{"id":166058,"date":"2019-01-25T12:00:58","date_gmt":"2019-01-25T04:00:58","guid":{"rendered":"\/\/m.iemloyee.com\/?p=166058"},"modified":"2019-01-24T21:38:15","modified_gmt":"2019-01-24T13:38:15","slug":"%e4%b8%ad%e7%a7%91%e5%a4%a7%e5%88%98%e5%ba%86%e5%8d%8enat-energy%ef%bc%9a%e6%99%b6%e6%a0%bc%e5%ba%94%e5%8f%98%e7%9a%84%e9%87%91%e5%b1%9e-%e6%9c%89%e6%9c%ba%e9%aa%a8%e6%9e%b6%ef%bc%88mofs%ef%bc%89","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=166058","title":{"rendered":"\u4e2d\u79d1\u5927\u5218\u5e86\u534eNat. Energy\uff1a\u6676\u683c\u5e94\u53d8\u7684\u91d1\u5c5e-\u6709\u673a\u9aa8\u67b6\uff08MOFs\uff09\u7528\u4e8e\u53cc\u529f\u80fd\u6c27\u7535\u50ac\u5316\u5242"},"content":{"rendered":"
\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n \u6c27\u8fd8\u539f\u53cd\u5e94\uff08ORR\uff09\u548c\u6c27\u6790\u51fa\u53cd\u5e94\uff08OER\uff09\u5bf9\u80fd\u91cf\u5b58\u50a8\u548c\u8f6c\u6362\u6280\u672f\u975e\u5e38\u91cd\u8981\u3002\u56e0\u6b64\uff0c\u5f00\u53d1\u5177\u6709\u4f18\u5f02\u50ac\u5316\u6d3b\u6027\u548c\u8010\u4e45\u6027\u7684\u6c27\u50ac\u5316\u5242\u662f\u5f53\u52a1\u4e4b\u6025\u3002\u76ee\u524d\uff0c\u91d1\u5c5e\u539f\u5b50\u4e0e\u6709\u673a\u914d\u4f53\u5f62\u6210\u7684\u91d1\u5c5e\u6709\u673a\u9aa8\u67b6\uff08MOFs\uff09\uff0c\u5bf9CO2<\/sub>\u8fd8\u539f\u548c\u6c34\u6c27\u5316\u5177\u6709\u4e00\u5b9a\u7684\u50ac\u5316\u6d3b\u6027\u3002\u7136\u800c\uff0c\u5bf9\u4e8e4e–<\/sup>\u8def\u5f84\u7684\u5feb\u901f\u53cd\u5e94\u7684\u9ad8\u6d3b\u6027\u8fc7\u6e21\u91d1\u5c5eMOF\u50ac\u5316\u5242\u63a2\u7a76\u4ecd\u7136\u662f\u4e00\u4e2a\u5de8\u5927\u7684\u6311\u6218\u3002\u66f4\u91cd\u8981\u7684\u662f\uff0c\u5bf9\u50ac\u5316\u673a\u7406\u7684\u4e0d\u4e86\u89e3\uff0c\u4e25\u91cd\u963b\u788d\u4e86\u9ad8\u6548\u548c\u4f4e\u6210\u672c\u6c27\u7535\u50ac\u5316\u7684\u8fc7\u6e21\u91d1\u5c5eMOF\u57fa\u50ac\u5316\u5242\u7684\u8bbe\u8ba1\u3002\u672c\u6587\u8bbe\u8ba1\u548c\u53d1\u73b0\u4e86\u4e0d\u540c\u6676\u683c\u5e94\u53d8NiFe MOF\uff0c\u53ef\u4ee5\u4f5c\u4e3a\u9ad8\u6d3b\u6027\u53cc\u529f\u80fd\u6c27\u7535\u50ac\u5316\u5242\uff0c\u5e76\u89e3\u91ca\u4e86\u5176\u50ac\u5316\u673a\u5236\u3002<\/p>\n \u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n \u8fd1\u65e5\uff0c\u4e2d\u56fd\u79d1\u5b66\u6280\u672f\u5927\u5b66<\/strong>\u7684\u5218\u5e86\u534e\uff08\u901a\u8baf\uff09\u3001\u7a0b\u4f4d\u4efb\uff08\u7b2c\u4e00\u4f5c\u8005\uff09<\/strong>\u4f5c\u8005\u7b49\u4eba\uff0c\u8bc1\u660e\u4e0d\u542b\u8d35\u91d1\u5c5e\u7684\u91d1\u5c5e-\u6709\u673a\u9aa8\u67b6\uff08MOF\uff09\u7684\u8bf1\u5bfc\u6676\u683c\u5e94\u53d8\u53ef\u4ee5\u83b7\u5f97\u7a33\u5b9a\u7684\u53cc\u529f\u80fd\u6c27\u8fd8\u539f\u53cd\u5e94\uff08ORR\uff09\u548c\u6790\u6c27\u53cd\u5e94\uff08OER\uff09\u6d3b\u6027\u3002\u6676\u683c\u5e94\u53d8NiFe MOF\u5728ORR\u7684\u534a\u6ce2\u7535\u4f4d\u4e3a0.83 V\u65f6\uff0c\u5177\u6709500 A gmetal<\/sub>-1<\/sup>\u7684\u8d28\u91cf\u6d3b\u6027\uff1b\u5728OER\u76840.30 V\u8fc7\u7535\u4f4d\u65f6\uff0c\u5177\u67092000 A gmetal<\/sub>-1<\/sup>\uff0c\u8fd9\u662f\u65e0\u5e94\u53d8NiFe MOF\u7684OER\u6027\u80fd\u768450-100\u500d\u3002\u5728100-200 mA cm-2<\/sup>\u7684\u9ad8\u7535\u6d41\u5bc6\u5ea6\u4e0b\uff0c\u8fde\u7eedORR\/OER\u53cd\u5e94200\u5c0f\u65f6\u540e\uff0c\u50ac\u5316\u5242\u7684\u6d3b\u6027\u4fdd\u6301\u7ea6\u4e3a97\uff05\u3002\u5229\u7528\u5728\u5408\u80a5\u540c\u6b65\u8f90\u5c04\u5149\u6e90\u5efa\u7acb\u7684\u539f\u4f4d\u540c\u6b65\u8f90\u5c04\u7535\u5316\u5b66\u5085\u7acb\u53f6\u53d8\u6362\u7ea2\u5916\u5149\u8c31\u53d1\u73b0\u5728ORR\u548cOER\u8fc7\u7a0b\u4e2d\uff0cNi4+<\/sup>\u4f4d\u70b9\u4e0a\u51fa\u73b0\u8d85\u6c27\u5316\u7269*OOH\u4e2d\u95f4\u4f53\uff0c\u8fd9\u8868\u660e\u4e86\u4e00\u79cd4e–<\/sup>\u8def\u5f84\u3002\u76f8\u5173\u6210\u679c\u4ee5\u201c<\/strong>Lattice-strained metal\u2013organic-framework arrays for bifunctional oxygen electrocatalysis<\/strong>\u201d\u4e3a\u9898\u53d1\u8868\u5728Nature Energy<\/strong>\u4e0a\u3002<\/p>\n \u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n \u56fe<\/strong> 1 <\/strong>\u6676\u683c\u5e94\u53d8<\/strong>MOF<\/strong>\u7684\u7ed3\u6784\u8868\u5f81<\/strong><\/p>\n \uff08a-d\uff09MOF\u4e0d\u540c\u6676\u683c\u5e94\u53d8\u7684SEM\u548cTEM\u56fe\u50cf\uff1a(a)0%\uff0c(b)1.7\uff05\uff0c(c)3.6\uff05\uff0c(d)4.3\uff05\uff1b<\/p>\n \uff08e\uff0cf\uff09MOF\u4e0d\u540c\u6676\u683c\u5e94\u53d8\u7684XRD\u56fe\u53ca\u5176XRD\u6a21\u62df\u56fe\uff1b<\/p>\n \uff08g\uff09\u7d2b\u5916\u7ebf\u7167\u5c04\u4e0b\uff0cNiFe MOF\u5728\u7684\u6676\u4f53\u7ed3\u6784\u53d8\u5316\u7684\u793a\u610f\u56fe\u3002<\/p>\n \u56fe<\/strong> 2 <\/strong>\u4e0d\u540c\u6676\u683c\u5e94\u53d8<\/strong>MOF<\/strong>\u7684\u6c27\u7535\u50ac\u5316\u6027\u80fd<\/strong><\/p>\n \uff08a\uff09\u4e0d\u540c\u6676\u683c\u5e94\u53d8\u7684MOF\u4e0ePt\/C\u7684LSV\u66f2\u7ebf\uff1b<\/p>\n \uff08b\uff09\u4e0d\u540c\u6676\u683c\u5e94\u53d8\u7684MOF\u4e0ePt\/C\u7684\u8d28\u91cf\u6d3b\u5ea6\u5bf9\u6bd4\u56fe\uff1b<\/p>\n \uff08c\uff094.3%\u6676\u683c\u5e94\u53d8MOF\u4e0ePt\/C\u7684\u7a33\u5b9a\u6027\u5bf9\u6bd4\u56fe\uff1b<\/p>\n \uff08d\uff09\u4e0d\u540c\u6676\u683c\u5e94\u53d8\u7684MOF\u4e0eRuO2<\/sub>\u7684LSV\u66f2\u7ebf\uff1b<\/p>\n \uff08e\uff09\u4e0d\u540c\u6676\u683c\u5e94\u53d8\u7684MOF\u4e0eRuO2<\/sub>\u7684\u8d28\u91cf\u6d3b\u5ea6\u5bf9\u6bd4\u56fe\uff1b<\/p>\n \uff08f\uff094.3%\u6676\u683c\u5e94\u53d8MOF\u4e0eRuO2<\/sub>\u7684\u7a33\u5b9a\u6027\u5bf9\u6bd4\u56fe\u3002<\/p>\n \u56fe<\/strong> 3 <\/strong>\u4e0d\u540c\u6676\u683c\u5e94\u53d8<\/strong>MOF<\/strong>\u7684\u539f\u5b50\u548c\u7535\u5b50\u7ed3\u6784<\/strong><\/p>\n \uff08a\uff09Ni K\u8fb9EXAFS\u5149\u8c31\u7684\u5085\u91cc\u53f6\u53d8\u6362\u56fe\uff1b<\/p>\n \uff08b\uff09Ni 3d\u5e26\u7684\u80fd\u91cf\u8f6c\u79fb\u548c\u672a\u5360\u7528\u72b6\u6001\u56fe\uff1b<\/p>\n \uff08c\uff09\u4e0d\u540c\u6676\u683c\u5e94\u53d8MOF\u7684\u4ef7\u5e26\u9876\u548c\u7406\u8bba\u504f\u79fb\u56fe\uff1b<\/p>\n \uff08d\uff09\u4e0d\u540c\u6676\u683c\u5e94\u53d8MOF\u7684\u7535\u5b50\u4ea4\u6362\u793a\u610f\u56fe\u3002<\/p>\n \u56fe<\/strong> 4 ORR<\/strong>\u548c<\/strong>OER<\/strong>\u5f62\u6210\u8d85\u6c27\u5316\u7269\u4e2d\u95f4\u4f53\u548c\u9ad8\u4ef7<\/strong>Ni4+<\/sup><\/strong>\u7269\u79cd<\/strong><\/p>\n \uff08a\uff09\u6676\u683c\u5e94\u53d84.3%MOF\u7684Operando SR-FTIR\u5149\u8c31\u56fe\uff1b<\/p>\n \uff08b\uff09\u6676\u683c\u5e94\u53d84.3%MOF\u7684\u540c\u4f4d\u7d20\u6807\u8bb0\u7684SR-FTIR\u5149\u8c31\u56fe\uff1b<\/p>\n \uff08c\uff09\u6676\u683c\u5e94\u53d84.3%MOF\u7684ORR\u4e2dNi L3,2<\/sub>-\u8fb9XAS\u8c31\u56fe\uff1b<\/p>\n \uff08d\uff09\u6676\u683c\u5e94\u53d84.3%MOF\u7684OER\u4e2dNi L3,2<\/sub>-\u8fb9XAS\u8c31\u56fe\u3002<\/p>\n \u56fe<\/strong> 5 <\/strong>\u529b\u5b66\u89c6\u89d2\u89c2\u5bdf\u6676\u683c\u5e94\u53d8<\/strong>MOF<\/strong>\u7684\u7535\u50ac\u5316\u6d3b\u6027<\/strong><\/p>\n \uff08a\uff0cb\uff094.3%\u6676\u683c\u5e94\u53d8MOF\u7684ORR\u548cOER\u8fc7\u7a0b\u4e2d\uff0c4.3\uff05MOF\u7684\u4e0d\u540c\u7535\u4f4d\u7684Operando SR-FTIR\u8c31\u56fe\uff1b<\/p>\n \uff08c\uff0cd\uff094.3%\u6676\u683c\u5e94\u53d8MOF\u7684ORR\u548cOER\u8fc7\u7a0b\u4e2d\uff0c1048 cm-1<\/sup>\u548cNi4+<\/sup>\/Ni2+<\/sup>\u6bd4\u7387\u4e0b\u7684\u7ea2\u5916\u4fe1\u53f7\u5bf9\u6bd4\u56fe\uff1b<\/p>\n \uff08e\uff0cf\uff09\u6676\u683c\u5e94\u53d8MOF\u7684ORR\u548cOER\u50ac\u5316\u673a\u5236\u793a\u610f\u56fe\u3002<\/p>\n \u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n \u672c\u6587\u91c7\u7528\u5149\u81f4\u6676\u683c\u5e94\u53d8\u7684\u53ef\u63a7\u7b56\u7565\uff0c\u5f00\u53d1\u4e86\u9ad8\u6548\u7684\u3001\u4f4e\u6210\u672c\u7684\u548c\u4e0d\u542b\u8d35\u91d1\u5c5eNiFe MOF\u7684\u53cc\u529f\u80fd\u6c27\u7535\u50ac\u5316\u5242\u3002\u672c\u6587\u91c7\u7528\u5148\u8fdb\u7684Operando SR-FTIR\u548cXAS\u7684\u5206\u6790\u8868\u660e\uff1a\u4e0e\u4f4e\u6548\u73872e–<\/sup>\u62162e–<\/sup>+2e–<\/sup>\u76f8\u6bd4\uff0c\u6676\u683c\u5e94\u53d8NiFe MOF\u7684ORR\u548cOER\u7684\u6c27\u7535\u50ac\u5316\u673a\u5236\u662f\u5feb\u901f\u6709\u6548\u76844e–<\/sup>\u8def\u5f84\uff0c\u5728\u9ad8\u4ef7Ni4+<\/sup>\u50ac\u5316\u6d3b\u6027\u4f4d\u70b9\u4e0a\u51fa\u73b0\u5173\u952e\u7684\u4e2d\u95f4\u4f53\u8d85\u6c27\u5316\u7269*OOH\u7269\u8d28\u3002\u8fd9\u9879\u5de5\u4f5c\u4e0d\u4ec5\u4e3a\u8bbe\u8ba1\u9ad8\u6548\u3001\u4f4e\u6210\u672c\u7684\u6c27\u6c14\u50ac\u5316\u5242\u63d0\u4f9b\u4e86\u65b0\u7684\u9014\u5f84\uff0c\u4e5f\u6709\u52a9\u4e8e\u50ac\u5316\u673a\u5236\u7684\u7406\u89e3\u3002<\/p>\n<\/p>\n
<\/p>\n
<\/p>\n
<\/p>\n
<\/p>\n