{"id":16937,"date":"2016-06-04T08:00:19","date_gmt":"2016-06-04T00:00:19","guid":{"rendered":"\/\/m.iemloyee.com\/?p=16937"},"modified":"2016-06-03T14:20:19","modified_gmt":"2016-06-03T06:20:19","slug":"%e5%90%89%e5%a4%a7%e8%a3%98%e5%bc%8f%e7%ba%b6%e6%95%99%e6%8e%88%e7%bb%84jacs%ef%bc%9acof-mof%e5%a4%8d%e5%90%88%e8%86%9c%e7%9a%84%e5%88%b6%e5%a4%87%e5%8f%8a%e5%85%b6%e5%af%b9h2co2%e6%b7%b7%e5%90%88","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=16937","title":{"rendered":"\u5409\u5927\u88d8\u5f0f\u7eb6\u6559\u6388\u7ec4JACS\uff1aCOF-MOF\u590d\u5408\u819c\u7684\u5236\u5907\u53ca\u5176\u5bf9H2\/CO2\u6df7\u5408\u6c14\u4f53\u7684\u9ad8\u6548\u9009\u62e9\u6027\u5206\u79bb"},"content":{"rendered":"

\"JACS0-table-of-contents\"<\/p>\n

\u5bfb\u627e\u65b0\u578b\u819c\u6750\u6599\u5bf9\u4e8e\u5b66\u672f\u754c\u548c\u5de5\u4e1a\u9886\u57df\u6709\u7740\u91cd\u8981\u7684\u610f\u4e49\uff0c\u56e0\u4e3a\u65b0\u578b\u819c\u6750\u6599\u5728\u9009\u62e9\u6027\u5206\u79bb\u6280\u672f\u65b9\u9762\u53d1\u6325\u7740\u81f3\u5173\u91cd\u8981\u7684\u4f5c\u7528\u3002\u76f8\u6bd4\u4e8e\u5176\u4ed6\u5206\u79bb\u65b9\u6cd5\uff0c\u819c\u5206\u79bb\u7684\u4e3b\u8981\u4f18\u70b9\u5728\u4e8e\u5176\u66f4\u9ad8\u7684\u80fd\u91cf\/\u635f\u8017\u6548\u7387\u3002\u8fd1\u5e74\u6765\uff0c\u91d1\u5c5e\u6709\u673a\u6846\u67b6\uff08MOFs\uff09\u819c\u662f\u4e00\u5927\u7814\u7a76\u70ed\u95e8\u3002MOF\u6750\u6599\u5177\u6709\u7ed3\u6784\u591a\u6837\u5316\u3001\u5b54\u5f84\u5c3a\u5bf8\u5747\u5300\u53ef\u63a7\u3001\u5b54\u58c1\u591a\u529f\u80fd\u5316\u3001\u5316\u5b66\u9009\u62e9\u6027\u7b49\u4f18\u70b9\uff0c\u56e0\u6b64\u88ab\u5e7f\u6cdb\u7528\u4e8e\u6c14\u4f53\u3001\u6db2\u4f53\u548c\u79bb\u5b50\u5206\u79bb\u3002<\/strong>\u5171\u4ef7\u6709\u673a\u6846\u67b6\uff08COFs\uff09\u662f\u4e00\u79cd\u7531\u8f7b\u5143\u7d20\uff08C\u3001B\u3001N\u3001O\u3001Si\u7b49\uff09\u5f62\u6210\u5f3a\u5171\u4ef7\u952e\u800c\u6784\u6210\u7684\u4e00\u79cd\u65b0\u578b\u591a\u5b54\u6750\u6599\u3002COF\u6750\u6599\u5177\u6709\u7ed3\u6784\u4f38\u7f29\u6027\u597d\u3001\u8868\u9762\u79ef\u5927\u3001\u5b54\u5f84\u53ef\u8c03\u3001\u5316\u5b66\u7a33\u5b9a\u6027\u9ad8\u53ca\u5bc6\u5ea6\u4f4e\u7b49\u7279\u70b9\uff0c\u88ab\u5e7f\u6cdb\u7528\u4e8e\u6c14\u4f53\u50a8\u5b58\u4e0e\u5206\u79bb\u3001\u50ac\u5316\u3001\u50a8\u80fd\u7b49\u9886\u57df\u3002<\/strong>COF\u4e0eMOF\u590d\u5408\u53ef\u4ee5\u4f53\u73b0COF\u548cMOF\u8fd9\u4e24\u79cd\u4e0d\u540c\u7684\u591a\u5b54\u6750\u6599\u95f4\u7684\u534f\u540c\u4f5c\u7528\uff0c\u5373COF-MOF\u819c\u6bd4\u5355\u4e2a\u819c\u6750\u6599\u5177\u6709\u66f4\u9ad8\u7684\u6c14\u4f53\u5206\u79bb\u9009\u62e9\u6027\u3002<\/span><\/p>\n

CO2\u662f\u4e00\u79cd\u6e29\u5ba4\u6c14\u4f53\uff0c\u4ece\u957f\u8fdc\u6765\u770b\u4f1a\u5bf9\u73af\u5883\u9020\u6210\u6bc1\u706d\u6027\u7684\u540e\u679c\u3002CO2\u7684\u6355\u83b7\u662f\u89e3\u51b3\u8be5\u95ee\u9898\u6700\u76f4\u622a\u4e86\u5f53\u7684\u9014\u5f84\u3002\u6355\u83b7\u78b3\u7684\u5316\u5b66\u53cd\u5e94\u8fc7\u7a0b\u6d89\u53ca\u5230\u4e86\u5408\u6210\u6c14\uff08H2\u548cCO\u7684\u6df7\u5408\u6c14\u4f53\uff09\u4e0e\u6c34\u84b8\u6c14\u7684\u53cd\u5e94\uff08\u751f\u6210H2\u548cCO2\uff09\u3002\u56e0\u6b64\uff0c\u5bf9CO2\u548cH2\u5177\u6709\u9ad8\u6548\u5206\u79bb\u9009\u62e9\u6027\u7684\u805a\u5408\u7269\u8584\u819c\u53ef\u4ee5\u7528\u4e8eCO2\u7684\u6355\u83b7\u3002<\/p>\n

\u5c3d\u7ba1\u4f7f\u7528MOF\u3001COF\u7b49\u591a\u5b54\u6750\u6599\u5728\u819c\u57fa\u6c14\u4f53\u5206\u79bb\u4e0a\u5df2\u53d6\u5f97\u4e86\u4e0d\u5c11\u8fdb\u5c55\uff0c\u4f46\u5236\u5907\u517c\u5177\u9ad8\u9009\u62e9\u6027\u4e0e\u9ad8\u6e17\u900f\u6027\u7684\u819c\u6750\u6599\u4ecd\u662f\u4e00\u5927\u6311\u6218\u3002<\/strong>\u65e9\u524d\u7f57\u4f2f\u900a\uff08L. M. Robeson\uff09\u66fe\u63d0\u51fa\u805a\u5408\u7269\u819c\u7684\u6c14\u4f53\u5206\u79bb\u4e0a\u9650<\/span>\uff0c\u5373\u4f20\u7edf\u8584\u819c\u6c14\u4f53\u5206\u79bb\u4e2d\u6e17\u900f\u7387\u4e0e\u9009\u62e9\u7387\u65e0\u6cd5\u517c\u987e\u800c\u6709\u4e00\u4e0a\u9650\uff0c\u5f88\u96be\u540c\u65f6\u5177\u5907\u9ad8\u6e17\u900f\u6027\u548c\u9ad8\u9009\u62e9\u6027\u3002<\/strong>\u7c7b\u4f3c\u4e8e\u79d1\u5b66\u9886\u57df\u7684\u5176\u4ed6\u4e0a\u9650\uff0c\u7f57\u4f2f\u900a\u4e0a\u9650\u5173\u7cfb\u5f15\u53d1\u4e86\u4e00\u5927\u6279\u8bd5\u56fe\u8d85\u8d8a\u8be5\u4e0a\u9650\u7684\u7814\u7a76\u3002<\/p>\n

\u5409\u6797\u5927\u5b66\u8d32\u817e\u6559\u6388\uff08\u88d8\u5f0f\u7eb6\u6559\u6388\u8bfe\u9898\u7ec4\uff09<\/strong>\u4e0e\u6cd5\u56fd\u56fd\u5bb6\u79d1\u5b66\u7814\u7a76\u4e2d\u5fc3(\u5361\u6602)\u7814\u7a76\u4e3b\u4efb\u74e6\u4f26\u4e01\u00b7\u74e6\u5c14\u5207\u592b\uff08Valentin Valtchev\uff09\u7b49\u4eba\u7684\u7814\u7a76\u56e2\u961f\uff0c\u9996\u6b21\u5c06MOF\u751f\u957f\u5728COF\u4e0a\uff0c\u5236\u5907\u51fa\u4e86\u65b0\u9896\u7684COF-MOF\u590d\u5408\u819c\u3002\u76f8\u5bf9\u4e8e\u5355\u4e2a\u7684MOF\u548cCOF\u6750\u6599\uff0c\u8fd9\u79cdCOF-MOF\u590d\u5408\u819c\u5bf9H2\/CO2\u6df7\u5408\u6c14\u4f53\u5177\u6709\u66f4\u9ad8\u7684\u9009\u62e9\u6027\u5206\u79bb\u6027\u80fd\uff0c\u4e14\u8d85\u8fc7\u4e86\u4ee3\u8868\u6c14\u4f53\u5206\u79bb\u6700\u4f73\u6027\u80fd\u7684\u7f57\u4f2f\u900a\u4e0a\u9650\u3002\u8fd9\u79cd\u4f18\u5f02\u7684\u6027\u80fd\u6e90\u4e8eCOF\u548cMOF\u7684\u5316\u5b66\u7279\u6027\u53ca\u5176\u754c\u9762\u539f\u5b50\u5c42\u95f4\u7684\u76f8\u4e92\u4f5c\u7528\u3002<\/span><\/strong>\u4ee5\u4e0b\u662f\u8be5\u5de5\u4f5c\u56fe\u6587\u89e3\u8bfb\uff1a<\/p>\n

\u56fe\u6587\u89e3\u8bfb<\/strong><\/p>\n

\u3010\u590d\u5408\u819c\u7684\u5236\u5907\u3011<\/strong><\/p>\n

\"JACS1\"<\/p>\n

\u56fe1 COF-MOF\u590d\u5408\u819c\u7684\u5236\u5907\u6d41\u7a0b\u56fe<\/strong><\/p>\n

COF\u819c\u7684\u5236\u5907\u6d41\u7a0b\u5982\u4e0b\uff1a
\n<\/strong>
\n\u591a\u5b54SiO2\u7528\u521a\u7389\u7802\u7eb8\u629b\u5149\u3001\u8d85\u58f0\u6e05\u6d17\u540e\uff0c\u7528\u65e0\u6c34\u4e59\u9187\u6e05\u6d17\u3001\u5e72\u71e5\uff0c\u7136\u540e\u5728SiO2\u7684\u5149\u6ed1\u9762\u6d82\u8986\u4e0a\u8fc7\u9971\u548c\u805a\u82ef\u80fa\uff08PANI\uff09\u6eb6\u6db2\uff08\u7531PANI\u6eb6\u89e3\u5728\u4e8c\u7532\u57fa\u7532\u9170\u80fa\uff08DMF\uff09\u4e2d\u5f97\u5230\uff09\uff0c\u4e4b\u540e\u572870\u2103\u4e0b\u5e72\u71e5\uff0c\u53cd\u590d\u6d82\u62b9-\u5e72\u71e5\u4e09\u6b21\uff0c\u5f97\u5230PANI\u4fee\u9970\u7684SiO2\u5706\u7247\u3002\u5bf9\u82ef\u4e8c\u7532\u919b\u548ctetra-(4-anilyl)-methane\u6eb6\u89e3\u5728\u65e0\u6c341,4-\u4e8c\u6c27\u516d\u73af\u548c\u4e59\u9178\u7684\u6df7\u5408\u6eb6\u6db2\u4e2d\u5145\u5206\u53cd\u5e94\uff0c\u5f97\u5230COF-300\u6bcd\u6db2\uff0c\u7f6e\u4e8e\u805a\u56db\u6c1f\u4e59\u70ef\u886c\u91cc\u7684\u9ad8\u538b\u706d\u83cc\u5668\u4e2d\uff0c\u7136\u540e\u5c06PANI\u4fee\u9970\u7684SiO2\u5706\u7247\u7f6e\u4e8e\u5176\u4e2d100\u2103\u4fdd\u6e293\u5929\u3002\u6700\u540e\u53d6\u51fa\u7528\u65e0\u6c341,4-\u4e8c\u6c27\u516d\u73af\u548c\u65e0\u6c34\u56db\u6c22\u544b\u5583\u6e05\u6d17\u6570\u6b21\u540e\u5728\u5ba4\u6e29\u4e0b\u5e72\u71e5\u5373\u5f97\u5230COF\u819c\u3002<\/p>\n

MOF\u819c\u7684\u5236\u5907\u6d41\u7a0b\u5982\u4e0b\uff1a
\n<\/strong>
\n\uff081\uff09Zn2(bdc)2(dabco)\u819c\uff1a<\/strong>\u516d\u6c34\u785d\u9178\u950c\u3001\u5bf9\u82ef\u4e8c\u7532\u9178\u30011,4-\u4e8c\u6c2e\u6742\u4e8c\u73af[2.2.2]\u8f9b\u70f7\uff08DABCO\uff09\u548c\u4e8c\u7532\u57fa\u7532\u9170\u80fa\uff08DMF\uff09\u6df7\u5408\u5f97\u5230Zn2(bdc)2(dabco)\u6bcd\u6db2\uff0c\u7f6e\u4e8e\u805a\u56db\u6c1f\u4e59\u70ef\u886c\u91cc\u7684\u9ad8\u538b\u706d\u83cc\u5668\u4e2d\u3002\u7136\u540e\u5c06PANI\u4fee\u9970\u7684SiO2\u5706\u7247\u7f6e\u4e8e\u5176\u4e2d120\u2103\u751f\u957f2\u5929\u3002\u7528DMF\u6e05\u6d17\u540e\u5728\u65e0\u6c34\u7532\u9187\u4e2d\u6d78\u6ce1\u4e00\u591c\uff0c\u6700\u540e\u5728\u5ba4\u6e29\u4e0b\u5e72\u71e5\u5f97\u5230\u3002<\/p>\n

\uff082\uff09ZIF-8\u819c\uff1a<\/strong>\u6c2f\u5316\u950c\u30012-\u7532\u57fa\u54aa\u5511\u3001\u7532\u9178\u94a0\u548c\u7532\u9187\u6df7\u5408\u5f97\u5230ZIF-8\u6bcd\u6db2\uff0c\u7f6e\u4e8e\u805a\u56db\u6c1f\u4e59\u70ef\u886c\u91cc\u7684\u9ad8\u538b\u706d\u83cc\u5668\u4e2d\u3002\u7136\u540e\u5c06PANI\u4fee\u9970\u7684SiO2\u5706\u7247\u7f6e\u4e8e\u5176\u4e2d120\u2103\u4fdd\u6e294 h\uff0c\u7528\u7532\u9187\u6e05\u6d17\u540e\u5728\u5ba4\u6e29\u4e0b\u5e72\u71e5\u5f97\u5230\u3002<\/p>\n

COF-MOF\u590d\u5408\u819c\u7684\u5236\u5907\u6d41\u7a0b\u5982\u4e0b\uff1a
\n<\/strong>
\n\uff081\uff09[COF-300]-[Zn2(bdc)2(dabco)]\u590d\u5408\u819c\uff1a<\/strong>\u5c06\u8868\u9762\u751f\u957f\u6709COF-300\u819c\u7684PANI\u4fee\u9970\u7684SiO2\u5706\u7247\u6c34\u5e73\u653e\u7f6e\u4e8e\u542bZn2(bdc)2(dabco)\u6bcd\u6db2\u7684\u9ad8\u538b\u706d\u83cc\u5668\u4e2d\uff0c\u5176\u4f59\u7684\u6b65\u9aa4\u548cZn2(bdc)2(dabco)\u819c\u7684\u5236\u5907\u6d41\u7a0b\u76f8\u540c\u3002<\/p>\n

\uff082\uff09[COF-300]-[ZIF-8]\u590d\u5408\u819c\uff1a<\/strong>\u5c06\u8868\u9762\u751f\u957f\u6709COF-300\u819c\u7684PANI\u4fee\u9970\u7684SiO2\u5706\u7247\u6c34\u5e73\u653e\u7f6e\u4e8e\u542bZIF-8\u6bcd\u6db2\u7684\u9ad8\u538b\u706d\u83cc\u5668\u4e2d\uff0c\u5176\u4f59\u7684\u6b65\u9aa4\u540cZIF-8\u819c\u7684\u5236\u5907\u6d41\u7a0b\u3002<\/p>\n

\u3010\u590d\u5408\u819c\u7684\u5f62\u8c8c\u4e0e\u7ed3\u6784\u8868\u5f81\u3011<\/strong><\/p>\n

\"JACS2-1\"<\/p>\n

\"JACS2-2\"<\/p>\n

\u56fe2 <\/strong>\uff08ABCD\uff09COF-300\u819c\uff1a<\/strong>\uff08A\uff09SEM\u4fef\u89c6\u56fe\uff0c\uff08B\uff09\u5143\u7d20\u6620\u5c04\u56fe\u50cf\uff08\u78b3\uff09\uff0c\uff08C\uff09SEM\u5256\u9762\u56fe\uff0c\uff08D\uff09\u5143\u7d20\u6620\u5c04\u56fe\u50cf\uff08\u7845\uff09\uff1b\uff08EFGH\uff09Zn2(bdc)2(dabco)\u819c\uff1a<\/strong>\uff08E\uff09SEM\u4fef\u89c6\u56fe\uff0c\uff08F\uff09\u5143\u7d20\u6620\u5c04\u56fe\u50cf\uff08\u950c\uff09\uff0c\uff08G\uff09SEM\u5256\u9762\u56fe\uff0c\uff08H\uff09\u5143\u7d20\u6620\u5c04\u56fe\u50cf\uff08\u7845\uff09\uff1b\uff08IJKL\uff09ZIF-8\u819c\uff1a<\/strong>\uff08I\uff09SEM\u4fef\u89c6\u56fe\uff0c\uff08J\uff09\u5143\u7d20\u6620\u5c04\u56fe\u50cf\uff08\u950c\uff09\uff0c\uff08K\uff09SEM\u5256\u9762\u56fe\uff0c\uff08L\uff09\u5143\u7d20\u6620\u5c04\u56fe\u50cf\uff08\u7845\uff09\uff1b\uff08MNOP\uff09[COF-300]-[Zn2(bdc)2(dabco)]\u590d\u5408\u819c\uff1a<\/strong>\uff08M\uff09\u5143\u7d20\u6620\u5c04\u56fe\u50cf\uff08\u950c\uff09\uff0c\uff08N\uff09SEM\u5256\u9762\u56fe\uff0c\uff08O\uff09\u5143\u7d20\u6620\u5c04\u56fe\u50cf\uff08\u7845\uff09\uff0c\uff08P\uff09\u7167\u7247\uff1b\uff08QRST\uff09[COF-300]-[ZIF-8]\u590d\u5408\u819c\uff1a<\/strong>\uff08Q\uff09\u5143\u7d20\u6620\u5c04\u56fe\u50cf\uff08\u950c\uff09\uff0c\uff08R\uff09SEM\u5256\u9762\u56fe\uff0c\uff08S\uff09\u5143\u7d20\u6620\u5c04\u56fe\u50cf\uff08\u7845\uff09\uff0c\uff08T\uff09\u7167\u7247\u3002<\/p>\n

\u56fe2\u4e2d\u7684SEM\u8bf4\u660e\u4e86COF\u3001MOF\u53caCOF-MOF\u590d\u5408\u819c\u7684\u6210\u529f\u5236\u5907\u3002<\/strong>\u590d\u5408\u819c\u7684SEM\u5256\u9762\u56fe\uff08\u56fe2 N\uff0cR\uff09\u5c55\u73b0\u4e86\u5176\u5c3a\u5bf8\u5747\u4e00\u6027\u548cMOF\u4e0eCOF\u4e0d\u540c\u5c42\u7684\u539a\u5ea6\u3002[COF-300]-[Zn2(bdc)2(dabco)]\u590d\u5408\u819c\u7684COF\u5c42\u548cMOF\u5c42\u7684\u539a\u5ea6\u5206\u522b\u4e3a42\u00b5m\u548c55\u00b5m\u3002[COF-300]-[ZIF-8]\u590d\u5408\u819c\u4e2dCOF\u5c42\u548cMOF\u5c42\u7684\u539a\u5ea6\u5206\u522b\u4e3a40\u00b5m\u548c60\u00b5m\u3002<\/p>\n

\u3010\u590d\u5408\u819c\u7684\u6027\u80fd\u6d4b\u8bd5\u4e0e\u8868\u5f81\u3011<\/strong><\/p>\n

\"JACS3\"<\/p>\n

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\"JACS3\"<\/p>\n

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\"JACS5-1\" \"JACS5-2\"<\/p>\n

\u56fe5<\/strong> \uff08A\uff09<\/strong>[COF-300]-[Zn2(bdc)2(dabco)]\u590d\u5408\u819c\u7684TEM\u56fe\u548c\u5feb\u901f\u5085\u7acb\u53f6\u53d8\u6362\uff08FFT\uff09\u5206\u6790\uff08\u5982\u56fe\u4e2da\uff0cb\u6240\u793a\uff09\u3002\u56fe\u4e2d\uff08a\uff09\u662f\u767d\u8272\u533a\u57df\u7684FFT\u5206\u6790\uff0c\uff08b\uff09\u662f\u7ea2\u8272\u533a\u57df\u7684FFT\u5206\u6790\u3002\uff08B\uff09<\/strong>\u7531\u975e\u6676\u6001MOF\u6784\u6210\u7684\u5185\u5c42\u7684\u793a\u610f\u56fe\uff0c\u5b83\u4e0e\u6676\u6001MOF\u6709\u76f8\u4f3c\u7684\u5b54\u5f84\uff0c\u6c14\u4f53\u5145\u6ee1\u5728\u975e\u6676MOF\u4e0eCOF\u7eb3\u7c73\u6676\u4e4b\u95f4\u4ee5\u53caCOF\u4e0eMOF\u6676\u5c42\u754c\u9762\u5904\u3002<\/p>\n

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\u3010\u603b\u7ed3\u3011<\/strong><\/p>\n

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\u88d8\u5f0f\u7eb6\u6559\u6388\u7b80\u4ecb<\/strong><\/p>\n

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\u6587\u732e\u94fe\u63a5\uff1aFabrication of COF-MOF Composite Membranes and Their Highly Selective Separation of H2\/CO2<\/a> \uff082016, J. Am. Chem. Soc., DOI: 10.1021\/jacs.6b03348\uff09<\/p>\n

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