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Gerbrand Ceder\u8bfe\u9898\u7ec4[1]<\/sup>\u63d0\u51fa\u5c06\u9ad8\u4ef7\u4f4d\u7684\u9633\u79bb\u5b50\u548c\u6c1f\u90e8\u5206\u53d6\u4ee3\u65e0\u5e8f\u7684\u5ca9\u76d0\u7ed3\u6784\u7684\u7b56\u7565\uff0c\u5c06\u53ef\u9006\u7684Mn2+<\/sup>\/ Mn4+<\/sup>\u53cc\u6c27\u5316\u8fd8\u539f\u5bf9\u7ed3\u5408\u5230\u5bcc\u9502\u9530\u57fa\u6b63\u6781\u6750\u6599\u4e2d\u3002\u7528\u6b64\u65b9\u6cd5\u5236\u5907\u7684\u5bcc\u9502\u9530\u57fa\u6b63\u6781\u6750\u6599\u5177\u6709\u9ad8\u5bb9\u91cf\u548c\u9ad8\u80fd\u91cf\u5bc6\u5ea6\uff0c\u4e14Mn2+<\/sup>\/ Mn4+<\/sup>\u53cc\u6c27\u5316\u8fd8\u539f\u5bf9\u7684\u4f7f\u7528\u964d\u4f4e\u4e86\u6c27\u7684\u6c27\u5316\u8fd8\u539f\u6027\uff0c\u56e0\u800c\u4f7f\u6b63\u6781\u6750\u6599\u66f4\u52a0\u7a33\u5b9a\uff0c\u5e76\u4e14\u4e3a\u9502\u79bb\u5b50\u7535\u6c60\u9ad8\u6027\u80fd\u5bcc\u9530\u57fa\u6b63\u6781\u6750\u6599\u7684\u8bbe\u8ba1\u5f00\u62d3\u4e86\u65b0\u601d\u8def\u3002Prof. Dingguo\u00a0Xia\u8bfe\u9898\u7ec4[2]<\/sup>\u8fd1\u671f\u62a5\u9053\u4e86\u4ed6\u4eec\u5728\u5bcc\u9530\u57fa\u6b63\u6781\u6750\u6599\u7684\u53ef\u63a7\u5236\u5907\u548c\u9634\u79bb\u5b50\u7535\u8377\u8865\u507f\u673a\u5236\u7814\u7a76\u65b9\u9762\u7684\u6700\u8fd1\u8fdb\u5c55\uff0c\u901a\u8fc7\u6784\u7b51\u4e00\u79cdO2\u578b\u5177\u6709\u5355\u5c42Li2<\/sub>MnO3<\/sub>\u8d85\u7ed3\u6784\u7684\u5bcc\u9502\u6750\u6599\uff0c\u53ef\u63d0\u4f9b400mAh\/g\u7684\u53ef\u9006\u5bb9\u91cf\uff0c\u80fd\u91cf\u5bc6\u5ea6\u53ef\u9ad8\u8fbe1360wh\/kg\uff0c\u662f\u76ee\u524d\u9502\u79bb\u5b50\u7535\u6c60\u5bcc\u9530\u57fa\u6b63\u6781\u6750\u6599\u7684\u6700\u9ad8\u53ef\u9006\u5bb9\u91cf\u3002\u8fd9\u79cd\u6750\u6599\u901a\u8fc7\u4e00\u4e2a\u5355\u5c42\u7684Li2<\/sub>MnO3<\/sub>\u6765\u6fc0\u6d3b\u7a33\u5b9a\u7684\u9634\u79bb\u5b50\u6c27\u7684\u6c27\u5316\u8fd8\u539f\u53cd\u5e94\uff0c\u5bfc\u81f4\u4e00\u4e2a\u9ad8\u5ea6\u53ef\u9006\u7684\u5145\u653e\u7535\u5faa\u73af\u3002\u6587\u7ae0\u8fd8\u63d0\u51fa\uff0c\u7814\u7a76\u9634\u79bb\u5b50\u7535\u8377\u8865\u507f\u673a\u5236\u3001\u63a2\u7d22\u53ef\u9006\u6027\u7684\u5f71\u54cd\u56e0\u7d20\u5bf9\u4e8e\u4e0b\u4e00\u4ee3\u65b0\u578b\u9ad8\u6bd4\u5bb9\u91cf\u9502\u79bb\u5b50\u7535\u6c60\u6b63\u6781\u6750\u6599\u8bbe\u8ba1\u4e0e\u5236\u5907\u6709\u7740\u5341\u5206\u91cd\u8981\u7684\u610f\u4e49\u3002\u5176\u8bfe\u9898\u7ec4\u8fd8\u62a5\u9053\u5c06Fe3+<\/sup>\u63ba\u6742\u8fdb\u5165\u7acb\u65b9\u578bLi2<\/sub>TiO3<\/sub>\u4e2d\uff0c\u63d0\u4f9b\u4e86\u7a33\u5b9a\u7684\u9634\u79bb\u5b50\u6c27\u5316\u8fd8\u539f\u53cd\u5e94\uff0c\u7ed3\u5408\u7b2c\u4e00\u6027\u539f\u7406\u8ba1\u7b97\uff0c\u7535\u5b50\u8f6c\u79fb\u4e3b\u8981\u53d1\u751f\u5728\u88abFe3+<\/sup>\u5305\u56f4\u7684\u6c27\u9662\u5b50\u4e0a\uff0c\u800c\u4e0d\u662fTi4+<\/sup>\uff0cFe3+<\/sup>\u4f5c\u4e3a\u50ac\u5316\u5242\u5f15\u5165\u5230\u6750\u6599\u4e2d\u4fc3\u8fdb\u7a33\u5b9a\u7684\u6c27\u5316\u8fd8\u539f\u53cd\u5e94[3]<\/sup>\u3002<\/p>\n 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\u867d\u7136\u73b0\u5728\u5bf9\u591a\u5b54\u7845\u7eb3\u7c73\u9897\u7c92\u5e94\u7528\u7684\u8f83\u591a\uff0c\u5176\u5408\u6210\u5236\u5907\u5de5\u827a\u8f83\u4e3a\u590d\u6742\uff0c\u6210\u672c\u8f83\u9ad8\uff0c\u80fd\u8017\u8f83\u5927\u3002Prof. Yan Yuk\u8bfe\u9898\u7ec4[4]<\/sup>\u53d1\u73b0\u5927\u81ea\u7136\u4e2d\u7684\u82a6\u82c7\u5c31\u53ef\u4ee5\u5236\u5907\u591a\u5b54\u7845\uff08\u89c1\u56fe1\uff09\uff0c\u4ed6\u4eec\u5c06\u82a6\u82c7\u53f6\u7145\u70e7\u5e76\u4f5c\u4e3a\u7845\u6e90\u548c\u6a21\u677f\uff0c\u518d\u8fdb\u884cHcl\u8680\u523b\u3001\u8fc7\u6ee4\u5f97\u52303D\u7684\u591a\u5b54SiO2<\/sub>\uff0c\u5e76\u539f\u4f4d\u751f\u6210MgO\uff0c\u901a\u8fc7\u9541\u70ed\u8fd8\u539f\u6cd5\u5236\u5907\u5f97\u5230\u4e863D\u7684\u591a\u5b54Si-C\u8d1f\u6781\uff0c\u636e\u62a5\u9053\u572810C\u7535\u6d41\u5bc6\u5ea6\u4e0b\uff0c\u7ecf\u8fc74000\u4e2a\u5faa\u73af\uff0c\u5bb9\u91cf\u4ecd\u53ef\u8fbe420mAh\/g\uff0c\u800c\u4e14\u5236\u5907\u65b9\u6cd5\u7b80\u6613\u73af\u4fdd\u3002Prof. Jia Zhu\u8bfe\u9898\u7ec4[5]<\/sup>\u4f7f\u7528\u5de5\u4e1a\u751f\u4ea7\u4e2d\u7684\u4f4e\u7eaf\u5ea6\u7845\uff0c\u91c7\u7528\u7279\u6b8a\u7684\u7eb3\u7c73\u6210\u5b54\u5de5\u827a\uff0c\u901a\u8fc7\u7403\u78e8\u3001\u9000\u706b\u3001\u9178\u5904\u7406\uff0c\u5f97\u5230\u591a\u5b54\u7845\uff08\u5982\u56fe2\uff09\uff0c\u4e14\u800c\u8fd8\u53ef\u4ee5\u51c6\u786e\u8fde\u7eed\u7684\u8c03\u63a7\u5176\u5b54\u9699\u7387\u4ece17%\u523070%\u3002\u4f20\u7edf\u7684\u7403\u78e8\u6cd5\u5927\u591a\u662f\u901a\u8fc7\u673a\u68b0\u4f5c\u7528\u5c06\u7845\u7834\u788e\u6765\u964d\u4f4e\u9897\u7c92\u5c3a\u5bf8\uff0c\u4e14\u5c3a\u5bf8\u4e5f\u662f\u4e9a\u5fae\u7c73\uff0cProf. Xingguo Li\u7b49\u4eba[6]<\/sup>\u4e3a\u4e86\u89e3\u51b3\u7eb3\u7c73\u7845\u5236\u5907\u8fc7\u7a0b\u590d\u6742\u53ca\u4e0a\u8ff0\u95ee\u9898\uff0c\u63d0\u51fa\u4e86\u4e00\u79cd\u201c\u53cd\u5e94\u7403\u78e8-\u758f\u6c34\u5904\u7406\u201d\u7684\u65b9\u6cd5\uff0c\u5f97\u5230\u7c92\u5f84<50nm\u4e14\u5206\u5e03\u5747\u5300\u7684\u7eb3\u7c73\u7845\u9897\u7c92\uff0c\u4e14\u80fd\u591f\u5747\u5300\u7684\u5206\u6563\u5728\u4e59\u9187\u7b49\u6eb6\u5242\u4e2d\uff0c\u6709\u5229\u4e8e\u4e0e\u78b3\u590d\u5408\uff0c\u5236\u5907\u5f97\u5230\u7684\u7845\u78b3\u8d1f\u6781\u5728\u7535\u6d41\u5bc6\u5ea62.1A\/g\u4e0b\u5faa\u73af1000\u5708\u540e\u4ecd\u80fd\u4fdd\u75591750mAh\/g\u7684\u5bb9\u91cf\u3002<\/p>\n \u56fe1.\u82a6\u82c7\u53f6\u4e2d\u7684\u6c27\u5316\u7845\u7ed3\u6784<\/p>\n \u56fe2.\u7528\u5de5\u4e1a\u4f4e\u7eaf\u5ea6\u7845\u5236\u5907\u591a\u5b54\u7845\u7684\u793a\u610f\u56fe<\/p>\n \u4e3a\u4e86\u7f13\u51b2Si\u8d1f\u6781\u6750\u6599\u7684\u4f53\u79ef\u81a8\u80c0\uff0cSi\u6750\u6599\u4e0e\u77f3\u58a8\u6750\u6599\u7684\u590d\u5408\u6210\u4e3a\u4e86\u6700\u4f73\u7684\u9009\u62e9\u3002Si-C\u590d\u5408\u6280\u672f\uff0c\u8fd9\u4e5f\u662f\u76ee\u524d\u5e02\u573a\u4e0a\u4e3b\u6d41\u7684Si\u8d1f\u6781\u6750\u6599\u6280\u672f\u3002\u4f46\u662f\u5e02\u9762\u4e0a\u901a\u5e38\u662f\u5c06\u7845\u548c\u78b3\u7c89\u8fdb\u884c\u7b80\u5355\u7684\u7269\u7406\u6df7\u5408\uff0c\u5176\u5bf9\u7845\u81a8\u80c0\u5f62\u53d8\u7684\u5438\u6536\u8fd8\u662f\u4e0d\u5c3d\u4eba\u610f\u3002\u4e3a\u4e86\u5b9e\u73b0\u5927\u6279\u91cf\u751f\u4ea7\uff0cProf. Yi Cui\u7b49\u4eba[7]<\/sup>\u91c7\u7528\u5316\u5b66\u6c14\u76f8\u6c89\u79ef\u6cd5\uff08CVD\uff09\uff0c\u5c06\u5929\u7136\u77f3\u58a8\u653e\u5728900\u2103\u7684\u7089\u4e2d\uff0c\u901a\u4ee5\u7845\u70f7\u548c\u4e59\u7094\uff0c\u5236\u5907\u5f97\u5230Si-C\u590d\u5408\u6750\u6599\u3002\u7eb3\u7c73Si\u4e00\u90e8\u5206\u6c89\u79ef\u5728\u77f3\u58a8\u8868\u9762\uff0c\u4e00\u90e8\u5206\u5d4c\u5165\u77f3\u58a8\u5b54\u9699\u95f4\uff0c\u964d\u4f4e\u4e86Si\u4f53\u79ef\u81a8\u80c0\uff0c\u63d0\u9ad8\u7535\u6c60\u5bb9\u91cf\u548c\u5faa\u73af\u7a33\u5b9a\u6027\uff0c\u5e76\u6709\u671b\u5b9e\u73b0\u91cf\u4ea7\u5316\u3002\u8fd8\u53ef\u4ee5\u901a\u8fc7\u5c06\u7845\u8fdb\u884c\u78b3\u5305\u8986\uff0c\u00a0Prof. Jianping\u00a0Yang\u7b49\u4eba[8]<\/sup>\u9996\u5148\u5236\u5907\u4e86Si@C\u6838\u58f3\u7ed3\u6784\uff0c\u5305\u8986\u5728\u7845\u6838\u5916\u9762\u7684\u78b3\u4e0d\u4ec5\u53ef\u4ee5\u963b\u6b62\u7845\u76f4\u63a5\u63a5\u89e6\u7535\u89e3\u6db2\u53d1\u751f\u526f\u53cd\u5e94\u5f62\u6210\u4e0d\u7a33\u5b9a\u7684SEI\u819c\uff0c\u8fd8\u53ef\u4ee5\u63d0\u9ad8\u7535\u6781\u7684\u5bfc\u7535\u6027\uff0c\u66f4\u91cd\u8981\u7684\u662f\u80fd\u591f\u7f13\u51b2\u5145\u653e\u7535\u8fc7\u7a0b\u4e2d\u7845\u4f53\u79ef\u81a8\u80c0\u5e26\u6765\u7684\u7ed3\u6784\u5e94\u53d8\uff0c\u7136\u540e\u5728\u6b64\u57fa\u7840\u4e0a\u5f15\u5165\u5c11\u91cf\u7684Ge\u7eb3\u7c73\u6676\u7c92\uff08\u89c1\u56fe3\uff09\u5bf9Si@C\u8fdb\u884c\u8868\u9762\u4fee\u9970\u5f97\u5230Si@C@GeO2<\/sub>,Ge\u7eb3\u7c73\u6676\u7c92\u8d77\u5230\u8ff7\u4f60\u96c6\u6d41\u4f53\u7684\u4f5c\u7528\uff0c\u63d0\u9ad8\u9502\u79bb\u5b50\u6269\u6563\u901f\u7387\uff0c\u4ece\u800c\u83b7\u5f97\u9ad8\u5bb9\u91cf\u7684\u9502\u7535\u6c60\uff0c\u5728150\u4e2a\u5faa\u73af\u540e\u8fd8\u53ef\u4ee5\u4fdd\u63011854mAh\/g\u7684\u5bb9\u91cf\u3002Prof. Xianmao Lu[9]<\/sup>\u7b49\u4eba\u8fd8\u5236\u5907\u4e86Si@Cu\u590d\u5408\u8d1f\u6781\uff0c\u5148\u662f\u5c06\u94dc\u57fa\u5e95\u6d78\u5728NaOH\u548c(NH4<\/sub>)2<\/sub>S2<\/sub>O8<\/sub>\u4e2d\u8fdb\u884c\u523b\u8680\u5f97\u5230Cu(OH)2<\/sub>\u7684\u7eb3\u7c73\u7ebf\u9635\u5217\uff0c\u5728\u7eb3\u7c73\u7ebf\u8868\u9762\u78c1\u63a7\u6e85\u5c04Si\uff0c\u518d\u8fdb\u884c\u6c22\u6c14\u8fd8\u539f\u5f97\u5230Si@Cu\u7684\u7eb3\u7c73\u7ebf\uff0c\u8fd8\u53ef\u4ee5\u591a\u6b21\u6e85\u5c04\u5f97\u5230\u591a\u5c42\u7684Si@Cu\u7eb3\u7c73\u7ebf\u590d\u5408\u7ed3\u6784\uff0c\u5c06Si@Cu\u8d1f\u6781\u505a\u6210\u7535\u6c60\u5faa\u73af1500\u5468\u540e\u8fd8\u53ef\u4ee5\u7ef4\u630187%\u7684\u521d\u59cb\u5bb9\u91cf\u3002<\/p>\n \u56fe3. Si@C@GeO2<\/sub>\u7684\u5236\u5907\u8fc7\u7a0b<\/p>\n 2\u3001\u949b\u9178\u9502<\/p>\n \u968f\u7740\u5feb\u901f\u5145\u653e\u7535\u3001\u9ad8\u500d\u7387\u653e\u7535\u3001\u9ad8\u5b89\u5168\u6027\u9700\u6c42\u7684\u589e\u5927\uff0c\u949b\u9178\u9502\uff08Li2<\/sub>O-TiO2<\/sub>\uff09\u8fd1\u51e0\u5e74\u4e5f\u662f\u7814\u7a76\u7684\u70ed\u70b9\u3002\u94f6\u9686\u949b\u9178\u9502\u7535\u6c60\u7684\u5145\u653e\u7535\u500d\u7387\u80fd\u8fbe\u523010-20C\uff0c\u800c\u666e\u901a\u7684\u77f3\u58a8\u8d1f\u6781\u7535\u6c60\u5145\u653e\u7535\u500d\u7387\u4ec5\u67092-4C\uff0c\u4e3b\u8981\u7528\u5728\u65b0\u80fd\u6e90\u516c\u4ea4\u8f66\u548c\u5927\u578b\u8f66\u80fd\u88c5\u5907\u4e0a\u3002<\/p>\n 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Li\u8bfe\u9898\u7ec4[10]<\/sup>\u5374\u9a8c\u8bc1\u4e86\u6839\u672c\u4e0d\u9700\u8981\u9ad8\u6e29\u7145\u70e7\uff0c\u53ea\u9700\u8981\u5728\u4e00\u4e2a\u8f83\u4f4e\u7684\u6e29\u5ea6\u4e0b<260\u2103\u4e0b\u52a0\u70ed\u9664\u53bb\u7ed3\u5408\u6c34\u5373\u53ef\uff0c\u800c\u8fd9\u4e2a\u8fc7\u7a0b\u4e0d\u4f1a\u5f15\u8d77\u7eb3\u7c73\u949b\u9178\u9502\u7684\u7c97\u5316\u6216\u8005\u56e2\u805a\u73b0\u8c61\u3002\u800cLi2<\/sub>O-TiO2<\/sub>\u4e2d\u7684\u6df1\u5ea6\u7ed3\u5408\u7684\u6c34\u4e0d\u9700\u8981\u9664\u53bb\uff0c\u751a\u81f3\u8fd9\u90e8\u5206\u6c34\u8fd8\u6709\u5229\u4e8e\u7535\u6c60\u6027\u80fd\u7684\u53d1\u6325\u3002\u5e76\u4e14\u4ed6\u4eec\u5f00\u53d1\u4e86\u4e00\u7cfb\u5217\u7684\u949b\u9178\u9502\u6c34\u5408\u7269Li2<\/sub>O-TiO2<\/sub>-H2<\/sub>O\uff0c\u7528\u4f5c\u9502\u79bb\u5b50\u7535\u6c60\u8d1f\u6781\u540e\uff0c\u572835C\u653e\u7535\u540e\u5bb9\u91cf\u8fd8\u80fd\u8fbe\u5230130mAh\/g\uff0c\u5b9e\u73b0\u9ad8\u500d\u7387\u6027\u80fd\u4e14\u8d85\u957f\u5faa\u73af\u5bff\u547d\u7684\u9502\u79bb\u5b50\u7535\u6c60\u3002<\/p>\n \u56fe4 .Li2<\/sub>O-TiO2<\/sub>\u8131\u6c34\u5e72\u71e5\u8fc7\u7a0b\u4e2d\u9897\u7c92\u7c97\u5316\u56e2\u805a<\/p>\n 3\u3001\u77f3\u58a8\u70ef<\/p>\n 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Xianjun Zhu\u7b49\u4eba[11]<\/sup>\u91c7\u7528\u4e24\u6b65\u5408\u6210\u6cd5\u5236\u5907\u4e86\u8fd8\u539f\u6c27\u5316\u77f3\u58a8\u70ef(RG-O)\/Fe2<\/sub>O3<\/sub>\u590d\u5408\u7535\u6781\uff0c\u5148\u5747\u76f8\u6c89\u79ef\uff0c\u7136\u540e\u5728\u5c06\u6c27\u5316\u77f3\u58a8\u70ef\u5728\u5fae\u6ce2\u7167\u5c04\u4e0b\u7528\u80bc\u8fd8\u539f\uff0c\u5f97\u5230Fe2<\/sub>O3<\/sub>\u4fee\u9970\u7684\u77f3\u58a8\u70ef\u7247\uff0cFe2<\/sub>O3<\/sub>\u7eb3\u7c73\u9897\u7c92\u5747\u5300\u5730\u5206\u6563\u5728\u77f3\u58a8\u70ef\u7247\u5c42\u7684\u8868\u9762\uff08\u56fe5\uff09\u3002\u653e\u7535\u5bb9\u91cf\u548c\u5145\u7535\u5bb9\u91cf\u5206\u522b\u80fd\u8fbe\u52301693\u548c1227mAh\/g\u3002<\/p>\n 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Cheng\u7b49\u4eba[12]<\/sup>\u901a\u8fc7N-\u63ba\u6742\u548cB-\u63ba\u6742\u77f3\u58a8\u70ef\u4f5c\u9502\u7535\u6c60\u8d1f\u6781\uff0c\u80fd\u591f\u57281h\u5185\u751a\u81f3\u51e0\u5341\u79d2\u5185\u5b8c\u6210\u5feb\u901f\u5145\u653e\u7535\uff0c\u540c\u65f6\u83b7\u5f97\u9ad8\u5bb9\u91cf\u5bc6\u5ea6\u548c\u4f18\u826f\u7684\u5faa\u73af\u5bff\u547d\u3002\u8fd1\u51e0\u5e74\u7814\u7a76\u8005\u4eec\u8fd8\u63d0\u51fa\u591a\u5b54\u77f3\u58a8\u70ef\uff0c\u8ba4\u4e3a\u591a\u5b54\u77f3\u58a8\u70ef\u53ef\u4ee5\u63d0\u9ad8\u7535\u6c60\u7684\u80fd\u91cf\u5bc6\u5ea6\u548c\u5bb9\u91cf\u5bc6\u5ea6\uff0c\u77f3\u58a8\u70ef\u7247\u5c42\u4e0a\u7684\u5b54\u6709\u5229\u4e8e\u4f7f\u591a\u5b54\u77f3\u58a8\u70ef\u7247\u5c42\u4fdd\u6301\u4e00\u4e2a\u63d2\u5c42\u7684\u72b6\u6001\uff0c\u4ece\u800c\u6709\u5229\u4e8e\u7535\u89e3\u6db2\u80fd\u591f\u66f4\u5feb\u7684\u4ece\u5b54\u4e2d\u6e17\u900f\u5230\u6574\u4e2a\u77f3\u58a8\u70ef\u7535\u6781\uff0c\u63d0\u9ad8\u79bb\u5b50\u6269\u6563\u901f\u7387\u3002Liming Dai\u7b49\u4eba[13]<\/sup>\u63d0\u51fa\u4e86N-\u63ba\u6742\u7684\u591a\u5b54\u77f3\u58a8\u70ef\u7528\u4f5c\u9502\u79bb\u5b50\u7535\u6c60\u7684\u8d1f\u6781\uff0c\u53ef\u4ee5\u8fdb\u4e00\u6b65\u63d0\u9ad8\u9694\u819c\u7684\u8868\u9762\u6da6\u6e7f\u6027\u3001\u77f3\u58a8\u70ef\u7684\u5bfc\u7535\u6027\u548c\u7535\u6c60\u5bb9\u91cf\uff0c\u5176\u5236\u5907\u7684\u4e00\u7cfb\u5217N-\u63ba\u6742\u7684\u591a\u5b54\u77f3\u58a8\u70ef\u4f5c\u8d1f\u6781\u7684\u9502\u7535\u6c60\uff0c\u53ef\u4ee5\u57280.1A\/g\u7684\u7535\u6d41\u5bc6\u5ea6\u4e0b6000\u4e2a\u5faa\u73af\u540e\u5bb9\u91cf\u4f9d\u7136\u80fd\u8fbe\u5230384 mAh\/cm3<\/sup>.<\/p>\n \u56fe5. RG-O\/Fe2<\/sub>O3<\/sub>\u590d\u5408\u673a\u7406\u56fe<\/p>\n \u4e09\u3001\u9694\u819c<\/strong><\/p>\n \u52a8\u529b\u7535\u6c60\u9ad8\u80fd\u91cf\u5bc6\u5ea6\u3001\u9ad8\u5b89\u5168\u6027\u3001\u4f4e\u6210\u672c\u7684\u53d1\u5c55\u65b9\u5411\u5bf9\u9694\u819c\u7684\u5b89\u5168\u6027\u548c\u7535\u6c60\u6027\u80fd\u63d0\u51fa\u4e86\u66f4\u9ad8\u7684\u8981\u6c42\u3002\u4f20\u7edf\u7684\u805a\u70ef\u70c3PE\u548cPP\u9694\u819c\u7531\u4e8e\u8010\u9ad8\u6e29\u6027\u6bd4\u8f83\u5dee\u800c\u5df2\u7ecf\u65e0\u6cd5\u6ee1\u8db3\u52a8\u529b\u7535\u6c60\u9ad8\u5b89\u5168\u6027\uff0c\u4e14\u5176\u5bf9\u7535\u89e3\u6db2\u8f83\u5dee\u7684\u6d78\u6da6\u6027\u5bf9\u5176\u7535\u6c60\u6027\u80fd\u9020\u6210\u4e0d\u826f\u5f71\u54cd\u3002\u7efc\u5408\u8fd9\u4e24\u65b9\u9762\uff0c\u6539\u5584\u9694\u819c\u7684\u6280\u672f\u9014\u5f84\u76ee\u524d\u4e3b\u8981\u6709\uff1a\u9676\u74f7\u6d82\u8986\uff0c\u9ad8\u805a\u7269\u6d82\u8986\uff0c\u65e0\u7eba\u5e03\uff0c\u53ca\u65b0\u578b\u6750\u6599\u819c\u3002\u65b0\u578b\u6750\u6599\u819c\u7684\u5b89\u5168\u4f7f\u7528\u6e29\u5ea6\u901a\u5e38\u90fd\u6bd4\u8f83\u9ad8\uff0c\u4e5f\u662f\u5f53\u4e0b\u79d1\u5b66\u5bb6\u4eec\u7814\u7a76\u7684\u70ed\u70b9\u3002<\/p>\n \u805a\u9170\u4e9a\u80fa\uff08PI\uff09<\/strong>\u662f\u4e00\u79cd\u7efc\u5408\u6027\u80fd\u826f\u597d\u7684\u9ad8\u805a\u7269\uff0c\u5177\u6709\u4f18\u5f02\u7684\u70ed\u7a33\u5b9a\u6027\u3001\u9ad8\u5b54\u9699\u7387\u548c\u8010\u9ad8\u6e29\u6027\uff0c\u80fd\u591f\u5728-200\uff5e300\u2103\u4e0b\u957f\u671f\u4f7f\u7528\u3002Xingxing Liang[14]<\/sup>\u7b49\u5c06PAA\u6eb6\u6db2\u9759\u7535\u7eba\u4e1d\u5236\u5907PAA\u7eb3\u7c73\u7ea4\u7ef4\u819c\uff0c\u7136\u540e\u5c06PAA\u7eb3\u7c73\u7ea4\u7ef4\u819c\u70ed\u4e9a\u80fa\u5316\u5236\u5907\u5f97\u5230PI\u591a\u5b54\u819c\uff0c\u518d\u5c06PI\u591a\u5b54\u819c\u6d78\u6ce1\u5728PEO\u7684\u6eb6\u6db2\u4e2d\uff0c\u5e72\u71e5\u540e\u5f97\u5230PI\/PEO\u7684\u590d\u5408\u9694\u819c\u3002Liyun\u00a0Cao[<\/sup>15<\/sup>]<\/sup>\u7b49\u4eba\u901a\u8fc7\u9759\u7535\u7eba\u4e1d\u7684\u65b9\u6cd5\u5236\u5907\u5f97\u5230\u7684PI\u7eb3\u7c73\u7ea4\u7ef4\u57fa\u65e0\u7eba\u5e03\u80fd\u591f\u5728500\u2103\u9ad8\u6e29\u4e0b\u7a33\u5b9a\u4f7f\u7528\uff0c\u5b54\u9699\u7387\u8fbe\u523090%\uff0c\u5bf9\u6781\u6027\u7535\u89e3\u6db2\u7684\u5438\u6db2\u7387\u9ad8\uff0c\u963b\u6297\u4f4e\uff0c\u500d\u7387\u6027\u80fd\u597d\uff0c5C\u5145\u653e\u7535320\u5708\u540e\u5bb9\u91cf\u4fdd\u6301\u7387\u4e3a99.66%\u3002<\/p>\n \u9759\u7535\u7eba\u4e1d\u6cd5<\/strong>\u5236\u5907\u9502\u7535\u6c60\u9694\u819c\u6548\u7387\u6bd4\u8f83\u4f4e\uff0c\u5236\u5907\u5f97\u5230\u7684\u9502\u7535\u6c60\u9694\u819c\u901a\u5e38\u5b54\u5f84\u4f1a\u8f83\u5927\u800c\u5bfc\u81f4\u81ea\u653e\u7535\uff0c\u5f71\u54cd\u7535\u6c60\u7684\u5b89\u5168\u6027\u80fd\u548c\u7535\u5316\u5b66\u6027\u80fd\u3002Prof. Baoku Zhu\u56e2\u961f[16]<\/sup>\u63d0\u51fa\u4e86\u7528\u975e\u6eb6\u5242\u81f4\u76f8\u8f6c\u6362\u7684\u65b9\u6cd5\u6765\u5236\u5907\u9502\u7535\u6c60\u9694\u819c\uff0c\u5e76\u7528\u6b64\u65b9\u6cd5\u5236\u5907\u4e86\u805a\u95f4\u82ef\u4e8c\u7532\u9170\u95f4\u82ef\u4e8c\u80fa\uff08\u82b3\u7eb61313\uff0cPMIA\uff09\u7684\u591a\u5b54\u9694\u819c\uff0c\u5177\u6709\u5f88\u597d\u7684\u70ed\u7a33\u5b9a\u6027\uff0c\u5728160\u2103\u4e0b1h\u7684\u70ed\u6536\u7f29\u4e3a0\uff1b\u4e14\u6b64\u591a\u5b54\u819c\u7684\u5b54\u4e3a\u6d77\u7ef5\u72b6\uff0c\u5b54\u5185\u90e8\u4e92\u76f8\u8fde\u901a\uff0c\u63d0\u9ad8\u4e86\u9694\u819c\u7684\u79bb\u5b50\u7535\u5bfc\u7387\uff1b\u805a\u95f4\u82ef\u4e8c\u7532\u9170\u95f4\u82ef\u4e8c\u80fa\u7531\u4e8e\u81ea\u8eab\u5177\u6709\u5f3a\u6781\u6027\u5b98\u80fd\u56e2\uff0c\u5bf9\u7535\u89e3\u6db2\u7684\u6d78\u6da6\u6027\u5927\u5927\u63d0\u9ad8\uff0c\u6709\u5229\u4e8e\u6539\u5584\u7535\u6c60\u7684\u5faa\u73af\u6027\u80fd\u3002<\/p>\n Prof. Sang-Young Lee\u7b49\u4eba[17]<\/sup>\u5de7\u5999\u7684\u5c06Janus\u7ed3\u6784\u5e94\u7528\u5728\u9502\u79bb\u5b50\u7535\u6c60\u9694\u819c\u4e2d\u3002Janus\u819c\u6700\u65e9\u7814\u7a76\u7684\u662f\u5176\u5b9a\u5411\u6e17\u900f\u7684\u6027\u80fd\uff0c\u591a\u7528\u5728\u6cb9\u6c34\u5206\u79bb\u7b49\u9886\u57df\uff0c\u5176\u56e2\u961f\u91c7\u7528\u540c\u6b65\u7535\u7eba\/\u7535\u55b7\u6280\u672f\u5236\u5907\u4e86\u5177\u6709Janus\u7ed3\u6784\u7684\u590d\u5408\u9502\u7535\u6c60\u9694\u819c\uff0c\u4e00\u5c42\u662f\u91c7\u7528\u540c\u6b65\u9759\u7535\u7eba\u4e1d\u5236\u5907\u805a\u4e59\u70ef\u57fa\u5421\u54af\u70f7\u916e\/\u805a\u4e19\u70ef\u8148\u7684\u590d\u5408\u7eb3\u7c73\u7ea4\u7ef4\uff0c\u5e76\u5728\u4e0a\u9762\u7535\u55b7\u4e0a\u5def\u57fa\u6539\u6027\u7684SiO2<\/sub>\u9897\u7c92\uff1b\u4e00\u5c42\u662f\u9759\u7535\u7eba\u4e1d\u5236\u5907\u7684\u805a\u919a\u9170\u4e9a\u80fa\u7ea4\u7ef4\uff0c\u5e76\u5728\u4e0a\u9762\u7535\u55b7\u78b3\u7eb3\u7c73\u7ba1\uff0c\u6700\u540e\u7528\u70ed\u8f8a\u538b\u7684\u6280\u672f\u5c06\u4e24\u5c42\u7c98\u5408\u5728\u4e00\u8d77\u5236\u5907\u5f97\u5230\u590d\u5408\u9694\u819c\u3002\u5def\u57fa\u6539\u6027\u7684SiO2<\/sub>\u9897\u7c92\u53ef\u4ee5\u6355\u83b7\u5145\u653e\u7535\u8fc7\u7a0b\u4e2d\u6eb6\u89e3\u7684\u91cd\u91d1\u5c5e\u79bb\u5b50\uff08\u5982Mn2+<\/sup>\uff0cNi2+<\/sup>\uff0cCo2+<\/sup>\uff09\uff0c\u4ece\u800c\u6291\u5236\u9502\u7535\u6c60\u5728\u591a\u6b21\u5145\u653e\u7535\u5faa\u73af\u540e\u7535\u6c60\u5bb9\u91cf\u4e0b\u964d\u7684\u73b0\u8c61\uff1b\u53e6\u4e00\u65b9\u9762\uff0c\u805a\u919a\u9170\u4e9a\u80fa\/\u78b3\u7eb3\u7c73\u7ba1\u6709\u5bfc\u7535\u6027\uff0c\u6709\u5229\u4e8e\u7535\u6781\u7684\u7535\u5b50\u4f20\u5bfc\uff08\u56fe6\uff09\u3002<\/p>\n \u56fe6 .PE\u9694\u819c\u548cJanus\u9694\u819c\u5728\u9502\u79bb\u5b50\u7535\u6c60\u4e2d\u4f5c\u7528\u793a\u610f\u56fe<\/p>\n \u8fd1\u671f\uff0cYingjie Zhu \u548cProf. Xianluo Hu\u7b49\u4eba[18]<\/sup>\u5236\u5907\u4e86\u4e00\u79cd\u7528\u7f9f\u57fa\u78f7\u7070\u77f3\u8d85\u957f\u7eb3\u7c73\u7ebf\u505a\u7684\u8010\u9ad8\u6e29\u9502\u7535\u6c60\u9694\u819c\uff0c\u80fd\u591f\u5728700\u2103\u7684\u9ad8\u6e29\u4e0b\u4f9d\u7136\u4fdd\u6301\u5176\u5b8c\u6574\u7684\u7ed3\u6784\u4e0d\u53d1\u751f\u7834\u635f\u3002\u8be5\u7535\u6c60\u9694\u819c\u8fd8\u6709\u5f88\u597d\u7684\u67d4\u97e7\u6027\u3001\u529b\u5b66\u5f3a\u5ea6\u3001\u9ad8\u5b54\u9699\u7387\uff0c\u826f\u597d\u7684\u7535\u89e3\u6db2\u6d78\u6da6\u6027\u548c\u963b\u71c3\u6027\u80fd\u3002\u7ec4\u88c5\u7684\u9502\u7535\u6c60\u5728150\u2103\u9ad8\u6e29\u73af\u5883\u4e2d\u4ecd\u80fd\u591f\u6b63\u5e38\u5de5\u4f5c\uff0c\u800c\u7528PP\u9694\u819c\u7ec4\u88c5\u7684\u9502\u7535\u6c60\u5728150\u2103\u4e0b\u53d1\u751f\u77ed\u8def\uff0c\u5927\u5e45\u5ea6\u63d0\u9ad8\u9502\u79bb\u5b50\u7535\u6c60\u7684\u5de5\u4f5c\u6e29\u5ea6\u8303\u56f4\u548c\u5b89\u5168\u6027\u3002<\/p>\n \u56db\u3001\u7c98\u7ed3\u5242<\/strong><\/p>\n \u968f\u7740\u7845\u6750\u6599\u5728\u9502\u79bb\u5b50\u7535\u6c60\u8d1f\u6781\u6750\u6599\u4e2d\u7684\u5e94\u7528\uff0c\u5176\u7c98\u7ed3\u5242\u7684\u4f7f\u7528\u7814\u7a76\u968f\u4e4b\u800c\u8d77\u3002\u4f46\u662f\u7845\u5728\u53cd\u5e94\u4e2d\u5b58\u5728\u4f53\u79ef\u81a8\u80c0\u7684\u95ee\u9898\uff0c\u5bfc\u81f4\u9897\u7c92\u5206\u5316\u3001\u7535\u6c60\u5faa\u73af\u6027\u80fd\u5dee\uff0c\u6d3b\u6027\u7269\u8d28\u4e0e\u5bfc\u7535\u5242\u7c98\u7ed3\u5242\u63a5\u89e6\u5dee\u7b49\u73b0\u8c61\u3002<\/p>\n \u6700\u8fd1\u6709\u7814\u7a76\u53d1\u73b0\u7c98\u7ed3\u5242\u5728\u7535\u6781\u6750\u6599\u4e2d\u80fd\u591f\u5927\u5e45\u5ea6\u63d0\u9ad8\u7535\u6781\u7684\u5faa\u73af\u5bff\u547d\uff0c\u4f46\u662f\u4f20\u7edf\u7684PVDF\u7c98\u7ed3\u5242\u4e0e\u8d1f\u6781\u96c6\u6d41\u4f53\u94dc\u7b94\u4ec5\u9760\u5fae\u5f31\u7684\u8303\u5fb7\u534e\u529b\u800c\u4e0d\u9002\u7528\u4e8e\u7845\u8d1f\u6781\u6750\u6599\u3002<\/p>\n PAA\uff0cSBR\u7b49\u5e38\u89c4\u9502\u7535\u6c60\u7c98\u7ed3\u5242\u96be\u4ee5\u9002\u5e94\u7845\u9897\u7c92\u81a8\u80c0\u4ea7\u751f\u7684\u5e94\u529b\u3002Ali Coskun\u548cJang Wook Choi\u7684\u56e2\u961f[19]<\/sup>\u4e00\u5f00\u59cb\u901a\u8fc7\u5229\u7528\u03b2-\u73af\u7cca\u7cbe\u548c6AD\u7684\u5206\u5b50\u95f4\u76f8\u4e92\u4f5c\u7528\u6765\u89e3\u51b3\u7845\u8d1f\u6781\u5d4c\u9502\u8131\u9502\u8fc7\u7a0b\u4e2d\u4f53\u79ef\u81a8\u80c0\u6536\u7f29\u7684\u95ee\u9898\u3002\u4e4b\u540e\u4ed6\u4eec\u8bfe\u9898\u7ec4\u53c8\u5de7\u5999\u7684\u8bbe\u8ba1\u4e86\u201c\u5206\u5b50\u6ed1\u8f6e\u7ec4\u201d\uff0c\u7528\u94fe\u72b6\u5206\u5b50PEG\u5c06\u03b1-\u73af\u7cca\u7cbe\u4e32\u8d77\u6765\u5f62\u6210\u805a\u8f6e\u70f7PR\uff0c\u6700\u540e\u901a\u8fc7\u916f\u952e\u5c06PAA\u548cPR\u4ea4\u8054\uff0c\u7ec4\u6210PR-PAA\u7684\u5206\u5b50\u6ed1\u8f6e\u7ec4\u7ed3\u6784[20]<\/sup>\u3002\u03b1-\u73af\u7cca\u7cbe\u4e0e\u4e00\u6761PAA\u94fe\u7ed3\u5408\u7c7b\u4f3c\u201c\u5b9a\u6ed1\u8f6e\u201d\uff0c\u4e0e\u53e6\u4e00\u6761\u7ed3\u5408\u7c7b\u4f3c\u201c\u52a8\u6ed1\u8f6e\u201d\uff0c\u4ece\u800c\u5747\u5300\u5206\u6563\u7845\u8d1f\u6781\u5728\u5145\u653e\u7535\u5faa\u73af\u4f53\u4e2d\u4f53\u79ef\u53d8\u5316\u65f6\u7c98\u5408\u5242\u6240\u53d7\u7684\u529b\uff0c\u63d0\u9ad8\u6750\u6599\u6574\u4f53\u7684\u7a33\u5b9a\u6027\uff08\u56fe7\uff09\u3002<\/p>\n \u56fe7\u00a0 . PR-PAA\u7c98\u5408\u5242\u5728\u7845\u7535\u6781\u4e2d\u7684\u4f5c\u7528\u673a\u7406<\/p>\n \u4e94\u3001\u7535\u89e3\u6db2<\/strong><\/p>\n \u9502\u79bb\u5b50\u7535\u6c60\u7684\u53d1\u5c55\u9762\u4e34\u7740\u5b89\u5168\u6027\u548c\u9ad8\u80fd\u91cf\u5bc6\u5ea6\u7684\u4e24\u5927\u6311\u6218\uff0c\u63d0\u9ad8\u80fd\u91cf\u5bc6\u5ea6\u7684\u65b9\u5f0f\u6709\u4e24\u79cd\uff0c\u4e00\u79cd\u662f\u63d0\u9ad8\u5b83\u7684\u5145\u7535\u622a\u6b62\u7535\u538b\uff0c\u53e6\u4e00\u79cd\u662f\u91c7\u7528\u65b0\u578b\u7684\u9ad8\u6bd4\u5bb9\u91cf\u7684\u6b63\u8d1f\u6781\u6750\u6599\uff0c\u800c\u968f\u7740\u6b63\u8d1f\u6781\u6750\u6599\u7684\u53d1\u5c55\uff0c\u7535\u89e3\u6db2\u5df2\u7ecf\u662f\u9650\u5236\u9502\u79bb\u5b50\u7535\u6c60\u5f80\u9ad8\u80fd\u91cf\u5bc6\u5ea6\u548c\u9ad8\u5b89\u5168\u53d1\u5c55\u7684\u74f6\u9888\uff0c\u76ee\u524d\u7535\u89e3\u6db2\u7684\u9ad8\u7535\u538b\u7a33\u5b9a\u6027\u5dee\uff0c\u4f20\u7edf\u7684\u78b3\u9178\u916f\u7c7b\u7535\u89e3\u6db2\u5728\u8d85\u8fc74.5V\u4ee5\u540e\u5c31\u4f1a\u53d1\u751f\u660e\u663e\u7684\u6c27\u5316\u5206\u89e3\u73b0\u8c61\u3002\u4ece\u7ecf\u6d4e\u6548\u76ca\u8003\u8651\uff0c\u53d1\u5c55\u5408\u9002\u7684\u7535\u89e3\u6db2\u6dfb\u52a0\u5242\u6765\u7a33\u5b9a\u7535\u6781\/\u7535\u89e3\u6db2\u754c\u9762\u53d7\u5230\u7814\u7a76\u8005\u4eec\u7684\u9752\u7750\u3002\u76ee\u524d\u7814\u7a76\u7684\u9ad8\u7535\u538b\u7535\u89e3\u6db2\u6dfb\u52a0\u5242\u6709\uff1a\u542b\u787c\u7c7b\u6dfb\u52a0\u5242\u3001\u6709\u673a\u78f7\u7c7b\u6dfb\u52a0\u5242\u3001\u78b3\u9178\u916f\u7c7b\u6dfb\u52a0\u5242\u3001\u79bb\u5b50\u6db2\u4f53\u6dfb\u52a0\u5242\u7b49\u7c7b\u578b\u6dfb\u52a0\u5242\u3002Xiaoguang Sun\u7b49\u4eba[21]<\/sup>\u4ee5NCA\u6750\u6599\u4e3a\u6b63\u6781\uff0c\u5728\u4f20\u7edf\u7684LiPF6\u7535\u89e3\u6db2\u4e2d\u6dfb\u52a05%\u7684\u4e09\u7532\u57fa\u7845\u57fa\u4e19\u4e8c\u9178\u8102\u7c7b\u6dfb\u52a0\u5242\u80fd\u63d0\u9ad8NCA\u6750\u6599\u57284.2V,4.3V,4..4V\u548c4.5V\u4e0b\u7684\u5faa\u73af\u7a33\u5b9a\u6027\uff0c\u5728LiPF6\u7535\u89e3\u6db2\u6dfb\u52a0\u53cc\uff08\u4e09\u7532\u57fa\u7845\u57fa\uff092-\u7532\u57fa-2-\u6c1f\u4e19\u4e8c\u9178\u76d0\uff08BTMSMFM\uff09\u3001\u53cc\uff08\u4e09\u7532\u57fa\u7845\u57fa\uff092-\u4e59\u57fa-2-\u6c1f\u4e19\u4e8c\u9178\u76d0\uff08BTMSEFM\uff09\u3001\u53cc\uff08\u4e09\u7532\u57fa\u7845\u57fa\uff092-\u4e19\u57fa-2-\u6c1f\u4e19\u4e8c\u9178\u76d0\uff08BTMSPFM\uff09\u6dfb\u52a0\u5242\uff0c\u80fd\u591f\u6709\u6548\u7684\u6291\u5236\u7535\u89e3\u6db2\u5728NCA\u6750\u6599\u8868\u9762\u7684\u5206\u89e3\uff0c\u5e76\u51cf\u5c11NCA\u9897\u7c92\u7684\u7c89\u5316\u548c\u7834\u788e\uff0c\u4ece\u800c\u6709\u6548\u7684\u63d0\u5347\u7535\u6c60\u7684\u5faa\u73af\u7a33\u5b9a\u6027\uff0c\u4f5c\u8005\u8ba4\u4e3a\u6dfb\u52a0\u5242\u63d0\u5347NCA\u5faa\u73af\u6027\u80fd\u7684\u5173\u952e\u5728\u4e8e\u6dfb\u52a0\u5242\u5728NCA\u6750\u6599\u8868\u9762\u5206\u89e3\u5f62\u6210\u4e86\u4e00\u5c42\u4fdd\u62a4\u5c42\uff0c\u4ece\u800c\u6709\u6548\u6291\u5236HF\u5bf9\u6b63\u6781\u8868\u9762\u7684\u4fb5\u8680\u3002\u5b9e\u9a8c\u6570\u636e\u8868\u660e\uff0cBTMSMFM\u6dfb\u52a0\u5242\u80fd\u591f\u663e\u8457\u6539\u5584NCA\u5728\u9ad8\u7535\u538b\u4e0b\u7684\u5faa\u73af\u7a33\u5b9a\u6027\uff0c\u6291\u5236SEI\u819c\u7684\u751f\u957f\uff0c\u51cf\u5c11NCA\u9897\u7c92\u7684\u7c89\u5316\u548c\u7834\u574f\uff0c\u662f\u4e00\u79cd\u7406\u60f3\u7684\u9ad8\u7535\u538b\u7535\u89e3\u6db2\u6dfb\u52a0\u5242\u3002<\/p>\n \u4e3a\u4e86\u6539\u5584\u7535\u89e3\u6db2\u7684\u9ad8\u7535\u538b\u7a33\u5b9a\u6027\uff0cNiloofar Ehteshami\u7b49\u4eba[22]<\/sup>\u7528\u5df1\u4e8c\u8148(AND)\u4ee3\u66ff\u4f20\u7edf\u7535\u89e3\u6db2\u4e2d\u7684\u78b3\u9178\u4e59\u70ef\u916f\uff08EC\uff09\u6eb6\u5242\uff0c\u4ee5LiDFOB\u4f5c\u4e3a\u7535\u89e3\u8d28\u76d0\uff0c\u80fd\u591f\u5927\u5e45\u5ea6\u63d0\u5347\u7535\u89e3\u6db2\u5728\u5e38\u6e29\u4e0b\u7684\u6297\u6c27\u5316\u80fd\u529b\uff0c\u4ece\u800c\u63d0\u9ad8\u7535\u89e3\u6db2\u5728\u9ad8\u538b\u4e0b\u7684\u7a33\u5b9a\u6027\uff0c\u57285V\u4ee5\u4e0b\uff0c\u7535\u89e3\u6db2\u6ca1\u6709\u660e\u663e\u7684\u6c27\u5316\u53cd\u5e94\u3002\u4ed6\u4eec\u8fd8\u6dfb\u52a0FEC\u4f5c\u4e3a\u6210\u819c\u6dfb\u52a0\u5242\uff0cFEC\u80fd\u591f\u5728\u8d1f\u6781\u8868\u9762\u5f62\u6210\u5bcc\u542bLiF\u7684SEI\u819c\uff0c\u4ece\u800c\u663e\u8457\u63d0\u5347\u8d1f\u6781\/\u7535\u89e3\u6db2\u754c\u9762\u7684\u7a33\u5b9a\u6027\uff0c\u63d0\u5347\u7535\u6c60\u7684\u5faa\u73af\u6027\u80fd\u3002<\/p>\n \u53c2\u8003\u6587\u732e\uff1a<\/strong><\/p>\n 1.Jinhyuk Lee, Daniil A. Kitchaev, Deok-Hwang Kwon et al. Reversible Mn2+\/Mn4+double redox in lithium-excess cathode materials. Nature, 2018, 556:185-190.<\/p>\n 2.Yuxuan Zuo, Biao Li, Ning Jiang et al. A high-capacity O2-type Li-rich cathode materialwith a single-Layer Li2MnO3 superstructure. Mater.<\/i><\/em>\u00a02018, 30:1707255.<\/p>\n 3.Biao Li, Ning Jiang, Weifeng Huang et al. Thermodynamic activation of charge transfer in anionic\u00a0redox process for Li-ion batteries.\u00a0Adv. Funct. Mater.<\/i><\/em>\u00a02018,\u00a028:1704864.<\/p>\n 4.Jun Liu, Peter Kopold, Peter A. van Aken et al. Nanotechnology: A sustainable route from reed plants to a silicon anode for lithium-ion batteries. Angew. Chem. Int. Ed.<\/i><\/em>, 2015, 54:9632-9636.<\/p>\n 5.Linqi Zong, Yan Jin, Chang Liu et al. Precise perforation and scalable production of Si particles from low-grade sources for high-performance lithium ion battery anodes. Nano Lett.<\/i><\/em>, 2016, 16:7210-7215.<\/p>\n 6.Zhiliang Liu, Xinghua Chang, Teng Wang\u00a0et al. Silica-Derived Hydrophobic Colloidal Nano-Si for Lithium-Ion Batteries. ACS Nano<\/i><\/em>,\u00a02017, 11:6065-6073.<\/p>\n 7.Min-seong Ko, Sujong Chae, Jiyoung Ma et al. Scalable synthesisi of silicon-nanolayer-embedded graphite for high-energy lithium-ion batteries. Nature Energy, 2016, 1:16113.<\/p>\n 8.Wei Luo, Dengke Shen, Renyuan Zhang et al. Germanium Nano-Grains Decoration on Carbon Shell: Boosting Lithium-Storage Properties of Silicon Nanoparticles. Adv. Funct. Mater.<\/i><\/em>,\u00a02016, 26:7800-7806.<\/p>\n 9.Zailei Zhang, Zhong Lin Wang\u00a0Xianmao Lu\u00a0et al. Multishelled Si@Cu Microparticles Supported on 3D Cu Current Collectors for Stable and Binder-free Anodes of Lithium-Ion Batteries. ACS Nano<\/i><\/em>,\u00a02018, 12:3587.<\/p>\n 10.Shitong Wang, Wei Quan, Zhi Zhu et al. Lithium titanate hydrates with superfast and stable cycling in lithium ion batteries. Nature Communications, 2017, 8:627.<\/p>\n 11.Xianjun Zhu, Yanwu Zhu, Shanthi Murali et al. Nanostructured reduced graphene oxide\/Fe2O3 composite as a high performance anode material for lithium ion batteries. ACS Nano.<\/i><\/em>, 2011, 5:3333-3338.<\/p>\n 12.Zhongshuai Wu, Wencai Ren, Li Xu et al. Doped graphene sheets as anode materials with superhigh rate and large capacity for lithim ion batteries. ACS Nano.<\/i><\/em>, 2011, 5:5463-5471.<\/p>\n 13.Jiantie Xu, Yi Lin, John W. Connell et al. Nigrogen-doped holey graphene as anode for lithium-ion batteries with high volumetric energy density and long cycle life. Small, 2015, 11:6179-6185.<\/p>\n 14.Xingxing Liang, Ying Yang, Xin Jin et al. Polyethylene oxide-coated electrospun polyimide fibrous separator for high-performance lithium-ion battery. Journal of Materials Science &Technology, 2015.<\/p>\n 15.Liyun Cao, Ping An, Zhanwei Xu et al. Performance evaluation of electrospun polyimide non-woven separators for high power lithium-ion batteries. Journal of Electroanalytical Chemistry, 2016, 767:34-39.<\/p>\n 16.Chun-Er Lin, Jun Wang, Mingyong Zhou et al. Poly(m-phenylene isophthalamide) (PMIA): A potential polymer for breaking through the selectivity-permeability trade-off for ultrafiltration membranes. Journal of Membrane Science, 2016, 15:72-78.<\/p>\n 17.Yeon-Su Oh, Gwan Yeong Jung, Jeong-Hoon Kim et al. Janus-faced, dual-conductive\/chemically active battery separator membranes. Advanced Functional Materials, 2016, 26:7074-7083.<\/p>\n 18.Heng Li, Dabei Wu, Jin Wu\u00a0et al. Flexible, High-Wettability and Fire-Resistant Separators Based on Hydroxyapatite Nanowires for Advanced Lithium-Ion Batteries. Adv. Mater.<\/i><\/em>,\u00a02017, 29:170354.<\/p>\n 19.Tae-woo Kwon, You Kyeong Jeong, Erhan Deniz et al. Dynamic cross-linking of polymeric binders based on host-guest interactions for silicon anodes in lithium ion batteries. ACS Nano.<\/i><\/em>, 2015, 9:11317-11324.<\/p>\n 20.Sunghun Choi, Tae-woo Kwon, Ali Coskun et al. Highly elastic binders integrating polyrotaxanes for silicon microparticle anodes in lithium ion batteries. Science,\u00a02017, 357:279-283.<\/p>\n 21.Hailong Lyu, Yunchao Li, Charl J. Jafta et al. Bis(trimethylsilyl)2-fluoromalonate derivatives as electrolyte additives for high voltage lithium ion batteries. Journal of Power Sources, 2019, 412:527-535.<\/p>\n 22.Niloofar Ehteshami, Aitor Eguia-Barrio, Iratxe de Meatza et al. Adiponitrile-based electrolytes for high voltage, graphite-based Li-ion battery. Journal of Power Sources, 2018, 397:52-58.<\/p>\n \u2014\u672c\u6587\u5b8c\u2014<\/p>\n \u5f80\u671f\u9502\u7535\u56de\u987e\uff1a<\/strong><\/p>\n<\/p>\n
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