{"id":167271,"date":"2019-02-17T06:17:49","date_gmt":"2019-02-16T22:17:49","guid":{"rendered":"\/\/m.iemloyee.com\/?p=167271"},"modified":"2019-02-16T20:36:58","modified_gmt":"2019-02-16T12:36:58","slug":"%e5%b7%b2%e6%a0%a1%e7%a8%bf%e4%bb%b6-%e5%90%89%e5%a4%a7-%e6%ae%b5%e7%be%bd-ucla-%e6%9d%a8%e9%98%b3-adv-funct-mater-%e7%bb%bc%e8%bf%b0-%e5%85%b3%e4%ba%8e%e9%92%99%e9%92%9b%e7%9f%bf%e5%a4%aa","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=167271","title":{"rendered":"\u5409\u5927 \u6bb5\u7fbd & UCLA \u6768\u9633 Adv. Funct. Mater. \u7efc\u8ff0: \u5173\u4e8e\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u7a33\u5b9a\u6027\u7684\u7efc\u8ff0"},"content":{"rendered":"

\u3010\u80cc\u666f\u4ecb\u7ecd\u3011<\/strong><\/p>\n

\u00a0 \u00a0 \u00a0 \u00a0 \u00a0\u5982\u4eca\uff0c\u968f\u7740\u5168\u4e16\u754c\u4eba\u53e3\u7684\u5feb\u901f\u589e\u957f\uff0c\u5168\u7403\u7684\u80fd\u6e90\u6d88\u8017\u9010\u6e10\u589e\u52a0\uff0c\u80fd\u6e90\u95ee\u9898\u4e9f\u5f85\u89e3\u51b3\u3002\u56e0\u6b64\uff0c\u73b0\u5728\u5bf9\u53ef\u6301\u7eed\u548c\u53ef\u518d\u751f\u80fd\u6e90\u7684\u6025\u9700\u6c42\uff0c\u8feb\u4f7f\u4eba\u4eec\u52a0\u5feb\u5728\u8fd9\u65b9\u9762\u7684\u7814\u7a76\u3002\u5176\u4e2d\uff0c\u5145\u5206\u5229\u7528\u5de8\u5927\u7684\u592a\u9633\u80fd\uff0c\u5c06\u5176\u8f6c\u5316\u4e3a\u7535\u80fd\u662f\u6700\u6709\u5e0c\u671b\u7684\u7814\u7a76\u4e4b\u4e00\u3002\u56e0\u4e3a\u592a\u9633\u80fd\u7535\u6c60\u6280\u672f\u901a\u8fc7\u5149\u5b50\u80fd\u91cf\u76f4\u63a5\u8f6c\u6362\u4e3a\u7535\u80fd\uff0c\u63d0\u4f9b\u4e86\u4e00\u79cd\u751f\u6001\u53cb\u597d\u7684\u53ef\u518d\u751f\u80fd\u6e90\u9014\u5f84\u3002\u73b0\u5728\uff0c\u9762\u4e34\u7684\u95ee\u9898\u662f\u5982\u4f55\u8bbe\u8ba1\u51fa\u9ad8\u8f6c\u6362\u6548\u7387\u3001\u4f4e\u6210\u672c\u4ee5\u5927\u89c4\u6a21\u5236\u9020\u7684\u5149\u4f0f\u5668\u4ef6\u3002
\n \u00a0 \u00a0 \u00a0 \u00a0 \u00a0\u6700\u8fd1\uff0c\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\uff08PSCs\uff09\u88ab\u5e7f\u6cdb\u8ba4\u4e3a\u662f\u53ef\u4ee5\u66ff\u4ee3\u4f20\u7edf\u592a\u9633\u80fd\u7535\u6c60\u6280\u672f\u7684\u53ef\u518d\u751f\u6280\u672f\uff0c\u4ee5\u5e94\u5bf9\u5168\u7403\u80fd\u6e90\u751f\u4ea7\u548c\u6c14\u5019\u53d8\u5316\u7684\u6311\u6218\u3002\u6700\u8fd1\u51fa\u73b0\u4e86\u4e00\u7c7b\u5177\u6709ABX3<\/sub>\u7ed3\u6784\u7684\u6709\u673a-\u65e0\u673a\u9499\u949b\u77ff\u6709\u8da3\u7684\u534a\u5bfc\u4f53\uff0c\u5176\u4e2dA\u662f\u94ef\uff08Cs\uff09\u3001\u7532\u57fa\u94f5\uff08MA\uff09\u6216\u7532\u8112\uff08FA\uff09\uff1bB\u662fPb\u6216Sn\uff1bX\u662fCl\u3001Br\u6216I\u3002\u5229\u7528\u5305\u62ec\u55b7\u6d82\u3001\u6d78\u6d82\u3001\u5316\u5b66\u6c14\u76f8\u6c89\u79ef\uff08CVD\uff09\u7b49\u6280\u672f\u624b\u6bb5\u52a0\u5de5\u9499\u949b\u77ff\uff0c\u5236\u5907\u7684\u9499\u949b\u77ff\u5177\u6709\u4f18\u5f02\u7684\u6027\u80fd\uff0c\u4f8b\u5982\u5728\u5bbd\u5149\u8c31\u8303\u56f4\u5185\u7684\u5438\u6536\u3001\u76f4\u63a5\u5e26\u9699\u3001\u5fae\u7c73\u8303\u56f4\u5185\u7684\u7535\u8377\u8f7d\u6d41\u5b50\u6269\u6563\u957f\u5ea6\u548c\u7f3a\u9677\u5bb9\u9650\uff0c\u5c06\u6548\u7387\u4ece3.8\uff05\u63d0\u9ad8\u523023.7\uff05\u3002\u901a\u5e38\uff0cPSCs\u5177\u6709\u4e24\u79cd\u67b6\u6784\uff1ai)\u3001\u4ecb\u5b54\u7ed3\u6784\u5668\u4ef6\uff1bii)\u3001\u5e73\u9762\u5668\u4ef6\u3002\u5728\u4ecb\u5b54\u7ed3\u6784\u7684\u88c5\u7f6e\u4e2d\uff0c\u9499\u949b\u77ff\u7528\u4e8e\u4f7f\u4ecb\u5b54\u4e8c\u6c27\u5316\u949b\uff08TiO2<\/sub>\uff09\u5c42\u654f\u5316\uff0c\u800c\u5e73\u9762\u5668\u4ef6\u5177\u6709\u76f8\u5bf9\u7b80\u5355\u7684\u7ed3\u6784\u5e76\u4e14\u63d0\u4f9b\u66f4\u597d\u7684\u7535\u6c60\u6027\u80fd\u3002\u7136\u800c\uff0c\u957f\u671f\u7a33\u5b9a\u6027\u662f\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u6700\u5177\u6311\u6218\u6027\u7684\u95ee\u9898\uff0c\u5e94\u5f53\u5728\u5c06\u5176\u6295\u5165\u5b9e\u9645\u5e94\u7528\u4e4b\u524d\u4e88\u4ee5\u6df1\u5165\u7814\u7a76\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u6700\u8fd1\uff0c\u5409\u6797\u5927\u5b66\u7684\u6bb5\u7fbd\u6559\u6388\u548c\u52a0\u5dde\u5927\u5b66\u6d1b\u6749\u77f6\u5206\u6821\u7684\u6768\u9633\u6559\u6388\uff08\u5171\u540c\u901a\u8baf\u4f5c\u8005\uff09\uff0c\u7b2c\u4e00\u4f5c\u8005\u52a0\u5dde\u5927\u5b66\u6d1b\u6749\u77f6\u5206\u6821\u738b\u777f<\/strong>\u7b49\u4eba\u603b\u7ed3\u53d1\u8868\u5173\u4e8e\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u7a33\u5b9a\u6027\u7684\u7efc\u8ff0\u3002\u9996\u5148\uff0c\u5728\u6587\u4e2d\u5f3a\u8c03\u4e86\u5f71\u54cd\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\uff08PSCs\uff09\u529f\u7387\u8f6c\u6362\u6548\u7387\uff08PCE\uff09\u7684\u56e0\u7d20\u3002PSCs\u7684PCE\u4ece3.8\uff05\u663e\u7740\u589e\u52a0\u523023.7\uff05\uff0c\u4f46\u7a33\u5b9a\u6027\u5dee\u662f\u5bfc\u81f4PSCs\u5546\u4e1a\u5316\u7684\u4e3b\u8981\u969c\u788d\u4e4b\u4e00\u3002\u63a5\u7740\uff0c\u7b80\u8981\u6982\u8ff0\u4e86\u76ee\u524d\u4e3a\u63d0\u9ad8PSCs\u7a33\u5b9a\u6027\u6240\u505a\u7684\u52aa\u529b\uff0c\u5e76\u603b\u7ed3\u4e86\u9000\u5316\u7684\u539f\u56e0\u548c\u673a\u5236\u3002\u7136\u540e\uff0c\u603b\u7ed3\u4e86\u76ee\u524d\u63d0\u9ad8\u5668\u4ef6\u7a33\u5b9a\u6027\u7684\u7b56\u7565\u4e3b\u8981\u662f\u7ed3\u6784\u6548\u5e94\u3001\u5149\u6d3b\u6027\u5c42\u3001\u7a7a\u7a74\u548c\u7535\u5b50\u4f20\u8f93\u5c42\u3001\u7535\u6781\u6750\u6599\u548c\u5668\u4ef6\u5c01\u88c5\u3002\u6700\u540e\uff0c\u5bf9PSCs\u7684\u7ecf\u6d4e\u53ef\u884c\u6027\u8fdb\u884c\u4e86\u7b80\u8981\u7684\u8ba8\u8bba\u3002\u7814\u7a76\u6210\u679c\u4ee5\u9898\u4e3a\u201cA Review of Perovskites Solar Cell Stability\u201d<\/strong>\u53d1\u5e03\u5728\u8457\u540d\u671f\u520aAdv. Funct. Mater.<\/strong>\u4e0a\u3002<\/p>\n

\u3010\u56fe\u6587\u89e3\u8bfb\u3011<\/strong><\/p>\n

1\u3001\u7ed3\u6784\u5bf9PSCs\u7a33\u5b9a\u6027\u7684\u5f71\u54cd<\/strong><\/p>\n

1.1\u3001\u9499\u949b\u77ff\u5668\u4ef6\u7684\u7ed3\u6784<\/strong><\/p>\n

PSCs\u7531\u5939\u5728\u7535\u5b50\u4f20\u8f93\u5c42\uff08ETL\uff09\u548c\u7a7a\u7a74\u4f20\u8f93\u5c42\uff08HTL\uff09\u4e4b\u95f4\u7684\u6d3b\u6027\u9499\u949b\u77ff\u5c42\u7ec4\u6210\u3002<\/p>\n

\u56fe\u4e00\u3001PSCs\u7684\u4e24\u79cd\u7ed3\u6784<\/strong>
\n \"\"\uff08a\uff09 \u5178\u578b\u7684n-i-p\u7ed3\u6784\u7684PSCs\u80fd\u5e26\u56fe\uff1b<\/p>\n

\uff08b\uff09 \u5178\u578b\u7684p-i-n\u7ed3\u6784\u7684PSCs\u80fd\u5e26\u56fe\uff1b<\/p>\n

\uff08c\uff09\u4ecb\u5b54\u7684n-i-p\u7684PSCs\u5668\u4ef6\u7ed3\u6784\uff1b<\/p>\n

\uff08d\uff09\u5e73\u677f\u7684n-i-p\u7684PSCs\u5668\u4ef6\u7ed3\u6784\uff1b<\/p>\n

\uff08e\uff09\u5e73\u677f\u7684p-i-n\u7684PSCs\u5668\u4ef6\u7ed3\u6784\u3002<\/p>\n

1.2\u3001\u4ecb\u5b54\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60<\/strong><\/p>\n

\u65b0\u4e00\u4ee3\u5149\u7535\u8f6c\u6362\u5668-\u4ecb\u5b54\u592a\u9633\u80fd\u7535\u6c60\uff08\u5982\u67d3\u6599\u654f\u5316\u592a\u9633\u80fd\u7535\u6c60\u548c\u4ecb\u5b54\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\uff09\u7531\u4e8e\u5176\u6750\u6599\u6210\u672c\u4f4e\u3001\u5236\u9020\u5de5\u827a\u7b80\u5355\u3001\u80fd\u91cf\u8f6c\u6362\u6548\u7387\u9ad8\u800c\u53d7\u5230\u5e7f\u6cdb\u7684\u5173\u6ce8\u3002\u4f8b\u5982\uff0c\u901a\u8fc7\u4f7f\u7528CH3<\/sub>NH3<\/sub>PbI3<\/sub> (MAPbI3<\/sub>) \u7684\u9499\u949b\u77ff\u7eb3\u7c73\u6676\u4f53\u4f5c\u4e3a\u5149\u5438\u6536\u5242\u6765\u5236\u9020\u56fa\u6001MPSC\uff0c\u6210\u529f\u5b9e\u73b0\u4e86\u9ad8\u8fbe9.7\uff05\u7684PCE\u3002\u76ee\u524d\uff0c\u6709\u4e09\u79cd\u7b56\u7565\u5e7f\u6cdb\u7528\u4e8e\u6c89\u79efTiO2<\/sub>\u5c42\uff1a1)\u3001\u65cb\u6d82TiO2<\/sub>\u7eb3\u7c73\u9897\u7c92\u7684\u80f6\u4f53\u5206\u6563\u4f53\uff0c\u5728\u8fdb\u884c\u70ed\u5904\u7406 (\u949b\u6e90\uff1aTiCl4<\/sub>\u3001\u5f02\u4e19\u9187\u949b\u3001\u56db\u6b63\u4e01\u57fa\u949b\u9178\u76d0)\uff1b2)\u3001\u65cb\u6d82\u949b\u7684\u524d\u4f53\u6eb6\u6db2\u63a5\u7740\u8fdb\u884c\u70ed\u5904\u7406 [\u949b\u6e90\uff1aTiCl4<\/sub>\u3001\u5f02\u4e19\u9187\u949b\u3001\u4e8c\u5f02\u4e19\u9187\u949b\u4e8c (\u4e59\u9170\u4e19\u916e)]\uff1b3)\u3001\u55b7\u96fe\u70ed\u89e3\u6c89\u79ef [\u949b\u6e90\uff1a\u4e8c\u5f02\u4e19\u9187\u949b\u53cc (\u4e59\u9170\u4e59\u9178\u76d0)]\u3002\u6700\u8fd1\u4e5f\u62a5\u9053\u4e86\u5229\u7528\u4f4e\u6e29\u70e7\u7ed3\u7684\u65b9\u6cd5\u5728\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u4e2d\u5236\u5907\u6709\u6548TiO2<\/sub>\u5c42\u3002<\/p>\n

1.3\u3001\u5e73\u677f\u7684\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60 (n-i-p)<\/strong><\/p>\n

\u5e73\u677f\u7684\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\uff08PPSCs\uff09\u56e0\u5176\u5177\u6709\u4f4e\u6210\u672c\u3001\u6613\u52a0\u5de5\u548c\u4f4e\u6e29\u5de5\u827a\u7684\u72ec\u7279\u4f18\u70b9\u800c\u5f97\u5230\u5e7f\u6cdb\u7814\u7a76\u3002PPSCs\u53ef\u4ee5\u4f7f\u7528\u6b63\u5e38\u7ed3\u6784\u6216\u5012\u7f6e\u7ed3\u6784\u5236\u9020\u3002\u6b63\u5e38\u7ed3\u6784\u7c7b\u4f3c\u4e8eMPSCs\u4f46\u4e0d\u5229\u7528\u4ecb\u5b54\u6750\u6599\uff0c\u800c\u5012\u7f6e\u7ed3\u6784\u901a\u5e38\u4f7f\u7528\u6709\u673a\u534a\u5bfc\u4f53\u4f5c\u4e3aHTL\u548cETL\u3002\u5728PPSCs\u4e2d\uff0c\u6bcf\u4e00\u5c42\u90fd\u5bf9\u5668\u4ef6\u7684\u6027\u80fd\u6709\u91cd\u8981\u5f71\u54cd\u3002\u76ee\u524d\u5df2\u91c7\u7528\u8bb8\u591a\u7b56\u7565\u6765\u4f18\u5316\u5e73\u9762n-i-p PSCs\u7684\u6027\u80fd\uff0c\u4f8b\u5982\u9499\u949b\u77ff\u6676\u4f53\u8c03\u8282\u3001\u65b0\u9499\u949b\u77ff\u7ec4\u5206\u7684\u8bbe\u8ba1\u3001\u5f62\u8c8c\u63a7\u5236\u548c\u7535\u8377\u8f7d\u6d41\u5b50\u4f20\u8f93\u5c42\u7684\u6539\u6027\u3002<\/p>\n

1.4\u3001\u5e73\u677f\u7684\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60 (p-i-n)<\/strong><\/p>\n

\u5012\u7f6e\u7ed3\u6784\u5668\u4ef6\u5177\u6709\u8bb8\u591a\u4f18\u70b9\uff0c\u4f8b\u5982\u6613\u4e8e\u5236\u9020\u3001\u53ef\u5ffd\u7565\u7684\u78c1\u6ede\u73b0\u8c61\u548c\u9ad8\u7a33\u5b9a\u6027\u3002\u540c\u65f6\uff0c\u5012\u7f6e\u7684PSCs\u5728\u67d4\u6027\u548c\u9ad8\u6027\u80fd\u5149\u4f0f\u5668\u4ef6\u4e2d\u5177\u6709\u5f88\u5927\u7684\u5e94\u7528\u6f5c\u529b\u3002PEDOT\uff1aPSS\u56e0\u5176\u8f83\u9ad8\u7684\u5bfc\u7535\u6027\u548c\u53ef\u89c1\u5149\u8303\u56f4\u5185\u7684\u826f\u597d\u900f\u660e\u6027\u800c\u88ab\u5e7f\u6cdb\u7528\u4f5c\u5012\u7f6ePSCs\u7684\u7a7a\u7a74\u4f20\u8f93\u6750\u6599\u3002\u4f46\u662f\uff0cPEDOT\uff1aPSS\u5177\u6709\u4eb2\u6c34\u6027\uff0c\u53ef\u4ee5\u5f88\u5bb9\u6613\u5730\u5438\u6536\u5468\u56f4\u73af\u5883\u4e2d\u7684\u6c34\u5206\uff0c\u5bfc\u81f4\u5668\u4ef6\u7a33\u5b9a\u6027\u4e0b\u964d\u3002<\/p>\n

2\u3001PSCs\u7684\u5149\u6d3b\u6027\u5c42\u7684\u4e0d\u7a33\u5b9a\u6027<\/strong><\/p>\n

\u6700\u8fd1\uff0cPSCs\u56e0\u5176\u9ad8PCE\u3001\u4f4e\u5ec9\u7684\u8d77\u59cb\u6750\u6599\u548c\u6613\u4e8e\u5236\u9020\u800c\u5f15\u8d77\u4e86\u5f88\u591a\u5173\u6ce8\u3002\u7136\u800c\uff0c\u5668\u4ef6\u7684\u7a33\u5b9a\u6027\u4ecd\u7136\u662f\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u5546\u4e1a\u5316\u7684\u4e25\u91cd\u969c\u788d\uff0c\u5176\u4e0d\u7a33\u5b9a\u6027\u4e3b\u8981\u6765\u81ea\u9499\u949b\u77ff\u6750\u6599\u7684\u964d\u89e3\u3002\u540c\u65f6\uff0c\u4e0d\u7a33\u5b9a\u6027\u4e0e\u6709\u673a\u91d1\u5c5e\u5438\u6536\u5242\u3001\u6e7f\u5ea6\u6709\u5173\uff0c\u5e76\u4e14\u5b83\u4eec\u603b\u4f53\u4e0a\u5177\u6709\u8f83\u5dee\u7684\u957f\u671f\u70ed\u7a33\u5b9a\u6027\u3002 \u867d\u7136\u76ee\u524d\u5df2\u5c1d\u8bd5\u8bb8\u591a\u7b56\u7565\u4ee5\u5b9e\u73b0PSCs\u7684\u66f4\u597d\u7684\u7a33\u5b9a\u6027\uff0c\u4f8b\u59822D\u9499\u949b\u77ff\u7ed3\u6784\u8bbe\u8ba1\u3001\u9633\u79bb\u5b50\u5de5\u7a0b\u3001\u5728\u5b54\u548c\u7535\u5b50\u4f20\u9012\u5c42\u4e2d\u6dfb\u52a0\u6dfb\u52a0\u5242\u7528\u4e8e\u589e\u5f3aPCSs\u7684\u7a33\u5b9a\u6027\uff0c\u4f46\u662f\u89e3\u51b3\u9499\u949b\u77ff\u6750\u6599\u672c\u8eab\u7684\u4e0d\u7a33\u5b9a\u95ee\u9898\u662f\u63d0\u5347\u957f\u671f\u7a33\u5b9a\u6027\u7684\u5173\u952e\u6027\u7b56\u7565\u3002<\/p>\n

2.1\u3001\u6e7f\u5ea6\u5bfc\u81f4\u7684\u4e0d\u7a33\u5b9a\u6027<\/p>\n

PSCs\u5728\u6f6e\u6e7f\u73af\u5883\u4e2d\u7684\u964d\u89e3\u662f\u4e00\u4e2a\u6311\u6218\u6027\u7684\u95ee\u9898\u3002\u5728\u4e0d\u540c\u7684\u5f71\u54cd\u56e0\u7d20\u4e2d\uff0c\u6c34\u5206\u88ab\u8ba4\u4e3a\u662f\u6700\u5927\u7684\u6311\u6218\u4e4b\u4e00\u3002\u7531\u4e8e\u80fa\u76d0\u7684\u5438\u6e7f\u6027\u3001\u6c34\u5206\u7684\u4e0d\u7a33\u5b9a\u6027\uff0cMAPbI3-x<\/sub>Clx<\/sub>\u548cMAPbI3<\/sub>\u90fd\u7ecf\u53d7\u7c7b\u4f3c\u7684\u6c34\u5206\u8f85\u52a9\u964d\u89e3\u8fc7\u7a0b\uff0c\u5176\u4e2d\u7532\u80fa\u57fa\u56e2\u901a\u8fc7\u5347\u534e\u800c\u635f\u5931\u5e76\u5f62\u6210PbI2<\/sub>\u3002\u9499\u949b\u77ff\u7684\u9ad8\u4eb2\u6c34\u6027\u53ef\u5bfc\u81f4\u6750\u6599\u5bb9\u6613\u4ece\u5468\u56f4\u73af\u5883\u5438\u6536\u6c34\u5206\u5e76\u8bf1\u5bfc\u5f62\u6210\u7c7b\u4f3c\u4e8e(CH3<\/sub>NH3<\/sub>)4<\/sub>PbI6<\/sub> . 2H2<\/sub>O\u7684\u6c34\u5408\u7269\u4ea7\u7269\u3002\u7531\u4e8e\u6c34\u89e3\u548c\u6c27\u6c14\u73af\u5883\u654f\u611f\u6027\uff0cPCSs\u53d7\u5230\u4e25\u91cd\u5f71\u54cd\u3002\u9499\u949b\u77ff\u901a\u8fc7\u6c34\u89e3\u53cd\u5e94\u964d\u89e3\u53ef\u4ee5\u7531\u4ee5\u4e0b\u5316\u5b66\u65b9\u7a0b\u5f0f\u8868\u793a\uff1a<\/p>\n

CH3<\/sub>NH3<\/sub>PbI3<\/sub> (s) \u2194 PbI2<\/sub> (s) + CH3<\/sub>NH3<\/sub>I (aq)\u00a0 \u00a0(1)<\/p>\n

CH3<\/sub>NH3<\/sub>I (aq) \u2194 CH3<\/sub>NH2<\/sub> (aq) +HI (aq)\u00a0 \u00a0 \u00a0 \u00a0 \u00a0 (2)<\/p>\n

4HI (aq) + O2<\/sub>(g) \u2194 2I2<\/sub> (s) + 2H2<\/sub>O (l)\u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0(3)<\/p>\n

2HI (aq) \u2194 H2<\/sub> (g) + I2<\/sub> (s)\u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 (4)<\/p>\n

\u56fe\u4e8c\u3001\u6e7f\u5ea6\u4e3a45\uff05\u65f6\uff0c\u6e7f\u5ea6\u7a33\u5b9a\u6027\u6d4b\u91cf<\/strong>
\n \"\"
\n \u56fe\u4e09\u3001\u81ea\u4e0a\u800c\u4e0b\u7684\u626b\u63cf\u7535\u5b50\u663e\u5fae\u7167\u7247\u663e\u793a\u57280\uff05\u300150\uff05\u548c90\uff05RH\u4e0b\u50a8\u5b5814\u5929<\/strong>
\n \"\"
\n 2.2\u3001\u7d2b\u5916\u7ebf\u4e0d\u7a33\u5b9a\u6027<\/strong><\/p>\n

\u9664\u4e86\u6e7f\u5ea6\u5f71\u54cdPSCs\u7684\u7a33\u5b9a\u6027\u5916\uff0c\u5f71\u54cd\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u7a33\u5b9a\u6027\u7684\u53e6\u4e00\u4e2a\u91cd\u8981\u56e0\u7d20\u662f\u7d2b\u5916\u7ebf\u7167\u5c04\u3002\u4e0e\u5176\u4ed6\u591a\u79cd\u592a\u9633\u80fd\u7535\u6c60\u6280\u672f\u4e00\u6837\uff0c\u7167\u660e\u6210\u4e3a\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u52a3\u5316\u7684\u539f\u56e0\u4e4b\u4e00\u3002\u5f53\u9499\u949b\u77ff\u8584\u819c\u7ecf\u53d7\u8f7b\u548c\u5e72\u71e5\u7a7a\u6c14\u65f6\uff0c\u9499\u949b\u77ff\u5c42\u8fc5\u901f\u5206\u89e3\u6210\u7532\u80fa\u3001PbI2<\/sub>\u548cI2<\/sub>\u3002\u9499\u949b\u77ff\u4e0a\u7684\u5149\u751f\u7535\u5b50\u4e0e\u5206\u5b50\u6c27\u53cd\u5e94\u5f62\u6210\u8d85\u6c27\u5316\u7269\uff0c\u8d85\u6c27\u5316\u7269\u8fdb\u4e00\u6b65\u4e0e\u9499\u949b\u77ff\u6d3b\u6027\u5c42\u7684MA\u53cd\u5e94\u3002\u56e0\u6b64\uff0c\u7528\u4e0d\u542b\u9178\u8d28\u5b50\u7684\u7269\u8d28\u4ee3\u66ff\u7532\u57fa\u94f5\u7ec4\u5206CH3<\/sub>NH3<\/sub>PbI3<\/sub>\u662f\u53ef\u4ee5\u63d0\u9ad8\u5bf9\u6c27\u7684\u8010\u53d7\u6027\u5e76\u589e\u5f3a\u7a33\u5b9a\u6027\u3002<\/p>\n

2.3\u3001\u70ed\u4e0d\u7a33\u5b9a\u6027<\/strong><\/p>\n

PSCs\u7684\u70ed\u7a33\u5b9a\u6027\u4e5f\u5f15\u8d77\u91cd\u5927\u5173\u6ce8\uff0c\u56e0\u4e3a\u5176\u53d7\u5230\u9ad8\u6e29\u5f71\u54cd\uff0c\u4f1a\u4f7f\u88c5\u7f6e\u9000\u5316\u3002\u90e8\u5206\u7814\u7a76\u4eba\u5458\u8868\u793a\uff0c\u9499\u949b\u77ff\u7684\u4e0d\u7a33\u5b9a\u6027\u4e0e\u6676\u754c\uff08GBs\uff09\u6216\u8868\u9762\u6709\u5173\uff0c\u7528\u5408\u9002\u7684\u4fdd\u62a4\u6750\u6599\u5c01\u76d6\u8fd9\u4e9bGB\u662f\u63d0\u9ad8\u9499\u949b\u77ff\u7a33\u5b9a\u6027\u7684\u6709\u5438\u5f15\u529b\u7684\u7b56\u7565\u3002\u4f17\u6240\u5468\u77e5\uff0c\u6e29\u5ea6\u5bf9\u9499\u949b\u77ff\u7684\u6676\u4f53\u7ed3\u6784\u548c\u76f8\u662f\u5177\u6709\u5f88\u5927\u7684\u5f71\u54cd\u3002\u4f8b\u5982\u5148\u524d\u62a5\u9053\uff0c\u4ece\u56db\u65b9\u5230\u7acb\u65b9\u7684\u76f8\u53d8\u53d1\u751f\u572854-56 \u2103\u3002\u6839\u636e\u56fd\u9645\u6807\u51c6\uff0c\u592a\u9633\u80fd\u6a21\u5757\u5728\u8fd0\u884c\u671f\u95f4\u5c06\u66b4\u9732\u5728\u9ad8\u6e29\u4e0b\uff0c\u56e0\u800c\u8981\u6c42\u592a\u9633\u80fd\u7535\u6c60\u5fc5\u987b\u6709\u9ad8\u8fbe85 \u00b0C\u7684\u70ed\u7a33\u5b9a\u6027\u3002<\/p>\n

\u56fe\u56db\u30013D\u9499\u949b\u77ff\u548c2D\u9499\u949b\u77ff\u7684TGA\u66f2\u7ebf<\/strong>
\n \"\"<\/strong>
\n \u56fe\u4e94\u3001\u5728\u70ed\u5e94\u529b\u6d4b\u8bd5\u671f\u95f4\uff081000 h@85\u00a0o<\/sup>C\u300185\uff05RH\uff09\u4e0b\u6700\u4f73\u5c01\u88c5DSCs\u7684\u7a33\u5b9a\u6027\u6d4b\u8bd5\u793a\u4f8b<\/strong>
\n \"\"
\n \u56fe\u516d\u3001\u4fee\u9970\u548c\u672a\u4fee\u9970\u9499\u949b\u77ff\u5bf9\u6e7f\u5ea6\u3001\u70ed\u4ee5\u53ca\u540c\u5b58\u6e7f\u5ea6\u548c\u70ed\u7684\u7a33\u5b9a\u6027<\/strong>
\n \"\"\uff08a\uff09\u5728\u6e7f\u5ea6\u4e3a45\uff05\u7684\u6761\u4ef6\u4e0b\u6d4b\u91cf\u7684\u6e7f\u5ea6\u7a33\u5b9a\u6027\uff1b<\/p>\n

\uff08b\uff09\u5728N2<\/sub>\u73af\u5883\u4e2d\uff0c85 \u2103\u4e0b\u6d4b\u91cf\u7684\u52a0\u70ed\u7a33\u5b9a\u6027\uff1b<\/p>\n

\uff08c\uff09\u572885 \u2103\u3001\u6e7f\u5ea6\u4e3a45\uff05\u7684\u6761\u4ef6\u4e0b\u6d4b\u8bd5\u6e7f\u5ea6\u548c\u52a0\u70ed\u7a33\u5b9a\u6027\uff1b<\/p>\n

\uff08d\uff09\u9499\u949b\u77ff\u819c\u7684\u7167\u7247\uff08\u5de6\uff09\u548c\u4e0d\uff08\u53f3\uff09\u4fee\u6539\u572885 \u2103\u3001\u6e7f\u5ea645\uff05\u548c\u4e0d\u540c\u65f6\u95f4\u4e0b\u50a8\u5b58\u3002<\/p>\n

2.4\u3001\u7ed3\u6784\u7a33\u5b9a\u6027<\/strong><\/p>\n

\u5728\u5f71\u54cd\u9499\u949b\u77ff\u6750\u6599\u7a33\u5b9a\u6027\u7684\u5404\u79cd\u56e0\u7d20\u4e2d\uff0c\u6676\u4f53\u7ed3\u6784\u4e5f\u662f\u4e00\u4e2a\u91cd\u8981\u56e0\u7d20\u3002 \u6709\u62a5\u9053\u53d1\u73b0\uff0c\u9499\u949b\u77ff\u5316\u5408\u7269\u4e0e\u6709\u673a\u5206\u5b50\u5728\u6e7f\u5ea6\u3001\u6c27\u6c14\u3001\u5149\u548c\u70ed\u7684\u5b58\u5728\u4e0b\u662f\u4e0d\u7a33\u5b9a\u7684\u3002\u56e0\u6b64\uff0c\u63d0\u9ad8\u6676\u4f53\u7ed3\u6784\u7684\u7a33\u5b9a\u6027\u662f\u4e00\u4e2a\u5173\u952e\u6027\u95ee\u9898\u3002\u56e0\u800c\uff0c\u76ee\u524d\u6709\u5404\u79cd\u5de5\u5177\u548c\u6307\u6807\u53ef\u4ee5\u4fc3\u8fdb\u6676\u4f53\u7ed3\u6784\u7684\u8bc4\u4f30\u3002\u4f8b\u5982\uff0c\u63d0\u51fa\u4e86\u5bb9\u5dee\u56e0\u5b50\u7684\u6982\u5ff5\u6765\u63cf\u8ff0\u9499\u949b\u77ff\u6750\u6599\u7684\u7ed3\u6784\u7a33\u5b9a\u6027\u3002Goldschmidt\u5bb9\u5dee\u56e0\u5b50\uff08t\uff09\u662f\u4e00\u4e2a\u53ef\u9760\u7684\u7ecf\u9a8c\u6307\u6807\uff0c\u7528\u4e8e\u9884\u6d4b\u54ea\u79cd\u7ed3\u6784\u4f18\u5148\u5f62\u6210\u3002<\/p>\n

\u56fe\u4e03\u3001\u9499\u949b\u77ff\u6750\u6599\u5bb9\u5dee\u56e0\u5b50\u4e0e\u6676\u4f53\u7ed3\u6784\u7684\u76f8\u5173\u6027<\/strong>
\n \"\"
\n 2.5\u3001\u79bb\u5b50\u8fc1\u79fb\u5bf9\u7a33\u5b9a\u6027\u7684\u5f71\u54cd<\/strong><\/p>\n

\u5bf9\u6bd4\u4f20\u7edf\u7684\u5149\u6d3b\u6027\u6750\u6599\u5982\u7845\uff0c\u6709\u673a-\u65e0\u673a\u6742\u5316\u9499\u949b\u77ff\u6750\u6599\u663e\u793a\u51fa\u4e86\u663e\u7740\u7684\u79bb\u5b50\u7279\u6027\uff0c\u7531\u4e8e\u9499\u949b\u77ff\u5c42\u5185\u79bb\u5b50\u8fc1\u79fb\u7684\u6d3b\u5316\u80fd\u76f8\u5bf9\u8f83\u4f4e\uff0c\u800c\u9650\u5236\u4e86\u9499\u949b\u77ff\u6750\u6599\u7684\u957f\u671f\u7a33\u5b9a\u6027\u3002\u76ee\u524d\u5df2\u53d1\u73b0\uff0c\u5f53\u5668\u4ef6\u7ecf\u53d7\u70ed\u5e94\u529b\u3001\u5916\u90e8\u7535\u504f\u538b\u6216\u5728\u7167\u5c04\u4e0b\u65f6\uff0c\u79bb\u5b50\u6269\u6563\u5c06\u53d8\u5f97\u4e25\u91cd\u3002<\/p>\n

3\u3001\u7535\u8377\u4f20\u8f93\u5c42\u5bf9\u7a33\u5b9a\u6027\u7684\u5f71\u54cd<\/strong><\/p>\n

\u9664\u4e86\u5149\u6d3b\u6027\u5c42\u81ea\u8eab\u7684\u4e0d\u7a33\u5b9a\u6027\u4e4b\u5916\uff0c\u4e3a\u4e86\u8bc4\u4f30\u5668\u4ef6\u7684\u7a33\u5b9a\u6027\uff0c\u8fd8\u9700\u8981\u8003\u8651\u5176\u4ed6\u5143\u4ef6\u7684\u5f71\u54cd\uff0c\u5982\u7535\u5b50\u548c\u7a7a\u7a74\u4f20\u8f93\u5c42\u548c\u7535\u6781\u3002\u4f20\u8f93\u5c42\u4e3b\u8981\u6709\u4e24\u4e2a\u4f5c\u7528\uff1a1)\u3001\u63d0\u4f9b\u8db3\u591f\u7684\u7535\u8377\u6536\u96c6\u6548\u7387\uff1b2)\u3001\u4e0e\u7535\u6781\u5f62\u6210\u6b27\u59c6\u63a5\u89e6\u3002 \u4e3a\u4e86\u7406\u89e3\u4f20\u8f93\u5c42\u5bf9\u8bbe\u5907\u7a33\u5b9a\u6027\u7684\u5f71\u54cd\uff0c\u4e0b\u9762\u56de\u987e\u4f20\u8f93\u6750\u6599\u7684\u7279\u6027\u3002<\/p>\n

3.1\u3001\u7535\u5b50\u4f20\u8f93\u5c42<\/strong><\/p>\n

\u9ad8\u6548\u7684PSCs\u901a\u5e38\u9700\u8981\u7535\u5b50\u4f20\u8f93\u6750\u6599\uff08ETM\uff09\u548c\u9499\u949b\u77ff\u6750\u6599\u4e4b\u95f4\u826f\u597d\u7684\u7535\u5b50\u9009\u62e9\u6027\u63a5\u89e6\uff0c\u4ee5\u51cf\u5c11\u7535\u5b50\u8f6c\u79fb\u7684\u52bf\u5792\uff0c\u540c\u65f6\u963b\u6321\u7a7a\u7a74\u4f20\u8f93\uff0c\u4ece\u800c\u6700\u5c0f\u5316\u754c\u9762\u5904\u7684\u8f7d\u6d41\u5b50\u590d\u5408\u3002ETM\u4ece\u5149\u6d3b\u6027\u5c42\u4e2d\u63d0\u53d6\u5149\u751f\u7535\u5b50\u5e76\u5c06\u5176\u4f20\u8f93\u5230\u9634\u6781\uff0c\u5728\u5149\u4f0f\u6027\u80fd\u4e2d\u4e5f\u8d77\u7740\u91cd\u8981\u4f5c\u7528\u3002\u9002\u7528\u4e8ePSCs\u7684ETM\u5e94\u6ee1\u8db3\u4ee5\u4e0b\u8981\u6c42\uff1a\u9499\u949b\u77ff\u6750\u6599\u548c\u7535\u6781\u4e4b\u95f4\u826f\u597d\u7684\u80fd\u91cf\u6392\u5217\u3001\u9ad8\u7535\u5b50\u8fc1\u79fb\u7387\u3001\u6613\u6eb6\u4e8e\u6709\u673a\u6eb6\u5242\u548c\u826f\u597d\u7684\u7a7a\u6c14\u7a33\u5b9a\u6027\u3002\u4f7f\u7528\u6709\u673a\u6750\u6599\u4f5c\u4e3aETM\u4e5f\u5e94\u5177\u6709\u4ee5\u4e0b\u4f18\u70b9\uff1a\u4e0e\u67d4\u6027\u57fa\u677f\u7684\u517c\u5bb9\u6027\u3001\u4f4e\u6eb6\u6db2\u5904\u7406\u6e29\u5ea6\u3001\u53ef\u5ffd\u7565\u7684\u6ede\u540e\u548c\u6613\u4e8e\u5236\u9020\u3002 \u5728n-i-p\u7ed3\u6784\u7684PSCs\u4e2d\u7684\u5e38\u89c1ETM\u5305\u62ecTiO2<\/sub>\u3001SnO2<\/sub>\u3001\u548cZnO2<\/sub>\u4ee5\u53ca\u4e00\u4e9b\u63ba\u6742\u7684\u6c27\u5316\u7269\u3002<\/p>\n

3.2\u3001\u7a7a\u7a74\u4f20\u8f93\u5c42<\/strong><\/p>\n

HTMs\u901a\u5e38\u6709\u5fc5\u8981\u964d\u4f4e\u4f20\u8f93\u963b\u6321\u5c42\u5e76\u963b\u6b62\u9499\u949b\u77ff\u548c\u7535\u6781\u4e4b\u95f4\u7684\u7535\u5b50\u4f20\u8f93\uff0c\u540c\u65f6\u8f7d\u6d41\u5b50\u590d\u5408\u8f83\u5c11\u4ee5\u63d0\u9ad8\u5668\u4ef6\u6548\u7387\u3002HTMs\u5728\u63d0\u9ad8PSCs\u7684\u6548\u7387\u65b9\u9762\u53d1\u6325\u7740\u5173\u952e\u4f5c\u7528\u3002\u7279\u522b\u5730\u662f\u5728\u4f20\u7edf\u4f20\u8f93\u7a7a\u7a74\u7ed3\u6784\u4e2d\u7684HTL\uff0c\u963b\u6321\u7535\u5b50\u548c\u4fdd\u62a4\u9499\u949b\u77ff\u514d\u53d7\u5916\u90e8\u56e0\u7d20\uff08\u5305\u62ec\u6c34\u5206\u3001\u70ed\u91cf\u548c\u6c27\u6c14\uff09\u65b9\u9762\u8d77\u7740\u91cd\u8981\u4f5c\u7528\u3002\u5e38\u89c1\u6709\u7ec4\u6210\u6709PEDOT:PSS\u3001Spiro-OMeTAD\u3001PTAA\u548c\u65e0\u673a\u6750\u6599\u7b49\u3002<\/p>\n

4\u3001\u7535\u6781\u6750\u6599\u7684\u4f5c\u7528<\/strong><\/p>\n

4.1\u3001\u7535\u6781\u6750\u6599<\/strong><\/p>\n

\u5c3d\u7ba1\u7535\u6781\u6750\u6599\u4e0d\u4e0e\u9499\u949b\u77ff\u5c42\u76f4\u63a5\u63a5\u89e6\uff0c\u4f46\u662f\u7535\u6781\u6750\u6599\u7684\u7a33\u5b9a\u6027\u5bf9\u4e8e\u957f\u671f\u64cd\u4f5c\u4e5f\u662f\u91cd\u8981\u7684\u3002\u7535\u6781\u5728\u6700\u4e0a\u5c42\uff0c\u662f\u6700\u63a5\u8fd1\u73af\u5883\u3002\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\uff08PSCs\uff09\u662f\u901a\u5e38\u5305\u62ec\u57fa\u677f\u3001\u7535\u6781\u3001\u9499\u949b\u77ff\u5149\u6d3b\u6027\u5c42\u4ee5\u53ca\u5fc5\u8981\u7684\u7535\u8377\u4f20\u8f93\u5c42\u7684\u7ed3\u6784\u3002\u56e0\u6b64\uff0c\u7535\u6781\u5fc5\u987b\u8db3\u591f\u81f4\u5bc6\u4ee5\u51cf\u7f13\u6e17\u900f\u5230\u9499\u949b\u77ff\u5c42\u4e2d\u7684\u6c34\u5206\u3002<\/p>\n

4.2\u3001\u7535\u6781\u9000\u5316<\/strong><\/p>\n

\u9499\u949b\u77ff\u5c42\u5bf9\u6c34\u3001\u6c27\u548c\u6e29\u5ea6\u7684\u9ad8\u654f\u611f\u6027\u662f\u5176\u7a33\u5b9a\u6027\u5dee\u7684\u6839\u672c\u539f\u56e0\u3002\u9664\u9499\u949b\u77ff\u5c42\u5916\uff0c\u754c\u9762\u5c42\u548c\u7535\u6781\u7684\u9000\u5316\u4e5f\u662f\u5bfc\u81f4\u9499\u949b\u77ff\u5c42\u9000\u5316\u7684\u539f\u56e0\u3002\u56e0\u6b64\uff0c\u5728\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u4e2d\u901a\u5e38\u91c7\u7528Ag\u6216Au\u4f5c\u4e3a\u9876\u90e8\u7535\u6781\u3002\u5728\u5f15\u8d77\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u5931\u7a33\u7684\u8bf8\u591a\u56e0\u7d20\u4e2d\uff0c\u666e\u901a\u7535\u6781\u6750\u6599\u4e0e\u9499\u949b\u77ff\u7684\u53cd\u5e94\u4e5f\u91cd\u8981\u539f\u56e0\u4e4b\u4e00\u3002\u540c\u65f6\uff0c\u5c06\u5668\u4ef6\u66b4\u9732\u5728\u9ad8\u538b\u73af\u5883\u4e2d\u4e5f\u53ef\u80fd\u4f1a\u5bfc\u81f4\u9876\u90e8\u7535\u6781\u7684\u5206\u89e3\u3002<\/p>\n

4.3\u3001\u7535\u6781\u6750\u6599\u7684\u5f71\u54cd<\/strong><\/p>\n

\u901a\u5e38\uff0cAg\u3001Al\u3001Au\u662fMAPbX3<\/sub>\u5149\u7535\u5b50\u5668\u4ef6\u4e2d\u6700\u5e38\u7528\u7684\u7535\u6781\u4e4b\u4e00\u3002\u91d1\u3001\u94f6\u3001\u94dd\u7b49\u91d1\u5c5e\u7535\u6781\u4e5f\u5b58\u5728\u7a33\u5b9a\u6027\u95ee\u9898\u3002\u94f6\u548c\u94dd\u7535\u6781\u5728\u9499\u949b\u77ff\u4e2d\u53d7\u5230\u79bb\u5b50\u8fc1\u79fb\u7684\u8150\u8680\uff0c\u5bfc\u81f4\u660e\u663e\u7684\u989c\u8272\u53d8\u5316\u548cPCE\u8870\u51cf\u3002<\/p>\n

5\u3001\u5668\u4ef6\u5c01\u88c5<\/strong><\/p>\n

\u4f17\u6240\u5468\u77e5\uff0c\u7531\u4e8e\u9499\u949b\u77ff\u5728\u63a5\u89e6\u6c34\u5206\u65f6\u6613\u5206\u89e3\uff0c\u56e0\u6b64PSCs\u88c5\u7f6e\u7684\u6027\u80fd\u5728\u66b4\u9732\u4e8e\u73af\u5883\u5927\u6c14\u6761\u4ef6\u4e0b\u6781\u6613\u9000\u5316\u3002\u901a\u8fc7\u5668\u4ef6\u5c01\u88c5\u8fdb\u884c\u6700\u5916\u5c42\u7684\u4fee\u9970\uff0c\u662f\u53ef\u4ee5\u63d0\u9ad8\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u7684\u7a33\u5b9a\u6027\u3002\u5668\u4ef6\u7684\u5c01\u88c5\u5c06\u5728\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u7684\u5546\u4e1a\u5316\u8fc7\u7a0b\u4e2d\u53d1\u6325\u4e00\u5b9a\u7684\u4f5c\u7528\uff0c\u56e0\u4e3a\u672a\u5c01\u88c5\u7684\u5668\u4ef6\u901a\u5e38\u5728\u8fde\u7eed\u5149\u7167\u4e0b\u6570\u5c0f\u65f6\u540e\u51fa\u73b0\u4e25\u91cd\u9000\u5316\uff0c\u800c\u5c01\u88c5\u7684\u5668\u4ef6\u5bff\u547d\u66f4\u957f\u3002\u5c01\u88c5\u7b56\u7565\u6d89\u53ca\u4e00\u79cd\u5177\u6709\u6297\u6c34\u3001\u6297\u6c27\u6e17\u900f\u6027\u7684\u6750\u6599\uff0c\u8be5\u6750\u6599\u901a\u8fc7\u653e\u7f6e\u5f15\u51fa\u7535\u6781\u5bf9\u5668\u4ef6\u8fdb\u884c\u5c01\u88c5\uff0c\u5728\u4e0d\u5f71\u54cd\u4fdd\u62a4\u5c01\u88c5\u5b8c\u6574\u6027\u7684\u60c5\u51b5\u4e0b\u4ecd\u53ef\u63a5\u5165\u3002\u5c01\u88c5\u662f\u5149\u4f0f\u5668\u4ef6\u7684\u91cd\u8981\u7ec4\u6210\u90e8\u5206\uff0c\u5b83\u53ef\u4ee5\u4fdd\u62a4\u5149\u4f0f\u5668\u4ef6\u4e0d\u53d7\u6c27\u6c14\u548c\u6c34\u5206\u7684\u7834\u574f\u3002\u4e00\u822c\u60c5\u51b5\u4e0b\uff0c\u8be5\u88c5\u7f6e\u7531\u4e00\u5c42\u8584\u8584\u7684\u73bb\u7483\u8986\u76d6\u7269\u8986\u76d6\uff0c\u5e76\u7528\u7d2b\u5916\u7ebf\u56fa\u5316\u7684\u73af\u6c27\u6811\u8102\u5bc6\u5c01\u3002<\/p>\n

6\u3001\u9499\u949b\u77ff\u88c5\u7f6e\u7684\u7ecf\u6d4e\u53ef\u884c\u6027<\/strong><\/p>\n

\u5728\u5efa\u7acb\u4efb\u4f55\u65b0\u578b\u592a\u9633\u80fd\u7535\u6c60\u6280\u672f\u4e4b\u524d\uff0c\u9700\u8981\u4ed4\u7ec6\u5904\u7406\u6709\u8bb8\u591a\u65e2\u5b9a\u7684\u8d44\u91d1\u6210\u672c\u548c\u8fd0\u8425\u6210\u672c\u95ee\u9898\u3002\u89c2\u5bdf\u592a\u9633\u80fd\u7535\u6c60\u7684\u7ecf\u6d4e\u65b9\u6cd5\u662f\u901a\u8fc7\u8bc4\u4f30\u4e0d\u540c\u592a\u9633\u80fd\u7535\u6c60\u7684\u80fd\u91cf\u56de\u6536\u65f6\u95f4\uff08EPBT\uff09\u3002EPBT\u53ef\u4ee5\u901a\u8fc7Bhandari\u7b49\u4eba\u7ed9\u51fa\u7684\u516c\u5f0f\u8ba1\u7b97\u3002<\/p>\n

\"\"
\n 7\u3001\u603b\u7ed3<\/strong><\/p>\n

\u7efc\u4e0a\u6240\u8ff0\uff0c\u968f\u7740\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u8f6c\u6362\u6548\u7387\u7684\u5feb\u901f\u8fdb\u5c55\uff0c\u4eba\u4eec\u5f00\u59cb\u663e\u8457\u7684\u5173\u6ce8\u5bf9PSCs\u7684\u4e0d\u7a33\u5b9a\u6027\u95ee\u9898\u7684\u7814\u7a76\u3002\u4e3a\u4e86\u4f7f\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u80fd\u5546\u4e1a\u5316\uff0c\u5728\u5b9e\u9a8c\u5ba4\u4e2d\u5fc5\u987b\u9996\u5148\u514b\u670d\u7684\u4e3b\u8981\u969c\u788d\u4e4b\u4e00\u5c31\u662f\u5668\u4ef6\u7684\u4e0d\u7a33\u5b9a\u6027\u3002\u867d\u7136\u9499\u949b\u77ff\u7684\u7a33\u5b9a\u6027\u5df2\u4ece\u6700\u5f00\u59cb\u7684\u51e0\u5206\u949f\u63d0\u9ad8\u5230\u73b0\u5728\u7684\u6570\u5343\u5c0f\u65f6\uff0c\u4f46\u662f\u5bf9\u4e8e\u5b9e\u9645\u5e94\u7528\u8fd8\u662f\u4e0d\u591f\u597d\u3002\u6700\u597d\u662f\u80fd\u5c06\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u7684\u5bff\u547d\u5ef6\u957f\u5230\u5341\u5e74\u4ee5\u4e0a\uff0c\u4ee5\u66f4\u597d\u7684\u5b9e\u73b0\u5546\u4e1a\u5316\u3002\u4e3a\u4e86\u589e\u5f3a\u9499\u949b\u77ff\u7684\u7a33\u5b9a\u6027\uff0c\u5fc5\u987b\u8003\u8651\u5230\u7ed3\u6784\u8bbe\u8ba1\u3001\u7535\u8377\u4f20\u8f93\u6750\u6599\u3001\u7535\u6781\u6750\u6599\u5236\u5907\u548c\u5c01\u88c5\u65b9\u6cd5\u7b49\u56e0\u7d20\u3002\u5176\u4e2d\uff0c\u5c01\u88c5\u5728\u63d0\u9ad8\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u7684\u7a33\u5b9a\u6027\u65b9\u9762\u8d77\u7740\u81f3\u5173\u91cd\u8981\u7684\u4f5c\u7528\uff0c\u5c06\u6709\u52a9\u4e8e\u52a0\u901fPSCs\u7684\u5546\u4e1a\u5316\u3002\u82e5\u8981\u540c\u65f6\u517c\u987e\u6709\u6548\u6027\u548c\u7a33\u5b9a\u6027\uff0c\u76ee\u524d\u4ec5\u4ec5\u4fee\u6539\u662f\u9499\u949b\u77ff\u6750\u6599\u6216\u754c\u9762\u662f\u4e0d\u591f\u7684\u3002\u6700\u597d\u662f\u5728\u6076\u52a3\u6761\u4ef6\u4e0b\u5f00\u53d1\u4e00\u4e9b\u5177\u6709\u9ad8\u7a33\u5b9a\u6027\u7684\u65b0\u6750\u6599\u548c\u8bbe\u8ba1\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1aA Review of Perovskites Solar Cell Stability<\/a><\/strong>\uff08Adv. Funct. Mater., 2019<\/strong>, DOI: 10.1002\/adfm.201808843\uff09<\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u5c0f\u80d6\u7eb8\u7f16\u8bd1\uff0c\u6750\u6599\u4eba\u7f16\u8f91\u6574\u7406<\/strong>\u3002<\/p>\n

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