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Ic<\/sub><\/em> = Ic<\/sub><\/em>+\uff08n-1\uff09\u00d73.35 \u00c5=\u0394d+ n\u00d73.35 \u00c5=I<\/em>\u00d7dobs\u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0\u00a0<\/sub>\uff081\uff09<\/p>\n \u00a0 \u00a0 \u5176\u4e2dI<\/em>\u662f\u5728\u5806\u53e0\u65b9\u5411\u4e0a\u53d6\u5411\u7684\uff0800l\uff09\u9762\u7684\u6307\u6570\uff0cdobs<\/sub>\u662f\u4e24\u4e2a\u76f8\u90bb\u9762\u7684\u95f4\u8ddd\u3002<\/p>\n \u6839\u636eGIC\u4e2d\uff0800n\uff09\u548c\uff0800n + x\uff09\u5cf0\u7684\u5e03\u62c9\u683c\u89d2\u4e4b\u95f4\u7684\u5173\u7cfb\uff0c\uff0800n\uff09\u9762\u7684\u95f4\u8dddd00n<\/sub>\u53ef\u7531\u4e0b\u5f0f\u7ed9\u51fa\uff1a<\/p>\n d00n<\/sub>=Ic<\/em>\/n=\u03bb<\/em>\/\uff082sin\u03b8<\/em>00n<\/sub>\uff09\u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \uff082\uff09<\/p>\n \u00a0 \u00a0\u03bb\u662fX\u5c04\u7ebf\u6ce2\u957f\u3002\u5bf9\u4e8e\u4e24\u4e2a\u4e0d\u540c\u7684\u5e73\u9762\uff0c\uff0800n\uff09\u548c\uff0800n+x\uff09\uff0c\u901a\u8fc7\u6c42\u89e3d00n<\/sub>\u548cd00n + x<\/sub>\uff08x\u662f\u6574\u6570\uff09\u7684\u65b9\u7a0b\u7ec4\uff0cn\u53ef\u4ee5\u8868\u793a\u5982\u4e0b\uff1a<\/p>\n n=x\/[\uff08sin\u03b8<\/em>00n<\/sub>+x\/sin\u03b8<\/em>00n<\/sub>+x\uff09-1]\u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0\uff083\uff09<\/p>\n 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\u56fe 4 R\u00fcdorff\u548cDaumas-Herold\u6a21\u578b\u7684\u79bb\u5fc3\u5206\u7ea7\u673a\u5236\uff0c\u7528\u4e8e\u6cbf\u5806\u53e0\u65b9\u5411\u79bb\u5b50\u63d2\u5165\u77f3\u58a8\u9634\u6781;\u5468\u671f\u6027\u91cd\u590d\u8ddd\u79bbIc\uff0c\u63d2\u5165\u5eca\u9053\u9ad8\u5ea6di\uff0c\u5eca\u9053\u6269\u5c55\u0394d\u3002<\/strong><\/p>\n \u56fe 5 \u6b63\u6781\u6750\u6599\u4e2d\u4e0d\u540c\u9634\u79bb\u5b50\u7684\u63d2\u5c42\u793a\u610f\u56fe\u3002<\/strong><\/p>\n PF6<\/sub>–<\/sup>\u9634\u79bb\u5b50\u7684\u7535\u89e3\u8d28\u5e7f\u6cdb\u5e94\u7528\u4e8eDIB\u3002\u5728\u5145\u7535\/\u653e\u7535\u8fc7\u7a0b\u4e2d\uff0c\u539f\u4f4dXRD\u53d1\u73b0PF6<\/sub>–<\/sup>\u5728\u77f3\u58a8\u4e2d\u7684\u7535\u5316\u5b66\u5d4c\u5165\/\u8131\u5d4c\u8fc7\u7a0b\u4e2d\uff0c\u53d1\u751f\u4e86\u4e00\u7cfb\u5217\u53ef\u9006\u7684\u9636\u6bb5\u8f6c\u6362\u3002\u539f\u4f4dXRD\u548c\u81a8\u80c0\u6d4b\u5b9a\u6cd5\uff08\u56fe6a-b\uff09\u89c2\u5bdf\u9634\u79bb\u5b50\u63d2\u5c42\u8fc7\u7a0b\u4e2d\u7684\u5f62\u6210\u548c\u8f6c\u53d8\uff1aC24<\/sub>PF6<\/sub>\uff08\u9636\u6bb54\uff09\u2192C24<\/sub>PF6<\/sub>\uff08\u9636\u6bb53\uff09\u2192C24<\/sub>PF6<\/sub>\uff08\u9636\u6bb52\uff09\u2192C20<\/sub>PF6<\/sub>\uff08\u9636\u6bb52\uff09\u2192C24<\/sub>PF6<\/sub>\uff08\u9636\u6bb51\uff09\u2192C20<\/sub>PF6<\/sub>\uff08\u9636\u6bb51\uff09\u3002\u5149\u5b66\u5e73\u53f0\u5b9e\u65f6\u76d1\u6d4b\u77f3\u58a8\u6b63\u6781\u5728\u5145\u7535\/\u653e\u7535\u8fc7\u7a0b\u4e2d\u7684\u539a\u5ea6\u6f14\u53d8\uff0c\u53d1\u73b0\u77f3\u58a8\u6b63\u6781\u7684\u4e0d\u53ef\u9006\u7684\u539a\u5ea6\u53d8\u5316\u4e0e\u9634\u79bb\u5b50\u548c\u5316\u5b66\u7ec4\u5206\u7684\u4e0d\u53ef\u9006\u5206\u89e3\u6709\u5173\u3002\u63d2\u5c42PF6<\/sub>–<\/sup>\u9634\u79bb\u5b50\u7684\u4f18\u5316\u51e0\u4f55\u5f62\u72b6\uff0c\u5982\u56fe6\u6240\u793a\u3002PF6<\/sub>–<\/sup>\u9634\u79bb\u5b50\u6269\u6563\u7684\u7406\u8bba\u6d3b\u5316\u80fd\u4f30\u8ba1\u4e3a\u7ea60.23 eV\uff08\u56fe6d\uff09\u3002\u8003\u8651\u5230\u5927\u7684\u79bb\u5b50\u5c3a\u5bf8\uff0cPF6<\/sub>–<\/sup>\u9634\u79bb\u5b50\u4f18\u5148\u6cbf\uff08100\uff09\u65b9\u5411\u6269\u6563\u3002\u53e6\u5916\uff0c\u968f\u7740PF6<\/sub>–<\/sup>\u9634\u79bb\u5b50\u7684\u5206\u7ea7\u6c34\u5e73\u589e\u52a0\uff0c\u6269\u6563\u5e38\u6570\u964d\u4f4e\u3002PF6<\/sub>–<\/sup>\u9634\u79bb\u5b50\u5728\u8f83\u9ad8\u7535\u4f4d\u4e0b\uff0c\u5bf9\u77f3\u58a8\u78b3\u7684\u5d4c\u5165\u884c\u4e3a\u4e0d\u4ec5\u4e0e\u9634\u79bb\u5b50\u5d4c\u5165\u7684\u9636\u6bb5\u7ed3\u6784\u6709\u5173\uff0c\u800c\u4e14\u8fd8\u4e0e\u7eb3\u7c73\u6c14\u6ce1\u7ed3\u6784\u7684\u5f62\u6210\u6709\u5173\u3002<\/p>\n \u56fe 6 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cm-1<\/sup>\uff09\u548cE2g2<\/sub>\uff08b\uff09\u6a21\u5f0f\uff081607 cm-1<\/sup>\uff09\u7684\u53cc\u5cf0\uff0c\u5982\u56fe7a-b\u6240\u793a\u3002\u5728\u5145\u7535\u8fc7\u7a0b\u4e2d\uff0c\u56fe7c\u4e2d\uff08002\uff09\u5cf0\u5206\u88c2\u73b0\u8c61\u4e3a\u4e24\u4e2a\u65b0\u5cf0\uff0c\u610f\u5473\u7740AlCl4<\/sub>–<\/sup>\u9634\u79bb\u5b50\u5d4c\u5165\u5929\u7136\u77f3\u58a8\u4e2d\u3002\u653e\u7535\u8fd9\u4e24\u4e2aXRD\u5cf0\u9010\u6e10\u5408\u5e76\u5728~26.6\u00b0\u6062\u590d\u4e3a\u5355\u5cf0\u3002\u7b2c\u4e00\u539f\u7406DFT\u8ba1\u7b97\u8868\u660e\uff0c\u6765\u81ea\u77f3\u58a8\u5c42\u7684\u538b\u529b\uff0c\u5bfc\u81f4\u56db\u9762\u4f53AlCl4<\/sub>–<\/sup>\u9634\u79bb\u5b50\u7684\u7ed3\u6784\u53d8\u5f62\uff0c\u5176\u56db\u4e2a\u952e\u89d2\u4ece\u81ea\u7531\u6001\u7684109.5\u00b0\u53d8\u4e3a107.8\u00b0\uff0c106.8\u00b0\uff0c110.1\u00b0\u548c107.6\u00b0\u5206\u522b\u5904\u4e8e\u626d\u66f2\u72b6\u6001\u3002AlCl4<\/sub>–<\/sup>\u9634\u79bb\u5b50\u7684\u5c3a\u5bf8\u4ece4.88 \u00c5\u964d\u4f4e\u5230~4.79 \u00c5\uff08\u56fe7d\uff09\u3002\u7406\u8bba\u8ba1\u7b97\u53d1\u73b0AlCl4<\/sub>–<\/sup>\u9634\u79bb\u5b50\u5d4c\u5165\u77f3\u58a8\u540e\uff0c\u5e73\u9762\u56db\u8fb9\u5f62\u7684\u51e0\u4f55\u5f62\u72b6\u5bf9\u50a8\u80fd\u662f\u6709\u5229\u7684\u3002\u5e73\u9762\u51e0\u4f55\u5f62\u72b6\u4e0e\u5e73\u8eba\u6784\u578b\u76f8\u6bd4\u603b\u80fd\u91cf\u9ad80.69 eV\uff0c\u53cc\u5c42\u5806\u53e0\u56db\u9762\u4f53\u51e0\u4f55\u5f62\u72b6\uff0c\u5728\u6b63\u5e38\u6761\u4ef6\u4e0b\u6bd4\u5355\u5c42\u56db\u9762\u4f53\u51e0\u4f55\u5f62\u72b6\u66f4\u4e0d\u7a33\u5b9a\u3002\u6b64\u5916\uff0c\u4ece\u56db\u9762\u4f53\u51e0\u4f55\u5f62\u72b6\u5230\u5e73\u9762\u51e0\u4f55\u5f62\u72b6\u7684\u7ed3\u6784\u8f6c\u53d8\u7684\u80fd\u5792\uff08\u56fe7g\uff09\u8fdc\u8fdc\u9ad8\u4e8e\u56db\u9762\u4f53\u51e0\u4f55\u5f62\u72b6\u7684\u6269\u6563\u3002\u968f\u7740\u4e2d\u6027AlCl4<\/sub>\u5728\u77f3\u58a8\u4e2d\u6269\u6563\u7684\u4e0d\u540c\u9014\u5f84\uff0c\u80fd\u91cf\u52bf\u5792\u8ba1\u7b97\u5f97\u975e\u5e38\u5c0f\uff0c\u8303\u56f4\u4ece0.012\u52300.029eV\u3002\u7ed3\u679c\uff0cAlCl4<\/sub>\uff0cD\u7684\u6269\u6563\u5e38\u6570\u4f30\u8ba1\u572810-4<\/sup> cm2<\/sup> s-1<\/sup>\u7684\u6570\u91cf\u7ea7\uff0c\u901a\u8fc7\u4ee5\u4e0b\u7b49\u5f0f\uff1a<\/p>\n D = 1\/6l<\/em>2<\/sup>v0<\/sub>exp[-E<\/em>d<\/sub>\/\uff08kb<\/sub>T<\/em>\uff09]\u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \uff085\uff09<\/p>\n \u00a0 \u00a0\u8fd9\u91ccI<\/em>\u8868\u793a\u6cbf\u67d0\u4e00\u8def\u5f84\u7684\u521d\u59cb\u548c\u6700\u7ec8\u4f4d\u7f6e\u4e4b\u95f4\u7684\u6269\u6563\u8ddd\u79bb\uff0cv0<\/sub>\u8868\u793a\u65bd\u52a0\u7684\u9891\u7387\uff081013 Hz\uff09\uff1bEd<\/sub>\u662f\u9634\u79bb\u5b50\u6269\u6563\u7684\u80fd\u5792\uff1bkb<\/sub>\u8868\u793a\u73bb\u5c14\u5179\u66fc\u5e38\u6570\uff0cT\u8868\u793a\u7edd\u5bf9\u6e29\u5ea6\u3002<\/p>\n \u56fe 7 \uff08a\uff09\u5728\u5145\u7535\u7535\u538b1.99\u30012.37\u30012.42\u548c2.45 V\u4ee5\u53ca\u653e\u7535\u7535\u538b\u4e3a2.3\u30012.24\u30011.8\u548c0.5 V\u65f6\u7684NG\u7684\u62c9\u66fc\u5149\u8c31\uff1b\uff08b\uff09\u5145\u7535-\u653e\u7535\u5faa\u73af\u8bb0\u5f55NG\u9634\u6781\u7684\u539f\u4f4d\u62c9\u66fc\u5149\u8c31\uff1b\uff08c\uff09\u7b2c\u4e8c\u4e2a\u5faa\u73af\u4e2d\u5404\u79cd\u5145\u7535\u548c\u653e\u7535\u72b6\u6001\u7684NG\u7684\u975e\u539f\u4f4dXRD\u56fe\u8c31\uff1b\uff08d\uff09\u5d4c\u5165\u77f3\u58a8\u5c42\u4e2d\u7684AlCl4-<\/sub>\u9634\u79bb\u5b50\u6a21\u578b;\uff08e\uff09\u77f3\u58a8\u4e2d\u7684\u4e2d\u6027AlCl4<\/sub>\u7684\u56db\u4e2a\u57fa\u672c\u6269\u6563\u9014\u5f84;\uff08f\uff09\u4e0d\u540c\u9636\u6bb5-4GIC\u7684\u539f\u5b50\u7ed3\u6784\u548c\u603b\u80fd\u91cf\uff0c\u5305\u62ec\u5e73\u9762\u548c\u56db\u9762\u4f53\uff08\u5e73\u8eba\u548c\u76f4\u7acb\uff09\u51e0\u4f55\u5f62\u72b6;\uff08g\uff09\u5e73\u8eba\u56db\u9762\u4f53\u51e0\u4f55\u7684\u80fd\u91cf\u53d6\u4e3a\u96f6\u3002<\/strong><\/p>\n \u79bb\u5b50\u6db2\u4f53\u7535\u89e3\u8d28\u56e0\u5176\u72ec\u7279\u7684\u4f18\u70b9\u800c\u53d7\u5230\u5173\u6ce8\uff0c\u4f8b\u5982\u4f4e\u53ef\u71c3\u6027\uff0c\u5bbd\u7535\u5316\u5b66\u7a97\u53e3\uff0c\u4e0e\u6eb6\u5242\u5206\u89e3\u548c\u6eb6\u5242\u5171\u63d2\u5165\u9634\u6781\u65e0\u5173\u3002\u77f3\u58a8\u6b63\u6781\u4e2dTFSI–<\/sup>\u9634\u79bb\u5b50\u7684\u5d4c\u5165\u79bb\u5b50\u6db2\u4f53\u7535\u89e3\u8d28\u7684\u5206\u6790\u53d1\u73b0\uff0c\u9634\u79bb\u5b50\u63d2\u5c42\u7684\u5206\u7ea7\u73b0\u8c61\u4e0e\u5de5\u4f5c\u6e29\u5ea6\u548c\u622a\u6b62\u7535\u4f4d\u6709\u5173\u3002\u539f\u4f4dXRD\u7ed3\u5408\u5faa\u73af\u4f0f\u5b89\u6cd5\uff08CV\uff09\u63ed\u793a\u4e86GIC\u7684\u7279\u5b9a\u9636\u6bb5\u76f8\u8f6c\u53d8\uff08\u56fe8\uff09\u3002\u5728\u5145\u7535\/\u653e\u7535\u8fc7\u7a0b\u4e2d\uff0cXRD\u5cf0\u51fa\u73b0\u5206\u88c2\u548c\u79fb\u4f4d\u884c\u4e3a\u3002\u5e73\u5747TFSI–<\/sup>\u63d2\u5165\u7684\u5eca\u9053\u9ad8\u5ea6di<\/sub><\/em>\u548c\u76f8\u5e94\u7684\u5eca\u9053\u6269\u5c55\u0394d<\/em>\u4e3a7.96\u00b10.05\u548c4.61\u00b10.05\uff0c\u4f53\u79ef\u81a8\u80c0\u4e3a137\uff05\u3002\u572820\u2103\u4e0b\uff0cTFSI–<\/sup>\u5d4c\u5165\u77f3\u58a8\u7684\u6700\u5927\u5316\u5b66\u8ba1\u91cf\u7ea6\uff08TFSI\uff09C26\uff0c\u572860\u2103\u4e0b\uff0c\u4e3a\uff08TFSI\uff09C20\u3002<\/p>\n \u56fe 8 \uff08a\uff09\u5faa\u73af\u4f0f\u5b89\u5b9e\u9a8c\uff08\u7b2c1\u6b21\u5faa\u73af\uff09\u7684\u7535\u6c60\u7535\u538b\u4e0e\u65f6\u95f4\u548c\u6bd4\u7535\u6d41\u4e0e\u65f6\u95f4\u7684\u5173\u7cfb\u66f2\u7ebf\uff1b\uff08b\uff09\u53cc\u79bb\u5b50\u7535\u6c60\u7684\u91d1\u5c5e\u9502\/KS6L\u7684\u539f\u4f4dX\u5c04\u7ebf\u884d\u5c04\u56fe\u8c31\u3002<\/strong><\/p>\n \u4e0d\u540c\u9634\u79bb\u5b50\u5b58\u5728\u4e0d\u540c\u7684\u63d2\u5c42\u6548\u5e94\uff0c\u5305\u62ecPF6<\/sub>–<\/sup>\uff0cBF4<\/sub>–<\/sup>\uff0cTFSI–<\/sup>\u548cFTFSI–<\/sup>\u3002\u7814\u7a76\u53d1\u73b0DIB\u4e2d\u7684\u77f3\u58a8\u6b63\u6781\u4e2d\u7684\u9634\u79bb\u5b50\u7684\u5c3a\u5bf8\u4e0e\u7535\u5316\u5b66\u6027\u80fd\u5bc6\u5207\u76f8\u5173\u3002\u9634\u79bb\u5b50\u5d4c\u5165\u77f3\u58a8\u7684\u8d77\u59cb\u7535\u4f4d\u5177\u6709\u4ee5\u4e0b\u964d\u5e8f\uff1aBETI–<\/sup>>FSI–<\/sup>>FTFSI–<\/sup>>FSI–<\/sup>\/TFSI–<\/sup>>TFSI–<\/sup>>TFSI–<\/sup>\/FSI–<\/sup>\u300220\u2103\u65f6\uff0c\u79bb\u5b50\u7535\u5bfc\u7387\uff0c\u968f\u7740\u79bb\u5b50\u5c3a\u5bf8\u7684\u51cf\u5c11\u800c\u589e\u52a0\uff1aBETI–<\/sup><TFSI–<\/sup><TFSI–<\/sup>\/FSI–<\/sup><FTFSI–<\/sup><FSI–<\/sup>\/TFSI–<\/sup><FSI–<\/sup>\uff0c\u8fd9\u610f\u5473\u7740\u79bb\u5b50\u5bf9\u5f62\u6210\u548c\u81ea\u805a\u96c6\u6548\u5e94\uff0c\u4e3b\u5bfc\u4e86\u9634\u79bb\u5b50\u7684\u7535\u5316\u5b66\u6269\u6563\u8fc7\u7a0b\u3002\u6b64\u5916\uff0c\u63d2\u5c42\u80fd\u4e0e\u77f3\u58a8\u548c\u63d2\u5c42\u5242\uff08\u5982PF6<\/sub>–<\/sup>\u548cClO4<\/sub>–<\/sup>\uff09\u4e4b\u95f4\u7684\u7535\u5b50\u8f6c\u79fb\u5bc6\u5207\u76f8\u5173\uff0c\u63d2\u5c42\u7684\u7535\u79bb\u52bf\u6216\u7535\u5b50\u4eb2\u548c\u529b\u4e0e\u63d2\u5165\u5242\u7684\u5927\u5c0f\u76f8\u5173\uff0c\u53ef\u4ee5\u7528\u6765\u6d4b\u91cfGIC\u7684\u7a33\u5b9a\u6027\u3002<\/p>\n \u8d1f\u6781\u7684\u53cd\u5e94\u52a8\u529b\u5b66\u5bf9DIB\u7684\u7535\u5316\u5b66\u6027\u8d28\u5177\u6709\u91cd\u8981\u610f\u4e49\u3002\u8d1f\u6781\u6750\u6599\u7684\u53cd\u5e94\u673a\u7406\u4e0eLIB\u4e2d\u7684\u76f8\u4f3c\uff0c\u5305\u62ec\u8131\u5d4c\u3001\u5408\u91d1\u5316\u3001\u8f6c\u5316\u548c\u5265\u79bb\/\u7535\u9540\u3002\u8131\u51fa\u548c\u5d4c\u5165\u4e0e\u5408\u91d1\u5316\u662f\u5927\u591a\u6570DIB\u8d1f\u6781\u6700\u4e3b\u8981\u7684\u4e24\u79cd\u53cd\u5e94\u673a\u5236\u3002<\/p>\n \u77f3\u58a8\u662fDIB\u8d1f\u6781\u6700\u5e38\u7528\u7684\u6750\u6599\uff0c\u63d2\u5c42\u77f3\u58a8\u4e2d\u7684\u9502\u7684\u53cd\u5e94\u5982\u4e0b\uff1a<\/p>\n Li+<\/sup>+6C+e–<\/sup>\u2194LiC6<\/sub>\u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \uff086\uff09<\/p>\n \u53cd\u5e94\u6700\u663e\u7740\u7684\u7279\u5f81\u662f\u5206\u7ea7\u73b0\u8c61\uff0c\u5176\u7c7b\u4f3c\u9634\u79bb\u5b50\u5d4c\u5165\u77f3\u58a8\u6b63\u6781\u3002\u5728\u5206\u671f\u8fc7\u7a0b\u4e2d\uff0c\u901a\u8fc7\u5b9e\u9a8c\u548c\u7406\u8bba\u5efa\u7acb\u4e86GIC\u7684\u63d2\u5c42\u52bf\u56fe\u3002\u5bf9\u4e8eLix<\/sub>C6<\/sub>\uff080<x<1\uff09\u89c2\u5bdf\u5230\u4e24\u4e2a\u660e\u663e\u7684\u5e73\u53f0\uff1a\u7b2c\u4e00\u4e2a\u8303\u56f4\u4ecex = 0.25-0.5\u8868\u793a\u5f62\u6210\u9636\u6bb52 GIC\u7684LiC12<\/sub>\uff0c\u53e6\u4e00\u4e2a\u8303\u56f4\u4ecex = 0.5-0.9\u8868\u793a\u5f62\u6210\u9636\u6bb51 GIC\u7684LiC6<\/sub>\uff0cDFT\u8ba1\u7b97\u6240\u9884\u6d4b\uff0cLi\u5728\u77f3\u58a8\u6676\u4f53ab\u5e73\u9762\u4e2d\u7684\u8fc1\u79fb\u6bd4\u6cbfc\u65b9\u5411\u7684\u8fc1\u79fb\u66f4\u4e3a\u6709\u5229\u3002\u5728ab\u5e73\u9762\u4e2d\uff0c\u5b58\u5728\u4e24\u79cd\u53ef\u80fd\u7684\u8fc1\u79fb\u9014\u5f84\uff1a\uff08i\uff09\u6865\uff08B\uff09\u8fc1\u79fb\u8def\u5f84\uff0c\u5176\u4e2dLi\u901a\u8fc7\u540e\u7eed\u5c42\u7684\u78b3\u539f\u5b50\u77e9\u5f62\u6269\u6563\uff0c\u4ee5\u53ca\uff08ii\uff09\u9876\u90e8\uff08T\uff09\u8fc1\u79fb\u8def\u5f84\uff0c\u5176\u4e2dLi\u5728\u4e24\u4e2a\u5168\u7b49\u4e4b\u95f4\u901a\u8fc7\u78b3\u539f\u5b50\uff0c\u5982\u56fe9b\u6240\u793a\u3002\u6865\u8fc1\u79fb\u9014\u5f84\u6709\u7a7a\u4f4d\u548cFrenkel\u673a\u5236\uff1b\u800c\u9876\u90e8\u8fc1\u79fb\u9014\u5f84\u53ea\u6709Frenkel\u673a\u5236\uff08\u56fe9c-e\uff09\u3002\u6cbf\u7740\u6865\u548c\u9876\u90e8\u8fc1\u79fb\u8def\u5f84\u7684LiC6<\/sub>\u4e2dLi\u6269\u6563\u7684\u6fc0\u6d3b\u52bf\u5792\u5206\u522b\u4e3a0.42 eV\uff08\u7a7a\u4f4d\u548cFrenkel\u673a\u5236\uff09\u548c0.51 eV\uff08Frenkel\u673a\u5236\uff09\u3002\u6269\u6563\u7cfb\u6570\u662f\u5f71\u54cd\u53cd\u5e94\u52a8\u529b\u5b66\u7684\u53e6\u4e00\u4e2a\u91cd\u8981\u53c2\u6570\u3002\u53e6\u5916\uff0c\u5728Li\u5728\u77f3\u58a8\u4e2d\u7684\u9636\u6bb5\u5d4c\u5165\u671f\u95f4\uff0c\u4f53\u79ef\u81a8\u80c0\u662f\u4e0d\u53ef\u907f\u514d\u7684\u3002<\/p>\n \u56fe 9 \uff08a\uff09Lix<\/sub>C6<\/sub>\u4e2dx\u7684\u51fd\u6570\u7684\u7a33\u5b9a\u76f8\u7684\u5d4c\u5165\/\u76f8\u53d8\u7535\u4f4d\uff1b\uff08b\uff09LiC6<\/sub>\u4e2dLi+<\/sup>\u8fc1\u79fb\u7684\u4e24\u79cd\u53ef\u80fd\u7684\u5e73\u9762\u5185\u9014\u5f84\uff1b\u7a7a\u4f4d\u673a\u5236\u548cB\u9014\u5f84\uff08e\uff09Frenkel\u673a\u5236\u548cT\uff08c\uff09\u548cB\uff08d\uff09\u9014\u5f84\u7684\u6bd4\u8f83\u3002<\/strong><\/p>\n \u5408\u91d1\u6750\u6599\uff08\u4f8b\u5982\uff0cAl\uff0cSn\uff0cSi\uff0cZn\uff0cBi\u7b49\uff09\u7531\u4e8e\u5176\u9ad8\u7406\u8bba\u5bb9\u91cf\uff0c\u76f8\u5bf9\u4f4e\u7684\u6210\u672c\uff0c\u73af\u5883\u53cb\u597d\u6027\u548c\u5b89\u5168\u7684\u64cd\u4f5c\u7535\u4f4d\uff0c\u662f\u5f88\u6709\u524d\u666f\u7684\u8d1f\u6781\u6750\u6599\u3002Al\u548cSn\u666e\u904d\u7528\u4f5cDIB\u7684\u8d1f\u6781\u3002\u7136\u800c\uff0c\u4f53\u79ef\u53d8\u5316\u9650\u5236\u4e86\u5408\u91d1\u8d1f\u6781\u7684\u53d1\u5c55\u3002\u4e3a\u63ed\u793a\u5931\u6548\u673a\u7406\uff0c\u672c\u8282\u5c06\u5bf9\u57fa\u4e8eAl\u548cSn\u8d1f\u6781\u7684\u5408\u91d1\u5316\u53cd\u5e94\u673a\u7406\u8fdb\u884c\u7efc\u8ff0\u548c\u8ba8\u8bba\u3002Al\u4f5c\u4e3aDIB\u7684\u8d1f\u6781\u6750\u6599\u5177\u6709\u4ee5\u4e0b\u51e0\u4e2a\u4f18\u70b9\uff1a\uff08i\uff09\u9ad8\u7406\u8bba\u5bb9\u91cf\uff08LiAl\u7ea6\u4e3a993 mAh g-1<\/sup>\uff09\uff1b\uff08ii\uff09\u5e73\u5766\u548c\u5bbd\u7535\u538b\u5e73\u53f0\u63d0\u4f9b\u7a33\u5b9a\u7684\u529f\u7387\u8f93\u51fa\uff1b\uff08iii\uff09\u4f4e\u6210\u672c\u548c\u5e7f\u6cdb\u7684\u53ef\u7528\u6027\u4f5c\u4e3a\u56de\u6536\u6750\u6599\u3002\u7136\u800c\uff0c\u7531\u4e8e\u5927\u7684\u4f53\u79ef\u81a8\u80c0\uff0cAl\u8d1f\u6781\u7684\u7c89\u788e\u4ecd\u7136\u662f\u4e00\u4e2a\u5de8\u5927\u7684\u6311\u6218\u3002\u5728\u5ba4\u6e29\u4e0b\uff0cLi-Al\u7cfb\u7edf\u7684\u7535\u538b\u5206\u5e03\u4ec5\u5728\u7b2c\u4e00\u6b21\u9502\u5316\u671f\u95f4\uff0c\u57280.26 V\u5904\u51fa\u5148\u4e00\u4e2a\u5bbd\u7684\u5e73\u53f0\uff08\u56fe10\uff09\u3002\u521d\u59cb\u7535\u538b\u533a\u57dfI\uff082-0.26 V\uff09\u4e0e\u94dd\u7535\u6781\u9876\u90e8\u6c27\u5316\u5c42\u7684\u5b58\u5728\u6709\u5173\u3002\u7535\u538b\u5e73\u53f0\uff08\u533a\u57dfII\uff09\u88ab\u6307\u5b9a\u4e3aLiAl\u76f8\u7684\u5f62\u6210\uff0c\u4ea7\u751f\u5305\u62ecAl\u548cLiAl\u7684\u4e24\u76f8\u533a\u57df\u3002\u533a\u57dfIII\uff080.26-0.01 V\uff09\u7684\u503e\u659c\u7279\u5f81\u6697\u793a\u6ca1\u6709\u5f62\u6210\u5176\u4ed6\u5bcc\u9502\u76f8\uff08\u5982Li9<\/sub>Al4<\/sub>\uff09\u3002\u9502\u5728AlLi\u76f8\u4e2d\u7684\u5316\u5b66\u6269\u6563\u7cfb\u6570\u4ece10-9<\/sup>\u523010-12<\/sup>cm2<\/sup> s-1<\/sup>\u7684\u6570\u91cf\u7ea7\u53d8\u5316\u3002\u94dd\u7eb3\u7c73\u7ebf\u7c89\u788e\u7684\u539f\u4f4d\u900f\u5c04\u7535\u5b50\u663e\u5fae\u955c\uff08TEM\uff09\u89c2\u5bdf\uff0c\u5982\u56fe10c\u6240\u793a\u3002\u539f\u59cbAl\u7eb3\u7c73\u7ebf\u7684\u76f4\u5f84\u4e3a\u7ea640 nm\uff0c\u8868\u9762Al2<\/sub>O3<\/sub>\u58f3\u4e3a\u7ea65 nm\u3002\u9502\u5316\u4e4b\u540e\uff0c\u7eb3\u7c73\u7ebf\u5f84\u5411\u81a8\u80c0\u81f362 nm\uff0c\u4f53\u79ef\u81a8\u80c0\u8d85\u8fc7100\uff05\uff08\u56fe10d\uff09\u3002<\/p>\n \u56fe 10 \uff08a\uff09\u9502-\u94dd\u4f53\u7cfb\u5728423\u2103\u7684\u5e93\u4ed1\u6ef4\u5b9a\u66f2\u7ebf\uff1b\uff08b\uff09\u94dd\u8584\u819c\u7684\u6052\u7535\u6d41\u56fe\u3002\u5728\u7b2c\u4e00\u6b21\u5faa\u73af\u671f\u95f4Al\u7eb3\u7c73\u7ebf\u7684\u5f62\u6001\u6f14\u53d8\uff1a\uff08c\uff09\u539f\u59cbAl\u7eb3\u7c73\u7ebf\uff1b\uff08d\uff09\u5b8c\u5168\u9502\u5316\u7684\u7eb3\u7c73\u7ebf\uff1b\uff08e\uff09\u7b2c\u4e00\u6b21\u8131\u9502\u540e\u7684\u7eb3\u7c73\u7ebf\uff1b\uff08f\uff09\u4e09\u6b21\u7535\u5316\u5b66\u5faa\u73af\u540e\u7684\u96f6\u635f\u5931\u56fe\u50cf\uff1b\uff08g\uff09Al\u7684EELS\u56fe<\/strong>\u3002<\/p>\n \u5728\u5ba4\u6e29\u4e0b\uff0c\u5e73\u8861Na-Sn\u76f8\u56fe\u5f62\u6210\u4e03\u4e2a\u4e2d\u95f4\u76f8\uff0c\u5373NaSn6<\/sub>\uff0cNaSn4<\/sub>\uff0cNaSn3<\/sub>\uff0cNaSn2<\/sub>\uff0cNa9<\/sub>Sn4<\/sub>\uff0cNa3<\/sub>Sn\u548cNa15<\/sub>Sn4<\/sub>\u3002\u5728120\u2103\u65f6\uff0c\u89c2\u5bdf\u5230\u4e09\u79cdNa-Sn\u5408\u91d1\u4e3aNa1\u3001\u524d\u8a00<\/h1>\n
2\u3001DIB\u7535\u6c60\u7684\u53d1\u5c55\u73b0\u72b6<\/h1>\n
2.1 DIB\u7535\u6c60\u7684\u4e3b\u8981\u74f6\u9888<\/h2>\n
<\/p>\n
2.2 DIB\u7535\u6c60\u548cLIB\u7684\u533a\u522b<\/h2>\n
<\/p>\n
<\/p>\n
3\u3001DIB\u7535\u6c60\u7684\u53cd\u5e94\u673a\u5236<\/h1>\n
3.1 \u6b63\u6781\u6750\u6599\u7684\u53cd\u5e94\u673a\u5236\uff1a\u9634\u79bb\u5b50\u63d2\u5c42<\/h2>\n
<\/p>\n
<\/p>\n
3.1.1 PF6<\/sub>–<\/sup>\u9634\u79bb\u5b50\u7684\u63d2\u5c42\u673a\u5236<\/h3>\n
<\/p>\n
3.1.2 AlCl4<\/sub>–<\/sup>\u9634\u79bb\u5b50\u7684\u63d2\u5c42\u673a\u5236<\/h3>\n
<\/p>\n
3.1.3 TFSI–<\/sup>\u9634\u79bb\u5b50\u7684\u63d2\u5c42\u673a\u5236<\/h3>\n
<\/p>\n
3.1.4 \u4e0d\u540c\u7c7b\u578b\u9634\u79bb\u5b50\u7684\u63d2\u5c42\u673a\u5236<\/h3>\n
3.2 \u8d1f\u6781\u7684\u53cd\u5e94\u673a\u5236<\/h2>\n
3.2.1 \u63d2\u5c42\u673a\u5236<\/h3>\n
<\/p>\n
3.2.2 \u5408\u91d1\u5316\u53cd\u5e94<\/h3>\n
<\/p>\n