{"id":168609,"date":"2019-03-04T06:42:29","date_gmt":"2019-03-03T22:42:29","guid":{"rendered":"\/\/m.iemloyee.com\/?p=168609"},"modified":"2019-03-03T20:33:17","modified_gmt":"2019-03-03T12:33:17","slug":"%e5%b7%b2%e6%a0%a1-j-am-chem-soc-%e5%8e%9f%e5%ad%90%e5%b1%82%e5%8e%9a%e5%8d%95%e6%99%b6invo4%e7%ba%b3%e7%b1%b3%e7%89%87%e7%9a%84%e5%88%b6%e5%a4%87%e5%8f%8a%e5%85%b6%e9%ab%98%e6%95%88%e3%80%81","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=168609","title":{"rendered":"J. Am. Chem. Soc. : \u539f\u5b50\u5c42\u539a\u5355\u6676InVO4\u7eb3\u7c73\u7247\u7684\u5236\u5907\u53ca\u5176\u9ad8\u6548\u3001\u9ad8\u9009\u62e9\u6027\u5149\u50ac\u5316CO2\u8fd8\u539f"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n

\n \u4f7f\u7528\u592a\u9633\u80fd\u5c06CO2<\/sub>\u50ac\u5316\u8fd8\u539f\u4e3a\u589e\u503c\u5316\u5b66\u54c1\u5f97\u5230\u4e86\u7814\u7a76\u4eba\u5458\u6781\u5927\u7684\u5173\u6ce8\u3002\u539f\u5b50\u5c42\u539a\u7684\u534a\u5bfc\u4f53\u53ef\u63d0\u4f9b\u4e30\u5bcc\u7684\u50ac\u5316\u6d3b\u6027\u4f4d\u70b9\u6765\u4fc3\u8fdbCO2<\/sub>\u8fd8\u539f\u3002\u8d85\u8584\u4e8c\u7ef4\u6750\u6599\u5177\u6709\u5927\u91cf\u4f4e\u914d\u4f4d\u8868\u9762\u539f\u5b50\uff0c\u5176\u53ef\u4f5c\u4e3a\u5f15\u53d1CO2<\/sub>\u8fd8\u539f\u53cd\u5e94\u7684\u50ac\u5316\u4f4d\u70b9\u3002\u539f\u5b50\u7ea7\u539a\u5ea6\u8fd8\u4f7f\u5f97\u5149\u751f\u8f7d\u6d41\u5b50\u6613\u4e8e\u4ece\u5185\u90e8\u8f6c\u79fb\u5230\u8868\u9762\uff0c\u540c\u65f6\u7f29\u77ed\u4e86\u7535\u8377\u8f6c\u79fb\u8ddd\u79bb\uff0c\u56e0\u6b64\u964d\u4f4e\u4e86\u4f53\u76f8\u590d\u5408\u3002\u867d\u7136\u5df2\u6210\u529f\u5236\u5907\u4e00\u4e9b\u539f\u5b50\u5c42\u539a\u4e8c\u7ef4\u4e8c\u5143\u91d1\u5c5e\u5316\u5408\u7269[\u5982MX2<\/sub>(M = Mo\uff0cW\u548cX = S\uff0cSe\uff0cTe)]\uff0c\u7531\u4e8e\u5728\u8fd9\u6837\u7684\u539f\u5b50\u6c34\u5e73\u4e0a\u63a7\u5236\u591a\u7ec4\u5206\u751f\u957f\u7684\u96be\u5ea6\u589e\u52a0\uff0c\u4e09\u5143\u534a\u5bfc\u4f53\u7b49\u590d\u6742\u5316\u5408\u7269\u7684\u5236\u5907\u53d7\u5230\u9650\u5236\u3002\u9492\u9178\u94df(InVO4<\/sub>)\u4f5c\u4e3a\u4e00\u79cd\u91cd\u8981\u7684\u4e09\u5143\u91d1\u5c5e\u6c27\u5316\u7269\u534a\u5bfc\u4f53\uff0c\u7531\u4e8e\u5176\u7a84\u5e26\u9699(~2.0 eV)\u548c\u5316\u5b66\u7a33\u5b9a\u6027\uff0c\u5728\u4e0d\u540c\u5149\u50ac\u5316\u9886\u57df\u6709\u671b\u5f97\u5230\u5e7f\u6cdb\u5e94\u7528\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\n \u8fd1\u65e5\uff0c\u5357\u4eac\u5927\u5b66\u5468\u52c7\u6559\u6388\u3001\u4e1c\u5357\u5927\u5b66\u738b\u91d1\u5170\u6559\u6388(\u5171\u540c\u901a\u8baf\u4f5c\u8005)\u7b49<\/strong>\u5408\u6210\u4e86\u5177\u6709~1.5 nm\u5747\u5300\u539a\u5ea6\u7684\u539f\u5b50\u5c42\u5355\u6676InVO4<\/sub>\u7247\u6750\uff0c\u5e76\u5728J. Am. Chem. Soc.<\/strong>\u4e0a\u53d1\u8868\u4e86\u9898\u4e3a\u201cConvincing Synthesis of Atomically-Thin, Single-Crystaline InVO4<\/sub> Sheets toward Promoting Highly Selective and Efficient Solar Conversion of CO2<\/sub> into CO<\/strong>\u201d\u7684\u7814\u7a76\u8bba\u6587\u3002\u4e0a\u8ff0\u7eb3\u7c73\u7247\u901a\u8fc7\u5f3a\u7684\u4f4e\u89d2\u5ea6X\u5c04\u7ebf\u884d\u5c04\u5cf0\u786e\u5b9a\u3002\u6cbf[110]\u53d6\u5411\u76843\u4e2a\u6676\u80de\u539aInVO4<\/sub>\u539f\u5b50\u5c42\u5728\u6c34\u84b8\u6c14\u5b58\u5728\u4e0b\u5177\u6709\u9ad8\u9009\u62e9\u6027\u548c\u9ad8\u6548\u7684\u5149\u50ac\u5316CO2<\/sub>\u8f6c\u5316\u4e3aCO\u6d3b\u6027\u3002\u8868\u9762\u7535\u4f4d\u53d8\u5316\u6d4b\u91cf\u548c\u6db2\u4f53\u5149\u81f4\u53d1\u5149\u8870\u51cf\u5149\u8c31\u8bc1\u5b9e\uff0c\u539f\u5b50\u8d85\u8584\u7ed3\u6784\u53ef\u4ee5\u7f29\u77ed\u8f7d\u6d41\u5b50\u4ece\u5185\u90e8\u5230\u8868\u9762\u7684\u8f6c\u79fb\u8ddd\u79bb\uff0c\u5e76\u51cf\u5c11\u4f53\u76f8\u590d\u5408\u3002\u56e0\u6b64\uff0c\u66f4\u591a\u7535\u5b50\u5728\u5176\u8868\u9762\u4e0a\u5b58\u7eed\u548c\u79ef\u7d2f\uff0c\u6709\u5229\u4e8eCO2<\/sub>\u7684\u6d3b\u5316\u548c\u8fd8\u539f\u3002\u6b64\u5916\uff0c\u53d1\u73b0InVO4<\/sub>\u539f\u5b50\u5c42\u7279\u5b9a\u66b4\u9732\u7684{110}\u9762\u4e0e\u4ea7\u751f\u7684CO\u76f8\u4e92\u4f5c\u7528\u5f88\u5f31\uff0c\u4fc3\u8fdb\u4ece\u50ac\u5316\u5242\u8868\u9762\u5feb\u901f\u89e3\u5438\u4ee5\u5f62\u6210\u6e38\u79bb\u7684CO\u5206\u5b50\uff0c\u4e3a\u50ac\u5316\u9009\u62e9\u6027CO\u4ea7\u7269\u63d0\u4f9b\u4e86\u7406\u60f3\u7684\u5e73\u53f0\u3002<\/p>\n

\u3010\u56fe\u6587\u7b80\u4ecb\u3011<\/strong>
\n \u56fe1 \u8d85\u8584InVO4<\/sub>\u7eb3\u7c73\u7247\u7684\u5f62\u8c8c\u8868\u5f81<\/strong><\/p>\n

\"\"<\/p>\n

a) \u8d85\u8584InVO4<\/sub>\u7eb3\u7c73\u7247\u7684\u4f4e\u500dSEM\u56fe\u50cf\uff1b
\n b) \u8d85\u8584InVO4<\/sub>\u7eb3\u7c73\u7247\u7684\u9ad8\u500dSEM\u56fe\u50cf\u3002<\/p>\n

\u56fe2 \u8d85\u8584InVO4<\/sub>\u7eb3\u7c73\u7247\u7684\u7ed3\u6784\u8868\u5f81<\/strong><\/p>\n

\"\"<\/p>\n

a) \u5206\u5b50\u8584InVO4<\/sub>\u7eb3\u7c73\u7247\u7684TEM\u56fe\u50cf\uff1b
\n b) \u5c40\u90e8\u653e\u5927\u7ec6\u8282\uff1b
\n c) \u5e73\u94fa\u7684HRTEM\u56fe\u50cf\uff1b
\n d) \u76f8\u5e94\u7684FFT\u56fe\u50cf\uff1b
\n e) \u6a2a\u5411HRTEM\u56fe\u50cf\uff1b
\n f) \u7eb3\u7c73\u7247\u7684\u6676\u4f53\u6a21\u578b\u3002<\/p>\n

\u56fe3 \u5149\u50ac\u5316\u8fd8\u539fCO2<\/sub>\u6d3b\u6027<\/strong><\/p>\n

\"\"<\/p>\n

a) \u5149\u50ac\u5316CO\u751f\u6210\u91cf\u968f\u5149\u7167\u65f6\u95f4\u7684\u53d8\u5316\uff1b
\n b) \u5149\u50ac\u5316CH4<\/sub>\u751f\u6210\u91cf\u968f\u5149\u7167\u65f6\u95f4\u7684\u53d8\u5316\uff1b
\n c) \u8d85\u8584InVO4<\/sub>\u7eb3\u7c73\u7247\u3001\u7eb3\u7c73\u7acb\u65b9\u4f53\u548c\u5757\u4f53\u6750\u6599(SSR)\u7684\u5149\u50ac\u5316\u6d3b\u6027\u6bd4\u8f83\uff1b
\n d) \u8d85\u8584InVO4<\/sub>\u7eb3\u7c73\u7247\u3001\u7eb3\u7c73\u7acb\u65b9\u4f53\u548c\u5757\u4f53\u6750\u6599\u7684\u5149\u50ac\u5316\u9009\u62e9\u6027\u6bd4\u8f83\u3002<\/p>\n

\u56fe4 \u8d85\u8584InVO4<\/sub>\u7eb3\u7c73\u7247\u7684\u5149\u751f\u8f7d\u6d41\u5b50\u5206\u79bb\u548c\u4f20\u8f93\u884c\u4e3a<\/strong><\/p>\n

\"\"<\/p>\n

a,a’) \u539f\u5b50\u5c42\u539aInVO4<\/sub>\u7eb3\u7c73\u7247\u7684\u9ad8\u5ea6\u56fe\u50cf\u4ee5\u53ca\u5149\u6697\u4e4b\u95f4\u7684\u5dee\u5206\u56fe\u50cf\uff1b
\n b,b’) \u7eb3\u7c73\u7acb\u65b9\u4f53\u7684\u9ad8\u5ea6\u56fe\u50cf\u4ee5\u53ca\u5149\u6697\u4e4b\u95f4\u7684\u5dee\u5206\u56fe\u50cf\uff1b
\n c,c’) SSR\u7684\u9ad8\u5ea6\u56fe\u50cf\u4ee5\u53ca\u5149\u6697\u4e4b\u95f4\u7684\u5dee\u5206\u56fe\u50cf\uff1b
\n d) \u8868\u9762\u5149\u7535\u538b\u7684\u53d8\u5316\uff0c\u901a\u8fc7\u6697\u5904\u7684\u7535\u4f4d\u51cf\u53bb\u5149\u7167\u4e0b\u7684\u7535\u4f4d(SPV\uff0c\u0394CPD=CPD\u6697<\/sub>-CPD\u5149<\/sub>)\u3002<\/p>\n

\u56fe5 \u8d85\u8584InVO4<\/sub>\u7eb3\u7c73\u7247\u5149\u50ac\u5316\u8fd8\u539fCO2<\/sub>\u53cd\u5e94\u5386\u7a0b\u7684\u7406\u8bba\u8ba1\u7b97<\/strong><\/p>\n

\"\"<\/p>\n

a) \u4f18\u5316InVO4<\/sub>\u7684(110)\u9762\u7684\u9876\u89c6\u56fe\u548c\u4fa7\u89c6\u56fe\uff0c\u5176\u4e2dIn\u3001V\u3001O\u3001C\u548cH\u539f\u5b50\u7531\u6d45\u7eff\u8272\u3001\u7d2b\u8272\u3001\u7ea2\u8272\u3001\u68d5\u8272\u548c\u767d\u8272\u7403\u4f53\u8868\u793a\uff0c\u9ed1\u8272\u865a\u7ebf\u5708\u8868\u793a\u6d3b\u6027\u4f4d\u70b9(\u4e0b\u540c)\uff1b
\n b) InVO4<\/sub>\u7684(100)\u9762\u7684\u9876\u89c6\u56fe\u548c\u4fa7\u89c6\u56fe\uff1b
\n c) (110)\u50ac\u5316(\u9ed1\u7ebf)\u548c(100)\u50ac\u5316(\u6a59\u7ebf)CO2<\/sub>\u8fd8\u539f\u4e3aCO\u7684\u5409\u5e03\u65af\u81ea\u7531\u80fd\u66f2\u7ebf\u8ba1\u7b97\u3002<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n

\n \u7efc\u4e0a\u6240\u8ff0\uff0c\u4f5c\u8005\u6210\u529f\u5730\u5408\u6210\u4e86\u539f\u5b50\u5c42\u539a\u7684\u5355\u6676InVO4<\/sub>\u7eb3\u7c73\u7247\uff0c\u5176\u539a\u5ea6\u4e3a~1.5 nm\uff0c\u5bf9\u5e94\u4e8e\u6b63\u4ea4\u6676\u7cfbInVO4<\/sub>\u76843\u4e2a\u6676\u80de\u3002\u8d85\u8584\u7eb3\u7c73\u51e0\u4f55\u7ed3\u6784\u53ef\u4ee5\u7f29\u77ed\u8f7d\u6d41\u5b50\u4f20\u8f93\u8ddd\u79bb\uff0c\u4f7f\u5176\u4ece\u5185\u90e8\u5feb\u901f\u79fb\u52a8\u5230\u8868\u9762\uff0c\u964d\u4f4e\u7535\u5b50\u548c\u7a7a\u7a74\u5728\u4f53\u76f8\u5185\u7684\u590d\u5408\u51e0\u7387\u3002CO\u5206\u5b50\u6613\u4e8e\u4ece(110)\u8868\u9762\u91ca\u653e\u51fa\u6765\u5f62\u6210\u6e38\u79bb\u7684CO\u5206\u5b50\uff0c\u4ece\u800c\u6709\u52a9\u4e8eCO2<\/sub>\u5149\u8fd8\u539f\u9009\u62e9\u6027\u4ea7\u751fCO\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1aConvincing Synthesis of Atomically-Thin, Single-Crystaline InVO4<\/sub> Sheets toward Promoting Highly Selective and Efficient Solar Conversion of CO2<\/sub> into CO <\/a><\/strong>(J. Am. Chem. Soc.<\/strong>, 2019, DOI: 10.1021\/jacs.8b13673)<\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u7f16\u8f91\u90e8\u65b0\u80fd\u6e90\u5c0f\u7ec4abc940504\u3010\u8096\u6770\u3011\u7f16\u8bd1\u6574\u7406\uff0c\u53c2\u4e0e\u65b0\u80fd\u6e90\u8bdd\u9898\u8ba8\u8bba\u8bf7\u52a0\u5165\u201c\u6750\u6599\u4eba\u65b0\u80fd\u6e90\u6750\u6599\u4ea4\u6d41\u7fa4 422065953\u201d\u3002<\/p>\n

\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1acailiaokefu\uff0c\u6211\u4eec\u4f1a\u9080\u8bf7\u5404\u4f4d\u8001\u5e08\u52a0\u5165\u4e13\u5bb6\u7fa4\u3002<\/strong><\/p>\n

\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1tougao@cailiaoren.com\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"

\u3010\u5f15\u8a00\u3011 \u4f7f\u7528\u592a\u9633\u80fd\u5c06CO2\u50ac\u5316\u8fd8\u539f\u4e3a\u589e\u503c\u5316\u5b66\u54c1\u5f97\u5230\u4e86\u7814\u7a76\u4eba\u5458\u6781\u5927\u7684\u5173\u6ce8\u3002\u539f\u5b50\u5c42\u539a\u7684\u534a\u5bfc\u4f53\u53ef\u63d0\u4f9b\u4e30\u5bcc\u7684\u50ac\u5316\u6d3b\u6027\u4f4d\u70b9\u6765\u4fc3\u8fdbCO2\u8fd8\u539f\u3002\u8d85\u8584\u4e8c\u7ef4\u6750\u6599\u5177\u6709\u5927\u91cf\u4f4e\u914d\u4f4d\u8868…<\/p>\n","protected":false},"author":4931,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[258,2564,3911,3653],"class_list":["post-168609","post","type-post","status-publish","format-standard","hentry","category-jiedu","tag-2d","tag-co2","tag-3911","tag-3653"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/168609"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/4931"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=168609"}],"version-history":[{"count":3,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/168609\/revisions"}],"predecessor-version":[{"id":168681,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/168609\/revisions\/168681"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=168609"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=168609"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=168609"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}