{"id":167400,"date":"2019-02-20T06:30:00","date_gmt":"2019-02-19T22:30:00","guid":{"rendered":"\/\/m.iemloyee.com\/?p=167400"},"modified":"2019-02-19T09:52:15","modified_gmt":"2019-02-19T01:52:15","slug":"%e5%8c%97%e5%8c%96%e5%b7%a5%e5%b0%b9%e6%a2%85%e8%b4%9enature-communications%ef%bc%9a%e5%85%b7%e6%9c%89%e8%bf%91%e7%ba%a2%e5%a4%96%e5%85%89%e7%83%ad%e6%80%a7%e8%83%bd%e7%9a%84%e8%8b%9d%e9%85%b0","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=167400","title":{"rendered":"\u5317\u5316\u5de5\u5c39\u6885\u8d1eNature Communications\uff1a\u5177\u6709\u8fd1\u7ea2\u5916\u5149\u70ed\u6027\u80fd\u7684\u82dd\u9170\u4e9a\u80fa\u57fa\u591a\u5b54MOF\u6750\u6599"},"content":{"rendered":"
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Chem. Int. Ed.<\/i><\/b><\/em><\/strong>\u00a0<\/b><\/strong>2019, 58, 1638\u20131642; ACS Nano<\/i><\/b><\/em><\/strong>\u00a0<\/b><\/strong>2017, 11, 3797\u20133805; Sci. Bull.<\/i><\/b><\/em><\/strong>, 2018, 63,\u00a0101-107\u00a0\u7b49\u6742\u5fd7\u3002<\/p>\n \u56fe<\/b><\/strong>3<\/b><\/strong>\u00a0<\/b><\/strong>\u5149\u8bf1\u5bfc\u7535\u5b50\u8f6c\u79fb\u751f\u6210\u9634\u79bb\u5b50\u81ea\u7531\u57fa<\/b><\/strong><\/p>\n \u5149\u8bf1\u5bfc\u7535\u5b50\u8f6c\u79fb\u524d\u540eZr-PDI\u6676\u4f53\u7684(a)\u7d2b\u5916-\u53ef\u89c1-\u8fd1\u7ea2\u5916\u5438\u6536\u5149\u8c31\uff0c(b)\u8367\u5149\u5149\u8c31\u3002(c)\u4e09\u4e59\u80fa\u548cP-2COOH\u7684\u80fd\u7ea7\u793a\u610f\u56fe\uff0c(d)\u4e09\u4e59\u80fa\u548cP-2COOH\u7684\u5149\u8bf1\u5bfc\u7535\u5b50\u8f6c\u79fb\u8fc7\u7a0b\u793a\u610f\u56fe\u3002<\/p>\n \u56fe<\/b><\/strong>4<\/b><\/strong>\u7a33\u5b9a\u7684\u9634\u79bb\u5b50\u81ea\u7531\u57fa<\/b><\/strong><\/p>\n \u00a0<\/b><\/strong>(a) Zr-PDI\u7684\u4e09\u4e59\u80fa\u5438\u9644\u6d4b\u8bd5\uff0c(b)\u7528\u6c22\u6c27\u5316\u94a0\u6c34\u6eb6\u6db2\u6eb6\u89e3\u540e\u7684Zr-PDI\u2022\u2013<\/sup>\uff0c(c) Zr-PDI\u2022\u2013<\/sup>\u53caP-2COOH\u2022\u2013<\/sup>\u7684\u7535\u5b50\u987a\u78c1\u6d4b\u8bd5\uff0c(d) Zr-PDI\u2022\u2013<\/sup>\u7684\u7a33\u5b9a\u6027\u6d4b\u8bd5TEA=\u4e09\u4e59\u80fa\uff0cEDA=\u4e59\u4e8c\u80fa\uff0cTPA=\u4e09\u4e19\u80fa\uff0cDEA=\u4e8c\u4e59\u80fa\uff0cIPA=\u5f02\u4e19\u80fa\uff0cTMA=\u4e09\u7532\u80fa\u3002<\/p>\n \u56fe<\/b><\/strong>5<\/b><\/strong>\u5149\u70ed\u8f6c\u5316\u6027\u8d28<\/b><\/strong><\/p>\n \u00a0<\/b><\/strong>(a) Zr-PDI\u2022\u2013<\/sup>\u7684\u5149\u70ed\u8f6c\u5316\u793a\u610f\u56fe\uff0c(b)\u5149\u70ed\u8f6c\u5316\u66f2\u7ebf\uff0c(c)\u4e0d\u540c\u529f\u7387\u4e0bZr-PDI\u2022\u2013<\/sup>\u7684\u5347\u6e29\u66f2\u7ebf\uff0c(d) Zr-PDI\u2022\u2013<\/sup>\u7684\u5149\u70ed\u7a33\u5b9a\u6027\u6d4b\u8bd5\uff0c(e) Zr-PDI\u2022\u2013<\/sup>\u7684\u5149\u70ed\u6210\u50cf\u6d4b\u8bd5\u3002<\/p>\n \u3010\u603b\u7ed3\u3011<\/b><\/strong><\/p>\n \u8be5\u5de5\u4f5c\u62a5\u9053\u4e86\u4e00\u79cd\u591a\u5b54\u7684\u4e09\u7ef4\u82dd\u9170\u4e9a\u80fa\u91d1\u5c5e\u6709\u673a\u9aa8\u67b6Zr-PDI\uff0c\u8868\u73b0\u51fa\u4ee5\u4e0b\u7279\u70b9\uff1a<\/p>\n \uff081\uff09\u4f18\u5f02\u7684<\/b><\/strong>3<\/b><\/strong>D\u591a\u5b54\u6750\u6599\u53ca\u826f\u597d\u7684\u6c14\u4f53\u5438\u9644\u80fd\u529b<\/b><\/strong>\u3002<\/b><\/strong>\u4f20\u7edf\u7684\u82dd\u9170\u4e9a\u80fa\u6750\u6599\u7531\u4e8e\u5206\u5b50\u95f4\u7684\u7d27\u5bc6\u5806\u79ef\uff0c\u901a\u5e38\u7531\u4e00\u7ef4\u6216\u8005\u4e8c\u7ef4\u7ed3\u6784\u7ec4\u6210\uff0c\u672c\u5de5\u4f5c\u901a\u8fc7\u4f7f\u82dd\u9170\u4e9a\u80fa\u4e0e\u91d1\u5c5e\u914d\u4f4d\u5c06\u8fd9\u7c7b\u6750\u6599\u6269\u5c55\u5230\u4e09\u7ef4\u7ed3\u6784\uff0c\u5177\u6709\u4f18\u5f02\u7684\u591a\u5b54\u6027\u80fd\u53ca\u6c14\u4f53\u5438\u9644\u80fd\u529b\u3002<\/p>\n \uff082\uff09\u5f62\u6210\u5177\u6709\u6781\u9ad8\u7a33\u5b9a\u6027\u7684\u9634\u79bb\u5b50\u81ea\u7531\u57fa<\/b><\/strong>\u3002<\/b><\/strong>\u7531\u4e8eZr-PDI\u672c\u8eab\u7684\u7f3a\u7535\u5b50\u6027\uff0cZr-PDI\u53ef\u4ee5\u4e0e\u80fa\u7c7b\u84b8\u6c7d\u53d1\u751f\u5149\u8bf1\u5bfc\u7535\u5b50\u8f6c\u79fb\uff0c\u751f\u6210\u9634\u79bb\u5b50\u81ea\u7531\u57faZr-PDI\u2022\u2013<\/sup>\u3002\u7531\u4e8e\u4e09\u7ef4\u00a0MOF\u7684\u6846\u67b6\u5c4f\u853d\u4f5c\u7528\u53ef\u7a33\u5b9a\u751f\u6210\u7684\u9634\u79bb\u5b50\u81ea\u7531\u57fa\uff0c\u8be5\u65b9\u6cd5\u4e0d\u9700\u8981\u989d\u5916\u7684\u5316\u5b66\u4fee\u9970\uff0c\u7b80\u5355\u4fbf\u6377\u3002<\/p>\n \uff083\uff09\u9ad8\u6548\u7684\u5149\u70ed\u8f6c\u5316<\/b><\/strong>\u6027\u80fd<\/b><\/strong>\u3002<\/b><\/strong>Zr-PDI\u2022\u2013<\/sup>\u6709\u5f88\u5f3a\u7684\u8fd1\u7ea2\u5916\u5438\u6536\u7279\u70b9\uff0c\u5728808 nm\u7684\u8fd1\u7ea2\u5916\u6fc0\u5149\u7167\u5c04\u4e0b\uff0c\u5149\u70ed\u8f6c\u5316\u6548\u7387\u8fbe\u523052.3%\u3002\u8fd9\u4e5f\u662f\u9996\u6b21\u62a5\u9053\u7684PDI\u57faMOF\u6750\u6599\uff0c\u5c55\u73b0\u51fa\u8fd1\u7ea2\u5916\u5149\u70ed\u5347\u6e29\u6027\u80fd\uff0c\u5728\u5149\u70ed\u6297\u80bf\u7624\u9886\u57df\u5177\u6709\u6f5c\u5728\u5e94\u7528\u3002<\/p>\n \u8be5\u7814\u7a76\u7684\u610f\u4e49\u5728\u4e8e\uff1a\u5f00\u521b\u6027\u5730\u6784\u5efa\u4e86\u4e00\u79cd\u57fa\u4e8e\u82dd\u9170\u4e9a\u80fa\u7684\u4e09\u7ef4\u591a\u5b54MOF\u6750\u6599\uff0c\u53ef\u7a33\u5b9a\u9634\u79bb\u5b50\u81ea\u7531\u57fa\uff0c\u5177\u6709\u5f88\u5f3a\u7684\u8fd1\u7ea2\u5916\u5438\u6536\u7279\u70b9\u4ee5\u53ca\u9ad8\u6548\u7684\u5149\u70ed\u8f6c\u5316\u6027\u80fd\uff0c\u56e0\u800c\u63d0\u4f9b\u4e86\u4e00\u79cd\u5e94\u7528\u4e8e\u5149\u70ed\u7597\u9886\u57df\u7684MOF\u6750\u6599\u3002<\/p>\n
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