9e\u9a8c\uff08\u7b2c1\u6b21\u5faa\u73af\uff09\u7684\u7535\u6c60\u7535\u538b\u4e0e\u65f6\u95f4\u548c\u6bd4\u7535\u6d41\u4e0e\u65f6\u95f4\u7684\u5173\u7cfb\u66f2\u7ebf\uff1b\uff08b\uff09\u53cc\u79bb\u5b50\u7535\u6c60\u7684\u91d1\u5c5e\u9502\/KS6L\u7684\u539f\u4f4dX\u5c04\u7ebf\u884d\u5c04\u56fe\u8c31\u3002<\/strong><\/p>\n

3.1.4 \u4e0d\u540c\u7c7b\u578b\u9634\u79bb\u5b50\u7684\u63d2\u5c42\u673a\u5236<\/h3>\n

\u4e0d\u540c\u9634\u79bb\u5b50\u5b58\u5728\u4e0d\u540c\u7684\u63d2\u5c42\u6548\u5e94\uff0c\u5305\u62ecPF6<\/sub>–<\/sup>\uff0cBF4<\/sub>–<\/sup>\uff0cTFSI–<\/sup>\u548cFTFSI–<\/sup>\u3002\u7814\u7a76\u53d1\u73b0DIB\u4e2d\u7684\u77f3\u58a8\u6b63\u6781\u4e2d\u7684\u9634\u79bb\u5b50\u7684\u5c3a\u5bf8\u4e0e\u7535\u5316\u5b66\u6027\u80fd\u5bc6\u5207\u76f8\u5173\u3002\u9634\u79bb\u5b50\u5d4c\u5165\u77f3\u58a8\u7684\u8d77\u59cb\u7535\u4f4d\u5177\u6709\u4ee5\u4e0b\u964d\u5e8f\uff1aBETI–<\/sup>>FSI–<\/sup>>FTFSI–<\/sup>>FSI–<\/sup>\/TFSI–<\/sup>>TFSI–<\/sup>>TFSI–<\/sup>\/FSI–<\/sup>\u300220\u2103\u65f6\uff0c\u79bb\u5b50\u7535\u5bfc\u7387\uff0c\u968f\u7740\u79bb\u5b50\u5c3a\u5bf8\u7684\u51cf\u5c11\u800c\u589e\u52a0\uff1aBETI–<\/sup><TFSI–<\/sup><TFSI–<\/sup>\/FSI–<\/sup><FTFSI–<\/sup><FSI–<\/sup>\/TFSI–<\/sup><FSI–<\/sup>\uff0c\u8fd9\u610f\u5473\u7740\u79bb\u5b50\u5bf9\u5f62\u6210\u548c\u81ea\u805a\u96c6\u6548\u5e94\uff0c\u4e3b\u5bfc\u4e86\u9634\u79bb\u5b50\u7684\u7535\u5316\u5b66\u6269\u6563\u8fc7\u7a0b\u3002\u6b64\u5916\uff0c\u63d2\u5c42\u80fd\u4e0e\u77f3\u58a8\u548c\u63d2\u5c42\u5242\uff08\u5982PF6<\/sub>–<\/sup>\u548cClO4<\/sub>–<\/sup>\uff09\u4e4b\u95f4\u7684\u7535\u5b50\u8f6c\u79fb\u5bc6\u5207\u76f8\u5173\uff0c\u63d2\u5c42\u7684\u7535\u79bb\u52bf\u6216\u7535\u5b50\u4eb2\u548c\u529b\u4e0e\u63d2\u5165\u5242\u7684\u5927\u5c0f\u76f8\u5173\uff0c\u53ef\u4ee5\u7528\u6765\u6d4b\u91cfGIC\u7684\u7a33\u5b9a\u6027\u3002<\/p>\n

3.2 \u8d1f\u6781\u7684\u53cd\u5e94\u673a\u5236<\/h2>\n

\u8d1f\u6781\u7684\u53cd\u5e94\u52a8\u529b\u5b66\u5bf9DIB\u7684\u7535\u5316\u5b66\u6027\u8d28\u5177\u6709\u91cd\u8981\u610f\u4e49\u3002\u8d1f\u6781\u6750\u6599\u7684\u53cd\u5e94\u673a\u7406\u4e0eLIB\u4e2d\u7684\u76f8\u4f3c\uff0c\u5305\u62ec\u8131\u5d4c\u3001\u5408\u91d1\u5316\u3001\u8f6c\u5316\u548c\u5265\u79bb\/\u7535\u9540\u3002\u8131\u51fa\u548c\u5d4c\u5165\u4e0e\u5408\u91d1\u5316\u662f\u5927\u591a\u6570DIB\u8d1f\u6781\u6700\u4e3b\u8981\u7684\u4e24\u79cd\u53cd\u5e94\u673a\u5236\u3002<\/p>\n

3.2.1 \u63d2\u5c42\u673a\u5236<\/h3>\n

\u77f3\u58a8\u662fDIB\u8d1f\u6781\u6700\u5e38\u7528\u7684\u6750\u6599\uff0c\u63d2\u5c42\u77f3\u58a8\u4e2d\u7684\u9502\u7684\u53cd\u5e94\u5982\u4e0b\uff1a<\/p>\n

Li+<\/sup>+6C+e–<\/sup>\u2194LiC6<\/sub>\u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \uff086\uff09<\/p>\n

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\"\"<\/p>\n

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3.2.2 \u5408\u91d1\u5316\u53cd\u5e94<\/h3>\n

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\"\"<\/p>\n

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\"\"<\/p>\n

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\"\"<\/p>\n

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\"\"<\/p>\n

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4\u3001\u9634\u79bb\u5b50\u53cd\u5e94\u52a8\u529b\u5b66\u7684\u7b56\u7565<\/h1>\n

4.1 \u6b63\u6781\u7ed3\u6784\u8bbe\u8ba1\u548c\u6539\u6027<\/h2>\n

\u78b3\u8d28\u6b63\u6781\u7684\u77f3\u58a8\u5316\u7a0b\u5ea6\u548c\u7ed3\u6676\u5ea6\u5f71\u54cd\u79bb\u5b50\u6269\u6563\u7684\u7ed3\u6784\u7a33\u5b9a\u6027\uff0c\u7535\u5b50\u4f20\u5bfc\u6027\uff0c\u80fd\u5792\u548c\u7535\u6781\u4e2d\u9634\u79bb\u5b50\u7684\u5d4c\u5165\u52a8\u529b\u5b66\u3002\u9634\u79bb\u5b50\u5728\u77f3\u58a8\u6b63\u6781\u4e2d\u7684\u7535\u5316\u5b66\u5d4c\u5165\u8fc7\u7a0b\uff0c\u53d6\u51b3\u4e8e\u77f3\u58a8\u7684\u7269\u7406\u6027\u8d28\uff0c\u4f8b\u5982\u7c92\u5ea6\u548c\u8868\u9762\u5f62\u6001\u3002\u5927\u7c92\u5f84\u53ef\u4ee5\u589e\u5f3a\u77f3\u58a8\u6b63\u6781\u7684\u7ed3\u6784\u7a33\u5b9a\u6027\uff0c\u63d0\u9ad8\u5faa\u73af\u7a33\u5b9a\u6027\uff1b\u4f46\u662f\u964d\u4f4e\u6bd4\u8868\u9762\u79ef\u5e76\u5ef6\u957f\u6b63\u6781\u4e2d\u9634\u79bb\u5b50\u7684\u6269\u6563\u8def\u5f84\uff0c\u5bfc\u81f4\u500d\u7387\u80fd\u529b\u76f8\u5bf9\u8f83\u5dee\u3002\u9634\u79bb\u5b50\u5d4c\u5165\u8fc7\u7a0b\u53d7\u53cd\u5e94\u52a8\u529b\u5b66\u9650\u5236\u3002\u7247\u72b6\u7ed3\u6784\u80fd\u591f\u4fc3\u8fdbTFSI–<\/sup>\u9634\u79bb\u5b50\u7684\u5d4c\u5165\u3002\u5546\u4e1a\u77f3\u58a8\u7eb3\u7c73\u7247\uff0c\u77f3\u58a8\u7c89\u548cEGN\u77f3\u58a8\u90fd\u5177\u6709\u53ef\u9006\u7684TFSI–<\/sup>\u79bb\u5b50\u5d4c\u5165\u884c\u4e3a\u3002\u4f46EGN\u77f3\u58a8\u7684\u6bd4\u5bb9\u91cf\u548c\u500d\u7387\u80fd\u529b\u660e\u663e\u4f18\u4e8e\u5176\u4ed6\u4e24\u79cd\u77f3\u58a8\u6750\u6599\uff08\u56fe14b-c\uff09\uff0c\u56e0\u4e3a\u72ec\u7279\u7684\u7eb3\u7c73\u8584\u7247\u6784\u9020\u7684\u591a\u5b54\u7ed3\u6784\u53ef\u63d0\u4f9b\u5927\u7684\u6bd4\u8868\u9762\u79ef\uff0c\u6709\u6548\u5730\u7f13\u51b2\u7531\u9634\u79bb\u5b50\u5d4c\u5165\u5f15\u8d77\u7684\u53ef\u80fd\u7684\u4f53\u79ef\u81a8\u80c0\u3002\u4f17\u6240\u5468\u77e5\uff0c\u589e\u52a0\u7f3a\u9677\u7684\u91cf\u53ef\u4ee5\u4ea7\u751f\u66f4\u591a\u7684\u6d3b\u6027\u4f4d\u70b9\uff0c\u7136\u800c\uff0c\u8fd9\u5c06\u4e0d\u53ef\u907f\u514d\u5730\u589e\u52a0\u9634\u79bb\u5b50\u6269\u6563\u80fd\u5792\uff0c\u963b\u788d\u9634\u79bb\u5b50\u5d4c\u5165\u52a8\u529b\u5b66\u3002\u56e0\u6b64\uff0c\u8c03\u6574\u7f3a\u9677\u548c\u63ba\u6742\u662f\u589e\u5f3a\u9634\u79bb\u5b50\u63d2\u5165\u78b3\u8d28\u6b63\u6781\u7684\u52a8\u529b\u5b66\u7684\u91cd\u8981\u7b56\u7565\u3002\u4e00\u79cd3000\u2103\uff08GA-3000\uff09\u9000\u706b\u7684\u3001\u9ad8\u5ea6\u7ed3\u6676\u548c\u65e0\u7f3a\u9677\u5c11\u5c42\u77f3\u58a8\u70ef\u6c14\u51dd\u80f6\uff08GA\uff09\u6b63\u6781\uff0c\u5982\u56fe15\u6240\u793a\u3002GA-3000\u7684\u65e0\u7f3a\u9677\u591a\u5b54\u7ed3\u6784\uff0c\u5176\u63d0\u4f9b\u4f4e\u80fd\u91cf\u52bf\u5792\uff0c\u4fc3\u8fdbAlCl4<\/sub>–<\/sup>\u9634\u79bb\u5b50\u7684\u5feb\u901f\u5d4c\u5165\u52a8\u529b\u5b66\u548c\u7535\u5b50\u7684\u4f20\u8f93\u3002\u5bf9\u6bd4\u7814\u7a76\u8868\u660e\uff0c\u7f3a\u9677\u90e8\u4f4d\u4e0d\u80fd\u4f5c\u4e3a\u5bb9\u7eb3\u5d4c\u5165\u7684AlCl4<\/sub>–<\/sup>\u9634\u79bb\u5b50\u7684\u6d3b\u6027\u4f4d\u70b9\u3002\u7f3a\u9677\u7684\u5b58\u5728\u5bfc\u81f4\u7535\u5316\u5b66\u6027\u80fd\u4e0b\u964d\u3002\u56e0\u6b64\u63d0\u51fa\u4e86\u4e00\u79cd\u77f3\u58a8\u70ef\u6b63\u6781\u7684\u65e0\u7f3a\u9677\u8bbe\u8ba1\uff1a\u7f3a\u9677\u8d8a\u5c11\uff0c\u7535\u5316\u5b66\u6027\u80fd\u8d8a\u597d\u3002 \u201c\u4e09\u9ad8\u4e09\u8fde\u7eed\u201d\uff083H3C\uff1a\u9ad8\u8d28\u91cf\uff0c\u9ad8\u53d6\u5411\uff0c\u9ad8\u6c9f\u9053\uff1b\u77f3\u58a8\u70ef\u57fa\u8d28\u7684\u8fde\u7eed\u7535\u5b50\u5bfc\u4f53\uff0c\u901a\u9053\u7f51\u7edc\u7684\u8fde\u7eed\u7535\u89e3\u8d28\/\u79bb\u5b50\u6e17\u900f\u65b9\u5f0f\uff0c\u4ee5\u53ca\u5c11\u91cf\u77f3\u58a8\u70ef\u9aa8\u67b6\u7684\u8fde\u7eed\u6d3b\u6027\u6750\u6599\uff09\u77f3\u58a8\u70ef\u8584\u819c\uff08GF-HC\uff09\u6b63\u6781\uff08\u56fe15c\uff09\u30023H3C\u7ed3\u6784\u4f7f\u6b63\u6781\u5177\u6709\u589e\u5f3a\u7684\u7535\u5b50\u548c\u9634\u79bb\u5b50\u7684\u7535\u5316\u5b66\u53cd\u5e94\u52a8\u529b\u5b66\u7279\u5f81\u3002<\/p>\n

\"\"<\/p>\n

\u56fe 14 \u6b63\u6781\u6750\u6599\u7684\u7eb3\u7c73\u7ed3\u6784\u8bbe\u8ba1\u548c\u9634\u79bb\u5b50\u7684\u63d2\u5c42\u52a8\u529b\u5b66\u7814\u7a76\uff1a\uff08a\uff09\u7eb3\u7c73\u8584\u7247EGN\u77f3\u58a8\u7684SEM\u56fe\u50cf\uff1b\uff08b\uff09\u500d\u7387\u6027\u80fd\uff082.25-5.0 V\u5bf9Li\/Li+<\/sup>\uff09\uff1b\uff08c\uff09200\u6b21\u7684\u5faa\u73af\u6027\u80fd\u548c\u5e93\u4ed1\u6548\u7387\u56fe\uff081800 mAg-1<\/sup>, 2.5-5-5.0 V vs. Li\/Li+<\/sup>\uff09\uff1b\uff08d\uff09\u5f00\u653e\u6846\u67b6\u7ed3\u6784\u7684\u77f3\u58a8\u6ce1\u6cab\u7684SEM\u56fe\u50cf\uff1b\uff08e\uff09Al\/\u77f3\u58a8\u6ce1\u6cab\u888b\u7535\u6c60\u7684\u957f\u671f\u7a33\u5b9a\u6027\u8bd5\u9a8c\uff1b\uff08f\uff09\u9ad8\u5b54\u96993D\u77f3\u58a8\u70ef\u6ce1\u6cab\u4e2d\u7eb3\u7c73\u5e26\u4e2dAlCl4-<\/sub>\u9634\u79bb\u5b50\u5d4c\u5165\/\u8131\u5d4c\u7684\u793a\u610f\u56fe;\uff08g\uff092000\u30014000\u30015000\u30016000\u30017000\u548c8000 mA g-1<\/sup>\u4e0b\uff0c\u8f6f\u5305\u7535\u6c60\u5145\u7535\u548c\u653e\u7535\u7684\u901f\u7387\u6027\u80fd\uff1b\uff08h\uff09Al-\u77f3\u58a8\u70ef\u548cAl-\u77f3\u58a8\u7535\u6c60\u7684\u793a\u610f\u56fe\uff08\u5de6\uff09\uff0c\u77f3\u58a8\u70ef\u548c\u77f3\u58a8\u7535\u6781\u7684\u7167\u7247\uff08\u53f3\uff09\uff1b\uff08i\uff09\u77f3\u58a8\u70ef\u548c\u77f3\u58a8\u7535\u6781\u4e2dAlCl4<\/sub>–<\/sup>\u9634\u79bb\u5b50\u5d4c\u5165\u5316\u5b66\u7684\u793a\u610f\u56fe\u3002<\/strong><\/p>\n

\"\"<\/p>\n

\u56fe 15 \u78b3\u8d28\u6b63\u6781\u7684\u7535\u5316\u5b66\u53cd\u5e94\u7684\u65e0\u7f3a\u9677\u548c\u63ba\u6742\u4f9d\u8d56\u6027\uff1a\uff08a\uff09\u65e0\u7f3a\u9677\u8bbe\u8ba1\u7684\u793a\u610f\u56fe\uff1b\uff08b\uff09\u5145\u7535\u548c\u653e\u7535\u8fc7\u7a0b\u4e2d\uff0cGA-2000\u7684\u62c9\u66fc\u5149\u8c31\uff1b\uff08c\uff09\u77f3\u58a8\u70ef\u6b63\u6781\u76843C3H\u7684\u8bbe\u8ba1\u793a\u610f\u56fe\uff1b\uff08d\uff09NPHC\u7684PF6<\/sub>–<\/sup>\u7684\u6c2e\u63ba\u6742\u53cd\u5e94\u6a21\u62df\u56fe\u3002<\/strong><\/p>\n

4.2 \u65b0\u578b\u6b63\u6781\u6750\u6599<\/h2>\n

\u65b0\u578b\u6b63\u6781\u6750\u6599\uff08\u4f8b\u5982\uff1a\u6709\u673a\u6750\u6599\u548c\u77f3\u58a8\u70ef\u57fa\u590d\u5408\u6750\u6599\uff09\u662f\u4f4e\u6210\u672c\u3001\u50a8\u91cf\u4e30\u5bcc\u7684\u548c\u6709\u5438\u5f15\u529b\u7684\u7814\u7a76\u6750\u6599\u3002\u6709\u673a\u6750\u6599\u5177\u6709\u4e30\u5bcc\u6027\uff0c\u7075\u6d3b\u6027\uff0c\u91cd\u91cf\u8f7b\uff0c\u73af\u5883\u53cb\u597d\u6027\uff0c\u7ed3\u6784\u591a\u6837\u6027\u548c\u6613\u4e8e\u529f\u80fd\u5316\u3002\u6709\u673a\u6750\u6599\u80fd\u591f\u589e\u5f3a\u9634\u79bb\u5b50\u5d4c\u5165\u52a8\u529b\u5b66\u548c\u6539\u5584\u6b63\u6781\u6750\u6599\u7684\u7535\u5316\u5b66\u6027\u80fd\u3002\u7f57\u5fb7\u91cc\u683c\u65af-\u4f69\u96f7\u65af\u7b49\u4eba\u8bc1\u660e\u4e86coronene\u5206\u5b50\u56fa\u4f53\u7684\u591a\u73af\u82b3\u70c3\uff08PAH\uff09\u6b63\u6781\uff08\u56fe16a\uff09\u5177\u6709\u9ad8\u5ea6\u53ef\u9006\u7684\u9634\u79bb\u5b50\u50a8\u5b58\u6027\u80fd\u3002\u4e3a\u4e86\u5728p\u578b\u6b63\u6781\u4e2d\u83b7\u5f97\u66f4\u9ad8\u7684\u6bd4\u5bb9\u91cf\uff0cLee\u7b49\u4eba\u5f00\u53d1\u4e86\u4e00\u7c7b\u57fa\u4e8eN\uff0cN-\u53d6\u4ee3\u5429\u55ea\uff08NSPZ\uff09\u884d\u751f\u7269\u7684\u65b0\u578b\u591a\u7535\u5b50p\u578b\u6709\u673a\u6b63\u6781\uff08\u56fe16b\uff09\u3002\u7531\u4e8e\u6700\u7b80\u5355\u5f62\u5f0f\u7684NSPZ 5,10-\u4e8c\u6c22-5,10-\u4e8c\u7532\u57fa\u5429\u55ea\uff08DMPZ\uff09\u5177\u6709\u591a\u7535\u5b50\u6c27\u5316\u8fd8\u539f\u80fd\u529b\uff0c\u5176\u7535\u5316\u5b66\u53cd\u5e94\u673a\u7406\u4e0e\u4e24\u4e2a\u8fde\u7eed\u7684\u5355\u7535\u5b50\u8f6c\u79fb\u53cd\u5e94\u6709\u5173\uff08\u56fe16c\uff09\u3002\u5982\u524d\u6240\u8ff0\uff0c\u5f00\u53d1\u65e0\u9502\u7cfb\u7edf\u662f\u4f4e\u6210\u672cDIB\u7684\u91cd\u8981\u7b56\u7565\u3002K\u79bb\u5b50\u7684DIB\u4e2d\u7684\u6709\u673aPTPAn\u6b63\u6781\u3002PTPAn\u6b63\u6781\uff0c\u5728\u5145\u7535\u65f6\uff0cPF6<\/sub>–<\/sup>\u9634\u79bb\u5b50\u5d4c\u5165\u5e76\u4e14\u7531\u4e8ep\u63ba\u6742\u800c\u4e0eN+<\/sup>\u4f4d\u70b9\u76f8\u4e92\u4f5c\u7528\uff08\u56fe16d-e\uff09\u3002\u91d1\u5c5e-\u6709\u673a\u6846\u67b6\u6750\u6599\uff08MOFs\uff09\u7531\u4e8e\u5176\u72ec\u7279\u7684\u591a\u5b54\u7ed3\u6784\u800c\u53d7\u5230\u5173\u6ce8\uff0c\u5177\u6709\u5bbd\u901a\u9053\u548c\u7528\u4e8e\u8f6c\u79fb\u9634\u79bb\u5b50\u7684\u77ed\u8def\u5f84\uff0c\u6709\u52a9\u4e8e\u589e\u5f3a\u9634\u79bb\u5b50\u5d4c\u5165\u52a8\u529b\u5b66\u3002Fe2<\/sub>\uff08dobpdc\u5177\u6709\u72ec\u7279\u7684\u516d\u8fb9\u5f62\u901a\u9053\u6846\u67b6\uff0c\u5176\u4e2d\u4e94\u4e2a\u914d\u4f4d\u7684Fe2+<\/sup>\u79bb\u5b50\u5728\u8fb9\u7f18\u5171\u4eab\u7684\u65b9\u5f62\u91d1\u5b57\u5854\u7684\u65e0\u9650\u4e00\u7ef4\u94fe\u4e2d\u6392\u5217\u9876\u70b9\u3002\u5728\u8be5\u6846\u67b6\u4e2d\uff0c\u5b58\u5728\u5927\u91cf\u7ed3\u6676\u5b54\uff0c\u5176\u5728\u4e2d\u5fc3\u5904\u5305\u542b\u5927\u91cf\u7a7a\u9699\u7a7a\u95f4\uff08\u56fe16f\uff09\u3002\u5927\u5b54\u5f84\u4fc3\u8fdb\u4e86Fe2<\/sub>\uff08dobpdc\uff09\u9634\u79bb\u5b50\u7684\u5feb\u901f\u5d4c\u5165\u3002\u53e6\u5916\uff0c\u7531\u4e8e\u6eb6\u5242\u4e0e\u94c1\u4f4d\u70b9\u7684\u914d\u4f4d\uff0cFe2<\/sub>\uff08dobpdc\uff09\u7684\u6c27\u5316\u63d2\u5c42\u53cd\u5e94\u53d7\u5230\u53cd\u5e94\u6eb6\u5242\u7684\u5f3a\u70c8\u5f71\u54cd\u3002\u603b\u7684\u6765\u8bf4\uff0c\u6709\u673a\u6750\u6599\u53ef\u7528\u4f5cDIB\u6b63\u6781\u3002\u6709\u673a\u6b63\u6781\u7684Na\u57faDIB\u53ef\u4ee5\u63d0\u4f9b\u4e0e\u77f3\u58a8\u6b63\u6781\u76f8\u5f53\u7684\u5bb9\u91cf\u548c\u5faa\u73af\u7a33\u5b9a\u6027\u3002\u7136\u800c\uff0c\u4e0e\u540e\u8005\u76f8\u6bd4\uff0c\u4ee5K\u4e3a\u57fa\u7840\u7684\u540c\u884c\u8868\u73b0\u51fa\u660e\u663e\u8f83\u4f4e\u7684\u80fd\u529b\u3002\u6709\u673a\u6b63\u6781\u6750\u6599\u4ecd\u7136\u9700\u8981\u9488\u5bf9\u5148\u8fdb\u7684DIB\u8fdb\u4e00\u6b65\u4f18\u5316\uff0c\u4f46\u662f\u5b83\u4eec\u76f8\u5bf9\u5bb9\u6613\u7684\u5236\u9020\u5de5\u827a\u548c\u4e30\u5bcc\u7684\u8d44\u6e90\u4e3a\u5546\u4e1a\u5e94\u7528\u63d0\u4f9b\u4e86\u5149\u660e\u7684\u524d\u666f\u3002<\/p>\n

\"\"<\/p>\n

\u56fe 16 \u6709\u673a\u6b63\u6781\u6750\u6599\u53ca\u5176\u53cd\u5e94\u673a\u7406\uff1a\uff08a\uff09\u5728\u52a0\u5165\u516d\u82ef\u5e76\u82ef\u6b63\u6781\u65f6PF6<\/sub>–<\/sup>\u9634\u79bb\u5b50\u53ef\u80fd\u4f4d\u70b9\u7684\u793a\u610f\u56fe\uff1b\uff08b\uff09NSPZ\u7684\u5316\u5b66\u7ed3\u6784\u548c\u6c27\u5316\u8fd8\u539f\u673a\u7406\uff1b\uff08c\uff09DMPZ\u4f5c\u4e3ap\u578b\u6b63\u6781\u7684DIB\u4e2d\u7684\u80fd\u91cf\u5b58\u50a8\u7684\u793a\u610f\u56fe\uff1b\uff08d\uff09PTPAn\u6b63\u6781|KPF6|\u77f3\u58a8\u8d1f\u6781\u7684\u7535\u6c60\u6784\u9020\u7684DIB\u7684\u673a\u7406\uff1b\uff08e\uff09\u5145\u7535-\u653e\u7535\u8fc7\u7a0b\u4e2d\uff0c\u7535\u5b50\u4ea4\u6362PTPAn\u5206\u5b50\uff1b\uff08f\uff09Fe2<\/sub>(dobpdc)\u7684\u7ed3\u6784\u6846\u67b6\u548cFe2<\/sub>(dobpdc)\u7684\u50a8\u80fd\u793a\u610f\u56fe\u3002<\/strong><\/p>\n

5 \u9633\u79bb\u5b50\u53cd\u5e94\u52a8\u529b\u5b66\u7684\u7b56\u7565<\/h1>\n

5.1 \u8d1f\u6781\u6750\u6599\u7684\u63d2\u5c42\u7b56\u7565<\/h2>\n

\u63d2\u5c42\u8d1f\u6781\u7684\u7406\u8bba\u5bb9\u91cf\u4f4e\u548c\u53cd\u5e94\u52a8\u529b\u5b66\u4e0d\u5145\u5206\uff0c\u9650\u5236\u4e86DIB\u5728\u80fd\u91cf\u5bc6\u5ea6\u548c\u500d\u7387\u6027\u80fd\u3002\u56e0\u6b64\uff0c\u5f00\u53d1\u4e86\u591a\u5b54\u7ed3\u6784\u7684\u4f18\u70b9\u5982\u4e0b\uff1a\uff08i\uff09\u7535\u89e3\u8d28\u5145\u5206\u8fdb\u5165\u7535\u6781\u8868\u9762\uff1b\uff08ii\uff09\u5927\u8868\u9762\u79ef\u4fc3\u8fdb\u7535\u6781\/\u7535\u89e3\u8d28\u754c\u9762\u4e0a\u7684\u7535\u8377\u8f6c\u79fb\uff1b\uff08iii\uff09\u51cf\u5c11\u79bb\u5b50\u6269\u6563\u957f\u5ea6\uff1b\uff08iv\uff09\u5728\u7535\u6781\u4e2d\u63d0\u4f9b\u5feb\u901f\u7535\u5b50\u901a\u8def\uff1b\uff08v\uff09\u63d0\u4f9b\u7a7a\u9699\u7a7a\u95f4\u6765\u9002\u5e94\u4f53\u79ef\u53d8\u5316\uff0c\u4ece\u800c\u51cf\u8f7b\u6d3b\u6027\u6750\u6599\u7c89\u788e\u7684\u538b\u529b\u3002\u57fa\u4e8e\u4e0a\u8ff0\u591a\u5b54\u7ed3\u6784\u7684\u4f18\u70b9\uff0c\u5408\u6210\u591a\u5b54\u8f6f\u78b3\uff08SC\uff09\u4f5c\u4e3a\u8d1f\u6781\uff0c\u5206\u79bb\u7684\u4e3b\u94fe\u4e4b\u95f4\u7684\u4ea4\u8054\u6761\u7eb9\uff08\u56fe17a\uff09\uff0c\u83b7\u5f97\u66f4\u5927\u7684\u5c42\u95f4\u8ddd\u79bb\uff08SC\u4e3a0.39 nm\u5bf9\u6bd4\u77f3\u58a8\u76840.34 nm\uff09\uff08\u56fe17b\uff09\uff0c\u5c06\u4fc3\u8fdbNa+<\/sup>\u7684\u5d4c\u5165\u5e76\u63d0\u9ad8\u901f\u7387\u6027\u80fd\u3002\u9664\u4e86\u591a\u5b54\u7ed3\u6784\u8bbe\u8ba1\u5916\uff0c\u78b3\u6d82\u5c42\u590d\u5408\u6750\u6599\u8bbe\u8ba1\u4e5f\u6210\u529f\u7528\u4e8eDIB\u4e2d\u7684\u5d4c\u5165\u9633\u6781\u6750\u6599\u3002\u8be5\u590d\u5408\u8bbe\u8ba1\u7684\u4f18\u70b9\u53ef\u5217\u4e3e\u5982\u4e0b\uff1a\uff08i\uff09\u6539\u5584\u79bb\u5b50\u6216\u7535\u5b50\u4f20\u5bfc\u6027\uff1b\uff08ii\uff09\u4fc3\u8fdb\u56fa\u6001\u754c\u9762\uff08SEI\uff09\u8584\u819c\u7684\u5f62\u6210\uff1b\uff08iii\uff09\u63d0\u9ad8\u7ed3\u6784\u7a33\u5b9a\u6027\u3002\u7136\u800c\uff0cMoS2<\/sub>\u7684\u5bfc\u7535\u6027\u5dee\u963b\u788d\u4e86\u5176\u5e94\u7528\u3002Z\u4e00\u79cd\u7c7b\u4f3c\u4e8epenne\u7684MoS2<\/sub>\/C\u7eb3\u7c73\u590d\u5408\u6750\u6599\u4f5c\u4e3a\u57fa\u4e8eNa\u79bb\u5b50\u7684DIB\u7684\u8d1f\u6781\uff08\u56fe17d-e\uff09\u3002\u7eb3\u7c73\u7ba1\u7684\u5e73\u5747\u957f\u5ea6\uff0c\u5185\u5f84\u548c\u58c1\u539a\u5206\u522b\u4e3a\u7ea61.5 \u03bcm\uff0c200 nm\u548c100 nm\u3002\u6ce8\u610f\uff0c\u5c42\u95f4\u8ddd\u79bb\u88ab\u786e\u5b9a\u4e3a~0.98 nm\uff08\u56fe17f\uff09\uff0c\u5176\u8fdc\u5927\u4e8e\u77f3\u58a8\uff080.34 nm\uff09\uff0c\u5e76\u4e14\u5c06\u4fc3\u8fdbNa+<\/sup>\u7684\u5d4c\u5165\/\u8131\u5d4c\u3002<\/p>\n

\"\"<\/p>\n

\u56fe 17 \u8f6f\u78b3\u7684TEM\u56fe\u50cf\uff08a\uff09\u548cHRTEM\u56fe\u50cf\uff08b\uff09\uff1b\uff08c\uff09N2<\/sub>\u5438\u9644-\u8131\u9644\u7684\u7b49\u6e29\u7ebf\u548c\u5b54\u5f84\u5206\u5e03\uff08\u63d2\u56fe\uff09\uff1b\uff08d\uff0ce\uff09\u4e0d\u540c\u653e\u5927\u7387\u9000\u706b\u540e\u7684MoS2<\/sub>\/C\u7eb3\u7c73\u7ba1\u7684SEM\u56fe\u50cf\uff1b\uff08f\uff09\u9000\u706b\u540eMoS2<\/sub>\/C\u7eb3\u7c73\u7ba1\u7684HRTEM\u56fe\u50cf\uff1b\uff08g\uff09SEM\u56fe\u50cf\u548c\uff08h\uff09\uff08MoS2<\/sub>\/F\uff09@MoS2<\/sub>@C\u7684TEM\u56fe\u50cf\uff1b\uff08i\uff09HRTEM\u56fe\u50cf\u7684\u9009\u5b9a\u533a\u57df\u548c\uff08MoS2<\/sub>\/F\uff09@MoS2<\/sub>@C\u7684\u793a\u610f\u56fe\u3002<\/strong><\/p>\n

5.2 \u5408\u91d1\u5316\u8d1f\u6781\u6750\u6599\u7684\u7b56\u7565<\/h2>\n

\u5927\u4f53\u79ef\u81a8\u80c0\u5bfc\u81f4\u7684\u5faa\u73af\u548c\u901f\u7387\u6027\u80fd\u5dee\u662f\u8d1f\u6781\u6750\u6599\u5408\u91d1\u5316\u7684\u4e3b\u8981\u6311\u6218\u3002Al\u7b94\u4e3a\u8d1f\u6781\u7684Li\u57faDIB\uff0c\u57282\u2103\u65f6\uff0c\u5faa\u73af\u5bff\u547d200\u6b21\uff0c\u5bb9\u91cf\u4fdd\u6301\u7387\u4e3a88\uff05\uff0c\u5e76\u4e14\u500d\u7387\u80fd\u529b\u4e5f\u4e0d\u8db3\uff1b\u57285\u2103\u65f6\uff0c\u5bb9\u91cf\u4fdd\u6301\u7387\u4e3a75\uff05\u3002\u4f4e\u6210\u672c\u9633\u79bb\u5b50\uff08Na+<\/sup>\uff0cK+<\/sup>\uff0cCa2+<\/sup>\u7b49\uff09\u57faDIB\u4e5f\u663e\u793a\u51fa\u4e0d\u4ee4\u4eba\u6ee1\u610f\u7684\u7535\u5316\u5b66\u6027\u8d28\u3002\u4f8b\u5982\uff0cSn\u7b94\u4f5c\u4e3a\u8d1f\u6781\u5faa\u73af\u7684Na\u79bb\u5b50\u7684DIB\u5faa\u73af400\u6b21\u5faa\u73af\uff0c\u57285\u2103\u65f6\uff0c\u5bb9\u91cf\u4fdd\u6301\u4e3a61 mAh g-1<\/sup>\u3002\u56e0\u6b64\uff0c\u5fc5\u987b\u89e3\u51b3\u4f53\u79ef\u81a8\u80c0\u95ee\u9898\uff0c\u4ee5\u5b9e\u73b0\u5177\u6709\u9ad8\u6027\u80fd\u7684\u4f4e\u6210\u672cDIB\u3002\u7136\u800c\uff0c\u5173\u4e8e\u8d1f\u6781\u6750\u6599\uff08\u4f8b\u5982\uff0cSn\uff09\u7684\u6539\u6027\u7684\u7814\u7a76\u5de5\u4f5c\uff0c\u4f7f\u5f97\u80fd\u591f\u4ee5\u4f4e\u6210\u672c\u7684\u9633\u79bb\u5b50\uff08Na+<\/sup>\uff0cK+<\/sup>\uff0cCa2+<\/sup>\u7b49\uff09\u8fdb\u884c\u53ef\u9006\u5408\u91d1\u5316\u7684DIB\u5f88\u5c11\u88ab\u62a5\u9053\u3002\u672c\u6587\u56de\u987e\u4e86\u5408\u91d1\u8d1f\u6781\u6750\u6599\uff08\u4f8b\u5982Al\uff09\u7528\u4e8e\u57fa\u4e8e\u9502\u79bb\u5b50\u7684DIB\u7684\u7b56\u7565\uff0c\u4f8b\u5982\u591a\u5b54\u7ed3\u6784\u8bbe\u8ba1\uff08\u56fe18\uff09\uff0c\u78b3\u6d82\u5c42\u590d\u5408\u6750\u6599\uff0c\u754c\u9762\u6539\u6027\uff0c\u7eb3\u7c73\u7ed3\u6784\u8bbe\u8ba1\uff08\u56fe19\uff09\u7b49\u3002\u8fd9\u4e9b\u7b56\u7565\u8fd8\u63d0\u4f9b\u4e86\u53ef\u884c\u7684\u9014\u5f84\uff0c\u4ee5\u57fa\u4e8e\u4f4e\u6210\u672c\u9633\u79bb\u5b50\u589e\u5f3a\u7528\u4e8eDIB\u7684\u5408\u91d1\u5316\u8d1f\u6781\u6750\u6599\uff08\u4f8b\u5982\uff0cSn\uff09\u7684\u7535\u5316\u5b66\u6027\u80fd\u3002<\/p>\n

\"\"<\/p>\n

\u56fe 18 \uff08a\uff09\u591a\u5b54\u94dd\u819c\u4e3a\u8d1f\u6781\u548c\u96c6\u6d41\u4f53\u7684\u53cc\u79bb\u5b50\u7535\u6c60\u793a\u610f\u56fe\uff1b\uff08b\uff09\u8d1f\u6781Al\u819c\u7684SEM\u5f62\u6001\uff08c\uff09\u78b3\u6d82\u8986\u7684\u591a\u5b54Al\uff08pAl\/C\uff09\u8d1f\u6781\u7684\u793a\u610f\u56fe\uff1b\uff08d\uff09\u78b3\u6d82\u8986\u7684pAl\u7684\u6a2a\u622a\u9762SEM\u56fe\u50cf\uff1b\uff08e\uff09\u57282\u2103\u4e0b\uff0cpAl\/CGDIB\u7684\u5faa\u73af\u6027\u80fd\u5bf9\u6bd4\u56fe\u3002<\/strong><\/p>\n

\"\"<\/p>\n

\u56fe 19 \uff08a\uff09Al\u7eb3\u7c73\u7403\uff08nAl\uff09\uff1b\uff08b\uff09\u78b3\u5305\u8986Al\u7eb3\u7c73\u7403\uff08nAl@C\uff09\u7684SEM\u5f62\u6001\uff1b\uff08c\uff09nAl@Cnanospheres\u7684HRTEM\u56fe\u50cf\uff1b\uff08d\uff09nAl@G DBI\u572815 C\u4e0b\u5faa\u73af\u6027\u80fd\u56fe\u3002<\/strong><\/p>\n

5.3 \u65b0\u578b\u7684\u8d1f\u6781\u6750\u6599<\/h2>\n

\u9664\u4e86\u4e0a\u8ff0\u8d1f\u6781\u6750\u6599\u7684\u7ed3\u6784\u8bbe\u8ba1\u548c\u6539\u8fdb\u5916\uff0c\u5f00\u53d1\u65b0\u578b\u8d1f\u6781\u6750\u6599\u4e5f\u662f\u4e00\u79cd\u6709\u524d\u666f\u7684\u7814\u7a76\u7b56\u7565\uff0c\u5982\u8fc7\u6e21\u91d1\u5c5e\u6c27\u5316\u7269\uff08TiO2<\/sub>\uff0cMoO3<\/sub>\uff0cNb2<\/sub>O5<\/sub>\u7b49\uff09\uff0c\u8fc7\u6e21\u91d1\u5c5e\u76d0\uff08FePO4<\/sub>\uff09\uff0c\u4e8c\u7ef4\u5c42\u72b6\u91d1\u5c5e\u786b\u5c5e\u5143\u7d20\u5316\u7269\uff0cMOF\uff0cMXenes\uff08Ti3<\/sub>C2<\/sub>\uff0cTi2<\/sub>C\uff0cV2<\/sub>C\uff0cNb2<\/sub>C\uff0cTi3<\/sub>CN\u7b49\uff09\uff0c\u548c\u65b0\u578b\u78b3\u57fa\u8d1f\u6781\u6750\u6599\u3002<\/p>\n

6\u3001\u7ed3\u8bba\u4e0e\u5c55\u671b<\/h1>\n

DIB\u662f\u4e00\u79cd\u8d85\u8d8a\u4f20\u7edf\u7535\u6c60\u7684\u65b0\u578b\u7535\u6c60\u7cfb\u7edf\u3002\u672c\u6587\u6982\u8ff0\u4e86DIB\u7684\u53d1\u5c55\u5386\u7a0b\u548c\u53cd\u5e94\u673a\u5236\uff0c\u63d0\u51fa\u4e86\u53d1\u5c55\u7b56\u7565\u3002\u672c\u6587\u5206\u6790\u4e86DIB\u4e2d\u6d89\u53ca\u7684\u53cd\u5e94\u52a8\u529b\u5b66\uff0c\u5305\u62ec\u6b63\u6781\u7684\u9634\u79bb\u5b50\u5d4c\u5165\u673a\u7406\uff0c\u9633\u79bb\u5b50\u5d4c\u5165\uff0c\u8d1f\u6781\u7684\u5408\u91d1\u5316\u52a8\u529b\u5b66\u3002\u8ba8\u8bba\u4e86DIB\u7684\u6210\u672c\uff0c\u7535\u6781\u6750\u6599\u7684\u7ed3\u6784\u8bbe\u8ba1\u548c\u65b0\u578b\u7535\u6781\u6750\u6599\u7684\u5f00\u53d1\u3002<\/p>\n

\uff081\uff09\u6bd4\u5bb9\u91cf\u548c\u80fd\u91cf\u5bc6\u5ea6\u4e0d\u80fd\u6ee1\u8db3\u8981\u6c42\u3002\u9634\u79bb\u5b50\u7684\u79bb\u5b50\u534a\u5f84\uff08TFSI\u4e3a3.9 \u00c5\uff0cPF6<\/sub>–<\/sup>\u4e3a4.36 \u00c5\uff0cAlCl4<\/sub>–<\/sup>\u4e3a5.28 \u00c5\uff09\u548c\u95f4\u9699\u4f4d\u7f6e\u4e0d\u8db3\uff0c\u5bfc\u81f4\u7406\u8bba\u6bd4\u5bb9\u91cf\u4f4e\uff08C20<\/sub>PF6<\/sub>\u4e3a112 mAhg-1<\/sup>\uff09\u548c\u80fd\u91cf\u5bc6\u5ea6\u4f4e\u3002\u56e0\u6b64\uff0c\u8fdb\u4e00\u6b65\u63d0\u9ad8\u6b63\u6781\u7684\u6bd4\u5bb9\u91cf\u548c\u63d0\u9ad8DIB\u7684\u80fd\u91cf\u5bc6\u5ea6\u662f\u9996\u8981\u4efb\u52a1\u3002\u53ef\u80fd\u7684\u63d0\u5347\u7b56\u7565\u662f\uff1aa\uff09\u5f00\u53d1\u9ad8\u6bd4\u5bb9\u91cf\u7684\u78b3\u8d28\u6750\u6599\uff1bb\uff09\u63a2\u7d22\u5206\u5c42\u7ed3\u6784\u7684\u66ff\u4ee3\u6750\u6599\uff0c\uff1bc\uff09\u5f15\u5165\u9ad8\u6bd4\u5bb9\u91cf\u7684\u6b63\u6781\uff1bd\uff09\u63a2\u7d22\u65b0\u578b\u7684\u591a\u4ef7\u9634\u79bb\u5b50\u3002<\/p>\n

\uff082\uff09\u975e\u9502\u9633\u79bb\u5b50\u7684\u53cd\u5e94\u52a8\u529b\u5b66\u76f8\u5bf9\u8f83\u5dee\u3002DIB\u7684\u7535\u5316\u5b66\u6027\u80fd\uff0c\u53d6\u51b3\u4e8e\u9633\u79bb\u5b50\u7684\u53cd\u5e94\u52a8\u529b\u5b66\uff0c\u53d7\u5230\u975e\u9502\u9633\u79bb\u5b50\u7684\u79bb\u5b50\u534a\u5f84\u7684\u9650\u5236\uff08Na+<\/sup>\u4e3a1.02 \u00c5\uff0cK+<\/sup>\u4e3a1.38 \u00c5\uff0cCa2+<\/sup>\u4e3a1.00 \u00c5\uff09\u3002\u56e0\u6b64\uff0c\u91c7\u53d6\u6709\u6548\u63aa\u65bd\u6539\u5584\u8d1f\u6781\u4e0e\u975e\u9502\u9633\u79bb\u5b50\u53ef\u9006\u5408\u91d1\u5316\u7684\u53cd\u5e94\u52a8\u529b\u5b66\u662f\u5fc5\u4e0d\u53ef\u5c11\u7684\uff0c\u8fd9\u5bf9\u4e8e\u5f00\u53d1\u9ad8\u6027\u80fd\u7684\u4f4e\u6210\u672cDIB\u5177\u6709\u91cd\u8981\u610f\u4e49\u3002\u89e3\u51b3\u65b9\u6848\u5305\u62ec\uff1aa\uff09\u8d1f\u6781\u6750\u6599\u7684\u7ed3\u6784\u8bbe\u8ba1\u548c\u6539\u8fdb\uff1bb\uff09\u5f00\u53d1\u65b0\u578b\u9ad8\u5bb9\u91cf\u8d1f\u6781\u6750\u6599\uff1bc\uff09\u4f7f\u7528\u4f18\u5f02\u52a8\u529b\u5b66\u7684\u65b0\u578b\u53cd\u5e94\u673a\u7406\u3002<\/p>\n

\uff083\uff09\u4f4e\u6210\u672c\u7535\u89e3\u8d28\u76d0\u7684\u6eb6\u89e3\u5ea6\u6709\u9650\u3002\u7535\u89e3\u8d28\u662f\u6d3b\u6027\u79bb\u5b50\u7684\u552f\u4e00\u6765\u6e90\uff0c\u4f5c\u4e3aDIB\u4e2d\u6d3b\u6027\u6750\u6599\u7684\u4e00\u90e8\u5206\u3002\u56e0\u6b64\uff0c\u5f00\u53d1\u9ad8\u6d53\u5ea6\u7535\u89e3\u8d28\u662f\u89e3\u51b3\u8be5\u95ee\u9898\u7684\u53ef\u884c\u65b9\u6cd5\u3002\u53ef\u80fd\u7684\u7b56\u7565\u5982\u4e0b\uff1aa\uff09\u5f00\u53d1\u9ad8\u6eb6\u89e3\u5ea6\u7535\u89e3\u8d28\u76d0\uff1bb\uff09\u63a2\u7d22\u5408\u9002\u7684\u6eb6\u5242\u4ee5\u4fc3\u8fdb\u7535\u89e3\u8d28\u76d0\u7684\u6eb6\u89e3\uff1bc\uff09\u5229\u7528\u52a9\u6eb6\u5242\u6765\u6539\u5584\u6eb6\u89e3\u6027\u7535\u89e3\u8d28\u76d0\uff1bd\uff09\u63a2\u7d22\u9ad8\u6d53\u5ea6\u7684\u542b\u6c34\u7cfb\u7edf\u3002<\/p>\n

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\u6587\u732e\u94fe\u63a5\uff1a<\/strong>Beyond Conventional Batteries: Strategies towards Low-Cost Dual-Ion Batteries with High Performances<\/strong><\/a>\uff08Angew. Chem. Int. Ed., 2019, DOI:10.1002\/anie.201814294\uff09\u3002<\/p>\n

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