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\u3010\u5f15\u8bed\u3011<\/strong><\/p>\n

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1.\u5f15\u8bed<\/b><\/strong><\/p>\n

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2.\u91d1\u5c5e\u70ef\u7684\u5e38\u7528\u5408\u6210\u7b56\u7565<\/b><\/strong><\/p>\n

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2.1\u4e8c\u7ef4\u6a21\u677f\u9650\u57df\u751f\u957f\u6cd5<\/b><\/strong><\/p>\n

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2.2\u6676\u79cd\u751f\u957f\u6cd5<\/b><\/strong><\/p>\n

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2.3\u6dfb\u52a0\u5242\u8f85\u52a9\u7684\u6e7f\u5316\u5b66\u5408\u6210<\/b><\/strong><\/p>\n

\u5728\u6e7f\u5316\u5b66\u5408\u6210\u4f53\u7cfb\u4e2d \uff08\u91d1\u5c5e\u524d\u4f53\u3001\u8fd8\u539f\u5242\u548c\u4fdd\u62a4\u914d\u4f53\u6df7\u5408\u6eb6\u6db2\u4e2d\uff09\uff0c\u52a0\u5165\u5c11\u91cf\u7684\u6dfb\u52a0\u5242\u53ef\u4ee5\u4fc3\u8fdb\u4e8c\u7ef4\u91d1\u5c5e\u7684\u5404\u5411\u5f02\u6027\u751f\u957f\uff0c\u4ece\u800c\u8fbe\u5230\u8c03\u63a7\u91d1\u5c5e\u7eb3\u7c73\u6676\u4f53\u7684\u4e8c\u7ef4\u751f\u957f\u3002\u8fd9\u7c7b\u6dfb\u52a0\u5242\u901a\u5e38\u662f\u5c0f\u5206\u5b50\uff08\u4f8b\u5982O2<\/sub>\uff0cCO, H2<\/sub>O2<\/sub>\uff09\u6216\u8005\u79bb\u5b50\uff08\u4f8b\u5982\u5364\u7d20\u79bb\u5b50\u548c\u67d0\u4e9b\u91d1\u5c5e\u79bb\u5b50\uff09\u3002\u4ed6\u4eec\u7684\u4f5c\u7528\u673a\u5236\u662f\u57fa\u4e8e\u8c03\u8282\u91d1\u5c5e\u524d\u4f53\u6c27\u5316\u8fd8\u539f\u7535\u4f4d\u548c\u4e0d\u540c\u6676\u9762\u7684\u8868\u9762\u80fd\u3002\u6bd4\u5982CO\u5206\u5b50\u901a\u8fc7\u4e0e\u8868\u9762\u539f\u5b50\u5f62\u6210\u8f83\u5f3a\u7684\u914d\u4f4d\u952e\uff0c\u53ef\u4ee5\u4f18\u5148\u5438\u9644\u5728\u67d0\u4e9b\u91d1\u5c5e\u7684\u4e00\u4e9b\u4f4e\u6307\u6570\u7684\u6676\u9762\u4e0a\uff0c\u5bfc\u81f4\u8fd9\u4e9b\u6676\u9762\u7684\u5728\u6676\u9762\u751f\u957f\u8fc7\u7a0b\u5b8c\u6210\u540e\u5f97\u5230\u6700\u5927\u7a0b\u5ea6\u7684\u66b4\u9732[7]\u3002\u5f53\u7136\uff0c\u51fa\u4e8e\u5b89\u5168\u8003\u8651\uff0c\u76f4\u63a5\u4f7f\u7528\u4e00\u6c27\u5316\u78b3\u6c14\u4f53\u5f80\u5f80\u53d7\u5230\u9650\u5236\u3002\u4f5c\u4e3aCO\u6dfb\u52a0\u5242\u7684\u66ff\u4ee3\u54c1\uff0c\u56fa\u4f53\u91d1\u5c5e\u7fb0\u57fa\u5316\u5408\u7269(\u5982W(CO)6<\/sub>\u3001Mo(CO)6<\/sub>\u3001CO (CO)8<\/sub>)\u7b49\u5171\u53ef\u4ee5\u91ca\u653eCO\u7684\u6dfb\u52a0\u5242\u5728\u4e8c\u7ef4\u91d1\u5c5e\u7eb3\u7c73\u6750\u6599\u7684\u5408\u6210\u4e2d\u8d8a\u6765\u8d8a\u53d7\u6b22\u8fce[8]\u3002\u8fd9\u4e9b\u56fa\u4f53\u5316\u5408\u7269\u5728\u5e38\u6e29\u4e0b\u76f8\u5bf9\u7a33\u5b9a\uff0c\u800c\u5728\u9ad8\u6e29\u5408\u6210\u8fc7\u7a0b\u4e2d\u53ef\u4ee5\u9010\u6e10\u5206\u89e3\u91ca\u653eCO\u5c0f\u5206\u5b50\u6dfb\u52a0\u5242\u3002<\/p>\n

2.4\u591a\u5143\u9187\u6cd5<\/b><\/strong><\/p>\n

\u591a\u5143\u9187\u6cd5\u4e00\u822c\u662f\u6307\u4ee5\u591a\u5143\u9187\u4e3a\u53cd\u5e94\u4ecb\u8d28\uff0c\u5728\u9ad8\u6e29\u9ad8\u538b\u7684\u53cd\u5e94\u91dc\u4e2d\uff0c\u5229\u7528\u9187\u4e2d\u7f9f\u57fa\u7f29\u5408\u6216\u8005\u5c40\u90e8\u5f62\u6210\u7684\u5fae\u91cf\u6c34\u7684\u73af\u5883\u6765\u8fbe\u5230\u7eb3\u7c73\u91d1\u5c5e\u6750\u6599\u751f\u957f\u7684\u8fc7\u7a0b\uff0c\u8fd9\u7b97\u662f\u4e00\u7c7b\u7279\u6b8a\u7684\u6eb6\u5242\u70ed\u6cd5\u3002\u4f7f\u7528\u591a\u5143\u9187\u4f5c\u4e3a\u6eb6\u5242\u548c\/\u6216\u8fd8\u539f\u5242\uff0c\u5df2\u88ab\u5e7f\u6cdb\u4f7f\u7528\u83b7\u5f97\u5177\u6709\u53ef\u63a7\u5f62\u6001\u7684\u4e8c\u7ef4\u91d1\u5c5e\u7eb3\u7c73\u7ed3\u6784\u3002\u8bb8\u591a\u4e0d\u540c\u7684\u591a\u5143\u9187\uff0c\u5982\u4e59\u4e8c\u9187\uff0c1,4-\u4e01\u4e8c\u9187\uff0c1,5-\u620a\u4e8c\u9187\uff0c\u4e8c\uff08\u4e59\u4e8c\u9187\uff09\uff0c\u7518\u6cb9\u548c\u805a\uff08\u4e59\u4e8c\u9187\uff09\u3002\u9664\u591a\u5143\u9187\u5916\uff0c\u8fd8\u52a0\u5165\u805a\u5408\u7269\u914d\u4f53\u4ee5\u7a33\u5b9a\u5408\u6210\u7684\u91d1\u5c5e\u7eb3\u7c73\u7ed3\u6784\u3002\u6bd4\u5982\u91d1\u5c5e\u76d0\u524d\u9a71\u4f53\u5728\u591a\u5143\u9187\u6eb6\u5242\u7684\u8fd8\u539f\u8fc7\u7a0b\u4e2d\uff0c\u65e9\u671f\u751f\u957f\u8fc7\u7a0b\u4e2d\u7684\u6e29\u5ea6\u53d8\u5316\u53ef\u4ee5\u4fc3\u8fdbAu\uff08111\uff09\u6676\u9762\u6cbf[211]\u7b49\u9ad8\u6307\u6570\u7684\u6676\u5411\u4f18\u5148\u751f\u957f\uff0c\u4ece\u800c\u5f62\u6210\u7279\u6b8a\u5f62\u8c8c\u7684\u8d85\u8584Au\u7eb3\u7c73\u7247[9]\u3002\u6709\u65f6\u5019\u5728\u591a\u5143\u9187\u8fd8\u539f\u8fc7\u7a0b\u4e2d\u53ef\u4ee5\u52a0\u5165\u5176\u5b83\u8868\u9762\u6d3b\u6027\u5242\uff0c\u6bd4\u5982\u5341\u516d\u70f7\u57fa\u4e09\u7532\u57fa\u6eb4\u5316\u94f5\uff08CTAB\uff09\uff0c\u805a\u4e19\u70ef\u9170\u80fa\uff08PAM\uff09\uff0c \u805a\u4e59\u70ef\u5421\u54af\u70f7\u916e\uff08PVP\uff09\u7b49\u3002\u8fd9\u4e9b\u8868\u9762\u6d3b\u6027\u5242\u53ef\u4ee5\u4f5c\u4e3a\u4e8c\u7ef4\u91d1\u5c5e\u7684\u8868\u9762\u7a33\u5b9a\u5242\uff0c\u4e5f\u53ef\u4ee5\u4f5c\u4e3a\u914d\u4f53\u4e0e\u91d1\u5c5e\u79bb\u5b50\u7ed3\u5408\u3002\u91d1\u5c5e\u79bb\u5b50-\u8868\u9762\u6d3b\u6027\u5242\u914d\u4f4d\u590d\u5408\u7269\u7684\u5f62\u6210\u53ef\u4ee5\u6539\u53d8\u91d1\u5c5e\u79bb\u5b50\u7684\u8fd8\u539f\u901f\u7387\uff0c\u4ece\u800c\u8fbe\u5230\u63a7\u5236\u5176\u4e8c\u7ef4\u5f62\u8c8c\u751f\u957f\u7684\u76ee\u7684\u3002<\/p>\n

2.5\u5149\u5316\u5b66\u5408\u6210\u6cd5<\/b><\/strong><\/p>\n

\u8fd1\u5e74\u6765\uff0c\u5149\u5316\u5b66\u5408\u6210\u4f5c\u4e3a\u4e00\u79cd\u72ec\u7279\u800c\u9ad8\u6548\u7684\u5408\u6210\u4e8c\u7ef4\u91d1\u5c5e\u7eb3\u7c73\u7ed3\u6784\u7684\u65b9\u6cd5\u5f97\u5230\u4e86\u5e7f\u6cdb\u7684\u5e94\u7528\u3002\u5b83\u5229\u7528\u7d2b\u5916\u6216\u8005\u53ef\u89c1\u5149\u8f90\u7167\u4f5c\u4e3a\u4e00\u79cd\u5f3a\u5927\u7684\u5de5\u5177\uff0c\u6765\u51cf\u5c11\u91d1\u5c5e\u524d\u9a71\u4f53\u7684\u8fd8\u539f\u901f\u5ea6\u548c\u8bf1\u5bfc\u4e8c\u7ef4\u91d1\u5c5e\u7eb3\u7c73\u7ed3\u6784\u7684\u5f62\u6210\u3002\u9ad8\u80fd\u7d2b\u5916\u5149\u80fd\u4f7f\u4e59\u9187\u5206\u5b50\u4ea7\u751f\u8d85\u6c27\u5316\u7269\u548c\u4e59\u6c27\u57fa\uff0c\u53ef\u4ee5\u4f5c\u4e3a\u5f3a\u8fd8\u539f\u5242\u53bb\u8fd8\u539f\u91d1\u5c5e\u79bb\u5b50\u5f97\u5230\u4e8c\u7ef4\u91d1\u5c5e\u3002\u540c\u65f6\uff0c\u4e5f\u53ef\u4ee5\u5f15\u5165\u67d0\u4e9b\u72ec\u7279\u7684\u5149\u654f\u5242\u6765\u8f85\u52a9\u91d1\u5c5e\u76d0\u7684\u8fd8\u539f\u3002\u6bd4\u5982\u4f7f\u7528\u9521\u535f\u5549(SnP)\u4f5c\u4e3a\u5149\u654f\u5242\uff0c\u5728\u5355\u5c42\u8102\u8d28\u4f53\u6a21\u677f\u7684\u4f5c\u7528\u4e0b\uff0c\u53ef\u4ee5\u5236\u5907\u5f97\u5230\u679d\u6676\u72b6\u7684\u8d85\u8584\u4e8c\u7ef4\u94c2\u7eb3\u7c73\u7247[10]\u3002\u5176\u4f5c\u7528\u673a\u5236\u662f\u5728\u53ef\u89c1\u5149\u6216\u7d2b\u5916\u5149\u4e0b\uff0c\u9521\u535f\u5549\uff08SnP\uff09\u5c06\u4ea7\u751f\u6fc0\u53d1\u7684\u03c0-\u03c0*\u72b6\u6001 \uff08SnP *\uff09\uff0cSnP *\u53ef\u4ee5\u8fc5\u901f\u7684\u88ab\u6297\u574f\u8840\u9178\u8fd8\u539f\u5f62\u6210\u81ea\u7531\u57fa\u9634\u79bb\u5b50\uff08SnP\u2014<\/sup>\u00b7<\/b><\/sup><\/strong>\uff09\u3002\u81ea\u7531\u57fa\u9634\u79bb\u5b50SnP\u2014<\/sup>\u00b7<\/b><\/sup><\/strong>\u662f\u4e00\u79cd\u5f3a\u8fd8\u539f\u5242\uff0c\u80fd\u591f\u8fd8\u539f\u591a\u79cd\u91d1\u5c5e\u79bb\u5b50\u3002\u57fa\u4e8e\u8d35\u91d1\u5c5e\u7eb3\u7c73\u7ed3\u6784\u72ec\u7279\u7684\u7b49\u79bb\u5b50\u4f53\u7684\u6027\u8d28\uff0c\u53ef\u89c1\u5149\u4e5f\u53ef\u4ee5\u88ab\u7528\u4e8e\u5408\u6210\u4e8c\u7ef4\u91d1\u5c5e\u7eb3\u7c73\u7ed3\u6784\u3002\u5728\u53ef\u89c1\u5149\u7b49\u79bb\u5b50\u4f53\u6fc0\u53d1\u94f6\u8d35\u91d1\u5c5e\u7c73\u6750\u6599\u540e\uff0c\u5176\u7eb3\u7c73\u7ed3\u6784\u53ef\u4ee5\u53d1\u751f\u5f62\u72b6\u8f6c\u5316\u3002\u57fa\u4e8e\u6b64\uff0c\u7b49\u79bb\u5b50\u4f53\u8f85\u52a9\u7684\u5408\u6210\u4e5f\u88ab\u7528\u4e8e\u5408\u6210\u4e8c\u7ef4\u91d1\u7eb3\u7c73\u7ed3\u6784\u3002\u66f4\u5177\u4f53\u7684\u8bb2\uff0c\u5229\u7528\u53ef\u89c1\u5149\u7167\u5c04\u542b\u6709\u91d1\u7eb3\u7c73\u6676\u79cd\u3001HAuCl4<\/sub>\u3001PVP\u548c\u7532\u9187\u7684\u6df7\u5408\u6eb6\u6db2\uff0c\u53ef\u4ee5\u5b9e\u73b0\u4e86\u4e8c\u7ef4\u8d85\u8584\u7eb3\u7c73Au\u516d\u8fb9\u5f62\u7684\u5f62\u6210[11]\u3002\u5728\u53ef\u89c1\u5149\u7684\u7167\u5c04\u4e0b\uff0c\u8868\u9762\u7b49\u79bb\u5b50\u4f53\u6fc0\u53d1\u4ea7\u751f\u70ed\u7535\u5b50\u7a7a\u7a74\u5bf9\uff0c\u5f53\u70ed\u7535\u5b50\u7a7a\u7a74\u5bf9\u88ab\u7532\u9187\u5feb\u901f\u6d88\u8017\u65f6\uff0c\u70ed\u7535\u5b50\u4f7fAu\u524d\u4f53\u5411\u7684\u7684\u751f\u957f\u65b9\u5411\u53d1\u751f\u6539\u53d8\u3002\u6709\u8da3\u7684\u662f\uff0cPVP\u7684\u9009\u62e9\u6027\u5438\u9644\u5728\u8fd9\u4e00\u5149\u5316\u5b66\u8fc7\u7a0b\u7684\u52a8\u529b\u5b66\u63a7\u5236\u4e2d\u53d1\u6325\u4e86\u91cd\u8981\u4f5c\u7528\u3002<\/p>\n

2.6\u7eb3\u7c73\u7c92\u5b50\u8d85\u6676\u683c\u81ea\u7ec4\u88c5<\/b><\/strong><\/p>\n

\u56fe2\u7eb3\u7c73\u7c92\u5b50\u8d85\u6676\u683c\u81ea\u7ec4\u88c5\u5408\u6210\u4e8c\u7ef4\u8d85\u8584Au\u7eb3\u7c73\u7247<\/b><\/strong><\/p>\n

\"\"<\/p>\n

\u5728\u6db2-\u6c14\uff0c\u6db2-\u6db2\u548c\u56fa-\u6db2\u754c\u9762\uff0c\u901a\u8fc7\u63a7\u5236\u754c\u9762\u5904\u7eb3\u7c73\u7c92\u5b50\u4e4b\u95f4\u7684\u5404\u5411\u5f02\u6027\u76f8\u4e92\u4f5c\u7528\uff0c\u53ef\u4ee5\u89e6\u53d1\u7eb3\u7c73\u7c92\u5b50\u7684\u4e8c\u7ef4\u81ea\u7ec4\u88c5\u3002\u8be5\u65b9\u6cd5\u53ef\u4ee5\u8bf1\u5bfc\u5f62\u6210\u5177\u6709\u8d85\u6676\u683c\u7ed3\u6784\u7684\u4e8c\u7ef4\u91d1\u5c5e\u7eb3\u7c73\u7247\uff0c\u8fd9\u662f\u4e0d\u540c\u4e8e\u4ee5\u4e0a\u5176\u4ed6\u65b9\u6cd5\u5236\u5907\u7684\u5355\u6676\u4e8c\u7ef4\u91d1\u5c5e\u3002\u4ee5\u6db2-\u6c14\u754c\u9762\u5904\u7684\u6eb6\u5242\u84b8\u53d1\u4e3a\u4f8b\uff0c\u6eb6\u5242\u7684\u6325\u53d1\u51cf\u5c11\u53ef\u7834\u574f\u80f6\u4f53\u60ac\u6d6e\u6db2\u7684\u5e73\u8861\u5e76\u8bf1\u5bfc\u5355\u5c42\u7ed3\u6784\u7684\u5f62\u6210[12]\uff0c\u6700\u7ec8\u901a\u8fc7\u8fde\u7eed\u5e72\u71e5\u8fc7\u7a0b\u5c31\u53ef\u4ee5\u5f97\u5230\u5177\u6709\u8fde\u7eed\u7684\u8d85\u6676\u683c\u7ed3\u6784\u7684\u4e8c\u7ef4\u91d1\u5c5e\u819c\uff08\u56fe2a\uff09\u3002\u57fa\u4e8e\u8fd9\u4e00\u7b56\u7565\uff0c\u53ef\u4ee5\u901a\u8fc7\u4f7f\u7528\u4e0d\u540c\u7684\u8868\u9762\u914d\u4f53\u6765\u5e73\u8861\u7eb3\u7c73\u7c92\u5b50\u4e4b\u95f4\u7684\u5f15\u529b\u548c\u65a5\u529b\u6765\u8c03\u8282\u7eb3\u7c73\u7c92\u5b50\u7684\u7ec4\u88c5\u884c\u4e3a\u3002\u5728\u5fae\u5b54\u5c01\u95ed\u3001\u5e72\u71e5\u8f85\u52a9\u7684\u7684\u81ea\u7ec4\u88c5\u8fc7\u7a0b\u4e2d\u4f7f\u752850-\u786b\u9187\u5316\u5355\u94feDNA\uff08\u53ef\u4ee5\u5c01\u7aefAu\u7eb3\u7c73\u9897\u7c92\uff09\u4f5c\u4e3a\u5e72\u71e5\u914d\u4f53\uff0c\u53ef\u4ee5\u5f97\u5230\u5355\u5c42\u4e8c\u7ef4Au\u8d85\u6676\u683c\u7eb3\u7c73\u7247\uff08\u56fe2b\uff09\u3002\u6709\u8da3\u7684\u662f\uff0c\u7ec4\u88c5\u7684Au\u7eb3\u7c73\u9897\u7c92\u7684\u5728\u5355\u5c42\u7eb3\u7c73\u7247\u7684\u5185\u90e8\u987a\u5e8f\u662f\u7531DNA\u5bc6\u5ea6\u548c\u957f\u5ea6\u51b3\u5b9a\u7684\u3002\u7531\u4e8eDNA\u957f\u5ea6\u7684\u5e7f\u6cdb\u53ef\u63a7\u6027\uff0c\u8be5\u8d85\u6676\u683c\u5177\u6709\u53ef\u8c03\u7684\u5185\u90e8\u95f4\u9699[13]\u3002<\/p>\n

2.7\u76f4\u63a5\u5265\u79bb\u6cd5<\/b><\/strong><\/p>\n

\u56fe3\u53ef\u76f4\u63a5\u5265\u79bb\u7684\u91d1\u5c5e\u7ed3\u6784\u793a\u610f\u56fe\u4ee5\u53ca\u673a\u68b0\u5265\u79bb\u548c\u6db2\u76f8\u8d85\u58f0\u5265\u79bb\u7684\u793a\u610f\u56fe<\/b><\/strong><\/p>\n

\u00a0\"\"<\/b><\/strong><\/p>\n

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2.8\u673a\u68b0\u538b\u7f29\u6cd5<\/b><\/strong><\/p>\n

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\"\"<\/p>\n

2.9\u5206\u5b50\u675f\u5916\u5ef6\u6280\u672f<\/b><\/strong><\/p>\n

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3\u5c0f\u7ed3<\/b><\/strong><\/p>\n

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\u53c2\u8003\u6587\u732e\uff1a<\/b><\/strong><\/p>\n

[1]\u00a0Ultrathin rhodium nanosheets.\u00a0N<\/i><\/em>at. Commun.<\/i><\/em>\u00a05, 3093\u00a0(2014).<\/p>\n

[2] Free-standing single-atom-thick iron membranes suspended in graphene pores.\u00a0<\/i><\/em>Science<\/i><\/em>\u00a0343, 1228\u20131232\u00a0(2014).<\/p>\n

[3] Two-dimensional gold nanostructures with high\u00a0activity for selective oxidation of carbon\u2013hydrogen\u00a0bonds. Nat. Commun.<\/i><\/em>\u00a06, 6957\u00a0(2015).<\/p>\n

[4] Synthesis of nanohole-structured single-crystalline platinum nanosheets using surfactant-liquid-crystals and their electrochemical characterization. Adv. Funct. Mater.<\/i><\/em>\u00a019, 545\u2013553\u00a0(2009).<\/p>\n

[5] Successive deposition of silver on silver nanoplates: lateral versus\u00a0vertical growth. Angew. Chem., Int. Ed.<\/i><\/em>\u00a050, 244\u2212249\u00a0(2011).<\/p>\n

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\u672c\u6587\u7531\u6750\u6599\u4eba\u79d1\u6280\u987e\u95ee\u5fb7\u6751\u00a0<\/strong>\u4f9b\u7a3f\uff0c\u7f16\u8f91\u90e8\u7f16\u8f91\u3002<\/p>\n

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