{"id":167960,"date":"2019-02-26T11:30:38","date_gmt":"2019-02-26T03:30:38","guid":{"rendered":"\/\/m.iemloyee.com\/?p=167960"},"modified":"2019-02-25T20:25:55","modified_gmt":"2019-02-25T12:25:55","slug":"%e3%80%90%e5%9b%bd%e5%a4%96%e3%80%91%e5%8c%97%e6%b5%b7%e9%81%93%e5%a4%a7%e5%ad%a6nat-rev-chem-%e7%94%a8%e4%ba%8e%e5%85%a8%e5%9b%ba%e6%80%81%e9%94%82%e7%94%b5%e6%b1%a0%e7%9a%84%e7%a1%ab%e5%8c%96","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=167960","title":{"rendered":"\u5317\u6d77\u9053\u5927\u5b66Nat. Rev. Chem.:\u7528\u4e8e\u5168\u56fa\u6001\u9502\u7535\u6c60\u7684\u786b\u5316\u7269\u7535\u89e3\u8d28\u7684\u6db2\u76f8\u5408\u6210"},"content":{"rendered":"

\u3010\u5f15\u8a00<\/b><\/strong>\u3011<\/p>\n

\u8f83\u9ad8\u7684\u80fd\u91cf\u5bc6\u5ea6\u548c\u8f83\u957f\u7684\u5faa\u73af\u5bff\u547d\u5bf9\u4e8e\u53ef\u5145\u7535\u7535\u6c60\u662f\u5341\u5206\u91cd\u8981\u7684\uff0c\u5c24\u5176\u662f\u5bf9\u4e8e\u8f66\u8f7d\u7535\u6c60\u548c\u5927\u89c4\u6a21\u50a8\u5b58\u7535\u529b\u8bbe\u5907\u3002\u9502\u7535\u6c60\u53ef\u5b9e\u73b0\u5355\u4f4d\u91cd\u91cf\u8f83\u9ad8\u7684\u80fd\u91cf\u5bc6\u5ea6\uff0c\u56e0\u4e3a\u9502\u662f\u73af\u5883\u538b\u529b\u4e0b\u6700\u8f7b\u7684\u56fa\u4f53\u5143\u7d20\uff0c\u4e14\u5177\u6709\u8f83\u4f4e\u7684\u8fd8\u539f\u7535\u4f4d\u3002\u7136\u800c\uff0c\u9502\u79bb\u5b50\u7535\u6c60\u4e2d\u7684\u53ef\u71c3\u6709\u673a\u7535\u89e3\u8d28\u5b58\u5728\u7684\u5b89\u5168\u95ee\u9898\u9650\u5236\u4e86\u7535\u6c60\u7684\u64cd\u4f5c\u6e29\u5ea6\u8303\u56f4\u3002\u8fc7\u53bb\u51e0\u5341\u5e74\u6765\uff0c\u5168\u56fa\u6001\u9502\u7535\u6c60\u5df2\u7ecf\u901a\u8fc7\u907f\u514d\u4f7f\u7528\u6613\u71c3\u7535\u89e3\u8d28\u6765\u89e3\u51b3\u8fd9\u4e9b\u5b89\u5168\u95ee\u9898\u3002\u56fa\u4f53\u7535\u6781\u7684\u4f7f\u7528\u6709\u52a9\u4e8e\u5b9e\u73b0\u8f83\u9ad8\u7684\u9502\u79bb\u5b50\u4f20\u5bfc\u6027\uff0c\u56e0\u4e3a\u5728\u56fa\u4f53\u6846\u67b6\u4e2d\u4ec5\u6709\u9502\u79bb\u5b50\u7684\u4f20\u8f93\u800c\u6ca1\u6709\u9634\u79bb\u5b50\u7684\u6269\u6563\u3002\u56fa\u4f53\u7535\u89e3\u8d28\u5728\u5f88\u5bbd\u7684\u6e29\u5ea6\u8303\u56f4\u5185\u662f\u7a33\u5b9a\u7684\uff0c\u5e76\u4e14\u53ef\u4ee5\u5728\u5bbd\u7535\u538b\u8303\u56f4\u5185\u4e0e\u7535\u6781\u8026\u5408\u3002\u7531\u786b\u5316\u7269\u7535\u6781\u548c\u786b\u5316\u7269\u7535\u89e3\u8d28\u7ec4\u6210\u7684\u5168\u56fa\u6001\u7535\u6c60\u53ef\u4ee5\u5728-30\u00b1160o<\/sup>C\u7684\u5bbd\u6e29\u5ea6\u8303\u56f4\u5185\u4f5c\u4e3a\u4e8c\u6b21\u7535\u6c60\u8fd0\u884c\uff0c\u4f46\u7531\u4e8e\u786b\u5316\u7269\u7535\u6781\u6eb6\u89e3\u5230\u56fa\u4f53\u7535\u89e3\u8d28\u4e2d\uff0c\u5373\u4f7f\u5728\u9ad8\u6e29\u4e0b\u4e5f\u4e0d\u4f1a\u663e\u8457\u964d\u89e3\u3002\u4f46\u662f\u5927\u591a\u6570\u57fa\u4e8e\u786b\u5316\u7269\u7684\u7535\u89e3\u8d28\u5728\u6c34\u4e2d\u4e0d\u7a33\u5b9a\uff0c\u4f1a\u4ea7\u751fH2<\/sub>S\u6c14\u4f53\u7684\u4ea7\u751f\uff0c\u5e76\u4f7f\u5408\u6210\u8fc7\u7a0b\u53d8\u5f97\u590d\u6742\uff08\u901a\u5e38\uff0c\u539f\u6599\u548c\u4ea7\u7269\u90fd\u9700\u8981\u5728\u624b\u5957\u7bb1\u4e2d\u5904\u7406\uff09\u3002<\/p>\n

\u8fd1\u6765\uff0c\u6db2\u76f8\u5408\u6210\u53d7\u5230\u8d8a\u6765\u8d8a\u591a\u7684\u5173\u6ce8\uff0c\u5e76\u5728\u5236\u5907\u56fa\u6001\u7535\u89e3\u8d28\u4e2d\u5f97\u5230\u4e86\u5e94\u7528\u3002\u5c31\u5408\u6210\u6e29\u5ea6\u3001\u5408\u6210\u65f6\u95f4\u548c\u53ef\u6269\u5c55\u6027\u800c\u8a00\uff0c\u6db2\u76f8\u5408\u6210\u8f83\u56fa\u6001\u5408\u6210\u5177\u6709\u4ee5\u4e0b\u51e0\u4e2a\u4f18\u70b9\u3002\u6db2\u76f8\u5408\u6210\u901a\u5e38\u5728\u4f4e\u4e8e300o<\/sup>C\u7684\u6e29\u5ea6\u4e0b\u8fdb\u884c\uff0c\u6e29\u5ea6\u6bd4\u56fa\u6001\u5408\u6210\u6240\u9700\u7684\u6e29\u5ea6\u4f4e\u5f88\u591a\u3002\u6db2\u76f8\u5408\u6210\u53ef\u4ee5\u5728\u73bb\u7483\u5bb9\u5668\u4e2d\u8fdb\u884c\u3002\u6b64\u5916\uff0c\u5b83\u4eec\u53ef\u4ee5\u5f62\u6210\u5177\u6709\u9ad8\u7535\u5bfc\u7387\u7684\u4e9a\u7a33\u6001\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb<\/b><\/strong>\u3011<\/p>\n

\u65e5\u672c\u5317\u6d77\u9053\u5927\u5b66<\/b><\/strong>\u7684<\/b><\/strong>Kiyoharu Tadanaga<\/b><\/strong>\u548c\u5927\u962a\u5e9c\u7acb\u5927\u5b66\u7684<\/b><\/strong>Masahiro Tatsumisago<\/b><\/strong>\u5408\u4f5c<\/b><\/strong>\u5728Nat. Rev. Chem.<\/b><\/strong>\u4e0a\uff0c\u53d1\u8868\u4e86\u9898\u4e3a”Liquid-Phase Syntheses of Sulfide Electrolytes for All-Solid-State Lithium Battery<\/b><\/strong>“\u7684\u7efc\u8ff0\u3002\u5728\u8fd9\u7bc7\u7efc\u8ff0\u4e2d\uff0c\u4f5c\u8005\u4ecb\u7ecd\u4e86\u7528\u4e8e\u5168\u56fa\u6001\u9502\u7535\u6c60\u7684\u786b\u5316\u7269\u7535\u89e3\u8d28\u7684\u6db2\u76f8\u5408\u6210\u3002\u4f5c\u8005\u5c06\u5176\u5206\u4e3a\u4e24\u7ec4\uff1a\u9996\u5148\uff0c\u4eceLi2<\/sub>S\u548cP2<\/sub>S5<\/sub>\u60ac\u6d6e\u5408\u6210\u786b\u5316\u7269\u7535\u89e3\u8d28\uff1b\u5176\u6b21\uff0c\u4f7f\u7528\u786b\u5316\u7269\u7684\u9ad8\u5ea6\u53ef\u6eb6\u6eb6\u6db2\uff0c\u4f7f\u5176\u5b8c\u6210\u6eb6\u89e3-\u6c89\u6dc0\u3002\u6700\u540e\uff0c\u4f5c\u8005\u603b\u7ed3\u4e86\u5168\u56fa\u6001\u9502\u7535\u6c60\u7684\u6db2\u76f8\u5de5\u827a\u548c\u6027\u80fd\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/b><\/strong><\/p>\n

\u56fe<\/b><\/strong>\u00a0<\/b><\/strong>1.\u786b\u5316\u7269\u7535\u89e3\u8d28\u7684\u6db2\u76f8\u5408\u6210\u793a\u610f\u56fe<\/b><\/strong><\/p>\n

\"\"<\/p>\n

\u56fe\u00a0<\/b><\/strong>2<\/b><\/strong>.<\/b><\/strong>\u786b\u5316\u7269\u7535\u89e3\u8d28\u7684\u60ac\u6d6e\u5408\u6210<\/b><\/strong><\/p>\n

\"\"<\/p>\n

(a).\u53cd\u5e94\u65b9\u7a0b\u5f0f<\/p>\n

(b).\u524d\u4f53Li7<\/sub>P3<\/sub>S11<\/sub><\/p>\n

(c).\u6676\u4f53\u7ed3\u6784<\/p>\n

\u56fe<\/strong> 3<\/b>.<\/b><\/strong>\u786b\u5316\u7269\u7535\u89e3\u8d28\u7684\u6eb6\u89e3-\u6c89\u6dc0<\/b><\/strong><\/p>\n

\"\"<\/p>\n

(a).\u53cd\u5e94\u65b9\u7a0b\u5f0f<\/p>\n

(b).Li6<\/sub>PS5<\/sub>Cl-\u4e59\u9187\u6eb6\u6db2\u7684\u56fe\u7247\u4ee5\u53ca\u62c9\u66fc\u5149\u8c31<\/p>\n

(c).Li6<\/sub>PS5<\/sub>Cl\u7684\u6676\u4f53\u7ed3\u6784<\/p>\n

(d).\u901a\u8fc7\u9ad8\u80fd\u7403\u78e8\u5de5\u827a\u5408\u6210\u7684\u5f62\u72b6\u4e0d\u89c4\u5219\u7684Li6<\/sub>PS5<\/sub>Cl\u9897\u7c92<\/p>\n

(e).\u7528\u5206\u6563\u5242\u4eceLi6<\/sub>PS5<\/sub>Cl-\u4e59\u9187\u6eb6\u6db2\u4e2d\u6c89\u6dc0\u51fa\u5747\u76f8\u548c\u4e9a\u5fae\u7c73\u7ea7Li6<\/sub>PS5<\/sub>Cl\u9897\u7c92<\/p>\n

(f).\u4e0d\u542b\u5206\u6563\u5242\u7684Li6<\/sub>PS5<\/sub>Cl-\u4e59\u9187\u6eb6\u6db2\u4e2d\u6c89\u6dc0\u51fa\u5f62\u72b6\u4e0d\u89c4\u5219\u7684Li6<\/sub>PS5<\/sub>Cl\u9897\u7c92<\/p>\n

(g).\u6eb6\u89e3-\u6c89\u6dc0\u8fc7\u7a0b\u7684\u52a0\u70ed\u6e29\u5ea6\u548c\u6c89\u6dc0\u7535\u89e3\u8d28\u7684\u7535\u5bfc\u7387<\/p>\n

\u56fe\u00a0<\/b><\/strong>4<\/b><\/strong>.<\/b><\/strong>\u5168\u56fa\u6001\u9502\u7535\u6c60\u590d\u5408\u7535\u6781\u7684\u6db2\u76f8\u5de5\u827a<\/b><\/strong><\/p>\n

\"\"<\/p>\n

(a).\u590d\u5408\u7535\u6781\u6db2\u76f8\u8fc7\u7a0b\u793a\u610f\u56fe<\/p>\n

(b).\u60ac\u6d6e\u5408\u6210\u590d\u5408\u7535\u6781\u7684\u622a\u9762\u56fe<\/p>\n

(c).\u5168\u56fa\u6001\u7535\u6c60\u7684\u9996\u6b21\u5145\u653e\u7535\u66f2\u7ebf<\/p>\n

(d,e).\u626b\u63cf\u7535\u5b50\u663e\u5fae\u955c\u548c\u80fd\u91cf\u8272\u6563X\u5c04\u7ebf\u5206\u6790<\/p>\n

(f).\u91c7\u7528\u6eb6\u89e3-\u6c89\u6dc0\u6cd5\u5236\u5907\u7684\u5168\u56fa\u6001\u7535\u6c60\u7684\u5145\u653e\u7535\u66f2\u7ebf<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/b><\/strong><\/p>\n

\u56fa\u4f53\u786b\u5316\u7269\u7535\u89e3\u8d28\u662f\u5168\u56fa\u6001\u9502\u7535\u6c60\u4e2d\u7684\u5173\u952e\u6750\u6599\uff0c\u56e0\u4e3a\u5176\u5177\u6709\u8f83\u9ad8\u7684\u9502\u79bb\u5b50\u4f20\u5bfc\u6027\u548c\u53ef\u53d8\u5f62\u6027\uff0c\u4f7f\u5f97\u9502\u79bb\u5b50\u901a\u8def\u80fd\u591f\u5728\u63a5\u8fd1\u5ba4\u6e29\u7684\u538b\u529b\u4e0b\u8fde\u63a5\u5728\u6750\u6599\u7684\u6676\u754c\u4e4b\u95f4\u3002\u7136\u800c\uff0c\u786b\u5316\u7269\u5bf9\u6e7f\u5ea6\u654f\u611f\u5e76\u5177\u6709\u8f83\u9ad8\u7684\u84b8\u6c14\u538b\uff0c\u56e0\u6b64\u786b\u5316\u7269\u7535\u89e3\u8d28\u7684\u5408\u6210\u5177\u6709\u4e00\u5b9a\u7684\u96be\u5ea6\u3002\u6db2\u76f8\u53cd\u5e94\u4f7f\u786b\u5316\u7269\u7535\u89e3\u8d28\u7684\u5236\u5907\u53ef\u5728\u8f83\u4f4e\u6e29\u5ea6\u4e0b\u8f7d\u53d7\u63a7\u6c14\u6c1b\u4e2d\u8fdb\u884c\uff0c\u4e3a\u786b\u5316\u7269\u7535\u89e3\u8d28\u7684\u5236\u5907\u5f00\u8f9f\u4e86\u65b0\u7684\u5929\u5730\u3002\u8fd9\u7bc7\u7efc\u8ff0\u4e2d\uff0c\u4f5c\u8005\u56de\u987e\u4e86\u786b\u5316\u7269\u7535\u89e3\u8d28\u7684\u6db2\u76f8\u5408\u6210\uff0c\u5e76\u6bd4\u8f83\u4e86\u4e0d\u540c\u5168\u56fa\u6001\u9502\u7535\u6c60\u7684\u5145\u653e\u7535\u6027\u80fd\u3002<\/p>\n

Liquid-Phase Syntheses of Sulfide Electrolytes for All-Solid-State Lithium Battery<\/a><\/p>\n

(Nat. Rev. Chem., 2018, DOI: 10.1038\/s41570-019-0078-2)<\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u5b66\u672f\u7ec4tt\u4f9b\u7a3f\uff0c\u6750\u6599\u725b\u6574\u7406\u7f16\u8f91\u3002 \u00a0<\/p>\n

\u6750\u6599\u725b\u7f51\u4e13\u6ce8\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u53ca\u884c\u4e1a\u8fdb\u5c55\uff0c\u8fd9\u91cc\u6c47\u96c6\u4e86\u5404\u5927\u9ad8\u6821\u7855\u535a\u751f\u3001\u4e00\u7ebf\u79d1\u7814\u4eba\u5458\u4ee5\u53ca\u884c\u4e1a\u4ece\u4e1a\u8005\uff0c\u5982\u679c\u60a8\u5bf9\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u8fdb\u5c55\uff0c\u89e3\u8bfb\u9ad8\u6c34\u5e73\u6587\u7ae0\u6216\u662f\u8bc4\u8ff0\u884c\u4e1a\u6709\u5174\u8da3\uff0c\u70b9\u6211\u52a0\u5165\u7f16\u8f91\u90e8\u5927\u5bb6\u5ead\u3002 \u00a0<\/p>\n

\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1tougao@cailiaoren.com\u3002<\/p>\n

\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1acailiaokefu\uff0c\u6211\u4eec\u4f1a\u9080\u8bf7\u5404\u4f4d\u8001\u5e08\u52a0\u5165\u4e13\u5bb6\u7fa4\u3002 \u00a0<\/p>\n","protected":false},"excerpt":{"rendered":"

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