{"id":169106,"date":"2019-03-09T06:30:20","date_gmt":"2019-03-08T22:30:20","guid":{"rendered":"\/\/m.iemloyee.com\/?p=169106"},"modified":"2019-03-08T11:10:50","modified_gmt":"2019-03-08T03:10:50","slug":"nature-communications%ef%bc%9a%e7%a2%b1%e6%80%a7%e5%af%b9%e9%92%99%e9%92%9b%e7%9f%bf%e5%a4%aa%e9%98%b3%e8%83%bd%e7%94%b5%e6%b1%a0%e7%bc%ba%e9%99%b7%e6%80%a7%e8%b4%a8%e5%92%8c%e7%bb%93%e6%99%b6","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=169106","title":{"rendered":"Nature Communications\uff1a\u78b1\u6027\u5bf9\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u7f3a\u9677\u6027\u8d28\u548c\u7ed3\u6676\u52a8\u529b\u5b66\u7684\u5f71\u54cd"},"content":{"rendered":"
\u3010\u5f15\u8a00\u3011<\/b><\/strong><\/p>\n 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\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/b><\/strong><\/p>\n \u8fd1\u65e5\uff0c\u5317\u4eac\u5927\u5b66\u5468\u6b22\u840d\u8bfe\u9898\u7ec4\u53ca\u5408\u4f5c\u8005\uff08\u5317\u4eac\u7406\u5de5\u5927\u5b66\u9648\u68cb\u8bfe\u9898\u7ec4\u3001\u9999\u6e2f\u79d1\u6280\u5927\u5b66\u9ec4\u52c3\u9f99\u8bfe\u9898\u7ec4\u3001\u5357\u4eac\u5de5\u4e1a\u5927\u5b66\u738b\u5efa\u6d66\u8bfe\u9898\u7ec4\u3001\u56fd\u5bb6\u7eb3\u7c73\u4e2d\u5fc3\u5218\u65b0\u98ce\u8bfe\u9898\u7ec4\u3001\u6fb3\u95e8\u5927\u5b66\u90a2\u8d35\u5ddd\u6559\u6388\u3001\u4e2d\u56fd\u79d1\u5b66\u9662\u4e0a\u6d77\u9ad8\u7b49\u7814\u7a76\u9662\u674e\u4e1c\u680b\u7814\u7a76\u5458\u7b49\uff09<\/b><\/strong>\uff0c\u901a\u8fc7\u5728\u524d\u9a71\u6db2\u4e2d\u5f15\u5165\u78b1\u6027\u7269\u79cd\uff0c\u4fc3\u4f7f\u5355\u8d28\u7898\u6742\u8d28\u5728\u4e0d\u540c\u7684\u78b1\u6027\u73af\u5883\u4e0b\u53d1\u751f\u6b67\u5316\u53cd\u5e94\uff0c\u6709\u6548\u7684\u6291\u5236\u548c\u6d88\u9664\u4e86\u524d\u9a71\u6db2\u4e2d\u7684\u5355\u8d28\u7898\u6742\u8d28\u3002\u540c\u65f6\uff0c\u78b1\u6027\u7684\u5f15\u5165\u8fdb\u4e00\u6b65\u5730\u5f71\u54cd\u4e86\u9499\u949b\u77ff\u8584\u819c\u7684\u7ed3\u6676\u52a8\u529b\u5b66\u548c\u7f3a\u9677\u6027\u8d28\uff0c\u5927\u5e45\u5ea6\u63d0\u5347\u4e86\u76f8\u5e94\u7684\u9499\u949b\u77ff\u5149\u4f0f\u5668\u4ef6\u7684\u5f00\u8def\u7535\u538b\u548c\u5149\u7535\u8f6c\u5316\u6548\u7387\u3002\u8be5\u5de5\u4f5c\u6df1\u5165\u7cfb\u7edf\u5730\u7814\u7a76\u4e86\u4e0d\u540c\u78b1\u6027\u5f3a\u5f31\u5bf9\u524d\u9a71\u6db2\u4e2d\u7898\u5355\u8d28\u7684\u6b67\u5316\u53cd\u5e94\uff08\u78b1\u6027\u4ecb\u8d28\u53ef\u4f7f\u5927\u90e8\u5206\u96f6\u4ef7\u7898\u7f3a\u9677\u8fd8\u539f\u6210\u7898\u79bb\u5b50\uff09\u3001\u6210\u819c\u8fc7\u7a0b\u4e2d\u9ec4\u76f8\u9ed1\u76f8\u7684\u7ed3\u6676\u52a8\u529b\u5b66\uff08\u5f31\u78b1\u6027\u4ecb\u8d28\u6709\u5229\u4e8e\u5149\u6d3b\u6027\u76f8\u9ed1\u76f8\u7684\u5f62\u6210\uff0c\u800c\u5f3a\u78b1\u6027\u4ecb\u8d28\u5219\u6291\u5236\u5149\u6d3b\u6027\u76f8\u9ed1\u76f8\u5f62\u6210\uff09\u3001\u9499\u949b\u77ff\u8584\u819c\u4e2d\u7f3a\u9677\u6001\u5bc6\u5ea6\u7684\u5f71\u54cd\u3002\u540c\u65f6\uff0c\u4ee5\u4e59\u9178\u7532\u8112\u4f5c\u4e3a\u4e00\u79cd\u201c\u65e0\u6b8b\u7559\u201d\u7684\u5f31\u78b1\u6027\u7269\u8d28\u4e3a\u4f8b\uff0c\u53ef\u4ee5\u6709\u6548\u5730\u8c03\u63a7\u6df7\u5364\u9499\u949b\u77ff(FA,MA,Cs)Pb(I,Br)3<\/sub>\u524d\u9a71\u4f53\u4e2d\u9633\u79bb\u5b50\u7684\u5316\u5b66\u8ba1\u91cf\u6bd4\uff0c\u540c\u65f6\u901a\u8fc7\u6d88\u9664\u524d\u9a71\u6db2\u4e2d\u7684\u7898\u5355\u8d28\uff0c\u5927\u5e45\u964d\u4f4e\u5176\u8584\u819c\u4e2d\u6df1\u5c42\u7f3a\u9677\u7684\u5bc6\u5ea6\u3002\u636e\u6b64\uff0c\u8be5\u8bfe\u9898\u7ec4\u6210\u529f\u5236\u5907\u4e86\u7ecf\u7f8e\u56fdNewport\u8ba4\u8bc1\u768420.87%\u6548\u7387\u7684\u6df7\u5364\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\uff0c\u540c\u65f6\uff0c\u5f00\u8def\u7535\u538b\u635f\u5931\u4e5f\u964d\u4f4e\u81f3413 mV\uff0c\u4e3a\u5e73\u9762\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u4e2d\u8ba4\u8bc1\u503c\u6700\u5c0f\u7684\u5668\u4ef6\u4e4b\u4e00\u3002\u8be5\u6210\u679c\u4ee5\u201cImpacts of Alkaline on the Defects Property and Crystallization Kinetics in Perovskite Solar Cells<\/b><\/strong>\u201d\u4e3a\u9898\u53d1\u8868\u5728Nature Communications<\/b><\/strong>\u4e0a\u3002<\/p>\n \u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/b><\/strong><\/p>\n Fig. 1: \u78b1\u6027\u6dfb\u52a0\u5242\u6291\u5236\u524d\u9a71\u6db2\u4e2d\u7684\u5355\u8d28\u7898\u6742\u8d28<\/p>\n \u78b1\u6027\u6dfb\u52a0\u5242\u6291\u5236\u524d\u9a71\u6db2\u4e2d\u7684\u5355\u8d28\u7898\u6742\u8d28\u3002\u4e0d\u540c\u91cf\u7684 (a) FAAc,\u00a0(b) CH3<\/sub>COONa,\u00a0(c) NaHCO3<\/sub>,\u00a0(d) NaOH \u548c\u00a0(e) KOH\u4e59\u9187\u6eb6\u6db2\u6dfb\u52a0\u7684\u5364\u5316\u7269\u6eb6\u6db2\u7684\u7d2b\u5916\u53ef\u89c1\u5438\u6536\u5149\u8c31\u3002(f)\u00a0\u4e0d\u540c\u6dfb\u52a0\u5242\u5bf9\u5364\u5316\u7269\u6eb6\u6db2\u7684\u5438\u5149\u5ea6\u548c\u7528\u91cf\u7684\u5173\u7cfb\u3002<\/p>\n Fig. 2: \u9499\u949b\u77ff\u5f62\u8c8c\u3001\u76f8\u6001\u3001\u8f7d\u6d41\u5b50\u5bff\u547d\u5206\u6790<\/p>\n \u9499\u949b\u77ff\u5f62\u8c8c\u3001\u76f8\u6001\u3001\u8f7d\u6d41\u5b50\u5bff\u547d\u5206\u6790\u3002\u4e0d\u540c\u78b1\u6027\u524d\u9a71\u6db2\u5236\u5907\u7684\u9499\u949b\u77ff\u8584\u819c\u7684SEM\u56fe\u00a0(a) Reference, (b) FAAc, (c) CH3<\/sub>COONa \u548c\u00a0(d)\u00a0NaOH\u3002(e) \u4e0d\u540c\u78b1\u6027\u524d\u9a71\u6db2\u5236\u5907\u7684\u9499\u949b\u77ff\u8584\u819c\u7684XRD\u56fe\u3002(f) \u4e0d\u540c\u91cfMA\/\u4e59\u9187\u6dfb\u52a0\u7684\u9499\u949b\u77ff\u8584\u819c\u7684XRD\u56fe\u3002(g) \u4e0d\u540c\u78b1\u6027\u524d\u9a71\u6db2\u5236\u5907\u7684\u9499\u949b\u77ff\u8584\u819c\u7684\u65f6\u95f4\u5206\u8fa8\u5149\u81f4\u53d1\u5149\u5149\u8c31\u3002<\/p>\n Fig. 3: \u9499\u949b\u77ff\u8584\u819c\u7684\u7ed3\u6676\u52a8\u529b\u5b66\u8c03\u63a7<\/p>\n \u9499\u949b\u77ff\u8584\u819c\u7684\u7ed3\u6676\u52a8\u529b\u5b66\u8c03\u63a7\u3002\u4e0d\u540c\u78b1\u6027\u524d\u9a71\u6db2\u5236\u5907\u7684\u672a\u9000\u706b\u9499\u949b\u77ff\u8584\u819c\u7684\u7d2b\u5916\u53ef\u89c1\u5438\u6536\u5149\u8c31\u3002(b) \u5f31\u78b1\u6027\u6216\u00a0(c) \u5f3a\u78b1\u6027\u524d\u9a71\u6db2\u5236\u5907\u7684\u672a\u9000\u706b\u9499\u949b\u77ff\u8584\u819c\u7684\u539f\u4f4d\u5438\u6536\u6d4b\u91cf\u3002(d) \u78b1\u6027\u5bf9\u9499\u949b\u77ff\u8584\u819c\u7ed3\u6676\u52a8\u529b\u5b66\u5f71\u54cd\u7684\u793a\u610f\u56fe\u3002(e) \u9ec4\u76f8\u548c\u9ed1\u76f8\u9499\u949b\u77ff\u6d3b\u5316\u80fd\u4e0e\u6c22\u6c27\u6839\u79bb\u5b50\u6d53\u5ea6\u95f4\u7684\u4f9d\u8d56\u6027\u8ba1\u7b97\u3002<\/p>\n Fig. 4: \u5f31\u78b1\u6027\u964d\u4f4e\u9499\u949b\u77ff\u8584\u819c\u7f3a\u9677\u6001\u5bc6\u5ea6<\/p>\n \u5f31\u78b1\u6027\u964d\u4f4e\u9499\u949b\u77ff\u8584\u819c\u7f3a\u9677\u6001\u5bc6\u5ea6\u3002(a) PVSK\u548c\u00a0(b) PVSK-FA\u8584\u819c\u7684\u53d8\u6e29PL\u5149\u8c31\u3002(c) \u76f8\u5e94\u7684\u4e8c\u7ef4\u53d8\u6e29PL\u5149\u8c31\u3002(d) PVSK\u548c\u00a0(b) PVSK-FA\u8584\u819c\u7684PL\u91cf\u5b50\u6548\u7387\u3002(e) PVSK\u548c\u00a0(f) PVSK-FA\u5668\u4ef6\u7684\u70ed\u5bfc\u7eb3\u5149\u8c31\u3002\u76f8\u5e94\u7684\u00a0(g) \u7279\u5f81\u9891\u7387\u8c31\u56fe\u548c (g) \u7f3a\u9677\u6001\u5bc6\u5ea6\u8c31\u56fe\u3002<\/p>\n Fig. 5: \u5f31\u78b1\u6027\u63d0\u9ad8\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u5149\u4f0f\u6027\u80fd<\/p>\n \u592a\u9633\u80fd\u7535\u6c60\u5149\u4f0f\u6027\u80fd\u3002(a) PVSK\u548cPVSK-FA\u5668\u4ef6\u7684\u7535\u6d41-\u7535\u538b\u66f2\u7ebf\u3002(b) \u5de6\u56fe\uff1aPVSK\u548cPVSK-FA\u8584\u819c\u7684\u5438\u6536\u548cPL\u5149\u8c31\uff1b\u53f3\u56fe\uff1aPVSK\u548cPVSK-FA\u5668\u4ef6\u5f00\u8def\u7535\u538b\u7edf\u8ba1\u76f4\u65b9\u56fe\u3002(c) PVSK-FA\u5668\u4ef6\u7684\u6b63\u53cd\u626b\u3002(d)\u00a0PVSK-FA\u5668\u4ef6\u7684\u7a33\u6001\u7535\u6d41\u5bc6\u5ea6\u548c\u6548\u7387\u3002PVSK\u548cPVSK-FA\u5668\u4ef6\u7684\u00a0(e) \u77ac\u6001\u5149\u7535\u538b\u8870\u51cf\u66f2\u7ebf\u548c\u00a0(f) \u53d8\u5149\u5f3a\u5f00\u8def\u7535\u538b\u66f2\u7ebf\u3002<\/p>\n \u3010\u603b\u7ed3\u3011<\/b><\/strong><\/p>\n \u8be5\u7814\u7a76\u63d0\u51fa\u4e86\u4e00\u79cd\u5728\u78b1\u6027\u73af\u5883\u4e0b\u901a\u8fc7\u7898\u6b67\u5316\u53cd\u5e94\u6709\u6548\u6291\u5236\u5355\u8d28\u7898\u6742\u8d28\u548c\u64cd\u7eb5\u5316\u5b66\u8ba1\u91cf\u7684\u666e\u9002\u53ef\u9760\u7684\u624b\u6bb5\uff0c\u63ed\u793a\u4e86\u524d\u9a71\u6db2\u7684\u78b1\u6027\u662f\u5f71\u54cd\u9499\u949b\u77ff\u8584\u819c\u7ed3\u6676\u52a8\u529b\u5b66\u548c\u5149\u7535\u5b66\u6027\u80fd\u7684\u5173\u952e\u53c2\u6570\uff0c\u6df1\u5165\u7cfb\u7edf\u5730\u7814\u7a76\u4e86\u4e0d\u540c\u78b1\u6027\u5f3a\u5f31\u5bf9\u524d\u9a71\u6db2\u4e2d\u7898\u6b67\u5316\u53cd\u5e94\u3001\u6210\u819c\u8fc7\u7a0b\u4e2d\u9ec4\u76f8\u9ed1\u76f8\u7684\u7ed3\u6676\u52a8\u529b\u5b66\u3001\u9499\u949b\u77ff\u8584\u819c\u4e2d\u7f3a\u9677\u6001\u5bc6\u5ea6\u7684\u5f71\u54cd\u3002\u540c\u65f6\uff0c\u7531\u7532\u8112\u9633\u79bb\u5b50\u7ec4\u6210\u7684\u918b\u9178\u7532\u8112\u4f5c\u4e3a\u4e00\u79cd\u201c\u65e0\u6b8b\u7559\u201d\u7684\u5f31\u78b1\u6027\u7269\u8d28\uff0c\u53ef\u4ee5\u6709\u6548\u5730\u6291\u5236\u6df7\u5364\u9499\u949b\u77ff(FA,MA,Cs)Pb(I,Br)3<\/sub>\u4e2d\u7684\u6df1\u80fd\u7ea7\u7f3a\u9677\u6001\u5bc6\u5ea6\uff0c\u5927\u5e45\u5ea6\u63d0\u9ad8\u4e86\u6df7\u5364\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u7684\u5f00\u8def\u7535\u538b\u548c\u5149\u7535\u8f6c\u5316\u6548\u7387\u3002\u5728\u6b63\u53cd\u626b\u5e73\u5747\u8ba4\u8bc1\u6548\u7387\u4e3a20.87%\u7684\u5e73\u9762\u5f02\u8d28\u7ed3\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u4e2d\uff0c\u5b9e\u73b0\u4e86\u4ec5\u4ec5413 mV\u7684\u5f00\u8def\u7535\u538b\u635f\u5931\u3002\u8fd9\u4e9b\u53d1\u73b0\u63ed\u793a\u4e86\u9499\u949b\u77ff\u8584\u819c\uff0c\u7279\u522b\u662f\u7898\u57fa\u9499\u949b\u77ff\u4e2d\u524d\u9a71\u6db2\u5316\u5b66\u4e0e\u6df1\u80fd\u7ea7\u7f3a\u9677\u884c\u4e3a\u4e4b\u95f4\u7684\u5173\u7cfb\uff0c\u4e3a\u4e0b\u4e00\u4ee3\u9ad8\u6027\u80fd\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u7684\u8bbe\u8ba1\u63d0\u4f9b\u4e86\u6709\u529b\u7684\u6307\u5bfc\u3002<\/p>\n \u6587\u732e\u5f15\u7528\u4e0e\u94fe\u63a5<\/b><\/strong><\/p>\n Impacts of alkaline on the defects property and crystallization kinetics in perovskite solar cells. Nat Commun 10, 1112(2019). DOI: 10.1038\/s41467-019-09093-1<\/p>\n https:\/\/www.nature.com\/articles\/s41467-019-09093-1<\/u><\/a><\/p>\n \u56e2\u961f\u4ecb\u7ecd<\/b><\/strong><\/p>\n \u5468\u6b22\u840d\uff0c2010\u5e74\u535a\u58eb\u6bd5\u4e1a\u4e8e\u5317\u4eac\u5927\u5b66\u5316\u5b66\u4e0e\u5206\u5b50\u5de5\u7a0b\u5b66\u9662\uff0c\u968f\u540e\u4ee5\u535a\u58eb\u540e\u8eab\u4efd\u5728\u52a0\u5dde\u5927\u5b66\u6d1b\u6749\u77f6\u5206\u6821(UCLA)\u6750\u6599\u79d1\u5b66\u4e0e\u5de5\u7a0b\u7cfb\u4ece\u4e8b\u8584\u819c\u592a\u9633\u80fd\u7535\u6c60\u7814\u7a76\u5de5\u4f5c\u3002\u7b2c\u5341\u4e00\u6279\u201c\u9752\u5e74\u5343\u4eba\u8ba1\u5212\u201d\u5165\u9009\u8005\u30022015\u5e746\u6708\u52a0\u5165\u5317\u4eac\u5927\u5b66\u5de5\u5b66\u9662\u3002\u672c\u4eba\u957f\u671f\u4ece\u4e8b\u65e0\u673a\u6750\u6599\uff0c\u4ee5\u53ca\u65e0\u673a\u6709\u673a\u6742\u5316\u6750\u6599\u7684\u53ef\u63a7\u5408\u6210\uff0c\u8584\u819c\u751f\u957f\u4ee5\u53ca\u5149\u7535\u5668\u4ef6\u6784\u7b51\u7b49\u7814\u7a76\uff0c\u5177\u4f53\u5305\u62ec\u592a\u9633\u80fd\u7535\u6c60\u3001\u53d1\u5149\u4e8c\u6781\u7ba1\u3001\u63a2\u6d4b\u5668\u7b49\u5404\u7c7b\u65b0\u578b\u5149\u7535\u529f\u80fd\u5316\u5668\u4ef6\uff0c\u5c24\u5176\u662f\u65b0\u578b\u7eb3\u7c73\u590d\u5408\u7ed3\u6784\u6784\u7b51\u3001\u7eb3\u7c73\u7ed3\u6784\u52a0\u5de5\u3001\u5149\u7535\u6750\u6599\u5236\u5907\u3001\u8584\u819c\u592a\u9633\u80fd\u7535\u6c60\u7684\u5236\u5907\u53ca\u5de5\u827a\u5f00\u53d1\u7b49\u4ea4\u53c9\u524d\u6cbf\u9879\u76ee\u3002\u8fc4\u4eca\u53d1\u8868\u8bba\u6587100\u4f59\u7bc7\uff0c\u5f15\u7528\u8d85\u8fc714000\u6b21\uff0c\u5305\u62ecScience\u3001Nature Communications\u3001Journal of the American Chemical Society\u3001Nano Letters\u3001Advanced Materials\u7b49\u3002\u8bfe\u9898\u7ec4\u957f\u671f\u62db\u8058\u535a\u58eb\u540e\u548c\u535a\u58eb\u3001\u7855\u58eb\u7814\u7a76\u751f\u53ca\u8054\u5408\u57f9\u517b\u5b66\u751f\u3002<\/p>\n \u8bfe\u9898\u7ec4\u8fd1\u671f\u6587\u7ae0\u5c55\u793a<\/b><\/strong><\/p>\n \u94fe\u63a51\u3001Science\u62a5\u9053\u5317\u4eac\u5927\u5b66\u5468\u6b22\u840d\u7ec4\u3001\u4e25\u7eaf\u534e\u7ec4\u53ca\u5408\u4f5c\u8005\u5728\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u7a33\u5b9a\u6027\u7814\u7a76\u4e0a\u7684\u91cd\u8981\u8fdb\u5c55\u3002<\/p>\n http:\/\/www.coe.pku.edu.cn\/xzky\/kyxx\/kyxw\/911967.htm<\/u><\/a>\u3002<\/p>\n \u94fe\u63a52\u3001\u5317\u5927\u5468\u6b22\u840d\u56e2\u961f&\u5317\u7406\u5de5\u9648\u68cb\u56e2\u961f&\u4e0a\u6d77\u5149\u6e90\u9ad8\u5174\u5b87\u56e2\u961fnature\u5b50\u520a\uff1a\u57fa\u4e8e\u9633\u79bb\u5b50\u7ea7\u8054\u63ba\u6742\u8c03\u63a7\u9499\u949b\u77ff\u591a\u6676\u8584\u819c\u6676\u9762\u53d6\u5411\u3002<\/p>\n https:\/\/mp.weixin.qq.com\/s\/lYd3v9YZplCK9pMTfngvKw<\/u><\/a>\u3002<\/p>\n \u94fe\u63a53\u3001Nature Communications\uff1a\u68af\u5ea6\u5e94\u53d8\u53ca\u5176\u5bf9\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u4e2d\u8f7d\u6d41\u5b50\u52a8\u529b\u5b66\u7684\u8c03\u63a7\u3002<\/p>\n https:\/\/mp.weixin.qq.com\/s\/KdubOrs8N5l0lUUkyooU-A<\/u><\/a>\u3002<\/p>\n \u94fe\u63a54\u3001\u5317\u5927\u5468\u6b22\u840d\u8bfe\u9898\u7ec4JACS\uff1a\u63a2\u7a76\u9ad8\u6027\u80fd\u51c6\u4e8c\u7ef4\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u7684\u7ed3\u6676\u52a8\u529b\u5b66<\/p>\n<\/p>\n
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