{"id":168465,"date":"2019-03-06T06:30:24","date_gmt":"2019-03-05T22:30:24","guid":{"rendered":"\/\/m.iemloyee.com\/?p=168465"},"modified":"2019-03-05T19:47:13","modified_gmt":"2019-03-05T11:47:13","slug":"%e3%80%90%e5%b7%b2%e6%a0%a1%e7%a8%bf%e3%80%91%e8%83%a1%e8%89%af%e5%85%b5%e6%95%99%e6%8e%88%e8%af%be%e9%a2%98%e7%bb%84ees%ef%bc%9a%e7%9e%ac%e9%97%b4%e5%8e%9f%e4%bd%8d%e5%90%88%e6%88%90%e8%b6%85","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=168465","title":{"rendered":"\u80e1\u826f\u5175\u6559\u6388\u8bfe\u9898\u7ec4EES\uff1a\u77ac\u95f4\u539f\u4f4d\u5408\u6210\u8d85\u7ec6\u948c\u7eb3\u7c73\u9897\u7c92\u7528\u4e8e\u9ad8\u500d\u7387Li-CO2\u7535\u6c60"},"content":{"rendered":"

\u3010\u5f15\u8a00<\/strong>\u3011<\/p>\n

Li-CO2<\/sub>\u7535\u6c60\u5229\u7528CO2<\/sub>\u8fdb\u884c\u7535\u5316\u5b66\u50a8\u80fd\uff0c\u5177\u6709\u80fd\u91cf\u5bc6\u5ea6\u9ad8\u7684\u7279\u70b9\u3002\u7136\u800c\uff0cLi-CO2<\/sub>\u7535\u6c60\u7684\u653e\u7535\u4ea7\u7269Li2<\/sub>CO3<\/sub>\uff0c\u5728\u5145\u7535\u8fc7\u7a0b\u4e2d\u9700\u8981\u9ad8\u7535\u538b\u624d\u80fd\u591f\u5206\u89e3\u3002\u542b\u78b3\u57fa\u4f53\u4e0a\u62c5\u8f7d\u91d1\u5c5e\u7eb3\u7c73\u9897\u7c92\u6709\u5229\u4e8e\u63d0\u9ad8Li-CO2<\/sub>\u7535\u6c60\u53cd\u5e94\u7684\u53ef\u9006\u6027\u3002\u6e7f\u5316\u5b66\u6cd5\u662f\u4e00\u79cd\u7b80\u5355\u3001\u5ec9\u4ef7\u3001\u53ef\u6301\u7eed\u5236\u5907\u78b3\u8f7d\u91d1\u5c5e\u9897\u7c92\u7684\u65b9\u6cd5\uff0c\u7136\u800c\uff0c\u7eb3\u7c73\u9897\u7c92\u5728\u8f83\u957f\u7684\u53cd\u5e94\u65f6\u95f4\u3001\u9ad8\u538b\u6761\u4ef6\u6216\u70ed\u5904\u7406\u6761\u4ef6\u4e0b\u6613\u4e8e\u53d1\u751f\u56e2\u805a\uff0c\u8fdb\u800c\u5931\u53bb\u4e00\u5b9a\u7684\u50ac\u5316\u6d3b\u6027\u3002\u6b64\u5916\uff0c\u78b3\u57fa\u4f53\u7684\u7269\u7406\u548c\u5316\u5b66\u6027\u8d28\u5bf9\u91d1\u5c5e\u7eb3\u7c73\u9897\u7c92\u7684\u5c3a\u5bf8\u5206\u5e03\u3001\u62c5\u8f7d\u91cf\u548c\u53ef\u5206\u6563\u6027\u6709\u663e\u8457\u7684\u5f71\u54cd\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb<\/strong>\u3011<\/p>\n

\u8fd1\u65e5\uff0c\u4ee5\u4e54\u82b8\/\u5f90\u52ad\u61cb\u4e3a\u5171\u540c\u7b2c\u4e00\u4f5c\u8005\uff0c\u9a6c\u91cc\u5170\u5927\u5b66\u80e1\u826f\u5175\u6559\u6388\uff08\u901a\u8baf\u4f5c\u8005\uff09\u8bfe\u9898\u7ec4\uff0c\u5728Energy Environ. Sci.\u4e0a\u62a5\u9053\u4e86\u91c7\u7528\u77ac\u95f4\u70ed\u51b2\u51fb\u6cd5\uff0c\u539f\u4f4d\u5408\u6210\u51fa\u6d3b\u5316\u78b3\u7eb3\u7c73\u7ea4\u7ef4\uff08ACNF\uff09\u62c5\u8f7d\u8d85\u7ec6\u948c\u7eb3\u7c73\u9897\u7c92\uff0c\u5c06\u5176\u4f5c\u4e3a\u6b63\u6781\uff0c\u7ec4\u88c5\u7684Li-CO2<\/sub>\u7535\u6c60\u4e0d\u4ec5\u5faa\u73af\u6027\u80fd\u51fa\u8272\uff0c\u800c\u4e14\u8fc7\u7535\u4f4d\u4f4e\u3002\u5728\u7535\u6d41\u5bc6\u5ea6\u4e3a0.1 A g\u20131<\/sup>\u6761\u4ef6\u4e0b\uff0c\u7ecf\u8fc750\u4e2a\u5faa\u73af\uff0c\u5176\u8fc7\u7535\u4f4d\u4e3a1.43V\u3002\u57280.8\u548c1.0 A g\u20131<\/sup>\u7684\u9ad8\u7535\u6d41\u5bc6\u5ea6\u4e0b\uff0c\u7535\u6c60\u8fc7\u7535\u4f4d\u4ec5\u4e3a1.79 \u548c1.81 V\uff0c\u8868\u660e\u948c\u7eb3\u7c73\u9897\u7c92\u50ac\u5316\u5242\u53ef\u4ee5\u4fc3\u8fdbCO2<\/sub>\u548cLi2<\/sub>CO3<\/sub>\u7684\u53ef\u9006\u53cd\u5e94\u3002\u56e0\u6b64\uff0c\u8fd9\u79cd\u65b9\u6cd5\u4e3a\u5236\u5907\u9ad8\u6027\u80fdLi-CO2<\/sub>\u7535\u6c60\u63d0\u4f9b\u4e86\u5168\u65b0\u7684\u5236\u5907\u65b9\u6cd5\uff0c\u5e76\u6709\u671b\u5e94\u7528\u4e8e\u50ac\u5316\u548c\u5176\u5b83\u53ef\u518d\u751f\u80fd\u6e90\u50a8\u80fd\u6280\u672f\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb<\/strong>\u3011<\/p>\n

\u56fe1. (a) \u78b3\u7eb3\u7c73\u7ea4\u7ef4 (CNF) \u548c (b) \u6d3b\u5316\u78b3\u7eb3\u7c73\u7ea4\u7ef4 (ACNF) \u8d1f\u8f7d\u948c\u7eb3\u7c73\u9897\u7c92\u7684\u8fc7\u7a0b\u793a\u610f\u56fe.<\/p>\n

\"\"<\/p>\n

\u56fe<\/strong>2. <\/strong>\u948c\u7eb3\u7c73\u9897\u7c92\u7684\u5408\u6210\u548c\u8868\u5f81<\/p>\n

\"\"<\/p>\n

(a) \u70ed\u51b2\u51fb\u524d\u548c\u70ed\u51b2\u51fb\u8fc7\u7a0b\u4e2d\u7684ACNF-RuCl3<\/sub>\u819c\uff1b(b) \u6ce2\u957f\u8303\u56f4\u4e3a464 – 867 nm\u7684\u53d1\u5c04\u5149\u8c31\uff1b (c) 0-100 ms\u7684\u70ed\u51b2\u51fb\u7684\u6e29\u5ea6-\u65f6\u95f4\u66f2\u7ebf\uff1b(d-f) Ru\/CNF\u7684SEM\u56fe\u3001TEM\u56fe\u548c\u7eb3\u7c73\u9897\u7c92\u7684\u5c3a\u5bf8\u5206\u5e03\uff1b(g-i) Ru\/ACNF\u7684SEM\u56fe (g)\u3001TEM\u56fe (h, j)\u3001HRTEM\u56fe (k) \u548c\u7eb3\u7c73\u9897\u7c92\u7684\u5c3a\u5bf8\u5206\u5e03 (i)\uff1b(l) Ru\/ACNF\u7684SAED\u56fe\uff1b(m-n) Ru\/CNF\u7535\u6781\u548cRu\/ACNF\u7535\u6781\u7684\u622a\u9762SEM\u56fe\uff1b(o) \u622a\u9762SEM\u56fe\u4e2d\u6807\u8bb0\u4f4d\u7f6e\u7684EDX\u56fe\u3002<\/p>\n

\u56fe3. Ru\/ACNF\u6b63\u6781\u7684\u7535\u5316\u5b66\u6027\u80fd<\/p>\n

\"\"(a) Ru\/CNF\u548cRu\/ACNF\u5728\u7535\u6d41\u5bc6\u5ea6\u4e3a1 A g\u20131<\/sup>\u65f6\u7684\u5145\u653e\u7535\u66f2\u7ebf\uff1b(b) Ru\/ACNF\u5728\u7b2c1\u4e2a\u3001\u7b2c2\u4e2a\u3001\u7b2c10\u4e2a\u3001\u7b2c20\u4e2a\u3001\u7b2c50\u4e2a\u5faa\u73af\u7684\u5145\u653e\u7535\u66f2\u7ebf\uff1b(c) \u5faa\u73af\u8fc7\u7a0b\u4e2d\u7684\u5145\u653e\u7535\u7684\u622a\u81f3\u7535\u538b\uff1b(d) \u4e0d\u540c\u7535\u6d41\u5bc6\u5ea6\u4e0bRu\/ACNF\u7684\u5145\u653e\u7535\u66f2\u7ebf\uff1b(d) \u4e0d\u540c\u7535\u6d41\u5bc6\u5ea6\u4e0bRu\/ACNF\u7684\u653e\u7535\u653e\u7535\u622a\u81f3\u7535\u538b\uff1b(f) \u8fc7\u7535\u4f4d\u7684\u5bf9\u6bd4\u3002<\/p>\n

\u56fe4. \u5faa\u73af\u540eRu\/ACNF\u6b63\u6781\u7684\u8868\u5f81<\/p>\n

\"\"(a) \u653e\u7535\u540eRu\/ACNF\u6b63\u6781\u7684SEM\u56fe\uff1b(b) \u653e\u7535\u540eRu\/ACNF\u6b63\u6781\u7684TEM\u56fe\uff1b(c) \u653e\u7535\u540eRu\/ACNF\u6b63\u6781\u7684\u793a\u610f\u56fe\uff1b(d) \u9996\u6b21\u5145\u7535\u540eRu\/ACNF\u6b63\u6781\u7684SEM\u56fe\uff1b(e) \u9996\u6b21\u5145\u7535\u540eRu\/ACNF\u6b63\u6781\u7684TEM\u56fe\uff1b(f) \u9996\u6b21\u5145\u7535\u540eRu\/ACNF\u6b63\u6781\u7684\u793a\u610f\u56fe\uff1b(g) \u5b8c\u5168\u653e\u7535\u548c\u5145\u7535\u540eRu\/ACNF\u6b63\u6781\u7684XRD\u56fe\uff1b(h) \u5b8c\u5168\u653e\u7535\u548c\u5145\u7535\u540eRu\/ACNF\u6b63\u6781\u7684XPS\u56fe\uff1b(i) \u5145\u7535\u8fc7\u7a0b\u4e2d\u7684Ru\/ACNF\u6b63\u6781\u7684\u4ea7\u6c14\u901f\u7387\u3002<\/p>\n

\u3010\u5c0f\u7ed3<\/strong>\u3011<\/p>\n

\u80e1\u826f\u5175\u6559\u6388\u56e2\u961f\u5408\u6210\u62c5\u8f7d\u5728ACNF\u4e0a\u7684\u948c\u7eb3\u7c73\u9897\u7c92\u4f5c\u4e3aLi-CO2<\/sub>\u7535\u6c60\u6b63\u6781\u3002\u948c\u7eb3\u7c73\u9897\u7c92\u5747\u5300\u5730\u951a\u5b9a\u5728ACNF\u4e0a\uff0c\u589e\u52a0\u4e86\u53cd\u5e94\u4f4d\u70b9\u3002\u76f8\u4e92\u4ea4\u8054\u7684\u7eb3\u7c73\u7ea4\u7ef4\u95f4\u7684\u7a7a\u9699\uff0c\u4e3aCO2<\/sub>\u7684\u6269\u6563\u63d0\u4f9b\u4e86\u901a\u9053\u3002\u540c\u65f6\uff0cACNF\u5177\u6709\u7684\u591a\u5b54\u7ed3\u6784\uff0c\u4e0d\u4ec5\u6709\u5229\u4e8e\u7535\u89e3\u6db2\u6e17\u5165\uff0c\u4fc3\u8fdb\u9502\u79bb\u5b50\u4f20\u8f93\uff0c\u4e5f\u4e3aLi2<\/sub>CO3<\/sub>\u6c89\u79ef\u63d0\u4f9b\u4e86\u7a7a\u95f4\u3002\u56e0\u6b64\uff0cRu\/ACNF\u6b63\u6781\u8868\u73b0\u51fa\u4f18\u5f02\u7684\u500d\u7387\u6027\u80fd\u3002\u8fd9\u9879\u7814\u7a76\u4e3a\u5f00\u53d1\u5faa\u73af\u6027\u80fd\u548c\u500d\u7387\u6027\u80fd\u4f18\u5f02\u7684Li-CO2<\/sub>\u7535\u6c60\u7535\u6781\u6750\u6599\u63d0\u4f9b\u4e86\u5168\u65b0\u7684\u5236\u5907\u65b9\u6cd5\uff0c\u8fd9\u79cd\u65b9\u6cd5\u540c\u65f6\u4e5f\u53ef\u5e94\u7528\u4e8e\u50ac\u5316\u548c\u5176\u5b83\u53ef\u518d\u751f\u7684\u50a8\u80fd\u6280\u672f\u3002\u5357\u4eac\u5927\u5b66\u4f55\u5e73\u6559\u6388\u56e2\u961f\u63d0\u4f9b\u4e86\u5dee\u5206\u7535\u5316\u5b66\u8d28\u8c31\u7684\u6d4b\u5b9a\u548c\u5206\u6790\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1aTransient, in situ Synthesis of Ultrafine Ruthenium Nanoparticles for a High-rate Li-CO2<\/sub> Battery<\/a>\u00a0 \uff08Energy Environ. Sci.\uff0c2019\uff0c<\/em>DOI\uff1a10.1039\/C8EE03506G\uff09<\/p>\n

\u3010\u76f8\u5173\u4f18\u8d28\u6587\u732e\u63a8\u8350<\/strong>\u3011<\/p>\n

    \n
  1. Xu, Shaomao; Chen, Chaoji; Kuang, Yudi; Song, Jianwei; Gan, Wentao; Liu, Boyang; Hitz, Emily M.; Connell, John W.; Lin, Yi; Hu, Liangbing, Flexible lithium\u2013CO2<\/sub> battery with ultrahigh capacity and stable cycling. Energy Environ Sci <\/em>2018,<\/strong> 11<\/em> (11), 3231-3237.<\/li>\n
  2. Qiao, Yun; Liu, Yang; Chen, Chaoji; Xie, Hua; Yao, Yonggang; He, Shuaiming; Ping, Weiwei; Liu, Boyang; Hu, Liangbing, 3D-Printed Graphene Oxide Framework with Thermal Shock Synthesized Nanoparticles for Li-CO2<\/sub> Batteries. Adv Funct Mater <\/em>2018,<\/strong> 28<\/em> (51), 1805899.<\/li>\n
  3. Qiao, Yu; Yi, Jin; Wu, Shichao; Liu, Yang; Yang, Sixie; He, Ping; Zhou, Haoshen, Li-CO2<\/sub> Electrochemistry: A New Strategy for CO2<\/sub> Fixation and Energy Storage. Joule <\/em>2017,<\/strong> 1<\/em> (2), 359-370.<\/li>\n
  4. Qie, Long; Lin, Yi; Connell, John W.; Xu, Jiantie; Dai, Liming, Highly Rechargeable Lithium-CO2<\/sub> Batteries with a Boron and Nitrogen-Codoped Holey-Graphene Cathode. Angew Chem <\/em>2017,<\/strong> 56<\/em> (24), 7074-7078.<\/li>\n
  5. Zhang, Zhang; Yang, Chao; Wu, Shuangshuang; Wang, Aonan; Zhao, Linlin; Zhai, Dandan; Ren, Bo; Cao, Kangzhe; Zhou, Zhen, Exploiting Synergistic Effect by Integrating Ruthenium-Copper Nanoparticles Highly Co-Dispersed on Graphene as Efficient Air Cathodes for Li-CO2<\/sub> Batteries. Adv Energy Mater <\/em>2019,<\/strong> 9<\/em> (8), 1802805.<\/li>\n<\/ol>\n

    \u672c\u6587\u7531\u6750\u6599\u4eba\u7f16\u8f91\u90e8kv1004\u4f9b\u7a3f\uff0c\u6750\u6599\u725b\u7f16\u8f91\u6574\u7406\u3002\u611f\u8c22\u80e1\u6559\u6388\u8bfe\u9898\u7ec4\u5728\u767e\u5fd9\u4e4b\u4e2d\u5bf9\u672c\u6587\u8fdb\u884c\u6821\u7a3f\uff01<\/p>\n","protected":false},"excerpt":{"rendered":"

    \u3010\u5f15\u8a00\u3011 Li-CO2\u7535\u6c60\u5229\u7528CO2\u8fdb\u884c\u7535\u5316\u5b66\u50a8\u80fd\uff0c\u5177\u6709\u80fd\u91cf\u5bc6\u5ea6\u9ad8\u7684\u7279\u70b9\u3002\u7136\u800c\uff0cLi-CO2\u7535\u6c60\u7684\u653e\u7535\u4ea7\u7269Li2CO3\uff0c\u5728\u5145\u7535\u8fc7\u7a0b\u4e2d\u9700\u8981\u9ad8\u7535\u538b\u624d\u80fd\u591f\u5206\u89e3\u3002\u542b\u78b3\u57fa…<\/p>\n","protected":false},"author":1592,"featured_media":168469,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[2989],"class_list":["post-168465","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-jiedu","tag-li-co2"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/168465"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/1592"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=168465"}],"version-history":[{"count":8,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/168465\/revisions"}],"predecessor-version":[{"id":168863,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/168465\/revisions\/168863"}],"wp:featuredmedia":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/media\/168469"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=168465"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=168465"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=168465"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}