{"id":168817,"date":"2019-03-06T06:31:42","date_gmt":"2019-03-05T22:31:42","guid":{"rendered":"\/\/m.iemloyee.com\/?p=168817"},"modified":"2019-03-05T17:34:17","modified_gmt":"2019-03-05T09:34:17","slug":"%e5%a4%8d%e6%97%a6%e5%a4%a7%e5%ad%a6%e9%82%93%e5%8b%87%e8%be%89%e6%95%99%e6%8e%88%e7%ad%89acc-chem-res-%e5%af%8c%e5%90%absp2-%e6%9d%82%e5%8c%96%e7%a2%b3%e7%9a%84%e5%b5%8c%e6%ae%b5%e5%85%b1","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=168817","title":{"rendered":"\u590d\u65e6\u5927\u5b66\u9093\u52c7\u8f89\u6559\u6388\u7b49Acc. Chem. Res.: \u5bcc\u542bsp2-\u6742\u5316\u78b3\u7684\u5d4c\u6bb5\u5171\u805a\u7269\u5bfc\u5411\u5408\u6210\u4ecb\u5b54\u91d1\u5c5e\u6c27\u5316\u7269\u534a\u5bfc\u4f53\u4f20\u611f\u5668\u6750\u6599"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n

\u534a\u5bfc\u4f53\u91d1\u5c5e\u6c27\u5316\u7269\u5177\u6709\u72ec\u7279\u7684\u7535\u5b50\u7ed3\u6784\u3001\u53ef\u8c03\u8282\u7684\u80fd\u5e26\u5bbd\u5ea6\u53ca\u534a\u5bfc\u4f53\u8868\/\u754c\u9762\u7279\u6027\uff0c\u56e0\u6b64\u5728\u975e\u5747\u76f8\u50ac\u5316\u3001\u6c14\u4f53\u4f20\u611f\u5668\u3001\u80fd\u91cf\u50a8\u5b58\u4e0e\u8f6c\u5316\u7b49\u9886\u57df\u5f97\u5230\u5e7f\u6cdb\u5e94\u7528\u3002\u5982\u4f55\u521b\u5236\u5177\u6709\u9ad8\u6bd4\u8868\u9762\u79ef\u3001\u4e30\u5bcc\u5b54\u9699\u7387\u3001\u826f\u597d\u7535\u5b50\u4f20\u8f93\u6548\u7387\u548c\u5faa\u73af\u4f7f\u7528\u6027\u7684\u91d1\u5c5e\u6c27\u5316\u7269\u6750\u6599\u662f\u7814\u7a76\u8005\u666e\u904d\u5173\u5207\u7684\u5171\u540c\u95ee\u9898\u3002\u57fa\u4e8e\u8d85\u5206\u5b50\u8f6f\u6a21\u677f\u7684\u201c\u81ea\u4e0b\u800c\u4e0a\uff08bottom-up\uff09\u201d\u5316\u5b66\u5408\u6210\u9014\u5f84\u53ef\u4ee5\u521b\u9020\u5177\u6709\u5de8\u5927\u5b54\u9699\u7387\u7684\u7eb3\u7c73\u5b54\u6750\u6599\uff0c\u5305\u62ec\u5b54\u5f84\u4e3a2-50 nm\u7684\u6709\u5e8f\u4ecb\u5b54\u6750\u6599\u3002\u65e9\u671f\uff0c\u7814\u7a76\u4eba\u5458\u5229\u7528\u5546\u4e1a\u5316\u7684\u805a\u919a\u7c7b\u3001\u5b63\u94f5\u76d0\u7c7b\u7b49\u4f20\u7edf\u8f6f\u6a21\u677f\u5242\uff0c\u5408\u6210\u4e86\u4e00\u7cfb\u5217\u6709\u5e8f\u4ecb\u5b54\u6750\u6599\uff0c\u4ee5\u4e8c\u6c27\u5316\u7845\u57fa\u548c\u78b3\u57fa\u6750\u6599\u4e3a\u4e3b\u3002\u7136\u800c\uff0c\u8fd9\u4e9b\u4f20\u7edf\u8f6f\u6a21\u677f\u5242\u7684\u94fe\u6bb5\u7ec4\u6210\u5355\u4e00\uff0c\u5206\u5b50\u91cf\u4f4e\uff0c\u4e14\u70ed\u7a33\u5b9a\u6027\u5dee\uff0c\u4ee5\u5b83\u4eec\u4e3a\u8f6f\u6a21\u677f\u5242\uff0c\u96be\u4ee5\u5408\u6210\u51fa\u5177\u6709\u6d3b\u6027\u9ad8\u3001\u7ed3\u6784\u7a33\u5b9a\u7684\u529f\u80fd\u6027\u4ecb\u5b54\u91d1\u5c5e\u6c27\u5316\u7269\u534a\u5bfc\u4f53\u6750\u6599\u3002\u7531\u4e8e\u542bsp2<\/sup>\u6742\u5316\u78b3\u7684\u9ad8\u5206\u5b50\u805a\u5408\u7269\u5177\u6709\u76f8\u5bf9\u8f83\u597d\u7684\u70ed\u7a33\u5b9a\u6027\u548c\u8f83\u9ad8\u7684\u88c2\u89e3\u6b8b\u70ad\u7387\uff0c\u4ee5\u5bcc\u542bsp2<\/sup>\u6742\u5316\u78b3\u7684\u5d4c\u6bb5\u5171\u805a\u7269\u4f5c\u4e3a\u8f6f\u6a21\u677f\u53ef\u4ee5\u89e3\u51b3\u4e0a\u8ff0\u96be\u9898\uff0c\u5728\u5408\u6210\u9ad8\u6027\u80fd\u4ecb\u5b54\u91d1\u5c5e\u6c27\u5316\u7269\u534a\u5bfc\u4f53\u6750\u6599\u65b9\u9762\u5177\u6709\u72ec\u7279\u7684\u4f18\u52bf\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u590d\u65e6<\/b><\/strong>\u5927\u5b66\u9093\u52c7\u8f89<\/b><\/strong>\u6559\u6388\uff08\u901a\u8baf<\/b><\/strong>\u4f5c\u8005<\/b><\/strong>\uff09<\/b><\/strong>\u7b49\u5728Accounts of Chemical Research<\/b><\/strong>\u671f\u520a\u4e0a\u5728\u7ebf\u53d1\u8868\u4e86\u9898\u4e3a\u201csp<\/b><\/strong>2<\/b><\/sup><\/strong>-Hybridized Carbon-Containing Block Copolymer Templated Synthesis of Mesoporous Semiconducting Metal Oxides with Excellent Gas Sensing Property<\/b><\/strong>\u201d\u7684\u7efc\u8ff0\u3002\u5168\u6587\u7cfb\u7edf\u5730\u603b\u7ed3\u4e86\u8bfe\u9898\u7ec4\u5728sp2<\/sup>\u6742\u5316\u78b3\u5d4c\u6bb5\u5171\u805a\u7269\u5bfc\u5411\u5408\u6210\u6709\u5e8f\u4ecb\u5b54\u91d1\u5c5e\u6c27\u5316\u7269\u6c14\u654f\u4f20\u611f\u6750\u6599\u65b9\u9762\u7684\u5de5\u4f5c\uff0c\u9610\u8ff0\u4e86\u5728\u5408\u6210\u8fc7\u7a0b\u4e2dsp2<\/sup>\u6742\u5316\u78b3\u5d4c\u6bb5\u5171\u805a\u7269\u4e0e\u524d\u9a71\u4f53\u4e4b\u95f4\u7684\u4f5c\u7528\u5f62\u5f0f\u548c\u7ec4\u88c5\u884c\u4e3a\uff08\u5982\u4e0b\u56fe\uff09\uff0c\u5e76\u5bf9\u8be5\u9886\u57df\u4eca\u540e\u7684\u53d1\u5c55\u65b9\u5411\u8fdb\u884c\u4e86\u63a2\u8ba8\u4e0e\u5c55\u671b\uff0c\u7b2c\u4e00\u4f5c\u8005\u4e3a\u590d\u65e6\u5927\u5b662017\u7ea7\u535a\u58eb\u7814\u7a76\u751f\u90b9\u4e49\u51ac\uff0c\u901a\u8baf\u4f5c\u8005\u4e3a\u9093\u52c7\u8f89\u6559\u6388\u3002<\/p>\n

\"\"<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n

\u5728\u672c\u7efc\u8ff0\u4e2d\uff0c\u4f5c\u8005\u9996\u5148\u5bf9\u6bd4\u5f52\u7eb3\u4e86\u4f20\u7edf\u8f6f\u6a21\u677f\u5242\u4e0esp2<\/sup>\u6742\u5316\u78b3\u5d4c\u6bb5\u5171\u805a\u7269\u7684\u7ed3\u6784\u3001\u6027\u80fd\u5dee\u5f02\uff0c\u7b80\u8981\u4ecb\u7ecd\u4e86\u5229\u7528\u539f\u5b50\u8f6c\u79fb\u81ea\u7531\u57fa\u805a\u5408\u6280\u672f\uff08ATRP\uff09\u5408\u6210sp2<\/sup>\u6742\u5316\u78b3\u5d4c\u6bb5\u5171\u805a\u7269\u7684\u65b9\u6cd5\u3002\u968f\u540e\uff0c\u8be6\u7ec6\u4ecb\u7ecd\u4e86\u8bfe\u9898\u7ec4\u5229\u7528\u81ea\u4e3b\u5408\u6210\u7684sp2<\/sup>\u6742\u5316\u78b3\u5d4c\u6bb5\u5171\u805a\u7269\u5bfc\u5411\u5408\u6210\u6709\u5e8f\u4ecb\u5b54\u91d1\u5c5e\u6c27\u5316\u7269\u534a\u5bfc\u4f53\u7684\u7b56\u7565\u3002\u7b56\u7565<\/b><\/strong>\u4e00<\/b><\/strong>\u662f\u91c7\u7528\u76f4\u63a5\u754c\u9762\u5171\u7ec4\u88c5\u7b56\u7565\uff0c\u901a\u8fc7\u6eb6\u5242\u6325\u53d1\u8bf1\u5bfc\u5171\u7ec4\u88c5\u6280\u672f\uff0c\u968f\u7740\u6325\u53d1\u6027\u6eb6\u5242\u6d53\u5ea6\u7684\u9010\u6e10\u964d\u4f4e\uff0c\u4eb2\u6c34\u7684\u9ad8\u5206\u5b50\u5d4c\u6bb5\uff08\u5982PEO\uff09\u80fd\u591f\u4e0e\u91d1\u5c5e\u524d\u9a71\u4f53\u7ed3\u5408\uff0c\u4ee5\u6c22\u952e\u7684\u5f62\u5f0f\u8bf1\u5bfc\u758f\u6c34\u5d4c\u6bb5\uff08\u5982PI\uff09\u5f62\u6210\u7403\u5f62\u80f6\u675f\u5806\u79ef\u9aa8\u67b6\uff0c\u4ece\u800c\u5408\u6210\u67d0\u4e9b\u7279\u5b9a\u7684\u6709\u5e8f\u4ecb\u5b54\u91d1\u5c5e\u6c27\u5316\u7269\uff08\u5982WO3<\/sub>\u3001In2<\/sub>O3<\/sub>\u3001SnO2<\/sub>\u3001TiO2<\/sub>\u7b49\uff09\u3002<\/p>\n

\u56fe1<\/b><\/strong>\u00a0\u00a0<\/b><\/strong>\u76f4\u63a5<\/b><\/strong>\u754c\u9762\u5171\u7ec4\u88c5<\/b><\/strong>\u7b56\u7565<\/b><\/strong>\u5408\u6210<\/b><\/strong>\u4ecb\u5b54\u6676\u5316<\/b><\/strong>\u91d1\u5c5e\u6c27\u5316\u7269<\/b><\/strong><\/p>\n

\"\"<\/p>\n

\uff08a\uff09sp2<\/sup>\u6742\u5316\u78b3\u5d4c\u6bb5\u5171\u805a\u7269\u5bfc\u5411\u5408\u6210\u6709\u5e8f\u4ecb\u5b54\u6676\u5316WO3<\/sub>;<\/p>\n

\uff08b\uff09\u6709\u5e8f\u4ecb\u5b54\u6676\u5316WO3<\/sub>\u7684XRD\u56fe\u8c31\uff1b<\/p>\n

\uff08c\uff09\u6709\u5e8f\u4ecb\u5b54\u6676\u5316WO3<\/sub>\u7684FESEM\u56fe\uff1aa)\u6cbf\u8868\u9762\uff1bb)\u6cbf\u622a\u9762\uff1bTEM\u56fe\uff1ac)\u6cbf[110]\u6676\u9762\uff1bd)\u6cbf[100]\u6676\u9762\uff1be)\u6cbf[211]\u6676\u9762\uff1bf)HRTEM\u56fe\uff1b<\/p>\n

\uff08d\uff09\u6709\u5e8f\u4ecb\u5b54\u6676\u5316WO3<\/sub>\u7684SAXS\u56fe\uff1ba)as-made\u6837\u54c1\uff1bb)500 \u00b0C\u7a7a\u6c14\u7145\u70e7\u6837\u54c1\u3002<\/p>\n

\u7136\u800c\uff0c\u7531\u4e8e\u91d1\u5c5e\u524d\u9a71\u4f53\u4e0esp2<\/sup>\u6742\u5316\u78b3\u5d4c\u6bb5\u5171\u805a\u7269\u4e4b\u95f4\u8f83\u5f31\u7684\u76f8\u4e92\u4f5c\u7528\u53ca\u91d1\u5c5e\u524d\u9a71\u4f53\u8f83\u5feb\u7684\u6c34\u89e3\u901f\u7387\uff0c\u76f4\u63a5\u754c\u9762\u5171\u7ec4\u88c5\u7b56\u7565\u96be\u4ee5\u5408\u6210\u5177\u6709\u8f83\u4f4e\u7ed3\u6676\u6e29\u5ea6\u7684\u91d1\u5c5e\u6c27\u5316\u7269\uff0c\u5982ZnO, Co3<\/sub>O4<\/sub>, Fe2<\/sub>O3<\/sub>\u7b49\u3002\u56e0\u6b64\uff0c\u8bfe\u9898\u7ec4\u53d1\u5c55\u4e86\u7b56\u7565\u4e8c<\/b><\/strong>\uff1a\u65b0\u9896\u7684\u914d\u4f53\u8f85\u52a9\u7ec4\u88c5\u7b56\u7565\u3002\u501f\u52a9\u5177\u6709\u4e0d\u540c\u5b98\u80fd\u56e2\uff08\u5982\u786b\u9187\u3001\u7fa7\u57fa\u3001\u6c28\u57fa\u7b49\uff09\u7684\u5c0f\u5206\u5b50\u914d\u4f53\u4f5c\u4e3a\u201c\u6865\u6881\u201d\uff0c\u4e0d\u4ec5\u80fd\u591f\u964d\u4f4e\u91d1\u5c5e\u6c27\u5316\u7269\u7684\u6c34\u89e3\u901f\u7387\uff0c\u800c\u4e14\u80fd\u591f\u901a\u8fc7\u6c22\u952e\u548c\u914d\u4f4d\u952e\u63d0\u9ad8\u4eb2\u6c34PEO\u5d4c\u6bb5\u4e0e\u91d1\u5c5e\u524d\u9a71\u4f53\u4e4b\u95f4\u7684\u76f8\u4e92\u4f5c\u7528\u3002<\/p>\n

\u56fe2 \u00a0\u914d\u4f53\u8f85\u52a9\u7ec4\u88c5\u7b56\u7565\u5408\u6210\u4ecb\u5b54\u6676\u5316\u91d1\u5c5e\u6c27\u5316\u7269<\/b><\/strong><\/p>\n

\"\"<\/p>\n

\u9664\u4e86\u501f\u52a9\u5c0f\u5206\u5b50\u914d\u4f53\u4f5c\u4e3a\u201c\u6865\u6881\u201d\u8f85\u52a9\u5d4c\u6bb5\u5171\u805a\u7269\u4e0e\u91d1\u5c5e\u524d\u9a71\u4f53\u7684\u5171\u7ec4\u88c5\uff0c\u4f4e\u805a\u5408\u5ea6\u7684\u53ef\u6eb6\u6027\u915a\u919b\u6811\u8102\uff08resol\uff09\u80fd\u591f\u540c\u65f6\u4e0esp2<\/sup>\u6742\u5316\u78b3\u5d4c\u6bb5\u5171\u805a\u7269\u7684\u4eb2\u6c34\u5d4c\u6bb5\u3001\u91d1\u5c5e\u524d\u9a71\u4f53\u76f8\u4e92\u4f5c\u7528\u3002\u4e3a\u6b64\uff0c\u8bfe\u9898\u7ec4\u63d0\u51fa\u7b56\u7565\u4e09<\/b><\/strong>\uff1aResol-\u8f85\u52a9\u7684\u5171\u7ec4\u88c5\u7b56\u7565\uff0c\u501f\u52a9resol\u7684\u4ea4\u8054\u4f5c\u7528\u548c\u5f3a\u76f8\u4e92\u4f5c\u7528\uff0c\u5b9e\u73b0resol\u3001sp2<\/sup>\u6742\u5316\u78b3\u5d4c\u6bb5\u5171\u805a\u7269\u548c\u91d1\u5c5e\u524d\u9a71\u4f53\u7684\u4e09\u5143\u5171\u7ec4\u88c5\u3002\u7279\u522b\u5730\uff0c\u9664\u53bb\u915a\u919b\u6811\u8102\u5f62\u6210\u78b3\u9aa8\u67b6\u540e\uff0c\u53ef\u4ee5\u5728\u539f\u6709\u7684\u4ecb\u5b54\u5b54\u9053\u4e2d\u4ea7\u751f\u4e30\u5bcc\u7684\u4e8c\u7ea7\u4ecb\u5b54\u7ed3\u6784\uff0c\u663e\u8457\u63d0\u9ad8\u6750\u6599\u7684\u5b54\u9699\u7387\u3002<\/p>\n

\u4ee5\u5bcc\u542bsp2<\/sup>\u6742\u5316\u78b3\u5d4c\u6bb5\u5171\u805a\u7269\u4e3a\u57fa\u7840\uff0c\u901a\u8fc7\u5de7\u5999\u7684\u8c03\u63a7\u754c\u9762\u7ec4\u88c5\u73af\u5883\u3001\u5408\u6210\u7b56\u7565\u7b49\u80fd\u591f\u5b9e\u73b0\u591a\u79cd\u6709\u5e8f\u4ecb\u5b54\u91d1\u5c5e\u6c27\u5316\u7269\u7684\u5408\u6210\uff0c\u7279\u522b\u662f\u4ecb\u5b54\u8fc7\u6e21\u91d1\u5c5e\u6c27\u5316\u7269\u534a\u5bfc\u4f53\u3002\u8fd9\u7c7b\u6750\u6599\u5728\u6c14\u4f53\u4f20\u611f\u9886\u57df\u5c55\u73b0\u51fa\u975e\u5e38\u4f18\u5f02\u7684\u4f20\u611f\u6027\u80fd\uff0c\u8bfe\u9898\u7ec4\u9488\u5bf9\u5e38\u89c1\u7684\u73af\u5883\u6709\u6bd2\u6709\u5bb3\u6c14\u6c1b\u548c\u91cd\u8981\u5f85\u6d4b\u7ec4\u5206\u8fdb\u884c\u4e86\u6df1\u5165\u7814\u7a76\uff0c\u5e76\u5bf9\u5176\u4f20\u611f\u4f5c\u7528\u673a\u5236\u8fdb\u884c\u4e86\u63a2\u8ba8\u3002<\/p>\n

\u56fe<\/b><\/strong>3<\/b><\/strong>\u00a0\u00a0<\/b><\/strong>sp2<\/b><\/strong>\u6742\u5316<\/b><\/strong>\u78b3\u5d4c\u6bb5\u5171\u805a\u7269<\/b><\/strong>\u5bfc\u5411<\/b><\/strong>\u5408\u6210\u7684\u4ecb\u5b54\u91d1\u5c5e\u6c27\u5316\u7269\u534a\u5bfc\u4f53\u4f20\u611f\u673a\u5236<\/b><\/strong><\/p>\n

\"\"<\/p>\n

\uff08a\uff09n<\/i><\/em>-\u578b\u4ecb\u5b54WO3<\/sub>\u534a\u5bfc\u4f53\u6750\u6599\u68c0\u6d4b3-\u7f9f\u57fa-2-\u4e01\u916e\u7684\u4f20\u611f\u673a\u7406\uff1b<\/p>\n

\uff08b\uff09n<\/i><\/em>-\u578b\u4ecb\u5b54SnO2<\/sub>\u534a\u5bfc\u4f53\u6750\u6599\u68c0\u6d4bH2<\/sub>S\u6c14\u4f53\u7684\u4f20\u611f\u673a\u7406\uff1b<\/p>\n

\uff08c\uff09p<\/i><\/em>-\u578b\u4ecb\u5b54CoOx<\/i><\/sub><\/em>\/C\u534a\u5bfc\u4f53\u6750\u6599\u68c0\u6d4bH2<\/sub>\u7684\u4f20\u611f\u673a\u7406\uff1b<\/p>\n

\uff08d\uff09p<\/i><\/em>–n<\/i><\/em>\u578bPt\/WO3<\/sub>\u5f02\u8d28\u7ed3\u534a\u5bfc\u4f53\u6750\u6599\u68c0\u6d4bCO\u7684\u4f20\u611f\u673a\u7406\u3002<\/p>\n

\u3010\u5c55\u671b\u3011<\/strong><\/p>\n

\u6587\u672b\uff0c\u4f5c\u8005\u8fd8\u5c55\u671b\u4e86\u672a\u6765\u6709\u5e8f\u4ecb\u5b54\u91d1\u5c5e\u6c27\u5316\u7269\u534a\u5bfc\u4f53\u6750\u6599\u7684\u5408\u6210\u3001\u8bbe\u8ba1\u53ca\u5e94\u7528\u7684\u6f5c\u5728\u65b9\u5411\u3002\uff081\uff09\u6c14\u4f53\u4f20\u611f\u6027\u80fd\u76f4\u63a5\u53d6\u51b3\u4e8e\u6750\u6599\u7684\u5b54\u7279\u5f81\uff08\u5982\u5b54\u7c7b\u578b\u3001\u5b54\u5f84\u3001\u5b54\u58c1\u539a\u5ea6\u548c\u7ec4\u6210\u7b49\uff09\uff0c\u56e0\u6b64\u5408\u7406\u8bbe\u8ba1\u9002\u5e94\u6027\u66f4\u5e7f\u7684sp2<\/sup>\u6742\u5316\u78b3\u5d4c\u6bb5\u5171\u805a\u7269\uff0c\u5e76\u901a\u8fc7\u8c03\u8282\u4eb2\/\u758f\u6c34\u5d4c\u6bb5\u7684\u6bd4\u4f8b\u548c\u957f\u5ea6\u6709\u671b\u5b9e\u73b0\u6750\u6599\u5b54\u7279\u5f81\u7684\u53ef\u63a7\u8c03\u8282\u3002\uff082\uff09\u5728\u6750\u6599\u7ec4\u6210\u65b9\u9762\uff0c\u4f5c\u8005\u8ba4\u4e3a\u591a\u7ec4\u5206\u91d1\u5c5e\u6c27\u5316\u7269\uff08\u5982\u63ba\u6742\uff09\u3001\u8d35\u91d1\u5c5e\u8d1f\u8f7d\u53cap<\/i><\/em>–n<\/i><\/em>\u6216n<\/i><\/em>–n<\/i><\/em>\u5f02\u8d28\u7ed3\u6709\u5e8f\u4ecb\u5b54\u91d1\u5c5e\u6c27\u5316\u7269\u5c06\u6210\u4e3a\u6c14\u4f53\u4f20\u611f\u6750\u6599\u7684\u7814\u7a76\u91cd\u70b9\u3002\uff083\uff09\u65e0\u5b9a\u578b\u7684\u975e\u91d1\u5c5e\u7ec4\u5206\uff08\u5982SiO2<\/sub>\u3001C\u7b49\uff09\u4e5f\u80fd\u591f\u6291\u5236\u91d1\u5c5e\u6676\u7c92\u70e7\u7ed3\u751f\u957f\u4ece\u800c\u63d0\u9ad8\u6750\u6599\u7684\u957f\u7a0b\u7a33\u5b9a\u6027\uff0c\u4e14\u65e0\u5b9a\u578b\u7ec4\u5206\u80fd\u591f\u8c03\u8282\u76ee\u6807\u6c14\u4f53\u5206\u5b50\u7684\u5438\u9644\/\u6269\u6563\u884c\u4e3a\uff0c\u6709\u671b\u89e3\u51b3\u534a\u5bfc\u4f53\u4f20\u611f\u6750\u6599\u5728\u6c14\u4f53\u9009\u62e9\u6027\u65b9\u9762\u7684\u7814\u7a76\u74f6\u9888\u3002\u57fa\u4e8esp2<\/sup>\u6742\u5316\u78b3\u5d4c\u6bb5\u5171\u805a\u7269\u7684\u8bbe\u8ba1\u5408\u6210\uff0c\u53ef\u4ee5\u8bbe\u8ba1\u51fa\u5404\u79cd\u4e0d\u540c\u7ec4\u6210\u3001\u5b54\u9053\u5927\u5c0f\u53ca\u8868\u9762\u6027\u8d28\u7684\u91d1\u5c5e\u6c27\u5316\u7269\u534a\u5bfc\u4f53\u6750\u6599\uff0c\u8fd9\u5c06\u4e3a\u672a\u6765\u5f00\u53d1\u9ad8\u6027\u80fd\u6c14\u4f53\u4f20\u611f\u5668\u5e26\u6765\u65b0\u7684\u673a\u9047\uff0c\u4e3a\u4f9d\u6258\u6c14\u4f53\u4f20\u611f\u6280\u672f\u7684\u73af\u5883\u76d1\u6d4b\u3001\u75be\u75c5\u8bca\u65ad\u7b49\u5e94\u7528\u5960\u5b9a\u57fa\u7840\u3002\u540c\u6837\u5730\uff0c\u53d1\u5c55\u4ee5sp2<\/sup>\u6742\u5316\u78b3\u5d4c\u6bb5\u5171\u805a\u7269\u5bfc\u5411\u5408\u6210\u7684\u9ad8\u5ea6\u6676\u5316\u4ecb\u5b54\u91d1\u5c5e\u6c27\u5316\u7269\u7684\u65b9\u6cd5\u4e5f\u9002\u5e94\u4e8e\u591a\u5b54\u6750\u6599\u5728\u50ac\u5316\u3001\u80fd\u6e90\u8f6c\u5316\u53ca\u73af\u5883\u4fee\u590d\u7b49\u9886\u57df\u3002\u8be5\u5de5\u4f5c\u5f97\u5230\u4e86\u590d\u65e6\u5927\u5b66\u5316\u5b66\u7cfb\u3001\u805a\u5408\u7269\u5206\u5b50\u5de5\u7a0b\u56fd\u5bb6\u91cd\u70b9\u5b9e\u9a8c\u5ba4\u30012011\u80fd\u6e90\u6750\u6599\u5316\u5b66\u534f\u540c\u521b\u65b0\u4e2d\u5fc3\uff08iChEM\uff09\u4ee5\u53ca\u56fd\u5bb6\u4e07\u4eba\u8ba1\u5212\u9752\u5e74\u62d4\u5c16\u4eba\u624d\u652f\u6301\u548c\u56fd\u5bb6\u81ea\u7136\u79d1\u5b66\u57fa\u91d1\u4f18\u79c0\u9752\u5e74\u57fa\u91d1\u7684\u5927\u529b\u652f\u6301\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5<\/b><\/strong>\uff1aYidong Zou, Xinran\u00a0Zhou, Yongheng Zhu, Xiaowei Cheng, Dongyuan Zhao, and Yonghui Deng*, sp2<\/sup>-Hybridized Carbon-Containing Block Copolymer\u00a0Templated Synthesis of Mesoporous Semiconducting Metal Oxides with Excellent Gas Sensing Property\u00a0(Acc. Chem. Res., 2019, DOI:<\/b><\/strong>\u00a010.1021\/acs.accounts.8b00598)<\/b><\/strong><\/p>\n

\u9093\u52c7\u8f89<\/b><\/strong>\u6559\u6388\u8bfe\u9898\u7ec4\u7f51\u9875<\/b><\/strong>\uff1ahttp:\/\/www.yhdenggroup.fudan.edu.cn\/<\/u><\/a><\/p>\n

\u3010\u901a\u8baf\u4f5c\u8005\u4ecb\u7ecd\u3011<\/strong><\/p>\n

\u9093\u52c7\u8f89<\/b><\/strong>\uff0c\u590d\u65e6\u5927\u5b66\u6559\u6388\uff0c\u535a\u58eb\u751f\u5bfc\u5e08\uff0c\u56fd\u5bb6\u4f18\u79c0\u9752\u5e74\u57fa\u91d1\u83b7\u5f97\u8005\uff0c2009-2010 University of California, Berkeley \u8bbf\u95ee\u5b66\u8005\u3002\u4e2d\u56fd\u5316\u5b66\u4f1a\u4f1a\u5458\uff0c\u4e2d\u56fd\u6750\u6599\u7814\u7a76\u5b66\u4f1a\u4f1a\u5458\uff0c\u7f8e\u56fd\u79d1\u5b66\u51fa\u7248\u793eAdvanced Porous Materials\u526f\u4e3b\u7f16\uff0cChinese Chemical Letters \u6267\u884c\u526f\u4e3b\u7f16\uff0c\u6fb3\u5927\u5229\u4e9aARC\u57fa\u91d1\u56fd\u9645\u8bc4\u5ba1\u4e13\u5bb6\uff0cAdv. Mater.\u3001J. Am. Chem. Soc.\u3001Angew. Chem. -Int. Ed.\u7b49\u56fd\u9645\u9876\u7ea7\u6750\u6599\u4e0e\u5316\u5b66\u520a\u7269\u7684\u8bba\u6587\u5ba1\u7a3f\u4eba\u3002\u7814\u7a76\u65b9\u5411\u5305\u62ec\uff1a\uff081\uff09\u70ed\u56fa\u578b\u9ad8\u5206\u5b50\u3001\u5d4c\u6bb5\u5171\u805a\u7269\u3001\u9ad8\u5206\u5b50\u529f\u80fd\u5fae\u7403; \u6d3b\u6027\u81ea\u7531\u57fa\u805a\u5408\u3001\u4e73\u6db2\u805a\u5408\u7b49\u9ad8\u5206\u5b50\u5408\u6210\u5316\u5b66\u76f8\u5173\u7814\u7a76\u5de5\u4f5c; \uff082\uff09\u57fa\u4e8e\u65b0\u578b\u9ad8\u5206\u5b50\u5d4c\u6bb5\u5171\u805a\u7269\u4e3a\u6a21\u677f\u7684\u529f\u80fd\u591a\u5b54\u7ed3\u6784\u6750\u6599\u7684\u5408\u6210\u53ca\u5176\u5728\u50ac\u5316\u3001\u4f20\u611f\u65b9\u9762\u7684\u5e94\u7528;\uff083\uff09\u57fa\u4e8e\u8d85\u5206\u5b50\u8bf1\u5bfc\u8868\u754c\u9762\u53ef\u63a7\u7ec4\u88c5\u7684\u529f\u80fd\u6838-\u58f3\u7eb3\u7c73\u591a\u5b54\u6750\u6599\u7684\u5408\u6210\u53ca\u5176\u5728\u751f\u7269\u533b\u5b66\u3001\u50ac\u5316\u65b9\u9762\u7684\u5e94\u7528\u3002\u83b7\u5f97\u6559\u80b2\u90e8\u81ea\u7136\u79d1\u5b66\u4e8c\u7b49\uff082014\u5e74\uff0c\u6392\u540d\u7b2c\u4e00\uff09\u53ca\u4e00\u7b49\u5956\uff082017\u5e74\uff0c\u6392\u540d\u7b2c\u4e8c\uff09\uff0c2014-2018\u8fde\u7eed\u5165\u9009\u7231\u601d\u552f\u5c14\u4e2d\u56fd\u9ad8\u88ab\u5f15\u7528\u5b66\u8005\u699c\u5355\uff08\u6750\u6599\u79d1\u5b66\uff09\uff1b2014\u5e74\u83b7\u5f97\u56fd\u5bb6\u4f18\u79c0\u9752\u5e74\u57fa\u91d1\uff0c2015\u5e74\u5165\u9009\u56fd\u5bb6\u4e07\u4eba\u8ba1\u5212\u9752\u5e74\u62d4\u5c16\u4eba\u624d\u548c\u9996\u5c4a\u6559\u80b2\u90e8\u9752\u5e74\u957f\u6c5f\u5b66\u8005\u3002\u5df2\u5728\u56fd\u9645\u91cd\u8981SCI\u671f\u520a\u4e0a\u53d1\u8868\u8bba\u6587130\u4f59\u7bc7\uff0c\u5176\u4e2d\u4ee5\u901a\u8baf\u4f5c\u8005\u53d1\u8868JACS\uff0810\u7bc7\uff09\uff0cAdv. Mater.\uff084\u7bc7\uff09\uff0cAngew. Chem. Int. Ed.\uff086 \u7bc7\uff09\uff0cAcc. Chem. Res.\uff081\u7bc7\uff09\u7b49\u3002\u8bba\u6587\u88ab\u5f1513000\u4f59\u6b21\uff08H\u6307\u657051\uff0cGoogle Scholar\uff09\uff0c\u5355\u7bc7\u7814\u7a76\u8bba\u6587\u6700\u9ad8\u88ab\u5f15\u75281300\u4f59\u6b21\uff1b\u5e94\u9080\u64b0\u5199\u82f1\u6587\u5b66\u672f\u4e13\u8457\u4e00\u90e8\uff08Semiconducting metal oxides for gas sensing\uff0cSpringer\uff0c2019\uff09\uff0c\u53c2\u4e0e\u64b0\u5199\u4e2d\u3001\u82f1\u6587\u5b66\u672f\u8bba\u8457\u5404\u4e00\u4e2a\u7ae0\u8282\u3002\u7533\u8bf7\u4e2d\u56fd\u53d1\u660e\u4e13\u522932\u9879\uff0c\u5176\u4e2d18\u9879\u83b7\u5f97\u6388\u6743\u3002\u00a0<\/p>\n

\u672c\u6587\u7531\u590d\u65e6<\/b><\/strong>\u5927\u5b66\u9093\u52c7\u8f89<\/b><\/strong>\u6559\u6388\u56e2\u961f<\/b><\/strong>\u4f9b\u7a3f\uff0c<\/b><\/strong>\u6750\u6599\u4eba\u7f16\u8f91\u90e8Alisa\u7f16\u8f91\u3002<\/p>\n

\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1: tougao@cailiaoren.com.<\/p>\n

\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1acailiaorenVIP.<\/p>\n","protected":false},"excerpt":{"rendered":"

\u3010\u5f15\u8a00\u3011 \u534a\u5bfc\u4f53\u91d1\u5c5e\u6c27\u5316\u7269\u5177\u6709\u72ec\u7279\u7684\u7535\u5b50\u7ed3\u6784\u3001\u53ef\u8c03\u8282\u7684\u80fd\u5e26\u5bbd\u5ea6\u53ca\u534a\u5bfc\u4f53\u8868\/\u754c\u9762\u7279\u6027\uff0c\u56e0\u6b64\u5728\u975e\u5747\u76f8\u50ac\u5316\u3001\u6c14\u4f53\u4f20\u611f\u5668\u3001\u80fd\u91cf\u50a8\u5b58\u4e0e\u8f6c\u5316\u7b49\u9886\u57df\u5f97\u5230\u5e7f\u6cdb\u5e94\u7528\u3002\u5982\u4f55\u521b\u5236\u5177\u6709…<\/p>\n","protected":false},"author":10213,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[],"class_list":["post-168817","post","type-post","status-publish","format-standard","hentry","category-jiedu"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/168817"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/10213"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=168817"}],"version-history":[{"count":3,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/168817\/revisions"}],"predecessor-version":[{"id":168839,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/168817\/revisions\/168839"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=168817"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=168817"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=168817"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}