{"id":168784,"date":"2019-03-06T06:42:16","date_gmt":"2019-03-05T22:42:16","guid":{"rendered":"\/\/m.iemloyee.com\/?p=168784"},"modified":"2019-03-05T17:43:04","modified_gmt":"2019-03-05T09:43:04","slug":"%e6%98%86%e5%a3%ab%e5%85%b0%e5%a4%a7%e5%ad%a6%e9%99%88%e5%bf%97%e5%88%9a%e6%95%99%e6%8e%88%e9%82%b9%e8%bf%9b%e6%95%99%e6%8e%88%e5%9b%a2%e9%98%9f%e5%9c%a8snse%e5%9f%ba%e7%83%ad%e7%94%b5%e6%9d%90","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=168784","title":{"rendered":"\u6606\u58eb\u5170\u5927\u5b66\u9648\u5fd7\u521a\u6559\u6388&#038;\u90b9\u8fdb\u6559\u6388\u56e2\u961f\u5728SnSe\u57fa\u70ed\u7535\u6750\u6599\u53d6\u5f97\u8fdb\u5c55\uff1a\u5b9e\u73b0\u5177\u6709\u8f83\u9ad8\u6027\u80fd\u7684\u7852\u5316\u9521\u57fa\u70ed\u7535\u6750\u6599\u7684\u591a\u79cd\u9014\u5f84\u53ca\u673a\u7406"},"content":{"rendered":"<p><strong><b>\u3010\u5f15\u8a00\u3011<\/b><\/strong><\/p>\n<p>\u70ed\u7535\u6750\u6599\u80fd\u591f\u5b9e\u73b0\u70ed\u80fd\u4e0e\u7535\u80fd\u7684\u76f4\u63a5\u8f6c\u6362\uff0c\u56e0\u6b64\u5728\u5e9f\u70ed\u56de\u6536\uff0c\u7a7a\u8c03\u548c\u5236\u51b7\u7b49\u5de5\u4e1a\u9886\u57df\u5177\u6709\u76f8\u5f53\u5e7f\u9614\u7684\u5e94\u7528\u524d\u666f\u3002\u4f5c\u4e3a\u65b0\u4e00\u4ee3\u70ed\u7535\u6750\u6599\u7684\u5178\u578b\u4ee3\u8868\uff0c\u7852\u5316\u9521\uff08SnSe\uff09\u7531\u4e8e\u5176\u4f4e\u6bd2\uff0c\u73af\u5883\u53cb\u597d\uff0c\u5730\u58f3\u542b\u91cf\u4e30\u5bcc\uff0c\u76f8\u53d8\u70b9\u4e0b\u6027\u80fd\u7a33\u5b9a\uff0c\u4ee5\u53ca\u8d85\u4f4e\u6676\u683c\u70ed\u5bfc\u7387\u7b49\u663e\u8457\u7279\u70b9\u800c\u5907\u53d7\u5173\u6ce8\u3002\u8fd1\u5e74\u6765\uff0c\u5355\u6676\u7852\u5316\u9521\u5c61\u6709\u62a5\u9053\u5176\u53ef\u80fd\u5177\u6709\u8d85\u9ad8\u7684\u70ed\u7535\u6027\u80fd\uff0c\u7136\u800c\u7531\u4e8e\u5176\u8f83\u5dee\u7684\u673a\u68b0\u6027\u80fd\u4ee5\u53ca\u82db\u523b\u7684\u6676\u4f53\u751f\u957f\u6761\u4ef6\uff0c\u5355\u6676\u7852\u5316\u9521\u8f83\u96be\u5e94\u7528\u4e8e\u5b9e\u9645\u70ed\u7535\u5668\u4ef6\u4e2d\u3002\u4e3a\u4e86\u89e3\u51b3\u8fd9\u4e00\u96be\u9898\uff0c\u591a\u6676\u7852\u5316\u9521\u540c\u65f6\u4e5f\u6210\u4e3a\u4e86\u4e00\u4e2a\u65b0\u7684\u7814\u7a76\u70ed\u70b9\u3002<\/p>\n<p>\u65f6\u81f3\u4eca\u65e5\uff0c\u7852\u5316\u9521\u57fa\u70ed\u7535\u6750\u6599\u7684\u70ed\u7535\u4f18\u503c\uff08ZT\u503c\uff09\u5df2\u7ecf\u5728\u5f88\u5927\u7a0b\u5ea6\u4e0a\u5f97\u5230\u4e86\u63d0\u9ad8\uff0c\u5982\u56fe1\u6240\u793a\u3002SnSe\u4f5c\u4e3a\u4e00\u79cd\u5178\u578b\u7684\u534a\u5bfc\u4f53\u70ed\u7535\u6750\u6599\uff0c\u62e5\u6709\u5982\u4e0b\u7279\u70b9\uff1a\uff081\uff09\u5728~800\u00a0K\u53d1\u751f\u76f8\u53d8\uff0c\u4ece\u6b63\u4ea4Pnma\u7ed3\u6784\u53d8\u4e3a\u6b63\u4ea4Cmcm\u7ed3\u6784\uff0c\uff082\uff09\u5177\u6709\u8f83\u9ad8\u7684\u8f7d\u6d41\u5b50\u6d53\u5ea6\uff0c\u5e76\u80fd\u591f\u901a\u8fc7\u5f15\u5165\u7a7a\u4f4d\u8fdb\u4e00\u6b65\u63d0\u9ad8\u8f7d\u6d41\u5b50\u6d53\u5ea6\uff1b\uff083\uff09\u8f83\u4e3a\u590d\u6742\u7684\u80fd\u5e26\u7ed3\u6784\u4ee5\u53ca\u5408\u9002\u7684\u5e26\u9699\uff08\u7ea60.9 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m<\/b><\/strong><strong><sup><b>\u2212<\/b><\/sup><\/strong><strong><sup><b>1<\/b><\/sup><\/strong><strong><b>\u00a0K<\/b><\/strong><strong><sup><b>\u2212<\/b><\/sup><\/strong><strong><sup><b>1<\/b><\/sup><\/strong><strong><b>\uff09<\/b><\/strong>\u3002\u56e0\u6b64\uff0c\u4e0e\u5c11Sn\u7a7a\u4f4d\u7684\u6750\u6599\u76f8\u6bd4\uff0c\u5176\u5728\u4e2d\u4f4e\u6e29\u533a\u7684\u70ed\u7535\u4f18\u503c\u5f97\u5230\u4e86\u663e\u8457\u63d0\u5347\u3002\u76f8\u5173\u5de5\u4f5c\u53d1\u8868\u5728\u56fd\u9645\u9876\u7ea7\u80fd\u6e90\u6750\u6599\u671f\u520aEnergy\u00a0Storage Materials\uff08Energy Storage Mater. 10 (2018): 130-138\uff09\u3002<\/p>\n<p><strong><b>\u56fe2<\/b><\/strong>\u00a0\u5177\u5907\u9ad8\u6d53\u5ea6Sn\u7a7a\u4f4d\u7684SnSe\u5355\u6676\u7247<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"wp-image-168786 size-full aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2019\/03\/\u56fe\u724711-1.png\" alt=\"\" width=\"600\" height=\"290\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2019\/03\/\u56fe\u724711-1.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2019\/03\/\u56fe\u724711-1-300x145.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>\uff08a\uff09\u5149\u5b66\u7167\u7247\uff1b\uff08b\uff09SEM\u7167\u7247\uff1b\uff08c\uff09\u70e7\u7ed3\u5757\u4f53\u7684\u622a\u9762SEM\u7167\u7247\uff1b\uff08d\uff09\u70e7\u7ed3\u5757\u4f53\u7684HREM\u548cSAED\uff1b\u4ee5\u53ca(e)\u4e0e\u5355\u6676\u6837\u54c1\u5728\u4e2d\u4f4e\u6e29\u6761\u4ef6\u4e0b\u7684\u70ed\u7535\u4f18\u503c\u5bf9\u6bd4\u3002<\/p>\n<p>\u80fd\u5e26\u5de5\u7a0b\u80fd\u591f\u5b9e\u73b0\u5bf9\u8f7d\u6d41\u5b50\u6d53\u5ea6\u548c\u585e\u8d1d\u514b\u7cfb\u6570\u7684\u6709\u6548\u8c03\u63a7\uff0c\u800c\u5f02\u8d28\u5143\u7d20\u63ba\u6742\u662f\u5b9e\u73b0\u80fd\u5e26\u5de5\u7a0b\u7684\u4e3b\u8981\u65b9\u6cd5\u4e4b\u4e00\u3002\u5728\u4f17\u591a\u63ba\u6742\u5143\u7d20\u5f53\u4e2d\uff0c\u94dc\u5143\u7d20\u7531\u4e8e\u540c\u65f6\u5177\u6709+1\u548c+2\u4e24\u79cd\u7a33\u5b9a\u4ef7\u6001\uff0c\u56e0\u6b64\u662f\u53ef\u4ee5\u5bf9\u591a\u6676\u7852\u5316\u9521\u8fdb\u884c\u6709\u6548\u8c03\u63a7\u7684\u5173\u952e\u5143\u7d20\u4e4b\u4e00\u3002\u8be5\u56e2\u961f\u9996\u6b21\u901a\u8fc7\u6eb6\u5242\u70ed\u6cd5\u5b9e\u73b0\u4e86<strong><b>\u94dc\u5143\u7d20\u91cd\u63ba\u6742\u7684p\u578b\u7852\u5316\u9521\u5fae\u7c73\u7ea7\u5e26\u72b6\u6676\u4f53<\/b><\/strong>\uff0c\u5982\u56fe3\u6240\u793a\uff0c\u5176\u70e7\u7ed3\u540e\u7684\u5757\u4f53\u6750\u6599\u7684ZT\u503c\u5728823K\u4e0b\u53ef\u8fbe\u52301.41\u3002\u8fd9\u79cd\u6750\u6599\u6240\u5c55\u73b0\u51fa\u6765\u7684\u4f18\u5f02\u7684\u70ed\u7535\u6027\u80fd\u5f97\u76ca\u4e8e\u5176<strong><b>\u8f83\u9ad8\u7684\u529f\u7387\u56e0\u5b50\uff08<\/b><\/strong><strong><b>5<\/b><\/strong><strong><b>.<\/b><\/strong><strong><b>7 <\/b><\/strong><strong><b>\u03bc<\/b><\/strong><strong><b>W<\/b><\/strong><strong><b>\u00a0<\/b><\/strong><strong><b>cm<\/b><\/strong><strong><sup><b>-1<\/b><\/sup><\/strong><strong><b>\u00a0K<\/b><\/strong><strong><sup><b>-2<\/b><\/sup><\/strong><strong><b>\uff09<\/b><\/strong>\u4ee5\u53ca\u5176<strong><b>\u8f83\u4f4e\u7684\u70ed\u5bfc\u7387\uff080.<\/b><\/strong><strong><b>32 <\/b><\/strong><strong><b>W m<\/b><\/strong><strong><sup><b>-1<\/b><\/sup><\/strong><strong><b>\u00a0K<\/b><\/strong><strong><sup><b>-1<\/b><\/sup><\/strong><strong><b>\uff09<\/b><\/strong>\u3002\u5176\u9ad8\u529f\u7387\u56e0\u5b50\u6765\u81ea\u4e8e\u901a\u8fc7\u6709\u6548\u7684\u94dc\u63ba\u6742\u800c\u5b9e\u73b0\u7684<strong><b>\u9ad8\u7a7a\u7a74\u8f7d\u6d41\u5b50\u6d53\u5ea6\uff08<\/b><\/strong><strong><b>1<\/b><\/strong><strong><b>.9<\/b><\/strong><strong><b>5<\/b><\/strong><strong><b>\u00d710<\/b><\/strong><strong><sup><b>19<\/b><\/sup><\/strong><strong><b>cm<\/b><\/strong><strong><sup><b>-3<\/b><\/sup><\/strong><strong><b>\uff09<\/b><\/strong>\uff0c\u800c\u5176\u4f4e\u70ed\u5bfc\u7387\u5219\u6e90\u4e8e\u94dc\u63ba\u6742\u6240\u5bfc\u81f4\u7684<strong><b>\u5bc6\u96c6\u6676\u4f53\u7f3a\u9677<\/b><\/strong>\uff0c\u5305\u62ec\u5f3a\u70c8\u7684\u6676\u683c\u7578\u53d8\uff0c\u4f4d\u9519\uff0c\u5fae\u89c2\u6676\u4f53\u5f2f\u66f2\uff0c\u4ee5\u53ca\u660e\u663e\u589e\u52a0\u7684\u6676\u754c\u5bc6\u5ea6\uff0c\u8fd9\u4e9b\u6676\u4f53\u7f3a\u9677\u80fd\u591f\u6709\u6548\u5730\u6563\u5c04\u4e0d\u540c\u9891\u7387\u7684\u58f0\u5b50\uff0c\u8fdb\u800c\u6709\u6548\u964d\u4f4e\u70ed\u5bfc\u7387\u3002\u5728\u94dc\u63ba\u6742\u673a\u7406\u7684\u7814\u7a76\u4e0a\uff0c\u8be5\u56e2\u961f\u53d6\u5f97\u91cd\u5927\u7a81\u7834\uff0c\u5b9e\u73b0\u4e86<strong><b>\u5728\u6eb6\u6db2\u6cd5\u5408\u6210\u73af\u5883\u4e0b\u6240\u80fd\u8fbe\u5230\u7684\u94dc\u63ba\u6742\u7684\u6700\u5927\u6d53\u5ea6<\/b><\/strong>\uff0811.8%\uff09\u3002\u540c\u65f6\uff0c\u8be5\u56e2\u961f\u53d1\u73b0\u968f\u7740\u94dc\u63ba\u6742\u6d53\u5ea6\u7684\u63d0\u5347\uff0c\u7852\u5316\u9521\u5355\u6676\u7684<strong><b>\u62e9\u4f18\u751f\u957f\u4f1a\u53d1\u751f\u53d8\u5316<\/b><\/strong>\uff0c\u7531\u677f\u6761\u72b6\u9010\u6e10\u5411\u5e26\u72b6\u8fc7\u6e21\uff0c\u8fdb\u800c\u964d\u4f4e\u4e86\u70e7\u7ed3\u5757\u4f53\u6750\u6599\u7684\u5404\u5411\u5f02\u6027\u3002\u6b64\u5916\uff0c\u901a\u8fc7XRD\uff0cXPS\uff0cSEM\uff0cTEM\u4ee5\u53caCs-STEM\u7b49\u5148\u8fdb\u8868\u5f81\u624b\u6bb5\uff0c\u8be5\u56e2\u961f\u53d1\u73b0\u5728\u6eb6\u5242\u70ed\u6cd5\u5408\u6210\u94dc\u63ba\u6742\u7852\u5316\u9521\u5fae\u6676\u7684\u8fc7\u7a0b\u4e2d\uff0c\u63ba\u5165\u7684\u94dc\u5143\u7d20<strong><b>\u540c\u65f6\u663e\u793a<\/b><\/strong><strong><b>+<\/b><\/strong><strong><b>1\u548c<\/b><\/strong><strong><b>+<\/b><\/strong><strong><b>2\u4ef7<\/b><\/strong>\u3002\u94dc\u7684\u63ba\u6742\u5bfc\u81f4<strong><b>\u6676\u683c\u6536\u7f29<\/b><\/strong>\uff0c\u5e76\u80fd\u591f\u5728\u6676\u683c\u4e2d\u5f15\u5165<strong><b>\u7eb3\u7c73\u7ea7\u5e94\u529b\u533a<\/b><\/strong>\uff0c\u9020\u6210\u5c40\u90e8\u6676\u683c\u7578\u53d8\uff1b\u800c\u901a\u8fc7\u5bf9\u91cd\u63ba\u6742\u7684\u7852\u5316\u9521\u6240\u8fdb\u884c\u7684\u57fa\u4e8e\u80fd\u5e26\u7ed3\u6784\u548c\u6001\u5bc6\u5ea6\u5206\u5e03\u7684\u7b2c\u4e00\u6027\u539f\u7406\u8ba1\u7b97\u53d1\u73b0\uff0c\u94dc\u5143\u7d20\u7684\u63ba\u6742\u80fd\u591f\u6709\u6548<strong><b>\u5b9e\u73b0\u80fd\u5e26\u7b80\u5e76<\/b><\/strong>\uff0c<strong><b>\u63d0\u9ad8\u4ef7\u5e26\u6001\u5bc6\u5ea6<\/b><\/strong>\u91ca\u653e\u66f4\u591a\u7a7a\u7a74\uff0c\u4e3a\u94dc\u63ba\u6742\u5bf9\u8f7d\u6d41\u5b50\u6d53\u5ea6\u7684\u8fdb\u4e00\u6b65\u8c03\u63a7\u63d0\u4f9b\u4e86\u7269\u7406\u652f\u6301\u3002\u8be5\u5de5\u4f5c\u586b\u8865\u4e86\u7852\u5316\u9521\u57fa\u5757\u4f53\u70ed\u7535\u6750\u6599\u4e2d\u94dc\u63ba\u6742\u673a\u7406\u7684\u7a7a\u767d\uff0c\u5e76\u4e3a\u8fdb\u4e00\u6b65\u63d0\u9ad8\u591a\u6676\u7852\u5316\u9521\u7684\u70ed\u7535\u6027\u80fd\u63d0\u4f9b\u4e86\u65b0\u7684\u89e3\u51b3\u65b9\u6848\u3002\u76f8\u5173\u6210\u679c\u53d1\u8868\u4e8e\u82f1\u56fd\u5316\u5b66\u4f1a(RSC)\u65d7\u4e0b\u9876\u7ea7\u671f\u520a Chemical Science\uff08Chem.\u00a0Sci. 9.37 (2018): 7376-7389.\uff09\u3002<\/p>\n<p><strong><b>\u56fe<\/b><\/strong><strong><b>3<\/b><\/strong>\u00a0\u5177\u5907\u9ad8Cu\u63ba\u6742\u6d53\u5ea6\u7684SnSe\u5fae\u6676<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"wp-image-168787 size-full aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2019\/03\/\u56fe\u724712-1.png\" alt=\"\" width=\"600\" height=\"279\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2019\/03\/\u56fe\u724712-1.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2019\/03\/\u56fe\u724712-1-300x140.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>\uff08a\uff09\u4f4e\u500dSEM\u7167\u7247\uff1b\uff08b\uff09\u9ad8\u500dSEM\u7167\u7247\uff1b\uff08c\uff09\u4f4e\u500dTEM\u53caSAED\uff1b\uff08d\uff09HRTEM\u53ca\u5178\u578b\u4f4d\u9519\uff1b(e)XPS\u7ed3\u679c\u663e\u793aCu\u7684\u4ef7\u6001\uff1b\uff08f\uff09\u7403\u5deeTEM\uff1b\uff08g\uff09\u5176\u5728SnSe-plane\u7684\u7ebf\u626b\u7ed3\u679c\uff1b\uff08h\uff09\u6001\u5bc6\u5ea6\u3002<\/p>\n<p>\u7ec4\u6210\u70ed\u7535\u6a21\u5757\u7684\u524d\u63d0\u662f\u540c\u65f6\u9700\u8981p\u578b\u548cn\u578b\u4e24\u79cd\u70ed\u7535\u6750\u6599\uff0c\u56e0\u6b64\uff0c\u5408\u6210\u5177\u6709\u9ad8\u70ed\u7535\u6027\u80fd\u7684n\u578b\u591a\u6676\u7852\u5316\u9521\u4e5f\u662f\u7814\u7a76\u91cd\u70b9\u4e4b\u4e00\u3002\u7531\u4e8e\u666e\u901a\u7852\u5316\u9521\u534a\u5bfc\u4f53\u4e2d\u7a7a\u7a74\u4e3a\u591a\u6570\u8f7d\u6d41\u5b50\uff0cn\u578b\u591a\u6676\u7852\u5316\u9521\u5757\u4f53\u4e00\u822c\u8f83\u96be\u5b9e\u73b0\u3002\u8be5\u56e2\u961f\u901a\u8fc7\u6eb6\u5242\u70ed\u6cd5\u5b9e\u73b0\u4e86n\u578b<strong><b>\u9511\u5143\u7d20\u63ba\u6742<\/b><\/strong>\u7684\u7852\u5316\u9521\u5fae\u7c73\u7ea7\u677f\u6761\u72b6\u6676\u4f53\uff0c\u5982\u56fe4\u6240\u793a\uff0c\u5176\u6240\u5c55\u73b0\u51fa\u6765\u7684\u4f18\u5f02\u7684\u70ed\u7535\u6027\u80fd\uff08773K\u4e0bZT\u8fbe\u52301.1\uff09\u5f97\u76ca\u4e8e\u5176\u8f83\u9ad8\u7684\u529f\u7387\u56e0\u5b50\uff082.4 \u03bcWcm<sup>-1<\/sup>\u00a0K<sup>-2<\/sup>\uff09\u4ee5\u53ca\u5176<strong><b>\u8d85\u4f4e\u7684\u70ed\u5bfc\u7387\uff080.17 W m<\/b><\/strong><strong><sup><b>-1<\/b><\/sup><\/strong><strong><b>\u00a0K<\/b><\/strong><strong><sup><b>-1<\/b><\/sup><\/strong><strong><b>\uff09<\/b><\/strong>\u3002\u8be5\u5757\u4f53\u6750\u6599\u7684\u9ad8\u529f\u7387\u56e0\u5b50\u6765\u81ea\u4e8e\u901a\u8fc7\u6709\u6548\u7684\u9511\u63ba\u6742\u800c\u5b9e\u73b0\u7684<strong><b>\u9ad8\u7535\u5b50\u8f7d\u6d41\u5b50\u6d53\u5ea6<\/b><\/strong>\uff083.94\u00d710<sup>19<\/sup>\u00a0cm<sup>-3<\/sup>\uff09\uff0c\u800c\u5176\u8d85\u4f4e\u70ed\u5bfc\u7387\u5219\u6e90\u4e8e\u9511\u63ba\u6742\u800c\u5bfc\u81f4\u7684\u5bc6\u96c6\u6676\u4f53\u7f3a\u9677\uff0c\u5305\u62ec\u5f3a\u70c8\u7684\u6676\u683c\u7578\u53d8\uff0c\u4f4d\u9519\u4ee5\u53ca\u5b8f\u89c2\u7684\u6676\u4f53\u5f2f\u66f2\uff0c\u8fd9\u4e9b\u6676\u4f53\u7f3a\u9677\u80fd\u591f\u6709\u6548\u5730\u6563\u5c04\u58f0\u5b50\uff0c\u8fdb\u800c\u964d\u4f4e\u70ed\u5bfc\u7387\u3002\u6b64\u5916\uff0c\u9488\u5bf9\u4e8e\u9511\u5143\u7d20\u63ba\u6742\u673a\u7406\u7684\u7814\u7a76\uff0c\u901a\u8fc7XRD\uff0cXPS\uff0cSEM\u4ee5\u53caTEM\u7b49\u8868\u5f81\u624b\u6bb5\uff0c\u8be5\u56e2\u961f\u53d1\u73b0\u5728\u6eb6\u5242\u70ed\u6cd5\u5408\u6210\u7852\u5316\u9521\u5fae\u6676\u7684\u8fc7\u7a0b\u4e2d\uff0c\u63ba\u5165\u7684\u9511\u5143\u7d20\u663e\u793a-3\u4ef7\uff0c\u5176\u80fd\u591f\u53d6\u4ee3\u7852\u7684\u4f4d\u7f6e\u5e76\u751f\u6210\u989d\u5916\u7684\u7852\u7a7a\u4f4d\uff0c\u56e0\u800c\u4f7f\u8be5\u6750\u6599\u4f53\u7cfb\u5c55\u73b0\u51fan\u578b\u534a\u5bfc\u4f53\u7279\u6027\u3002\u8be5\u5de5\u4f5c\u586b\u8865\u4e86\u7852\u5316\u9521\u57fa\u5757\u4f53\u70ed\u7535\u6750\u6599\u4e2dn\u578b\u9511\u63ba\u6742\u673a\u7406\u7684\u7a7a\u767d\uff0c\u5e76\u4e3a\u8fdb\u4e00\u6b65\u63d0\u9ad8n\u578b\u591a\u6676\u7852\u5316\u9521\u7684\u9ad8\u70ed\u7535\u6027\u80fd\u63d0\u4f9b\u4e86\u65b0\u7684\u601d\u8def\u3002\u76f8\u5173\u6210\u679c\u53d1\u8868\u4e8e\u56fd\u9645\u9876\u7ea7\u80fd\u6e90\u671f\u520aAdvanced Energy Materials\uff08Adv. Energy Mater. 8.21 (2018): 1800775.\uff09\u3002<\/p>\n<p><strong><b>\u56fe4<\/b><\/strong>\u00a0Sb\u63ba\u6742\u7684SnSe\u5fae\u6676<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"wp-image-168788 size-full aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2019\/03\/\u56fe\u724713-1.png\" alt=\"\" width=\"600\" height=\"580\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2019\/03\/\u56fe\u724713-1.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2019\/03\/\u56fe\u724713-1-300x290.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>\uff08a\uff09\u4f4e\u500dSEM\u7167\u7247\u89c2\u5bdf\u5176\u8868\u9762\u5b8f\u89c2\u7f3a\u9677\uff1b\uff08b\uff09TEM\u7167\u7247\u89c2\u5bdf\u5176\u7f3a\u9677\u7fa4\uff1b\uff08c\uff09HRTEM\u89c2\u5bdf\u5176\u6676\u683c\u626d\u66f2\uff1b\uff08d\uff09\u70e7\u7ed3\u5757\u4f53\u5207\u7247\u7684TEM\u7167\u7247\uff1b(e) \u70e7\u7ed3\u5757\u4f53\u5207\u7247\u7684\u7403\u5deeTEM\u7167\u7247\uff1b\uff08f\uff09\u70e7\u7ed3\u5757\u4f53\u7684XRD\u7ed3\u679c\uff1b\uff08g\uff09\u57fa\u4e8e\uff08100\uff09\u7684\u80fd\u8c31\u7ebf\u626b\u7ed3\u679c\u8bc1\u660eSb\u591a\u6570\u4ee3\u4f4d\u4e8eSe\u4f4d\uff1b\uff08h\uff09\u70ed\u7535\u4f18\u503c\u3002<\/p>\n<p>\u5728\u57fa\u4e8e\u9ad8Sn\u7a7a\u4f4d\u6d53\u5ea6\u7684\u57fa\u7840\u4e0a\uff0c\u8be5\u56e2\u961f\u9996\u6b21\u5b9e\u73b0\u4e86<strong><b>\u5177\u6709\u9ad8\u5bc6\u5ea6\u7eb3\u7c73\u5b54\u7ed3\u6784<\/b><\/strong>\u7684p\u578b\u7852\u5316\u9521\u591a\u6676\u5757\u4f53\uff0c\u5176ZT\u503c\u5728773K\u4e0b\u53ef\u8fbe\u52301.1\uff0c\u5982\u56fe5\u6240\u793a\u3002\u8fd9\u79cd\u6750\u6599\u6240\u5c55\u73b0\u51fa\u6765\u7684\u4f18\u5f02\u7684\u70ed\u7535\u6027\u80fd\u5f97\u76ca\u4e8e\u5176<strong><b>\u8f83\u4f4e\u7684\u70ed\u5bfc\u7387\uff080.<\/b><\/strong><strong><b>24 <\/b><\/strong><strong><b>W m<\/b><\/strong><strong><sup><b>-1<\/b><\/sup><\/strong><strong><b>\u00a0K<\/b><\/strong><strong><sup><b>-1<\/b><\/sup><\/strong><strong><b>\uff09<\/b><\/strong>\u3002\u5c3d\u7ba1\u5728\u5f15\u5165\u9ad8\u5bc6\u5ea6\u7eb3\u7c73\u5b54\u540e\u7531\u4e8e\u6750\u6599\u7535\u963b\u7684\u589e\u52a0\u5bfc\u81f4\u8be5\u5757\u4f53\u6750\u6599\u7684\u529f\u7387\u56e0\u5b50\u6709\u6240\u964d\u4f4e\uff08\u7ea623%\uff09\uff0c\u7136\u800c\u7531\u4e8e\u5f15\u5165\u4e86\u9ad8\u5bc6\u5ea6\u7684\u7eb3\u7c73\u5b54\uff0c\u8fd9\u4e9b\u7eb3\u7c73\u5b54\u660e\u663e\u5730\u963b\u788d\u4e86\u70ed\u6d41\u7684\u4f20\u5bfc\u5e76\u540c\u65f6\u6709\u6548\u5730\u6563\u5c04\u58f0\u5b50\uff0c\u4f7f\u5f97\u5176\u70ed\u5bfc\u7387\u5927\u5e45\u5ea6\u964d\u4f4e\uff08\u7ea643%\uff09\uff0c\u56e0\u800cZT\u503c\u76f8\u6bd4\u4e8e\u6ca1\u6709\u7eb3\u7c73\u5b54\u65f6\u63d0\u5347\u4e86\u8fd135%\u3002\u5728\u7eb3\u7c73\u5b54\u7ed3\u6784\u7684\u8bbe\u8ba1\u65b9\u6848\u4e0a\uff0c\u8be5\u56e2\u961f\u9996\u5148\u5229\u7528\u6eb6\u5242\u70ed\u6cd5\u5b9e\u73b0\u4e86<strong><b>\u5177\u6709\u9ad8\u5bc6\u5ea6\u7852\u5316\u94df\u7eb3\u7c73\u6790\u51fa\u76f8<\/b><\/strong>\u7684\u7852\u5316\u9521\u5fae\u6676\uff0c\u7136\u540e\u5229\u7528\u7b49\u79bb\u5b50\u4f53\u653e\u7535\u70e7\u7ed3\u5de5\u827a\u5bf9\u8fd9\u4e9b\u5fae\u6676\u8fdb\u884c\u70e7\u7ed3\uff0c\u5728\u70e7\u7ed3\u7684\u8fc7\u7a0b\u4e2d\u5229\u7528\u7852\u5316\u94df\u7eb3\u7c73\u6790\u51fa\u76f8\u7684\u5206\u89e3\u6e29\u5ea6\u6bd4\u7852\u5316\u9521\u7684\u7194\u70b9\u4f4e\u8fd9\u4e00\u6761\u4ef6\uff0c\u901a\u8fc7<strong><b>\u9ad8\u6e29\u9ad8\u538b\u9ad8\u771f\u7a7a\u73af\u5883<\/b><\/strong>\u4f7f\u7852\u5316\u94df\u7eb3\u7c73\u6790\u51fa\u76f8\u5728\u70e7\u7ed3\u7684\u8fc7\u7a0b\u4e2d\u5b8c\u5168\u5206\u89e3\uff0c\u751f\u6210\u6db2\u6001\u7852\u5355\u8d28\u4ee5\u53ca\u94df\u5355\u8d28\u3002\u6db2\u6001\u7852\u5728\u9ad8\u538b\u4e0b\u88ab\u6210\u529f\u6324\u51fa\uff0c\u800c\u94df\u5355\u8d28\u5219\u5728\u9ad8\u771f\u7a7a\u73af\u5883\u4e0b\u5347\u534e\u4e3a\u6c14\u6001\u5e76\u6392\u51fa\uff0c\u56e0\u6b64\u5728\u5757\u4f53\u4e2d\u5f62\u6210\u4e86\u9ad8\u5bc6\u5ea6\u7684\u7eb3\u7c73\u5b54\u6d1e\u3002\u8be5\u56e2\u961f\u901a\u8fc7XRD\uff0cSEM\uff0cEDS\u4ee5\u53ca\u9ad8\u5206\u8fa8TEM\u7b49\u8868\u5f81\u624b\u6bb5\u8bc1\u5b9e\u4e86\u7852\u5316\u9521\u5fae\u6676\u4e2d\u7852\u5316\u94df\u7eb3\u7c73\u6790\u51fa\u76f8\u7684\u5f62\u6210\u4e0e\u5177\u4f53\u7ec4\u6210\u6210\u5206\uff0c\u901a\u8fc7<strong><b>\u70ed\u91cd\u5206\u6790\u548c\u5dee\u70ed\u5206\u6790\u66f2\u7ebf<\/b><\/strong>\u8bc1\u5b9e\u4e86\u7852\u5316\u94df\u7eb3\u7c73\u6790\u51fa\u76f8\u7684\u5206\u89e3\uff0c\u5e76\u901a\u8fc7XRD\uff0cXPS\uff0cSEM\uff0cEDS\u4ee5\u53ca\u9ad8\u5206\u8fa8TEM\u7b49\u8868\u5f81\u624b\u6bb5\u8bc1\u5b9e\u4e86\u70e7\u7ed3\u540e\u7684\u5757\u4f53\u4e2d\u6240\u5f62\u6210\u7684\u5bc6\u96c6\u5b54\u7ed3\u6784\u3002\u5176\u5b54\u5f84\u5927\u5c0f\u8f83\u4e3a\u5747\u5300\u4e14\u5e73\u5747\u5b54\u5f84\u53ea\u6709\u7ea650\u7eb3\u7c73\uff0c\u56e0\u6b64\u8be5\u5757\u4f53\u6750\u6599\u662f\u4e00\u79cd\u5178\u578b\u7684\u7eb3\u7c73\u5b54\u7ed3\u6784\u70ed\u7535\u6750\u6599\u3002\u8be5\u5de5\u4f5c\u586b\u8865\u4e86\u591a\u6676\u7852\u5316\u9521\u57fa\u7eb3\u7c73\u5b54\u70ed\u7535\u6750\u6599\u7684\u5408\u6210\u7a7a\u767d\u3002\u76f8\u5173\u6210\u679c\u53d1\u8868\u4e8e\u7f8e\u56fd\u5316\u5b66\u4f1a(ACS)\u65d7\u4e0b\u9876\u7ea7\u7eb3\u7c73\u671f\u520aACS Nano\uff08ACS nano 12.11 (2018): 11417-11425.\uff09\u3002<\/p>\n<p><strong><b>\u56fe5<\/b><\/strong>\u00a0\u5177\u6709\u7eb3\u7c73\u5b54\u7684SnSe<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"wp-image-168789 size-full aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2019\/03\/\u56fe\u724714-1.png\" alt=\"\" width=\"600\" height=\"547\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2019\/03\/\u56fe\u724714-1.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2019\/03\/\u56fe\u724714-1-300x274.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>\uff08a\uff09\u7eb3\u7c73\u5b54\u8bbe\u8ba1\u601d\u8def\u4ee5\u53caTEM\u7ed3\u679c\u4ee5\u8bc1\u660e\u7852\u5316\u94df\u7eb3\u7c73\u76f8\u548c\u5408\u6210\u4e0e\u53bb\u9664\uff1b\uff08b\uff09DTA\u66f2\u7ebf\u4ee5\u8bc1\u660e\u7852\u5316\u94df\u7eb3\u7c73\u76f8\u7684\u53bb\u9664\uff1b\uff08c\uff09\u70ed\u7535\u4f18\u503c\u3002<\/p>\n<p>\u4e3a\u4e86\u80fd\u591f\u8fdb\u4e00\u6b65\u63d0\u9ad8Sn\u7684\u7a7a\u4f4d\u7387\u4ee5\u5b9e\u73b0\u8f7d\u6d41\u5b50\u6d53\u5ea6\u7684\u8fdb\u4e00\u6b65\u4f18\u5316\uff0c\u8be5\u56e2\u961f\u9996\u6b21\u5b9e\u73b0\u4e86<strong><b>Cd\u63ba\u6742<\/b><\/strong>\u7684SnSe\u5fae\u7c73\u7ea7\u5355\u6676\u7247\uff0c\u5982\u56fe6\u6240\u793a\uff0c\u4f7f\u70ed\u7535\u4f18\u503c\u5f97\u5230\u4e86\u8fdb\u4e00\u6b65\u7684\u63d0\u9ad8\u3002\u901a\u8fc7\u7b2c\u4e00\u6027\u539f\u7406\u8ba1\u7b97\u5f97\u77e5Cd\u7684\u6210\u529f\u63ba\u6742\u53ef\u4ee5<strong><b>\u4f7fSn\u7684\u7a7a\u4f4d\u5f62\u6210\u80fd\u663e\u8457\u964d\u4f4e<\/b><\/strong>\uff0c\u8fdb\u800c\u5f97\u5230<strong><b>\u66f4\u9ad8\u7684\u7a7a\u4f4d\u7387<\/b><\/strong>\uff0c\u800c\u5b9e\u9a8c\u7ed3\u679c\u8bc1\u5b9e\u4e86Cd\u7684\u63ba\u6742\u53ef\u4ee5\u4f7fSn\u7a7a\u4f4d\u7387\u63d0\u9ad8\u5230\u7ea62.9%\uff0c\u8fdb\u800c\u4f7f\u8f7d\u6d41\u5b50\u6d53\u5ea6\u5f97\u5230\u8fdb\u4e00\u6b65\u7684\u63d0\u9ad8\uff08\u7ea62.6\u00d710<sup>19<\/sup>\u00a0cm<sup>-3<\/sup>\uff09\uff0c<strong><b>\u5341\u5206\u63a5\u8fd1\u8f7d\u6d41\u5b50\u6d53\u5ea6\u7406\u8bba\u6700\u4f18\u503c<\/b><\/strong>\u3002\u540c\u65f6\uff0c\u8be5\u56e2\u961f\u901a\u8fc7XRD\uff0cSEM\uff0cEDS\u4ee5\u53ca\u9ad8\u5206\u8fa8TEM\u7b49\u8868\u5f81\u624b\u6bb5\u8bc1\u5b9e\u7531\u4e8eCd\u63ba\u6742\u5f15\u8d77\u4e86\u7684<strong><b>\u5bc6\u96c6\u6676\u4f53\u7f3a\u9677<\/b><\/strong>\uff0c\u5305\u62ec\u6676\u683c\u7578\u53d8\uff0c\u4f4d\u9519\uff0c\u5b8f\u89c2\u6676\u4f53\u751f\u957f\u7f3a\u9677\u4ee5\u53ca\u5bc6\u96c6\u7684\u7a7a\u4f4d\u7fa4\u7b49\uff0c\u8fd9\u4e9b\u6676\u4f53\u7f3a\u9677\u80fd\u591f\u6709\u6548\u5730\u6563\u5c04\u4e0d\u540c\u9891\u7387\u7684\u58f0\u5b50\uff0c\u8fdb\u800c\u6709\u6548\u964d\u4f4e\u70ed\u5bfc\u7387\u3002\u901a\u8fc7\u57fa\u4e8e\u80fd\u5e26\u7ed3\u6784\u548c\u6001\u5bc6\u5ea6\u5206\u5e03\u7684\u7b2c\u4e00\u6027\u539f\u7406\u8ba1\u7b97\u53d1\u73b0\uff0cCd\u5143\u7d20\u7684\u63ba\u6742\u6240\u5bfc\u81f4\u7684\u9633\u79bb\u5b50\u7a7a\u4f4d\u7387\u63d0\u5347\u80fd\u591f\u4f7f\u8d39\u7c73\u80fd\u7ea7\u5411\u4ef7\u5e26\u65b9\u5411\u79fb\u52a8\uff0c\u56e0\u6b64\u5176\u5177\u5907\u6f5c\u529b\u91ca\u653e\u66f4\u591a\u7a7a\u7a74\uff0c\u4e3aCd\u63ba\u6742\u5bf9\u8f7d\u6d41\u5b50\u6d53\u5ea6\u7684\u8fdb\u4e00\u6b65\u8c03\u63a7\u63d0\u4f9b\u4e86\u7269\u7406\u652f\u6301\u3002\u8be5\u5de5\u4f5c\u586b\u8865\u4e86\u7852\u5316\u9521\u57fa\u5757\u4f53\u70ed\u7535\u6750\u6599\u4e2d\u94dc\u63ba\u6742\u673a\u7406\u7684\u7a7a\u767d\uff0c\u5e76\u4e3a\u8fdb\u4e00\u6b65\u63d0\u9ad8\u591a\u6676\u7852\u5316\u9521\u7684\u70ed\u7535\u6027\u80fd\u63d0\u4f9b\u4e86\u65b0\u7684\u601d\u8def\u3002\u76f8\u5173\u6210\u679c\u53d1\u8868\u4e8e\u56fd\u9645\u9876\u7ea7\u80fd\u6e90\u671f\u520aAdvanced Energy Materials\uff08Adv.\u00a0Energy Mater.(2019): 1803242.\uff09\u3002<\/p>\n<p><strong><b>\u56fe6<\/b><\/strong>\u00a0Cd\u63ba\u6742\u7684SnSe<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"wp-image-168790 size-full aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2019\/03\/\u56fe\u724715-1.png\" alt=\"\" width=\"600\" height=\"346\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2019\/03\/\u56fe\u724715-1.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2019\/03\/\u56fe\u724715-1-300x173.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>\uff08a\uff09\u8ba1\u7b97\u5f97\u5230\u7684\u8f7d\u6d41\u5b50\u6d53\u5ea6\u4e0e\u529f\u7387\u56e0\u5b50\u53ca\u70ed\u5bfc\u7387\u7684\u5173\u7cfb\uff1b\uff08b\uff09\u8ba1\u7b97\u5f97\u5230\u7684\u6700\u4f18\u8f7d\u6d41\u5b50\u6d53\u5ea6\u533a\u95f4\uff1b\uff08c\uff09\u7b2c\u4e00\u6027\u539f\u7406\u8ba1\u7b97\u8bc1\u660eCd\u63ba\u6742\u5f15\u8d77Sn\u7a7a\u4f4d\u5f62\u6210\u80fd\u4e0b\u964d\uff1b\uff08d\uff09\u6001\u5bc6\u5ea6\u7ed3\u679c\uff1b\u4ee5\u53ca\uff08e\uff09\u6750\u6599\u4e2d\u5b58\u5728\u7684\u6240\u6709\u58f0\u5b50\u6563\u5c04\u6e90\u7684\u793a\u610f\u56fe\u3002<\/p>\n<p>\u5bf9\u4e8e\u5355\u6676SnSe\uff0c\u8be5\u56e2\u961f\u4e0e\u4e0a\u6d77\u7535\u673a\u5b66\u9662\u91d1\u654f\u56e2\u961f\u5408\u4f5c\uff0c\u5b9e\u73b0\u4e86<strong><b>\u8d85\u5927\u5c3a\u5bf8SnSe\u5355\u6676<\/b><\/strong>\u7684\u5408\u6210\u5236\u5907\u53ca\u6027\u80fd\u8868\u5f81\uff0c\u5982\u56fe7\u6240\u793a\u3002\u901a\u8fc7\u5de5\u827a\u53c2\u6570\u7684\u6539\u8fdb\u5f97\u5230\u4e86\u5c3a\u5bf8\u4e3a70 mm\u00d750 mm\u00d715 mm \u7684\u8d85\u5927\u5355\u6676\uff0c\u5176<strong><b>\u8d28\u91cf\u8fbe\u5230148 g<\/b><\/strong>\uff0c\u8fdc\u8d85\u4e4b\u524d\u6240\u62a5\u9053\u7684\u6c34\u5e73\u3002\u8be5\u56e2\u961f\u901a\u8fc7XRD\uff0cXPS\uff0cSEM\uff0cTEM\uff0cEDS\uff0cTEM\u4ee5\u53ca\u9ad8\u5206\u8fa8\u7403\u5deeTEM\u7b49\u8868\u5f81\u624b\u6bb5\u8bc1\u5b9e\u5355\u6676\u7684\u6210\u529f\u5236\u5907\uff0c\u540c\u65f6\u53d1\u73b0\u8be5\u5355\u6676\u5177\u6709<strong><b>\u8f83\u9ad8\u7684\u5bc6\u5ea6<\/b><\/strong><strong><b>\uff08<\/b><\/strong><strong><b>6.1 g cm<\/b><\/strong><strong><sup><b>-3<\/b><\/sup><\/strong><strong><b>\uff09<\/b><\/strong>\u548c<strong><b>\u7a33\u5b9a\u7684\u70ed\u7535\u6027\u80fd<\/b><\/strong>\u3002\u5b9e\u9a8c\u6d4b\u8bd5\u7ed3\u679c\u8bc1\u5b9e\u5176\u5177\u6709\u7ea60.3 % \u7684Sn\u7a7a\u4f4d\uff0c\u8fd9\u4e9bSn\u7a7a\u4f4d\u5bfc\u81f4\u4e86\u8f83\u9ad8\u7684\u8f7d\u6d41\u5b50\u6d53\u5ea6\uff08793K\u4e0b\u901a\u8fc7\u8fdb\u4e00\u6b65\u70ed\u6fc0\u53d1\u53ef\u8fbe\u52301.2\u00d710<sup>19<\/sup>\u00a0cm<sup>-3<\/sup>\uff09\uff0c\u8fdb\u800c\u5f97\u5230\u8f83\u9ad8\u7684\u529f\u7387\u56e0\u5b50\uff086.1 \u03bcW cm<sup>-1<\/sup>\u00a0K<sup>-2<\/sup>\uff09\u3002\u540c\u65f6\uff0c\u6676\u4f53\u4e2d\u5b58\u5728\u7684Sn\u7a7a\u4f4d\u70b9\u7f3a\u9677\u53ef\u4ee5\u6709\u6548\u6563\u5c04\u9ad8\u9891\u58f0\u5b50\uff0c\u8fdb\u800c\u8fdb\u4e00\u6b65\u964d\u4f4e\u70ed\u5bfc\u7387\uff080.39 W m<sup>-1<\/sup>\u00a0K<sup>-1<\/sup>\uff09\uff0c\u5e76\u5f97\u5230\u8f83\u9ad8\u7684\u70ed\u7535\u4f18\u503c\uff08793K\u4e0b\u7ea6\u4e3a1.24\uff09\u3002\u76f8\u5173\u6210\u679c\u53d1\u8868\u4e8eACS\u65d7\u4e0b\u8457\u540d\u6750\u6599\u671f\u520aACS Applied Materials &amp; Interface\uff08ACS\u00a0Appl.\u00a0Mater. Inter. 2019, 11, 8, 8051-8059\uff09\u3002<\/p>\n<p><strong><b>\u56fe7<\/b><\/strong>\u00a0\u8d85\u5927\u5c3a\u5bf8SnSe\u5355\u6676<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"wp-image-168791 size-full aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2019\/03\/\u56fe\u724716-1.png\" alt=\"\" width=\"600\" height=\"248\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2019\/03\/\u56fe\u724716-1.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2019\/03\/\u56fe\u724716-1-300x124.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>\uff08a\uff09\u5236\u5907\u5de5\u827a\u793a\u610f\u56fe\uff1b\uff08b\uff09\u5236\u5907\u5de5\u827a\u6e29\u5ea6\u53c2\u6570\uff1b\uff08c\uff09\u5236\u5f97\u7684\u539f\u59cbSnSe\u6837\u54c1\uff1b\uff08d\uff09\u6e05\u6d17\u540e\u5f97\u5230\u7684\u5355\u6676\u4f53\uff1b\uff08e\uff09\u5355\u6676\u8868\u9762\u7684Sn\u7a7a\u4f4d\uff1b\uff08f\uff09Sn\u7a7a\u4f4d\u5f15\u8d77\u7684\u6001\u5bc6\u5ea6\u7684\u53d8\u5316\uff1b\uff08g\uff09\u70ed\u7535\u4f18\u503c\uff1b\u4ee5\u53ca\uff08h\uff09\u5355\u80fd\u5e26\u6a21\u578b\u8ba1\u7b97\u7684\u4e0d\u540c\u6e29\u5ea6\u4e0b\u8f7d\u6d41\u5b50\u6d53\u5ea6\u4e0e\u70ed\u7535\u4f18\u503c\u4e4b\u95f4\u7684\u5173\u7cfb\u3002<\/p>\n<p>\u57fa\u4e8e\u8fd9\u4e9b\u539f\u521b\u5de5\u4f5c\uff0c\u8bfe\u9898\u7ec4\u53d1\u8868\u4e86SnSe\u57fa\u70ed\u7535\u6750\u6599\u7684\u7efc\u8ff0\u6587\u7ae0 \uff08Progress in Materials Science, 2018, 97: 283-346\uff09\uff0c\u603b\u7ed3\u4e86SnSe\u7684\u7ed3\u6784\u7279\u5f81\u4e0e\u5176\u9ad8\u70ed\u7535\u6027\u80fd\u4e4b\u95f4\u7684<strong><b>\u5185\u5728\u8054\u7cfb<\/b><\/strong>\uff0c\u5305\u62ec<strong><b>\u70ed\u529b\u5b66<\/b><\/strong>\uff0c<strong><b>\u6676\u4f53\u7ed3\u6784<\/b><\/strong>\u548c<strong><b>\u7535\u5b50\u7ed3\u6784<\/b><\/strong>\uff0c\u5e76\u8be6\u7ec6\u8ba8\u8bba\u4e86<strong><b>\u58f0\u5b50\u6563\u5c04<\/b><\/strong>\uff0c\u6750\u6599<strong><b>\u5185\u5916\u5e94\u529b<\/b><\/strong>\uff0c\u4ee5\u53ca<strong><b>\u6c27\u5316\u884c\u4e3a<\/b><\/strong>\u5bf9\u5176\u70ed\u7535\u6027\u80fd\u7684\u5f71\u54cd\u3002\u6b64\u5916\uff0c\u8be5\u7efc\u8ff0\u603b\u7ed3\u4e86\u9488\u5bf9\u4e8e\u7852\u5316\u9521\u7684<strong><b>\u7406\u8bba\u8ba1\u7b97<\/b><\/strong>\u4ee5\u9884\u6d4b\u5176\u70ed\u7535\u6027\u80fd\u6f5c\u529b\uff0c<strong><b>\u4ee5\u53ca\u8fd1\u5e74\u6765\u5173\u4e8e\u7852\u5316\u9521\u5355\u6676\u3001\u591a\u6676\u5757\u4f53\u6750\u6599<\/b><\/strong>\uff0c\u4ee5\u53ca<strong><b>\u4e8c\u7ef4\u6750\u6599<\/b><\/strong>\u7684\u5408\u6210\u5de5\u827a\uff0c\u7ed3\u6784\u8868\u5f81\u548c\u70ed\u7535\u6027\u80fd\u3002\u6700\u540e\uff0c\u8be5\u7efc\u8ff0\u6307\u51fa\u4e86\u76ee\u524d\u9488\u5bf9\u4e8e\u7852\u5316\u9521\u57fa\u70ed\u7535\u6750\u6599\u6240\u5b58\u5728\u7684<strong><b>\u4e89\u8bae\uff0c\u6311\u6218\uff0c\u4ee5\u53ca\u76f8\u5e94\u7684\u7b56\u7565<\/b><\/strong>\uff0c\u5982\u56fe8\u6240\u793a\u3002<\/p>\n<p><strong><b>\u56fe<\/b><\/strong><strong><b>8<\/b><\/strong>\u00a0\u6307\u5357\u9488\u578b\u793a\u610f\u56fe\u4ee5\u8bf4\u660e\u63d0\u9ad8\u7852\u5316\u9521\u57fa\u70ed\u7535\u6750\u6599\u6027\u80fd\u7684\u65b9\u6cd5\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"wp-image-168792 size-full aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2019\/03\/\u56fe\u724717-1.png\" alt=\"\" width=\"600\" height=\"600\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2019\/03\/\u56fe\u724717-1.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2019\/03\/\u56fe\u724717-1-150x150.png 150w, \/\/m.iemloyee.com\/wp-content\/uploads\/2019\/03\/\u56fe\u724717-1-300x300.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p><strong>\u56e2\u961f\u4ecb\u7ecd\uff1a<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"wp-image-168793 size-full aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2019\/03\/\u56fe\u724718-1.png\" alt=\"\" width=\"133\" height=\"171\" \/><\/p>\n<p><strong><b>\u9648\u5fd7\u521a\u6559\u6388<\/b><\/strong>\u662f\u6fb3\u5927\u5229\u4e9a\u5357\u6606\u58eb\u5170\u5927\u5b66\u80fd\u6e90\u5b66\u79d1\u8bb2\u5e2d\u6559\u6388\uff08Professor of Energy Materials\uff09\uff0c\u6fb3\u5927\u5229\u4e9a\u5357\u6606\u58eb\u5170\u5927\u5b66\u529f\u80fd\u6750\u6599\u5b66\u79d1\u5e26\u5934\u4eba\u3002\u957f\u671f\u4ece\u4e8b\u529f\u80fd\u6750\u6599\u5728\u80fd\u91cf\u8f6c\u5316\u7684\u57fa\u7840\u548c\u5e94\u7528\u7814\u7a76\u3002\u4ee5\u91d1\u5c5e\u6c27\u786b\u65cf\u5316\u5408\u7269\u4e3a\u7814\u7a76\u5207\u5165\u70b9\uff0c\u901a\u8fc7\u63a7\u5236\u6750\u6599\u7684\u6676\u4f53\u7ed3\u6784\u3001\u5c3a\u5bf8\u3001\u548c\u63ba\u6742\u6539\u6027\u6765\u8c03\u63a7\u5176\u5149\uff0c\u7535\uff0c\u5316\u5b66\u7279\u6027\u3002\u5f00\u53d1\u4e86\u6027\u80fd\u4f18\u8d8a\u7684\u70ed\u7535\u6750\u6599\uff0c\u5e76\u901a\u8fc7\u80fd\u5e26\u52a0\u5de5\u548c\u5fae\u89c2\u7ed3\u6784\u63a7\u5236\uff0c\u5b9e\u73b0\u4e86\u70ed\u7535\u6027\u80fd\u7684\u63d0\u5347\uff1b\u901a\u8fc7\u5bf9\u91d1\u5c5e\u6c27\u786b\u65cf\u5316\u5408\u7269\u8868\u9762\u4f20\u8f93\u7279\u6027\u7684\u7406\u89e3\u548c\u7814\u5236\uff0c\u5f00\u53d1\u4e86\u65b0\u4e00\u4ee3\u7684\u72c4\u62c9\u514b\u534a\u91d1\u5c5e\u6750\u6599\uff0c\u4e3a\u5f00\u53d1\u65b0\u4e00\u4ee3\u7535\u5b50\u6750\u6599\u63d0\u4f9b\u65b0\u7684\u7814\u7a76\u5e73\u53f0\u3002\u9648\u5fd7\u521a\u6559\u6388\u5e08\u4ece\u6210\u4f1a\u660e\u9662\u58eb\u548c\u902f\u9ad8\u6e05\u9662\u58eb\u30022008\u5e74\u535a\u58eb\u6bd5\u4e1a\u540e\u5373\u6210\u529f\u7533\u8bf7\u5230\u201c\u6fb3\u5927\u5229\u4e9a\u7814\u7a76\u7406\u4e8b\u4f1a\u535a\u58eb\u540e\u7814\u7a76\u5458\u201d\u804c\u4f4d\uff0c\u524d\u5f80\u6fb3\u5927\u5229\u4e9a\u6606\u58eb\u5170\u5927\u5b66\u673a\u68b0\u4e0e\u77ff\u4e1a\u5b66\u9662\u5de5\u4f5c\uff0c\u5148\u540e\u62c5\u4efb\u7814\u7a76\u5458\uff0c\u9ad8\u7ea7\u7814\u7a76\u5458\uff0c\u8363\u8a89\u526f\u6559\u6388\uff0c\u540e\u8f6c\u5165\u6fb3\u5927\u5229\u4e9a\u5357\u6606\u58eb\u5170\u5927\u5b66\u62c5\u4efb\u529f\u80fd\u6750\u6599\u5b66\u79d1\u5e26\u5934\u4eba\uff0c\u5148\u540e\u4e3b\u6301\u5171\u8ba1\u4e03\u767e\u4e07\u6fb3\u5143\u7684\u79d1\u7814\u9879\u76ee\uff0c\u5176\u4e2d\u5305\u62ec6\u9879\u6fb3\u5927\u5229\u4e9a\u7814\u7a76\u59d4\u5458\u4f1a\u30011\u9879\u6fb3\u5927\u5229\u4e9a\u79d1\u5b66\u9662\u30012\u9879\u5dde\u653f\u5e9c\u300110\u9879\u5de5\u4e1a\u9879\u76ee\u548c10\u9879\u6821\u7ea7\u7684\u79d1\u7814\u9879\u76ee\u3002\u5728\u5357\u6606\u58eb\u5170\u5927\u5b66\u548c\u6606\u58eb\u5170\u5927\u5b66\u5de5\u4f5c\u671f\u95f4\uff0c\u5171\u6307\u5bfc17\u540d\u535a\u58eb\u751f\u548c3\u540d\u7855\u58eb\u7814\u7a76\u751f\uff0c\u5176\u4e2d\u5df2\u6bd5\u4e1a\u535a\u58eb\u751f5\u540d\u548c\u7855\u58eb\u751f2\u540d\u3002\u5728Nat. Nanotech. \uff081\u7bc7\uff09\u3001 Nat. Commun. \uff083\u7bc7\uff09\u3001 Prog. Mater. Sci. \uff081\u7bc7\uff09\u3001 Adv. Mater. \uff087\u7bc7\uff09\u3001 J. Am. Chem. Soc. \uff083\u7bc7\uff09\u3001Angew. Chem. Int. Edit.,\uff082\u7bc7\uff09, Nano Lett. \uff083\u7bc7\uff09\u3001Energy Environ. Sci. \uff081\u7bc7\uff09\u3001ACS Nano\uff0813\u7bc7\uff09\u3001Adv. Energy Mater. \uff087\u7bc7\uff09\u3001Adv. Funct. Mater. \uff088\u7bc7\uff09\u3001Nano Energy\uff086\u7bc7\uff09\u548c Energy Storage Mater. \uff081\u7bc7\uff09\u7b49\u56fd\u9645\u5b66\u672f\u671f\u520a\u4e0a\u53d1\u8868200\u4f59\u7bc7\u5b66\u672f\u8bba\u6587\u3002\u8fd9\u4e9b\u8bba\u6587\u5171\u88abScopus\u5f15\u752810200\u4f59\u6b21\uff0cH-index\u8fbe\u523052\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"wp-image-168794 size-full aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2019\/03\/\u56fe\u724719-1.png\" alt=\"\" width=\"127\" height=\"171\" \/><\/p>\n<p><strong>\u90b9\u8fdb\u6559\u6388<\/strong>\u73b0\u4efb\u6fb3\u5927\u5229\u4e9a\u6606\u58eb\u5170\u5927\u5b66\u7684\u7eb3\u7c73\u79d1\u5b66\u8bb2\u5e2d\u6559\u6388\uff08Chair in Nanoscience\uff09\uff0c\u66fe\u4efb\u6fb3\u5927\u5229\u4e9a\u7535\u5b50\u663e\u5fae\u5b66\u4f1a\u79d8\u4e66\u957f\uff0c\u53ca\u6fb3\u5927\u5229\u4e9a\u6606\u58eb\u5170\u534e\u4eba\u5de5\u7a0b\u5e08\u4e0e\u79d1\u5b66\u5bb6\u534f\u4f1a\u526f\u4f1a\u957f\u3002\u90b9\u8fdb\u6559\u6388\u76ee\u524d\u7684\u7814\u7a76\u65b9\u5411\u5305\u62ec\uff1a\u534a\u5bfc\u4f53\u7eb3\u7c73\u7ed3\u6784\uff08\u91cf\u5b50\u70b9\uff0c\u7eb3\u7c73\u7ebf\uff0c\u7eb3\u7c73\u5e26\uff0c\u8d85\u7c3f\u7eb3\u7c73\u7247\uff09\u7684\u5f62\u6210\u673a\u7406\u53ca\u5176\u7269\u7406\u6027\u80fd\u7684\u7814\u7a76\uff1b\u5148\u8fdb\u529f\u80fd\u7eb3\u7c73\u6750\u6599\u7684\u5f62\u6210\u53ca\u5176\u9ad8\u7aef\u5e94\u7528\uff0c\u5c24\u5176\u5728\u80fd\u6e90\uff0c\u73af\u4fdd\u548c\u533b\u7597\u4e2d\u7684\u5e94\u7528\uff1b\u56fa\u4f53\u6750\u6599\u7684\u754c\u9762\u7814\u7a76\u3002\u90b9\u8fdb\u6559\u6388\u5728 ISI 9\uff08Web of Science\uff09 \u520a\u7269\u4e0a\u5df2\u53d1\u8868\u5b66\u672f\u8bba\u6587 650 \u591a\u7bc7\uff0c\u5176\u591a\u6570\u8bba\u6587\u53d1\u8868\u5728\u56fd\u9645\u77e5\u540d\u520a\u7269\u4e0a\u5e76\u88ab\u5f15\u7528 18,000\u6b21\u3002\u90b9\u8fdb\u6559\u6388\u76ee\u524d\u627f\u62c5\u591a\u9879\u6fb3\u5927\u5229\u4e9a\u7814\u7a76\u7406\u4e8b\u4f1a\u7684\u7814\u7a76\u8bfe\u9898\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-168795 aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2019\/03\/\u56fe\u724720-1.png\" alt=\"\" width=\"130\" height=\"170\" \/><\/p>\n<p><strong><b>\u53f2\u6653\u78ca<\/b><\/strong>\u4e8e2008\u5e74\u5728\u5317\u4eac\u79d1\u6280\u5927\u5b66\u6750\u6599\u79d1\u5b66\u4e0e\u5de5\u7a0b\u7cfb\u53d6\u5f97\u5b66\u58eb\u5b66\u4f4d\uff0c\u4e8e 2011 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in Materials Science \uff081\u7bc7\uff09\uff0cAdvanced Energy Materials\uff082\u7bc7\uff09\uff0cACS Nano\uff081\u7bc7\uff09\uff0cEnergy Storage Materials\uff081\u7bc7\uff09\uff0cNano Energy\uff081\u7bc7\uff09\uff0cCorrosion Science\uff081\u7bc7\uff09\u7b49\u56fd\u9645\u5b66\u672f\u671f\u520a\u4e0a\u53d1\u8868\u8bba\u658738\u7bc7\uff0c\u53d1\u660e\u4e13\u52292\u9879\uff0c\u5176\u4e2d\u4ee5\u7b2c\u4e00\u4f5c\u8005\u8eab\u4efd\u53d1\u8868\u8bba\u6587 14\u7bc7\u3002\u8fd9\u4e9b\u8bba\u6587\u88abSCI\u5f15\u7528400\u4f59\u6b21\uff0cH-index\u8fbe\u523011.<\/p>\n<p>\u53c2\u8003\u6587\u732e\uff1a<\/p>\n<p>1.Shi X, Chen Z G, Liu W, Yang L, Hong M, Moshwan R, Huang L, &amp; Zou J. Achieving high Figure of Merit in p-type polycrystalline Sn0.98Se via self-doping and anisotropy-strengthening. <strong><em><b><i>Energy Storage Materials<\/i><\/b><\/em><\/strong>, 2018, 10: 130-138.<\/p>\n<p>2.Shi X, Zheng K, Hong M, Liu W, Moshwan R, Wang Y, Qu X, Chen Z G, &amp; Zou J. Boosting the thermoelectric performance of p-type heavily Cu-doped polycrystalline SnSe via inducing intensive crystal imperfections and defect phonon scattering. <strong><em><b><i>Chemical Science<\/i><\/b><\/em><\/strong>, 2018, 9: 7376-7389.<\/p>\n<p>3.Shi X, Zheng K, Liu W, Wang Y, Yang Y, Chen Z G, &amp; Zou J. Realizing High Thermoelectric Performance in n-Type Highly Distorted Sb-Doped SnSe Microplates via Tuning High Electron Concentration and Inducing Intensive Crystal Defects. <strong><em><b><i>Advanced Energy Materials<\/i><\/b><\/em><\/strong>, 2018: 1800775.<\/p>\n<p>4.Shi X, Wu A, Liu W, Moshwan R, Wang Y, Chen Z G, &amp; Zou J. Polycrystalline SnSe with Extraordinary Thermoelectric Property via Nanoporous Design. <strong><em><b><i>ACS Nano<\/i><\/b><\/em><\/strong>, 2018, 12(11): 11417-11425.<\/p>\n<p>5.Shi X, Wu A, Feng T, Zheng K, Liu W, Sun Q, Hong M, Pantelides S T, Chen Z G, &amp; Zou J. High thermoelectric performance in p-type polycrystalline Cd-doped SnSe achieved by a combination of cation vacancies and localized lattice engineering. <strong><em><b><i>Advanced Energy Materials<\/i><\/b><\/em><\/strong>, 2019: 1803242.<\/p>\n<p>6.Jin M, Shi X (co-first author), Feng T, Liu W, Feng H, Pantelides S T, Jiang J, Chen Y, Du Y, Zou J, &amp; Chen Z G. Super Large Sn1-xSe Single Crystals with Excellent Thermoelectric Performance. <strong><em><b><i>ACS Applied Materials &amp; Interfaces<\/i><\/b><\/em><\/strong>, 2019, 11, 8, 8051-8059.<\/p>\n<p>7.Chen Z G, Shi X (co-first author), Zhao L D, &amp; Zou J. High-performance SnSe thermoelectric materials: Progress and future challenge. <strong><em><b><i>Progress in Materials Science<\/i><\/b><\/em><\/strong>, 2018, 97: 283-346.<\/p>\n<p>\u672c\u6587\u7531<strong>\u5357\u6606\u58eb\u5170\u5927\u5b66\u9648\u5fd7\u521a\u6559\u6388\u548c\u6606\u58eb\u5170\u5927\u5b66\u90b9\u8fdb\u6559\u6388\u7814\u7a76\u56e2\u961f<\/strong><strong><b>\u4f9b\u7a3f\uff0c<\/b><\/strong>\u6750\u6599\u4eba\u7f16\u8f91\u90e8Alisa\u7f16\u8f91\u3002<\/p>\n<p>\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1: tougao@cailiaoren.com.<\/p>\n<p>\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1acailiaorenVIP.<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u3010\u5f15\u8a00\u3011 \u70ed\u7535\u6750\u6599\u80fd\u591f\u5b9e\u73b0\u70ed\u80fd\u4e0e\u7535\u80fd\u7684\u76f4\u63a5\u8f6c\u6362\uff0c\u56e0\u6b64\u5728\u5e9f\u70ed\u56de\u6536\uff0c\u7a7a\u8c03\u548c\u5236\u51b7\u7b49\u5de5\u4e1a\u9886\u57df\u5177\u6709\u76f8\u5f53\u5e7f\u9614\u7684\u5e94\u7528\u524d\u666f\u3002\u4f5c\u4e3a\u65b0\u4e00\u4ee3\u70ed\u7535\u6750\u6599\u7684\u5178\u578b\u4ee3\u8868\uff0c\u7852\u5316\u9521\uff08SnSe\uff09\u7531\u4e8e&#8230;<\/p>\n","protected":false},"author":10213,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[],"class_list":["post-168784","post","type-post","status-publish","format-standard","hentry","category-jiedu"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/168784"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/10213"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=168784"}],"version-history":[{"count":2,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/168784\/revisions"}],"predecessor-version":[{"id":168797,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/168784\/revisions\/168797"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=168784"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=168784"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=168784"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}