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3.MOF<\/b><\/strong>\u53d1\u5c55\u5386\u7a0b\u4e2d\u7684\u91cc\u7a0b\u7891<\/b><\/strong><\/p>\n

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1995\u5e74\uff0c\u7f8e\u56fd\u52a0\u5dde\u5927\u5b66\u4f2f\u514b\u5229\u5206\u6821<\/b><\/strong>\u7684Omar M. Yaghi<\/b><\/strong>\u6559\u6388\u7814\u7a76\u5c0f\u7ec4<\/b><\/strong>\u5728Nature<\/i><\/b><\/em><\/strong>\u6742\u5fd7\u4e2d\u62a5\u9053\u4e86\u4e00\u4e2a\u7531\u521a\u6027\u6709\u673a\u914d\u4f53\u5747\u82ef\u4e09\u7532\u9178\uff08BTC\uff09\u4e0e\u8fc7\u6e21\u91d1\u5c5eCo\u5408\u6210\u7684\u5177\u6709\u4e8c\u7ef4\u7ed3\u6784\u7684\u914d\u4f4d\u5316\u5408\u7269\uff0c\u5e76\u79f0\u5176\u4e3aMOF[1]<\/b><\/sup><\/strong>\uff0c\u81f3\u6b64\uff0c\u91d1\u5c5e\u6709\u673a\u6846\u67b6\u8fd9\u4e00\u6982\u5ff5\u6b63\u5f0f\u88ab\u63d0\u51fa\uff0c\u5e76\u5728\u968f\u540e\u7684\u8fd1\u4e8c\u5341\u5e74\u4e2d\u4ee5\u60ca\u4eba\u901f\u5ea6\u53d1\u5c55\u30021999\u5e74\uff0cYaghi\u7814\u7a76\u5c0f\u7ec4\u5728Nature<\/i><\/b><\/em><\/strong>\u4e0a\u62a5\u9053\u4e86\u4ee5\u521a\u6027\u6709\u673a\u914d\u4f53\u5bf9\u82ef\u4e8c\u7532\u9178\uff08BDC\uff09\u548c\u8fc7\u6e21\u91d1\u5c5eZn\u6784\u7b51\u7684\u5177\u6709\u7b80\u5355\u7acb\u65b9\u7ed3\u6784\u7684\u4e09\u7ef4\u91d1\u5c5e\u6709\u673a\u9aa8\u67b6\u6750\u6599\u2014\u2014MOF-5\uff0c\u5904\u5728\u7acb\u65b9\u4f53\u516b\u4e2a\u9876\u70b9\u5904\u7684\u91d1\u5c5e\u8282\u70b9\u7531\u542b\u82ef\u73af\u7684\u7a33\u5b9a\u7684\u6709\u673a\u5206\u5b50\u8fde\u63a5\uff0c\u6bcf\u4e2a\u91d1\u5c5e\u8282\u70b9\u4e2d\u542b\u6709\u56db\u4e2a\u950c\u539f\u5b50\uff0c\u88ab\u78b3\u539f\u5b50\u548c\u6c27\u539f\u5b50\u6240\u56fa\u5b9a\u3002\u9aa8\u67b6\u7a7a\u65f7\u5ea655-61%\uff0c\u9aa8\u67b6\u7ed3\u6784\u53ef\u7a33\u5b9a\u81f3300\u2103\uff0c\u53ef\u4ee5\u8bf4MOF-5\u6750\u6599\u7684\u51fa\u73b0\u662fMOF\u53d1\u5c55\u53f2\u4e0a\u7684\u4e00\u4e2a\u91cc\u7a0b\u7891[2]<\/b><\/sup><\/strong>\u3002\u5176\u5b9e\u5728MOF-5\u4e4b\u524d\u8fd8\u6709Yaghi\u7814\u7a76\u5c0f\u7ec4\u5206\u522b\u62a5\u9053\u4e8e1995\u548c1998\u5e74JACS<\/i><\/b><\/em><\/strong>\u6742\u5fd7\u4e0a\u7684MOF-1\uff08\u7531\u4e00\u4ef7\u94dc\u79bb\u5b50\u548c4,4′-\u8054\u5421\u5576\u6784\u6210\u7684\u91d1\u521a\u70f7\u578b\u7684\u7f51\u72b6\u7ed3\u6784\uff09[3]<\/b><\/sup><\/strong>\u548cMOF-2\uff08\u7531\u950c\u79bb\u5b50\u548cBDC\u6784\u6210\u7684\u4e00\u4e2a\u5fae\u5b54\u7f51\u72b6\u4e8c\u7ef4\u7ed3\u6784\uff09[4]<\/b><\/sup><\/strong>\uff0c\u4e4b\u540e2004-2005\u5e74\u95f4\u8fd8\u76f8\u7ee7\u62a5\u9053\u4e86MOF-177[5]<\/b><\/sup><\/strong>\u3001MOF-74[6]<\/b><\/sup><\/strong>\u3002<\/p>\n

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\"\"<\/p>\n

\uff08A\uff09CoC6<\/sub>H3<\/sub>(COOH1\/3<\/sub>)3<\/sub>(NC5<\/sub>H5<\/sub>)2<\/sub>\u00a02\/3 NC5<\/sub>H5<\/sub>\u7684\u5355\u5c42\u6269\u5c55\u591a\u5b54\u7f51\u72b6\u7ed3\u6784\u3002\u91d1\u5c5e-\u7fa7\u9178\u76d0\u5c42\u5927\u81f4\u6cbfxy\u5e73\u9762\u663e\u793a\uff1a\u7eff\u8272\u4e3aCo\uff0c\u7ea2\u8272\u4e3aO\uff0c\u84dd\u8272\u4e3aN\uff0c\u7070\u8272\u4e3aC\u3002\u5bf9\u4e8e\u7edf\u8ba1\u5b66\u4e0a\u65e0\u5e8f\u7684\u914d\u4f4d\u5421\u5576\u5206\u5b50\uff0c\u4ec5\u663e\u793a\u5173\u4e8eCo-N\u952e\u7684\u4e24\u4e2a\u4f18\u9009\u53d6\u5411\u4e2d\u7684\u4e00\u4e2a\u3002\u4e3a\u6e05\u695a\u8d77\u89c1\uff0c\u7701\u7565\u4e86\u5421\u5576\u548cBTC\u5355\u5143\u4e0a\u7684\u6c22\u539f\u5b50[1]<\/b><\/sup><\/strong>\u3002\uff08B\uff09Zn4<\/sub>(O)(BDC)3<\/sub>\uff0cMOF-5\u6846\u67b6\u4e2d\u7684\u4e00\u4e2a\u7a7a\u8154\u3002\u516b\u4e2a\u7c07\uff08\u53ea\u6709\u4e03\u4e2a\u53ef\u89c1\uff09\u6784\u6210\u4e00\u4e2a\u5355\u4f4d\u6676\u80de\uff0c\u5e76\u5305\u56f4\u4e00\u4e2a\u5927\u7a7a\u8154\uff0c\u7531\u4e00\u4e2a\u76f4\u5f84\u4e3a18.5 \u00c5\u7684\u9ec4\u8272\u7403\u4f53\u4e0e72 C\u539f\u5b50\uff08\u7070\u8272\uff09\u63a5\u89e6[2]<\/b><\/sup><\/strong>\u3002<\/p>\n

2004\u548c2005\u5e74\uff0c\u6cd5\u56fd\u51e1\u5c14\u8d5b\u5927\u5b66<\/b><\/strong>\u00a0G\u00e9rard F\u00e9rey<\/b><\/strong>\u7814\u7a76\u5c0f\u7ec4<\/b><\/strong>\u5728Angew. Chem. Int. Ed.<\/i><\/b><\/em><\/strong>[7]<\/b><\/sup><\/strong>\u548cScience<\/i><\/b><\/em><\/strong>[8]<\/b><\/sup><\/strong>\u4e0a\u76f8\u7ee7\u62a5\u9053\u4e86\u4e24\u4e2a\u5177\u6709\u8d85\u5927\u5b54\u7279\u5f81\u7684\u7c7b\u5206\u5b50\u7b5b\u578bMOF\u00a0\u2014\u2014MIL-100\u548cMIL-101\u3002\u5176\u7ed3\u5408\u4e86\u76ee\u6807\u5316\u5b66\u548c\u8ba1\u7b97\u673a\u6a21\u62df\u65b9\u6cd5\uff0c\u5206\u522b\u4ee5\u5e38\u89c4\u7684\u6709\u673a\u914d\u4f53BTC\u548cBDC\u4e0e\u4e09\u4ef7\u91d1\u5c5eCr\u6784\u7b51\u4e86\u5177\u6709\u8d85\u5927\u7b3cMTN\u578b\u5206\u5b50\u7b5b\u62d3\u6251\u7ed3\u6784\u7684MOF\uff0c\u5b83\u4eec\u90fd\u5177\u6709\u4e24\u79cd\u4ecb\u5b54\u7b3c\uff0c\u5c3a\u5bf8\u5206\u522b\u4e3a25\u00c5\u300129\u00c5\u548c29\u00c5\u300134\u00c5\u3002\u6bd4\u8868\u9762\u79ef\u9ad8\u8fbe3100m2<\/sup>\/g\u548c5900m2<\/sup>\/g\u3002F\u00e9rey\u7814\u7a76\u5c0f\u7ec4\u7684\u8fd9\u4e00\u8d21\u732e\u4e0d\u4ec5\u89e3\u51b3\u4e86\u5355\u6676X\u5c04\u7ebf\u884d\u5c04\u624b\u6bb5\u5728\u89e3\u6790\u6676\u4f53\u7ed3\u6784\u65f6\u5bf9\u5e9e\u5927\u7684\u5355\u80de\u4f53\u79ef\u65e0\u80fd\u4e3a\u529b\u7684\u95ee\u9898\uff0c\u8fd8\u63d0\u51fa\u501f\u52a9\u8ba1\u7b97\u673a\u6a21\u62df\u8f85\u52a9\u8bbe\u8ba1\u5408\u6210\u76ee\u6807\u7ed3\u6784\u7684\u65b0\u7b56\u7565\uff0c\u53ef\u4ee5\u8bf4\u4e3aMOF\u6750\u6599\u7684\u53d1\u5c55\u7ffb\u5f00\u4e86\u65b0\u7684\u4e00\u9875\u3002<\/p>\n

\u56fe<\/b><\/strong>\u00a02<\/b><\/strong><\/p>\n

\"\"<\/p>\n

\uff08a\uff09\u539f\u59cb\u6784\u5efa\u5355\u5143\u5177\u6709\u7531\u4e09\u4e2a\u7fa7\u57fa\u5b98\u80fd\u56e2\u87af\u5408\u7684\u91d1\u5c5e\u516b\u9762\u4f53\u4e09\u805a\u4f53\u3002\uff08b\uff09\u901a\u8fc7\u4f7f\u7528\u5360\u6709\u8d85\u56db\u9762\u4f53\u7684\u9762\u7684BTC\u5f62\u6210\u7684\u8d85\u56db\u9762\u4f53\u3002\uff08c\uff09MIL-100\u7684\u5355\u5143\u6676\u80de\u7684\u7403\u68d2\u89c6\u56fe\u3002\u4e3a\u4e86\u66f4\u597d\u5730\u7406\u89e3\uff0c\u4f7f\u7528\u516b\u9762\u4f53\u6765\u8868\u793a\u4e00\u4e2a\u8d85\u7ea7\u56db\u9762\u4f53\u3002\u4e3a\u6e05\u695a\u8d77\u89c1\uff0c\u7701\u7565\u4e86\u6e38\u79bb\u6c34\u5206\u5b50[7]<\/b><\/sup><\/strong>\u3002<\/p>\n

\u56fe<\/b><\/strong>\u00a03<\/b><\/strong><\/p>\n

\"\"<\/p>\n

\uff08A\uff09\u8ba1\u7b97\u8bbe\u8ba1\u7531\u4e09\u4e2a\u7fa7\u57fa\u5b98\u80fd\u56e2\u87af\u5408\u7684\u4e09\u805a\u4f53\u7ed3\u6784\u5355\u5143\u3002\u8d85\u56db\u9762\u4f53\u7531\uff08B\uff09BDC\u6784\u6210\uff0c\u5176\u4f4d\u4e8e\uff08C\uff09\u8d85\u56db\u9762\u4f53\u7684\u8fb9\u7f18\u3002\uff08D\uff09\u4e00\u4e2a\u5355\u4f4d\u6676\u80de\u7684\u7403\u68d2\u6a21\u578b\uff0c\u7a81\u51fa\u663e\u793a\u4ee5\u591a\u9762\u4f53\u6a21\u5f0f\u7ed8\u5236\u7684\u4e00\u4e2a\u8d85\u56db\u9762\u4f53\u3002\uff08E\uff09MTN\u5206\u578b\u7ed3\u6784\uff08\u9876\u70b9\u4ee3\u8868\u6bcf\u4e2a\u8d85\u56db\u9762\u4f53\u7684\u4e2d\u5fc3\uff09\u76843D\u793a\u610f\u56fe\uff0c\u5176\u4e2d\u4e2d\u7b49\uff08\u7eff\u8272\uff0c\u5177\u670920\u4e2a\u56db\u9762\u4f53\uff09\u548c\u5927\uff08\u7ea2\u8272\uff0c\u5177\u670928\u4e2a\u56db\u9762\u4f53\uff09\u7b3c\u5b50\u7531\u8d85\u56db\u9762\u4f53\u7684\u9876\u70b9\u5171\u4eab\u754c\u5b9a\u3002\u516b\u9762\u4f53\u94ec\u7684O\uff0cF\u548cC\u539f\u5b50\u5206\u522b\u4e3a\u7eff\u8272\uff0c\u7ea2\u8272\u548c\u84dd\u8272[8]<\/b><\/sup><\/strong>\u3002<\/p>\n

2006\u5e74\uff0cYaghi\u7814\u7a76\u5c0f\u7ec4\u628a\u76ee\u5149\u8f6c\u5411\u5177\u6709\u4f18\u8d8a\u7a33\u5b9a\u6027\u80fd\u7684\u4f20\u7edf\u5206\u5b50\u7b5b\u6750\u6599\uff0c\u5728PNAS<\/i><\/b><\/em><\/strong>\u4e0a\u62a5\u9053\u5408\u6210\u51fa\u4e8612\u79cd\u5177\u67097\u79cd\u5178\u578b\u7684\u7845\u94dd\u5206\u5b50\u7b5b\u62d3\u6251\u7ed3\u6784\u7684\u7c7b\u5206\u5b50\u7b5b\u54aa\u5511\u9aa8\u67b6\u6750\u6599\u2014\u2014ZIF-1\u5230ZIF-12[9]<\/b><\/sup><\/strong>\uff0c\u8fd9\u4e9b\u6750\u6599\u8868\u73b0\u51fa\u4f18\u8d8a\u7684\u70ed\u7a33\u5b9a\u6027\u548c\u5316\u5b66\u7a33\u5b9a\u6027\uff0c\u5176\u4e2dZIF-8\u548cZIF-11\u4e0d\u4ec5\u80fd\u7a33\u5b9a\u5230550\u2103\uff0c\u5728\u6cb8\u817e\u7684\u78b1\u6027\u6c34\u6eb6\u6db2\u548c\u6709\u673a\u6eb6\u5242\u4e2d\u90fd\u80fd\u4fdd\u6301\u7a33\u5b9a\uff0c\u540e\u6765\u88ab\u5f88\u591a\u79d1\u7814\u5de5\u4f5c\u8005\u6240\u9752\u7750\uff0c\u53d1\u5c55\u4e86\u5f88\u591a\u5e94\u7528\u3002\u968f\u540e\uff0c2007-2008\u5e74\uff0cYaghi\u7814\u7a76\u5c0f\u7ec4\u53c8\u9646\u7eed\u5728Nature Materials<\/i><\/b><\/em><\/strong>[10]<\/b><\/sup><\/strong>\u3001<\/i><\/em>Science<\/i><\/b><\/em><\/strong>[11]<\/b><\/sup><\/strong>\u548cNature<\/i><\/b><\/em><\/strong>[12]<\/b><\/sup><\/strong>\u00a0<\/i><\/b><\/em><\/strong>\u4e0a\u62a5\u5bfc\u4e86ZIF-20\u5230ZIF-23\u3001ZIF-68\u3001ZIF-69\u3001ZIF-70\u3001ZIF-95\u548cZIF-100\u7b49\u7ed3\u6784\uff0c\u4f7fZIF\u5bb6\u65cf\u5f97\u5230\u5f88\u5927\u7684\u62d3\u5c55\u3002<\/p>\n

\u56fe<\/b><\/strong>\u00a04<\/b><\/strong>\u00a0ZIF\u7cfb\u5217\u7684\u5355\u6676X\u5c04\u7ebf\u7ed3\u6784\u00a0[9]<\/b><\/sup><\/strong>\u3002<\/p>\n

\u00a0\"\"<\/b><\/strong><\/p>\n

4.MOF<\/b><\/strong>\u7684\u547d\u540d\u89c4\u5219<\/b><\/strong><\/p>\n

\u57fa\u4e8e\u4ee5\u4e0a\u6211\u4eec\u4e86\u89e3\u4e86MOF\u7684\u7531\u6765\uff0c\u53ef\u4ee5\u53d1\u73b0MOF\u7684\u547d\u540d\u4e5f\u662f\u6709\u4e00\u5b9a\u7684\u89c4\u5219\u7684\uff0c\u4e3b\u8981\u6709\u4ee5\u4e0b\u56db\u4e2a\u65b9\u9762\u3002<\/p>\n

4.1 <\/b><\/strong>\u6750\u6599\u7684\u6210\u5206<\/b><\/strong><\/p>\n

MOF-n: Metal-Organic Framework\u91d1\u5c5e-\u6709\u673a\u6846\u67b6<\/p>\n

RPF-n: Rare-Earth Polymeric Framework\u7a00\u571f-\u805a\u5408\u7269\u9aa8\u67b6<\/p>\n

MPF-n: Metal Peptide Framework\u91d1\u5c5e-\u80bd\u9aa8\u67b6<\/p>\n

4.2 <\/b><\/strong>\u7ed3\u6784<\/b><\/strong><\/p>\n

ZMOF-n: Zeolite-like Metal-Organic Framework\u7c7b\u6cb8\u77f3\u91d1\u5c5e\u6709\u673a\u9aa8\u67b6<\/p>\n

ZIF-n: Zeolitic Imidazolate Framework\u6cb8\u77f3-\u54aa\u5511\u916f\u9aa8\u67b6\u2014\u2014\u5177\u6709\u56db\u9762\u4f53\u578b\u4e09\u7ef4\u7f51\u72b6\u7ed3\u6784\uff0c\u4ece\u7ed3\u6784\u4e0a\u7c7b\u4f3c\u6cb8\u77f3\uff0c\u4f7f\u7528\u950c\u6216\u94b4\u6765\u4ee3\u66ff\u6cb8\u77f3\u4e2d\u7684\u7845\uff0c\u7528\u54aa\u5511\u914d\u4f53\u66ff\u4ee3\u4e86\u6cb8\u77f3\u4e2d\u7684\u6c27\u6865<\/p>\n

PCN-n: Porous Coordination Network\u591a\u5b54\u534f\u8c03\u7f51\u7edc\uff08\u591a\u5b54\u91d1\u5c5e\u6709\u673a\u9aa8\u67b6\uff09<\/p>\n

4.3 <\/b><\/strong>\u529f\u80fd<\/b><\/strong><\/p>\n

IRMOF-n: Isoreticular Metal-organic Framework\u00a0\u540c\u6784\u7f51\u72b6\u91d1\u5c5e\u6709\u673a\u6846\u67b6\u2014\u2014\u4e0eMOF-5\u5177\u6709\u76f8\u540c\u62d3\u6251\u7f51\u7edc\u7ed3\u6784\u7684MOF\u591a\u5b54\u6750\u6599<\/p>\n

MTV-MOF-n: Multivariate Metal-organic Framework\u591a\u53d8\u529f\u80fd\u5316\u91d1\u5c5e\u6709\u673a\u9aa8\u67b6\u2014\u2014\u5373\u5728\u540c\u4e00\u4e2a\u6676\u4f53\u7ed3\u6784\u7684\u5b54\u9053\u8868\u9762\u540c\u65f6\u4fee\u9970\u4e0a\u4e0d\u540c\u79cd\u7c7b\u529f\u80fd\u56e2\u7684MOF\u6750\u6599<\/p>\n

4.4 <\/b><\/strong>\u5b9e\u9a8c\u5ba4\u6216\u5927\u5b66\u540d\u5b57<\/b><\/strong><\/p>\n

\u8fd9\u79cd\u547d\u540d\u65b9\u6cd5\u88ab\u540e\u7eed\u5927\u591a\u6570\u4eba\u91c7\u7528\uff0c\u5927\u90e8\u5206\u60c5\u51b5\u662f\u53d6\u5b9e\u9a8c\u5ba4\u6216\u5927\u5b66\u82f1\u6587\u540d\u79f0\u7684\u9996\u5b57\u6bcd\u7684\u7b80\u79f0\u52a0\u4e0a\u4e00\u4e2a\u6570\u5b57\uff0c\u6570\u5b57n\u4ee3\u8868\u5236\u5907\u7684\u5e8f\u53f7\u3002\u5f53\u7136\u6709\u7684\u5e76\u4e0d\u662f\u5b8c\u5168\u6309\u5236\u5907\u987a\u5e8f\u6765\u7684\uff0c\u6570\u5b57n\u7684\u9009\u62e9\u6709\u65f6\u5019\u770b\u521b\u59cb\u4eba\u7684\u5fc3\u60c5\u3002\u6bd4\u5982MOF-1\uff0cMOF-2\u51fa\u73b0\u4e4b\u540e\uff0c\u76f4\u63a5\u5230MOF-5\uff0c\u5e76\u4e0d\u662f\u56e0\u4e3a\u5b83\u662fYaghi\u7814\u7a76\u5c0f\u7ec4\u7684\u7b2c5\u4e2aMOF\uff0c\u800c\u662f\u5bf9\u6cb8\u77f3\u7ecf\u5178\u7ed3\u6784ZSM-5\u7684\u81f4\u656c\u3002<\/p>\n

MIL-n:\u00a0Materials of Institute Lavoisier\u62c9\u74e6\u9521\u6750\u6599\u7814\u7a76\u6240<\/p>\n

NU-n: Northwestern University\u00a0\u7f8e\u56fd\u897f\u5317\u5927\u5b66<\/p>\n

DUT-n: Dresden University of Technology\u00a0\u5fb7\u7d2f\u65af\u987f\u7406\u5de5\u5927\u5b66<\/p>\n

UiO-n: University of Oslo\u00a0\u632a\u5a01\u5965\u65af\u9646\u5927\u5b66<\/p>\n

CPO-n: Coordination Polymer of Oslo\u5965\u65af\u9646\u914d\u4f4d\u805a\u5408\u7269<\/p>\n

NOTT-n: University of Nottingham\u82f1\u56fd\u8bfa\u4e01\u6c49\u5927\u5b66<\/p>\n

UTSA-n: University of Texas U.S.A\u7f8e\u56fd\u5fb7\u514b\u8428\u65af\u5dde\u5927\u5b66<\/p>\n

UMCM-n: University of Michigan\u00a0Crystalline Material\u5bc6\u6b47\u6839\u5927\u5b66<\/p>\n

POST-n:\u00a0Pohang University of Science and Technology\u6d66\u9879\u79d1\u6280\u5927\u5b66<\/p>\n

HKUST-n: Hong Kong University of Science and Technology\u9999\u6e2f\u79d1\u6280\u5927\u5b66<\/p>\n

ZJU-n: Zhejiang University \u6d59\u6c5f\u5927\u5b66<\/p>\n

FJI-n: Fujian Institute of Research on the Structure of Matter\u798f\u5efa\u7269\u8d28\u7ed3\u6784\u7814\u7a76\u6240<\/p>\n

5.\u4ee3\u8868\u6027<\/b><\/strong>MOF<\/b><\/strong>\u6c47\u603b<\/b><\/strong><\/p>\n

\u4e0b\u9762\u5206\u522b\u5bf9\u4e00\u4e9b\u5177\u6709\u4ee3\u8868\u6027\u7684MOF\u8fdb\u884c\u6c47\u603b\u5f52\u7eb3\uff0c\u65b9\u4fbf\u5927\u5bb6\u67e5\u627e\u3002\u9700\u8981\u6ce8\u610f\u7684\u662f\uff0c\u540c\u4e00\u5316\u5408\u7269\u4f1a\u6709\u4e0d\u540c\u540d\u79f0\u3002\u5173\u4e8e\u8868\u683c\u4e2d\u4e0d\u540c\u79cd\u7c7bMOF\u7684\u5206\u5b50\u5f0f\u5728\u4e0d\u540c\u6587\u732e\u8868\u8fbe\u4f1a\u6709\u4e9b\u8bb8\u5dee\u5f02\uff0c\u4ec5\u4f9b\u53c2\u8003\u3002<\/p>\n

\u8868<\/b><\/strong>1 <\/b><\/strong>\u6709\u4ee3\u8868\u6027\u7684MOF\u6750\u6599<\/p>\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n
\n

MOF\u540d\u79f0<\/p>\n<\/td>\n

\n

\u5206\u5b50\u5f0f<\/p>\n<\/td>\n

\n

\u53d1\u660e\u8bfe\u9898\u7ec4<\/p>\n<\/td>\n

\n

\u9996\u6b21\u53d1\u8868\u6742\u5fd7\u540d\u79f0\u4ee5\u53ca\u5e74\u4efd<\/p>\n<\/td>\n<\/tr>\n

\n

MOF-5\u5373IRMOF-1<\/p>\n<\/td>\n

\n

Zn4<\/sub>O(BDC)3<\/sub>\u00b7(DMF)8<\/sub>(C6<\/sub>H5<\/sub>Cl)<\/p>\n<\/td>\n

\n

Omar M. Yaghi<\/p>\n<\/td>\n

\n

Nature, 1999[2]<\/b><\/sup><\/strong><\/p>\n<\/td>\n<\/tr>\n

\n

MOF-69C<\/p>\n<\/td>\n

\n

Zn3<\/sub>(OH)2<\/sub>(1,4-BDC)2<\/sub>\u00b7(DEF)2<\/sub><\/p>\n<\/td>\n

\n

Omar M. Yaghi<\/p>\n<\/td>\n

\n

JACS, 2005[6]<\/b><\/sup><\/strong><\/p>\n<\/td>\n<\/tr>\n

\n

MOF-74<\/p>\n<\/td>\n

\n

Zn2<\/sub>(DHBDC)(DMF)2<\/sub>\u00b7(H2<\/sub>O)2<\/sub><\/p>\n<\/td>\n

\n

Omar M. Yaghi<\/p>\n<\/td>\n

\n

JACS, 2005[6]<\/b><\/sup><\/strong><\/p>\n<\/td>\n<\/tr>\n

\n

HKUST-1\u5373MOF-199<\/p>\n<\/td>\n

\n

[Cu3<\/sub>(BTC)2<\/sub>(H2<\/sub>O)3<\/sub>]<\/p>\n<\/td>\n

\n

Ian D. Williams<\/p>\n<\/td>\n

\n

Science, 1999[13]<\/b><\/sup><\/strong><\/p>\n<\/td>\n<\/tr>\n

\n

POST-1<\/p>\n<\/td>\n

\n

[Zn3<\/sub>(\u03bc3<\/sub>-O)(1-H)6<\/sub>]\u00b72H3<\/sub>O\u00b712H2<\/sub>O<\/p>\n<\/td>\n

\n

Kimoon Kim<\/p>\n<\/td>\n

\n

Nature, 2000[14]<\/b><\/sup><\/strong><\/p>\n<\/td>\n<\/tr>\n

\n

ZIF-8<\/p>\n<\/td>\n

\n

Zn(MeIM)2<\/sub>\u00b7(DMF)\u00b7(H2<\/sub>O)3<\/sub><\/p>\n<\/td>\n

\n

Omar M. Yaghi<\/p>\n<\/td>\n

\n

PNAS, 2006[9]<\/b><\/sup><\/strong><\/p>\n<\/td>\n<\/tr>\n

\n

ZIF-67<\/p>\n<\/td>\n

\n

Co(MeIM)2<\/sub><\/p>\n<\/td>\n

\n

Omar M. Yaghi<\/p>\n<\/td>\n

\n

Science, 2008[11]<\/b><\/sup><\/strong><\/p>\n<\/td>\n<\/tr>\n

\n

MIL-100(Cr)<\/p>\n<\/td>\n

\n

Cr3<\/sub>F(H2<\/sub>O)3<\/sub>O[C6<\/sub>H3<\/sub>-(CO2<\/sub>)3<\/sub>]2<\/sub>\u00b728H2<\/sub>O<\/p>\n<\/td>\n

\n

G\u00e9rard F\u00e9rey<\/p>\n<\/td>\n

\n

Angew. Chem. Int. Ed., 2004[7]<\/b><\/sup><\/strong><\/p>\n<\/td>\n<\/tr>\n

\n

MIL-101(Cr)<\/p>\n<\/td>\n

\n

Cr3<\/sub>F(H2<\/sub>O)2<\/sub>O[(O2<\/sub>C)-C6<\/sub>H4<\/sub>-(CO2<\/sub>)]3<\/sub>\u00b725H2<\/sub>O<\/p>\n<\/td>\n

\n

G\u00e9rard F\u00e9rey<\/p>\n<\/td>\n

\n

Science, 2005[8]<\/b><\/sup><\/strong><\/p>\n<\/td>\n<\/tr>\n

\n

MIL-100(Fe)<\/p>\n<\/td>\n

\n

Fe3<\/sub>O(H2<\/sub>O)2<\/sub>F\u00b7{C6<\/sub>H3<\/sub>(CO2<\/sub>)3<\/sub>}2<\/sub>\u00b714.5H2<\/sub>O<\/p>\n<\/td>\n

\n

G\u00e9rard F\u00e9rey<\/p>\n<\/td>\n

\n

Chem. Comm, 2007[15]<\/b><\/sup><\/strong><\/p>\n<\/td>\n<\/tr>\n

\n

MIL-125<\/p>\n<\/td>\n

\n

Ti8<\/sub>O8<\/sub>(OH)4<\/sub>-(O2<\/sub>C-C6<\/sub>H4<\/sub>-CO2<\/sub>)6<\/sub><\/p>\n<\/td>\n

\n

G\u00e9rard F\u00e9rey<\/p>\n<\/td>\n

\n

JACS, 2009[16]<\/b><\/sup><\/strong><\/p>\n<\/td>\n<\/tr>\n

\n

UiO-66<\/p>\n<\/td>\n

\n

\u00a0[Zr6<\/sub>O4<\/sub>(OH)4<\/sub>](BDC)6<\/sub><\/p>\n<\/td>\n

\n

Karl Petter Lillerud<\/p>\n<\/td>\n

\n

JACS, 2008[17]<\/b><\/sup><\/strong><\/p>\n<\/td>\n<\/tr>\n

\n

NOTT-300<\/p>\n<\/td>\n

\n

[Al2<\/sub>(OH)2<\/sub>(C16<\/sub>O8<\/sub>H6<\/sub>)](H2<\/sub>O)6<\/sub><\/p>\n<\/td>\n

\n

Martin Schroder<\/p>\n<\/td>\n

\n

Nature Chem., 2012[18]<\/b><\/sup><\/strong><\/p>\n<\/td>\n<\/tr>\n

\n

NU-110\u5373PCN-610<\/p>\n<\/td>\n

\n

[Cu3<\/sub>(L6\u2212<\/sup>\u00a0(110)<\/sub>)(H2<\/sub>O)3<\/sub>]n<\/sub><\/p>\n<\/td>\n

\n

Omar K. Farha<\/p>\n<\/td>\n

\n

JACS, 2012[1<\/b><\/sup><\/strong>9<\/b><\/sup><\/strong>]<\/b><\/sup><\/strong><\/p>\n<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n


\n 6.\u5c55\u671b<\/b><\/strong><\/p>\n

\u901a\u8fc7MOF\u6750\u6599\u7684\u53d1\u5c55\u53f2\u6211\u4eec\u53ef\u4ee5\u770b\u51fa\uff0c\u8fd1\u51e0\u5341\u5e74\u6765\uff0c\u4e00\u4e2a\u53c8\u4e00\u4e2a\u65b0MOF\u88ab\u5408\u6210\u3001\u8868\u5f81\u3001\u53d1\u8868\uff0c\u6570\u636e\u5e93\u9010\u6e10\u4e30\u5bcc\u3002\u968f\u7740MOF\u6750\u6599\u79cd\u7c7b\u7684\u65e5\u76ca\u589e\u591a\u4ee5\u53ca\u590d\u5408MOF\u6750\u6599\u7684\u9010\u6e10\u5174\u8d77\uff0cMOF\u6750\u6599\u5c06\u6709\u4e0d\u53ef\u4f30\u91cf\u7684\u5e94\u7528\u524d\u666f\u3002MOF\u6750\u6599\u7531\u4e8e\u5177\u6709\u53ef\u8bbe\u8ba1\u7684\u4e30\u5bcc\u7684\u7ed3\u6784\u7c7b\u578b\uff0c\u4f4e\u5bc6\u5ea6\u3001\u6c38\u4e45\u5b54\u6d1e\u3001\u8d85\u9ad8\u7684\u6bd4\u8868\u9762\u79ef\u548c\u53ef\u529f\u80fd\u5316\u7684\u5b54\u7a7a\u95f4\uff0c\u5728\u6c14\u4f53\u5b58\u50a8\u4e0e\u5206\u79bb\u3001\u50ac\u5316\u3001\u4f20\u611f\u3001\u836f\u7269\u8fd0\u8f93\u7b49\u9886\u57df\u90fd\u6709\u5e7f\u6cdb\u7684\u5e94\u7528\u3002\u4f46\u4e5f\u5e76\u4e0d\u662f\u6240\u6709\u7684MOF\u6750\u6599\u90fd\u5177\u6709\u5e7f\u6cdb\u5e94\u7528\uff0c\u5b83\u9700\u8981\u6839\u636e\u4e0d\u540c\u7684\u5e94\u7528\u6ee1\u8db3\u4e0d\u540c\u7684\u9700\u6c42\uff0c\u6bd4\u5982\u5b54\u5f84\u5927\u5c0f\uff0c\u7a33\u5b9a\u6027\u7b49\u7b49\u3002\u90a3\u4e48\u76ee\u524d\u6709\u54ea\u4e9bMOF\u6750\u6599\u662f\u7814\u7a76\u8005\u4eec\u9752\u7750\u7684\u5462\uff1f\u5b83\u4eec\u53c8\u662f\u5982\u4f55\u5728\u5404\u4e2a\u9886\u57df\u53d1\u6325\u81ea\u5df1\u7684\u4f5c\u7528\u7684\uff1f\u60f3\u8981\u77e5\u9053\u7684\u5c0f\u4f19\u4f34\u4eec\u671f\u5f85\u4e0b\u671f\u5427\u3002\u6b22\u8fce\u4f60\u4eec\u7684\u6279\u8bc4\u6307\u6b63\u3002<\/p>\n

\u53c2\u8003\u6587\u732e<\/b><\/strong><\/p>\n

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Sci-hub<\/b><\/strong>\u4e0b\u8f7d\u7f51\u5740\uff1a<\/b><\/strong>http:\/\/sci-hub.tw\/10.1038\/378703a0<\/a><\/p>\n

[2] Li H L, Eddaoudi M M, O’Keeffe M, et al. Design and Synthesis of an Exceptionally Stable and Highly Porous Metal-Organic Framework[J]. Nature, 1999, 402(6759):276-279.<\/p>\n

Sci-hub<\/b><\/strong>\u4e0b\u8f7d\u7f51\u5740\uff1a<\/b><\/strong>http:\/\/sci-hub.tw\/10.1038\/46248<\/a><\/p>\n

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\u4e0b\u8f7d\u7f51\u5740\uff1a<\/b><\/strong>https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/ja00146a033<\/p>\n

[4] Li H, Eddaoudi M, Groy T L, et al. Establishing Microporosity in Open Metal-Organic Frameworks: Gas Sorption Isotherms for Zn(BDC) (BDC = 1,4-Benzenedicarboxylate)[J]. Journal of the American Chemical Society, 1998, 120(33):8571-8572.<\/p>\n

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[5] Chae H K, Diana Y. Siberio-P\u00e9rez, Kim J, et al. A route to high surface area, porosity and inclusion of large molecules in crystals[J]. Nature, 2004,\u00a0427, 523-527.<\/p>\n

\u4e0b\u8f7d\u7f51\u5740\uff1a<\/b><\/strong>https:\/\/www.nature.com\/articles\/nature02311<\/p>\n

[6] Rosi N L, Kim J, Eddaoudi M, et al. Rod packings and metal-organic frameworks constructed from rod-shaped secondary building units[J]. Journal of the American Chemical Society, 2005, 127(5):1504-1518.<\/p>\n

\u4e0b\u8f7d\u7f51\u5740\uff1a<\/b><\/strong>https:\/\/sci-hub.tw\/10.1021\/ja045123o<\/p>\n

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Sci-hub<\/b><\/strong>\u4e0b\u8f7d\u7f51\u5740<\/b><\/strong>: <\/b><\/strong>http:\/\/sci-hub.tw\/10.1002\/ange.200460592<\/p>\n

[8]\u00a0Ferey, G. A Chromium Terephthalate-Based Solid with Unusually Large Pore Volumes and Surface Area[J]. Science, 2005, 309(5743):2040-2042.<\/p>\n

\u4e0b\u8f7d\u7f51\u5740<\/b><\/strong>:<\/b><\/strong>\u00a0http:\/\/science.sciencemag.org\/content\/309\/5743\/2040<\/p>\n

[9]\u00a0Park K S, Ni Z, Adrien P. C\u00f4t\u00e9, et al. Exceptional chemical and thermal stability of zeolitic imidazolate frameworks[J]. Proc Natl Acad Sci U S A, 2006, 103(27):10186-10191.<\/p>\n

Sci-hub<\/b><\/strong>\u4e0b\u8f7d\u7f51\u5740<\/b><\/strong>:<\/b><\/strong>\u00a0https:\/\/sci-hub.tw\/https:\/\/doi.org\/10.2307\/30049598<\/p>\n

[10]\u00a0Hayashi H, Adrien P. C\u00f4t\u00e9, Furukawa H, et al. Zeolite A imidazolate frameworks[J]. Nature Materials, 2007, 6(7):501-506.<\/p>\n

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\u4e0b\u8f7d\u7f51\u5740\uff1a<\/b><\/strong>http:\/\/science.sciencemag.org\/content\/319\/5865\/939\/tab-pdf<\/p>\n

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\u4e0b\u8f7d\u7f51\u5740\uff1a<\/b><\/strong>https:\/\/www.nature.com\/articles\/nature06900<\/p>\n

[13]\u00a0Lo S M F, Chui S S Y. A Chemically Functionalizable Nanoporous Material [Cu3<\/sub>(TMA)2<\/sub>(H2<\/sub>O)3<\/sub>]n[J]. Science, 1999, 283(5405):1148-1150.<\/p>\n

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\u4e0b\u8f7d\u7f51\u5740\uff1a<\/b><\/strong>https:\/\/www.nature.com\/articles\/35010088<\/a><\/p>\n

[15]\u00a0Horcajada P, Surbl S, Serre C, et al. Synthesis and catalytic properties of MIL-100(Fe), an iron(iii) carboxylate with large pores[J]. Chemical Communications, 2007(27):2820-2822.<\/p>\n

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[16]\u00a0Dan-Hardi M, Serre C, Frot T, et al. A New Photoactive Crystalline Highly Porous Titanium\u00a0(IV) Dicarboxylate[J]. Journal of the American Chemical Society, 2009, 131(31):10857-10859.<\/p>\n

\u4e0b\u8f7d\u7f51\u5740\uff1a<\/b><\/strong>https:\/\/pubs.acs.org\/doi\/abs\/10.1021\/ja903726m<\/p>\n

[17] Cavka J H, Jakobsen S, Olsbye U, et al. A New Zirconium Inorganic Building Brick Forming Metal Organic Frameworks with Exceptional Stability[J]. Journal of the American Chemical Society, 2008, 130(42):13850-13851.<\/p>\n

\u4e0b\u8f7d\u7f51\u5740\uff1a<\/b><\/strong>https:\/\/pubs.acs.org\/doi\/pdfplus\/10.1021\/ja8057953<\/p>\n

[18] Yang S, Sun J, Ramirezcuesta A J, et al. Selectivity and direct visualization of carbon dioxide and sulfur dioxide in a decorated porous host[J]. Nature Chemistry, 2012, 4(11):887-894.<\/p>\n

\u4e0b\u8f7d\u7f51\u5740\uff1a<\/b><\/strong>https:\/\/www.nature.com\/articles\/nchem.1457<\/p>\n

[19] Farha O K, Eryazici I I, Jeong N C, et al. Metal-Organic Framework Materials with Ultrahigh Surface Areas: Is the Sky the Limit?[J]. Journal of the American Chemical Society, 2015, 134(36):15016-15021.<\/p>\n

\u4e0b\u8f7d\u7f51\u5740\uff1a<\/b><\/strong>https:\/\/pubs.acs.org.ccindex.cn\/doi\/pdfplus\/10.1021\/ja3055639<\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u4e13\u680f\u4f5c\u8005\u6768\u4e66\u51dd\u4f9b\u7a3f<\/strong>\uff0c\u6750\u6599\u4eba\u7f16\u8f91\u90e8\u7f16\u8f91<\/p>\n

\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1: tougao@cailiaoren.com.<\/p>\n

\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1acailiaorenVIP.<\/p>\n","protected":false},"excerpt":{"rendered":"

\u3010\u5f15\u8bed\u3011 MOF\u4e13\u680f\uff1a\u4e0d\u5b9a\u671f\u68b3\u7406\u603b\u7ed3MOF\u76f8\u5173\u77e5\u8bc6\u5185\u5bb9 \u6750\u6599\u4eba\u73b0\u5728\u8bbe\u7acb\u5404\u79cd\u6587\u7ae0\u4e13\u680f\uff0c\u6240\u6d89\u53ca\u9886\u57df\u6b63\u5728\u6162\u6162\u5b8c\u5584\uff0c\u7531\u6b64\u4e5f\u9700\u8981\u66f4\u591a\u7684\u4e13\u680f\u4f5c\u8005\uff0c\u6ca1\u9519\uff0c\u6211\u4eec\u6b63\u5728\u62db\u5175\u4e70\u9a6c\uff0c\u671f…<\/p>\n","protected":false},"author":10213,"featured_media":174193,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[1187],"tags":[],"class_list":["post-165693","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-zhuanlan"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/165693"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/10213"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=165693"}],"version-history":[{"count":4,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/165693\/revisions"}],"predecessor-version":[{"id":165702,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/165693\/revisions\/165702"}],"wp:featuredmedia":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/media\/174193"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=165693"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=165693"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=165693"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}