{"id":169467,"date":"2019-03-18T06:30:46","date_gmt":"2019-03-17T22:30:46","guid":{"rendered":"\/\/m.iemloyee.com\/?p=169467"},"modified":"2019-03-17T21:47:48","modified_gmt":"2019-03-17T13:47:48","slug":"%e3%80%90%e5%ae%a1%e7%a8%bf%e5%b7%b2%e5%9b%9e%e5%a4%8d%e3%80%91%e4%b8%ad%e5%b1%b1%e5%a4%a7%e5%ad%a6%e5%bc%a0%e5%bb%ba%e5%8b%87%e6%95%99%e6%8e%88%e8%af%be%e9%a2%98%e7%bb%84chem-soc-rev-%e5%a4%9a","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=169467","title":{"rendered":"\u4e2d\u5c71\u5927\u5b66\u5f20\u5efa\u52c7\u6559\u6388\u8bfe\u9898\u7ec4Chem. Soc. Rev.:\u591a\u5b54\u6750\u6599\u2014\u2014\u4ece\u8272\u8c31\u5e94\u7528\u5230\u6d41\u52a8\u5316\u5b66"},"content":{"rendered":"
\u3010\u5f15\u8a00<\/b><\/strong>\u3011<\/p>\n \u5c0f\u5206\u5b50\u6216\u624b\u6027\u5206\u5b50\uff08\u6bd4\u5982\u836f\u7269\uff09\u7684\u5206\u79bb\u5728\u5316\u5b66\u548c\u5236\u836f\u5de5\u4e1a\u4e2d\u7684\u7eaf\u5316\u5408\u7269\u751f\u4ea7\u4e2d\u5177\u6709\u5341\u5206\u91cd\u8981\u7684\u610f\u4e49\u3002\u8272\u8c31\u6280\u672f\u548c\u819c\u5206\u79bb\u6280\u672f\u662f\u76ee\u524d\u6240\u5e7f\u6cdb\u4f7f\u7528\u7684\u4e24\u79cd\u5206\u79bb\u6280\u672f\u3002\u4ed6\u4eec\u53ef\u4ee5\u66ff\u4ee3\u9ad8\u80fd\u8017\u548c\u9ad8\u6210\u672c\u7684\u65b9\u6cd5\uff08\u6bd4\u5982\u5206\u998f\uff09\u6765\u9ad8\u9009\u62e9\u6027\u5730\u5bf9\u6c14\u4f53\u6216\u6db2\u4f53\u6df7\u5408\u7269\u8fdb\u884c\u5206\u79bb\u3002\u540c\u65f6\uff0c\u8bb8\u591a\u6709\u6548\u7684\u9009\u62e9\u6027\u50ac\u5316\u5242\uff08\u5305\u62ec\u9176\uff09\u901a\u5e38\u9700\u8981\u56fa\u5b9a\u5728\u56fa\u4f53\u8f7d\u4f53\u4e0a\u8fdb\u884c\u5206\u79bb\u548c\u56de\u6536\u3002\u5177\u6709\u8f83\u9ad8\u5316\u5b66\u548c\u70ed\u7a33\u5b9a\u6027\u3001\u8f83\u5927\u8868\u9762\u79ef\u3001\u53ef\u8c03\u5b54\u9699\u7387\u548c\u591a\u79cd\u529f\u80fd\u7684\u5148\u8fdb\u591a\u5b54\u6750\u6599\uff0c\u5728\u5316\u5b66\u5206\u79bb\u548c\u56fa\u5b9a\u5316\u50ac\u5316\u4e2d\u5177\u6709\u5f88\u597d\u7684\u5e94\u7528\u3002\u6700\u8fd1\uff0c\u4e00\u7cfb\u5217\u65b0\u5174\u591a\u5b54\u6750\u6599\u5df2\u7ecf\u4f5c\u4e3a\u8272\u8c31\u5206\u79bb\u7684\u56fa\u4f53\u56fa\u5b9a\u76f8\u3001\u591a\u5b54\u819c\u57fa\u8d28\u548c\u7528\u4e8e\u50ac\u5316\u7684\u56fa\u4f53\u8f7d\u4f53\u53d7\u5230\u4e86\u5e7f\u6cdb\u5730\u5173\u6ce8\u3002<\/p>\n \u591a\u5b54\u6750\u6599\u5305\u62ec\u5404\u79cd\u65e0\u673a\u3001\u6709\u673a\u548c\u6709\u673a-\u65e0\u673a\u590d\u5408\u591a\u5b54\u6750\u6599\u3002\u4eba\u4eec\u8fc7\u53bb\u5bf9\u591a\u5b54\u6750\u6599\u7684\u8ba4\u77e5\u505c\u7559\u5728\u65e0\u673a\u591a\u5b54\u6750\u6599\u4e0a\uff0c\u6bd4\u5982\u91d1\u5c5e\u6c27\u5316\u7269\u548c\u6cb8\u77f3\u3002\u4f46\u6700\u8fd1\uff0c\u91d1\u5c5e-\u6709\u673a\u6846\u67b6\uff08MOF\uff09\u3001\u591a\u5b54\u6709\u673a\u805a\u5408\u7269\uff08POP\uff09\u548c\u5171\u4ef7\u6709\u673a\u6846\u67b6\uff08COF\uff09\u7684\u53d1\u73b0\uff0c\u4e3a\u8fd9\u4e2a\u9886\u57df\u6ce8\u5165\u4e86\u65b0\u7684\u6d3b\u529b\u3002\u5728\u8fc7\u53bb\u7684\u4e8c\u5341\u5e74\u4e2d\uff0c\u8fd9\u4e9b\u65b0\u578b\u591a\u5b54\u6750\u6599\uff0cMOF\u548cCOF\uff0c\u591a\u5b54\u6709\u673a\u7b3c\u5b50\uff0c\u591a\u5b54\u6709\u673a\u805a\u5408\u7269\u548c\u91d1\u5c5e-\u6709\u673a\/\u52a8\u6001\u5171\u4ef7\u51dd\u80f6\u7684\u7814\u7a76\u53d6\u5f97\u4e86\u5de8\u5927\u7684\u8fdb\u6b65\u3002\u8fd9\u4e9b\u591a\u5b54\u6750\u6599\u901a\u5e38\u7531\u5206\u5b50\u7ed3\u6784\u5355\u5143\u7ec4\u88c5\u800c\u6210\u3002\u5f88\u591a\u6750\u6599\u7684\u5206\u5b50\u7ed3\u6784\u5355\u5143\u901a\u8fc7\u52a8\u6001\u5171\u4ef7\u952e\u6216\u914d\u4f4d\u952e\u8fde\u63a5\u5728\u4e00\u8d77\u3002\u6240\u5f97\u5230\u7684\u6750\u6599\u901a\u5e38\u662f\u9ad8\u5ea6\u591a\u5b54\u7684\uff0c\u5177\u6709\u975e\u5e38\u5927\u7684\u8868\u9762\u79ef\u5e76\u4e14\u6613\u4e8e\u5316\u5b66\u5b98\u80fd\u5316\u3002<\/p>\n \u3010\u6210\u679c\u7b80\u4ecb<\/b><\/strong>\u3011<\/p>\n \u8fd1\u65e5\uff0c\u4e2d\u5c71\u5927\u5b66\u5f20\u5efa\u52c7\u6559\u6388\u8bfe\u9898\u7ec4<\/b><\/strong>\u603b\u7ed3\u4e86\u65b0\u5174\u7684\u591a\u5b54\u6750\u6599\u53ca\u5176\u5728\u6bdb\u7ec6\u7ba1\u67f1\u548c\u5fae\u6d41\u4f53\u88c5\u7f6e\u4e2d\u4f5c\u4e3a\u529f\u80fd\u6750\u6599\u5728\u5206\u79bb\u548c\u50ac\u5316\u7b49\u65b9\u9762\u7684\u5e94\u7528\u3002\u672c\u6587\u6db5\u76d6\u4e86\u591a\u5b54\u6750\u6599\u5728\u6bdb\u7ec6\u7ba1\u67f1\u4e2d\u7684\u5e94\u7528\uff0c\u591a\u5b54\u6750\u6599\u5728\u8272\u8c31\u4e2d\u7684\u5e94\u7528\u4ee5\u53ca\u5fae\u6d41\u4f53\u50ac\u5316\u548c\u5206\u79bb\u819c\u5236\u9020\u4e2d\u7684\u5e94\u7528\u3002\u5b9e\u73b0\u591a\u5b54\u6750\u6599\u5728\u6d41\u52a8\u7cfb\u7edf\u4e2d\u8fdb\u884c\u5206\u79bb\u548c\u50ac\u5316\u4e3b\u8981\u6709\u4e09\u79cd\u65b9\u6cd5\uff0c\u5305\u62ec\u591a\u5b54\u6750\u6599\u7684\u586b\u5145\u3001\u67f1\u4e2d\u6574\u6599\u7684\u5f00\u53d1\u4ee5\u53ca\u6bdb\u7ec6\u7ba1\u8868\u9762\u58c1\u4e0a\u591a\u5b54\u6750\u6599\u7684\u6d82\u8986\u3002\u9664\u6b64\u4e4b\u5916\uff0c\u6587\u7ae0\u8fd8\u603b\u7ed3\u4e86\u591a\u5b54\u6750\u6599\u5728\u6bdb\u7ec6\u7ba1\u67f1\u4e2d\u7684\u8272\u8c31\u5206\u79bb\u3001\u8fde\u7eed\u6d41\u52a8\u4f53\u7cfb\u50ac\u5316\u5408\u6210\u3001\u7a7a\u5fc3\u8f7d\u4f53\u591a\u5b54\u819c\u4e2d\u7684\u5e94\u7528\u3002\u8be5\u6210\u679c\u4ee5\u9898\u4e3a\u201dEmerging Porous Materials in Confined Spaces: From Chromatographic Applications to Flow Chemistry<\/b><\/strong>\u201d\u53d1\u8868\u5728Chem. Soc. Rev.<\/b><\/strong>\u4e0a\u3002<\/p>\n \u672c\u6587\u4f5c\u8005\u4f9d\u6b21\u4e3a\u5f20\u5efa\u52c7\u6559\u6388\uff08\u4e2d\u5c71\u5927\u5b66\uff09\uff0c\u9648\u541b\u884c\uff08\u4e2d\u5c71\u5927\u5b6617\u7ea7\u7855\u58eb\u7814\u7a76\u751f\uff09\uff0c\u5f6d\u5347\uff08\u4e2d\u5c71\u5927\u5b6616\u7ea7\u6750\u6599\u5316\u5b66\u672c\u79d1\u751f\uff09\uff0c\u5f6d\u4e66\u541f\uff08\u4e2d\u5c71\u5927\u5b6616\u7ea7\u6750\u6599\u5316\u5b66\u672c\u79d1\u751f\uff09\uff0c\u5f20\u6893\u54f2\uff08\u4e2d\u5c71\u5927\u5b6616\u7ea7\u6750\u6599\u5316\u5b66\u672c\u79d1\u751f\uff09\uff0c\u7ae5\u4e1a\u7fd4\u6559\u6388\uff08\u4e2d\u5c71\u5927\u5b66\uff09\uff0cPhilip W. Miller\u9ad8\u7ea7\u8bb2\u5e08\uff08\u5e1d\u56fd\u7406\u5de5\u5b66\u9662\uff09\uff0c\u4e25\u79c0\u5e73\u6559\u6388\uff08\u6c5f\u5357\u5927\u5b66\uff09\u3002\u901a\u8baf\u4f5c\u8005\u4e3a\u5f20\u5efa\u52c7\u6559\u6388\u548c\u4e25\u79c0\u5e73\u6559\u6388\u3002<\/p>\n \u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/b><\/strong><\/p>\n Figure <\/b><\/strong>1<\/b><\/strong>.<\/b><\/strong>\u51e0\u79cd\u4ee3\u8868\u6027\u7684MOF\u6750\u6599<\/b><\/strong> Figure <\/b><\/strong>2<\/b><\/strong>.<\/b><\/strong>\u591a\u5b54\u6709\u673a\u7b3c\u5b50\u7684\u5206\u5b50\u7ed3\u6784<\/b><\/strong><\/p>\n Scheme1<\/b><\/strong>.<\/b><\/strong>\u51e0\u79cd\u4ee3\u8868COF\u6750\u6599\u7684\u5316\u5b66\u7ed3\u6784<\/b><\/strong> Figure <\/b><\/strong>3<\/b><\/strong>.<\/b><\/strong>\u5fae\u901a\u9053\u548c\u5fae\u6d41\u4f53\u88c5\u7f6e\u5185\u7684\u591a\u5b54\u6750\u6599\uff0c\u7528\u4e8e\u5206\u79bb\u548c\u50ac\u5316<\/b><\/strong> Figure <\/b><\/strong>4<\/b><\/strong>.<\/b><\/strong>\u4e09\u79cd\u6bdb\u7ec6\u7ba1\u67f1\u7684\u793a\u610f\u56fe<\/b><\/strong> (a).\u6bdb\u7ec6\u7ba1\u586b\u5145\u67f1<\/p>\n (b).\u6bdb\u7ec6\u7ba1\u6574\u4f53\u67f1<\/p>\n (c).\u6bdb\u7ec6\u7ba1\u5f00\u53e3\u67f1<\/p>\n Figure <\/b><\/strong>5<\/b><\/strong>.<\/b><\/strong>\u6bdb\u7ec6\u7ba1\u586b\u5145\u67f1\u7684SEM\u8868\u5f81<\/b><\/strong> Figure <\/b><\/strong>6<\/b><\/strong>.<\/b><\/strong>\u901a\u8fc7\u7c89\u672b\u586b\u5145\u5408\u6210\u7684\u591a\u5b54\u6750\u6599\u7684SEM\u8868\u5f81<\/b><\/strong> Figure <\/b><\/strong>7<\/b><\/strong>.<\/b><\/strong>\u6bdb\u7ec6\u7ba1\u6a2a\u622a\u9762\u7684SEM\u8868\u5f81\u4ee5\u53caMn-salen\u4e9a\u80fa\u51dd\u80f6\u7684\u7ed3\u6784\u5f0f<\/b><\/strong> Figure <\/b><\/strong>8<\/b><\/strong>.<\/b><\/strong>\u52a8\u6001\u6d82\u8986\u65b9\u6cd5\u793a\u610f\u56fe<\/b><\/strong><\/p>\n Figure <\/b><\/strong>9<\/b><\/strong>.<\/b><\/strong>MIL-53ht\u53ca\u70f7\u57fa\u82b3\u65cf\u5f02\u6784\u7269\u5ba2\u4f53\u7684\u6676\u4f53\u7ed3\u6784<\/b><\/strong><\/p>\n Figure <\/b><\/strong>10.SiO<\/b><\/u><\/strong>2<\/b><\/sub><\/u><\/strong>\u548cZIF-8@SiO<\/b><\/u><\/strong>2<\/b><\/sub><\/u><\/strong><\/a>\u7684SEM\u8868\u5f81\u53ca\u5176HPLC\u5206\u79bb\u6548\u679c<\/b><\/strong><\/p>\n Figure <\/b><\/strong>11<\/b><\/u><\/strong>.<\/b><\/u><\/strong>\u7528\u4e8eHPLC\u7684TpBD@SiO<\/b><\/u><\/strong>2<\/b><\/sub><\/u><\/strong><\/a>\u5fae\u7403<\/b><\/strong>\u7684\u5408\u6210\u793a\u610f\u56fe<\/b><\/strong><\/p>\n Figure <\/b><\/strong>12<\/b><\/strong>.<\/b><\/strong>\u7845\u80f6\u4e0a\u5171\u4ef7\u4e09\u55ea\u57fa\u9aa8\u67b6\u56fa\u5b9a\u5316\u6d82\u8986\u7684\u5236\u5907\u6d41\u7a0b<\/b><\/strong><\/p>\n Figure <\/b><\/strong>13<\/b><\/strong>.<\/b><\/strong>\u5236\u5907\u7528\u4e8eHPLC\u7684\u805a(TpPa-MA-co-EDMA)\u6574\u4f53\u67f1\u793a\u610f\u56fe<\/b><\/strong><\/p>\n Figure <\/b><\/strong>14<\/b><\/strong>.<\/b><\/strong>ZIF-8\u6d82\u8986\u7684\u6bdb\u7ec6\u7ba1\u7528\u4e8e\u6c14\u76f8\u8272\u8c31\u5206\u79bb\u652f\u5316\u70f7\u70c3\u548c\u76f4\u94fe\u70f7\u70c3\u7684\u8272\u8c31\u56fe<\/b><\/strong><\/p>\n Figure <\/b><\/strong>15<\/b><\/strong>.<\/b><\/strong>\u6d82\u8986\u5728GC\u67f1\u8868\u9762\u7684HKUST-1\u7684SEM\u8868\u5f81\u4ee5\u53ca\u5206\u79bb\u6b63\u620a\u70f7\u548c\u4e8c\u4e59\u919a\u6df7\u5408\u7269\u7684\u8272\u8c31\u56fe<\/b><\/strong><\/p>\n Figure <\/b><\/strong>16<\/b><\/strong>.<\/b><\/strong>(a)\u586b\u5145\u578b\u6bdb\u7ec6\u7ba1\u548c(b)\u5f00\u53e3\u578b\u6bdb\u7ec6\u7ba1\u4e2d\u7684\u7535\u6e17\u6d41<\/b><\/strong><\/p>\n Figure <\/b><\/strong>17<\/b><\/strong>.<\/b><\/strong>MOF-5\u5728\u7194\u878d\u77f3\u82f1\u6bdb\u7ec6\u7ba1\u8868\u9762\u751f\u957f\u8fc7\u7a0b\u7684\u793a\u610f\u56fe<\/b><\/strong><\/p>\n Figure <\/b><\/strong>18<\/b><\/strong>.<\/b><\/strong>COF-LZU1\u5728\u919b\u57fa\u5b98\u80fd\u5316\u6bdb\u7ec6\u7ba1\u5185\u58c1\u4e0a\u751f\u957f\u7684\u793a\u610f\u56fe<\/b><\/strong><\/p>\n Figure <\/b><\/strong>19<\/b><\/strong>.<\/b><\/strong>CTpPa-1\u6d82\u8986\u6bdb\u7ec6\u7ba1\u7684SEM\u8868\u5f81\u4e0e\u5206\u79bb\u6548\u679c<\/b><\/strong><\/p>\n Figure <\/b><\/strong>20<\/b><\/strong>.<\/b><\/strong>[Zn(s-nip)<\/b><\/strong>2<\/b><\/sub><\/strong>]<\/b><\/strong>n<\/b><\/sub><\/strong>\u6d82\u8986\u7684\u6bdb\u7ec6\u7ba1\u67f1\u7684\u5236\u5907\u793a\u610f\u56fe<\/b><\/strong><\/p>\n Figure <\/b><\/strong>21<\/b><\/strong>.<\/b><\/strong>\u7528\u4e8e\u5fae\u53cd\u5e94\u5668\u4e2d\u56fa\u5b9a\u5316\u50ac\u5316\u7684\u591a\u5b54\u6750\u6599\u793a\u610f\u56fe<\/b><\/strong><\/p>\n Figure <\/b><\/strong>22<\/b><\/u><\/strong>.<\/b><\/u><\/strong>Pd@MIL-88B-NH<\/b><\/u><\/strong>2<\/b><\/sub><\/u><\/strong>@nano-SiO<\/b><\/u><\/strong><\/b><\/strong><\/p>\n
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