{"id":168386,"date":"2019-02-28T06:43:30","date_gmt":"2019-02-27T22:43:30","guid":{"rendered":"\/\/m.iemloyee.com\/?p=168386"},"modified":"2019-02-27T18:43:43","modified_gmt":"2019-02-27T10:43:43","slug":"%e4%b8%ad%e5%8d%97%e5%a4%a7%e5%ad%a6afm%ef%bc%9a%e5%af%8c%e6%b0%a7%e7%bc%ba%e9%99%b7%e7%9a%84%e9%94%b0%e9%85%b8%e9%92%be%e6%8a%91%e5%88%b6%e9%94%b0%e6%ba%b6%e8%a7%a3%e5%8a%a9%e5%8a%9b%e9%ab%98","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=168386","title":{"rendered":"\u4e2d\u5357\u5927\u5b66AFM\uff1a\u5bcc\u6c27\u7f3a\u9677\u7684\u9530\u9178\u94be\u6291\u5236\u9530\u6eb6\u89e3\u52a9\u529b\u9ad8\u80fd\u91cf\u5bc6\u5ea6\u3001 \u957f\u5bff\u547d\u6c34\u7cfb\u950c\u79bb\u5b50\u7535\u6c60"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/b><\/strong><\/p>\n

\u53ef\u5145\u7535\u7684\u6c34\u7cfb\u950c\u79bb\u5b50\u7535\u6c60\uff08ZIBs\uff09\u5177\u6709\u6210\u672c\u4f4e\u3001\u8fd0\u884c\u5b89\u5168\u6027\u9ad8\u3001\u73af\u5883\u53cb\u597d\u7b49\u4f18\u70b9\uff0c\u5728\u5927\u89c4\u6a21\u50a8\u80fd\u5e94\u7528\u4e0a\u5177\u6709\u5f88\u5927\u7684\u53d1\u5c55\u6f5c\u529b\u3002\u6709\u5173\u6c34\u7cfb\u950c\u79bb\u5b50\u7535\u6c60\u7684\u7cfb\u5217\u7814\u7a76\u8868\u660e\uff0c\u9530\u57fa\u6b63\u6781\u6bd4\u5176\u4ed6\u6b63\u6781\u5177\u6709\u66f4\u9ad8\u7684\u80fd\u91cf\u5bc6\u5ea6\u3002\u4e0d\u8fc7\uff0c\u9ad8\u80fd\u91cf\u5bc6\u5ea6\u7684\u9530\u57fa\u6b63\u6781\u901a\u5e38\u4f1a\u53d7\u5230\u9530\u6eb6\u89e3\u548c\u7ed3\u6784\u5d29\u584c\u7684\u56f0\u6270\uff0c\u8fd9\u662f\u56e0\u4e3a\u5176\u9ad8\u5145\u653e\u7535\u5bb9\u91cf\u548c\u9ad8\u5de5\u4f5c\u7535\u538b\u4f7f\u5176\u70ed\u529b\u5b66\u4e0d\u7a33\u5b9a\u6027\u589e\u52a0\uff0c\u4ece\u800c\u5bfc\u81f4\u663e\u8457\u7684\u5bb9\u91cf\u8870\u51cf\u3002\u8fc7\u53bb\u7684\u7814\u7a76\u8868\u660e\uff0c\u5728\u7535\u89e3\u6db2\u4e2d\u989d\u5916\u6dfb\u52a0Mn2+<\/sup>\u6216\u4f7f\u7528\u77f3\u58a8\u70ef\u6d82\u8986\u6280\u672f\u53ef\u4ee5\u5728\u4e00\u5b9a\u7a0b\u5ea6\u4e0a\u6291\u5236Mn3+<\/sup>\u6b67\u5316\u5bfc\u81f4\u7684Mn2+<\/sup>\u6eb6\u89e3\u3002\u7136\u800c\uff0c\u63d0\u9ad8\u9530\u57fa\u6b63\u6781\u7684\u672c\u5f81\u7a33\u5b9a\u6027\uff0c\u4f7f\u5176\u5728\u6c34\u7cfb\u950c\u79bb\u5b50\u7535\u6c60\u4e2d\u5177\u6709\u826f\u597d\u7684\u957f\u5faa\u73af\u7a33\u5b9a\u6027\u4ecd\u7136\u662f\u4e00\u4e2a\u5de8\u5927\u7684\u6311\u6218\u3002\u4e3a\u6b64\uff0c\u6211\u4eec\u5f00\u53d1\u4e86\u4e00\u79cd\u94be\u79bb\u5b50\u7a33\u5b9a\u5d4c\u5165\u7684\u542b\u6c27\u7f3a\u9677\u9530\u9178\u94be\uff08K0.8<\/sub>Mn8<\/sub>O16<\/sub>\uff09\uff0c\u4f5c\u4e3a\u4e00\u79cd\u9ad8\u80fd\u91cf\u5bc6\u5ea6\u3001\u957f\u5bff\u547d\u7684\u6c34\u7cfb\u950c\u79bb\u5b50\u7535\u6c60\u6b63\u6781\u6750\u6599\u3002\u7a33\u5b9a\u5d4c\u5165\u7684K+<\/sup>\u79bb\u5b50\u53ef\u4ee5\u6709\u6548\u5730\u7f13\u89e3\u9530\u5728\u5faa\u73af\u8fc7\u7a0b\u4e2d\u7684\u6eb6\u89e3\uff0c\u540c\u65f6\u6c27\u7f3a\u9677\u80fd\u63d0\u9ad8\u6750\u6599\u7684\u53cd\u5e94\u52a8\u529b\u5b66\u3002\u672c\u5de5\u4f5c\u5bf9\u9530\u6eb6\u89e3\u548c\u6c27\u7f3a\u9677\u7684\u7814\u7a76\uff0c\u4e3a\u9ad8\u6027\u80fd\u6c34\u7cfb\u950c\u79bb\u5b50\u7535\u6c60\u5f00\u8f9f\u65b0\u7684\u601d\u8def\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/b><\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u4e2d\u5357\u5927\u5b66\u5468\u6c5f<\/b><\/strong>\u3001<\/b><\/strong>\u6881\u53d4\u5168\u6559\u6388\u56e2\u961f<\/b><\/strong>\u5728Advanced\u00a0Functional\u00a0Materials\u4e0a\u53d1\u8868\u4e86\u9898\u4e3a\u201cSuppressing Manganese Dissolution in Potassium Manganate<\/b><\/strong>\u00a0<\/b><\/strong>with Rich Oxygen Defects Engaged High-Energy-Density and<\/b><\/strong>\u00a0<\/b><\/strong>Durable<\/b><\/strong>\u00a0<\/b><\/strong>Aqueous Zinc-Ion Battery<\/b><\/strong>\u201d\u7684\u6c34\u7cfb\u950c\u79bb\u5b50\u7535\u6c60\u6700\u65b0\u7814\u7a76\u6210\u679c\u3002\u8be5\u6587\u7ae0\u62a5\u9053\u4e86\u4e00\u79cd\u5177\u6709\u672c\u5f81\u7ed3\u6784\u7a33\u5b9a\u6027\u548c\u5feb\u901f\u53cd\u5e94\u52a8\u529b\u5b66\u7684\u94be\u79bb\u5b50\u5d4c\u5165\u7684\u5bcc\u6c27\u7f3a\u9677K0.8<\/sub>Mn8<\/sub>O16<\/sub>\u4f5c\u4e3a\u4e2d\u6027\u6c34\u7cfb\u950c\u79bb\u5b50\u7535\u6c60\u7684\u6b63\u6781\u6750\u6599\u3002\u4f5c\u8005\u901a\u8fc7K+<\/sup>\u79bb\u5b50\u7684\u7a33\u5b9a\u5d4c\u5165\u6765\u6291\u5236\u9530\u7684\u6eb6\u89e3\uff0c\u4ece\u672c\u8d28\u4e0a\u7a33\u5b9a\u4e86\u9530\u57fa\u6b63\u6781\u3002\u8fd9\u79cd\u6750\u6599\u8868\u73b0\u51fa398 W h kg-1<\/sup>\uff08\u57fa\u4e8e\u6b63\u6781\u8d28\u91cf\uff09\u7684\u9ad8\u80fd\u91cf\u5bc6\u5ea6\u548c\u8d85\u8fc71000\u6b21\u7684\u957f\u5faa\u73af\u7a33\u5b9a\u6027\u3002\u7efc\u5408\u7814\u7a76\u8868\u660e\uff0c\u6c27\u7f3a\u9677\u5bf9K0.8<\/sub>Mn8<\/sub>O16<\/sub>\u7684\u5feb\u901f\u53cd\u5e94\u52a8\u529b\u5b66\u548c\u5bb9\u91cf\u63d0\u9ad8\u8d77\u5230\u4e86\u5173\u952e\u4f5c\u7528\u3002\u6b64\u5916\uff0c\u4f5c\u8005\u8fd8\u5bf9\u8be5\u6750\u6599\u7684\u50a8\u80fd\u673a\u5236\u8fdb\u884c\u4e86\u8be6\u7ec6\u7684\u7814\u7a76\u3002\u65b9\u56fd\u8d75\u535a\u58eb\u4e3a\u8bba\u6587\u7684\u7b2c\u4e00\u4f5c\u8005\uff1b\u5468\u6c5f\u7279\u8058\u6559\u6388\u3001\u6881\u53d4\u5168\u6559\u6388\u4e3a\u8bba\u6587\u7684\u5171\u540c\u901a\u8baf\u4f5c\u8005\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/b><\/strong><\/p>\n

\u56fe1\u6750\u6599\u8868\u5f81<\/b><\/strong><\/p>\n

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\u56fe2\u63a2\u8ba8K<\/b><\/strong>+<\/b><\/sup><\/strong>\u79bb\u5b50\u63ba\u5165\u548c\u6c27\u7f3a\u9677\u5f15\u5165\u5bf9\u7535\u5316\u5b66\u6027\u80fd\u7684\u5f71\u54cd<\/b><\/strong><\/p>\n

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\uff08a\uff09100 mA g-1<\/sup>\u4e0b\u7684\u5faa\u73af\u6027\u80fd\u4ee5\u53ca\u7b2c10\u4e2a\u5faa\u73af\u65f6\u76f8\u5e94\u7684\u6052\u7535\u6d41\u5145\u653e\u7535\u66f2\u7ebf\uff1b<\/p>\n

\uff08b\uff09\u7535\u89e3\u8d28\u7535\u963bRs<\/sub>\u548c\u7535\u8377\u8f6c\u79fb\u7535\u963bRct<\/sub>\u56fe\uff1b<\/p>\n

\uff08c\uff09KMO\u548c\u03b1-MnO2<\/sub>\u5728\u5faa\u73af\u8fc7\u7a0b\u4e2d\uff0c\u57282 M ZnSO4<\/sub>\u6c34\u7cfb\u7535\u89e3\u8d28\u4e2d\u6eb6\u89e3\u7684Mn2+<\/sup>\u7684\u5143\u7d20\u5206\u6790\uff1b<\/p>\n

\uff08d\uff09K+<\/sup>\u79bb\u5b50\u63ba\u5165\u7a33\u5b9a\u9530\u591a\u9762\u4f53\u7684\u793a\u610f\u56fe\u3002<\/p>\n

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\"\"<\/p>\n

\uff08a\uff09KMO\u548c\u03b1-MnO2<\/sub>\u7535\u67810.1 mV s-1<\/sup>\u4e0b\u7684\u5178\u578bCV\u66f2\u7ebf\u3002\uff08a\uff09\u4e2d\u7684\u63d2\u56fe\uff1a\u5728\u4e0d\u540c\u626b\u63cf\u901f\u7387\u4e0b\uff0c\u7b2c\u4e00\u5bf9\u6c27\u5316\u8fd8\u539f\u5bf9\u7684\u8fc7\u7535\u4f4d\u95f4\u9699\uff08\u4f8b\u5982\uff0cKMO\u57280.1 mV s-1<\/sup>\u65f6\u4e3a1.399\/1.614 V\uff09\uff1b<\/p>\n

\uff08b\uff09H+<\/sup>\u6269\u6563\u5230\u5177\u6709\u65e0\u7f3a\u9677\u7ed3\u6784\u548c\u6c27\u7f3a\u9677\u7ed3\u6784\u7684KMO\u4e2d\u7684\u793a\u610f\u56fe\uff1b<\/p>\n

\uff08c\uff09\u4e0d\u540c\u5145\u653e\u7535\u72b6\u6001\u4e0bKMO\u548c\u03b1-MnO2<\/sub>\u7535\u6781\u7684GITT\uff08\u6052\u7535\u6d41\u95f4\u6b47\u6ef4\u5b9a\u6280\u672f\uff09\u66f2\u7ebf\u548c\u76f8\u5e94\u7684H+<\/sup>\u6269\u6563\u7cfb\u6570\uff1b<\/p>\n

\uff08d\uff09\u4e0d\u540c\u626b\u63cf\u901f\u7387\u4e0bKMO\u7535\u6781\u7684CV\u66f2\u7ebf\uff1b<\/p>\n

\uff08e\uff09\u8d5d\u7535\u5bb9\u8d21\u732e\u7684\u76f8\u5e94\u767e\u5206\u6bd4\uff1b<\/p>\n

\u56fe<\/b><\/strong>4\u57280.8~1.8V\u7535\u538b\u8303\u56f4\u5185\u7684\u7535\u5316\u5b66\u6027\u80fd<\/b><\/strong><\/p>\n

\"\"<\/p>\n

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\uff08b\uff09KMO\u7684\u80fd\u91cf\u6bd4\u8f83\u56fe\uff08\u4ec5\u57fa\u4e8e\u6b63\u6781\u6750\u6599\u7684\u91cd\u91cf\uff09\u4e0e\u5148\u524d\u4e00\u4e9b\u7528\u4f5c\u6c34\u7cfb\u950c\u79bb\u5b50\u7535\u6c60\u7684\u6b63\u6781\u6750\u6599\u8fdb\u884c\u6bd4\u8f83\uff1b<\/p>\n

\uff08c\uff09\u57281000 mA g-1<\/sup>\u4e0b\uff0cKMO\u548c\u03b1-MnO2<\/sub>\u7535\u6781\u7684\u957f\u5faa\u73af\u5bff\u547d\u6027\u80fd\u3002\uff08c\uff09\u4e2d\u7684\u63d2\u56fe\uff1a KMO\u7535\u6781\u57281000 mA g-1<\/sup>\u4e0b\u6700\u540e\u5341\u5708\u7684\u5145\u653e\u7535\u66f2\u7ebf\u3002<\/p>\n

\u56fe5<\/b><\/strong>. KMO\u7684\u50a8\u80fd\u673a\u5236\u7814\u7a76<\/b><\/strong><\/p>\n

\"\"<\/p>\n

\uff08a\uff09\u57280.1 A g-1<\/sup>\u4e0b\u524d\u4e24\u6b21\u5faa\u73af\u7684\u539f\u4f4dXRD\u56fe\u8c31\uff1b<\/p>\n

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\uff08c\uff09\u76f8\u5e94\u7684EDX\u5143\u7d20\uff08K\u3001Mn\u3001O\u3001Zn\u548cS\uff09\u6620\u5c04\u56fe\u50cf\uff1b<\/p>\n

\uff08d\uff09\u5728\u521d\u59cb\u548c\u5b8c\u5168\u653e\u7535\/\u5145\u7535\u72b6\u6001\u4e0b\u7684O 1s\u9ad8\u5206\u8fa8\u7387XPS\u5149\u8c31\uff1b<\/p>\n

\uff08e\uff09\u5b8c\u5168\u653e\u7535\u72b6\u6001\u4e0b\u7684\u539f\u4f4dHRTEM\u56fe\u50cf\uff1b<\/p>\n

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\u3010<\/b><\/strong>\u603b\u7ed3\u4e0e\u5c55\u671b<\/b><\/strong>\u3011<\/b><\/strong><\/p>\n

\u5728\u8fd9\u7bc7\u6587\u7ae0\u4e2d\uff0c\u6211\u4eec\u62a5\u9053\u4e86\u4e00\u79cd\u94be\u79bb\u5b50\u7a33\u5b9a\u548c\u5bcc\u6c27\u7f3a\u9677K0.8<\/sub>Mn8<\/sub>O16<\/sub>\u4f5c\u4e3a\u6c34\u7cfb\u950c\u79bb\u5b50\u7535\u6c60\uff08\u4e2d\u6027\u7535\u89e3\u6db2\uff09\u7684\u6b63\u6781\u6750\u6599\u3002\u6211\u4eec\u4e3a\u901a\u8fc7\u63ba\u5165K+<\/sup>\u79bb\u5b50\u7a33\u5b9a\u9530\u57fa\u6b63\u6781\uff0c\u4ece\u800c\u6291\u5236\u9530\u7684\u6eb6\u89e3\u3002\u540c\u65f6\u5bf9K0.8<\/sub>Mn8<\/sub>O16<\/sub>\u7684\u6c27\u7f3a\u9677\u8fdb\u884c\u4e86\u4e00\u7cfb\u5217\u7684\u5b9e\u9a8c\u7814\u7a76\uff0c\u8bc1\u660e\u5176\u5927\u5927\u63d0\u9ad8\u4e86K0.8<\/sub>Mn8<\/sub>O16<\/sub>\u7684\u7535\u5316\u5b66\u6d3b\u6027\u548c\u53cd\u5e94\u52a8\u529b\u5b66\u3002\u5f97\u76ca\u4e8e\u6b64\uff0c\u6211\u4eec\u7684\u6c34\u7cfbZn\/K0.8<\/sub>Mn8<\/sub>O16<\/sub>\u7535\u6c60\u83b7\u5f97\u4e86398W h kg-1<\/sup>\uff08\u57fa\u4e8e\u6b63\u6781\u8d28\u91cf\uff09\u7684\u9ad8\u80fd\u91cf\u8f93\u51fa\u548c\u9ad8\u8fbe1000\u6b21\u7684\u957f\u5faa\u73af\u5bff\u547d\uff0c\u8fd9\u5c06\u5927\u5927\u4fc3\u8fdb\u6c34\u7cfb\u950c\u79bb\u5b50\u7535\u6c60\u7684\u53d1\u5c55\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/b><\/strong>Suppressing Manganese Dissolution in Potassium<\/b><\/strong>\u00a0<\/b><\/strong>Manganate<\/b><\/strong>\u00a0<\/b><\/strong>with Rich Oxygen Defects Engaged High-Energy-Density and<\/b><\/strong>\u00a0<\/b><\/strong>Durable<\/b><\/strong>\u00a0<\/b><\/strong>Aqueous Zinc-Ion Battery<\/b><\/strong>\u00a0<\/a>(Advanced\u00a0Functional\u00a0Materials, DOI:\u00a010.1002\/adfm.201808375, https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/adfm.201808375)<\/p>\n

\u3010\u56e2\u961f\u5728\u8be5\u9886\u57df\u7684\u5de5\u4f5c\u5c0f\u7ed3\u3011<\/strong><\/p>\n

\u4e2d\u5357\u5927\u5b66\u6881\u53d4\u5168\u6559\u6388\u3001\u5468\u6c5f\u7279\u8058\u6559\u6388\u56e2\u961f\u8fd1\u5e74\u6765\u5728\u7eb3\u7c73\u80fd\u6e90\u9886\u57df\u4e2d\u53d6\u5f97\u4e86\u4e00\u7cfb\u5217\u7814\u7a76\u8fdb\u5c55\u3002<\/p>\n

\uff081\uff09\u5173\u4e8e\u6c34\u7cfb\u950c\u79bb\u5b50\u7535\u6c60\u7684\u7814\u7a76<\/p>\n

ACS Energy Letters \u7efc\u8ff0\u6587\u7ae0 \u201cRecent Advances in Aqueous Zinc-Ion Batteries<\/b><\/strong>\u201d\u3002\u8be5\u6587\u7ae0\u7efc\u8ff0\u4e86\u6c34\u7cfbZIBs\u7684\u7814\u7a76\u8fdb\u5c55\uff1a\u9996\u5148\uff0c\u4f5c\u8005\u5bf9\u6c34\u7cfbZIBs\u7684\u50a8\u80fd\u673a\u7406\u8fdb\u884c\u4e86\u7cfb\u7edf\u7684\u5206\u6790\u548c\u603b\u7ed3\uff1b\u5176\u6b21\uff0c\u5bf9\u5404\u79cd\u6b63\u6781\u6750\u6599\u3001\u950c\u8d1f\u6781\u548c\u7535\u89e3\u6db2\u7684\u4f18\u70b9\u548c\u5b58\u5728\u7684\u95ee\u9898\u4ee5\u53ca\u4f18\u5316\u7b56\u7565\u8fdb\u884c\u4e86\u8ba8\u8bba\uff1b\u6700\u540e\uff0c\u9488\u5bf9\u76ee\u524d\u6c34\u7cfbZIBs\u5b58\u5728\u7684\u95ee\u9898\uff0c\u4f5c\u8005\u5728\u672a\u6765\u7684\u7814\u7a76\u65b9\u5411\u65b9\u9762\u4e3a\u4eca\u540e\u7684\u6c34\u7cfbZIBs\u7814\u7a76\u63d0\u4f9b\u6307\u5bfc\uff08ACS Energy Lett. 2018, 3, 2480-2501\uff09\u3002<\/p>\n

\u901a\u8fc7\u4e00\u6b65\u6c34\u70ed\u6cd5\u5b9e\u73b0\u4e86\u9502\u79bb\u5b50\uff08Li+<\/sup>\uff09\u5728\u542b\u6c34\u4e94\u6c27\u5316\u4e8c\u9492\uff08V2<\/sub>O5<\/sub>\u2022n<\/i><\/em>H2<\/sub>O\uff09\u7ed3\u6784\u7684\u5c42\u95f4\u5d4c\u5165\uff0c\u5e76\u901a\u8fc7\u7119\u70e7\u8fc7\u7a0b\u63d0\u9ad8\u5176\u7ed3\u6676\u6027\uff0c\u8fdb\u800c\u6210\u529f\u5236\u5907\u51fa\u4e00\u79cd\u9002\u7528\u4e8e\u6c34\u7cfb\u950c\u79bb\u5b50\u7535\u6c60\u7684\u91d1\u5c5eLi+<\/sup>\u63ba\u6742\u4e0e\u7ed3\u6784\u6c34\u4fdd\u7559\u7684\u68c9\u82b1\u72b6Lix<\/i><\/sub><\/em>V2<\/sub>O5<\/sub>\u00b7n<\/i><\/em>H2<\/sub>O\uff08LVO-250\uff09\uff0c\u6709\u6548\u7684\u89e3\u51b3\u4e86\u4f20\u7edfV2<\/sub>O5<\/sub>\u4f5c\u4e3a\u6c34\u7cfb\u950c\u79bb\u5b50\u7535\u6c60\u6b63\u6781\u5728\u5145\u653e\u7535\u8fc7\u7a0b\u4e2d\u79bb\u5b50\u6269\u6563\u7f13\u6162\u3001\u6750\u6599\u7ed3\u6784\u4e0d\u7a33\u5b9a\u7b49\u74f6\u9888\u95ee\u9898\u3002\uff08Energy & Environmental Science,\u00a02018, DOI:\u00a010.1039\/C8EE01651H\uff09<\/p>\n

\u9996\u6b21\u62a5\u9053\u4e86\u4e0d\u540c\u7ed3\u6784\u7684\u9492\u9178\u94a0\u4f5c\u4e3a\u53ef\u5145\u7535\u6c34\u7cfbZIBs\u6b63\u6781\u6750\u6599\uff0c\u5e76\u5bf9\u5176\u5d4c\u950c\u673a\u7406\u8fdb\u884c\u4e86\u7cfb\u7edf\u7684\u7814\u7a76\uff0c\u63ed\u793a\u4e86\u5c42\u72b6\u7ed3\u6784\u7684NaV3<\/sub>O8<\/sub>\u548c\u96a7\u9053\u7ed3\u6784\u7684\u03b2<\/i><\/em>-Na0.33<\/sub>V2<\/sub>O5<\/sub>\u4e2d\u4e0d\u540c\u7684Zn2+<\/sup>\u50a8\u5b58\u673a\u7406\u3002Zn2+<\/sup>\u5d4c\u5165NaV3<\/sub>O8<\/sub>\u578b\u5c42\u72b6\u7ed3\u6784\u4e2d\u5bfc\u81f4\u7ed3\u6784\u7834\u574f\uff0c\u4f34\u968f\u7740\u7b2c\u4e8c\u76f8\u7684\u5f62\u6210\uff0c\u8fd9\u5c06\u5bfc\u81f4\u5bb9\u91cf\u7684\u8870\u51cf\uff0c\u4f7f\u5f97Na5<\/sub>V12<\/sub>O32<\/sub>\u57282000\u6b21\u5faa\u73af\u540e\u4ec5\u670971\uff05\u7684\u5bb9\u91cf\u4fdd\u6301\u7387\u3002\u7531\u4e8e\u03b2<\/i><\/em>-Na0.33<\/sub>V2<\/sub>O5<\/sub>\u578b\u96a7\u9053\u7ed3\u6784\u7684\u7a33\u5b9a\u6027\uff0c\u5728Zn2+<\/sup>\u53ef\u9006\u8131\u5d4c\u8fc7\u7a0b\u4e2d\u6ca1\u6709\u76f8\u53d8\u53d1\u751f\uff0c\u5c3d\u7ba1\u5bb9\u91cf\u4f4e\uff0c\u4f46\u8868\u73b0\u51fa\u4f18\u5f02\u7684\u5faa\u73af\u7a33\u5b9a\u6027 (Advanced Energy Materials, 2018, 8, 1801819)\u3002<\/p>\n

\u9996\u6b21\u62a5\u9053\u4e86\u4e00\u7cfb\u5217\u9492\u9178\u94be\uff0c\u5305\u62ecK2<\/sub>V8<\/sub>O21<\/sub>\u3001K0.25<\/sub>V2<\/sub>O5<\/sub>\u3001KV3<\/sub>O8<\/sub>\u548cKV3<\/sub>O8<\/sub>\u00b7x<\/i><\/em>H2<\/sub>O\uff0c\u7528\u4f5c\u53ef\u5145\u7535\u6c34\u6027\u950c\u79bb\u5b50\u7535\u6c60\u7684\u6b63\u6781\u6750\u6599\u3002\u901a\u8fc7\u975e\u539f\u4f4dXRD\u3001XPS\u3001HRTEM\u7b49\u624b\u6bb5\u5bf9\u9492\u9178\u94be\u7684\u50a8\u950c\u673a\u7406\u8fdb\u884c\u4e86\u6df1\u5165\u8868\u5f81\u3001\u8ba8\u8bba\u548c\u5206\u6790\u3002\u53d1\u73b0\u5177\u6709\u96a7\u9053\u7ed3\u6784\u7684K2<\/sub>V8<\/sub>O21<\/sub>\u548cK0.25<\/sub>V2<\/sub>O5<\/sub>\u53ef\u4ee5\u4e3a\u950c\u79bb\u5b50\u63d0\u4f9b\u6709\u6548\u7684\u6269\u6563\u8def\u5f84\uff0c\u5e76\u5728\u5145\u653e\u7535\u8fc7\u7a0b\u4e2d\u4fdd\u6301\u4e86\u7ed3\u6784\u7684\u7a33\u5b9a\u6027\uff0c\u800c\u5c42\u72b6\u7ed3\u6784\u7684KV3<\/sub>O8<\/sub>\u548cKV3<\/sub>O8<\/sub>\u00b7x<\/i><\/em>H2<\/sub>O\u5728\u5faa\u73af\u8fc7\u7a0b\u4e2d\u4f1a\u906d\u53d7\u4e25\u91cd\u7684\u7ed3\u6784\u7834\u574f\u3002\u56e0\u6b64\uff0c\u5177\u6709\u7a33\u5b9a\u7ed3\u6784\u548c\u5feb\u901f\u79bb\u5b50\u6269\u6563\u901a\u9053\u7684K2<\/sub>V8<\/sub>O21<\/sub>\u548cK0.25<\/sub>V2<\/sub>O5<\/sub>\u6bd4KV3<\/sub>O8<\/sub>\u548cKV3<\/sub>O8<\/sub>\u00b7x<\/i><\/em>H2<\/sub>O\u5177\u6709\u66f4\u597d\u7684\u50a8\u950c\u80fd\u529b\u3002\u53e6\u5916\uff0c\u5b83\u8fd8\u8868\u73b0\u51fa\u826f\u597d\u7684\u9ad8\u6e29\uff0850\u00b0C\uff09\u6027\u80fd (Nano Energy 2018, 51, 579\u2013587).<\/p>\n

\u8bbe\u8ba1\u4e86\u4e00\u79cd\u65b0\u9896\u7684\u7b56\u7565\uff0c\u7ed3\u5408\u6c34\u70ed\u6cd5\u548c\u51b7\u51bb\u5e72\u71e5\u6280\u672f\u5236\u5907\u4e86\u77f3\u58a8\u70ef\u5305\u8986Na1.1<\/sub>V3<\/sub>O7.9<\/sub>\u7eb3\u7c73\u5e26\uff0cNa1.1<\/sub>V3<\/sub>O7.9<\/sub>\u7eb3\u7c73\u5e26\u4e0e\u77f3\u58a8\u70ef\u7247\u4ea4\u8054\u590d\u5408\uff0c\u5f62\u6210\u4e86\u7a33\u5b9a\u7684\u6be1\u72b6\u7ed3\u6784\u3002\u8be5\u6750\u6599\u9996\u6b21\u5c06\u9492\u9178\u94a0\u5e94\u7528\u4e8e\u6c34\u7cfb\u950c\u79bb\u5b50\u7535\u6c60\uff0c\u5c55\u73b0\u51fa\u4e86\u4f18\u5f02\u7684\u5faa\u73af\u7a33\u5b9a\u6027\u3002\uff08Energy Storage Materials 2018, 13, 168\u2013174\uff09\u3002<\/p>\n

\u901a\u8fc7\u6c34\u70ed\u6cd5\u6210\u529f\u5408\u6210\u4e86Ag0.4<\/sub>V2<\/sub>O5<\/sub>\u6750\u6599\uff0c\u5e76\u5c06\u5176\u9996\u6b21\u5e94\u7528\u4e8e\u6c34\u7cfb\u950c\u79bb\u5b50\u7535\u6c60\u6b63\u6781\u3002\u901a\u8fc7\u7535\u5316\u5b66\u673a\u7406\u5206\u6790\u53d1\u73b0\uff0cAg0.4<\/sub>V2<\/sub>O5<\/sub>\u5728\u5145\u653e\u7535\u8fc7\u7a0b\u4e2d\u4f1a\u7ecf\u5386\u53d6\u4ee3\/\u5d4c\u5165\u5171\u53cd\u5e94\uff08Combination Displacement\/Intercalation\uff09\uff0c\u5176\u4e2d\uff0c\u653e\u7535\u8fc7\u7a0b\u4e2d\u6709\u65b0\u76f8\u9492\u9178\u950c\u4e0e\u5355\u8d28\u94f6\u751f\u6210\uff0c\u6709\u5229\u4e8e\u63d0\u5347\u7535\u5316\u5b66\u6027\u80fd\u4e0e\u5bfc\u7535\u6027\u3002\u4ee5Ag0.4<\/sub>V2<\/sub>O5<\/sub>\u4e3a\u6b63\u6781\u7684\u6c34\u7cfb\u950c\u79bb\u5b50\u7535\u6c60\u572810 A g–<\/sup>1<\/sup>\u7684\u9ad8\u7535\u6d41\u5bc6\u5ea6\u4e0b\u80fd\u591f\u7a33\u5b9a\u5faa\u73af2000\u5708\uff0c\u5c55\u73b0\u4e86\u4f18\u8d8a\u7684\u7535\u5316\u5b66\u6027\u80fd\u3002 (Energy Storage Materials, 2018, DOI: 10.1016\/j.ensm.2018.08.008)\u3002<\/p>\n

\u7814\u7a76\u4e86\u65e0\u7c98\u7ed3\u5242\u5c42\u72b6\u7eb3\u7c73\u82b1\u7ed3\u6784Mn3<\/sub>O4<\/sub>\u4f5c\u4e3a\u950c\u79bb\u5b50\u7535\u6c60\u6b63\u6781\u6750\u6599\u7684\u7535\u5316\u5b66\u6027\u80fd\uff0c\u5e76\u7ed3\u5408\u975e\u539f\u4f4d\u8868\u5f81\u63a2\u7d22\u4e86\u5176\u50a8\u950c\u673a\u5236\uff08J. Mater. Chem. A 2018, 6, 9677\u20139683\uff09\u3002<\/p>\n

\u6b64\u5916\uff0c\u56e2\u961f\u6709\u5173V2<\/sub>O5<\/sub>\u7eb3\u7c73\u6750\u6599\u7528\u4f5c\u6c34\u7cfb\u950c\u79bb\u5b50\u7535\u6c60\u6b63\u6781\u7684\u57fa\u7840\u7814\u7a76\u8fdb\u5c55\uff0c\u5728\u81ea\u7136\u6307\u6570\u671f\u520a\u300a\u5316\u5b66\u901a\u8baf\u300b(Chem. Commun., 2018, 54, 4457)\u4e0a\u53d1\u8868\u3002<\/p>\n

\uff082\uff09\u5173\u4e8e\u94a0\u79bb\u5b50\u7535\u6c60\u7684\u7814\u7a76\uff1a<\/p>\n

\u5229\u7528\u53cc\u91d1\u5c5eMOFs\u4e3a\u6a21\u677f\uff0c\u6210\u529f\u5f00\u53d1\u51fa\u4e00\u79cd\u7528\u4e8e\u94a0\u79bb\u5b50\u7535\u6c60\u8d1f\u6781\u7684\u6c2e\u63ba\u6742\u78b3\u5305\u8986\u53cc\u91d1\u5c5e\u786b\u5316\u7269\uff0c\u8be5\u6750\u6599\u5177\u6709\u9ad8\u94a0\u79bb\u5b50\u6269\u6563\u7cfb\u6570\uff0c\u4e30\u5bcc\u7684\u6676\u754c\u7f3a\u9677\uff0c\u548c\u8d5d\u7535\u5bb9\u6548\u5e94\u3002\u8be5\u6750\u6599\u6709\u6548\u89e3\u51b3\u4e86\u76ee\u524d\u94a0\u79bb\u5b50\u7535\u6c60\u8d1f\u6781\u6750\u6599\u5728\u5145\u653e\u7535\u8fc7\u7a0b\u4e2d\u79bb\u5b50\u6269\u6563\u7f13\u6162\u3001\u6750\u6599\u4f53\u79ef\u81a8\u80c0\u7b49\u74f6\u9888\u95ee\u9898\u3002\u8be5\u7814\u7a76\u6210\u679c\u8fd1\u65e5\u53d1\u8868\u5728\u56fd\u9645\u80fd\u6e90\u9876\u7ea7\u671f\u520a\u300a\u5148\u8fdb\u80fd\u6e90\u6750\u6599\u300b\uff08Adv. Energy Mater. 2018, 8, 1703155\uff09\uff0c\u5e76\u88ab\u9009\u4e3aBack Cover\u8bba\u6587\u3002<\/p>\n

\u901a\u8fc7\u6c34\u70ed\u4ee5\u53ca\u51b7\u51bb\u5e72\u71e5\u548c\u540e\u7eed\u7145\u70e7\u7684\u65b9\u6cd5\u5408\u6210\u4e86\u4ea4\u9519\u76f8\u8fde\u7684\u77f3\u58a8\u70ef\u7b3c\u5b50\u5305\u88f9Na3<\/sub>V2<\/sub>(PO4<\/sub>)2<\/sub>F3<\/sub>\u5fae\u7c73\u7acb\u65b9\u4f53\u590d\u5408\u6750\u6599\uff0c\u6709\u6548\u63d0\u9ad8\u5176\u7535\u5b50\u7535\u5bfc\u7387\uff0c\u83b7\u5f97\u4e86\u5f88\u597d\u7684\u7535\u5316\u5b66\u6027\u80fd\u3002\u7533\u8bf7\u4eba\u5229\u7528\u975e\u539f\u4f4dXRD\u3001TEM\u3001CV\u548cGITT\u6280\u672f\u63ed\u793a\u5176\u7535\u5316\u5b66\u884c\u4e3a\uff0c\u53d1\u73b0Na+<\/sup>\u5728\u5d4c\u5165\/\u8131\u5d4cNa3<\/sub>V2<\/sub>(PO4<\/sub>)2<\/sub>F3<\/sub>\u7535\u6781\u65f6\u5177\u6709\u4f18\u5f02\u7684\u7ed3\u6784\u53ef\u9006\u6027\u548c\u5f88\u597dNa+<\/sup>\u6269\u6563\u52a8\u529b\u5b66\u3002\u8be5\u5de5\u4f5c\u53d1\u8868\u5728Adv. Sci.<\/i><\/em>\u00a02018, 5,\u00a01800680\u3002<\/p>\n

\u5408\u7406\u5730\u8bbe\u8ba1\u4e86\u4e00\u79cd\u591a\u5b54\u6742\u5316\u53cc\u91d1\u5c5e\u6c27\u5316\u7269(Co3<\/sub>O4<\/sub>\/ZnO)\u7eb3\u7c73\u7247\uff0c\u8868\u73b0\u51fa\u4f18\u5f02\u7684\u50a8\u9502\u3001\u50a8\u94a0\u6027\u80fd\u3002\u8be5\u5de5\u4f5c\u6210\u4e3a\u300aJ. Mater. Chem. A\u300b\u7684\u5c01\u9762\u6587\u7ae0\uff08J. Mater. Chem. A, 2017, 5, 13983\uff09\u3002<\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u7f16\u8f91\u90e8\u7f16\u8f91<\/p>\n

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